Research article
| Highlight paper
19 Nov 2015
Research article
| Highlight paper
| 19 Nov 2015
Laboratory evidence of organic peroxide and peroxyhemiacetal formation in the aqueous phase and implications for aqueous OH
Y. B. Lim and B. J. Turpin
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Cited
32 citations as recorded by crossref.
- Chemical Characterization of Secondary Organic Aerosol from Oxidation of Isoprene Hydroxyhydroperoxides M. Riva et al. 10.1021/acs.est.6b02511
- Evolution of aqSOA from the Air–Liquid Interfacial Photochemistry of Glyoxal and Hydroxyl Radicals F. Zhang et al. 10.1021/acs.est.9b03642
- Fates of Organic Hydroperoxides in Atmospheric Condensed Phases S. Enami 10.1021/acs.jpca.1c01513
- Reactive oxygen species formed in aqueous mixtures of secondary organic aerosols and mineral dust influencing cloud chemistry and public health in the Anthropocene H. Tong et al. 10.1039/C7FD00023E
- Labile Peroxides in Secondary Organic Aerosol M. Krapf et al. 10.1016/j.chempr.2016.09.007
- Aqueous-Phase Decomposition of Isoprene Hydroxy Hydroperoxide and Hydroxyl Radical Formation by Fenton-like Reactions with Iron Ions T. Fang et al. 10.1021/acs.jpca.0c02094
- Oxygenated VOCs, aqueous chemistry, and potential impacts on residential indoor air composition S. Duncan et al. 10.1111/ina.12422
- Identification of organic hydroperoxides and peroxy acids using atmospheric pressure chemical ionization–tandem mass spectrometry (APCI-MS/MS): application to secondary organic aerosol S. Zhou et al. 10.5194/amt-11-3081-2018
- Role of liquid water in the formation of O3 and SOA particles from 1,2,3-trimethylbenzene H. Luo et al. 10.1016/j.atmosenv.2019.116955
- Interfacial Dark Aging Is an Overlooked Source of Aqueous Secondary Organic Aerosol F. Zhang et al. 10.3390/atmos13020188
- Volatility Change during Droplet Evaporation of Pyruvic Acid S. Petters et al. 10.1021/acsearthspacechem.0c00044
- Isomerization and Degradation of Levoglucosan via the Photo-Fenton Process: Insights from Aqueous-Phase Experiments and Atmospheric Particulate Matter C. Yang et al. 10.1021/acs.est.0c02499
- Multiphase reactivity of gaseous hydroperoxide oligomers produced from isoprene ozonolysis in the presence of acidified aerosols M. Riva et al. 10.1016/j.atmosenv.2016.12.040
- Real-time detection of highly oxidized organosulfates and BSOA marker compounds during the F-BEACh 2014 field study M. Brüggemann et al. 10.5194/acp-17-1453-2017
- Molecular composition and photochemical evolution of water-soluble organic carbon (WSOC) extracted from field biomass burning aerosols using high-resolution mass spectrometry J. Cai et al. 10.5194/acp-20-6115-2020
- Discrepant oxidation behavior of ferric ion and hydroxyl radical on syringic acid and vanillic acid in atmospheric Fenton-like system J. Zhao et al. 10.1016/j.chemosphere.2021.132022
- Hydroxyl radicals from secondary organic aerosol decomposition in water H. Tong et al. 10.5194/acp-16-1761-2016
- A quantification method for heat-decomposable methylglyoxal oligomers and its application on 1,3,5-trimethylbenzene SOA M. Rodigast et al. 10.5194/acp-17-3929-2017
- Predominance of secondary organic aerosol to particle-bound reactive oxygen species activity in fine ambient aerosol J. Zhou et al. 10.5194/acp-19-14703-2019
- Temperature Dependence of Aqueous-Phase Decomposition of α-Hydroxyalkyl-Hydroperoxides M. Hu et al. 10.1021/acs.jpca.0c09862
- Aqueous-phase fates of α-alkoxyalkyl-hydroperoxides derived from the reactions of Criegee intermediates with alcohols M. Hu et al. 10.1039/D0CP06308H
- On the performance of carbon-based screen-printed electrodes for (in)organic hydroperoxides sensing in rainwater R. Jiménez-Pérez et al. 10.1016/j.talanta.2021.122699
- Organic Peroxides and Sulfur Dioxide in Aerosol: Source of Particulate Sulfate S. Wang et al. 10.1021/acs.est.9b02591
- Chemical signatures of surface microheterogeneity on liquid mixtures S. Enami et al. 10.1063/1.5055684
- Dark air–liquid interfacial chemistry of glyoxal and hydrogen peroxide F. Zhang et al. 10.1038/s41612-019-0085-5
- Role of Ferryl Ion Intermediates in Fast Fenton Chemistry on Aqueous Microdroplets A. Gu et al. 10.1021/acs.est.1c01962
- Introductory lecture: atmospheric chemistry in the Anthropocene B. Finlayson-Pitts 10.1039/C7FD00161D
- Photochemical organonitrate formation in wet aerosols Y. Lim et al. 10.5194/acp-16-12631-2016
- Photooxidants from brown carbon and other chromophores in illuminated particle extracts R. Kaur et al. 10.5194/acp-19-6579-2019
- Mass Spectrometry Analysis in Atmospheric Chemistry J. Laskin et al. 10.1021/acs.analchem.7b04249
- Nighttime aqueous-phase secondary organic aerosols in Los Angeles and its implication for fine particulate matter composition and oxidative potential A. Saffari et al. 10.1016/j.atmosenv.2016.03.022
- Structural and Light-Absorption Characteristics of Complex Water-Insoluble Organic Mixtures in Urban Submicrometer Aerosols Q. Chen et al. 10.1021/acs.est.7b01630
30 citations as recorded by crossref.
- Chemical Characterization of Secondary Organic Aerosol from Oxidation of Isoprene Hydroxyhydroperoxides M. Riva et al. 10.1021/acs.est.6b02511
- Evolution of aqSOA from the Air–Liquid Interfacial Photochemistry of Glyoxal and Hydroxyl Radicals F. Zhang et al. 10.1021/acs.est.9b03642
- Fates of Organic Hydroperoxides in Atmospheric Condensed Phases S. Enami 10.1021/acs.jpca.1c01513
- Reactive oxygen species formed in aqueous mixtures of secondary organic aerosols and mineral dust influencing cloud chemistry and public health in the Anthropocene H. Tong et al. 10.1039/C7FD00023E
- Labile Peroxides in Secondary Organic Aerosol M. Krapf et al. 10.1016/j.chempr.2016.09.007
- Aqueous-Phase Decomposition of Isoprene Hydroxy Hydroperoxide and Hydroxyl Radical Formation by Fenton-like Reactions with Iron Ions T. Fang et al. 10.1021/acs.jpca.0c02094
- Oxygenated VOCs, aqueous chemistry, and potential impacts on residential indoor air composition S. Duncan et al. 10.1111/ina.12422
- Identification of organic hydroperoxides and peroxy acids using atmospheric pressure chemical ionization–tandem mass spectrometry (APCI-MS/MS): application to secondary organic aerosol S. Zhou et al. 10.5194/amt-11-3081-2018
- Role of liquid water in the formation of O3 and SOA particles from 1,2,3-trimethylbenzene H. Luo et al. 10.1016/j.atmosenv.2019.116955
- Interfacial Dark Aging Is an Overlooked Source of Aqueous Secondary Organic Aerosol F. Zhang et al. 10.3390/atmos13020188
- Volatility Change during Droplet Evaporation of Pyruvic Acid S. Petters et al. 10.1021/acsearthspacechem.0c00044
- Isomerization and Degradation of Levoglucosan via the Photo-Fenton Process: Insights from Aqueous-Phase Experiments and Atmospheric Particulate Matter C. Yang et al. 10.1021/acs.est.0c02499
- Multiphase reactivity of gaseous hydroperoxide oligomers produced from isoprene ozonolysis in the presence of acidified aerosols M. Riva et al. 10.1016/j.atmosenv.2016.12.040
- Real-time detection of highly oxidized organosulfates and BSOA marker compounds during the F-BEACh 2014 field study M. Brüggemann et al. 10.5194/acp-17-1453-2017
- Molecular composition and photochemical evolution of water-soluble organic carbon (WSOC) extracted from field biomass burning aerosols using high-resolution mass spectrometry J. Cai et al. 10.5194/acp-20-6115-2020
- Discrepant oxidation behavior of ferric ion and hydroxyl radical on syringic acid and vanillic acid in atmospheric Fenton-like system J. Zhao et al. 10.1016/j.chemosphere.2021.132022
- Hydroxyl radicals from secondary organic aerosol decomposition in water H. Tong et al. 10.5194/acp-16-1761-2016
- A quantification method for heat-decomposable methylglyoxal oligomers and its application on 1,3,5-trimethylbenzene SOA M. Rodigast et al. 10.5194/acp-17-3929-2017
- Predominance of secondary organic aerosol to particle-bound reactive oxygen species activity in fine ambient aerosol J. Zhou et al. 10.5194/acp-19-14703-2019
- Temperature Dependence of Aqueous-Phase Decomposition of α-Hydroxyalkyl-Hydroperoxides M. Hu et al. 10.1021/acs.jpca.0c09862
- Aqueous-phase fates of α-alkoxyalkyl-hydroperoxides derived from the reactions of Criegee intermediates with alcohols M. Hu et al. 10.1039/D0CP06308H
- On the performance of carbon-based screen-printed electrodes for (in)organic hydroperoxides sensing in rainwater R. Jiménez-Pérez et al. 10.1016/j.talanta.2021.122699
- Organic Peroxides and Sulfur Dioxide in Aerosol: Source of Particulate Sulfate S. Wang et al. 10.1021/acs.est.9b02591
- Chemical signatures of surface microheterogeneity on liquid mixtures S. Enami et al. 10.1063/1.5055684
- Dark air–liquid interfacial chemistry of glyoxal and hydrogen peroxide F. Zhang et al. 10.1038/s41612-019-0085-5
- Role of Ferryl Ion Intermediates in Fast Fenton Chemistry on Aqueous Microdroplets A. Gu et al. 10.1021/acs.est.1c01962
- Introductory lecture: atmospheric chemistry in the Anthropocene B. Finlayson-Pitts 10.1039/C7FD00161D
- Photochemical organonitrate formation in wet aerosols Y. Lim et al. 10.5194/acp-16-12631-2016
- Photooxidants from brown carbon and other chromophores in illuminated particle extracts R. Kaur et al. 10.5194/acp-19-6579-2019
- Mass Spectrometry Analysis in Atmospheric Chemistry J. Laskin et al. 10.1021/acs.analchem.7b04249
2 citations as recorded by crossref.
- Nighttime aqueous-phase secondary organic aerosols in Los Angeles and its implication for fine particulate matter composition and oxidative potential A. Saffari et al. 10.1016/j.atmosenv.2016.03.022
- Structural and Light-Absorption Characteristics of Complex Water-Insoluble Organic Mixtures in Urban Submicrometer Aerosols Q. Chen et al. 10.1021/acs.est.7b01630
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Latest update: 02 Jul 2022
Short summary
This paper demonstrates organic peroxide and peroxyhemiacetal formation during aqueous photooxidation of methylglyoxal using ultra-high-resolution Fourier transform ion cyclotron resonance electrospray ionization mass spectrometry (FTICR-MS). Then, we provide simulation results of organic peroxide/peroxyhemiacetal formation in clouds and wet aerosols and discuss organic peroxides as a source of condensed-phase OH radicals and as a contributor to aqueous secondary organic aerosol (SOA).
This paper demonstrates organic peroxide and peroxyhemiacetal formation during aqueous...
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