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Volume 15, issue 19
Atmos. Chem. Phys., 15, 11243–11256, 2015
https://doi.org/10.5194/acp-15-11243-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.

Special issue: Oxidant Production over Antarctic Land and its Export...

Atmos. Chem. Phys., 15, 11243–11256, 2015
https://doi.org/10.5194/acp-15-11243-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 09 Oct 2015

Research article | 09 Oct 2015

Isotopic effects of nitrate photochemistry in snow: a field study at Dome C, Antarctica

T. A. Berhanu et al.

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In this field study at Dome C, Antarctica, we investigated the effect of solar UV photolysis on the stable isotopes of nitrate in snow via comparison of two identical snow pits while exposing only one to solar UV. From the difference between the average isotopic fractionations calculated for each pit, we determined a purely photolytic nitrogen isotopic fractionation of -55.8‰, in good agreement with what has been recently determined in a laboratory study.
In this field study at Dome C, Antarctica, we investigated the effect of solar UV photolysis on...
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