Articles | Volume 15, issue 18
https://doi.org/10.5194/acp-15-10799-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-15-10799-2015
© Author(s) 2015. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
29 Sep 2015
Research article |
| 29 Sep 2015
The NOx dependence of bromine chemistry in the Arctic atmospheric boundary layer
K. D. Custard
CORRESPONDING AUTHOR
Department of Chemistry, Purdue University, West Lafayette, IN, USA
C. R. Thompson
Department of Chemistry, Purdue University, West Lafayette, IN, USA
now at: Chemical Sciences Division, National Oceanic and Atmospheric Administration, Boulder, CO, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, CO, USA
K. A. Pratt
Department of Chemistry, Purdue University, West Lafayette, IN, USA
Department of Chemistry, University of Michigan, Ann Arbor, MI, USA
P B. Shepson
Department of Chemistry, Purdue University, West Lafayette, IN, USA
Department of Earth, Atmospheric, and Planetary Sciences & Purdue Climate Change Research Center, Purdue University, West Lafayette, IN, USA
J. Liao
School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta, GA, USA
Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, CO, USA
Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO, USA
L. G. Huey
School of Earth and Atmospheric Sciences, Georgia Institute of Technology, Atlanta, GA, USA
J. J. Orlando
National Center for Atmospheric Research, Boulder, CO, USA
A. J. Weinheimer
National Center for Atmospheric Research, Boulder, CO, USA
National Center for Atmospheric Research, Boulder, CO, USA
S. R. Hall
National Center for Atmospheric Research, Boulder, CO, USA
F. Flocke
National Center for Atmospheric Research, Boulder, CO, USA
L. Mauldin
National Center for Atmospheric Research, Boulder, CO, USA
now at: Atmospheric and Ocean Sciences, University of Colorado, Boulder, CO, USA
R. S. Hornbrook
National Center for Atmospheric Research, Boulder, CO, USA
D. Pöhler
Institute of Environmental Physics, University of Heidelberg, Heidelberg, Germany
S. General
Institute of Environmental Physics, University of Heidelberg, Heidelberg, Germany
J. Zielcke
Institute of Environmental Physics, University of Heidelberg, Heidelberg, Germany
W. R. Simpson
Geophysical Institute and Department of Chemistry, University of Alaska Fairbanks, Fairbanks, AK, USA
U. Platt
Institute of Environmental Physics, University of Heidelberg, Heidelberg, Germany
A. Fried
Institute of Arctic and Alpine Research, University of Colorado, Boulder, CO, USA
P. Weibring
Institute of Arctic and Alpine Research, University of Colorado, Boulder, CO, USA
B. C. Sive
National Park Service, Air Resources Division, Lakewood, CO, USA
K. Ullmann
National Center for Atmospheric Research, Boulder, CO, USA
C. Cantrell
National Center for Atmospheric Research, Boulder, CO, USA
now at: Atmospheric and Ocean Sciences, University of Colorado, Boulder, CO, USA
D. J. Knapp
National Center for Atmospheric Research, Boulder, CO, USA
D. D. Montzka
National Center for Atmospheric Research, Boulder, CO, USA
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Cited
29 citations as recorded by crossref.
- Sensitivity of the Reaction Mechanism of the Ozone Depletion Events during the Arctic Spring on the Initial Atmospheric Composition of the Troposphere L. Cao et al. https://doi.org/10.3390/atmos7100124
- Tropospheric bromine monoxide vertical profiles retrieved across the Alaskan Arctic in springtime N. Brockway et al. https://doi.org/10.5194/acp-24-23-2024
- Nitrosyl iodide, INO: A combined ab initio and high-resolution spectroscopic study S. Bailleux et al. https://doi.org/10.1016/j.cplett.2016.02.069
- Bromine atom production and chain propagation during springtime Arctic ozone depletion events in Barrow, Alaska C. Thompson et al. https://doi.org/10.5194/acp-17-3401-2017
- Springtime Bromine Activation over Coastal and Inland Arctic Snowpacks P. Peterson et al. https://doi.org/10.1021/acsearthspacechem.8b00083
- A pivotal role for air pollution during rapid Arctic change S. Arnold et al. https://doi.org/10.1525/elementa.2025.00129
- Interactions of bromine, chlorine, and iodine photochemistry during ozone depletions in Barrow, Alaska C. Thompson et al. https://doi.org/10.5194/acp-15-9651-2015
- Polar boundary layer bromine explosion and ozone depletion events in the chemistry–climate model EMAC v2.52: implementation and evaluation of AirSnow algorithm S. Falk & B. Sinnhuber https://doi.org/10.5194/gmd-11-1115-2018
- Thermodynamics limits the reactivity of BrHg radical with volatile organic compounds T. Dibble & A. Schwid https://doi.org/10.1016/j.cplett.2016.07.065
- Arctic tropospheric ozone seasonality, depletion, and oil field influence E. Widmaier et al. https://doi.org/10.1039/D4FD00166D
- Time-dependent 3D simulations of tropospheric ozone depletion events in the Arctic spring using the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) M. Herrmann et al. https://doi.org/10.5194/acp-21-7611-2021
- Observation of BrO and ozone precursors in Hangzhou Bay using MAX-DOAS: Anthropogenic-marine coupling and potential source contribution . LV Chaonan et al. https://doi.org/10.7498/aps.75.20260587
- BrO and inferred Bry profiles over the western Pacific: relevance of inorganic bromine sources and a Bry minimum in the aged tropical tropopause layer T. Koenig et al. https://doi.org/10.5194/acp-17-15245-2017
- Influence of the Background Nitrogen Oxides on the Tropospheric Ozone Depletion Events in the Arctic during Springtime J. Zhou et al. https://doi.org/10.3390/atmos11040344
- Polar oceans and sea ice in a changing climate M. Willis et al. https://doi.org/10.1525/elementa.2023.00056
- Arctic Reactive Bromine Events Occur in Two Distinct Sets of Environmental Conditions: A Statistical Analysis of 6 Years of Observations W. Swanson et al. https://doi.org/10.1029/2019JD032139
- Tropospheric Halogen Photochemistry in the Rapidly Changing Arctic K. Pratt https://doi.org/10.1016/j.trechm.2019.06.001
- Quantifying the nitrogen isotope effects during photochemical equilibrium between NO and NO2: implications for δ15N in tropospheric reactive nitrogen J. Li et al. https://doi.org/10.5194/acp-20-9805-2020
- A Dual-Perspective Analysis of Ozone Formation Sensitivity in the Yangtze River Delta: Satellite and Ground-Based Evidence K. Cheng et al. https://doi.org/10.3390/rs18142336
- Molecular Halogens Above the Arctic Snowpack: Emissions, Diurnal Variations, and Recycling Mechanisms S. Wang & K. Pratt https://doi.org/10.1002/2017JD027175
- Troposphere–stratosphere-integrated bromine monoxide (BrO) profile retrieval over the central Pacific Ocean T. Koenig et al. https://doi.org/10.5194/amt-17-5911-2024
- Bromine Chloride in the Coastal Arctic: Diel Patterns and Production Mechanisms S. McNamara et al. https://doi.org/10.1021/acsearthspacechem.0c00021
- Impacts of Arctic oil field NOx emissions on downwind bromine chemistry: insights from 5 years of MAX-DOAS observations P. Peterson et al. https://doi.org/10.1039/D4FD00164H
- Springtime Nitrogen Oxide-Influenced Chlorine Chemistry in the Coastal Arctic S. McNamara et al. https://doi.org/10.1021/acs.est.9b01797
- Constraints on Arctic Atmospheric Chlorine Production through Measurements and Simulations of Cl2 and ClO K. Custard et al. https://doi.org/10.1021/acs.est.6b03909
- BrHgO• + C2H4 and BrHgO• + HCHO in Atmospheric Oxidation of Mercury: Determining Rate Constants of Reactions with Prereactive Complexes and Bifurcation K. Lam et al. https://doi.org/10.1021/acs.jpca.9b05120
- Atmospheric Chemistry of HOHg(II)O• Mimics That of a Hydroxyl Radical D. Hewa Edirappulige et al. https://doi.org/10.1021/acs.jpca.3c04159
- The Role of Snow in Controlling Halogen Chemistry and Boundary Layer Oxidation During Arctic Spring: A 1D Modeling Case Study S. Ahmed et al. https://doi.org/10.1029/2021JD036140
- Computational Study on the Photolysis of BrHgONO and the Reactions of BrHgO• with CH4, C2H6, NO, and NO2: Implications for Formation of Hg(II) Compounds in the Atmosphere K. Lam et al. https://doi.org/10.1021/acs.jpca.8b11216
29 citations as recorded by crossref.
- Sensitivity of the Reaction Mechanism of the Ozone Depletion Events during the Arctic Spring on the Initial Atmospheric Composition of the Troposphere L. Cao et al. https://doi.org/10.3390/atmos7100124
- Tropospheric bromine monoxide vertical profiles retrieved across the Alaskan Arctic in springtime N. Brockway et al. https://doi.org/10.5194/acp-24-23-2024
- Nitrosyl iodide, INO: A combined ab initio and high-resolution spectroscopic study S. Bailleux et al. https://doi.org/10.1016/j.cplett.2016.02.069
- Bromine atom production and chain propagation during springtime Arctic ozone depletion events in Barrow, Alaska C. Thompson et al. https://doi.org/10.5194/acp-17-3401-2017
- Springtime Bromine Activation over Coastal and Inland Arctic Snowpacks P. Peterson et al. https://doi.org/10.1021/acsearthspacechem.8b00083
- A pivotal role for air pollution during rapid Arctic change S. Arnold et al. https://doi.org/10.1525/elementa.2025.00129
- Interactions of bromine, chlorine, and iodine photochemistry during ozone depletions in Barrow, Alaska C. Thompson et al. https://doi.org/10.5194/acp-15-9651-2015
- Polar boundary layer bromine explosion and ozone depletion events in the chemistry–climate model EMAC v2.52: implementation and evaluation of AirSnow algorithm S. Falk & B. Sinnhuber https://doi.org/10.5194/gmd-11-1115-2018
- Thermodynamics limits the reactivity of BrHg radical with volatile organic compounds T. Dibble & A. Schwid https://doi.org/10.1016/j.cplett.2016.07.065
- Arctic tropospheric ozone seasonality, depletion, and oil field influence E. Widmaier et al. https://doi.org/10.1039/D4FD00166D
- Time-dependent 3D simulations of tropospheric ozone depletion events in the Arctic spring using the Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) M. Herrmann et al. https://doi.org/10.5194/acp-21-7611-2021
- Observation of BrO and ozone precursors in Hangzhou Bay using MAX-DOAS: Anthropogenic-marine coupling and potential source contribution . LV Chaonan et al. https://doi.org/10.7498/aps.75.20260587
- BrO and inferred Bry profiles over the western Pacific: relevance of inorganic bromine sources and a Bry minimum in the aged tropical tropopause layer T. Koenig et al. https://doi.org/10.5194/acp-17-15245-2017
- Influence of the Background Nitrogen Oxides on the Tropospheric Ozone Depletion Events in the Arctic during Springtime J. Zhou et al. https://doi.org/10.3390/atmos11040344
- Polar oceans and sea ice in a changing climate M. Willis et al. https://doi.org/10.1525/elementa.2023.00056
- Arctic Reactive Bromine Events Occur in Two Distinct Sets of Environmental Conditions: A Statistical Analysis of 6 Years of Observations W. Swanson et al. https://doi.org/10.1029/2019JD032139
- Tropospheric Halogen Photochemistry in the Rapidly Changing Arctic K. Pratt https://doi.org/10.1016/j.trechm.2019.06.001
- Quantifying the nitrogen isotope effects during photochemical equilibrium between NO and NO2: implications for δ15N in tropospheric reactive nitrogen J. Li et al. https://doi.org/10.5194/acp-20-9805-2020
- A Dual-Perspective Analysis of Ozone Formation Sensitivity in the Yangtze River Delta: Satellite and Ground-Based Evidence K. Cheng et al. https://doi.org/10.3390/rs18142336
- Molecular Halogens Above the Arctic Snowpack: Emissions, Diurnal Variations, and Recycling Mechanisms S. Wang & K. Pratt https://doi.org/10.1002/2017JD027175
- Troposphere–stratosphere-integrated bromine monoxide (BrO) profile retrieval over the central Pacific Ocean T. Koenig et al. https://doi.org/10.5194/amt-17-5911-2024
- Bromine Chloride in the Coastal Arctic: Diel Patterns and Production Mechanisms S. McNamara et al. https://doi.org/10.1021/acsearthspacechem.0c00021
- Impacts of Arctic oil field NOx emissions on downwind bromine chemistry: insights from 5 years of MAX-DOAS observations P. Peterson et al. https://doi.org/10.1039/D4FD00164H
- Springtime Nitrogen Oxide-Influenced Chlorine Chemistry in the Coastal Arctic S. McNamara et al. https://doi.org/10.1021/acs.est.9b01797
- Constraints on Arctic Atmospheric Chlorine Production through Measurements and Simulations of Cl2 and ClO K. Custard et al. https://doi.org/10.1021/acs.est.6b03909
- BrHgO• + C2H4 and BrHgO• + HCHO in Atmospheric Oxidation of Mercury: Determining Rate Constants of Reactions with Prereactive Complexes and Bifurcation K. Lam et al. https://doi.org/10.1021/acs.jpca.9b05120
- Atmospheric Chemistry of HOHg(II)O• Mimics That of a Hydroxyl Radical D. Hewa Edirappulige et al. https://doi.org/10.1021/acs.jpca.3c04159
- The Role of Snow in Controlling Halogen Chemistry and Boundary Layer Oxidation During Arctic Spring: A 1D Modeling Case Study S. Ahmed et al. https://doi.org/10.1029/2021JD036140
- Computational Study on the Photolysis of BrHgONO and the Reactions of BrHgO• with CH4, C2H6, NO, and NO2: Implications for Formation of Hg(II) Compounds in the Atmosphere K. Lam et al. https://doi.org/10.1021/acs.jpca.8b11216
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