Articles | Volume 14, issue 13
Atmos. Chem. Phys., 14, 6925–6940, 2014
Atmos. Chem. Phys., 14, 6925–6940, 2014

Research article 04 Jul 2014

Research article | 04 Jul 2014

Factors controlling pollutant plume length downwind of major roadways in nocturnal surface inversions

W. Choi1, A. M. Winer2, and S. E. Paulson1 W. Choi et al.
  • 1University of California, Los Angeles, Department of Atmospheric and Oceanic Sciences, Los Angeles, California, USA
  • 2University of California, Los Angeles, School of Public Health, Environmental Health Sciences Department, Los Angeles, California, USA

Abstract. A fitting method using a semi-empirical Gaussian dispersion model solution was successfully applied to obtain both dispersion coefficients and a particle number emission factor (PNEF) directly from ultrafine particle (UFP; particles smaller than <0.1 μm in diameter) concentration profiles observed downwind of major roadways in California's South Coast Air Basin (SoCAB). The effective Briggs' formulation for the vertical dispersion parameter σz was adopted in this study due to its better performance in describing the observed profiles compared to other formulations examined. The two dispersion coefficients in Briggs' formulation, α and β, ranged from 0.02 to 0.07 and from −0.5 × 10−3 to 2.8 × 10−3, respectively, for the four freeway transects studied and are significantly different for freeways passing over vs. under the street on which measurements of the freeway plume were made. These ranges are wider than literature values for α and β under stable conditions. The dispersion coefficients derived from observations showed strong correlations with both surface meteorology (wind speed/direction, temperature, and air stability) and differences in concentrations between the background and plume peak. The relationships were applied to predict freeway plume transport using a multivariate regression, and produced excellent agreement with observed UFP concentration profiles. The mean PNEF for a mixed vehicle fleet on the four freeways was estimated as 7.5 × 1013 particles km−1 vehicle−1, which is about 15% of the value estimated in 2001 for the I-405 freeway, implying significant reductions in UFP emissions over the past decade in the SoCAB.

Final-revised paper