Research article
07 Apr 2014
Research article
| 07 Apr 2014
Chlorine as a primary radical: evaluation of methods to understand its role in initiation of oxidative cycles
C. J. Young et al.
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Cited
70 citations as recorded by crossref.
- Kinetic Measurements of Cl Atom Reactions with C5–C8 Unsaturated Alcohols A. Grira et al. 10.3390/atmos11030256
- Long-chain alkanes in the atmosphere: A review J. Li et al. 10.1016/j.jes.2021.07.021
- Measurements of Total OH Reactivity During CalNex‐LA R. Hansen et al. 10.1029/2020JD032988
- Increases in wintertime PM2.5 sodium and chloride linked to snowfall and road salt application K. Kolesar et al. 10.1016/j.atmosenv.2018.01.008
- Multiphase Photochemistry of Iron-Chloride Containing Particles as a Source of Aqueous Chlorine Radicals and Its Effect on Sulfate Production M. Gen et al. 10.1021/acs.est.0c01540
- Formation of oxidized organic compounds from Cl-initiated oxidation of toluene S. Dhulipala et al. 10.1016/j.atmosenv.2018.11.002
- Tropospheric ozone and its precursors from the urban to the global scale from air quality to short-lived climate forcer P. Monks et al. 10.5194/acp-15-8889-2015
- Quantum Chemical Study on ·Cl-Initiated Atmospheric Degradation of Monoethanolamine H. Xie et al. 10.1021/acs.est.5b03324
- Significant concentrations of nitryl chloride sustained in the morning: investigations of the causes and impacts on ozone production in a polluted region of northern China Y. Tham et al. 10.5194/acp-16-14959-2016
- Anthropogenic Photolabile Chlorine in the Cold-Climate City of Montreal R. Hall et al. 10.3390/atmos11080812
- Urban inland wintertime N<sub>2</sub>O<sub>5</sub> and ClNO<sub>2</sub> influenced by snow-covered ground, air turbulence, and precipitation K. Kulju et al. 10.5194/acp-22-2553-2022
- Significant impact of heterogeneous reactions of reactive chlorine species on summertime atmospheric ozone and free-radical formation in north China X. Qiu et al. 10.1016/j.scitotenv.2019.133580
- Model simulation of NO 3 , N 2 O 5 and ClNO 2 at a rural site in Beijing during CAREBeijing-2006 H. Wang et al. 10.1016/j.atmosres.2017.06.013
- Reaction of Methyl Fluoroformyl Peroxycarbonate (FC(O)OOC(O)OCH3) with Cl Atoms: Formation of Hydro-ChloroFluoro-Peroxides M. Berasategui et al. 10.1021/acs.jpca.7b07449
- Oxidation of HOSO˙ by Cl˙: a new source of SO2 in the atmosphere? A. Kumar et al. 10.1039/D1CP01048D
- Development of a chlorine chemistry module for the Master Chemical Mechanism L. Xue et al. 10.5194/gmd-8-3151-2015
- A theoretical study of the mechanism of the atmospherically relevant reaction of chlorine atoms with methyl nitrate, and calculation of the reaction rate coefficients at temperatures relevant to the troposphere M. Ng et al. 10.1039/C4CP06007E
- Simulation Verification of Barrierless HONO Formation from the Oxidation Reaction System of NO, Cl, and Water in the Atmosphere X. Zhao et al. 10.1021/acs.est.1c01773
- Evidence for strong, widespread chlorine radical chemistry associated with pollution outflow from continental Asia A. Baker et al. 10.1038/srep36821
- Ubiquity of ClNO2 in the urban boundary layer of Calgary, Alberta, Canada L. Mielke et al. 10.1139/cjc-2015-0426
- Introductory lecture: atmospheric chemistry in the Anthropocene B. Finlayson-Pitts 10.1039/C7FD00161D
- High Levels of Daytime Molecular Chlorine and Nitryl Chloride at a Rural Site on the North China Plain X. Liu et al. 10.1021/acs.est.7b03039
- Atmospheric oxidation mechanism and kinetics of isoprene initiated by chlorine radicals: A computational study X. Guo et al. 10.1016/j.scitotenv.2019.136330
- Modeling the impact of heterogeneous reactions of chlorine on summertime nitrate formation in Beijing, China X. Qiu et al. 10.5194/acp-19-6737-2019
- Reactions of Three Lactones with Cl, OD, and O3: Atmospheric Impact and Trends in Furan Reactivity S. Ausmeel et al. 10.1021/acs.jpca.7b02325
- Experimental and Computational Studies of Criegee Intermediate syn-CH3CHOO Reaction with Hydrogen Chloride S. Liu et al. 10.1021/acs.jpca.1c05578
- The gas phase oxidation of HCOOH by Cl and NH2 radicals. Proton coupled electron transfer versus hydrogen atom transfer J. Anglada et al. 10.1080/00268976.2018.1554829
- The Atmospherically Important Reaction of Hydroxyl Radicals with Methyl Nitrate: A Theoretical Study Involving the Calculation of Reaction Mechanisms, Enthalpies, Activation Energies, and Rate Coefficients M. Ng et al. 10.1021/acs.jpca.7b05035
- Constraints on Arctic Atmospheric Chlorine Production through Measurements and Simulations of Cl2 and ClO K. Custard et al. 10.1021/acs.est.6b03909
- Anthropogenic Control Over Wintertime Oxidation of Atmospheric Pollutants J. Haskins et al. 10.1029/2019GL085498
- Winter ClNO<sub>2</sub> formation in the region of fresh anthropogenic emissions: seasonal variability and insights into daytime peaks in northern China M. Xia et al. 10.5194/acp-21-15985-2021
- N<sub>2</sub>O<sub>5</sub> uptake onto saline mineral dust: a potential missing source of tropospheric ClNO<sub>2</sub> in inland China H. Wang et al. 10.5194/acp-22-1845-2022
- Barrierless HNO3 formation from the hydrolysis reaction of NO2 with Cl atom in the atmosphere X. Zhao et al. 10.1016/j.atmosenv.2021.118871
- Observations of gas phase hydrochloric acid in the polluted marine boundary layer T. Crisp et al. 10.1002/2013JD020992
- Gas-Phase Chlorine Radical Oxidation of Alkanes: Effects of Structural Branching, NOx, and Relative Humidity Observed during Environmental Chamber Experiments L. Jahn et al. 10.1021/acs.jpca.1c03516
- Formation and emission of hydrogen chloride in indoor air K. Dawe et al. 10.1111/ina.12509
- Understanding Sources of Atmospheric Hydrogen Chloride in Coastal Spring and Continental Winter A. Angelucci et al. 10.1021/acsearthspacechem.1c00193
- Reactions of tropospheric oxidants- Cl, OH and O3 with cyclic hydrocarbons with eight carbon atoms at 298 K A. Sharma et al. 10.1016/j.atmosenv.2019.06.024
- Climate engineering by mimicking natural dust climate control: the iron salt aerosol method F. Oeste et al. 10.5194/esd-8-1-2017
- Non-methane hydrocarbon (C<sub>2</sub>–C<sub>8</sub>) sources and sinks around the Arabian Peninsula E. Bourtsoukidis et al. 10.5194/acp-19-7209-2019
- Atmospheric oxidation of C10~14 n-alkanes initiated by Cl atoms: Kinetics and mechanism B. Shi et al. 10.1016/j.atmosenv.2019.117166
- A theoretical investigation of the atmospherically important reaction between chlorine atoms and formic acid: determination of the reaction mechanism and calculation of the rate coefficient at different temperatures M. Ng et al. 10.1080/00268976.2014.980448
- Tropospheric chemistry of ethyl tiglate initiated by Cl atoms C. Ramya & B. Rajakumar 10.1016/j.cplett.2020.137371
- Study of Secondary Organic Aerosol Formation from Chlorine Radical-Initiated Oxidation of Volatile Organic Compounds in a Polluted Atmosphere Using a 3D Chemical Transport Model M. Choi et al. 10.1021/acs.est.0c02958
- Factors affecting wavelength‐resolved ultraviolet irradiance indoors and their impacts on indoor photochemistry S. Zhou et al. 10.1111/ina.12784
- Gas-phase reaction of two unsaturated ketones with atomic Cl and O3: kinetics and products J. Wang et al. 10.1039/C4CP05461J
- Computational Study of the Reactions of Chlorine Radicals with Atmospheric Organic Compounds Featuring NHx–π-Bond (x = 1, 2) Structures H. Xie et al. 10.1021/acs.jpca.6b11418
- Anthropogenic Impacts on Tropospheric Reactive Chlorine Since the Preindustrial S. Zhai et al. 10.1029/2021GL093808
- Tropospheric Halogen Chemistry: Sources, Cycling, and Impacts W. Simpson et al. 10.1021/cr5006638
- Chlorine-initiated oxidation of <i>n</i>-alkanes under high-NO<sub><i>x</i></sub> conditions: insights into secondary organic aerosol composition and volatility using a FIGAERO–CIMS D. Wang & L. Hildebrandt Ruiz 10.5194/acp-18-15535-2018
- Primary vs. secondary H-atom abstraction in the Cl-atom reaction with n-pentane S. Pandit et al. 10.1039/C6CP07164C
- Reactions of lactones with tropospheric oxidants: A kinetics and products study M. Walavalkar et al. 10.1016/j.atmosenv.2017.04.028
- Cl-Atom-Initiated Atmospheric Degradation of Saturated Cyclic Hydrocarbons: Kinetic and Mechanistic Investigation R. Cheramangalath Balan & B. Rajakumar 10.1021/acs.jpca.9b02225
- Study on the reaction of 3-methyl-2-butenal and 3-methylbutanal with Cl atoms: kinetics and reaction mechanism B. Shi et al. 10.1016/j.jes.2021.03.032
- Seasonal and geographical variability of nitryl chloride and its precursors in Northern Europe R. Sommariva et al. 10.1002/asl.844
- Atmospheric Chemistry of Volatile Methyl Siloxanes: Kinetics and Products of Oxidation by OH Radicals and Cl Atoms M. Alton & E. Browne 10.1021/acs.est.0c01368
- Atmospheric Oxidation of Piperazine Initiated by ·Cl: Unexpected High Nitrosamine Yield F. Ma et al. 10.1021/acs.est.8b02510
- Validation of a new cavity ring-down spectrometer for measuring tropospheric gaseous hydrogen chloride T. Furlani et al. 10.5194/amt-14-5859-2021
- Secondary organic aerosol from chlorine-initiated oxidation of isoprene D. Wang & L. Ruiz 10.5194/acp-17-13491-2017
- Low levels of nitryl chloride at ground level: nocturnal nitrogen oxides in the Lower Fraser Valley of British Columbia H. Osthoff et al. 10.5194/acp-18-6293-2018
- Computational study on the mechanism and kinetics of Cl-initiated oxidation of ethyl acrylate S. Zhang et al. 10.1007/s11224-017-0967-2
- Springtime Nitrogen Oxide-Influenced Chlorine Chemistry in the Coastal Arctic S. McNamara et al. 10.1021/acs.est.9b01797
- Integration of airborne and ground observations of nitryl chloride in the Seoul metropolitan area and the implications on regional oxidation capacity during KORUS-AQ 2016 D. Jeong et al. 10.5194/acp-19-12779-2019
- Observation of N2O5 Deposition and ClNO2 Production on the Saline Snowpack S. McNamara et al. 10.1021/acsearthspacechem.0c00317
- Photodissociation of Benzoyl Chloride: A Velocity Map Imaging Study Using VUV Detection of Chlorine Atoms C. Matthaei et al. 10.1021/acs.jpca.0c11236
- Modeling the impact of chlorine emissions from coal combustion and prescribed waste incineration on tropospheric ozone formation in China Y. Liu et al. 10.5194/acp-18-2709-2018
- Theoretical investigation on mechanisms and kinetics of the reactions of Cl atom with CH3OOH and CH3CH2OOH F. Liu et al. 10.1016/j.comptc.2014.04.011
- An MCM modeling study of nitryl chloride (ClNO<sub>2</sub>) impacts on oxidation, ozone production and nitrogen oxide partitioning in polluted continental outflow T. Riedel et al. 10.5194/acp-14-3789-2014
- The primary and recycling sources of OH during the NACHTT-2011 campaign: HONO as an important OH primary source in the wintertime S. Kim et al. 10.1002/2013JD019784
- The reaction mechanisms and kinetics of CF3CHFOCH3 and CHF2CHFOCF3 with atomic chlorine: a computational study F. Liu et al. 10.1007/s00894-014-2435-x
66 citations as recorded by crossref.
- Kinetic Measurements of Cl Atom Reactions with C5–C8 Unsaturated Alcohols A. Grira et al. 10.3390/atmos11030256
- Long-chain alkanes in the atmosphere: A review J. Li et al. 10.1016/j.jes.2021.07.021
- Measurements of Total OH Reactivity During CalNex‐LA R. Hansen et al. 10.1029/2020JD032988
- Increases in wintertime PM2.5 sodium and chloride linked to snowfall and road salt application K. Kolesar et al. 10.1016/j.atmosenv.2018.01.008
- Multiphase Photochemistry of Iron-Chloride Containing Particles as a Source of Aqueous Chlorine Radicals and Its Effect on Sulfate Production M. Gen et al. 10.1021/acs.est.0c01540
- Formation of oxidized organic compounds from Cl-initiated oxidation of toluene S. Dhulipala et al. 10.1016/j.atmosenv.2018.11.002
- Tropospheric ozone and its precursors from the urban to the global scale from air quality to short-lived climate forcer P. Monks et al. 10.5194/acp-15-8889-2015
- Quantum Chemical Study on ·Cl-Initiated Atmospheric Degradation of Monoethanolamine H. Xie et al. 10.1021/acs.est.5b03324
- Significant concentrations of nitryl chloride sustained in the morning: investigations of the causes and impacts on ozone production in a polluted region of northern China Y. Tham et al. 10.5194/acp-16-14959-2016
- Anthropogenic Photolabile Chlorine in the Cold-Climate City of Montreal R. Hall et al. 10.3390/atmos11080812
- Urban inland wintertime N<sub>2</sub>O<sub>5</sub> and ClNO<sub>2</sub> influenced by snow-covered ground, air turbulence, and precipitation K. Kulju et al. 10.5194/acp-22-2553-2022
- Significant impact of heterogeneous reactions of reactive chlorine species on summertime atmospheric ozone and free-radical formation in north China X. Qiu et al. 10.1016/j.scitotenv.2019.133580
- Model simulation of NO 3 , N 2 O 5 and ClNO 2 at a rural site in Beijing during CAREBeijing-2006 H. Wang et al. 10.1016/j.atmosres.2017.06.013
- Reaction of Methyl Fluoroformyl Peroxycarbonate (FC(O)OOC(O)OCH3) with Cl Atoms: Formation of Hydro-ChloroFluoro-Peroxides M. Berasategui et al. 10.1021/acs.jpca.7b07449
- Oxidation of HOSO˙ by Cl˙: a new source of SO2 in the atmosphere? A. Kumar et al. 10.1039/D1CP01048D
- Development of a chlorine chemistry module for the Master Chemical Mechanism L. Xue et al. 10.5194/gmd-8-3151-2015
- A theoretical study of the mechanism of the atmospherically relevant reaction of chlorine atoms with methyl nitrate, and calculation of the reaction rate coefficients at temperatures relevant to the troposphere M. Ng et al. 10.1039/C4CP06007E
- Simulation Verification of Barrierless HONO Formation from the Oxidation Reaction System of NO, Cl, and Water in the Atmosphere X. Zhao et al. 10.1021/acs.est.1c01773
- Evidence for strong, widespread chlorine radical chemistry associated with pollution outflow from continental Asia A. Baker et al. 10.1038/srep36821
- Ubiquity of ClNO2 in the urban boundary layer of Calgary, Alberta, Canada L. Mielke et al. 10.1139/cjc-2015-0426
- Introductory lecture: atmospheric chemistry in the Anthropocene B. Finlayson-Pitts 10.1039/C7FD00161D
- High Levels of Daytime Molecular Chlorine and Nitryl Chloride at a Rural Site on the North China Plain X. Liu et al. 10.1021/acs.est.7b03039
- Atmospheric oxidation mechanism and kinetics of isoprene initiated by chlorine radicals: A computational study X. Guo et al. 10.1016/j.scitotenv.2019.136330
- Modeling the impact of heterogeneous reactions of chlorine on summertime nitrate formation in Beijing, China X. Qiu et al. 10.5194/acp-19-6737-2019
- Reactions of Three Lactones with Cl, OD, and O3: Atmospheric Impact and Trends in Furan Reactivity S. Ausmeel et al. 10.1021/acs.jpca.7b02325
- Experimental and Computational Studies of Criegee Intermediate syn-CH3CHOO Reaction with Hydrogen Chloride S. Liu et al. 10.1021/acs.jpca.1c05578
- The gas phase oxidation of HCOOH by Cl and NH2 radicals. Proton coupled electron transfer versus hydrogen atom transfer J. Anglada et al. 10.1080/00268976.2018.1554829
- The Atmospherically Important Reaction of Hydroxyl Radicals with Methyl Nitrate: A Theoretical Study Involving the Calculation of Reaction Mechanisms, Enthalpies, Activation Energies, and Rate Coefficients M. Ng et al. 10.1021/acs.jpca.7b05035
- Constraints on Arctic Atmospheric Chlorine Production through Measurements and Simulations of Cl2 and ClO K. Custard et al. 10.1021/acs.est.6b03909
- Anthropogenic Control Over Wintertime Oxidation of Atmospheric Pollutants J. Haskins et al. 10.1029/2019GL085498
- Winter ClNO<sub>2</sub> formation in the region of fresh anthropogenic emissions: seasonal variability and insights into daytime peaks in northern China M. Xia et al. 10.5194/acp-21-15985-2021
- N<sub>2</sub>O<sub>5</sub> uptake onto saline mineral dust: a potential missing source of tropospheric ClNO<sub>2</sub> in inland China H. Wang et al. 10.5194/acp-22-1845-2022
- Barrierless HNO3 formation from the hydrolysis reaction of NO2 with Cl atom in the atmosphere X. Zhao et al. 10.1016/j.atmosenv.2021.118871
- Observations of gas phase hydrochloric acid in the polluted marine boundary layer T. Crisp et al. 10.1002/2013JD020992
- Gas-Phase Chlorine Radical Oxidation of Alkanes: Effects of Structural Branching, NOx, and Relative Humidity Observed during Environmental Chamber Experiments L. Jahn et al. 10.1021/acs.jpca.1c03516
- Formation and emission of hydrogen chloride in indoor air K. Dawe et al. 10.1111/ina.12509
- Understanding Sources of Atmospheric Hydrogen Chloride in Coastal Spring and Continental Winter A. Angelucci et al. 10.1021/acsearthspacechem.1c00193
- Reactions of tropospheric oxidants- Cl, OH and O3 with cyclic hydrocarbons with eight carbon atoms at 298 K A. Sharma et al. 10.1016/j.atmosenv.2019.06.024
- Climate engineering by mimicking natural dust climate control: the iron salt aerosol method F. Oeste et al. 10.5194/esd-8-1-2017
- Non-methane hydrocarbon (C<sub>2</sub>–C<sub>8</sub>) sources and sinks around the Arabian Peninsula E. Bourtsoukidis et al. 10.5194/acp-19-7209-2019
- Atmospheric oxidation of C10~14 n-alkanes initiated by Cl atoms: Kinetics and mechanism B. Shi et al. 10.1016/j.atmosenv.2019.117166
- A theoretical investigation of the atmospherically important reaction between chlorine atoms and formic acid: determination of the reaction mechanism and calculation of the rate coefficient at different temperatures M. Ng et al. 10.1080/00268976.2014.980448
- Tropospheric chemistry of ethyl tiglate initiated by Cl atoms C. Ramya & B. Rajakumar 10.1016/j.cplett.2020.137371
- Study of Secondary Organic Aerosol Formation from Chlorine Radical-Initiated Oxidation of Volatile Organic Compounds in a Polluted Atmosphere Using a 3D Chemical Transport Model M. Choi et al. 10.1021/acs.est.0c02958
- Factors affecting wavelength‐resolved ultraviolet irradiance indoors and their impacts on indoor photochemistry S. Zhou et al. 10.1111/ina.12784
- Gas-phase reaction of two unsaturated ketones with atomic Cl and O3: kinetics and products J. Wang et al. 10.1039/C4CP05461J
- Computational Study of the Reactions of Chlorine Radicals with Atmospheric Organic Compounds Featuring NHx–π-Bond (x = 1, 2) Structures H. Xie et al. 10.1021/acs.jpca.6b11418
- Anthropogenic Impacts on Tropospheric Reactive Chlorine Since the Preindustrial S. Zhai et al. 10.1029/2021GL093808
- Tropospheric Halogen Chemistry: Sources, Cycling, and Impacts W. Simpson et al. 10.1021/cr5006638
- Chlorine-initiated oxidation of <i>n</i>-alkanes under high-NO<sub><i>x</i></sub> conditions: insights into secondary organic aerosol composition and volatility using a FIGAERO–CIMS D. Wang & L. Hildebrandt Ruiz 10.5194/acp-18-15535-2018
- Primary vs. secondary H-atom abstraction in the Cl-atom reaction with n-pentane S. Pandit et al. 10.1039/C6CP07164C
- Reactions of lactones with tropospheric oxidants: A kinetics and products study M. Walavalkar et al. 10.1016/j.atmosenv.2017.04.028
- Cl-Atom-Initiated Atmospheric Degradation of Saturated Cyclic Hydrocarbons: Kinetic and Mechanistic Investigation R. Cheramangalath Balan & B. Rajakumar 10.1021/acs.jpca.9b02225
- Study on the reaction of 3-methyl-2-butenal and 3-methylbutanal with Cl atoms: kinetics and reaction mechanism B. Shi et al. 10.1016/j.jes.2021.03.032
- Seasonal and geographical variability of nitryl chloride and its precursors in Northern Europe R. Sommariva et al. 10.1002/asl.844
- Atmospheric Chemistry of Volatile Methyl Siloxanes: Kinetics and Products of Oxidation by OH Radicals and Cl Atoms M. Alton & E. Browne 10.1021/acs.est.0c01368
- Atmospheric Oxidation of Piperazine Initiated by ·Cl: Unexpected High Nitrosamine Yield F. Ma et al. 10.1021/acs.est.8b02510
- Validation of a new cavity ring-down spectrometer for measuring tropospheric gaseous hydrogen chloride T. Furlani et al. 10.5194/amt-14-5859-2021
- Secondary organic aerosol from chlorine-initiated oxidation of isoprene D. Wang & L. Ruiz 10.5194/acp-17-13491-2017
- Low levels of nitryl chloride at ground level: nocturnal nitrogen oxides in the Lower Fraser Valley of British Columbia H. Osthoff et al. 10.5194/acp-18-6293-2018
- Computational study on the mechanism and kinetics of Cl-initiated oxidation of ethyl acrylate S. Zhang et al. 10.1007/s11224-017-0967-2
- Springtime Nitrogen Oxide-Influenced Chlorine Chemistry in the Coastal Arctic S. McNamara et al. 10.1021/acs.est.9b01797
- Integration of airborne and ground observations of nitryl chloride in the Seoul metropolitan area and the implications on regional oxidation capacity during KORUS-AQ 2016 D. Jeong et al. 10.5194/acp-19-12779-2019
- Observation of N2O5 Deposition and ClNO2 Production on the Saline Snowpack S. McNamara et al. 10.1021/acsearthspacechem.0c00317
- Photodissociation of Benzoyl Chloride: A Velocity Map Imaging Study Using VUV Detection of Chlorine Atoms C. Matthaei et al. 10.1021/acs.jpca.0c11236
- Modeling the impact of chlorine emissions from coal combustion and prescribed waste incineration on tropospheric ozone formation in China Y. Liu et al. 10.5194/acp-18-2709-2018
4 citations as recorded by crossref.
- Theoretical investigation on mechanisms and kinetics of the reactions of Cl atom with CH3OOH and CH3CH2OOH F. Liu et al. 10.1016/j.comptc.2014.04.011
- An MCM modeling study of nitryl chloride (ClNO<sub>2</sub>) impacts on oxidation, ozone production and nitrogen oxide partitioning in polluted continental outflow T. Riedel et al. 10.5194/acp-14-3789-2014
- The primary and recycling sources of OH during the NACHTT-2011 campaign: HONO as an important OH primary source in the wintertime S. Kim et al. 10.1002/2013JD019784
- The reaction mechanisms and kinetics of CF3CHFOCH3 and CHF2CHFOCF3 with atomic chlorine: a computational study F. Liu et al. 10.1007/s00894-014-2435-x
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