Articles | Volume 14, issue 7
https://doi.org/10.5194/acp-14-3427-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-14-3427-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
07 Apr 2014
Research article |
| 07 Apr 2014
Chlorine as a primary radical: evaluation of methods to understand its role in initiation of oxidative cycles
C. J. Young
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO, USA
now at: Department of Chemistry, Memorial University, St. John's, NL, Canada
R. A. Washenfelder
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO, USA
P. M. Edwards
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO, USA
D. D. Parrish
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO, USA
J. B. Gilman
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO, USA
W. C. Kuster
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO, USA
L. H. Mielke
Department of Chemistry, University of Calgary, Calgary, AB, Canada
now at: School of Public and Environmental Affairs, Indiana University, Bloomington, IN, USA
H. D. Osthoff
Department of Chemistry, University of Calgary, Calgary, AB, Canada
C. Tsai
Department of Atmospheric and Oceanic Sciences, University of California, Los Angeles, CA, USA
O. Pikelnaya
Department of Atmospheric and Oceanic Sciences, University of California, Los Angeles, CA, USA
Department of Atmospheric and Oceanic Sciences, University of California, Los Angeles, CA, USA
P. R. Veres
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO, USA
J. M. Roberts
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO, USA
S. Griffith
School of Public and Environmental Affairs, Indiana University, Bloomington, IN, USA
S. Dusanter
School of Public and Environmental Affairs, Indiana University, Bloomington, IN, USA
Mines Douai, CE, 59508, Douai, France
P. S. Stevens
School of Public and Environmental Affairs, Indiana University, Bloomington, IN, USA
J. Flynn
Department of Earth and Atmospheric Sciences, University of Houston, Houston, TX, USA
N. Grossberg
Department of Earth and Atmospheric Sciences, University of Houston, Houston, TX, USA
Department of Earth and Atmospheric Sciences, University of Houston, Houston, TX, USA
J. S. Holloway
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO, USA
J. Peischl
Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO, USA
T. B. Ryerson
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO, USA
E. L. Atlas
Rosenstiel School of Marine and Atmospheric Science, University of Miami, Miami, FL, USA
D. R. Blake
Department of Chemistry, University of California Irvine, Irvine, CA, USA
S. S. Brown
Chemical Sciences Division, Earth System Research Laboratory, National Oceanic and Atmospheric Administration, Boulder, CO, USA
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- A theoretical investigation of the atmospherically important reaction between chlorine atoms and formic acid: determination of the reaction mechanism and calculation of the rate coefficient at different temperatures M. Ng et al. 10.1080/00268976.2014.980448
- Tropospheric chemistry of ethyl tiglate initiated by Cl atoms C. Ramya & B. Rajakumar 10.1016/j.cplett.2020.137371
- Study of Secondary Organic Aerosol Formation from Chlorine Radical-Initiated Oxidation of Volatile Organic Compounds in a Polluted Atmosphere Using a 3D Chemical Transport Model M. Choi et al. 10.1021/acs.est.0c02958
- Factors affecting wavelength‐resolved ultraviolet irradiance indoors and their impacts on indoor photochemistry S. Zhou et al. 10.1111/ina.12784
- Gas-phase reaction of two unsaturated ketones with atomic Cl and O3: kinetics and products J. Wang et al. 10.1039/C4CP05461J
- Computational Study of the Reactions of Chlorine Radicals with Atmospheric Organic Compounds Featuring NHx–π-Bond (x = 1, 2) Structures H. Xie et al. 10.1021/acs.jpca.6b11418
- Anthropogenic Impacts on Tropospheric Reactive Chlorine Since the Preindustrial S. Zhai et al. 10.1029/2021GL093808
- Tropospheric Halogen Chemistry: Sources, Cycling, and Impacts W. Simpson et al. 10.1021/cr5006638
- Insights into the role of the H-abstraction reaction kinetics of amines in understanding their degeneration fates under atmospheric and combustion conditions Y. Shang & S. Luo 10.1039/D4CP02187H
- Chlorine-initiated oxidation of <i>n</i>-alkanes under high-NO<sub><i>x</i></sub> conditions: insights into secondary organic aerosol composition and volatility using a FIGAERO–CIMS D. Wang & L. Hildebrandt Ruiz 10.5194/acp-18-15535-2018
- Primary vs. secondary H-atom abstraction in the Cl-atom reaction with n-pentane S. Pandit et al. 10.1039/C6CP07164C
- Reactions of lactones with tropospheric oxidants: A kinetics and products study M. Walavalkar et al. 10.1016/j.atmosenv.2017.04.028
- Cl-Atom-Initiated Atmospheric Degradation of Saturated Cyclic Hydrocarbons: Kinetic and Mechanistic Investigation R. Cheramangalath Balan & B. Rajakumar 10.1021/acs.jpca.9b02225
- Simultaneous formation of sulfate and nitrate via co-uptake of SO2 and NO2 by aqueous NaCl droplets: combined effect of nitrate photolysis and chlorine chemistry R. Zhang & C. Chan 10.5194/acp-23-6113-2023
- Study on the reaction of 3-methyl-2-butenal and 3-methylbutanal with Cl atoms: kinetics and reaction mechanism B. Shi et al. 10.1016/j.jes.2021.03.032
- Seasonal and geographical variability of nitryl chloride and its precursors in Northern Europe R. Sommariva et al. 10.1002/asl.844
- Atmospheric Chemistry of Volatile Methyl Siloxanes: Kinetics and Products of Oxidation by OH Radicals and Cl Atoms M. Alton & E. Browne 10.1021/acs.est.0c01368
- Atmospheric Oxidation of Piperazine Initiated by ·Cl: Unexpected High Nitrosamine Yield F. Ma et al. 10.1021/acs.est.8b02510
- Validation of a new cavity ring-down spectrometer for measuring tropospheric gaseous hydrogen chloride T. Furlani et al. 10.5194/amt-14-5859-2021
- Secondary organic aerosol from chlorine-initiated oxidation of isoprene D. Wang & L. Ruiz 10.5194/acp-17-13491-2017
- Low levels of nitryl chloride at ground level: nocturnal nitrogen oxides in the Lower Fraser Valley of British Columbia H. Osthoff et al. 10.5194/acp-18-6293-2018
- Computational study on the mechanism and kinetics of Cl-initiated oxidation of ethyl acrylate S. Zhang et al. 10.1007/s11224-017-0967-2
- Springtime Nitrogen Oxide-Influenced Chlorine Chemistry in the Coastal Arctic S. McNamara et al. 10.1021/acs.est.9b01797
- Integration of airborne and ground observations of nitryl chloride in the Seoul metropolitan area and the implications on regional oxidation capacity during KORUS-AQ 2016 D. Jeong et al. 10.5194/acp-19-12779-2019
- A study of the thermodynamics and mechanisms of the atmospherically relevant reaction dimethyl sulphide (DMS) with atomic chlorine (Cl) in the absence and presence of water, using electronic structure methods L. Rhyman et al. 10.1039/D2CP05814F
- Effects of Relative Humidity and Photoaging on the Formation, Composition, and Aging of Ethylbenzene SOA: Insights from Chamber Experiments on Chlorine Radical-Initiated Oxidation of Ethylbenzene L. Jahn et al. 10.1021/acsearthspacechem.3c00279
- Development and validation of a new in situ technique to measure total gaseous chlorine in air T. Furlani et al. 10.5194/amt-16-181-2023
- Observation of N2O5 Deposition and ClNO2 Production on the Saline Snowpack S. McNamara et al. 10.1021/acsearthspacechem.0c00317
- Photodissociation of Benzoyl Chloride: A Velocity Map Imaging Study Using VUV Detection of Chlorine Atoms C. Matthaei et al. 10.1021/acs.jpca.0c11236
- Isoprene–Chlorine Oxidation in the Presence of NOx and Implications for Urban Atmospheric Chemistry D. Wang et al. 10.1021/acs.est.1c07048
- Modeling the impact of chlorine emissions from coal combustion and prescribed waste incineration on tropospheric ozone formation in China Y. Liu et al. 10.5194/acp-18-2709-2018
- Reactive Chlorine Emissions from Cleaning and Reactive Nitrogen Chemistry in an Indoor Athletic Facility A. Moravek et al. 10.1021/acs.est.2c04622
- The effects of the gas–liquid interface and gas phase on Cl/ClO radical interaction with water molecules Q. Zhang et al. 10.1039/D3CP02796A
4 citations as recorded by crossref.
- Theoretical investigation on mechanisms and kinetics of the reactions of Cl atom with CH3OOH and CH3CH2OOH F. Liu et al. 10.1016/j.comptc.2014.04.011
- An MCM modeling study of nitryl chloride (ClNO<sub>2</sub>) impacts on oxidation, ozone production and nitrogen oxide partitioning in polluted continental outflow T. Riedel et al. 10.5194/acp-14-3789-2014
- The primary and recycling sources of OH during the NACHTT‐2011 campaign: HONO as an important OH primary source in the wintertime S. Kim et al. 10.1002/2013JD019784
- The reaction mechanisms and kinetics of CF3CHFOCH3 and CHF2CHFOCF3 with atomic chlorine: a computational study F. Liu et al. 10.1007/s00894-014-2435-x
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