Articles | Volume 14, issue 24
https://doi.org/10.5194/acp-14-13531-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-14-13531-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
19 Dec 2014
Research article |
| 19 Dec 2014
Overview of the Focused Isoprene eXperiment at the California Institute of Technology (FIXCIT): mechanistic chamber studies on the oxidation of biogenic compounds
Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California, USA
J. D. Crounse
Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California, USA
R. H. Schwantes
Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California, USA
A. P. Teng
Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California, USA
K. H. Bates
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California, USA
Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California, USA
J. M. St. Clair
Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California, USA
W. H. Brune
Department of Meteorology, Pennsylvania State University, University Park, Pennsylvania, USA
G. S. Tyndall
Atmospheric Chemistry Division, National Center for Atmospheric Research, Boulder, Colorado, USA
F. N. Keutsch
Department of Chemistry, University of Wisconsin – Madison, Madison, Wisconsin, USA
J. H. Seinfeld
Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California, USA
Division of Engineering and Applied Science, California Institute of Technology, Pasadena, California, USA
P. O. Wennberg
Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California, USA
Division of Engineering and Applied Science, California Institute of Technology, Pasadena, California, USA
Viewed
Total article views: 5,975 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 25 Aug 2014)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 3,379 | 2,365 | 231 | 5,975 | 141 | 185 |
- HTML: 3,379
- PDF: 2,365
- XML: 231
- Total: 5,975
- BibTeX: 141
- EndNote: 185
Total article views: 4,841 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 19 Dec 2014)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 2,791 | 1,841 | 209 | 4,841 | 133 | 183 |
- HTML: 2,791
- PDF: 1,841
- XML: 209
- Total: 4,841
- BibTeX: 133
- EndNote: 183
Total article views: 1,134 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 25 Aug 2014)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 588 | 524 | 22 | 1,134 | 8 | 2 |
- HTML: 588
- PDF: 524
- XML: 22
- Total: 1,134
- BibTeX: 8
- EndNote: 2
Cited
60 citations as recorded by crossref.
- Measuring energy efficiency financing: a way forward for reducing energy poverty through financial inclusion in OECD W. Fang et al. 10.1007/s11356-022-20139-8
- Tower-based profiles of wintertime secondary organic aerosols in the urban boundary layer over Guangzhou Y. Li et al. 10.1016/j.scitotenv.2024.175326
- Secondary organic aerosol and organic nitrogen yields from the nitrate radical (NO3) oxidation of alpha-pinene from various RO2 fates K. Bates et al. 10.5194/acp-22-1467-2022
- A comprehensive organic nitrate chemistry: insights into the lifetime of atmospheric organic nitrates A. Zare et al. 10.5194/acp-18-15419-2018
- Chemical ionization mass spectrometry utilizing ammonium ions (NH4+ CIMS) for measurements of organic compounds in the atmosphere L. Xu et al. 10.5194/amt-15-7353-2022
- Nitrate radicals and biogenic volatile organic compounds: oxidation, mechanisms, and organic aerosol N. Ng et al. 10.5194/acp-17-2103-2017
- Kinetics and Products of the Reaction of the First-Generation Isoprene Hydroxy Hydroperoxide (ISOPOOH) with OH J. St. Clair et al. 10.1021/acs.jpca.5b06532
- Online Calibration of a Chemical Ionization Mass Spectrometer for Multifunctional Biogenic Organic Nitrates M. Robinson et al. 10.1021/acsestair.4c00056
- Investigation of OH-reactivity budget in the isoprene, α-pinene and m-xylene oxidation with OH under high NOx conditions Y. Sakamoto et al. 10.1016/j.atmosenv.2021.118916
- Can Isoprene Oxidation Explain High Concentrations of Atmospheric Formic and Acetic Acid over Forests? M. Link et al. 10.1021/acsearthspacechem.0c00010
- Isoprene photochemistry over the Amazon rainforest Y. Liu et al. 10.1073/pnas.1524136113
- Alkoxy Radical Bond Scissions Explain the Anomalously Low Secondary Organic Aerosol and Organonitrate Yields From α-Pinene + NO3 T. Kurtén et al. 10.1021/acs.jpclett.7b01038
- Environmental effects of ozone depletion and its interactions with climate change: progress report, 2015 10.1039/c6pp90004f
- Always Lost but Never Forgotten: Gas-Phase Wall Losses Are Important in All Teflon Environmental Chambers J. Krechmer et al. 10.1021/acs.est.0c03381
- Southeast Atmosphere Studies: learning from model-observation syntheses J. Mao et al. 10.5194/acp-18-2615-2018
- Organic nitrate chemistry and its implications for nitrogen budgets in an isoprene- and monoterpene-rich atmosphere: constraints from aircraft (SEAC4RS) and ground-based (SOAS) observations in the Southeast US J. Fisher et al. 10.5194/acp-16-5969-2016
- Isoprene versus Monoterpenes as Gas-Phase Organic Acid Precursors in the Atmosphere M. Link et al. 10.1021/acsearthspacechem.1c00093
- Non-OH chemistry in oxidation flow reactors for the study of atmospheric chemistry systematically examined by modeling Z. Peng et al. 10.5194/acp-16-4283-2016
- Recent advances in understanding secondary organic aerosol: Implications for global climate forcing M. Shrivastava et al. 10.1002/2016RG000540
- Organic synthesis in the study of terpene-derived oxidation products in the atmosphere M. Upshur et al. 10.1039/D2NP00064D
- Organic peroxy radical chemistry in oxidation flow reactors and environmental chambers and their atmospheric relevance Z. Peng et al. 10.5194/acp-19-813-2019
- Secondary Organic Aerosol (SOA) from Nitrate Radical Oxidation of Monoterpenes: Effects of Temperature, Dilution, and Humidity on Aerosol Formation, Mixing, and Evaporation C. Boyd et al. 10.1021/acs.est.7b01460
- Effect of Oxidation Process on Complex Refractive Index of Secondary Organic Aerosol Generated from Isoprene T. Nakayama et al. 10.1021/acs.est.7b05852
- Comparison of secondary organic aerosol generated from the oxidation of laboratory precursors by hydroxyl radicals, chlorine atoms, and bromine atoms in an oxidation flow reactor A. Lambe et al. 10.1039/D2EA00018K
- A steady-state continuous flow chamber for the study of daytime and nighttime chemistry under atmospherically relevant NO levels X. Zhang et al. 10.5194/amt-11-2537-2018
- Observations of speciated isoprene nitrates in Beijing: implications for isoprene chemistry C. Reeves et al. 10.5194/acp-21-6315-2021
- Comparison of Isoprene Chemical Mechanisms with Chamber and Field Observations W. Brune et al. 10.1021/acsearthspacechem.4c00196
- Low-volatility compounds contribute significantly to isoprene secondary organic aerosol (SOA) under high-NOx conditions R. Schwantes et al. 10.5194/acp-19-7255-2019
- Probing isoprene photochemistry at atmospherically relevant nitric oxide levels X. Zhang et al. 10.1016/j.chempr.2022.08.003
- Photochemical Aging of α-pinene and β-pinene Secondary Organic Aerosol formed from Nitrate Radical Oxidation T. Nah et al. 10.1021/acs.est.5b04594
- Low-pressure gas chromatography with chemical ionization mass spectrometry for quantification of multifunctional organic compounds in the atmosphere K. Vasquez et al. 10.5194/amt-11-6815-2018
- Nitrate radical oxidation of γ-terpinene: hydroxy nitrate, total organic nitrate, and secondary organic aerosol yields J. Slade et al. 10.5194/acp-17-8635-2017
- Isoprene–Chlorine Oxidation in the Presence of NOx and Implications for Urban Atmospheric Chemistry D. Wang et al. 10.1021/acs.est.1c07048
- Secondary organic aerosol formation from the β-pinene+NO3 system: effect of humidity and peroxy radical fate C. Boyd et al. 10.5194/acp-15-7497-2015
- The Essential Role for Laboratory Studies in Atmospheric Chemistry J. Burkholder et al. 10.1021/acs.est.6b04947
- Kinetics of the reactions of the Criegee intermediate CH2OO with water vapour: experimental measurements as a function of temperature and global atmospheric modelling R. Lade et al. 10.1039/D4EA00097H
- Molecular characterization of alkyl nitrates in atmospheric aerosols by ion mobility mass spectrometry X. Zhang et al. 10.5194/amt-12-5535-2019
- Modeling the Current and Future Roles of Particulate Organic Nitrates in the Southeastern United States H. Pye et al. 10.1021/acs.est.5b03738
- Barrierless Reactions with Loose Transition States Govern the Yields and Lifetimes of Organic Nitrates Derived from Isoprene I. Piletic et al. 10.1021/acs.jpca.7b08229
- Changes to simulated global atmospheric composition resulting from recent revisions to isoprene oxidation chemistry M. Khan et al. 10.1016/j.atmosenv.2020.117914
- Gas-Phase Oxidation Rates and Products of 1,2-Dihydroxy Isoprene K. Bates et al. 10.1021/acs.est.1c04177
- Isoprene NO3 Oxidation Products from the RO2 + HO2 Pathway R. Schwantes et al. 10.1021/acs.jpca.5b06355
- Evolution of OH reactivity in NO-free volatile organic compound photooxidation investigated by the fully explicit GECKO-A model Z. Peng et al. 10.5194/acp-21-14649-2021
- ROOOH: a missing piece of the puzzle for OH measurements in low-NO environments? C. Fittschen et al. 10.5194/acp-19-349-2019
- Formation of Low Volatility Organic Compounds and Secondary Organic Aerosol from Isoprene Hydroxyhydroperoxide Low-NO Oxidation J. Krechmer et al. 10.1021/acs.est.5b02031
- Mechanism of the hydroxyl radical oxidation of methacryloyl peroxynitrate (MPAN) and its pathway toward secondary organic aerosol formation in the atmosphere T. Nguyen et al. 10.1039/C5CP02001H
- Towards a quantitative understanding of total OH reactivity: A review Y. Yang et al. 10.1016/j.atmosenv.2016.03.010
- Isoprene Peroxy Radical Dynamics A. Teng et al. 10.1021/jacs.6b12838
- Technical note: Conversion of isoprene hydroxy hydroperoxides (ISOPOOHs) on metal environmental simulation chamber walls A. Bernhammer et al. 10.5194/acp-17-4053-2017
- Observation of isoprene hydroxynitrates in the southeastern United States and implications for the fate of NOx F. Xiong et al. 10.5194/acp-15-11257-2015
- Importance of biogenic volatile organic compounds to acyl peroxy nitrates (APN) production in the southeastern US during SOAS 2013 S. Toma et al. 10.5194/acp-19-1867-2019
- Atmospheric fates of Criegee intermediates in the ozonolysis of isoprene T. Nguyen et al. 10.1039/C6CP00053C
- Analysis of Volatile Organic Compound Product Distributions under Reduced NOx Conditions in the NSF NCAR Atmospheric Simulation Chamber: Implications for In Situ VOC Measurements E. Asher et al. 10.1021/acsearthspacechem.4c00407
- Measurement of isoprene nitrates by GCMS G. Mills et al. 10.5194/amt-9-4533-2016
- Synthesis of the Southeast Atmosphere Studies: Investigating Fundamental Atmospheric Chemistry Questions A. Carlton et al. 10.1175/BAMS-D-16-0048.1
- Atmospheric Chemistry in a Box or a Bag G. Hidy 10.3390/atmos10070401
- Biomass burning emission disturbances of isoprene oxidation in a tropical forest F. Santos et al. 10.5194/acp-18-12715-2018
- Overview of ICARUS─A Curated, Open Access, Online Repository for Atmospheric Simulation Chamber Data T. Nguyen et al. 10.1021/acsearthspacechem.3c00043
- Processes Driving Diurnal and Seasonal Variations of Formaldehyde in an Urban Environment C. Du et al. 10.1021/acsearthspacechem.5c00020
- Uptake of Epoxydiol Isomers Accounts for Half of the Particle-Phase Material Produced from Isoprene Photooxidation via the HO2 Pathway Y. Liu et al. 10.1021/es5034298
59 citations as recorded by crossref.
- Measuring energy efficiency financing: a way forward for reducing energy poverty through financial inclusion in OECD W. Fang et al. 10.1007/s11356-022-20139-8
- Tower-based profiles of wintertime secondary organic aerosols in the urban boundary layer over Guangzhou Y. Li et al. 10.1016/j.scitotenv.2024.175326
- Secondary organic aerosol and organic nitrogen yields from the nitrate radical (NO3) oxidation of alpha-pinene from various RO2 fates K. Bates et al. 10.5194/acp-22-1467-2022
- A comprehensive organic nitrate chemistry: insights into the lifetime of atmospheric organic nitrates A. Zare et al. 10.5194/acp-18-15419-2018
- Chemical ionization mass spectrometry utilizing ammonium ions (NH4+ CIMS) for measurements of organic compounds in the atmosphere L. Xu et al. 10.5194/amt-15-7353-2022
- Nitrate radicals and biogenic volatile organic compounds: oxidation, mechanisms, and organic aerosol N. Ng et al. 10.5194/acp-17-2103-2017
- Kinetics and Products of the Reaction of the First-Generation Isoprene Hydroxy Hydroperoxide (ISOPOOH) with OH J. St. Clair et al. 10.1021/acs.jpca.5b06532
- Online Calibration of a Chemical Ionization Mass Spectrometer for Multifunctional Biogenic Organic Nitrates M. Robinson et al. 10.1021/acsestair.4c00056
- Investigation of OH-reactivity budget in the isoprene, α-pinene and m-xylene oxidation with OH under high NOx conditions Y. Sakamoto et al. 10.1016/j.atmosenv.2021.118916
- Can Isoprene Oxidation Explain High Concentrations of Atmospheric Formic and Acetic Acid over Forests? M. Link et al. 10.1021/acsearthspacechem.0c00010
- Isoprene photochemistry over the Amazon rainforest Y. Liu et al. 10.1073/pnas.1524136113
- Alkoxy Radical Bond Scissions Explain the Anomalously Low Secondary Organic Aerosol and Organonitrate Yields From α-Pinene + NO3 T. Kurtén et al. 10.1021/acs.jpclett.7b01038
- Environmental effects of ozone depletion and its interactions with climate change: progress report, 2015 10.1039/c6pp90004f
- Always Lost but Never Forgotten: Gas-Phase Wall Losses Are Important in All Teflon Environmental Chambers J. Krechmer et al. 10.1021/acs.est.0c03381
- Southeast Atmosphere Studies: learning from model-observation syntheses J. Mao et al. 10.5194/acp-18-2615-2018
- Organic nitrate chemistry and its implications for nitrogen budgets in an isoprene- and monoterpene-rich atmosphere: constraints from aircraft (SEAC4RS) and ground-based (SOAS) observations in the Southeast US J. Fisher et al. 10.5194/acp-16-5969-2016
- Isoprene versus Monoterpenes as Gas-Phase Organic Acid Precursors in the Atmosphere M. Link et al. 10.1021/acsearthspacechem.1c00093
- Non-OH chemistry in oxidation flow reactors for the study of atmospheric chemistry systematically examined by modeling Z. Peng et al. 10.5194/acp-16-4283-2016
- Recent advances in understanding secondary organic aerosol: Implications for global climate forcing M. Shrivastava et al. 10.1002/2016RG000540
- Organic synthesis in the study of terpene-derived oxidation products in the atmosphere M. Upshur et al. 10.1039/D2NP00064D
- Organic peroxy radical chemistry in oxidation flow reactors and environmental chambers and their atmospheric relevance Z. Peng et al. 10.5194/acp-19-813-2019
- Secondary Organic Aerosol (SOA) from Nitrate Radical Oxidation of Monoterpenes: Effects of Temperature, Dilution, and Humidity on Aerosol Formation, Mixing, and Evaporation C. Boyd et al. 10.1021/acs.est.7b01460
- Effect of Oxidation Process on Complex Refractive Index of Secondary Organic Aerosol Generated from Isoprene T. Nakayama et al. 10.1021/acs.est.7b05852
- Comparison of secondary organic aerosol generated from the oxidation of laboratory precursors by hydroxyl radicals, chlorine atoms, and bromine atoms in an oxidation flow reactor A. Lambe et al. 10.1039/D2EA00018K
- A steady-state continuous flow chamber for the study of daytime and nighttime chemistry under atmospherically relevant NO levels X. Zhang et al. 10.5194/amt-11-2537-2018
- Observations of speciated isoprene nitrates in Beijing: implications for isoprene chemistry C. Reeves et al. 10.5194/acp-21-6315-2021
- Comparison of Isoprene Chemical Mechanisms with Chamber and Field Observations W. Brune et al. 10.1021/acsearthspacechem.4c00196
- Low-volatility compounds contribute significantly to isoprene secondary organic aerosol (SOA) under high-NOx conditions R. Schwantes et al. 10.5194/acp-19-7255-2019
- Probing isoprene photochemistry at atmospherically relevant nitric oxide levels X. Zhang et al. 10.1016/j.chempr.2022.08.003
- Photochemical Aging of α-pinene and β-pinene Secondary Organic Aerosol formed from Nitrate Radical Oxidation T. Nah et al. 10.1021/acs.est.5b04594
- Low-pressure gas chromatography with chemical ionization mass spectrometry for quantification of multifunctional organic compounds in the atmosphere K. Vasquez et al. 10.5194/amt-11-6815-2018
- Nitrate radical oxidation of γ-terpinene: hydroxy nitrate, total organic nitrate, and secondary organic aerosol yields J. Slade et al. 10.5194/acp-17-8635-2017
- Isoprene–Chlorine Oxidation in the Presence of NOx and Implications for Urban Atmospheric Chemistry D. Wang et al. 10.1021/acs.est.1c07048
- Secondary organic aerosol formation from the β-pinene+NO3 system: effect of humidity and peroxy radical fate C. Boyd et al. 10.5194/acp-15-7497-2015
- The Essential Role for Laboratory Studies in Atmospheric Chemistry J. Burkholder et al. 10.1021/acs.est.6b04947
- Kinetics of the reactions of the Criegee intermediate CH2OO with water vapour: experimental measurements as a function of temperature and global atmospheric modelling R. Lade et al. 10.1039/D4EA00097H
- Molecular characterization of alkyl nitrates in atmospheric aerosols by ion mobility mass spectrometry X. Zhang et al. 10.5194/amt-12-5535-2019
- Modeling the Current and Future Roles of Particulate Organic Nitrates in the Southeastern United States H. Pye et al. 10.1021/acs.est.5b03738
- Barrierless Reactions with Loose Transition States Govern the Yields and Lifetimes of Organic Nitrates Derived from Isoprene I. Piletic et al. 10.1021/acs.jpca.7b08229
- Changes to simulated global atmospheric composition resulting from recent revisions to isoprene oxidation chemistry M. Khan et al. 10.1016/j.atmosenv.2020.117914
- Gas-Phase Oxidation Rates and Products of 1,2-Dihydroxy Isoprene K. Bates et al. 10.1021/acs.est.1c04177
- Isoprene NO3 Oxidation Products from the RO2 + HO2 Pathway R. Schwantes et al. 10.1021/acs.jpca.5b06355
- Evolution of OH reactivity in NO-free volatile organic compound photooxidation investigated by the fully explicit GECKO-A model Z. Peng et al. 10.5194/acp-21-14649-2021
- ROOOH: a missing piece of the puzzle for OH measurements in low-NO environments? C. Fittschen et al. 10.5194/acp-19-349-2019
- Formation of Low Volatility Organic Compounds and Secondary Organic Aerosol from Isoprene Hydroxyhydroperoxide Low-NO Oxidation J. Krechmer et al. 10.1021/acs.est.5b02031
- Mechanism of the hydroxyl radical oxidation of methacryloyl peroxynitrate (MPAN) and its pathway toward secondary organic aerosol formation in the atmosphere T. Nguyen et al. 10.1039/C5CP02001H
- Towards a quantitative understanding of total OH reactivity: A review Y. Yang et al. 10.1016/j.atmosenv.2016.03.010
- Isoprene Peroxy Radical Dynamics A. Teng et al. 10.1021/jacs.6b12838
- Technical note: Conversion of isoprene hydroxy hydroperoxides (ISOPOOHs) on metal environmental simulation chamber walls A. Bernhammer et al. 10.5194/acp-17-4053-2017
- Observation of isoprene hydroxynitrates in the southeastern United States and implications for the fate of NOx F. Xiong et al. 10.5194/acp-15-11257-2015
- Importance of biogenic volatile organic compounds to acyl peroxy nitrates (APN) production in the southeastern US during SOAS 2013 S. Toma et al. 10.5194/acp-19-1867-2019
- Atmospheric fates of Criegee intermediates in the ozonolysis of isoprene T. Nguyen et al. 10.1039/C6CP00053C
- Analysis of Volatile Organic Compound Product Distributions under Reduced NOx Conditions in the NSF NCAR Atmospheric Simulation Chamber: Implications for In Situ VOC Measurements E. Asher et al. 10.1021/acsearthspacechem.4c00407
- Measurement of isoprene nitrates by GCMS G. Mills et al. 10.5194/amt-9-4533-2016
- Synthesis of the Southeast Atmosphere Studies: Investigating Fundamental Atmospheric Chemistry Questions A. Carlton et al. 10.1175/BAMS-D-16-0048.1
- Atmospheric Chemistry in a Box or a Bag G. Hidy 10.3390/atmos10070401
- Biomass burning emission disturbances of isoprene oxidation in a tropical forest F. Santos et al. 10.5194/acp-18-12715-2018
- Overview of ICARUS─A Curated, Open Access, Online Repository for Atmospheric Simulation Chamber Data T. Nguyen et al. 10.1021/acsearthspacechem.3c00043
- Processes Driving Diurnal and Seasonal Variations of Formaldehyde in an Urban Environment C. Du et al. 10.1021/acsearthspacechem.5c00020
Saved (final revised paper)
Saved (preprint)
Latest update: 24 Jul 2025
Altmetrics
Final-revised paper
Preprint