Articles | Volume 14, issue 23
Atmos. Chem. Phys., 14, 12967–12982, 2014
Atmos. Chem. Phys., 14, 12967–12982, 2014

Research article 08 Dec 2014

Research article | 08 Dec 2014

Stratospheric ozone depletion from future nitrous oxide increases

W. Wang1,*, W. Tian1, S. Dhomse2, F. Xie3, J. Shu4, and J. Austin5 W. Wang et al.
  • 1College of Atmospheric Sciences, Lanzhou University, Lanzhou, China
  • 2Institute for Climate and Atmospheric Science, School of Earth and Environment, University of Leeds, Leeds, UK
  • 3College of Global Change and Earth System Science, Beijing Normal University, Beijing, China
  • 4Institute of Plateau Meteorology, China Meteorological Administration, Chengdu, China
  • 5Enigma Scientific Publications, Winnersh, Berkshire, UK
  • *now at: Freie Universität Berlin, Institut für Meteorologie, Berlin, Germany

Abstract. We have investigated the impact of the assumed nitrous oxide (N2O) increases on stratospheric chemistry and dynamics using a series of idealized simulations with a coupled chemistry-climate model (CCM). In a future cooler stratosphere the net yield of NOy from N2O is shown to decrease in a reference run following the IPCC A1B scenario, but NOy can still be significantly increased by extra increases of N2O over 2001–2050. Over the last decade of simulations, 50% increases in N2O result in a maximal 6% reduction in ozone mixing ratios in the middle stratosphere at around 10 hPa and an average 2% decrease in the total ozone column (TCO) compared with the control run. This enhanced destruction could cause an ozone decline in the first half of this century in the middle stratosphere around 10 hPa, while global TCO still shows an increase at the same time. The results from a multiple linear regression analysis and sensitivity simulations with different forcings show that the chemical effect of N2O increases dominates the N2O-induced ozone depletion in the stratosphere, while the dynamical and radiative effects of N2O increases are overall insignificant. The analysis of the results reveals that the ozone depleting potential of N2O varies with the time period and is influenced by the environmental conditions. For example, carbon dioxide (CO2) increases can strongly offset the ozone depletion effect of N2O.

Final-revised paper