Articles | Volume 14, issue 23
https://doi.org/10.5194/acp-14-12951-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-14-12951-2014
© Author(s) 2014. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
08 Dec 2014
Research article |
| 08 Dec 2014
Mechanistic study of secondary organic aerosol components formed from nucleophilic addition reactions of methacrylic acid epoxide
A. W. Birdsall
currently at: Department of Chemistry, University of Wisconsin-Madison, Madison, Wisconsin, USA
Department of Chemistry and Biochemistry, Oberlin College, Oberlin, Ohio, USA
C. R. Miner
Department of Chemistry and Biochemistry, Oberlin College, Oberlin, Ohio, USA
L. E. Mael
Department of Chemistry and Biochemistry, Oberlin College, Oberlin, Ohio, USA
M. J. Elrod
CORRESPONDING AUTHOR
Department of Chemistry and Biochemistry, Oberlin College, Oberlin, Ohio, USA
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Cited
16 citations as recorded by crossref.
- Evidence for C5 organosulfur secondary organic aerosol components from in-cloud processing of isoprene: Role of reactive SO4 and SO3 radicals R. Szmigielski 10.1016/j.atmosenv.2015.10.072
- Heterogeneous Reactions of Isoprene-Derived Epoxides: Reaction Probabilities and Molar Secondary Organic Aerosol Yield Estimates T. Riedel et al. 10.1021/ez500406f
- Aqueous Organic Chemistry in the Atmosphere: Sources and Chemical Processing of Organic Aerosols V. McNeill 10.1021/es5043707
- Higher-Energy Collisional Dissociation Mass Spectral Networks for the Rapid, Semi-automated Characterization of Known and Unknown Ribonucleoside Modifications M. Jora et al. 10.1021/acs.analchem.2c03172
- Organosulfates from Dark Aqueous Reactions of Isoprene-Derived Epoxydiols Under Cloud and Fog Conditions: Kinetics, Mechanism, and Effect of Reaction Environment on Regioselectivity of Sulfate Addition S. Petters et al. 10.1021/acsearthspacechem.0c00293
- Assessing Potential Oligomerization Reaction Mechanisms of Isoprene Epoxydiols on Secondary Organic Aerosol S. Stropoli et al. 10.1021/acs.est.8b05247
- NMR spectroscopic applications to atmospheric organic aerosol analysis – Part 1: A critical review of data source and analysis, potentialities and limitations S. Decesari et al. 10.1016/j.trac.2023.117516
- Efficient and Selective Hydrogenolysis of 5‐Hydroxymethylfurfural to 2,5‐Dimethylfuran by a Bimetallic Copper‐Palladium Catalyst on a Carbon‐Doped Boron Nitride Support X. Chen et al. 10.1002/slct.202300862
- Tracer-based source apportioning of atmospheric organic carbon and the influence of anthropogenic emissions on secondary organic aerosol formation in Hong Kong Y. Cheng et al. 10.5194/acp-21-10589-2021
- 5-Hydroxymethylfurfural Hydrodeoxygenation Coupled with Water-Gas Shift Reaction for 2,5-Dimethylfuran Production over Au/ZrO2 Catalysts Z. Li et al. 10.1021/acssuschemeng.1c00616
- Assessing the Potential for Oligomer Formation from the Reactions of Lactones in Secondary Organic Aerosols K. Jiang et al. 10.1021/acs.jpca.7b10411
- Significant Contributions of Isoprene to Summertime Secondary Organic Aerosol in Eastern United States Q. Ying et al. 10.1021/acs.est.5b02514
- Assessing the Potential for the Reactions of Epoxides with Amines on Secondary Organic Aerosol Particles S. Stropoli & M. Elrod 10.1021/acs.jpca.5b07852
- Acidity and the multiphase chemistry of atmospheric aqueous particles and clouds A. Tilgner et al. 10.5194/acp-21-13483-2021
- Organic synthesis in the study of terpene-derived oxidation products in the atmosphere M. Upshur et al. 10.1039/D2NP00064D
- Atmospheric oxidation of 1,3-butadiene: characterization of gas and aerosol reaction products and implications for PM<sub>2.5</sub> M. Jaoui et al. 10.5194/acp-14-13681-2014
15 citations as recorded by crossref.
- Evidence for C5 organosulfur secondary organic aerosol components from in-cloud processing of isoprene: Role of reactive SO4 and SO3 radicals R. Szmigielski 10.1016/j.atmosenv.2015.10.072
- Heterogeneous Reactions of Isoprene-Derived Epoxides: Reaction Probabilities and Molar Secondary Organic Aerosol Yield Estimates T. Riedel et al. 10.1021/ez500406f
- Aqueous Organic Chemistry in the Atmosphere: Sources and Chemical Processing of Organic Aerosols V. McNeill 10.1021/es5043707
- Higher-Energy Collisional Dissociation Mass Spectral Networks for the Rapid, Semi-automated Characterization of Known and Unknown Ribonucleoside Modifications M. Jora et al. 10.1021/acs.analchem.2c03172
- Organosulfates from Dark Aqueous Reactions of Isoprene-Derived Epoxydiols Under Cloud and Fog Conditions: Kinetics, Mechanism, and Effect of Reaction Environment on Regioselectivity of Sulfate Addition S. Petters et al. 10.1021/acsearthspacechem.0c00293
- Assessing Potential Oligomerization Reaction Mechanisms of Isoprene Epoxydiols on Secondary Organic Aerosol S. Stropoli et al. 10.1021/acs.est.8b05247
- NMR spectroscopic applications to atmospheric organic aerosol analysis – Part 1: A critical review of data source and analysis, potentialities and limitations S. Decesari et al. 10.1016/j.trac.2023.117516
- Efficient and Selective Hydrogenolysis of 5‐Hydroxymethylfurfural to 2,5‐Dimethylfuran by a Bimetallic Copper‐Palladium Catalyst on a Carbon‐Doped Boron Nitride Support X. Chen et al. 10.1002/slct.202300862
- Tracer-based source apportioning of atmospheric organic carbon and the influence of anthropogenic emissions on secondary organic aerosol formation in Hong Kong Y. Cheng et al. 10.5194/acp-21-10589-2021
- 5-Hydroxymethylfurfural Hydrodeoxygenation Coupled with Water-Gas Shift Reaction for 2,5-Dimethylfuran Production over Au/ZrO2 Catalysts Z. Li et al. 10.1021/acssuschemeng.1c00616
- Assessing the Potential for Oligomer Formation from the Reactions of Lactones in Secondary Organic Aerosols K. Jiang et al. 10.1021/acs.jpca.7b10411
- Significant Contributions of Isoprene to Summertime Secondary Organic Aerosol in Eastern United States Q. Ying et al. 10.1021/acs.est.5b02514
- Assessing the Potential for the Reactions of Epoxides with Amines on Secondary Organic Aerosol Particles S. Stropoli & M. Elrod 10.1021/acs.jpca.5b07852
- Acidity and the multiphase chemistry of atmospheric aqueous particles and clouds A. Tilgner et al. 10.5194/acp-21-13483-2021
- Organic synthesis in the study of terpene-derived oxidation products in the atmosphere M. Upshur et al. 10.1039/D2NP00064D
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Latest update: 16 Nov 2024
Short summary
We investigated how an important naturally emitted chemical, isoprene, can contribute to the formation of aerosol particles, which are a key component of air pollution that can also influence climate. Specifically, we found that a particular relative of isoprene, methacrylic acid epoxide, is capable of transforming into a number of different chemical components via reaction on existing aerosol particles. These results will help to make isoprene air quality model predictions more accurate.
We investigated how an important naturally emitted chemical, isoprene, can contribute to the...
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