Articles | Volume 13, issue 13
https://doi.org/10.5194/acp-13-6623-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-13-6623-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| Highlight paper
| 
12 Jul 2013
Research article | Highlight paper |
| 12 Jul 2013
Halogen species record Antarctic sea ice extent over glacial–interglacial periods
A. Spolaor
Department of Earth Science, University of Siena, Via Laterina 8, 53100 Siena, Italy
Institute for the Dynamics of Environmental Processes – CNR, University of Venice, Dorsoduro 2137, 30123 Venice, Italy
P. Vallelonga
Centre for Ice and Climate, Niels Bohr Institute, Juliane Maries Vej 30, 2100 Copenhagen, Denmark
J. M. C. Plane
School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK
N. Kehrwald
Department of Environmental Sciences, Informatics and Statistics, University Ca' Foscari of Venice, Dorsoduro 2137, 30123 Venice, Italy
J. Gabrieli
Institute for the Dynamics of Environmental Processes – CNR, University of Venice, Dorsoduro 2137, 30123 Venice, Italy
C. Varin
Department of Environmental Sciences, Informatics and Statistics, University Ca' Foscari of Venice, Dorsoduro 2137, 30123 Venice, Italy
C. Turetta
Institute for the Dynamics of Environmental Processes – CNR, University of Venice, Dorsoduro 2137, 30123 Venice, Italy
G. Cozzi
Institute for the Dynamics of Environmental Processes – CNR, University of Venice, Dorsoduro 2137, 30123 Venice, Italy
R. Kumar
Department of Chemistry, Multanimal Modi (Postgraduate) College, Modinagar-201204 (UP), India
C. Boutron
Laboratoire de Glaciologie et Géophysique de l'Environnement (UMR UJF/CNRS 5183), 54, rue Molière, Domaine Universitaire, B.P. 96, 38402 Saint Martin d' Hères, France
C. Barbante
Institute for the Dynamics of Environmental Processes – CNR, University of Venice, Dorsoduro 2137, 30123 Venice, Italy
Department of Environmental Sciences, Informatics and Statistics, University Ca' Foscari of Venice, Dorsoduro 2137, 30123 Venice, Italy
Viewed
Total article views: 8,703 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 12 Feb 2013)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 5,267 | 3,146 | 290 | 8,703 | 243 | 235 |
- HTML: 5,267
- PDF: 3,146
- XML: 290
- Total: 8,703
- BibTeX: 243
- EndNote: 235
Total article views: 7,203 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 12 Jul 2013)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 4,725 | 2,225 | 253 | 7,203 | 219 | 223 |
- HTML: 4,725
- PDF: 2,225
- XML: 253
- Total: 7,203
- BibTeX: 219
- EndNote: 223
Total article views: 1,500 (including HTML, PDF, and XML)
Cumulative views and downloads
(calculated since 12 Feb 2013)
| HTML | XML | Total | BibTeX | EndNote | |
|---|---|---|---|---|---|
| 542 | 921 | 37 | 1,500 | 24 | 12 |
- HTML: 542
- PDF: 921
- XML: 37
- Total: 1,500
- BibTeX: 24
- EndNote: 12
Cited
46 citations as recorded by crossref.
- Bromine, iodine and sodium along the EAIIST traverse: Bulk and surface snow latitudinal variability G. Celli et al. https://doi.org/10.1016/j.envres.2023.117344
- Climate changes modulated the history of Arctic iodine during the Last Glacial Cycle J. Corella et al. https://doi.org/10.1038/s41467-021-27642-5
- Sea-ice-related halogen enrichment at Law Dome, coastal East Antarctica P. Vallelonga et al. https://doi.org/10.5194/cp-13-171-2017
- Photolysis of frozen iodate salts as a source of active iodine in the polar environment Ó. Gálvez et al. https://doi.org/10.5194/acp-16-12703-2016
- Antarctic sea ice over the past 130 000 years – Part 1: a review of what proxy records tell us X. Crosta et al. https://doi.org/10.5194/cp-18-1729-2022
- Canadian Arctic sea ice reconstructed from bromine in the Greenland NEEM ice core A. Spolaor et al. https://doi.org/10.1038/srep33925
- Ion concentrations in ice wedges: An innovative approach to reconstruct past climate variability Y. Iizuka et al. https://doi.org/10.1016/j.epsl.2019.03.013
- Holocene atmospheric iodine evolution over the North Atlantic J. Corella et al. https://doi.org/10.5194/cp-15-2019-2019
- Antarctic ozone hole modifies iodine geochemistry on the Antarctic Plateau A. Spolaor et al. https://doi.org/10.1038/s41467-021-26109-x
- Arctic mercury flux increased through the Last Glacial Termination with a warming climate D. Segato et al. https://doi.org/10.1038/s41561-023-01172-9
- Tropospheric BrO in Western Antarctica: Distribution, seasonality and link to sea ice state of development C. Prados-Roman et al. https://doi.org/10.1016/j.atmosenv.2025.121588
- Bromine isotope ratio measurements in seawater by multi-collector inductively coupled plasma-mass spectrometry with a conventional sample introduction system J. de Gois et al. https://doi.org/10.1007/s00216-015-8820-1
- Feedback mechanisms between snow and atmospheric mercury: Results and observations from field campaigns on the Antarctic plateau A. Spolaor et al. https://doi.org/10.1016/j.chemosphere.2017.12.180
- Particle size distribution of inorganic and organic ions in coastal and inland Antarctic aerosol E. Barbaro et al. https://doi.org/10.1007/s11356-016-8042-x
- Sea salt sodium record from Talos Dome (East Antarctica) as a potential proxy of the Antarctic past sea ice extent M. Severi et al. https://doi.org/10.1016/j.chemosphere.2017.03.025
- Simultaneous and Synergic Production of Bioavailable Iron and Reactive Iodine Species in Ice K. Kim et al. https://doi.org/10.1021/acs.est.8b06659
- Bromine, iodine and sodium in surface snow along the 2013 Talos Dome–GV7 traverse (northern Victoria Land, East Antarctica) N. Maffezzoli et al. https://doi.org/10.5194/tc-11-693-2017
- Diurnal cycle of iodine, bromine, and mercury concentrations in Svalbard surface snow A. Spolaor et al. https://doi.org/10.5194/acp-19-13325-2019
- Concentration and isotopic composition of bromine and chlorine in Antarctic sea ice P. Vallelonga et al. https://doi.org/10.1016/j.gca.2020.10.020
- First direct observation of sea salt aerosol production from blowing snow above sea ice M. Frey et al. https://doi.org/10.5194/acp-20-2549-2020
- Comparative analysis of sea salt species in snow samples from Svalbard using ICP-QMS and IC techniques A. Spagnesi et al. https://doi.org/10.1016/j.apgeochem.2025.106492
- Glacial meltwater is the primary source of subsurface freshening off the Western Antarctic Peninsula A. Micallef et al. https://doi.org/10.3389/fmars.2026.1779006
- Sea ice fluctuations in the Baffin Bay and the Labrador Sea during glacial abrupt climate changes F. Scoto et al. https://doi.org/10.1073/pnas.2203468119
- Identifying imprints of externally derived dust and halogens in the sedimentary record of an Iberian alpine lake for the past ∼13,500 years – Lake Peixão, Serra da Estrela (Central Portugal) J. Moreno et al. https://doi.org/10.1016/j.scitotenv.2023.166179
- Sea-ice reconstructions from bromine and iodine in ice cores P. Vallelonga et al. https://doi.org/10.1016/j.quascirev.2021.107133
- Halogen-based reconstruction of Russian Arctic sea ice area from the Akademii Nauk ice core (Severnaya Zemlya) A. Spolaor et al. https://doi.org/10.5194/tc-10-245-2016
- Polyatomic Iodine Species at the Air–Water Interface and Its Relevance to Atmospheric Iodine Chemistry: An HD-VSFG and Raman-MCR Study S. Saha et al. https://doi.org/10.1021/acs.jpca.9b00828
- Implications of Snowpack Reactive Bromine Production for Arctic Ice Core Bromine Preservation S. Zhai et al. https://doi.org/10.1029/2023JD039257
- Calibration of Arctic ice core bromine enrichment records for past sea ice reconstructions F. Scoto et al. https://doi.org/10.1016/j.scitotenv.2024.177063
- Last Glacial Maximum sea surface temperature and sea-ice extent in the Pacific sector of the Southern Ocean V. Benz et al. https://doi.org/10.1016/j.quascirev.2016.06.006
- Investigation of factors controlling the mercury geochemical cycle in Kongsfjorden (Svalbard) under contrasting climatic conditions V. Amoruso et al. https://doi.org/10.1016/j.atmosenv.2026.122197
- Sea ice and pollution-modulated changes in Greenland ice core methanesulfonate and bromine O. Maselli et al. https://doi.org/10.5194/cp-13-39-2017
- Nitrite-Induced Activation of Iodate into Molecular Iodine in Frozen Solution K. Kim et al. https://doi.org/10.1021/acs.est.8b06638
- Determination of129I in Arctic snow by a novel analytical approach using IC-ICP-SFMS Ž. Ežerinskis et al. https://doi.org/10.1039/C4JA00179F
- Soluble Iodine Speciation in Marine Aerosols Across the Indian and Pacific Ocean Basins E. Droste et al. https://doi.org/10.3389/fmars.2021.788105
- Iodine speciation in snow during the MOSAiC expedition and its implications for Arctic iodine emissions L. Brown et al. https://doi.org/10.1039/D4FD00178H
- Antarctic Sea Ice Proxies from Marine and Ice Core Archives Suitable for Reconstructing Sea Ice over the Past 2000 Years E. Thomas et al. https://doi.org/10.3390/geosciences9120506
- Variability of bromine monoxide at Barrow, Alaska, over four halogen activation (March–May) seasons and at two on‐ice locations P. Peterson et al. https://doi.org/10.1002/2015JD024094
- A 120 000-year record of sea ice in the North Atlantic? N. Maffezzoli et al. https://doi.org/10.5194/cp-15-2031-2019
- An Age Scale for the First Shallow (Sub-)Antarctic Ice Core from Young Island, Northwest Ross Sea D. Moser et al. https://doi.org/10.3390/geosciences11090368
- 200-year ice core bromine reconstruction at Dome C (Antarctica): observational and modelling results F. Burgay et al. https://doi.org/10.5194/tc-17-391-2023
- Short- and long-term variability of the Antarctic and Greenland ice sheets E. Hanna et al. https://doi.org/10.1038/s43017-023-00509-7
- Seasonality of halogen deposition in polar snow and ice A. Spolaor et al. https://doi.org/10.5194/acp-14-9613-2014
- Dissolved organic matter in the deep TALDICE ice core: A nano-UPLC-nano-ESI-HRMS method R. Zangrando et al. https://doi.org/10.1016/j.scitotenv.2019.134432
- Causes of Enhanced Bromine Levels in Alpine Ice Cores During the 20th Century: Implications for Bromine in the Free European Troposphere M. Legrand et al. https://doi.org/10.1029/2020JD034246
- Implementation and Impacts of Surface and Blowing Snow Sources of Arctic Bromine Activation Within WRF‐Chem 4.1.1 L. Marelle et al. https://doi.org/10.1029/2020MS002391
46 citations as recorded by crossref.
- Bromine, iodine and sodium along the EAIIST traverse: Bulk and surface snow latitudinal variability G. Celli et al. https://doi.org/10.1016/j.envres.2023.117344
- Climate changes modulated the history of Arctic iodine during the Last Glacial Cycle J. Corella et al. https://doi.org/10.1038/s41467-021-27642-5
- Sea-ice-related halogen enrichment at Law Dome, coastal East Antarctica P. Vallelonga et al. https://doi.org/10.5194/cp-13-171-2017
- Photolysis of frozen iodate salts as a source of active iodine in the polar environment Ó. Gálvez et al. https://doi.org/10.5194/acp-16-12703-2016
- Antarctic sea ice over the past 130 000 years – Part 1: a review of what proxy records tell us X. Crosta et al. https://doi.org/10.5194/cp-18-1729-2022
- Canadian Arctic sea ice reconstructed from bromine in the Greenland NEEM ice core A. Spolaor et al. https://doi.org/10.1038/srep33925
- Ion concentrations in ice wedges: An innovative approach to reconstruct past climate variability Y. Iizuka et al. https://doi.org/10.1016/j.epsl.2019.03.013
- Holocene atmospheric iodine evolution over the North Atlantic J. Corella et al. https://doi.org/10.5194/cp-15-2019-2019
- Antarctic ozone hole modifies iodine geochemistry on the Antarctic Plateau A. Spolaor et al. https://doi.org/10.1038/s41467-021-26109-x
- Arctic mercury flux increased through the Last Glacial Termination with a warming climate D. Segato et al. https://doi.org/10.1038/s41561-023-01172-9
- Tropospheric BrO in Western Antarctica: Distribution, seasonality and link to sea ice state of development C. Prados-Roman et al. https://doi.org/10.1016/j.atmosenv.2025.121588
- Bromine isotope ratio measurements in seawater by multi-collector inductively coupled plasma-mass spectrometry with a conventional sample introduction system J. de Gois et al. https://doi.org/10.1007/s00216-015-8820-1
- Feedback mechanisms between snow and atmospheric mercury: Results and observations from field campaigns on the Antarctic plateau A. Spolaor et al. https://doi.org/10.1016/j.chemosphere.2017.12.180
- Particle size distribution of inorganic and organic ions in coastal and inland Antarctic aerosol E. Barbaro et al. https://doi.org/10.1007/s11356-016-8042-x
- Sea salt sodium record from Talos Dome (East Antarctica) as a potential proxy of the Antarctic past sea ice extent M. Severi et al. https://doi.org/10.1016/j.chemosphere.2017.03.025
- Simultaneous and Synergic Production of Bioavailable Iron and Reactive Iodine Species in Ice K. Kim et al. https://doi.org/10.1021/acs.est.8b06659
- Bromine, iodine and sodium in surface snow along the 2013 Talos Dome–GV7 traverse (northern Victoria Land, East Antarctica) N. Maffezzoli et al. https://doi.org/10.5194/tc-11-693-2017
- Diurnal cycle of iodine, bromine, and mercury concentrations in Svalbard surface snow A. Spolaor et al. https://doi.org/10.5194/acp-19-13325-2019
- Concentration and isotopic composition of bromine and chlorine in Antarctic sea ice P. Vallelonga et al. https://doi.org/10.1016/j.gca.2020.10.020
- First direct observation of sea salt aerosol production from blowing snow above sea ice M. Frey et al. https://doi.org/10.5194/acp-20-2549-2020
- Comparative analysis of sea salt species in snow samples from Svalbard using ICP-QMS and IC techniques A. Spagnesi et al. https://doi.org/10.1016/j.apgeochem.2025.106492
- Glacial meltwater is the primary source of subsurface freshening off the Western Antarctic Peninsula A. Micallef et al. https://doi.org/10.3389/fmars.2026.1779006
- Sea ice fluctuations in the Baffin Bay and the Labrador Sea during glacial abrupt climate changes F. Scoto et al. https://doi.org/10.1073/pnas.2203468119
- Identifying imprints of externally derived dust and halogens in the sedimentary record of an Iberian alpine lake for the past ∼13,500 years – Lake Peixão, Serra da Estrela (Central Portugal) J. Moreno et al. https://doi.org/10.1016/j.scitotenv.2023.166179
- Sea-ice reconstructions from bromine and iodine in ice cores P. Vallelonga et al. https://doi.org/10.1016/j.quascirev.2021.107133
- Halogen-based reconstruction of Russian Arctic sea ice area from the Akademii Nauk ice core (Severnaya Zemlya) A. Spolaor et al. https://doi.org/10.5194/tc-10-245-2016
- Polyatomic Iodine Species at the Air–Water Interface and Its Relevance to Atmospheric Iodine Chemistry: An HD-VSFG and Raman-MCR Study S. Saha et al. https://doi.org/10.1021/acs.jpca.9b00828
- Implications of Snowpack Reactive Bromine Production for Arctic Ice Core Bromine Preservation S. Zhai et al. https://doi.org/10.1029/2023JD039257
- Calibration of Arctic ice core bromine enrichment records for past sea ice reconstructions F. Scoto et al. https://doi.org/10.1016/j.scitotenv.2024.177063
- Last Glacial Maximum sea surface temperature and sea-ice extent in the Pacific sector of the Southern Ocean V. Benz et al. https://doi.org/10.1016/j.quascirev.2016.06.006
- Investigation of factors controlling the mercury geochemical cycle in Kongsfjorden (Svalbard) under contrasting climatic conditions V. Amoruso et al. https://doi.org/10.1016/j.atmosenv.2026.122197
- Sea ice and pollution-modulated changes in Greenland ice core methanesulfonate and bromine O. Maselli et al. https://doi.org/10.5194/cp-13-39-2017
- Nitrite-Induced Activation of Iodate into Molecular Iodine in Frozen Solution K. Kim et al. https://doi.org/10.1021/acs.est.8b06638
- Determination of129I in Arctic snow by a novel analytical approach using IC-ICP-SFMS Ž. Ežerinskis et al. https://doi.org/10.1039/C4JA00179F
- Soluble Iodine Speciation in Marine Aerosols Across the Indian and Pacific Ocean Basins E. Droste et al. https://doi.org/10.3389/fmars.2021.788105
- Iodine speciation in snow during the MOSAiC expedition and its implications for Arctic iodine emissions L. Brown et al. https://doi.org/10.1039/D4FD00178H
- Antarctic Sea Ice Proxies from Marine and Ice Core Archives Suitable for Reconstructing Sea Ice over the Past 2000 Years E. Thomas et al. https://doi.org/10.3390/geosciences9120506
- Variability of bromine monoxide at Barrow, Alaska, over four halogen activation (March–May) seasons and at two on‐ice locations P. Peterson et al. https://doi.org/10.1002/2015JD024094
- A 120 000-year record of sea ice in the North Atlantic? N. Maffezzoli et al. https://doi.org/10.5194/cp-15-2031-2019
- An Age Scale for the First Shallow (Sub-)Antarctic Ice Core from Young Island, Northwest Ross Sea D. Moser et al. https://doi.org/10.3390/geosciences11090368
- 200-year ice core bromine reconstruction at Dome C (Antarctica): observational and modelling results F. Burgay et al. https://doi.org/10.5194/tc-17-391-2023
- Short- and long-term variability of the Antarctic and Greenland ice sheets E. Hanna et al. https://doi.org/10.1038/s43017-023-00509-7
- Seasonality of halogen deposition in polar snow and ice A. Spolaor et al. https://doi.org/10.5194/acp-14-9613-2014
- Dissolved organic matter in the deep TALDICE ice core: A nano-UPLC-nano-ESI-HRMS method R. Zangrando et al. https://doi.org/10.1016/j.scitotenv.2019.134432
- Causes of Enhanced Bromine Levels in Alpine Ice Cores During the 20th Century: Implications for Bromine in the Free European Troposphere M. Legrand et al. https://doi.org/10.1029/2020JD034246
- Implementation and Impacts of Surface and Blowing Snow Sources of Arctic Bromine Activation Within WRF‐Chem 4.1.1 L. Marelle et al. https://doi.org/10.1029/2020MS002391
Saved (final revised paper)
Latest update: 07 Jul 2026
Altmetrics
Final-revised paper
Preprint