Articles | Volume 13, issue 7
Atmos. Chem. Phys., 13, 3547–3567, 2013
Atmos. Chem. Phys., 13, 3547–3567, 2013

Research article 02 Apr 2013

Research article | 02 Apr 2013

The influence of snow grain size and impurities on the vertical profiles of actinic flux and associated NOx emissions on the Antarctic and Greenland ice sheets

M. C. Zatko1, T. C. Grenfell1, B. Alexander1, S. J. Doherty2, J. L. Thomas3,4, and X. Yang5,6 M. C. Zatko et al.
  • 1Department of Atmospheric Sciences, Box 351640, University of Washington, Seattle, WA 98195, USA
  • 2Joint Institute for the Study of Atmosphere and Ocean, 3737 Brooklyn Ave NE, Seattle, WA 98195, USA
  • 3UPMC Univ. Paris 06, UMR8190, CNRS/INSU – Université Versailles St.-Quentin, LATMOS-IPSL, Paris, France
  • 4Department of Atmospheric and Oceanic Sciences, University of California, Los Angeles, CA 90095, USA
  • 5National Centre for Atmospheric Science (NCAS), Cambridge, CB2 1EW, UK
  • 6Centre for Atmospheric Science, Department of Chemistry, University of Cambridge, Cambridge CB2 1EW, UK

Abstract. We use observations of the absorption properties of black carbon and non-black carbon impurities in near-surface snow collected near the research stations at South Pole and Dome C, Antarctica, and Summit, Greenland, combined with a snowpack actinic flux parameterization to estimate the vertical profile and e-folding depth of ultraviolet/near-visible (UV/near-vis) actinic flux in the snowpack at each location. We have developed a simple and broadly applicable parameterization to calculate depth and wavelength dependent snowpack actinic flux that can be easily integrated into large-scale (e.g., 3-D) models of the atmosphere. The calculated e-folding depths of actinic flux at 305 nm, the peak wavelength of nitrate photolysis in the snowpack, are 8–12 cm near the stations and 15–31 cm away (>11 km) from the stations. We find that the e-folding depth is strongly dependent on impurity content and wavelength in the UV/near-vis region, which explains the relatively shallow e-folding depths near stations where local activities lead to higher snow impurity levels. We calculate the lifetime of NOx in the snowpack interstitial air produced by photolysis of snowpack nitrate against wind pumping (τwind pumping) from the snowpack, and compare this to the calculated lifetime of NOx against chemical conversion to HNO3chemical) to determine whether the NOx produced at a given depth can escape from the snowpack to the overlying atmosphere. Comparison of τwind pumping and τchemical suggests efficient escape of photoproduced NOx in the snowpack to the overlying atmosphere throughout most of the photochemically active zone. Calculated vertical actinic flux profiles and observed snowpack nitrate concentrations are used to estimate the potential flux of NOx from the snowpack. Calculated NOx fluxes of 4.4 × 108–3.8 × 109 molecules cm−2 s−1 in remote polar locations and 3.2–8.2 × 108 molecules cm−2 s−1 near polar stations for January at Dome C and South Pole and June at Summit suggest that NOx flux measurements near stations may be underestimating the amount of NOx emitted from the clean polar snowpack.

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