Articles | Volume 13, issue 4
https://doi.org/10.5194/acp-13-2031-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-13-2031-2013
© Author(s) 2013. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
21 Feb 2013
Research article |
| 21 Feb 2013
Evaluation of HOx sources and cycling using measurement-constrained model calculations in a 2-methyl-3-butene-2-ol (MBO) and monoterpene (MT) dominated ecosystem
S. Kim
now at: Department of Earth System Science, University of California, Irvine, CA, USA
ACD/NESL/NCAR Boulder, CO 80301, USA
G. M. Wolfe
Department of Chemistry, University of Wisconsin, Madison, WI, USA
now at: Joint Center for Earth Systems Technology, Baltimore County, MD USA
now at: NASA Goddard Space Flight Center, Greenbelt, MD, USA
L. Mauldin
ACD/NESL/NCAR Boulder, CO 80301, USA
now at: Department of Physics, University of Helsinki, Helsinki, Finland
now at: Department of Atmospheric and Oceanic Sciences, University of Colorado, Boulder, CO, USA
C. Cantrell
ACD/NESL/NCAR Boulder, CO 80301, USA
A. Guenther
ACD/NESL/NCAR Boulder, CO 80301, USA
T. Karl
ACD/NESL/NCAR Boulder, CO 80301, USA
A. Turnipseed
ACD/NESL/NCAR Boulder, CO 80301, USA
J. Greenberg
ACD/NESL/NCAR Boulder, CO 80301, USA
S. R. Hall
ACD/NESL/NCAR Boulder, CO 80301, USA
K. Ullmann
ACD/NESL/NCAR Boulder, CO 80301, USA
E. Apel
ACD/NESL/NCAR Boulder, CO 80301, USA
R. Hornbrook
ACD/NESL/NCAR Boulder, CO 80301, USA
Y. Kajii
Division of Applied Chemistry, Tokyo Metropolitan University, Tokyo
now at: Graduate School of Environmental Studies and Human and Environmental Studies, Kyoto University, Kyoto, Japan
Y. Nakashima
Division of Applied Chemistry, Tokyo Metropolitan University, Tokyo
now at: Department of Environmental and Natural Resource Sciences, Tokyo University of Agriculture and Technology, Tokyo, Japan
F. N. Keutsch
Department of Chemistry, University of Wisconsin, Madison, WI, USA
J. P. DiGangi
Department of Chemistry, University of Wisconsin, Madison, WI, USA
S. B. Henry
Department of Chemistry, University of Wisconsin, Madison, WI, USA
L. Kaser
University of Innsbruck, Innsbruck, Austria
R. Schnitzhofer
University of Innsbruck, Innsbruck, Austria
M. Graus
CIRES, University of Colorado, Boulder, CO 80309 USA
Chemical Science Division, ESRL-NOAA, Boulder, CO 80305, USA
A. Hansel
University of Innsbruck, Innsbruck, Austria
W. Zheng
ACD/NESL/NCAR Boulder, CO 80301, USA
F. F. Flocke
ACD/NESL/NCAR Boulder, CO 80301, USA
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44 citations as recorded by crossref.
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- Observation and modelling of HOx radicals in a boreal forest K. Hens et al. https://doi.org/10.5194/acp-14-8723-2014
- Measurement of interferences associated with the detection of the hydroperoxy radical in the atmosphere using laser-induced fluorescence M. Lew et al. https://doi.org/10.5194/amt-11-95-2018
- Investigation of the β-pinene photooxidation by OH in the atmosphere simulation chamber SAPHIR M. Kaminski et al. https://doi.org/10.5194/acp-17-6631-2017
- Isoprene photochemistry over the Amazon rainforest Y. Liu et al. https://doi.org/10.1073/pnas.1524136113
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- A portable, low-cost relaxed eddy accumulation (REA) system for quantifying ecosystem-level fluxes of volatile organics C. Sarkar et al. https://doi.org/10.1016/j.atmosenv.2020.117764
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- A new technique for the direct detection of HO2 radicals using bromide chemical ionization mass spectrometry (Br-CIMS): initial characterization J. Sanchez et al. https://doi.org/10.5194/amt-9-3851-2016
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- Unclassical Radical Generation Mechanisms in the Troposphere: A Review X. Yang et al. https://doi.org/10.1021/acs.est.4c00742
- Total OH reactivity measurements in ambient air in a southern Rocky mountain ponderosa pine forest during BEACHON-SRM08 summer campaign Y. Nakashima et al. https://doi.org/10.1016/j.atmosenv.2013.11.042
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- Evaluation of nitrous acid sources and sinks in urban outflow E. Gall et al. https://doi.org/10.1016/j.atmosenv.2015.12.044
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- Experimental chemical budgets of OH, HO2, and RO2 radicals in rural air in western Germany during the JULIAC campaign 2019 C. Cho et al. https://doi.org/10.5194/acp-23-2003-2023
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- Formation and temperature dependence of highly oxygenated organic molecules (HOMs) from Δ3-carene ozonolysis Y. Luo et al. https://doi.org/10.5194/acp-24-9459-2024
- Large Daytime Molecular Chlorine Missing Source at a Suburban Site in East China Q. Chen et al. https://doi.org/10.1029/2021JD035796
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- Formaldehyde production from isoprene oxidation across NOx regimes G. Wolfe et al. https://doi.org/10.5194/acp-16-2597-2016
- Isoprene photo-oxidation products quantify the effect of pollution on hydroxyl radicals over Amazonia Y. Liu et al. https://doi.org/10.1126/sciadv.aar2547
- Comprehensive characterization of atmospheric organic carbon at a forested site J. Hunter et al. https://doi.org/10.1038/ngeo3018
- Insight into decreased ozone formation across the Chinese National Day Holidays at a regional background site in the Pearl River Delta J. Chen et al. https://doi.org/10.1016/j.atmosenv.2023.120142
- OH and HO2 radical chemistry at a suburban site during the EXPLORE-YRD campaign in 2018 X. Ma et al. https://doi.org/10.5194/acp-22-7005-2022
44 citations as recorded by crossref.
- Testing Atmospheric Oxidation in an Alabama Forest P. Feiner et al. https://doi.org/10.1175/JAS-D-16-0044.1
- Contribution from biogenic organic compounds to particle growth during the 2010 BEACHON-ROCS campaign in a Colorado temperate needleleaf forest L. Zhou et al. https://doi.org/10.5194/acp-15-8643-2015
- Secondary Organic Aerosol Mass Yields from NO3 Oxidation of α-Pinene and Δ-Carene: Effect of RO2 Radical Fate D. Day et al. https://doi.org/10.1021/acs.jpca.2c04419
- Photooxidation of pinonaldehyde at ambient conditions investigated in the atmospheric simulation chamber SAPHIR M. Rolletter et al. https://doi.org/10.5194/acp-20-13701-2020
- Atmospheric photochemical reactivity and ozone production at two sites in Hong Kong: Application of a Master Chemical Mechanism–photochemical box model Z. Ling et al. https://doi.org/10.1002/2014JD021794
- Intercomparison of OH and OH reactivity measurements in a high isoprene and low NO environment during the Southern Oxidant and Aerosol Study (SOAS) D. Sanchez et al. https://doi.org/10.1016/j.atmosenv.2017.10.056
- Missing peroxy radical sources within a summertime ponderosa pine forest G. Wolfe et al. https://doi.org/10.5194/acp-14-4715-2014
- Observation and modelling of HOx radicals in a boreal forest K. Hens et al. https://doi.org/10.5194/acp-14-8723-2014
- Measurement of interferences associated with the detection of the hydroperoxy radical in the atmosphere using laser-induced fluorescence M. Lew et al. https://doi.org/10.5194/amt-11-95-2018
- Investigation of the β-pinene photooxidation by OH in the atmosphere simulation chamber SAPHIR M. Kaminski et al. https://doi.org/10.5194/acp-17-6631-2017
- Isoprene photochemistry over the Amazon rainforest Y. Liu et al. https://doi.org/10.1073/pnas.1524136113
- Overview of the Manitou Experimental Forest Observatory: site description and selected science results from 2008 to 2013 J. Ortega et al. https://doi.org/10.5194/acp-14-6345-2014
- Secondary organic aerosol formation from in situ OH, O3, and NO3 oxidation of ambient forest air in an oxidation flow reactor B. Palm et al. https://doi.org/10.5194/acp-17-5331-2017
- Atmospheric photooxidation and ozonolysis of Δ3-carene and 3-caronaldehyde: rate constants and product yields L. Hantschke et al. https://doi.org/10.5194/acp-21-12665-2021
- Investigation of the α-pinene photooxidation by OH in the atmospheric simulation chamber SAPHIR M. Rolletter et al. https://doi.org/10.5194/acp-19-11635-2019
- In situ secondary organic aerosol formation from ambient pine forest air using an oxidation flow reactor B. Palm et al. https://doi.org/10.5194/acp-16-2943-2016
- Investigation of the oxidation of methyl vinyl ketone (MVK) by OH radicals in the atmospheric simulation chamber SAPHIR H. Fuchs et al. https://doi.org/10.5194/acp-18-8001-2018
- Observation and modeling of atmospheric OH and HO2∗ radicals at a subtropical rural site and implications for secondary pollutants Z. Zou et al. https://doi.org/10.5194/acp-25-8147-2025
- Potential Role of Stabilized Criegee Radicals in Sulfuric Acid Production in a High Biogenic VOC Environment S. Kim et al. https://doi.org/10.1021/es505793t
- The Framework for 0-D Atmospheric Modeling (F0AM) v3.1 G. Wolfe et al. https://doi.org/10.5194/gmd-9-3309-2016
- Secondary organic aerosol formation from hydroxyl radical oxidation and ozonolysis of monoterpenes D. Zhao et al. https://doi.org/10.5194/acp-15-991-2015
- Comparison of different real time VOC measurement techniques in a ponderosa pine forest L. Kaser et al. https://doi.org/10.5194/acp-13-2893-2013
- The primary and recycling sources of OH during the NACHTT‐2011 campaign: HONO as an important OH primary source in the wintertime S. Kim et al. https://doi.org/10.1002/2013JD019784
- A portable, low-cost relaxed eddy accumulation (REA) system for quantifying ecosystem-level fluxes of volatile organics C. Sarkar et al. https://doi.org/10.1016/j.atmosenv.2020.117764
- Impact of isoprene and HONO chemistry on ozone and OVOC formation in a semirural South Korean forest S. Kim et al. https://doi.org/10.5194/acp-15-4357-2015
- A new technique for the direct detection of HO2 radicals using bromide chemical ionization mass spectrometry (Br-CIMS): initial characterization J. Sanchez et al. https://doi.org/10.5194/amt-9-3851-2016
- Atmospheric photo-oxidation of myrcene: OH reaction rate constant, gas-phase oxidation products and radical budgets Z. Tan et al. https://doi.org/10.5194/acp-21-16067-2021
- OH, HO2, and RO2 radical chemistry in a rural forest environment: measurements, model comparisons, and evidence of a missing radical sink B. Bottorff et al. https://doi.org/10.5194/acp-23-10287-2023
- OH and HO2 radical chemistry in a midlatitude forest: measurements and model comparisons M. Lew et al. https://doi.org/10.5194/acp-20-9209-2020
- Unclassical Radical Generation Mechanisms in the Troposphere: A Review X. Yang et al. https://doi.org/10.1021/acs.est.4c00742
- Total OH reactivity measurements in ambient air in a southern Rocky mountain ponderosa pine forest during BEACHON-SRM08 summer campaign Y. Nakashima et al. https://doi.org/10.1016/j.atmosenv.2013.11.042
- Insights into HOx and ROx chemistry in the boreal forest via measurement of peroxyacetic acid, peroxyacetic nitric anhydride (PAN) and hydrogen peroxide J. Crowley et al. https://doi.org/10.5194/acp-18-13457-2018
- Evaluation of nitrous acid sources and sinks in urban outflow E. Gall et al. https://doi.org/10.1016/j.atmosenv.2015.12.044
- Contributions to OH reactivity from unexplored volatile organic compounds measured by PTR-ToF-MS – a case study in a suburban forest of the Seoul metropolitan area during the Korea–United States Air Quality Study (KORUS-AQ) 2016 D. Sanchez et al. https://doi.org/10.5194/acp-21-6331-2021
- Experimental chemical budgets of OH, HO2, and RO2 radicals in rural air in western Germany during the JULIAC campaign 2019 C. Cho et al. https://doi.org/10.5194/acp-23-2003-2023
- Evaluation of OH and HO2 concentrations and their budgets during photooxidation of 2-methyl-3-butene-2-ol (MBO) in the atmospheric simulation chamber SAPHIR A. Novelli et al. https://doi.org/10.5194/acp-18-11409-2018
- Formation and temperature dependence of highly oxygenated organic molecules (HOMs) from Δ3-carene ozonolysis Y. Luo et al. https://doi.org/10.5194/acp-24-9459-2024
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- Observations of gas- and aerosol-phase organic nitrates at BEACHON-RoMBAS 2011 J. Fry et al. https://doi.org/10.5194/acp-13-8585-2013
- Formaldehyde production from isoprene oxidation across NOx regimes G. Wolfe et al. https://doi.org/10.5194/acp-16-2597-2016
- Isoprene photo-oxidation products quantify the effect of pollution on hydroxyl radicals over Amazonia Y. Liu et al. https://doi.org/10.1126/sciadv.aar2547
- Comprehensive characterization of atmospheric organic carbon at a forested site J. Hunter et al. https://doi.org/10.1038/ngeo3018
- Insight into decreased ozone formation across the Chinese National Day Holidays at a regional background site in the Pearl River Delta J. Chen et al. https://doi.org/10.1016/j.atmosenv.2023.120142
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