Articles | Volume 13, issue 1
Atmos. Chem. Phys., 13, 147–164, 2013
Atmos. Chem. Phys., 13, 147–164, 2013

Research article 08 Jan 2013

Research article | 08 Jan 2013

On the relationship between total ozone and atmospheric dynamics and chemistry at mid-latitudes – Part 1: Statistical models and spatial fingerprints of atmospheric dynamics and chemistry

L. Frossard1, H. E. Rieder*,2, M. Ribatet1,**, J. Staehelin2, J. A. Maeder2, S. Di Rocco2,3, A. C. Davison1, and T. Peter2 L. Frossard et al.
  • 1Mathematics Institute for Analysis and Applications, EPF Lausanne, Lausanne, Switzerland
  • 2Institute for Atmospheric and Climate Science, ETH Zurich, Zurich, Switzerland
  • 3Department for Geography, University of Zurich, Zurich, Switzerland
  • *now at: Lamont-Doherty Earth Observatory and Department of Applied Physics and Applied Mathematics, Columbia University, New York, NY, USA
  • **now at: Institute of Mathematics and Mathematical Modeling, University Montpellier II, Montpellier, France

Abstract. We use statistical models for mean and extreme values of total column ozone to analyze "fingerprints" of atmospheric dynamics and chemistry on long-term ozone changes at northern and southern mid-latitudes on grid cell basis. At each grid cell, the r-largest order statistics method is used for the analysis of extreme events in low and high total ozone (termed ELOs and EHOs, respectively), and an autoregressive moving average (ARMA) model is used for the corresponding mean value analysis. In order to describe the dynamical and chemical state of the atmosphere, the statistical models include important atmospheric covariates: the solar cycle, the Quasi-Biennial Oscillation (QBO), ozone depleting substances (ODS) in terms of equivalent effective stratospheric chlorine (EESC), the North Atlantic Oscillation (NAO), the Antarctic Oscillation (AAO), the El Niño/Southern Oscillation (ENSO), and aerosol load after the volcanic eruptions of El Chichón and Mt. Pinatubo. The influence of the individual covariates on mean and extreme levels in total column ozone is derived on a grid cell basis. The results show that "fingerprints", i.e., significant influence, of dynamical and chemical features are captured in both the "bulk" and the tails of the statistical distribution of ozone, respectively described by mean values and EHOs/ELOs. While results for the solar cycle, QBO, and EESC are in good agreement with findings of earlier studies, unprecedented spatial fingerprints are retrieved for the dynamical covariates. Column ozone is enhanced over Labrador/Greenland, the North Atlantic sector and over the Norwegian Sea, but is reduced over Europe, Russia and the Eastern United States during the positive NAO phase, and vice-versa during the negative phase. The NAO's southern counterpart, the AAO, strongly influences column ozone at lower southern mid-latitudes, including the southern parts of South America and the Antarctic Peninsula, and the central southern mid-latitudes. Results for both NAO and AAO confirm the importance of atmospheric dynamics for ozone variability and changes from local/regional to global scales.

Final-revised paper