Articles | Volume 12, issue 9
Atmos. Chem. Phys., 12, 4159–4179, 2012
https://doi.org/10.5194/acp-12-4159-2012
Atmos. Chem. Phys., 12, 4159–4179, 2012
https://doi.org/10.5194/acp-12-4159-2012

Research article 10 May 2012

Research article | 10 May 2012

Impact of January 2005 solar proton events on chlorine species

A. Damiani1, B. Funke2, D. R. Marsh3, M. López-Puertas2, M. L. Santee4, L. Froidevaux4, S. Wang4, C. H. Jackman5, T. von Clarmann6, A. Gardini2, R. R. Cordero1, and M. Storini7 A. Damiani et al.
  • 1Physics Department, University of Santiago de Chile, Santiago, Chile
  • 2Instituto de Astrof\'isica de Andaluc\'ia, CSIC, Granada, Spain
  • 3National Center for Atmospheric Research, Boulder, Colorado, USA
  • 4Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California, USA
  • 5NASA Goddard Space Flight Center, Greenbelt, Maryland, USA
  • 6Karlsruhe Institute of Technology, Institute for Meteorology and Climate Research, Karlsruhe, Germany
  • 7Institute of Interplanetary Space Physics, INAF, Rome, Italy

Abstract. Sudden changes in stratospheric chlorine species in the polar northern atmosphere, caused by the Solar Proton Events (SPEs) of 17 and 20 January 2005, have been investigated and compared with version 4 of the Whole Atmosphere Community Climate Model (WACCM4). We used Aura Microwave Limb Sounder (MLS) measurements to monitor the variability of ClO, HCl, HOCl and Michelson Interferometer for Passive Atmospheric Sounder (MIPAS) on ENVISAT to retrieve ClONO2. SPE-induced chlorine activation has been identified. HCl decrease occurred at nearly all the investigated altitudes (i.e., 10–0.5 hPa) with the strongest decrease (of about 0.25 ppbv) on 21 January. HOCl was found to be the main active chlorine species under nighttime conditions (with increases of more than 0.2 ppbv) whereas both HOCl and ClO enhancements (about 0.1 ppbv) have been observed at the polar night terminator. Further, small ClO decreases (of less than 0.1 ppbv) and ClONO2 enhancements (about 0.2 ppbv) have been observed at higher latitudes (i.e., at nighttime) roughly above 2 hPa.

While WACCM4 reproduces most of the SPE-induced variability in the chlorine species fairly well, in some particular regions discrepancies between the modeled and measured temporal evolution of the abundances of chlorine species were found. HOCl changes are modelled very well with respect to both magnitude and geographic distribution. ClO decreases are reproduced at high latitudes, whereas ClO enhancements in the terminator region are underestimated and attributed to background variations. WACCM4 also reproduces the HCl depletion in the mesosphere but it does not show the observed decrease below about 2 hPa. Finally, WACCM4 simulations indicate that the observed ClONO2 increase is dominated by background variability, although SPE-induced production might contribute by 0.1 ppbv.

Download
Altmetrics
Final-revised paper
Preprint