Articles | Volume 12, issue 21
Atmos. Chem. Phys., 12, 10519–10533, 2012

Special issue: Program of Regional Integrated Experiments on Air Quality...

Atmos. Chem. Phys., 12, 10519–10533, 2012

Technical note 12 Nov 2012

Technical note | 12 Nov 2012

Technical Note: The application of an improved gas and aerosol collector for ambient air pollutants in China

H.-B. Dong1,2,3, L.-M. Zeng2, M. Hu2, Y.-S. Wu2, Y.-H. Zhang2, J. Slanina2, M. Zheng2, Z.-F. Wang1, and R. Jansen2,4 H.-B. Dong et al.
  • 1State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing, China
  • 2State Key Joint Laboratory of Environmental Simulation and Pollution Control, College of Environmental Sciences and Engineering, Peking University, Beijing, China
  • 3Graduate University of Chinese Academy of Sciences, Beijing, China
  • 4Energy Research Centre of the Netherlands (ECN), Westerduinweg 3, Building 04, 1755 ZG Petten, The Netherlands

Abstract. An improved Gas and Aerosol Collector (GAC) equipped with a newly designed aerosol collector and a set of dull-polished wet annular denuder (WAD) was developed based on a Steam Jet Aerosol Collector (SJAC) sampler. Combined with Ion Chromatography (IC) the new sampler performed well in laboratory tests with high collection efficiencies for SO2 (above 98%) and particulate sulfate (as high as 99.5%). An inter-comparison between the GAC-IC system and the filter-pack method was performed and the results indicated that the GAC-IC system could supply reliable particulate sulfate, nitrate, chloride, and ammonium data in field measurement with a much wider range of ambient concentrations. When applied in two major field campaigns (rural and coastal sites) in China, the GAC-IC system provided high-quality data in ambient conditions even under high loadings of pollutants. Its measurements were highly correlated with data by other commercial instruments such as the SO2 analyzer (43c, Thermo-Fisher, USA; R2 as 0.96), the HONO analyzer (LOPAP, Germany; R2 as 0.91 for samples from 15:00 to 07:00), a filter sampler (Tianhong, China; R2 as 0.86 for SO42−), and Aerosol Mass Spectrometer (AMS, Aerodyne, USA; R2 above 0.77 for major species) over a wide range of concentrations. Through the application of the GAC-IC system, it was identified that 70% of chloride and nitrate by the filter method could be lost during daytime sampling due to high temperature in the rural site of Kaiping. In Changdao field campaign (coastal site), though a particle dryer was applied, its drying efficiency was not well considered for the collection efficiency of AMS seemed still interfered a bit by local high relative humidity. If the inter-comparison was done with relative humidity below 50%, the correlations ranged from 0.81 to 0.94 for major species. Through laboratory and field studies, this instrument is proved particularly useful in future intensive campaigns or long-term monitoring stations to study various environmental issues such as secondary aerosol and haze formation, as well as climate change.

Final-revised paper