Journal cover Journal topic
Atmospheric Chemistry and Physics An interactive open-access journal of the European Geosciences Union
Journal topic

Journal metrics

IF value: 5.414
IF5.414
IF 5-year value: 5.958
IF 5-year
5.958
CiteScore value: 9.7
CiteScore
9.7
SNIP value: 1.517
SNIP1.517
IPP value: 5.61
IPP5.61
SJR value: 2.601
SJR2.601
Scimago H <br class='widget-line-break'>index value: 191
Scimago H
index
191
h5-index value: 89
h5-index89
Volume 12, issue 2
Atmos. Chem. Phys., 12, 1021–1030, 2012
https://doi.org/10.5194/acp-12-1021-2012
© Author(s) 2012. This work is distributed under
the Creative Commons Attribution 3.0 License.
Atmos. Chem. Phys., 12, 1021–1030, 2012
https://doi.org/10.5194/acp-12-1021-2012
© Author(s) 2012. This work is distributed under
the Creative Commons Attribution 3.0 License.

Research article 20 Jan 2012

Research article | 20 Jan 2012

Isoprene in poplar emissions: effects on new particle formation and OH concentrations

A. Kiendler-Scharr1, S. Andres1, M. Bachner1, K. Behnke2,*, S. Broch1, A. Hofzumahaus1, F. Holland1, E. Kleist3, T. F. Mentel1, F. Rubach1, M. Springer1, B. Steitz1, R. Tillmann1, A. Wahner1, J.-P. Schnitzler2,*, and J. Wildt3 A. Kiendler-Scharr et al.
  • 1Institute of Energy and Climate Research, Troposphere (IEK-8), Forschungszentrum Jülich GmbH, Jülich, Germany
  • 2Institute of Meteorology and Climate Research, Karlsruhe Institute of Technology, Garmisch-Partenkirchen, Germany
  • 3Institute of Bio- and Geosciences, Plant Sciences (IBG-2), Forschungszentrum Jülich GmbH, Jülich, Germany
  • *present address: Research Unit Environmental Simulation, Institute of Biochemical Plant Pathology, Helmholtz Zentrum München, Neuherberg, Germany

Abstract. Stress-induced volatile organic compound (VOC) emissions from transgenic Grey poplar modified in isoprene emission potential were used for the investigation of photochemical secondary organic aerosol (SOA) formation. In poplar, acute ozone stress induces the emission of a wide array of VOCs dominated by sesquiterpenes and aromatic VOCs. Constitutive light-dependent emission of isoprene ranged between 66 nmol m−2 s−1 in non-transgenic controls (wild type WT) and nearly zero (<0.5 nmol m−2 s−1) in isoprene emission-repressed plants (line RA22), respectively. Nucleation rates of up to 3600 cm−3 s−1 were observed in our experiments. In the presence of isoprene new particle formation was suppressed compared to non-isoprene containing VOC mixtures. Compared to isoprene/monoterpene systems emitted from other plants the suppression of nucleation by isoprene was less effective for the VOC mixture emitted from stressed poplar. This is explained by the observed high efficiency of new particle formation for emissions from stressed poplar. Direct measurements of OH in the reaction chamber revealed that the steady state concentration of OH is lower in the presence of isoprene than in the absence of isoprene, supporting the hypothesis that isoprenes' suppressing effect on nucleation is related to radical chemistry. In order to test whether isoprene contributes to SOA mass formation, fully deuterated isoprene (C5D8) was added to the stress-induced emission profile of an isoprene free poplar mutant. Mass spectral analysis showed that, despite the isoprene-induced suppression of particle formation, fractions of deuterated isoprene were incorporated into the SOA. A fractional mass yield of 2.3% of isoprene was observed. Future emission changes due to land use and climate change may therefore affect both gas phase oxidation capacity and new particle number formation.

Publications Copernicus
Download
Citation
Altmetrics
Final-revised paper
Preprint