Satellite- and ground-based CO total column observations over 2010 Russian fires: accuracy of top-down estimates based on thermal IR satellite data

Abstract. CO total column data are presented from three space sounders and two ground-based spectrometers in Moscow and its suburbs during the forest and peat fires that occurred in Central Russia in July–August 2010. Also presented are ground-based in situ CO measurements. The Moscow area was strongly impacted by the CO plume from these fires. Concurrent satellite- and ground-based observations were used to quantify the errors of CO top-down emission estimates. On certain days, CO total columns retrieved from the data of the space-based sounders were 2–3 times less than those obtained from the ground-based sun-tracking spectrometers. The depth of the polluted layer over Moscow was estimated using total column measurements compared with CO volume mixing ratios in the surface layer and on the TV tower and found to be around 360 m. The missing CO that is the average difference between the CO total column accurately determined by the ground spectrometers and that retrieved by AIRS, MOPITT, and IASI was determined for the Moscow area between 1.6 and 3.3 × 10¹⁸ molec cm⁻². These values were extrapolated onto the entire plume; subsequently, the CO burden (total mass) over Russia during the fire event was corrected. A top-down estimate of the total emitted CO, obtained by a simple mass balance model increased by 40–100 % for different sensors due to this correction. Final assessments of total CO emitted by Russian wildfires obtained from different sounders are between 34 and 40 Tg CO during July–August 2010.