Articles | Volume 11, issue 13
https://doi.org/10.5194/acp-11-6749-2011
© Author(s) 2011. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-11-6749-2011
© Author(s) 2011. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
14 Jul 2011
Research article |
| 14 Jul 2011
Isoprene oxidation mechanisms: measurements and modelling of OH and HO2 over a South-East Asian tropical rainforest during the OP3 field campaign
D. Stone
School of Earth & Environment, University of Leeds, Leeds, UK
School of Chemistry, University of Leeds, Leeds, UK
M. J. Evans
School of Earth & Environment, University of Leeds, Leeds, UK
P. M. Edwards
School of Chemistry, University of Leeds, Leeds, UK
R. Commane
School of Chemistry, University of Leeds, Leeds, UK
now at: School of Engineering & Applied Sciences, Harvard University, Cambridge, USA
T. Ingham
School of Chemistry, University of Leeds, Leeds, UK
National Centre for Atmospheric Science, University of Leeds, Leeds, UK
A. R. Rickard
School of Chemistry, University of Leeds, Leeds, UK
National Centre for Atmospheric Science, University of Leeds, Leeds, UK
D. M. Brookes
Department of Chemistry, University of Leicester, Leicester, UK
J. Hopkins
Department of Chemistry, University of York, York, UK
National Centre for Atmospheric Science, University of York, York, UK
R. J. Leigh
Department of Chemistry, University of Leicester, Leicester, UK
A. C. Lewis
Department of Chemistry, University of York, York, UK
National Centre for Atmospheric Science, University of York, York, UK
P. S. Monks
Department of Chemistry, University of Leicester, Leicester, UK
D. Oram
School of Environmental Sciences, University of East Anglia, Norwich, UK
National Centre for Atmospheric Science, University of East Anglia, Norwich, UK
C. E. Reeves
School of Environmental Sciences, University of East Anglia, Norwich, UK
National Centre for Atmospheric Science, University of East Anglia, Norwich, UK
D. Stewart
School of Environmental Sciences, University of East Anglia, Norwich, UK
now at: Department of Chemistry, University of Reading, Reading, UK
D. E. Heard
School of Chemistry, University of Leeds, Leeds, UK
National Centre for Atmospheric Science, University of Leeds, Leeds, UK
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Cited
58 citations as recorded by crossref.
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- A Lagrangian model of air-mass photochemistry and mixing using a trajectory ensemble: the Cambridge Tropospheric Trajectory model of Chemistry And Transport (CiTTyCAT) version 4.2 T. Pugh et al. 10.5194/gmd-5-193-2012
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- The influence of isoprene peroxy radical isomerization mechanisms on ozone simulation with the presence of NOx H. Zhang & R. Kamens 10.1007/s10874-012-9230-9
- Quantitative study on the interference of OH radicalmeasurement in the air pollution complex X. Ma et al. 10.1360/TB-2022-0581
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- Comparisons of observed and modeled OH and HO<sub>2</sub> concentrations during the ambient measurement period of the HO<sub>x</sub>Comp field campaign Y. Kanaya et al. 10.5194/acp-12-2567-2012
- Direct ecosystem fluxes of volatile organic compounds from oil palms in South-East Asia P. Misztal et al. 10.5194/acp-11-8995-2011
- The MCM v3.3.1 degradation scheme for isoprene M. Jenkin et al. 10.5194/acp-15-11433-2015
- Exploring Oxidation in the Remote Free Troposphere: Insights From Atmospheric Tomography (ATom) W. Brune et al. 10.1029/2019JD031685
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- FORest Canopy Atmosphere Transfer (FORCAsT) 1.0: a 1-D model of biosphere–atmosphere chemical exchange K. Ashworth et al. 10.5194/gmd-8-3765-2015
- OH production from the photolysis of isoprene-derived peroxy radicals: cross-sections, quantum yields and atmospheric implications R. Hansen et al. 10.1039/C6CP06718B
- Formation of carbonyls and hydroperoxyenals (HPALDs) from the OH radical reaction of isoprene for low-NOx conditions: influence of temperature and water vapour content T. Berndt 10.1007/s10874-012-9245-2
- Direct Measurements of Isoprene Autoxidation: Pinpointing Atmospheric Oxidation in Tropical Forests D. J. Medeiros et al. 10.1021/jacsau.1c00525
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- The Framework for 0-D Atmospheric Modeling (F0AM) v3.1 G. Wolfe et al. 10.5194/gmd-9-3309-2016
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- An overview of the potential environmental impacts of large-scale microalgae cultivation P. Usher et al. 10.1080/17597269.2014.913925
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- Quantifying global terrestrial methanol emissions using observations from the TES satellite sensor K. Wells et al. 10.5194/acp-14-2555-2014
- Understanding the impact of recent advances in isoprene photooxidation on simulations of regional air quality Y. Xie et al. 10.5194/acp-13-8439-2013
- OH measurements in the coastal atmosphere of South China: possible missing OH sinks in aged air masses Z. Zou et al. 10.5194/acp-23-7057-2023
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- Radical chemistry at night: comparisons between observed and modelled HO<sub>x</sub>, NO<sub>3</sub> and N<sub>2</sub>O<sub>5</sub> during the RONOCO project D. Stone et al. 10.5194/acp-14-1299-2014
- Seasonal observations of OH and HO<sub>2</sub> in the remote tropical marine boundary layer S. Vaughan et al. 10.5194/acp-12-2149-2012
- Impacts of bromine and iodine chemistry on tropospheric OH and HO<sub>2</sub>: comparing observations with box and global model perspectives D. Stone et al. 10.5194/acp-18-3541-2018
- Transboundary atmospheric pollution in Southeast Asia: current methods, limitations and future developments Q. Chen & D. Taylor 10.1080/10643389.2018.1493337
- Evaluation of OH and HO<sub>2</sub> concentrations and their budgets during photooxidation of 2-methyl-3-butene-2-ol (MBO) in the atmospheric simulation chamber SAPHIR A. Novelli et al. 10.5194/acp-18-11409-2018
- How does tropospheric VOC chemistry affect climate? An investigation of preindustrial control simulations using the Community Earth System Model version 2 N. Stanton & N. Tandon 10.5194/acp-23-9191-2023
- Experimental evidence for efficient hydroxyl radical regeneration in isoprene oxidation H. Fuchs et al. 10.1038/ngeo1964
- iDirac: a field-portable instrument for long-term autonomous measurements of isoprene and selected VOCs C. Bolas et al. 10.5194/amt-13-821-2020
- OH reactivity in a South East Asian tropical rainforest during the Oxidant and Particle Photochemical Processes (OP3) project P. Edwards et al. 10.5194/acp-13-9497-2013
- Multiple Stable Isoprene–Ozone Complexes Reveal Complex Entrance Channel Dynamics in the Isoprene + Ozone Reaction M. Kumar et al. 10.1021/jacs.0c02360
- A new model mechanism for atmospheric oxidation of isoprene: global effects on oxidants, nitrogen oxides, organic products, and secondary organic aerosol K. Bates & D. Jacob 10.5194/acp-19-9613-2019
- A global model study of the impact of land-use change in Borneo on atmospheric composition N. Warwick et al. 10.5194/acp-13-9183-2013
- Key chemical NO<sub>x</sub> sink uncertainties and how they influence top-down emissions of nitrogen oxides T. Stavrakou et al. 10.5194/acp-13-9057-2013
- Photolysis, OH reactivity and ozone reactivity of a proxy for isoprene-derived hydroperoxyenals (HPALDs) G. Wolfe et al. 10.1039/c2cp40388a
- Rotamers of Isoprene: Infrared Spectroscopy in Helium Droplets and Ab Initio Thermochemistry P. Franke & G. Douberly 10.1021/acs.jpca.7b10260
- Influence of isoprene chemical mechanism on modelled changes in tropospheric ozone due to climate and land use over the 21st century O. Squire et al. 10.5194/acp-15-5123-2015
- The impact of anthropogenic emissions on atmospheric sulfate production pathways, oxidants, and ice core Δ<sup>17</sup>O(SO<sub>4</sub><sup>2–</sup>) E. Sofen et al. 10.5194/acp-11-3565-2011
57 citations as recorded by crossref.
- Chemistry‐turbulence interactions and mesoscale variability influence the cleansing efficiency of the atmosphere L. Kaser et al. 10.1002/2015GL066641
- Environmental Implications of Hydroxyl Radicals (•OH) S. Gligorovski et al. 10.1021/cr500310b
- Temperature-dependent rate coefficients for the reactions of the hydroxyl radical with the atmospheric biogenics isoprene, alpha-pinene and delta-3-carene T. Dillon et al. 10.5194/acp-17-15137-2017
- Observation and modelling of HO<sub>x</sub> radicals in a boreal forest K. Hens et al. 10.5194/acp-14-8723-2014
- Nucleation and growth of sulfate aerosol in coal-fired power plant plumes: sensitivity to background aerosol and meteorology R. Stevens et al. 10.5194/acp-12-189-2012
- Aircraft observations of the lower troposphere above a megacity: Alkyl nitrate and ozone chemistry E. Aruffo et al. 10.1016/j.atmosenv.2014.05.040
- Production of methyl vinyl ketone and methacrolein via the hydroperoxyl pathway of isoprene oxidation Y. Liu et al. 10.5194/acp-13-5715-2013
- The Atmospheric Chemistry and Canopy Exchange Simulation System (ACCESS): model description and application to a temperate deciduous forest canopy R. Saylor 10.5194/acp-13-693-2013
- Implementation of a chemical background method for atmospheric OH measurements by laser-induced fluorescence: characterisation and observations from the UK and China R. Woodward-Massey et al. 10.5194/amt-13-3119-2020
- Characterization of a chemical modulation reactor (CMR) for the measurement of atmospheric concentrations of hydroxyl radicals with a laser-induced fluorescence instrument C. Cho et al. 10.5194/amt-14-1851-2021
- Effects of biogenic nitrate chemistry on the NO<sub>x</sub> lifetime in remote continental regions E. Browne & R. Cohen 10.5194/acp-12-11917-2012
- OH and HO<sub>2</sub> radical chemistry at a suburban site during the EXPLORE-YRD campaign in 2018 X. Ma et al. 10.5194/acp-22-7005-2022
- A Lagrangian model of air-mass photochemistry and mixing using a trajectory ensemble: the Cambridge Tropospheric Trajectory model of Chemistry And Transport (CiTTyCAT) version 4.2 T. Pugh et al. 10.5194/gmd-5-193-2012
- Can we explain the observed methane variability after the Mount Pinatubo eruption? N. Bândă et al. 10.5194/acp-16-195-2016
- Insights into hydroxyl measurements and atmospheric oxidation in a California forest J. Mao et al. 10.5194/acp-12-8009-2012
- Testing Atmospheric Oxidation in an Alabama Forest P. Feiner et al. 10.1175/JAS-D-16-0044.1
- Theoretical studies of atmospheric reaction mechanisms in the troposphere L. Vereecken & J. Francisco 10.1039/c2cs35070j
- Update on Amazonian atmosphere M. Pilling 10.1038/ngeo1412
- The influence of isoprene peroxy radical isomerization mechanisms on ozone simulation with the presence of NOx H. Zhang & R. Kamens 10.1007/s10874-012-9230-9
- Quantitative study on the interference of OH radicalmeasurement in the air pollution complex X. Ma et al. 10.1360/TB-2022-0581
- Hydroxyl Radical Recycling in Isoprene Oxidation Driven by Hydrogen Bonding and Hydrogen Tunneling: The Upgraded LIM1 Mechanism J. Peeters et al. 10.1021/jp5033146
- Comparisons of observed and modeled OH and HO<sub>2</sub> concentrations during the ambient measurement period of the HO<sub>x</sub>Comp field campaign Y. Kanaya et al. 10.5194/acp-12-2567-2012
- Direct ecosystem fluxes of volatile organic compounds from oil palms in South-East Asia P. Misztal et al. 10.5194/acp-11-8995-2011
- The MCM v3.3.1 degradation scheme for isoprene M. Jenkin et al. 10.5194/acp-15-11433-2015
- Exploring Oxidation in the Remote Free Troposphere: Insights From Atmospheric Tomography (ATom) W. Brune et al. 10.1029/2019JD031685
- Global climate forcing driven by altered BVOC fluxes from 1990 to 2010 land cover change in maritime Southeast Asia K. Harper & N. Unger 10.5194/acp-18-16931-2018
- LES study of the impact of moist thermals on the oxidative capacity of the atmosphere in southern West Africa F. Brosse et al. 10.5194/acp-18-6601-2018
- FORest Canopy Atmosphere Transfer (FORCAsT) 1.0: a 1-D model of biosphere–atmosphere chemical exchange K. Ashworth et al. 10.5194/gmd-8-3765-2015
- OH production from the photolysis of isoprene-derived peroxy radicals: cross-sections, quantum yields and atmospheric implications R. Hansen et al. 10.1039/C6CP06718B
- Formation of carbonyls and hydroperoxyenals (HPALDs) from the OH radical reaction of isoprene for low-NOx conditions: influence of temperature and water vapour content T. Berndt 10.1007/s10874-012-9245-2
- Direct Measurements of Isoprene Autoxidation: Pinpointing Atmospheric Oxidation in Tropical Forests D. J. Medeiros et al. 10.1021/jacsau.1c00525
- Detailed comparisons of airborne formaldehyde measurements with box models during the 2006 INTEX-B and MILAGRO campaigns: potential evidence for significant impacts of unmeasured and multi-generation volatile organic carbon compounds A. Fried et al. 10.5194/acp-11-11867-2011
- The Framework for 0-D Atmospheric Modeling (F0AM) v3.1 G. Wolfe et al. 10.5194/gmd-9-3309-2016
- Comparison of Isoprene Chemical Mechanisms with Chamber and Field Observations W. Brune et al. 10.1021/acsearthspacechem.4c00196
- An overview of the potential environmental impacts of large-scale microalgae cultivation P. Usher et al. 10.1080/17597269.2014.913925
- Tropospheric OH and HO2 radicals: field measurements and model comparisons D. Stone et al. 10.1039/c2cs35140d
- Quantifying global terrestrial methanol emissions using observations from the TES satellite sensor K. Wells et al. 10.5194/acp-14-2555-2014
- Understanding the impact of recent advances in isoprene photooxidation on simulations of regional air quality Y. Xie et al. 10.5194/acp-13-8439-2013
- OH measurements in the coastal atmosphere of South China: possible missing OH sinks in aged air masses Z. Zou et al. 10.5194/acp-23-7057-2023
- Unclassical Radical Generation Mechanisms in the Troposphere: A Review X. Yang et al. 10.1021/acs.est.4c00742
- Observations of total RONO<sub>2</sub> over the boreal forest: NO<sub>x</sub> sinks and HNO<sub>3</sub> sources E. Browne et al. 10.5194/acp-13-4543-2013
- Radical chemistry at night: comparisons between observed and modelled HO<sub>x</sub>, NO<sub>3</sub> and N<sub>2</sub>O<sub>5</sub> during the RONOCO project D. Stone et al. 10.5194/acp-14-1299-2014
- Seasonal observations of OH and HO<sub>2</sub> in the remote tropical marine boundary layer S. Vaughan et al. 10.5194/acp-12-2149-2012
- Impacts of bromine and iodine chemistry on tropospheric OH and HO<sub>2</sub>: comparing observations with box and global model perspectives D. Stone et al. 10.5194/acp-18-3541-2018
- Transboundary atmospheric pollution in Southeast Asia: current methods, limitations and future developments Q. Chen & D. Taylor 10.1080/10643389.2018.1493337
- Evaluation of OH and HO<sub>2</sub> concentrations and their budgets during photooxidation of 2-methyl-3-butene-2-ol (MBO) in the atmospheric simulation chamber SAPHIR A. Novelli et al. 10.5194/acp-18-11409-2018
- How does tropospheric VOC chemistry affect climate? An investigation of preindustrial control simulations using the Community Earth System Model version 2 N. Stanton & N. Tandon 10.5194/acp-23-9191-2023
- Experimental evidence for efficient hydroxyl radical regeneration in isoprene oxidation H. Fuchs et al. 10.1038/ngeo1964
- iDirac: a field-portable instrument for long-term autonomous measurements of isoprene and selected VOCs C. Bolas et al. 10.5194/amt-13-821-2020
- OH reactivity in a South East Asian tropical rainforest during the Oxidant and Particle Photochemical Processes (OP3) project P. Edwards et al. 10.5194/acp-13-9497-2013
- Multiple Stable Isoprene–Ozone Complexes Reveal Complex Entrance Channel Dynamics in the Isoprene + Ozone Reaction M. Kumar et al. 10.1021/jacs.0c02360
- A new model mechanism for atmospheric oxidation of isoprene: global effects on oxidants, nitrogen oxides, organic products, and secondary organic aerosol K. Bates & D. Jacob 10.5194/acp-19-9613-2019
- A global model study of the impact of land-use change in Borneo on atmospheric composition N. Warwick et al. 10.5194/acp-13-9183-2013
- Key chemical NO<sub>x</sub> sink uncertainties and how they influence top-down emissions of nitrogen oxides T. Stavrakou et al. 10.5194/acp-13-9057-2013
- Photolysis, OH reactivity and ozone reactivity of a proxy for isoprene-derived hydroperoxyenals (HPALDs) G. Wolfe et al. 10.1039/c2cp40388a
- Rotamers of Isoprene: Infrared Spectroscopy in Helium Droplets and Ab Initio Thermochemistry P. Franke & G. Douberly 10.1021/acs.jpca.7b10260
- Influence of isoprene chemical mechanism on modelled changes in tropospheric ozone due to climate and land use over the 21st century O. Squire et al. 10.5194/acp-15-5123-2015
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