Articles | Volume 11, issue 19
https://doi.org/10.5194/acp-11-10293-2011
© Author(s) 2011. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-11-10293-2011
© Author(s) 2011. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Research article
| 
14 Oct 2011
Research article |
| 14 Oct 2011
Ultraviolet absorption cross sections of carbonyl sulfide isotopologues OC32S, OC33S, OC34S and O13CS: isotopic fractionation in photolysis and atmospheric implications
S. Hattori
Department of Environmental Science and Technology, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, Yokohama, 226-8502, Japan
S. O. Danielache
Department of Environmental Science and Technology, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, Yokohama, 226-8502, Japan
M. S. Johnson
Copenhagen Center for Atmospheric Research, Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen, Denmark
J. A. Schmidt
Copenhagen Center for Atmospheric Research, Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen, Denmark
H. G. Kjaergaard
Copenhagen Center for Atmospheric Research, Department of Chemistry, University of Copenhagen, Universitetsparken 5, 2100 Copenhagen, Denmark
S. Toyoda
Department of Environmental Chemistry and Engineering, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, Yokohama, 226-8502, Japan
Y. Ueno
Department of Earth and Planetary Science, Tokyo Institute of Technology, Meguro-ku, Tokyo, 152-8551, Japan
N. Yoshida
Department of Environmental Science and Technology, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, Yokohama, 226-8502, Japan
Department of Environmental Chemistry and Engineering, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology, Yokohama, 226-8502, Japan
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Cited
46 citations as recorded by crossref.
- Photodissociation of OCS: Deviations between theory and experiment, and the importance of higher order correlation effects J. Schmidt & J. Olsen 10.1063/1.4901426
- Sulfur isotope fractionation during oxidation of sulfur dioxide: gas-phase oxidation by OH radicals and aqueous oxidation by H<sub>2</sub>O<sub>2</sub>, O<sub>3</sub> and iron catalysis E. Harris et al. 10.5194/acp-12-407-2012
- Combinatorial effects on clumped isotopes and their significance in biogeochemistry L. Yeung 10.1016/j.gca.2015.09.020
- Theoretical study of electronic properties and isotope effects in the UV absorption spectrum of disulfur K. Sarka et al. 10.1016/j.chemphys.2018.08.045
- Sulfur isotope fractionation by broadband UV radiation to optically thin SO 2 under reducing atmosphere Y. Endo et al. 10.1016/j.epsl.2016.07.057
- On adduct formation and reactivity in the OCS + OH reaction: A combined theoretical and experimental study J. Schmidt et al. 10.1016/j.cplett.2017.03.005
- Photochemistry of Sulfur Dioxide and the Origin of Mass-Independent Isotope Fractionation in Earth's Atmosphere S. Ono 10.1146/annurev-earth-060115-012324
- Use of Isotope Effects To Understand the Present and Past of the Atmosphere and Climate and Track the Origin of Life M. Thiemens & M. Lin 10.1002/ange.201812322
- Photo-oxidation pathway as a potential CS<sub>2</sub> sink in the atmosphere Y. Li et al. 10.2343/geochemj.GJ24014
- Global measurements of atmospheric carbonyl sulfide (OCS), OC34S and O13CS M. Yousefi et al. 10.1016/j.jqsrt.2019.06.033
- OCS photolytic isotope effects from first principles: sulfur and carbon isotopes, temperature dependence and implications for the stratosphere J. Schmidt et al. 10.5194/acp-13-1511-2013
- SO2photoexcitation mechanism links mass-independent sulfur isotopic fractionation in cryospheric sulfate to climate impacting volcanism S. Hattori et al. 10.1073/pnas.1213153110
- Modeling the signature of sulfur mass-independent fractionation produced in the Archean atmosphere M. Claire et al. 10.1016/j.gca.2014.06.032
- Optimized approach to retrieve information on atmospheric carbonyl sulfide (OCS) above the Jungfraujoch station and change in its abundance since 1995 B. Lejeune et al. 10.1016/j.jqsrt.2016.06.001
- Multiple-sulfur isotope effects during photolysis of carbonyl sulfide Y. Lin et al. 10.5194/acp-11-10283-2011
- Communication: Multi-state analysis of the OCS ultraviolet absorption including vibrational structure J. Schmidt et al. 10.1063/1.3701699
- Photoabsorption cross‐section measurements of 32S, 33S, 34S, and 36S sulfur dioxide from 190 to 220 nm Y. Endo et al. 10.1002/2014JD021671
- Resonance-state selective photodissociation dynamics of OCS + hv → CS(X1Σ+) + O(3Pj=2,1,0) via the 21Σ+ state Q. Liu et al. 10.1063/5.0150850
- Photodissociation dynamics of OCS near 214 nm using ion imaging W. Wei et al. 10.1063/1.4955189
- A GC-IRMS method for measuring sulfur isotope ratios of carbonyl sulfide from small air samples S. Baartman et al. 10.12688/openreseurope.13875.1
- Atmospheric sulfur cycle elucidated by isotopologue measurements S. HATTORI et al. 10.3724/j.issn.1007-2802.20240068
- Radiative forcings for 28 potential Archean greenhouse gases B. Byrne & C. Goldblatt 10.5194/cp-10-1779-2014
- Nuclear Ensemble Approach with Importance Sampling F. Kossoski & M. Barbatti 10.1021/acs.jctc.8b00059
- Exit-channel recoil resonances by imaging the photodissociation of single quantum-state-selected OCS molecules D. Sofikitis et al. 10.1103/PhysRevA.98.033417
- Predictions of the sulfur and carbon kinetic isotope effects in the OH + OCS reaction J. Schmidt et al. 10.1016/j.cplett.2012.02.049
- Sulfur assimilation using gaseous carbonyl sulfide by the soil fungus Trichoderma harzianum R. Iizuka et al. 10.1128/aem.02015-23
- Isotope Effect in the Carbonyl Sulfide Reaction with O(3P) S. Hattori et al. 10.1021/jp2120884
- Recoil Inversion in the Photodissociation of Carbonyl Sulfide near 234 nm D. Sofikitis et al. 10.1103/PhysRevLett.118.253001
- Vacuum ultraviolet photodissociation of OCS via the 21Σ+ state: the S(1D2) elimination channel Z. Li et al. 10.1039/D2CP02044K
- Sulfur Isotopic Fractionation of Carbonyl Sulfide during Degradation by Soil Bacteria K. Kamezaki et al. 10.1021/acs.est.5b05325
- Large-volume air sample system for measuring <sup>34</sup>S∕<sup>32</sup>S isotope ratio of carbonyl sulfide K. Kamezaki et al. 10.5194/amt-12-1141-2019
- Photodissociation dynamics of OCS at ∼210 nm: The role of c(23A″) state X. Bai et al. 10.1063/1.4982684
- High-Resolution UV Absorption Cross-Section Measurements of 32S, 33S, 34S, and 36S Sulfur Dioxide for the B~1B1−X~1A1 Absorption Band Y. Li et al. 10.1021/acsearthspacechem.4c00147
- The ultraviolet spectrum of OCS from first principles: Electronic transitions, vibrational structure and temperature dependence J. Schmidt et al. 10.1063/1.4739756
- Sensitive Detection of OCS Using Thermal Conversion Combined with Spectral Reconstruction Filtering Differential Optical Absorption Spectroscopy Y. Wu et al. 10.1021/acs.analchem.4c00943
- Ultraviolet photodissociation of OCS: Product energy and angular distributions G. McBane et al. 10.1063/1.4793275
- Determination of the Sulfur Isotope Ratio in Carbonyl Sulfide Using Gas Chromatography/Isotope Ratio Mass Spectrometry on Fragment Ions 32S+, 33S+, and 34S+ S. Hattori et al. 10.1021/ac502704d
- Use of Isotope Effects To Understand the Present and Past of the Atmosphere and Climate and Track the Origin of Life M. Thiemens & M. Lin 10.1002/anie.201812322
- Excitation band dependence of sulfur isotope mass-independent fractionation during photochemistry of sulfur dioxide using broadband light sources A. Whitehill & S. Ono 10.1016/j.gca.2012.06.014
- UV absorption cross-sections of selected sulfur-containing compounds at temperatures up to 500°C H. Grosch et al. 10.1016/j.jqsrt.2014.11.020
- A study of the valence shell absolute photoabsorption, photoionisation and photodissociation cross sections and the photoionisation quantum efficiency of carbonyl sulphide D. Holland & D. Shaw 10.1016/j.chemphys.2016.10.002
- A GC-IRMS method for measuring sulfur isotope ratios of carbonyl sulfide from small air samples S. Baartman et al. 10.12688/openreseurope.13875.2
- Decomposing the First Absorption Band of OCS Using Photofragment Excitation Spectroscopy B. Toulson & C. Murray 10.1021/acs.jpca.6b06060
- Chain formation as a mechanism for mass-independent fractionation of sulfur isotopes in the Archean atmosphere C. Harman et al. 10.1016/j.epsl.2018.05.041
- Carbon dioxide photolysis from 150 to 210 nm: Singlet and triplet channel dynamics, UV-spectrum, and isotope effects J. Schmidt et al. 10.1073/pnas.1213083110
- The Effects of Virtual Reality (VR) Treatment on Prefrontal Cortex Activity in Patients with Social Anxiety Disorder: fNIRS measurement for VR-derived video exposure (Preprint) H. Lee et al. 10.2196/31844
45 citations as recorded by crossref.
- Photodissociation of OCS: Deviations between theory and experiment, and the importance of higher order correlation effects J. Schmidt & J. Olsen 10.1063/1.4901426
- Sulfur isotope fractionation during oxidation of sulfur dioxide: gas-phase oxidation by OH radicals and aqueous oxidation by H<sub>2</sub>O<sub>2</sub>, O<sub>3</sub> and iron catalysis E. Harris et al. 10.5194/acp-12-407-2012
- Combinatorial effects on clumped isotopes and their significance in biogeochemistry L. Yeung 10.1016/j.gca.2015.09.020
- Theoretical study of electronic properties and isotope effects in the UV absorption spectrum of disulfur K. Sarka et al. 10.1016/j.chemphys.2018.08.045
- Sulfur isotope fractionation by broadband UV radiation to optically thin SO 2 under reducing atmosphere Y. Endo et al. 10.1016/j.epsl.2016.07.057
- On adduct formation and reactivity in the OCS + OH reaction: A combined theoretical and experimental study J. Schmidt et al. 10.1016/j.cplett.2017.03.005
- Photochemistry of Sulfur Dioxide and the Origin of Mass-Independent Isotope Fractionation in Earth's Atmosphere S. Ono 10.1146/annurev-earth-060115-012324
- Use of Isotope Effects To Understand the Present and Past of the Atmosphere and Climate and Track the Origin of Life M. Thiemens & M. Lin 10.1002/ange.201812322
- Photo-oxidation pathway as a potential CS<sub>2</sub> sink in the atmosphere Y. Li et al. 10.2343/geochemj.GJ24014
- Global measurements of atmospheric carbonyl sulfide (OCS), OC34S and O13CS M. Yousefi et al. 10.1016/j.jqsrt.2019.06.033
- OCS photolytic isotope effects from first principles: sulfur and carbon isotopes, temperature dependence and implications for the stratosphere J. Schmidt et al. 10.5194/acp-13-1511-2013
- SO2photoexcitation mechanism links mass-independent sulfur isotopic fractionation in cryospheric sulfate to climate impacting volcanism S. Hattori et al. 10.1073/pnas.1213153110
- Modeling the signature of sulfur mass-independent fractionation produced in the Archean atmosphere M. Claire et al. 10.1016/j.gca.2014.06.032
- Optimized approach to retrieve information on atmospheric carbonyl sulfide (OCS) above the Jungfraujoch station and change in its abundance since 1995 B. Lejeune et al. 10.1016/j.jqsrt.2016.06.001
- Multiple-sulfur isotope effects during photolysis of carbonyl sulfide Y. Lin et al. 10.5194/acp-11-10283-2011
- Communication: Multi-state analysis of the OCS ultraviolet absorption including vibrational structure J. Schmidt et al. 10.1063/1.3701699
- Photoabsorption cross‐section measurements of 32S, 33S, 34S, and 36S sulfur dioxide from 190 to 220 nm Y. Endo et al. 10.1002/2014JD021671
- Resonance-state selective photodissociation dynamics of OCS + hv → CS(X1Σ+) + O(3Pj=2,1,0) via the 21Σ+ state Q. Liu et al. 10.1063/5.0150850
- Photodissociation dynamics of OCS near 214 nm using ion imaging W. Wei et al. 10.1063/1.4955189
- A GC-IRMS method for measuring sulfur isotope ratios of carbonyl sulfide from small air samples S. Baartman et al. 10.12688/openreseurope.13875.1
- Atmospheric sulfur cycle elucidated by isotopologue measurements S. HATTORI et al. 10.3724/j.issn.1007-2802.20240068
- Radiative forcings for 28 potential Archean greenhouse gases B. Byrne & C. Goldblatt 10.5194/cp-10-1779-2014
- Nuclear Ensemble Approach with Importance Sampling F. Kossoski & M. Barbatti 10.1021/acs.jctc.8b00059
- Exit-channel recoil resonances by imaging the photodissociation of single quantum-state-selected OCS molecules D. Sofikitis et al. 10.1103/PhysRevA.98.033417
- Predictions of the sulfur and carbon kinetic isotope effects in the OH + OCS reaction J. Schmidt et al. 10.1016/j.cplett.2012.02.049
- Sulfur assimilation using gaseous carbonyl sulfide by the soil fungus Trichoderma harzianum R. Iizuka et al. 10.1128/aem.02015-23
- Isotope Effect in the Carbonyl Sulfide Reaction with O(3P) S. Hattori et al. 10.1021/jp2120884
- Recoil Inversion in the Photodissociation of Carbonyl Sulfide near 234 nm D. Sofikitis et al. 10.1103/PhysRevLett.118.253001
- Vacuum ultraviolet photodissociation of OCS via the 21Σ+ state: the S(1D2) elimination channel Z. Li et al. 10.1039/D2CP02044K
- Sulfur Isotopic Fractionation of Carbonyl Sulfide during Degradation by Soil Bacteria K. Kamezaki et al. 10.1021/acs.est.5b05325
- Large-volume air sample system for measuring <sup>34</sup>S∕<sup>32</sup>S isotope ratio of carbonyl sulfide K. Kamezaki et al. 10.5194/amt-12-1141-2019
- Photodissociation dynamics of OCS at ∼210 nm: The role of c(23A″) state X. Bai et al. 10.1063/1.4982684
- High-Resolution UV Absorption Cross-Section Measurements of 32S, 33S, 34S, and 36S Sulfur Dioxide for the B~1B1−X~1A1 Absorption Band Y. Li et al. 10.1021/acsearthspacechem.4c00147
- The ultraviolet spectrum of OCS from first principles: Electronic transitions, vibrational structure and temperature dependence J. Schmidt et al. 10.1063/1.4739756
- Sensitive Detection of OCS Using Thermal Conversion Combined with Spectral Reconstruction Filtering Differential Optical Absorption Spectroscopy Y. Wu et al. 10.1021/acs.analchem.4c00943
- Ultraviolet photodissociation of OCS: Product energy and angular distributions G. McBane et al. 10.1063/1.4793275
- Determination of the Sulfur Isotope Ratio in Carbonyl Sulfide Using Gas Chromatography/Isotope Ratio Mass Spectrometry on Fragment Ions 32S+, 33S+, and 34S+ S. Hattori et al. 10.1021/ac502704d
- Use of Isotope Effects To Understand the Present and Past of the Atmosphere and Climate and Track the Origin of Life M. Thiemens & M. Lin 10.1002/anie.201812322
- Excitation band dependence of sulfur isotope mass-independent fractionation during photochemistry of sulfur dioxide using broadband light sources A. Whitehill & S. Ono 10.1016/j.gca.2012.06.014
- UV absorption cross-sections of selected sulfur-containing compounds at temperatures up to 500°C H. Grosch et al. 10.1016/j.jqsrt.2014.11.020
- A study of the valence shell absolute photoabsorption, photoionisation and photodissociation cross sections and the photoionisation quantum efficiency of carbonyl sulphide D. Holland & D. Shaw 10.1016/j.chemphys.2016.10.002
- A GC-IRMS method for measuring sulfur isotope ratios of carbonyl sulfide from small air samples S. Baartman et al. 10.12688/openreseurope.13875.2
- Decomposing the First Absorption Band of OCS Using Photofragment Excitation Spectroscopy B. Toulson & C. Murray 10.1021/acs.jpca.6b06060
- Chain formation as a mechanism for mass-independent fractionation of sulfur isotopes in the Archean atmosphere C. Harman et al. 10.1016/j.epsl.2018.05.041
- Carbon dioxide photolysis from 150 to 210 nm: Singlet and triplet channel dynamics, UV-spectrum, and isotope effects J. Schmidt et al. 10.1073/pnas.1213083110
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