Articles | Volume 10, issue 20
https://doi.org/10.5194/acp-10-9863-2010
© Author(s) 2010. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
https://doi.org/10.5194/acp-10-9863-2010
© Author(s) 2010. This work is distributed under
the Creative Commons Attribution 3.0 License.
the Creative Commons Attribution 3.0 License.
Improved global modelling of HOx recycling in isoprene oxidation: evaluation against the GABRIEL and INTEX-A aircraft campaign measurements
T. Stavrakou
Belgian Institute for Space Aeronomy, Avenue Circulaire 3, 1180, Brussels, Belgium
J. Peeters
Katholieke Universiteit Leuven, Celestijnenlaan 200F, 3001, Leuven, Belgium
J.-F. Müller
Belgian Institute for Space Aeronomy, Avenue Circulaire 3, 1180, Brussels, Belgium
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Cited
74 citations as recorded by crossref.
- Satellite isoprene retrievals constrain emissions and atmospheric oxidation K. Wells et al.
- Global terrestrial isoprene emission models: sensitivity to variability in climate and vegetation A. Arneth et al.
- Chemistry and deposition in the Model of Atmospheric composition at Global and Regional scales using Inversion Techniques for Trace gas Emissions (MAGRITTE v1.1) – Part 1: Chemical mechanism J. Müller et al.
- OH and HO2 radical chemistry during PROPHET 2008 and CABINEX 2009 – Part 1: Measurements and model comparison S. Griffith et al.
- Direct retrieval of isoprene from satellite-based infrared measurements D. Fu et al.
- Hydroxyl radicals in the tropical troposphere over the Suriname rainforest: comparison of measurements with the box model MECCA D. Kubistin et al.
- A comprehensive organic nitrate chemistry: insights into the lifetime of atmospheric organic nitrates A. Zare et al.
- Missing peroxy radical sources within a summertime ponderosa pine forest G. Wolfe et al.
- Intercomparison of OH and OH reactivity measurements in a high isoprene and low NO environment during the Southern Oxidant and Aerosol Study (SOAS) D. Sanchez et al.
- The influence of isoprene peroxy radical isomerization mechanisms on ozone simulation with the presence of NOx H. Zhang & R. Kamens
- In-canopy gas-phase chemistry during CABINEX 2009: sensitivity of a 1-D canopy model to vertical mixing and isoprene chemistry A. Bryan et al.
- Why do models overestimate surface ozone in the Southeast United States? K. Travis et al.
- A new gas-phase condensed mechanism of isoprene-NOx photooxidation H. Zhang et al.
- Nine years of global hydrocarbon emissions based on source inversion of OMI formaldehyde observations M. Bauwens et al.
- Technical note: Evaluation of the Copernicus Atmosphere Monitoring Service Cy48R1 upgrade of June 2023 H. Eskes et al.
- The Chemistry of Atmosphere-Forest Exchange (CAFE) Model – Part 2: Application to BEARPEX-2007 observations G. Wolfe et al.
- Improved retrieval of global tropospheric formaldehyde columns from GOME-2/MetOp-A addressing noise reduction and instrumental degradation issues I. De Smedt et al.
- Temperature dependence of the yields of methacrolein and methyl vinyl ketone from the OH-initiated oxidation of isoprene under NOx-free conditions M. Navarro et al.
- Impacts of HOxregeneration and recycling in the oxidation of isoprene: Consequences for the composition of past, present and future atmospheres A. Archibald et al.
- Isoprene Emissions, Oxidation Chemistry and Environmental Impacts M. Khan et al.
- Improved MEGAN predictions of biogenic isoprene in the contiguous United States P. Wang et al.
- Recent advances in understanding secondary organic aerosol: Implications for global climate forcing M. Shrivastava et al.
- Assessment of dicarbonyl contributions to secondary organic aerosols over China using RAMS-CMAQ J. Li et al.
- The atmospheric chemistry box model CAABA/MECCA-3.0 R. Sander et al.
- Observations of total RONO2 over the boreal forest: NOx sinks and HNO3 sources E. Browne et al.
- Ozone and organic nitrates over the eastern United States: Sensitivity to isoprene chemistry J. Mao et al.
- Quantifying the magnitude of a missing hydroxyl radical source in a tropical rainforest L. Whalley et al.
- Reconciling the changes in atmospheric methane sources and sinks between the Last Glacial Maximum and the pre-industrial era J. Levine et al.
- How consistent are top-down hydrocarbon emissions based on formaldehyde observations from GOME-2 and OMI? T. Stavrakou et al.
- Regional sources of atmospheric formaldehyde and acetaldehyde, and implications for atmospheric modeling D. Luecken et al.
- Can a “state of the art” chemistry transport model simulate Amazonian tropospheric chemistry? M. Barkley et al.
- Observations and modeling of formaldehyde at the PROPHET mixed hardwood forest site in 2008 M. Galloway et al.
- Unusually Fast 1,6-H Shifts of Enolic Hydrogens in Peroxy Radicals: Formation of the First-Generation C2 and C3 Carbonyls in the Oxidation of Isoprene J. Peeters & T. Nguyen
- Unclassical Radical Generation Mechanisms in the Troposphere: A Review X. Yang et al.
- Aqueous-phase mechanism for secondary organic aerosol formation from isoprene: application to the southeast United States and co-benefit of SO2 emission controls E. Marais et al.
- Understanding the impact of recent advances in isoprene photooxidation on simulations of regional air quality Y. Xie et al.
- Photochemical modeling of glyoxal at a rural site: observations and analysis from BEARPEX 2007 A. Huisman et al.
- Case study of the diurnal variability of chemically active species with respect to boundary layer dynamics during DOMINO B. van Stratum et al.
- The MCM v3.3.1 degradation scheme for isoprene M. Jenkin et al.
- Differences in BVOC oxidation and SOA formation above and below the forest canopy B. Schulze et al.
- Formation of carbonyls and hydroperoxyenals (HPALDs) from the OH radical reaction of isoprene for low-NOx conditions: influence of temperature and water vapour content T. Berndt
- Tropospheric OH and HO2 radicals: field measurements and model comparisons D. Stone et al.
- Key chemical NOx sink uncertainties and how they influence top-down emissions of nitrogen oxides T. Stavrakou et al.
- Regional evaluation of the performance of the global CAMS chemical modeling system over the United States (IFS cycle 47r1) J. Williams et al.
- Hydroxyl Radical Recycling in Isoprene Oxidation Driven by Hydrogen Bonding and Hydrogen Tunneling: The Upgraded LIM1 Mechanism J. Peeters et al.
- Quantifying the uncertainty in simulating global tropospheric composition due to the variability in global emission estimates of Biogenic Volatile Organic Compounds J. Williams et al.
- Consecutive Chemical Activation Steps in the OH‐Initiated Atmospheric Degradation of Isoprene: An Analysis with Coupled Master Equations M. Pfeifle & M. Olzmann
- Evaluation of MEGAN predicted biogenic isoprene emissions at urban locations in Southeast Texas S. Kota et al.
- Observational constraints on glyoxal production from isoprene oxidation and its contribution to organic aerosol over the Southeast United States J. Li et al.
- Photolysis, OH reactivity and ozone reactivity of a proxy for isoprene-derived hydroperoxyenals (HPALDs) G. Wolfe et al.
- Observations of the temperature dependent response of ozone to NOx reductions in the Sacramento, CA urban plume B. LaFranchi et al.
- Evaluation of HOx sources and cycling using measurement-constrained model calculations in a 2-methyl-3-butene-2-ol (MBO) and monoterpene (MT) dominated ecosystem S. Kim et al.
- Comparisons of observed and modeled OH and HO2concentrations during the ambient measurement period of the HOxComp field campaign Y. Kanaya et al.
- Optimization of a gas chromatographic unit for measuring biogenic volatile organic compounds in ambient air K. Mermet et al.
- Observation and modelling of OH and HO2 concentrations in the Pearl River Delta 2006: a missing OH source in a VOC rich atmosphere K. Lu et al.
- Impact of the isoprene photochemical cascade on tropical ozone F. Paulot et al.
- Peroxy radical isomerization in the oxidation of isoprene J. Crounse et al.
- Impacts of mechanistic changes on HOx formation and recycling in the oxidation of isoprene A. Archibald et al.
- Investigating missing sources of glyoxal over China using a regional air quality model (RAMS-CMAQ) J. Li et al.
- Contributions of primary and secondary biogenic VOC tototal OH reactivity during the CABINEX (Community Atmosphere-Biosphere INteractions Experiments)-09 field campaign S. Kim et al.
- An Observational Perspective on the Atmospheric Impacts of Alkyl and Multifunctional Nitrates on Ozone and Secondary Organic Aerosol A. Perring et al.
- First space-based derivation of the global atmospheric methanol emission fluxes T. Stavrakou et al.
- Preindustrial to present-day changes in tropospheric hydroxyl radical and methane lifetime from the Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP) V. Naik et al.
- Theoretical studies of atmospheric reaction mechanisms in the troposphere L. Vereecken & J. Francisco
- On Rates and Mechanisms of OH and O3 Reactions with Isoprene-Derived Hydroxy Nitrates L. Lee et al.
- Glyoxal yield from isoprene oxidation and relation to formaldehyde: chemical mechanism, constraints from SENEX aircraft observations, and interpretation of OMI satellite data C. Chan Miller et al.
- Development of an extended chemical mechanism for global–through–urban applications P. Karamchandani et al.
- Within‐plant isoprene oxidation confirmed by direct emissions of oxidation products methyl vinyl ketone and methacrolein K. Jardine et al.
- Global modeling of SOA formation from dicarbonyls, epoxides, organic nitrates and peroxides G. Lin et al.
- Isoprene oxidation mechanisms: measurements and modelling of OH and HO2 over a South-East Asian tropical rainforest during the OP3 field campaign D. Stone et al.
- Impacts of changes in land use and land cover on atmospheric chemistry and air quality over the 21st century S. Wu et al.
- Measurements of the Kinetics of the Reaction of OH Radicals with 3‐Methylfuran at Low Pressure J. Liljegren & P. Stevens
- Experimental evidence for efficient hydroxyl radical regeneration in isoprene oxidation H. Fuchs et al.
- Effects of biogenic nitrate chemistry on the NOx lifetime in remote continental regions E. Browne & R. Cohen
74 citations as recorded by crossref.
- Satellite isoprene retrievals constrain emissions and atmospheric oxidation K. Wells et al.
- Global terrestrial isoprene emission models: sensitivity to variability in climate and vegetation A. Arneth et al.
- Chemistry and deposition in the Model of Atmospheric composition at Global and Regional scales using Inversion Techniques for Trace gas Emissions (MAGRITTE v1.1) – Part 1: Chemical mechanism J. Müller et al.
- OH and HO2 radical chemistry during PROPHET 2008 and CABINEX 2009 – Part 1: Measurements and model comparison S. Griffith et al.
- Direct retrieval of isoprene from satellite-based infrared measurements D. Fu et al.
- Hydroxyl radicals in the tropical troposphere over the Suriname rainforest: comparison of measurements with the box model MECCA D. Kubistin et al.
- A comprehensive organic nitrate chemistry: insights into the lifetime of atmospheric organic nitrates A. Zare et al.
- Missing peroxy radical sources within a summertime ponderosa pine forest G. Wolfe et al.
- Intercomparison of OH and OH reactivity measurements in a high isoprene and low NO environment during the Southern Oxidant and Aerosol Study (SOAS) D. Sanchez et al.
- The influence of isoprene peroxy radical isomerization mechanisms on ozone simulation with the presence of NOx H. Zhang & R. Kamens
- In-canopy gas-phase chemistry during CABINEX 2009: sensitivity of a 1-D canopy model to vertical mixing and isoprene chemistry A. Bryan et al.
- Why do models overestimate surface ozone in the Southeast United States? K. Travis et al.
- A new gas-phase condensed mechanism of isoprene-NOx photooxidation H. Zhang et al.
- Nine years of global hydrocarbon emissions based on source inversion of OMI formaldehyde observations M. Bauwens et al.
- Technical note: Evaluation of the Copernicus Atmosphere Monitoring Service Cy48R1 upgrade of June 2023 H. Eskes et al.
- The Chemistry of Atmosphere-Forest Exchange (CAFE) Model – Part 2: Application to BEARPEX-2007 observations G. Wolfe et al.
- Improved retrieval of global tropospheric formaldehyde columns from GOME-2/MetOp-A addressing noise reduction and instrumental degradation issues I. De Smedt et al.
- Temperature dependence of the yields of methacrolein and methyl vinyl ketone from the OH-initiated oxidation of isoprene under NOx-free conditions M. Navarro et al.
- Impacts of HOxregeneration and recycling in the oxidation of isoprene: Consequences for the composition of past, present and future atmospheres A. Archibald et al.
- Isoprene Emissions, Oxidation Chemistry and Environmental Impacts M. Khan et al.
- Improved MEGAN predictions of biogenic isoprene in the contiguous United States P. Wang et al.
- Recent advances in understanding secondary organic aerosol: Implications for global climate forcing M. Shrivastava et al.
- Assessment of dicarbonyl contributions to secondary organic aerosols over China using RAMS-CMAQ J. Li et al.
- The atmospheric chemistry box model CAABA/MECCA-3.0 R. Sander et al.
- Observations of total RONO2 over the boreal forest: NOx sinks and HNO3 sources E. Browne et al.
- Ozone and organic nitrates over the eastern United States: Sensitivity to isoprene chemistry J. Mao et al.
- Quantifying the magnitude of a missing hydroxyl radical source in a tropical rainforest L. Whalley et al.
- Reconciling the changes in atmospheric methane sources and sinks between the Last Glacial Maximum and the pre-industrial era J. Levine et al.
- How consistent are top-down hydrocarbon emissions based on formaldehyde observations from GOME-2 and OMI? T. Stavrakou et al.
- Regional sources of atmospheric formaldehyde and acetaldehyde, and implications for atmospheric modeling D. Luecken et al.
- Can a “state of the art” chemistry transport model simulate Amazonian tropospheric chemistry? M. Barkley et al.
- Observations and modeling of formaldehyde at the PROPHET mixed hardwood forest site in 2008 M. Galloway et al.
- Unusually Fast 1,6-H Shifts of Enolic Hydrogens in Peroxy Radicals: Formation of the First-Generation C2 and C3 Carbonyls in the Oxidation of Isoprene J. Peeters & T. Nguyen
- Unclassical Radical Generation Mechanisms in the Troposphere: A Review X. Yang et al.
- Aqueous-phase mechanism for secondary organic aerosol formation from isoprene: application to the southeast United States and co-benefit of SO2 emission controls E. Marais et al.
- Understanding the impact of recent advances in isoprene photooxidation on simulations of regional air quality Y. Xie et al.
- Photochemical modeling of glyoxal at a rural site: observations and analysis from BEARPEX 2007 A. Huisman et al.
- Case study of the diurnal variability of chemically active species with respect to boundary layer dynamics during DOMINO B. van Stratum et al.
- The MCM v3.3.1 degradation scheme for isoprene M. Jenkin et al.
- Differences in BVOC oxidation and SOA formation above and below the forest canopy B. Schulze et al.
- Formation of carbonyls and hydroperoxyenals (HPALDs) from the OH radical reaction of isoprene for low-NOx conditions: influence of temperature and water vapour content T. Berndt
- Tropospheric OH and HO2 radicals: field measurements and model comparisons D. Stone et al.
- Key chemical NOx sink uncertainties and how they influence top-down emissions of nitrogen oxides T. Stavrakou et al.
- Regional evaluation of the performance of the global CAMS chemical modeling system over the United States (IFS cycle 47r1) J. Williams et al.
- Hydroxyl Radical Recycling in Isoprene Oxidation Driven by Hydrogen Bonding and Hydrogen Tunneling: The Upgraded LIM1 Mechanism J. Peeters et al.
- Quantifying the uncertainty in simulating global tropospheric composition due to the variability in global emission estimates of Biogenic Volatile Organic Compounds J. Williams et al.
- Consecutive Chemical Activation Steps in the OH‐Initiated Atmospheric Degradation of Isoprene: An Analysis with Coupled Master Equations M. Pfeifle & M. Olzmann
- Evaluation of MEGAN predicted biogenic isoprene emissions at urban locations in Southeast Texas S. Kota et al.
- Observational constraints on glyoxal production from isoprene oxidation and its contribution to organic aerosol over the Southeast United States J. Li et al.
- Photolysis, OH reactivity and ozone reactivity of a proxy for isoprene-derived hydroperoxyenals (HPALDs) G. Wolfe et al.
- Observations of the temperature dependent response of ozone to NOx reductions in the Sacramento, CA urban plume B. LaFranchi et al.
- Evaluation of HOx sources and cycling using measurement-constrained model calculations in a 2-methyl-3-butene-2-ol (MBO) and monoterpene (MT) dominated ecosystem S. Kim et al.
- Comparisons of observed and modeled OH and HO2concentrations during the ambient measurement period of the HOxComp field campaign Y. Kanaya et al.
- Optimization of a gas chromatographic unit for measuring biogenic volatile organic compounds in ambient air K. Mermet et al.
- Observation and modelling of OH and HO2 concentrations in the Pearl River Delta 2006: a missing OH source in a VOC rich atmosphere K. Lu et al.
- Impact of the isoprene photochemical cascade on tropical ozone F. Paulot et al.
- Peroxy radical isomerization in the oxidation of isoprene J. Crounse et al.
- Impacts of mechanistic changes on HOx formation and recycling in the oxidation of isoprene A. Archibald et al.
- Investigating missing sources of glyoxal over China using a regional air quality model (RAMS-CMAQ) J. Li et al.
- Contributions of primary and secondary biogenic VOC tototal OH reactivity during the CABINEX (Community Atmosphere-Biosphere INteractions Experiments)-09 field campaign S. Kim et al.
- An Observational Perspective on the Atmospheric Impacts of Alkyl and Multifunctional Nitrates on Ozone and Secondary Organic Aerosol A. Perring et al.
- First space-based derivation of the global atmospheric methanol emission fluxes T. Stavrakou et al.
- Preindustrial to present-day changes in tropospheric hydroxyl radical and methane lifetime from the Atmospheric Chemistry and Climate Model Intercomparison Project (ACCMIP) V. Naik et al.
- Theoretical studies of atmospheric reaction mechanisms in the troposphere L. Vereecken & J. Francisco
- On Rates and Mechanisms of OH and O3 Reactions with Isoprene-Derived Hydroxy Nitrates L. Lee et al.
- Glyoxal yield from isoprene oxidation and relation to formaldehyde: chemical mechanism, constraints from SENEX aircraft observations, and interpretation of OMI satellite data C. Chan Miller et al.
- Development of an extended chemical mechanism for global–through–urban applications P. Karamchandani et al.
- Within‐plant isoprene oxidation confirmed by direct emissions of oxidation products methyl vinyl ketone and methacrolein K. Jardine et al.
- Global modeling of SOA formation from dicarbonyls, epoxides, organic nitrates and peroxides G. Lin et al.
- Isoprene oxidation mechanisms: measurements and modelling of OH and HO2 over a South-East Asian tropical rainforest during the OP3 field campaign D. Stone et al.
- Impacts of changes in land use and land cover on atmospheric chemistry and air quality over the 21st century S. Wu et al.
- Measurements of the Kinetics of the Reaction of OH Radicals with 3‐Methylfuran at Low Pressure J. Liljegren & P. Stevens
- Experimental evidence for efficient hydroxyl radical regeneration in isoprene oxidation H. Fuchs et al.
- Effects of biogenic nitrate chemistry on the NOx lifetime in remote continental regions E. Browne & R. Cohen
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