Articles | Volume 10, issue 9
Atmos. Chem. Phys., 10, 4331–4341, 2010

Special issue: Measurement and modeling of aerosol emissions from biomass...

Atmos. Chem. Phys., 10, 4331–4341, 2010

  07 May 2010

07 May 2010

Technical Note: Fast two-dimensional GC-MS with thermal extraction for anhydro-sugars in fine aerosols

Y. Ma1,*, M. D. Hays1, C. D. Geron1, J. T. Walker1, and M. J. Gatari Gichuru2 Y. Ma et al.
  • 1National Risk Management Research Laboratory, United States Environmental Protection Agency, Research Triangle Park, North Carolina 27711, USA
  • 2Institute of Nuclear Science & Technology, College of Architecture and Engineering, University of Nairobi, Nairobi, Kenya
  • *currently at: California Air Resources Board, 9528 Telstar Avenue, El Monte, CA 91731, USA

Abstract. A fast two-dimensional gas chromatography (GC-MS) method that uses heart-cutting and thermal extraction (TE) and requires no chemical derivatization was developed for the determination of anhydro-sugars in fine aerosols. Evaluation of the TE-GC-GC-MS method shows high average relative accuracy (≥90%), reproducibility (≤10% relative standard deviation), detection limits of less than 3 ng/μL, and negligible carryover for levoglucosan, mannosan, and galactosan markers. TE-GC-GC-MS- and solvent extraction (SE)-GC-MS-measured levoglucosan concentrations correlate across several diverse types of biomass burning aerosols. Because the SE-GC-MS measurements were taken 8 years prior to the TE-GC-GC-MS ones, the stability of levoglucosan is established for quartz filter-collected biomass burning aerosol samples stored at ultra-low temperature (−50 °C). Levoglucosan concentrations (w/w) in aerosols collected following atmospheric dilution near open fires of varying intensity are similar to those in biomass burning aerosols produced in a laboratory enclosure. An average levoglucosan-mannosan-galactosan ratio of 15:2:1 is observed for these two aerosol sets. TE-GC-GC-MS analysis of atmospheric aerosols from the US and Africa produced levoglucosan concentrations (0.01–1.6 μg/m3) well within those reported for aerosols collected globally and examined using different analytical techniques (0.004–7.6 μg/m3). Further comparisons among techniques suggest that fast TE-GC-GC-MS is among the most sensitive, accurate, and precise methods for compound-specific quantification of anhydro-sugars. In addition, an approximately twofold increase in anhydro-sugar determination may be realized when combining TE with fast chromatography.

Final-revised paper