the Creative Commons Attribution-NonCommercial-ShareAlike 2.5 License.
the Creative Commons Attribution-NonCommercial-ShareAlike 2.5 License.
Air-to-sea flux of soluble iron: is it driven more by HNO3 or SO2? – an examination in the light of dust aging
Abstract. Aeolian dust provides the major micronutrient of soluble Fe to organisms in certain regions of the global ocean. In this study, we conduct numerical experiments using the MOZART-2 atmospheric chemistry transport model to simulate the global distribution of soluble Fe flux and Fe solubility. One of the mechanisms behind the hypothesis of acid mobilization of Fe in the atmosphere is that the coating of acidic gases changes dust from hydrophobic to hydrophilic, a prerequisite of Fe mobilization. We therefore include HNO3, SO2 and sulfate (SO42−) as dust transformation agents in the model. General agreement in Fe solubility within a factor of 2 is achieved between model and observations. The total flux of soluble Fe to the world ocean is estimated to be 731–924×109 g yr−1, and the average Fe solubility is 6.4–8.0%. Wet deposition contributes over 80% to total soluble Fe flux to most of the world oceans. Special attention is paid to the relative role of HNO3 versus SO2 and sulfate. We demonstrate that coating by HNO3 produces over 36% of soluble Fe fluxes compared to that by SO2 and sulfate combined in every major oceanic basin. Given present trends in the emissions of NOx and SO2, the relative contribution of HNO3 to Fe mobilization may get even larger in the future.
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RC S3458: 'nonymous Referee #1', Anonymous Referee #2, 26 Jul 2007
- AC S5727: 'Responses to Anonymous Referee #2', Huiyan Yang, 08 Oct 2007
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RC S3593: 'Dissolution by HNO3 vs SO2', Anonymous Referee #1, 01 Aug 2007
- AC S5736: 'Responses to Anonymous Referee #1', Huiyan Yang, 08 Oct 2007
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RC S4301: 'Referee comment', Anonymous Referee #3, 23 Aug 2007
- AC S5743: 'Responses to Anonymous Referee #3', Huiyan Yang, 08 Oct 2007
-
RC S3458: 'nonymous Referee #1', Anonymous Referee #2, 26 Jul 2007
- AC S5727: 'Responses to Anonymous Referee #2', Huiyan Yang, 08 Oct 2007
-
RC S3593: 'Dissolution by HNO3 vs SO2', Anonymous Referee #1, 01 Aug 2007
- AC S5736: 'Responses to Anonymous Referee #1', Huiyan Yang, 08 Oct 2007
-
RC S4301: 'Referee comment', Anonymous Referee #3, 23 Aug 2007
- AC S5743: 'Responses to Anonymous Referee #3', Huiyan Yang, 08 Oct 2007
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Cited
2 citations as recorded by crossref.
- Aeolian iron mobilisation by dust - acid interactions and their implications for soluble iron deposition to the ocean: a test involving potential anthropogenic organic acidic species C. Luo & Y. Gao 10.1071/EN09116
- Characterization of typical metal particles during haze episodes in Shanghai, China R. Li et al. 10.1016/j.chemosphere.2017.03.140