Geostationary Environment Monitoring Spectrometer (GEMS) is the first instrument to observe air quality from a geostationary Earth orbit (GEO) successfully launched on 19 February 2020 and in initial operation after in-orbit tests (IOTs). GEMS provides hourly air quality information on both aerosols and gases at unprecedented spatial resolution of 7 km × 8 km. GEMS is a scanning UV–visible spectrometer measuring the hyperspectral spectrum in the ultraviolet and visible, which allows for the observation of key atmospheric constituents including O₃, NO₂, CO, SO₂, CH₂O, CHOCHO, aerosols, clouds, and UV indices. The mission opened a new era of air quality monitoring from space and will be joined by NASA’s TEMPO and ESA’s Sentinel-4 to form the GEO Air Quality Constellation in ~3 years to cover the most polluted region in the Northern Hemisphere. In this ACP–AMT special issue, the first results will be presented including instruments, IOT results, initial products, algorithm, calibration, validation from the recent GMAP field campaign, applications in modelling, etc.