Articles | Volume 9, issue 3
Atmos. Chem. Phys., 9, 965–971, 2009
https://doi.org/10.5194/acp-9-965-2009
Atmos. Chem. Phys., 9, 965–971, 2009
https://doi.org/10.5194/acp-9-965-2009

  06 Feb 2009

06 Feb 2009

Thermodynamics of homogeneous nucleation of ice particles in the polar summer mesosphere

A. Y. Zasetsky1, S. V. Petelina2,3, and I. M. Svishchev1 A. Y. Zasetsky et al.
  • 1Trent University, Peterborough, Ontario, Canada
  • 2La Trobe University, Victoria, Australia
  • 3Formerly at the University of Saskatchewan, Saskatoon, Canada

Abstract. We present the hypothesis of homogeneous nucleation of ice nano-particles in the polar summer mesosphere. The nucleation of condensed phase is traced back to the first step on the formation pathway, which is assumed to be the transition of water vapor to amorphous cluster. Amorphous clusters then freeze into water ice, likely metastable cubic ice, when they reach the critical size. The estimates based on the equilibrium thermodynamics give the critical size (radius) of amorphous water clusters as about 1.0 nm. The same estimates for the final transition step, that is the transformation of cubic to hexagonal ice, give the critical size of about 15 nm at typical upper mesospheric conditions during the polar summer (temperature T=150 K, water vapor density ρvapor=109 cm−3).

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