Articles | Volume 8, issue 24
Atmos. Chem. Phys., 8, 7519–7532, 2008
https://doi.org/10.5194/acp-8-7519-2008
Atmos. Chem. Phys., 8, 7519–7532, 2008
https://doi.org/10.5194/acp-8-7519-2008

  16 Dec 2008

16 Dec 2008

Parameterization of middle atmospheric water vapor photochemistry for high-altitude NWP and data assimilation

J. P. McCormack1, K. W. Hoppel2, and D. E. Siskind1 J. P. McCormack et al.
  • 1Space Science Division, Naval Research Laboratory, Washington DC, USA
  • 2Remote Sensing Division, Naval Research Laboratory, Washington DC, USA

Abstract. This paper describes CHEM2D-H2O, a new parameterization of H2O photochemical production and loss based on the CHEM2D photochemical-transport model of the middle atmosphere. This parameterization accounts for the altitude, latitude, and seasonal variations in the photochemical sources and sinks of water vapor over the pressure region from 100–0.001 hPa (~16–90 km altitude). A series of free-running NOGAPS-ALPHA forecast model simulations offers a preliminary assessment of CHEM2D-H2O performance over the June 2007 period. Results indicate that the CHEM2D-H2O parameterization improves global 10-day forecasts of upper mesospheric water vapor compared to forecasts using an existing one-dimensional (altitude only) parameterization. Most of the improvement is seen at high winter latitudes where the one-dimensional parameterization specifies photolytic H2O loss year round despite the lack of sunlight in winter. The new CHEM2D-H2O parameterization should provide a better representation of the downwelling of dry mesospheric air into the stratospheric polar vortex in operational analyses that do not assimilate middle atmospheric H2O measurements.

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