Ultra-violet absorption cross sections of isotopically substituted nitrous oxide species: 14N14NO, 15N14NO, 14N15NO and 15N15NO

von Hessberg, P.; Kaiser, J.; Enghoff, M. B.; McLinden, C. A.; Sorensen, S. L.; Röckmann, T.; Johnson, M. S.

doi:https://doi.org/10.5194/acp-4-1237-2004

Articles | Volume 4, issue 5

https://doi.org/10.5194/acp-4-1237-2004

© Author(s) 2004. This work is licensed under
the Creative Commons Attribution-NonCommercial-ShareAlike 2.5 License.

https://doi.org/10.5194/acp-4-1237-2004

© Author(s) 2004. This work is licensed under
the Creative Commons Attribution-NonCommercial-ShareAlike 2.5 License.

Articles | Volume 4, issue 5

10 Aug 2004

| 10 Aug 2004

Ultra-violet absorption cross sections of isotopically substituted nitrous oxide species: ¹⁴N¹⁴NO, ¹⁵N¹⁴NO, ¹⁴N¹⁵NO and ¹⁵N¹⁵NO

P. von Hessberg, J. Kaiser, M. B. Enghoff, C. A. McLinden, S. L. Sorensen, T. Röckmann, and M. S. Johnson

Abstract. The isotopically substituted nitrous oxide species ¹⁴N¹⁴NO, ¹⁵N¹⁴NO, ¹⁴N¹⁵NO and ¹⁵N¹⁵NO were investigated by ultra-violet (UV) absorption spectroscopy. High precision cross sections were obtained for the wavelength range 181 to 218nm at temperatures of 233 and 283K. These data are used to calculate photolytic isotopic fractionation constants as a function of wavelength. The fractionation constants were used in a three-dimensional chemical transport model in order to simulate the actual fractionation of N₂O in the stratosphere, and the results were found to be in good agreement with field studies.