Articles | Volume 15, issue 14
Atmos. Chem. Phys., 15, 8065–8076, 2015

Special issue: The Modular Earth Submodel System (MESSy) (ACP/GMD inter-journal...

Atmos. Chem. Phys., 15, 8065–8076, 2015
Research article
22 Jul 2015
Research article | 22 Jul 2015

Partitioning and budget of inorganic and organic chlorine species observed by MIPAS-B and TELIS in the Arctic in March 2011

G. Wetzel1, H. Oelhaf1, M. Birk2, A. de Lange3, A. Engel4, F. Friedl-Vallon1, O. Kirner5, A. Kleinert1, G. Maucher1, H. Nordmeyer1, J. Orphal1, R. Ruhnke1, B.-M. Sinnhuber1, and P. Vogt2 G. Wetzel et al.
  • 1Karlsruhe Institute of Technology, Institute of Meteorology and Climate Research, Karlsruhe, Germany
  • 2Deutsches Zentrum für Luft und Raumfahrt, Institut für Methodik der Fernerkundung, Wessling, Germany
  • 3SRON-Netherlands Institute for Space Research, Utrecht, the Netherlands
  • 4Institut für Atmosphäre und Umwelt, J. W. Goethe Universität Frankfurt, Frankfurt, Germany
  • 5Karlsruhe Institute of Technology, Steinbuch Centre for Computing, Karlsruhe, Germany

Abstract. The Arctic winter 2010/2011 was characterized by a persistent vortex with extremely low temperatures in the lower stratosphere above northern Scandinavia leading to a strong activation of chlorine compounds (ClOx) like Cl, Cl2, ClO, ClOOCl, OClO, and HOCl, which rapidly destroyed ozone when sunlight returned after winter solstice. The MIPAS-B (Michelson Interferometer for Passive Atmospheric Sounding) and TELIS (TErahertz and submillimeter LImb Sounder) balloon measurements obtained in northern Sweden on 31 March 2011 inside the polar vortex have provided vertical profiles of inorganic and organic chlorine species as well as diurnal variations of ClO around sunrise over the whole altitude range in which chlorine has been undergoing activation and deactivation. This flight was performed at the end of the winter during the last phase of ClOx deactivation. The complete inorganic and organic chlorine partitioning and budget for 31 March 2011, assumed to be representative for the late-winter Arctic stratosphere, has been derived by combining MIPAS-B and TELIS simultaneously observed molecules. A total chlorine amount of 3.41 ± 0.30 parts per billion by volume is inferred from the measurements (above 24 km). This value is in line with previous stratospheric observations carried out outside the tropics confirming the slightly decreasing chlorine amount in the stratosphere. Observations are compared and discussed with the output of a multi-year simulation performed with the chemistry climate model EMAC (ECHAM5/MESSy Atmospheric Chemistry). The simulated stratospheric total chlorine amount is in accordance with the MIPAS-B/TELIS observations, taking into account the fact that some chlorine source gases and very short-lived species are not included in the model.

Final-revised paper