Articles | Volume 15, issue 4
Atmos. Chem. Phys., 15, 1939–1958, 2015
Atmos. Chem. Phys., 15, 1939–1958, 2015

Research article 24 Feb 2015

Research article | 24 Feb 2015

Increasing concentrations of dichloromethane, CH2Cl2, inferred from CARIBIC air samples collected 1998–2012

E. C. Leedham Elvidge1, D. E. Oram2,3, J. C. Laube2, A. K. Baker1, S. A. Montzka4, S. Humphrey2, D. A. O'Sullivan2,*, and C. A. M. Brenninkmeijer1 E. C. Leedham Elvidge et al.
  • 1CARIBIC, Max Plank Institute for Chemistry, Hahn-Meitner Weg 1, 55128 Mainz, Germany
  • 2Centre for Ocean and Atmospheric Sciences, School of Environmental Sciences, University of East Anglia, Norwich Research Park, Norwich, NR4 7TJ, UK
  • 3National Centre for Atmospheric Science, University of East Anglia, Norwich, NR4 7TJ, UK
  • 4National Oceanic and Atmospheric Administration, Boulder, CO 80304, USA
  • *now at: Met Office, FitzRoy road, Exeter, EX1 3PB, UK

Abstract. Atmospheric concentrations of dichloromethane, CH2Cl2, a regulated toxic air pollutant and minor contributor to stratospheric ozone depletion, were reported to have peaked around 1990 and to be declining in the early part of the 21st century. Recent observations suggest this trend has reversed and that CH2Cl2 is once again increasing in the atmosphere. Despite the importance of ongoing monitoring and reporting of atmospheric CH2Cl2, no time series has been discussed in detail since 2006. The CARIBIC project (Civil Aircraft for the Regular Investigation of the atmosphere Based on an Instrument Container) has analysed the halocarbon content of whole-air samples collected at altitudes of between ~ 10–12 km via a custom-built container installed on commercial passenger aircraft since 1998, providing a long-term record of CH2Cl2 observations. In this paper we present this unique CH2Cl2 time series, discussing key flight routes which have been used at various times over the past 15 years. Between 1998 and 2012 increases were seen in all northern hemispheric regions and at different altitudes, ranging from ~ 7–10 ppt in background air to ~ 13–15 ppt in regions with stronger emissions (equating to a 38–69% increase). Of particular interest is the rising importance of India as a source of atmospheric CH2Cl2: based on CARIBIC data we provide regional emission estimates for the Indian subcontinent and show that regional emissions have increased from 3–14 Gg yr−1 (1998–2000) to 16–25 Gg yr−1 (2008). Potential causes of the increasing atmospheric burden of CH2Cl2 are discussed. One possible source is the increased use of CH2Cl2 as a feedstock for the production of HFC-32, a chemical used predominantly as a replacement for ozone-depleting substances in a variety of applications including air conditioners and refrigeration.

Final-revised paper