Articles | Volume 15, issue 23
Atmos. Chem. Phys., 15, 13633–13646, 2015

Special issue: Haze-fog forecasts and near real time (NRT) data application...

Atmos. Chem. Phys., 15, 13633–13646, 2015

Research article 10 Dec 2015

Research article | 10 Dec 2015

Absorption coefficient of urban aerosol in Nanjing, west Yangtze River Delta, China

B. L. Zhuang1,2, T. J. Wang1,2, J. Liu1,3, Y. Ma4, C. Q. Yin1, S. Li1,2, M. Xie1,2, Y. Han1,2, J. L. Zhu1, X. Q. Yang1,2, and C. B. Fu1,2 B. L. Zhuang et al.
  • 1School of Atmospheric Sciences, Nanjing University, Xianlin Ave. 163, Nanjing 210023, China
  • 2Collaborative Innovation Center of Climate Change, Jiangsu, China
  • 3Department of Geography and Planning, University of Toronto, Toronto, M5S 3G3, Canada
  • 4School of Environmental Science and Engineering, Nanjing University of Information Science and Technology, Ningliu Rd. 219, Nanjing 210044, China

Abstract. Absorbing aerosols can significantly modulate short-wave solar radiation in the atmosphere, affecting regional and global climate. The aerosol absorption coefficient (AAC) is an indicator that assesses the impact of absorbing aerosols on radiative forcing. In this study, the near-surface AAC and absorption Ångström exponent (AAE) in the urban area of Nanjing, China, are characterized on the basis of measurements in 2012 and 2013 using the seven-channel Aethalometer (model AE-31, Magee Scientific, USA). The AAC is estimated with direct and indirect corrections, which result in consistent temporal variations and magnitudes of AAC at 532 nm. The mean AAC at 532 nm is about 43.23 ± 28.13 M m−1 in the urban area of Nanjing, which is much lower than that in Pearl River Delta and the same as in rural areas (Lin'an) in Yangtze River Delta. The AAC in the urban area of Nanjing shows strong seasonality (diurnal variations); it is high in cold seasons (at rush hour) and low in summer (in the afternoon). It also shows synoptic and quasi-2-week cycles in response to weather systems. Its frequency distribution follows a typical log-normal pattern. The 532 nm AAC ranging from 15 to 65 M m−1 dominates, accounting for more than 72 % of the total data samples in the entire study period. Frequent high pollution episodes, such as those observed in June 2012 and in winter 2013, greatly enhanced AAC and altered its temporal variations and frequency distributions. These episodes are mostly due to local emissions and regional pollution. Air masses flowing from northern China to Nanjing can sometimes be highly polluted and lead to high AAC at the site. AAE at 660/470 nm from the Schmid correction (Schmid et al., 2006) is about 1.56, which might be more reasonable than from the Weingartner correction (Weingartner et al., 2003). Low AAEs mainly occur in summer, likely due to high relative humidity (RH) in the season. AAC increases with increasing AAE at a fixed aerosol loading. The RH–AAC relationship is more complex. Overall, AAC peaks at RH values of around 40 % (1.3 < AAE < 1.6), 65 % (AAE < 1.3 and AAE > 1.6), and 80 % (1.3 < AAE < 1.6).

Short summary
The aerosol absorbing coefficient (AAC) assesses the direct radiative forcing of absorbing aerosols. The corrected AAC and absorption Ångström exponent (AAE) in Nanjing, YRD, are characterized using AE-31. Schmid-corrected AAC at 532nm and the AAE at 660/470nm are about 43.23±28.13 Mm-1 and 1.56, both with strong seasonal and diurnal variations. A high AAC is mostly resultant of local and subregional emissions in Nanjing. It peaks at RH values of 40, 65, and 80% at different AAE levels.
Final-revised paper