Black carbon over the South China Sea and in various continental locations in South China

Abstract. Black carbon (BC) is an important atmospheric constituent as an air pollutant and as a climate forcer. To our knowledge, field measurements of BC have not been reported over the South China Sea. Observations of light-absorption coefficients (σ_abs) and BC concentrations by Aethalometer were conducted on Yongxing Island in the South China Sea and at five continental sites in the Pearl River delta (PRD) region, South China, in two periods: 16 May–20 June 2008 in the rainy season and 12 December 2008–8 January 2009 in the dry season. At the oceanic site, the daily average BC concentrations varied from 0.28 to 2.14 μg m⁻³ and variations of BC were small between the two periods (0.67 in the dry season sampling period and 0.54 μg m⁻³ in the rainy season sampling period). Similarly, little difference in BC level was found at a rural site in PRD between the two sampling periods (2.88 and 2.62 μg m^–3). At the PRD urban sites, the daily average concentration of BC ranged from 1.56 to 37.9 μg m⁻³, higher in the dry season sampling period (12.31 μg m^–3) and lower in the rainy season sampling period (6.17 μg m^–3). The observed average σ_abs values in rainy vs. dry season sampling periods are 119 vs. 62 Mm⁻¹ at the PRD urban sites, 29 vs. 26 Mm⁻¹ at the PRD background site, and 8.4 vs. 7.2 Mm⁻¹ at the marine site. At urban/suburban PRD sites, BC was observed to have a diurnal pattern of higher concentrations at night and at the urban sites a small peak in the early morning rush hour.