Comparative evaluation of the impact of WRF/NMM and WRF/ARW meteorology on CMAQ simulations for PM_2.5 and its related precursors during the 2006 TexAQS/GoMACCS study

Abstract. This study presents a comparative evaluation of the impact of WRF-NMM and WRF-ARW meteorology on CMAQ simulations of PM_2.5, its composition and related precursors over the eastern United States with the intensive observations obtained by aircraft (NOAA WP-3), ship and surface monitoring networks (AIRNow, IMPROVE, CASTNet and STN) during the 2006 TexAQS/GoMACCS study. The results at the AIRNow surface sites show that both ARW-CMAQ and NMM-CMAQ reproduced day-to-day variations of observed PM_2.5 and captured the majority of observed PM_2.5 within a factor of 2 with a NMB value of −0.4% for ARW-CMAQ and −18% for NMM-CMAQ. Both models performed much better at the urban sites than at the rural sites, with greater underpredictions at the rural sites. Both models consistently underestimated the observed PM_2.5 at the rural IMPROVE sites by −1% for the ARW-CMAQ and −19% for the NMM-CMAQ. The greater underestimations of SO₄²⁻, OC and EC by the NMM-CMAQ contributed to increased underestimation of PM_2.5 at the IMPROVE sites. The NMB values for PM_2.5 at the STN urban sites are 15% and −16% for the ARW-CMAQ and NMM-CMAQ, respectively. The underestimation of PM_2.5 at the STN sites by the NMM-CMAQ mainly results from the underestimations of the SO₄²⁻, NH₄⁺ and TCM components, whereas the overestimation of PM_2.5 at the STN sites by the ARW-CMAQ results from the overestimations of SO₄²⁻, NO₃⁻, and NH₄⁺. The Comparison with WP-3 aircraft measurements reveals that both ARW-CMAQ and NMM-CMAQ have very similar model performance for vertical profiles for PM_2.5 chemical components (SO₄²⁻, NH₄⁺) and related gaseous species (HNO₃, SO₂, NH₃, isoprene, toluene, terpenes) as both models used the same chemical mechanisms and emissions. The results of ship along the coast of southeastern Texas over the Gulf of Mexico show that both models captured the temporal variations and broad synoptic change seen in the observed HCHO and acetaldehyde with the means NMB <30% most of the time but they consistently underestimated terpenes, isoprene, toluene and SO₂.