Articles | Volume 10, issue 9
Atmos. Chem. Phys., 10, 4167–4186, 2010

Special issue: European Integrated Project on Aerosol-Cloud-Climate and Air...

Atmos. Chem. Phys., 10, 4167–4186, 2010

  05 May 2010

05 May 2010

Aged organic aerosol in the Eastern Mediterranean: the Finokalia Aerosol Measurement Experiment – 2008

L. Hildebrandt1, G. J. Engelhart1, C. Mohr2, E. Kostenidou3,4, V. A. Lanz2, A. Bougiatioti5, P. F. DeCarlo2, A. S. H. Prevot2, U. Baltensperger2, N. Mihalopoulos5, N. M. Donahue1, and S. N. Pandis1,3,4 L. Hildebrandt et al.
  • 1Center for Atmospheric Particle Studies, Carnegie Mellon University, 5000 Forbes Ave., Pittsburgh, PA, 15213, USA
  • 2Laboratory of Atmospheric Chemistry, Paul Scherrer Institut, 5232 Villigen, Switzerland
  • 3Institute of Chemical Engineering and High Temperature Chemical Processes (ICE-HT), Foundation of Research and Technology (FORTH), Patra, Greece
  • 4Department of Chemical Engineering, University of Patras, Patra, Greece
  • 5Environmental Chemical Processes Laboratory (ECPL), University of Crete, Heraklion, Greece

Abstract. Aged organic aerosol (OA) was measured at a remote coastal site on the island of Crete, Greece during the Finokalia Aerosol Measurement Experiment-2008 (FAME-2008), which was part of the EUCAARI intensive campaign of May 2008. The site at Finokalia is influenced by air masses from different source regions, including long-range transport of pollution from continental Europe. A quadrupole aerosol mass spectrometer (Q-AMS) was employed to measure the size-resolved chemical composition of non-refractory submicron aerosol (NR-PM1), and to estimate the extent of oxidation of the organic aerosol. Factor analysis was used to gain insights into the processes and sources affecting the OA composition. The particles were internally mixed and liquid. The largest fraction of the dry NR-PM1 sampled was ammonium sulfate and ammonium bisulfate, followed by organics and a small amount of nitrate. The variability in OA composition could be explained with two factors of oxygenated organic aerosol (OOA) with differing extents of oxidation but similar volatility. Hydrocarbon-like organic aerosol (HOA) was not detected. There was no statistically significant diurnal variation in the bulk composition of NR-PM1 such as total sulfate or total organic aerosol concentrations. However, the OA composition exhibited statistically significant diurnal variation with more oxidized OA in the afternoon. The organic aerosol was highly oxidized, regardless of the source region. Total OA concentrations also varied little with source region, suggesting that local sources had only a small effect on OA concentrations measured at Finokalia. The aerosol was transported for about one day before arriving at the site, corresponding to an OH exposure of approximately 4×1011 molecules cm−3 s. The constant extent of oxidation suggests that atmospheric aging results in a highly oxidized OA at these OH exposures, regardless of the aerosol source.

Final-revised paper