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Volume 10, issue 3
Atmos. Chem. Phys., 10, 1287–1314, 2010
https://doi.org/10.5194/acp-10-1287-2010
© Author(s) 2010. This work is distributed under
the Creative Commons Attribution 3.0 License.
Atmos. Chem. Phys., 10, 1287–1314, 2010
https://doi.org/10.5194/acp-10-1287-2010
© Author(s) 2010. This work is distributed under
the Creative Commons Attribution 3.0 License.

  05 Feb 2010

05 Feb 2010

Contributions from DMS and ship emissions to CCN observed over the summertime North Pacific

L. Langley1,*, W. R. Leaitch2, U. Lohmann3, N. C. Shantz4,**, and D. R. Worsnop5 L. Langley et al.
  • 1Dalhousie University, Halifax, Nova Scotia, Canada
  • 2Environment Canada, Toronto, Ontario, Canada
  • 3Institute for Atmospheric and Climate Science, ETH Zurich, Switzerland
  • 4University of Toronto, Toronto, Ontario, Canada
  • 5Aerodyne Research Incorporated, Billerica, Massachusetts, USA
  • *now at: Meteorological Service of Canada, Dartmouth, Nova Scotia, Canada
  • **now at: Environment Canada, Toronto, Ontario, Canada

Abstract. Measurements of cloud condensation nuclei (CCN) made over the North Pacific Ocean in July 2002 are analysed with concurrent measurements of aerosol number, mass and composition. Overall the CCN are controlled by the sulphate, including one case that suggests particle nucleation and growth resulting from dimethyl sulphide oxidation that enhanced CCN concentrations. Hourly CCN concentrations are correlated with concentrations of sulphate plus methanesulphonic acid (MSA) over the entire study period (r2=0.43 and 0.52 for supersaturations of 0.34% and 0.19%, respectively), and are not well correlated with other organics (r2<0.2). One case study reveals elevated mass and number concentrations of ultrafine and fine organic particles due to regional ship emissions, identified through quadrupole aerosol mass spectrometer (Q-AMS) measurements, during which organic mass concentrations are correlated with CCN values (r2=0.39 and 0.46 for supersaturations of 0.19% and 0.34%, respectively). The evolution of the time series and mass distributions of organics, sulphate and MSA over this timeframe indicate that the regional distribution of small, diffuse ship-sourced organic particles act as condensation sites for sulphur species, resulting in a subsequent increase in number concentrations of CCN. We conclude that, where present, direct emissions of anthropogenic organic particles may exert a strong control on marine CCN concentrations once diffused into the marine atmosphere, by acting as condensation sites for biogenic and anthropogenic sulphur species.

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