17 Feb 2021
17 Feb 2021
Impact of firework on nitrooxy-organosulfates in urban aerosols during Chinese New Year Eve
- 1Institute of Surface-Earth System Science, School of Earth System Science, Tianjin University, Tianjin 300072, China
- 2LAPC, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing 100029, China
- 3School of Environmental Science and Engineering, Tianjin University, Tianjin, 300072, China
- 4School of Geography, Earth and Environmental Sciences, University of Birmingham, Birmingham, B15 2TT, UK
- 5Max Planck Institute for Chemistry, Multiphase Chemistry Department, Hahn-Meitner-Weg 1, 55128 Mainz, Germany
- 6Department of Civil and Environmental Engineering, The Hong Kong Polytechnic University, Hong Kong
- 7Chinese Research Academy of Environmental Sciences, Beijing 100012, China
- 8State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Science, Chinese Academy of Sciences, Beijing 100085, China
- 9Department of Chemistry, California University, Irvine, California 92697-2025, United States
- 10Chubu Institute for Advanced Studies, Chubu University, Kasugai 487-8501, Japan
- 1Institute of Surface-Earth System Science, School of Earth System Science, Tianjin University, Tianjin 300072, China
- 2LAPC, Institute of Atmospheric Physics, Chinese Academy of Sciences, Beijing 100029, China
- 3School of Environmental Science and Engineering, Tianjin University, Tianjin, 300072, China
- 4School of Geography, Earth and Environmental Sciences, University of Birmingham, Birmingham, B15 2TT, UK
- 5Max Planck Institute for Chemistry, Multiphase Chemistry Department, Hahn-Meitner-Weg 1, 55128 Mainz, Germany
- 6Department of Civil and Environmental Engineering, The Hong Kong Polytechnic University, Hong Kong
- 7Chinese Research Academy of Environmental Sciences, Beijing 100012, China
- 8State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Science, Chinese Academy of Sciences, Beijing 100085, China
- 9Department of Chemistry, California University, Irvine, California 92697-2025, United States
- 10Chubu Institute for Advanced Studies, Chubu University, Kasugai 487-8501, Japan
Abstract. Little is known about the formation processes of nitrooxy-organosulfates (nitrooxy-OSs) by nighttime chemistry. Here we characterize nitrooxy-OSs at a molecular level in firework-related aerosols in urban Beijing during Chinese New Year. High-molecular-weight nitrooxy-OSs with relatively low H / C and O / C ratios and high unsaturation, which are potentially aromatic-like nitrooxy-OSs, considerably increased during the New Year’s Eve. We find that large quantities of carboxylic-rich alicyclic molecules possibly formed by nighttime reactions. The sufficient abundance of aliphatic-like and aromatic-like nitrooxy-OSs demonstrates that both anthropogenic and biogenic volatile organic compounds are essential precursors of urban secondary organic aerosols (SOA). Besides, more than 98 % of nitrooxy-OSs were extremely low-volatile organic compounds that could easily partition into and consist in the particle phase, and affected the volatility, hygroscopicity, and even toxicity of urban aerosols. Our study provides new insights into the formation of nitrooxy-organosulfates from anthropogenic emissions through nighttime chemistry in the urban atmosphere.
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Qiaorong Xie et al.
Status: open (until 14 Apr 2021)
Qiaorong Xie et al.
Qiaorong Xie et al.
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