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https://doi.org/10.5194/acp-2020-940
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/acp-2020-940
© Author(s) 2020. This work is distributed under
the Creative Commons Attribution 4.0 License.

  16 Sep 2020

16 Sep 2020

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This preprint is currently under review for the journal ACP.

Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VIII – gas phase reactions of organic species with four, or more, carbon atoms (≥ C4)

Abdelwahid Mellouki1, Markus Ammann2, R. Anthony Cox3, John N. Crowley4, Hartmut Herrmann5, Michael E. Jenkin6, V. Faye McNeill7, Jürgen Troe8,9, and Timothy J. Wallington10 Abdelwahid Mellouki et al.
  • 1ICARE-CNRS, 1 C Av. de la Recherche Scientifique, 45071 Orléans Cedex 2, France
  • 2Laboratory of Radiochemistry and Environmental Chemistry, OFLB 103, Paul Scherrer Institut, 5232 Villigen, Switzerland
  • 3Centre for Atmospheric Science, Dept. of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EP, UK
  • 4Max Planck Institute for Chemistry, Division of Atmospheric Chemistry, 55128 Mainz, Germany
  • 5Leibniz Institute for Tropospheric Research (TROPOS), Atmospheric Chemistry Dept. (ACD), 04318 Leipzig, Germany
  • 6Atmospheric Chemistry Services, Okehampton, Devon, EX20 4QB, UK
  • 7Department of Chemical Engineering, Columbia University, New York, NY 10027, USA
  • 8Max Planck Institute for Biophysical Chemistry, Am Fassberg 11, 37077 Göttingen, Germany
  • 9Institute for Physical Chemistry, University of Göttingen, Tammannstr. 6, 37077 Göttingen, Germany
  • 10Ford Motor Company, Research and Advanced Engineering, Mail Drop RIC-2122, Dearborn, Michigan 48121-2053, USA

Abstract. This article, the eighth in the series, presents kinetic and photochemical datasheets evaluated by the IUPAC Task Group on Atmospheric Chemical Kinetic Data Evaluation. It covers the gas phase thermal and photochemical reactions of organic species with four, or more, carbon atoms (≥ C4) available on the IUPAC website in 2019, including thermal reactions of closed-shell organic species with HO and NO3 radicals, and their photolysis. The article consists of a summary table, containing the recommended kinetic parameters for the evaluated reactions, and a supplement containing the datasheets, which provide information upon which the recommendations are made.

Abdelwahid Mellouki et al.

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Short summary
Volatile organic compounds play an important role in atmospheric chemistry. This article, the eighth in the series, presents kinetic and photochemical datasheets evaluated by the IUPAC Task Group on Atmospheric Chemical Kinetic Data Evaluation. It covers the gas phase reactions of organic species with four, or more, carbon atoms (≥ C4) including thermal reactions of closed-shell organic species with HO and NO3 radicals, and their photolysis. These data are important for atmospheric models.
Volatile organic compounds play an important role in atmospheric chemistry. This article, the...
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