the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
18 Jan 2021
18 Jan 2021
Measurement report: The effect of aerosol chemical composition on light scattering due to the hygroscopic swelling effect
- 1State Key Laboratory of Remote Sensing Science, College of Global Change and Earth System Science, Beijing Normal University, Beijing 100875, China
- 2Earth System Science Interdisciplinary Center, Department of Atmospheric and Oceanic Science, University of Maryland, College Park, College Park, MD, USA
- 3CMA Meteorological Observation Center, Centre for Atmosphere Watch and Services, Beijing 100081, China
- 4Key Laboratory for Aerosol-Cloud-Precipitation of China Meteorological Administration, School of Atmospheric Physics, Nanjing University of Information Science and Technology, Nanjing 210044, China
- 5School of Electrical Engineering, Chengdu University of Information Technology, Chengdu 610225, China
- 1State Key Laboratory of Remote Sensing Science, College of Global Change and Earth System Science, Beijing Normal University, Beijing 100875, China
- 2Earth System Science Interdisciplinary Center, Department of Atmospheric and Oceanic Science, University of Maryland, College Park, College Park, MD, USA
- 3CMA Meteorological Observation Center, Centre for Atmosphere Watch and Services, Beijing 100081, China
- 4Key Laboratory for Aerosol-Cloud-Precipitation of China Meteorological Administration, School of Atmospheric Physics, Nanjing University of Information Science and Technology, Nanjing 210044, China
- 5School of Electrical Engineering, Chengdu University of Information Technology, Chengdu 610225, China
Abstract. Liquid water in aerosol particles has a significant effect on optical properties, especially on light scattering, whose dependence on chemical composition is investigated here using measurements made in southern Beijing in 2019. The effect is measured by the enhancement of aerosol hygroscopic factor, f(RH = 85 %, 525 nm), which is found to be positively and negatively impacted by the proportions of inorganic and organic matters respectively. Black carbon is also negatively correlated. The positive impact is more robust when the inorganic matter mass fraction was smaller than 40 % (correlation coefficient, R = 0.93) which becomes weaker as the inorganic matter mass fraction gets larger (R = 0.48). A similar pattern was also found in the negative impact for organic matter mass fraction. Nitrate played a more significant role in aerosol hygroscopicity than sulfate in Beijing. However, the deliquescence point of ambient aerosols was at about RH = 80 % when the ratio of the sulfate mass concentration to the nitrate mass concentration of the aerosol was high (mostly higher than ~4). Two schemes to parameterize f(RH) were developed in accounting for the deliquescent and non-deliquescent effects. Using only one f(RH) parameterization scheme to fit all f(RH) processes would incur large errors. A piecewise parameterization scheme is proposed, which can better describe deliquescence and reduces uncertainties in simulating aerosol hygroscopicity.
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Rongmin Ren et al.
Status: open (until 15 Mar 2021)
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RC1: 'Comment on acp-2020-1238', Anonymous Referee #2, 08 Feb 2021
reply
The effects of aerosol chemical composition on the relative humidity dependence of light scattering are presented for a site in Beijing. Parameterizations of f(RH) are developed for different observed conditions (e.g., very clean, moderately polluted, polluted based on measured light scattering levels). The paper is very well written and the figures (with one exception) clearly convey the results of the study. I only have minor comments - see below.
Line 39: change to “that REDUCES the amount”. Also, please add a brief description of how SO2 control reduces the amount of sulfate.
Lines 109 – 111: Why is the absorption coefficient at 880 nm transformed into those at 525 nm? Doesn’t the 7-wavelength aethalometer have a measurement wavelength near to 525 nm?
Lines 163 – 164: It is stated that “the proportion of organic matter and BC with weak hygroscopic abilities was low” from the southeast sector. Figure 3d indicates that mass fractions of BC were high in the southeast sector which seems to contradict this statement. Please clarify in the text.
Figure 6: The inset figures showing organic mass fraction vs. f(RH) are difficult to read because of their size – especially if a reader is looking at a print version of the paper. I recommend putting the insets into a separate figure.
Lines 258 – 260: Please report the mass fractions of organics, SO4, and NO3 if they were provided in Malm et al. (2003), Pan et al. (2009), Quinn et al. (2005), and Yan et al. (2009). It is difficult to assess differences in the role of NO3 versus SO4 in determining f(RH) in these different regions without knowing the chemical composition reported in these previously published papers.
Lines 261 – 263: Does this mean the Chinese government has made more efforts to control SO2 emissions than other governments or has made more efforts to control SO2 than NOx emissions? Please clarify in the text.
Line 315: Please define “DF”.
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RC2: 'Comment on acp-2020-1238', Anonymous Referee #1, 15 Feb 2021
reply
Review of “Measurement report: The effect of aerosol chemical composition on light scattering due to the hygroscopic swelling effect” by Rongmin Ren et al.
This manuscript presents the results of an intensive field campaign of two week duration in an area south of Beijing. The manuscript focuses on the study of the effect of aerosol hygroscopicity in the aerosol light scattering coefficient. Despite the short measurement period, the data collected are interesting and the results are of scientific significance. Nevertheless, I have some minor comments that need to be clarify by the authors.
Line 78: Briefly describe the humidifying scheme by Carrico et al. (1998)
Line 80: Was the tandem nephelometer calibrated with ammonium sulphate or other salt of known hygroscopicity? This is highly recommended to assure that the system is functioning correctly and that the RH inside the nephelometer chamber is correct (see Burgos et al. (2019) and Fierz-Schmidhauser et al. 2010b).
Line 80: Were the nephelometers operated with or without the kalman filter option?
Line 90: The equation to calculate the dew point temperature is not the most common one. I looked in the references provided by the authors but Kuang et al. (2017) doesn’t state which formula they use to calculate T dew point and the reference of Liu and Zhao (2016) is in Chinese. Please, use appropriate references for this formula.
Also, it would be interesting to see the comparison between RHin, RHoutlet and RHcalculated.
Line 105: I really don’t understand how the f(RH) is calculated. Why f(RH) is normalized? What is the reason behind this? Also, f(RH>40%) is averaged over what? Whole dataset, each scan? Then, in line 108 it is said that f(RH>40%) is 1. This is true for all the observations? Is it exactly 1? This calculation needs clarification.
Line 112: The absorption coefficient is measured at 7 wavelengths, the absorption coefficient at 520 nm is more appropriate than using the absorption coefficient at 880 nm and then convert it to 525 nm.
Eq 6: So, only f(RH=85%) is used to calculate gamma? If the frh measurements are performed at scanning RH it can be retrieved from a potential fit using the whole RH range, which will have less errors than using a single RH point (see Zieger et al. 2010, Titos et al., 2016).
Line 125: Include a reference to Zieger et al. 2010, who firstly introduced the hysteresis index.
Eq9: Actually, what it is here called g, it is usually referred as gamma.
Eq. 8: The RH range used to identify deliquesce is very narrow and can miss deliquescence processes occurring at slightly different RH. Maybe consider the procedure of Zieger et al.
Fig7: Why not consider all measured species, including NH4+, Cl- and BC? Is the organic mass fraction defined differently than in Figure 6?
Fig8: Use same color for WD from north (360º and 0º)
Line 220: Don’t understand the reasoning, which marine aeosols do the authors refer to?
Line 245: Do the authors refer to an instrument artefact due to water depletion?
Line 260: It is not that in the previous studies the role of NO3- was not as important as in the present study. Quinn et al. (2005) didn’t look at NO3-, their organic mass fraction was calculated using only SO42- as inorganic component. Why do the authors don’t include NH4+? Previously they stated the importance of ammonia, but here it is not included. See the relationships obtained by Zieger et al. and Zhang et al.
Burgos, M., Andrews, E., Titos, G., Alados-Arboledas, L., Baltensperger, U., Day, D., Jefferson, A., Kalivitis, N., Mihalopoulos, N., Sherman, J., Sun, J., Weingartner, E., and Zieger, P.: A global view on the effect of water uptake on aerosol particle light scattering, Scientific Data, 6, https://doi.org/10.1038/s41597-019-0158-7, 2019.
Rongmin Ren et al.
Rongmin Ren et al.
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