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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACPD</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACPD</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">Atmos. Chem. Phys. Discuss.</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7375</issn>
<publisher><publisher-name></publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-2017-928</article-id>
<title-group>
<article-title>Global impact of monocyclic aromatics on tropospheric composition</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Cabrera-Perez</surname>
<given-names>David</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Taraborrelli</surname>
<given-names>Domenico</given-names>
<ext-link>https://orcid.org/0000-0003-2213-6307</ext-link>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Lelieveld</surname>
<given-names>Jos</given-names>
<ext-link>https://orcid.org/0000-0001-6307-3846</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Hoffmann</surname>
<given-names>Thorsten</given-names>
<ext-link>https://orcid.org/0000-0003-0939-271X</ext-link>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Pozzer</surname>
<given-names>Andrea</given-names>
<ext-link>https://orcid.org/0000-0003-2440-6104</ext-link>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Atmospheric Chemistry Department, Max-Planck Institute of Chemistry, Hahn-Meitner-Weg 1, 55128 Mainz, Germany</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Institute of Energy and Climate Research (IEK-8), Forschungszentrum Jülich GmbH, Jülich, Germany</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Institute of Inorganic and Analytical Chemistry, University of Mainz, Duesbergweg 10–14, 55128 Mainz, Germany</addr-line>
</aff>
<pub-date pub-type="epub">
<day>27</day>
<month>10</month>
<year>2017</year>
</pub-date>
<volume>2017</volume>
<fpage>1</fpage>
<lpage>25</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2017 David Cabrera-Perez et al.</copyright-statement>
<copyright-year>2017</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://acp.copernicus.org/preprints/acp-2017-928/">This article is available from https://acp.copernicus.org/preprints/acp-2017-928/</self-uri>
<self-uri xlink:href="https://acp.copernicus.org/preprints/acp-2017-928/acp-2017-928.pdf">The full text article is available as a PDF file from https://acp.copernicus.org/preprints/acp-2017-928/acp-2017-928.pdf</self-uri>
<abstract>
<p>Aromatic compounds are reactive species influencing ozone formation, OH concentrations and organic aerosol formation. An assessment of their impacts on the gas-phase composition at a global scale has been performed using a general circulation atmospheric-chemistry model. 
&lt;br&gt;&lt;br&gt;
Globally, we found a small annual average net decrease (less than 3&amp;thinsp;%) in global OH, ozone, and NO&lt;sub&gt;x&lt;/sub&gt; mixing ratios when aromatic compounds are included in the chemical mechanism. This inclusion of aromatics also results in CO mixing ratio increases, which cause a general decrease in OH concentrations. The largest changes are found in glyoxal and NO&lt;sub&gt;3&lt;/sub&gt;, with increases in the atmospheric burden of 10&amp;thinsp;% and 6&amp;thinsp;%, respectively.
&lt;br&gt;&lt;br&gt;
Regionally, significant differences were found particularly in high NO&lt;sub&gt;x&lt;/sub&gt; regime areas, with an increase of up to 4&amp;thinsp;% in O&lt;sub&gt;3&lt;/sub&gt; mixing ratios and 8&amp;thinsp;% in OH concentrations. NO&lt;sub&gt;3&lt;/sub&gt; increased by more than 30&amp;thinsp;% in several regions of the northern hemisphere, and glyoxal increased up to 40&amp;thinsp;% in Europe and Asia. Large increases in formaldehyde were found in urban areas.
&lt;br&gt;&lt;br&gt;
Although the relative impact of aromatics at the global scale is limited, at a regional level they are important in atmospheric chemistry.</p>
</abstract>
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