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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACPD</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACPD</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">Atmos. Chem. Phys. Discuss.</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7375</issn>
<publisher><publisher-name></publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acpd-8-4499-2008</article-id>
<title-group>
<article-title>Validation of water vapour profiles from the Atmospheric Chemistry Experiment (ACE)</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Carleer</surname>
<given-names>M. R.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Boone</surname>
<given-names>C. D.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Walker</surname>
<given-names>K. A.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Bernath</surname>
<given-names>P. F.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Strong</surname>
<given-names>K.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Sica</surname>
<given-names>R. J.</given-names>
</name>
<xref ref-type="aff" rid="aff5">
<sup>5</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Randall</surname>
<given-names>C. E.</given-names>
</name>
<xref ref-type="aff" rid="aff6">
<sup>6</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Vömel</surname>
<given-names>H.</given-names>
</name>
<xref ref-type="aff" rid="aff7">
<sup>7</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Kar</surname>
<given-names>J.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Höpfner</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff8">
<sup>8</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Milz</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff8">
<sup>8</sup>
</xref>
<xref ref-type="aff" rid="aff17">
<sup>17</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>von Clarmann</surname>
<given-names>T.</given-names>
</name>
<xref ref-type="aff" rid="aff8">
<sup>8</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Kivi</surname>
<given-names>R.</given-names>
</name>
<xref ref-type="aff" rid="aff9">
<sup>9</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Valverde-Canossa</surname>
<given-names>J.</given-names>
</name>
<xref ref-type="aff" rid="aff10">
<sup>10</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Sioris</surname>
<given-names>C. E.</given-names>
</name>
<xref ref-type="aff" rid="aff11">
<sup>11</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Izawa</surname>
<given-names>M. R. M.</given-names>
</name>
<xref ref-type="aff" rid="aff12">
<sup>12</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Dupuy</surname>
<given-names>E.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>McElroy</surname>
<given-names>C. T.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
<xref ref-type="aff" rid="aff11">
<sup>11</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Drummond</surname>
<given-names>J. R.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
<xref ref-type="aff" rid="aff13">
<sup>13</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Nowlan</surname>
<given-names>C. R.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Zou</surname>
<given-names>J.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Nichitiu</surname>
<given-names>F.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Lossow</surname>
<given-names>S.</given-names>
</name>
<xref ref-type="aff" rid="aff14">
<sup>14</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Urban</surname>
<given-names>J.</given-names>
</name>
<xref ref-type="aff" rid="aff15">
<sup>15</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Murtagh</surname>
<given-names>D.</given-names>
</name>
<xref ref-type="aff" rid="aff15">
<sup>15</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Dufour</surname>
<given-names>D. G.</given-names>
</name>
<xref ref-type="aff" rid="aff16">
<sup>16</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Service de Chimie Quantique et Photophysique, Université Libre de Bruxelles, Brussels, Belgium</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Department of Chemistry, University of Waterloo, Waterloo, Ontario, Canada</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Department of Physics, University of Toronto, Toronto, Ontario, Canada</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Department of Chemistry, University of York, UK</addr-line>
</aff>
<aff id="aff5">
<label>5</label>
<addr-line>Department of Physics and Astronomy, University of Western Ontario, London, Ontario, Canada</addr-line>
</aff>
<aff id="aff6">
<label>6</label>
<addr-line>Laboratory for Atmospheric and Space Physics, University of Colorado, Boulder, CO, USA</addr-line>
</aff>
<aff id="aff7">
<label>7</label>
<addr-line>Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO, USA</addr-line>
</aff>
<aff id="aff8">
<label>8</label>
<addr-line>Forschungszentrum Karlsruhe and Universität Karlsruhe, Institut für Meteorologie und Klimaforschung, Karlsruhe, Germany</addr-line>
</aff>
<aff id="aff9">
<label>9</label>
<addr-line>Finnish Meteorological Institute, Arctic Research Center, Sodankylä, Finland</addr-line>
</aff>
<aff id="aff10">
<label>10</label>
<addr-line>Universidad Nacional, Heredia, Costa Rica</addr-line>
</aff>
<aff id="aff11">
<label>11</label>
<addr-line>Environment Canada, Downsview, Ontario, Canada</addr-line>
</aff>
<aff id="aff12">
<label>12</label>
<addr-line>Department of Earth Sciences, University of Western Ontario, London, Ontario, Canada</addr-line>
</aff>
<aff id="aff13">
<label>13</label>
<addr-line>Department of Physics &amp; Atmospheric Science, Dalhousie University, Halifax, Nova Scotia, Canada</addr-line>
</aff>
<aff id="aff14">
<label>14</label>
<addr-line>Department of Meteorology, Stockholm University, Stockholm, Sweden</addr-line>
</aff>
<aff id="aff15">
<label>15</label>
<addr-line>Department of Radio and Space Science, Chalmers University of Technology, Göteborg, Sweden</addr-line>
</aff>
<aff id="aff16">
<label>16</label>
<addr-line>Picomole Instruments Inc., Edmonton, Alberta, Canada</addr-line>
</aff>
<aff id="aff17">
<label>17</label>
<addr-line>now at: Institutionen för Rymdvetenskap, Lule&amp;aring; Tekniska Universitet, Kiruna, Sweden</addr-line>
</aff>
<pub-date pub-type="epub">
<day>04</day>
<month>03</month>
<year>2008</year>
</pub-date>
<volume>8</volume>
<issue>2</issue>
<fpage>4499</fpage>
<lpage>4559</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2008 M. R. Carleer et al.</copyright-statement>
<copyright-year>2008</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Generic License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by-nc-sa/2.5/">https://creativecommons.org/licenses/by-nc-sa/2.5/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://acp.copernicus.org/preprints/8/4499/2008/acpd-8-4499-2008.html">This article is available from https://acp.copernicus.org/preprints/8/4499/2008/acpd-8-4499-2008.html</self-uri>
<self-uri xlink:href="https://acp.copernicus.org/preprints/8/4499/2008/acpd-8-4499-2008.pdf">The full text article is available as a PDF file from https://acp.copernicus.org/preprints/8/4499/2008/acpd-8-4499-2008.pdf</self-uri>
<abstract>
<p>The Atmospheric Chemistry Experiment (ACE) mission was
launched in August 2003 to sound the atmosphere by solar occultation. Water
vapour (H&lt;sub&gt;2&lt;/sub&gt;O), one of the most important molecules for climate and
atmospheric chemistry, is one of the key species provided by the two
principal instruments, the infrared Fourier Transform Spectrometer (ACE-FTS)
and the MAESTRO UV-Visible spectrometer (ACE-MAESTRO). The first instrument
performs measurements on several lines in the 1362&amp;ndash;2137 cm&lt;sup&gt;&amp;minus;1&lt;/sup&gt; range,
from which vertically resolved H&lt;sub&gt;2&lt;/sub&gt;O concentration profiles are
retrieved, from 7 to 90 km altitude. ACE-MAESTRO measures profiles using the
water absorption band in the near infrared part of the spectrum at
926.0&amp;ndash;969.7 nm. This paper presents a comprehensive validation of the
ACE-FTS profiles. We have compared the H&lt;sub&gt;2&lt;/sub&gt;O volume mixing ratio profiles
with space-borne (SAGE II, HALOE, POAM III, MIPAS, SMR) observations and
measurements from balloon-borne frostpoint hygrometers and a ground based
lidar. We show that the ACE-FTS measurements provide H&lt;sub&gt;2&lt;/sub&gt;O profiles with
small retrieval uncertainties in the stratosphere (better than 5% from 15
to 70 km, gradually increasing above). The situation is unclear in the upper
troposphere, due mainly to the high variability of the water vapour volume
mixing ratio in this region. A new water vapour data product from the
ACE-MAESTRO (Measurement of Aerosol Extinction in the Stratosphere and
Troposphere Retrieved by Occultation) is also presented and initial
comparisons with ACE-FTS are discussed.</p>
</abstract>
<counts><page-count count="61"/></counts>
</article-meta>
</front>
<body/>
<back>
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