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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACPD</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics Discussions</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACPD</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">Atmos. Chem. Phys. Discuss.</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7375</issn>
<publisher><publisher-name></publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acpd-4-71-2004</article-id>
<title-group>
<article-title>Sources and distribution of trace species in Alpine precipitation inferred from two 60-year ice core paleorecords</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Eichler</surname>
<given-names>A.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Schwikowski</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Furger</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Schotterer</surname>
<given-names>U.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Gäggeler</surname>
<given-names>H. W.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Paul Scherrer Institute, CH-5232 Villigen PSI, Switzerland</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, CH-3012 Bern, Switzerland</addr-line>
</aff>
<pub-date pub-type="epub">
<day>07</day>
<month>01</month>
<year>2004</year>
</pub-date>
<volume>4</volume>
<issue>1</issue>
<fpage>71</fpage>
<lpage>108</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2004 A. Eichler et al.</copyright-statement>
<copyright-year>2004</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Generic License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by-nc-sa/2.5/">https://creativecommons.org/licenses/by-nc-sa/2.5/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://acp.copernicus.org/preprints/4/71/2004/acpd-4-71-2004.html">This article is available from https://acp.copernicus.org/preprints/4/71/2004/acpd-4-71-2004.html</self-uri>
<self-uri xlink:href="https://acp.copernicus.org/preprints/4/71/2004/acpd-4-71-2004.pdf">The full text article is available as a PDF file from https://acp.copernicus.org/preprints/4/71/2004/acpd-4-71-2004.pdf</self-uri>
<abstract>
<p>The Alps represent the largest barrier to meridional air flow in Europe,
      strongly influencing the weather and hence the distribution of atmospheric
      trace components. Here for the first time, chemical records from two ice cores retrieved from glaciers located in the northern and southern Swiss
      Alps were compared in conjunction with an analysis of &amp;quot;weather
      type&amp;quot;, in order to assess geographical and seasonal trends in the deposition of trace
      species and to identify source regions and transport patterns.&lt;br&gt;
      &lt;br&gt;
      Using a correlation analysis, investigated trace species (NH&lt;sub&gt;4&lt;/sub&gt;&lt;sup&gt;+&lt;/sup&gt;,
      NO&lt;sub&gt;3&lt;/sub&gt;&lt;sup&gt;&amp;minus;&lt;/sup&gt;, SO&lt;sub&gt;4&lt;/sub&gt;&lt;sup&gt;2&amp;minus;&lt;/sup&gt;, Ca&lt;sup&gt;2+&lt;/sup&gt;,
      Mg&lt;sup&gt;2+&lt;/sup&gt;, Na&lt;sup&gt;+&lt;/sup&gt;, K&lt;sup&gt;+&lt;/sup&gt;, and Cl&lt;sup&gt;&amp;minus;&lt;/sup&gt; were grouped into classes of different origin (anthropogenic,
      sea salt, or Saharan dust). Over the last 60 years, precipitation chemistry
      at both sites was dominated by NH&lt;sub&gt;4&lt;/sub&gt;&lt;sup&gt;+&lt;/sup&gt;, NO&lt;sub&gt;4&lt;/sub&gt;&lt;sup&gt;&amp;minus;&lt;/sup&gt;, and
      SO&lt;sub&gt;4&lt;/sub&gt;&lt;sup&gt;2&amp;minus;&lt;/sup&gt;, all of anthropogenic origin and deposited mainly in summer
      by way of convective precipitation. The similarity of the SO&lt;sub&gt;4&lt;/sub&gt;&lt;sup&gt;2&amp;minus;&lt;/sup&gt;
      profiles with historical records of SO&lt;sub&gt;4&lt;/sub&gt; emissions from France and Italy
      indicated these two countries as key source areas for the anthropogenic species.&lt;br&gt;
      &lt;br&gt;
      In contrast, sea salt and Saharan dust showed major differences in transport
      pattern and deposition across the Alps. Currently, the sea-salt constituents
      Na&lt;sup&gt;+&lt;/sup&gt;, K&lt;sup&gt;+&lt;/sup&gt;, and Cl&lt;sup&gt;&amp;minus;&lt;/sup&gt; are transported to the northern site during
      advective westerly-wind situations, independent of Saharan dust events. At
      the southern site, sea salt and Saharan dust are deposited simultaneously,
      indicating a coupled transport active mainly in summer during south-westerly
      wind situations.</p>
</abstract>
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