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<front>
<journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">Atmos. Chem. Phys.</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>
<article-meta>
<article-id pub-id-type="doi">10.5194/acp-9-1209-2009</article-id>
<title-group>
<article-title>Transport mechanisms for synoptic, seasonal and interannual SF&lt;sub&gt;6&lt;/sub&gt; variations and &quot;age&quot; of air in troposphere</article-title>
</title-group>
<contrib-group><contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Patra</surname>
<given-names>P. K.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Takigawa</surname>
<given-names>M.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Dutton</surname>
<given-names>G. S.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Uhse</surname>
<given-names>K.</given-names>
</name>
<xref ref-type="aff" rid="aff3">
<sup>3</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Ishijima</surname>
<given-names>K.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Lintner</surname>
<given-names>B. R.</given-names>
</name>
<xref ref-type="aff" rid="aff4">
<sup>4</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Miyazaki</surname>
<given-names>K.</given-names>
</name>
<xref ref-type="aff" rid="aff1">
<sup>1</sup>
</xref>
</contrib>
<contrib contrib-type="author" xlink:type="simple"><name name-style="western"><surname>Elkins</surname>
<given-names>J. W.</given-names>
</name>
<xref ref-type="aff" rid="aff2">
<sup>2</sup>
</xref>
</contrib>
</contrib-group><aff id="aff1">
<label>1</label>
<addr-line>Frontier Research Center for Global Change, JAMSTEC, Yokohama 236 001, Japan</addr-line>
</aff>
<aff id="aff2">
<label>2</label>
<addr-line>NOAA Earth System Research Laboratory, Boulder, CO 80305, USA</addr-line>
</aff>
<aff id="aff3">
<label>3</label>
<addr-line>Umweltbundesamt – Federal Environment Agency, 63225 Langen, Germany</addr-line>
</aff>
<aff id="aff4">
<label>4</label>
<addr-line>Department of Atmospheric and Oceanic Sciences and Institute of Geophysics and Planetary Physics, University of California Los Angeles, Los Angeles, CA 90095-1565, USA</addr-line>
</aff>
<pub-date pub-type="epub">
<day>17</day>
<month>02</month>
<year>2009</year>
</pub-date>
<volume>9</volume>
<issue>4</issue>
<fpage>1209</fpage>
<lpage>1225</lpage>
<permissions>
<copyright-statement>Copyright: &#x000a9; 2009 P. K. Patra et al.</copyright-statement>
<copyright-year>2009</copyright-year>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 3.0 Unported License. To view a copy of this licence, visit <ext-link ext-link-type="uri"  xlink:href="https://creativecommons.org/licenses/by/3.0/">https://creativecommons.org/licenses/by/3.0/</ext-link></license-p>
</license>
</permissions>
<self-uri xlink:href="https://acp.copernicus.org/articles/9/1209/2009/acp-9-1209-2009.html">This article is available from https://acp.copernicus.org/articles/9/1209/2009/acp-9-1209-2009.html</self-uri>
<self-uri xlink:href="https://acp.copernicus.org/articles/9/1209/2009/acp-9-1209-2009.pdf">The full text article is available as a PDF file from https://acp.copernicus.org/articles/9/1209/2009/acp-9-1209-2009.pdf</self-uri>
<abstract>
<p>We use an atmospheric general circulation model (AGCM) driven chemistry-transport
model (ACTM) to simulate the evolution of sulfur hexafluoride (SF&lt;sub&gt;6&lt;/sub&gt;) in the
troposphere. The model results are compared with continuous measurements at 6
sites over 71&amp;deg; N–90&amp;deg; S. These comparisons demonstrate that the
ACTM simulations lie within the measurement uncertainty over the analysis
period (1999–2006) and capture salient features of synoptic, seasonal and
interannual SF&lt;sub&gt;6&lt;/sub&gt; variability. To understand transport timescales of SF&lt;sub&gt;6&lt;/sub&gt;
within the troposphere, transport times of air parcels from the
surface to different regions of the troposphere (&quot;age&quot;) are estimated from a
simulation of an idealized tracer. The age estimation error and its sensitivity
to the selection of reanalysis meteorology for ACTM nudging or the tracer
transport by deep cumulus convection as represented in the model are discussed.
Monthly-mean, 2-box model exchange times
(&amp;tau;&lt;sub&gt;&lt;i&gt;ex&lt;/i&gt;&lt;/sub&gt;) are calculated from both the observed and simulated SF&lt;sub&gt;6&lt;/sub&gt; time
series at the 6 observing sites and show favorable agreement, suggesting that
the ACTM adequately represents large-scale interhemispheric transport. The
simulated SF&lt;sub&gt;6&lt;/sub&gt; variability is further investigated through decomposition of
the mixing ratio time-tendency into advective, convective, and vertical
diffusive components. The transport component analysis illustrates the role of
each process in SF&lt;sub&gt;6&lt;/sub&gt; synoptic variability at the site level and provides
insight into the seasonality of &amp;tau;&lt;sub&gt;&lt;i&gt;ex&lt;/i&gt;&lt;/sub&gt;.</p>
</abstract>
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