References

ACP

Atmospheric Chemistry and Physics

ACP

Atmos. Chem. Phys.

1680-7324

Copernicus Publications

Göttingen, Germany

10.5194/acp-7-2705-2007

Sub-micron atmospheric aerosols in the surroundings of Marseille and Athens: physical characterization and new particle formation

Petäjä

¹ Kerminen

V.-M.

² Dal Maso

¹ Junninen

¹ Koponen

I. K.

³ ¹ Hussein

⁴ ¹ Aalto

P. P.

¹ Andronopoulos

⁵ Robin

⁶ Hämeri

⁷ ¹ Bartzis

J. G.

⁵ ⁸ Kulmala

Division of Atmospheric Sciences, Dept. of Physical Sciences, University of Helsinki, Finland

Finnish Meteorological Institute, Climate and Global Change, Helsinki, Finland

Department of Chemistry, University of Copenhagen, Denmark

Dept. of Applied Environmental Sciences (ITM), Stockholm University, Stockholm, Sweden

National Centre for Scientific Research "Demokritos", Athens, Greece

AIRMARAIX, Marseille, France

Finnish Institute of Occupational Health, Helsinki, Finland

Department of Engineering and Management of Energy Resources, University of West Macedonia, Kozani, Greece

23 05 2007

7 10 2705 2720

2007

This work is licensed under the Creative Commons Attribution-NonCommercial-ShareAlike 2.5 Generic License. To view a copy of this licence, visit https://creativecommons.org/licenses/by-nc-sa/2.5/

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The full text article is available as a PDF file from https://acp.copernicus.org/articles/7/2705/2007/acp-7-2705-2007.pdf

The properties of atmospheric aerosol particles in Marseille and Athens were investigated. The studies were performed in Marseille, France, during July 2002 and in Athens, Greece, during June 2003. The aerosol size distribution and the formation and growth rates of newly formed particles were characterized using Differential Mobility Particle Sizers. Hygroscopic properties were observed using a Hygroscopic Tandem Differential Mobility Analyzer setup. During both campaigns, the observations were performed at suburban, almost rural sites, and the sites can be considered to show general regional background behavior depending on the wind direction. At both sites there were clear pattern for both aerosol number concentration and hygroscopic properties. Nucleation mode number concentration increased during the morning hours indicating new particle formation, which was observed during more than 30% of the days. The observed formation rate was typically more than 1 cm−3 s−1, and the growth rate was between 1.2–9.9 nm h−1. Based on hygroscopicity measurements in Athens, the nucleation mode size increase was due to condensation of both water insoluble and water soluble material. However, during a period of less anthropogenic influence, the growth was to a larger extent due to water insoluble components. When urban pollution was more pronounced, growth due to condensation of water soluble material dominated.

References 1

Aalto, P., Hämeri, K., Becker, E., Weber, R., Salm, J., Mäkelä, J M., Hoell, C., O'Dowd, C D., Karlsson, H., Hansson, H.-C., Väkevä, M., Koponen, I K., Buzorius, G., and Kulmala, M.: Physical characterization of aerosol particles during nucleation events, Tellus, 53B, 344–358, 2001.

Aklilu, Y. and Mozurkewich, M.: Determination of external and internal mixing of organic and inorganic aerosol components from hygroscopic properties of submicrometer particles during a field study in the Lower Fraser Valley, Aerosol Sci. Technol., 38, 140-154, 2004.

Baron, P. and Willeke, K.: Aerosol Measurement: Principles, Techniques, and Applications, 2nd edition, John Wiley and Sons, 2001.

Bastin, S., Drobinski, P., Dabas, A., Delville, P., Reitebuch, O., and Werner, C.: Impact of the Rh\^one and Durance valleys on sea-breeze circulation in the Marseille area, Atmos. Res., 74, 303–328, 2005.

Bilde, M. and Svenningsson, B.: CCN activation of slightly soluble organics: the importance of small amounts of inorganic salt and particle phase, Tellus, 56B, 128–134, 2004.

Boy, M., Kulmala, M., Ruuskanen, T. M., Pihlatie, M., Reissell, A., Aalto, P. P., Keronen, P., Dal Maso, M., Hellen, H., Hakola, H., Janson, R., Hanke, M., and Arnold, F.: Sulphuric acid closure and contribution to nucleation mode particle growth, Atmos. Chem. Phys., 5, 863–878, 2005.

Brunekreef, B. and Holgate, S.: Air pollution and health, The Lancet, 360, 1233–1242, 2002.

Cabada, J., Khlystov, A., Wittig, A., Pilinis, C., and Pandis, S.: Light scattering by fine particles during the Pittsburgh Air Quality Study: Measurements and modeling, J. Geophys. Res., 109, D16S03, https://doi.org/10.1029/2003JD004155, 2004.

Cachier, H., Aulagnier, F., Sarda, R., Gautier, F., Masclet, P., Besombes, J.-L., Marchand, N., Despiau, S., Croci, D., Mallet, M., Laj, P., Marinoni, A., Deveau, P.-A., Roger, J.-C., Putaud, J.-P., Van Dingenen, R., Dell'Acqua, A., Viidanoja, J., Martins-Dos Santos, S., Liousse, C., Cousin, F., Rosset, R., Gardrat, E., and Galy-Lacaux, C.: Aerosol studies during the ESCOMPTE: an overview, Atmos. Res., 74, 547–563, 2005.

Carrico, C., Kreidenweis, S., Malm, W., Day, D., Lee, T., Carillo, J., McMeeking, G., and Collett Jr., J.: Hygroscopic growth behavior of a carbon-dominated aerosol in Yosemite National Park, Atmos. Environ., 39, 1393–1404, 2005.

Chaloulakou, A., Kassomenos, P., Spyrellis, N., Demokritou, P., and Koutrakis, P.: Measurements of PM$_10$ and PM$_2.5$ particle concentrations in Athens, Greece, Atmos. Environ., 37, 649–660, 2003.

Colbeck, I., Chung, M. C., and Eleftheriadis, K.: Formation and transport of atmospheric aerosol over Athens, Greece, Water Air Soil Pollut. Focus, 2, 223–235, 2002.

Corsmeier, U., Behrendt, R., Drobinski, P., and Kottmeier, C.: The mistral and its effects on air pollution transport and vertical mixing, Atmos. Res., 74, 275–302, 2005.

Cros, B., Durand, P., Cachier, H., Drobinski, P., Frejafon, E., Kottmeier, C., Perros, P., Peuch, V.-H., Ponche, J.-L., Robin, D., Said, F., Toupance, G., and Wortham, H.: The ESCOMPTE program: an overview, Atmos. Res., 69, 241–279, 2004.

Dal Maso, M., Kulmala, M., Riipinen, I., Wagner, R., Hussein, T., Aalto, P., and Lehtinen, K.: Formation and growth of fresh atmospheric aerosols: Eight Years of Aerosol Size Distribution Data from SMEAR II, Hyytiälä, Finland, Boreal Environ. Res., 10, 323–336, 2005.

Draxler, R. and Rolph, G.: HYSPLIT (HYsplit Single-Particle Lagrangian Intregrated Trajectory) model, Website (http://www.arl.noaa.gov/ready/hysplit4.html), NOAA Air Resources Laboratory, Silver Spring, MD., USA, 2003.

Flocas, H., Assimakopoulos, V., Helmis, C., and Güsten, H.: VOC and O3 distributions over the densely populated area of greater Athens, Greece, J. Appl. Meteorol., 42, 1799–1810, 2003.

Flocas, H., Assimakopoulos, V. D., and Helmis, C. G.: An experimental study of aerosol distribution over a Mediterranean urban area, Sci. Tot. Environ. 367, 872–887, 2006.

Grivas, G., Chaloulakou, A., Samara, C., and Spyrellis, N.: Spatial and temporal variation of PM$_10$ mass concentrations within the greater area of Athens, Greece, Water Air Soil Pollut., 158, 357–371, 2004.

Hämeri, K., Väkevä, M., Hansson, H.-C., and Laaksonen, A.: Hygroscopic growth of ultrafine ammonium sulphate aerosol measured using an ultrafine tandem differential mobility analyser., J. Geophys. Res., 105, 22 231–22 242, 2000.

Hussein, T., Dal Maso, M., Petäjä, T., Koponen, I., Paatero, P., Aalto, P., Hämeri, K., and Kulmala, M.: Evaluation of an automatic algorithm for fitting the particle number size distributions, Boreal Environ. Res., 10, 337–355, 2005.

Janhäll, S. and Hallquist, M.: A novel method for determination of size-resolved, submicrometer particle traffic emission factors, Environ. Sci. Technol., 39, 7609–7615, 2005.

Jokinen, V. and Mäkelä, J M.: Closed loop arrangement with critical orifice for DMA sheath/excess flow system, J. Aerosol Sci., 28, 643–648, 1997.

Kittelson, D., Watts, W., and Johnson, J.: Nanoparticle emissions on Minnesota highways, Atmos. Environ., 38, 9–19, 2004.

Kulmala, M., Dal Maso, M., Mäkelä, J., Pirjola, L., Väkevä, M., Aalto, P., Miikkulainen, P., Hämeri, K., and O'Dowd, C.: On the formation, growth and composition of nucleation mode particles, Tellus B, 53, 479–490, 2001.

Kulmala, M.: How particles nucleate and grow, Science, 302, 1000–1001, 2003.

Kulmala, M., Laakso, L., Lehtinen, K., Riipinen, I., Dal~Maso, M., Anttila, T., Kerminen, V.-M., H\~orrak, U., Vana, M., and Tammet, H.: Initial steps of aerosol growth, Atmos. Chem. Phys., 4, 2553–2560, 2004a.

Kulmala, M., Vehkamäki, H., Petäjä, T., Dal Maso, M., Lauri, A., Kerminen, V.-M., Birmili, W., and McMurry, P.: Formation and growth rates of ultrafine atmospheric particles: a review of observations, J. Aerosol Sci., 35, 143–176, 2004b.

Kulmala, M., Petäjä, T., Mönkkönen, P., Koponen, I., Dal Maso, M., Aalto, P., Lehtinen, K., and Kerminen, V.-M.: On the growth of nucleation mode particles: source rates of condensable vapor in polluted and clean environments, Atmos. Chem. Phys., 5, 409–416, 2005.

Laaksonen, A., Hamed, A., Joutsensaari, J., Hiltunen, L., Cavalli, F., Junkermann, W., Asmi, A., Fuzzi, S., and Facchini, M, C.: Cloud condensation nucleus production from nucleation events at a highly polluted region, Geophys. Res. Lett., 32, L06812, https://doi.org/10.1029/2004GL022092, 2005.

Marinoni, A., Laj, P., Deveaux, P., Marino, F., Ghermandi, G., Aulagnier, F., and Cachier, H.: Physicochemical properties of fine aerosols at Plan d'Aups during ESCOMPTE, Atmos. Res., 74, 565–580, 2005.

Mertes, S., Schröder, F., and Wiedensohler, A.: The particle detection efficiency curve of the TSI-3010 CPC as a function of temperature difference between saturator and condenser, Aerosol Sci. Technol., 23, 257–261, 1995.

Mönkkönen, P., Koponen, I., Lehtinen, K., Hämeri, K., Uma, R., and Kulmala, M.: Measurements in a highly polluted Asian mega city: observations of aerosol number size distribution, modal parameters and nucleation events, Atmos. Chem. Phys., 5, 57–66, 2005.

O'Dowd, C.: Biogenic coastal production and its influence on aerosol radiative properties, J. Geophys. Res., 106, 1545–1549, 2001.

Peng, C., Chan, M., and Chan, C.: The hygroscopic properties of dicarboxylic and multifunctional acids: measurements and UNIFAC predictions, Environ. Sci. Tech., 35, 4495–4501, 2001.

Putaud, J.-P., Raes, F., Van Dingenen, R., Brüggemann, E., Facchini, M.-C., Decesari, S., Fuzzi, S., Gehrg, R., Güglin, C., Laj, P., Lorbeer, G., Maenhaut, W., Mihalopoulos, N., Müller, G., Querol, X., Rodriguez, S., Schneider, J., Spindler, G., ten Brink, H., T\orseth, K., and Wiedensohler, A.: A European aerosol phenomenology – 2: chemical characteristics of particulate matter at kerbside, urban, rural and background sites in Europe, Atmos. Environ., 38, 2579–2995, 2004.

Rader, D J. and McMurry, P H.: Application of the tandem differential mobility analyzer to studies of droplet growth or evaporation, J. Aerosol. Sci., 28, 771–787, 1986.

Rolph, G.: Real-time Environmental Applications and Display sYstem (READY), Website (http://www.arl.noaa.gov/ready/, NOAA Air Resources Laboratory, Silver Spring, MD., USA, 2003.

Sotiropoulou, R., Tagaris, E., Pilinis, C., Andronopoulos, S., Sfetsos, A., and Bartzis, J. The BOND project: Biogenic aerosols and air quality in Athens and Marseille greater areas, J. Geophys. Res., 109, D05205, https://doi.org/10.1029/2003JD003955, 2004.

Stier, P., Feichter, J., Kinne, S., Kloster, S., Vignati, E., Wilson, J., Ganzeveld, L., Tegen, I., Werner, M., Balkanski, Y., Schultz, M., Boucher, O., Minikin, A., and Petzold, A.: The aerosol-climate model ECHAM5-HAM, Atmos. Chem. Phys., 5, 1125–1156, 2005.

Stolzenburg, M. and McMurry, P.: An ultrafine aerosol condensation nucleus counter, Aerosol Sci. Technol., 14, 48–65, 1991.

Stolzenburg, M R.: An ultrafine aerosol size distribution measuring system, Ph. D. Thesis, University of Minnesota, 1988.

Stolzenburg, M., McMurry, P., Sakurai, H., Smith, J., Mauldin, R., Eisele, F., and Clement, C.: Growth rates of freshly nucleated atmospheric particles in Atlanta, J. Geophys. Res., 110, D22S05, https://doi.org/10.1029/2005JD005935, 2005.

Swietlicki, E., Zhou, J., Berg, O H., Martinsson, B G., Frank, G., Cederfelt, S I., Dusek, U., Berner, A., Birmili, W., Wiedensohler, A., Yuskiewicz, B., and Bower, K N.: A closure study of sub-micrometer aerosol particle hygroscopic behaviour, Atmos. Res., 50, 205–240, 1999.

Tunved, P., Hansson, H.-C., Kerminen, V.-M., Strom, J., M., D., Lihavainen, H., Viisanen, Y., Aalto, P., Komppula, M., and Kulmala, M.: High natural aerosol loading over boreal forests, Science, 312, 261–263, 2006.

Van Dingenen, R., Raes, F., Putaud, J.-P., Baltensperger, U., Charron, A., Facchini, M.-C., Decesari, S., Fuzzi, S., Gehrig, R., Hansson, H.-C., Harrison, R M., Hüglin, C., Jones, A., Laj, P., Lorbeer, G., Maenhaut, W., Palmgren, F., Querol, X., Rodriguez, S., Schneider, J., ten Brink, H., Tunved, P., T\orseth, K., Wehner, B., Weingartner, E., Wiedensohler, A., and W\aahlin, P.: A European aerosol phenomenology – I: physical characteristics of particulate matter at kerbside, urban, rural and background sites in Europe, Atmos. Environ., 38, 2561–2577, 2004.

Van Dingenen, R., Putaud, J.-P., Martins-Dos Santos, S., and Raes, F.: Physical aerosol properties and their relation to air mass origin at Monte Cimone (Italy) during the first MINATROC campaign, Atmos. Chem. Phys., 5, 2203–2226, 2005.

Virkkula, A., Van~Dingenen, R., Raes, F., and Hjort, J.: Hygroscopic properties of aerosol formed by oxidation of limonene, alpha-pinene, and beta-pinene., J. Geophys. Res., 104, 3569–3579, 1999.

Von Klot, S., Peters, A., Aalto, P., Bellander, T., Berglind, N., D'Ippoliti, D., Elosua, R., Hörmann, A., Kulmala, M., Lanki, T., Löwel, H., Pekkanen, J., Picciotto, S., Sunyer, J., Forastriere, F., and the HEAPSS~study group: Ambient air pollution is associated with increased risk of hospital cardiac readmission of myocardial infarction survivors in five European cities, Circulation, 112, 3073–3079, 2005.

Väkevä, M., Kulmala, M., Stratmann, F., and Hämeri, K.: Field measurements of hygroscopic properties and state of mixing of nucleation mode particles, Atmos. Chem. Phys., 2, 55–66, 2002.

Wiedensohler, A.: An approximation of the bipolar charge distribution for particles in the submicron range, J. Aerosol Sci., 19, 387–389, 1988.

Winklmayr, W., Reischl, G., Lindner, A., and Berner, A.: A new electromobility spectrometer for the measurement of aerosol size distributions in the size range from 1 to 1000 nm, J. Aerosol Sci., 22, 289–296, 1991.