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<!DOCTYPE article PUBLIC "-//NLM//DTD Journal Publishing with OASIS Tables v3.0 20080202//EN" "https://jats.nlm.nih.gov/nlm-dtd/publishing/3.0/journalpub-oasis3.dtd">
<article xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:oasis="http://docs.oasis-open.org/ns/oasis-exchange/table" xml:lang="en" dtd-version="3.0" article-type="research-article">
  <front>
    <journal-meta><journal-id journal-id-type="publisher">ACP</journal-id><journal-title-group>
    <journal-title>Atmospheric Chemistry and Physics</journal-title>
    <abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">Atmos. Chem. Phys.</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">1680-7324</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/acp-26-9337-2026</article-id><title-group><article-title>The remarkable inefficiency of stratocumulus</article-title><alt-title>The remarkable inefficiency of stratocumulus</alt-title>
      </title-group>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1">
          <name><surname>Hernandez</surname><given-names>Benjamin</given-names></name>
          <email>b.hernandez-2@tudelft.nl</email>
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Singh</surname><given-names>Martin S.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-4584-0885</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3 aff4">
          <name><surname>Yamaguchi</surname><given-names>Takanobu</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff4">
          <name><surname>Feingold</surname><given-names>Graham</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-0774-2926</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1 aff5">
          <name><surname>Glassmeier</surname><given-names>Franziska</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-1132-7821</ext-link></contrib>
        <aff id="aff1"><label>1</label><institution>Geoscience and Remote Sensing, Delft University of Technology, Delft, the Netherlands</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>School of Earth, Atmosphere, and Environment, Monash University, Melbourne, Australia</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, Colorado, USA</institution>
        </aff>
        <aff id="aff4"><label>4</label><institution>Chemical Sciences Laboratory, NOAA, Boulder, Colorado, USA</institution>
        </aff>
        <aff id="aff5"><label>5</label><institution>Max Planck Institute for Meteorology, Hamburg, Germany</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Benjamin Hernandez (b.hernandez-2@tudelft.nl)</corresp></author-notes><pub-date><day>2</day><month>July</month><year>2026</year></pub-date>
      
      <volume>26</volume>
      <issue>13</issue>
      <fpage>9337</fpage><lpage>9356</lpage>
      <history>
        <date date-type="received"><day>17</day><month>February</month><year>2026</year></date>
           <date date-type="rev-request"><day>4</day><month>March</month><year>2026</year></date>
           <date date-type="rev-recd"><day>15</day><month>June</month><year>2026</year></date>
           <date date-type="accepted"><day>17</day><month>June</month><year>2026</year></date>
      </history>
      <permissions>
        <copyright-statement>Copyright: © 2026 Benjamin Hernandez et al.</copyright-statement>
        <copyright-year>2026</copyright-year>
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://acp.copernicus.org/articles/26/9337/2026/acp-26-9337-2026.html">This article is available from https://acp.copernicus.org/articles/26/9337/2026/acp-26-9337-2026.html</self-uri><self-uri xlink:href="https://acp.copernicus.org/articles/26/9337/2026/acp-26-9337-2026.pdf">The full text article is available as a PDF file from https://acp.copernicus.org/articles/26/9337/2026/acp-26-9337-2026.pdf</self-uri>
      <abstract><title>Abstract</title>

      <p id="d2e147">Marine stratocumulus clouds play a central role in Earth's climate system by reflecting incoming solar radiation and exerting a strong cooling effect. Their organization into open and closed mesoscale cellular morphologies can be thought of as an example of bistable dynamics driven by aerosol–cloud interactions and mesoscale processes. From the perspective of non-equilibrium thermodynamics, these structures are an example of a far-from-equilibrium open system that continuously produces and exports entropy. While entropy production has been studied in idealized deep convective systems, it has not yet been quantified for shallow clouds. Here, we compute and decompose the internal entropy production of open- and closed-cell stratocumulus using an ensemble of large-eddy simulations. We show that the overall entropy production of stratocumulus is low, reflecting the limited vertical extent and corresponding reduced ability to utilize the energy fluxes at the system's boundaries. Moist processes dominate the overall irreversibility, which, combined with their low entropy production, leads to a mechanical efficiency about an order of magnitude smaller than in deep convective systems. Although the dominant irreversible processes differ between open- and closed-cell regimes, the distributions of total entropy production largely overlap across the ensemble, limiting the ability to distinguish the dynamics of individual cases based solely on total entropy production.</p>
  </abstract>
    
<funding-group>
<award-group id="gs1">
<funding-source>European Research Council</funding-source>
<award-id>101117462</award-id>
</award-group>
<award-group id="gs2">
<funding-source>Branco Weiss Fellowship – Society in Science</funding-source>
<award-id>n/a</award-id>
</award-group>
<award-group id="gs3">
<funding-source>Australian Research Council</funding-source>
<award-id>CE230100012</award-id>
<award-id>DP230102077</award-id>
</award-group>
<award-group id="gs4">
<funding-source>U.S. Department of Energy</funding-source>
<award-id>89243023SSC000114</award-id>
</award-group>
<award-group id="gs5">
<funding-source>U.S. Department of Commerce</funding-source>
<award-id>03-01-07-001</award-id>
<award-id>NA22OAR4320151</award-id>
</award-group>
</funding-group>
</article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <label>1</label><title>Introduction</title>
      <p id="d2e159">Covering roughly a quarter of the oceans, marine stratocumulus clouds are the most common cloud type by area and exert a strong cooling effect by efficiently reflecting incoming solar radiation <xref ref-type="bibr" rid="bib1.bibx22 bib1.bibx64" id="paren.1"/>. Stratocumulus often self-organize into striking mesoscale cellular patterns in two distinct configurations. Closed cells have cloudy interiors and narrow, cloud-free edges. They are primarily driven by cloud-top radiative cooling and are generally associated with minimal precipitation, representing a top-down driven convective regime <xref ref-type="bibr" rid="bib1.bibx40 bib1.bibx61" id="paren.2"><named-content content-type="pre">e.g.</named-content></xref>. In contrast, open cells appear as the inverse pattern, with cloud-free interiors surrounded by cloudy edges. These are maintained by cold-pool dynamics and feature light localized drizzle <xref ref-type="bibr" rid="bib1.bibx60 bib1.bibx69 bib1.bibx38 bib1.bibx71" id="paren.3"/>. It has been hypothesized that these morphologies may represent two dynamically stable states of mesoscale organization within the coupled aerosol-cloud-precipitation system, mostly distinguished by their low (open cells) or high (closed cells) cloud droplet number concentration <xref ref-type="bibr" rid="bib1.bibx5 bib1.bibx37 bib1.bibx20" id="paren.4"/>.</p>
      <p id="d2e176">Since the cloud fraction and scene albedo of open and closed cells are so different, Earth's energy budget is highly sensitive to the balance between these different morphologies within the climate system. Understanding how and why stratocumulus clouds self-organize is therefore crucial to reducing uncertainties in climate sensitivity and magnitude of transient warming of the climate in the 21st century <xref ref-type="bibr" rid="bib1.bibx3 bib1.bibx44 bib1.bibx6" id="paren.5"/>.</p>
      <p id="d2e182">Unfortunately, stratocumulus remain notoriously difficult to model. Their shallow vertical extent and sharp inversions demand very high vertical resolution <xref ref-type="bibr" rid="bib1.bibx67" id="paren.6"/>, while their cold-pool dynamics are highly sensitive to horizontal grid spacing <xref ref-type="bibr" rid="bib1.bibx26 bib1.bibx14" id="paren.7"/>. Furthermore, their apparent bistable dynamics are caused by processes operating on a wide range of scales, from collision-coalescence efficiencies at the microphysical level <xref ref-type="bibr" rid="bib1.bibx2" id="paren.8"/> to cloud-top cooling and entrainment at the single cloud and mesoscale level <xref ref-type="bibr" rid="bib1.bibx29" id="paren.9"/>. Despite these challenges, Large Eddy Simulations (LES) have proven increasingly capable of reproducing the key features of stratocumulus regimes, including their mesoscale cellular organization and temporal evolution <xref ref-type="bibr" rid="bib1.bibx66 bib1.bibx13 bib1.bibx27" id="paren.10"/>.</p>
      <p id="d2e200">From a statistical physics perspective, the marine stratocumulus-topped boundary layer represents a non-equilibrium open system, with continuous exchanges of mass and energy at its boundaries. At the surface, latent heat is exchanged through evaporation and precipitation, while sensible heat is transferred by turbulent mixing. Above the inversion layer, subsidence and entrainment drive substantial energy and mass fluxes, and strong radiative cooling dominates energy loss <xref ref-type="bibr" rid="bib1.bibx70 bib1.bibx28" id="paren.11"/>.</p>
      <p id="d2e207">A defining feature of non-equilibrium systems is their continuous production of entropy sustained by continuous energy exchange with the environment. In the marine stratocumulus-topped boundary layer, high-quality energy enters at the ocean surface and exits at the colder cloud top as degraded energy. This thermodynamic quality gap, induced by differences in absolute temperature, drives the system's entropy dissipation, which in turn enables self-organization <xref ref-type="bibr" rid="bib1.bibx56 bib1.bibx15" id="paren.12"/>. Studying how entropy is produced and exported can provide a way to understand the emergent complexity and dynamical organization of the system.</p>
      <p id="d2e213">Entropy production was first examined at the scale of the climate system as a whole <xref ref-type="bibr" rid="bib1.bibx48 bib1.bibx65 bib1.bibx42 bib1.bibx39 bib1.bibx17 bib1.bibx33" id="paren.13"/>. In the early 2000s, Pauluis and Held analyzed convective systems using idealized Radiative-Convective Equilibrium (RCE) simulations, decomposing the entropy budget into its components and linking them to physically meaningful processes such as updraft strength and convective activity <xref ref-type="bibr" rid="bib1.bibx51 bib1.bibx52" id="paren.14"/>. They showed how, for moist convection, most of the irreversibility is attributed to processes involving water (such as diffusion of water vapor, irreversible phase-changes and drag on hydrometeors) rather than turbulent dissipation. Subsequent studies have expanded this framework, applying it to both idealized RCE <xref ref-type="bibr" rid="bib1.bibx58 bib1.bibx62 bib1.bibx63" id="paren.15"/> and to extreme events such as tropical cyclones <xref ref-type="bibr" rid="bib1.bibx46 bib1.bibx53 bib1.bibx12 bib1.bibx59" id="paren.16"/>.</p>
      <p id="d2e228">In this study, we quantify and analyze the entropy production in stratocumulus clouds, focusing on the closed and open cell morphologies. Using an ensemble of LES that resolve the bistable nature of stratocumulus, we examine not only the total magnitude of entropy production but also its decomposition into physically meaningful contributions. This framework allows us to examine how entropy production differs between open and closed cells, whether the dominant processes contributing to it change across regimes, and whether these differences help explain the system's tendency to organize into one state or the other. We also examine the thermodynamic constraints on stratocumulus clouds relative to deeper convective systems studied in RCE, focusing on their efficiency in driving atmospheric convection.</p>
</sec>
<sec id="Ch1.S2">
  <label>2</label><title>Mathematical formulation</title>
      <p id="d2e239">For an open system, such as the atmospheric boundary layer, it is possible to express the total entropy <inline-formula><mml:math id="M1" display="inline"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mtext>tot</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> tendency as <xref ref-type="bibr" rid="bib1.bibx8" id="paren.17"/>

              <disp-formula id="Ch1.E1" content-type="numbered"><label>1</label><mml:math id="M2" display="block"><mml:mstyle class="stylechange" displaystyle="true"/><mml:mrow><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mi mathvariant="normal">d</mml:mi><mml:msub><mml:mi>S</mml:mi><mml:mtext>tot</mml:mtext></mml:msub></mml:mrow><mml:mrow><mml:mi mathvariant="normal">d</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mi mathvariant="normal">d</mml:mi><mml:msub><mml:mi>S</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mi mathvariant="normal">d</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>+</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mi mathvariant="normal">d</mml:mi><mml:msub><mml:mi>S</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mi mathvariant="normal">d</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle></mml:mrow></mml:math></disp-formula>

        where <inline-formula><mml:math id="M3" display="inline"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M4" display="inline"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> represent, respectively, the entropy produced inside the system and exported at the boundary. Here and in the following, <inline-formula><mml:math id="M5" display="inline"><mml:mi>S</mml:mi></mml:math></inline-formula> denotes the entropy (<inline-formula><mml:math id="M6" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">J</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">K</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>), while <inline-formula><mml:math id="M7" display="inline"><mml:mi>s</mml:mi></mml:math></inline-formula> represents the specific entropy (<inline-formula><mml:math id="M8" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">J</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">K</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">kg</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>).</p>
      <p id="d2e392">The second law of thermodynamics for an open system may be applied to the internal production, and reads

              <disp-formula id="Ch1.E2" content-type="numbered"><label>2</label><mml:math id="M9" display="block"><mml:mstyle class="stylechange" displaystyle="true"/><mml:mrow><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mi mathvariant="normal">d</mml:mi><mml:msub><mml:mi>S</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mi mathvariant="normal">d</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>≥</mml:mo><mml:mn mathvariant="normal">0</mml:mn><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula></p>
      <p id="d2e422">Equation (<xref ref-type="disp-formula" rid="Ch1.E1"/>) is the most general formulation of an entropy budget. The challenge is now to dissect all the components related to each term, in order to understand how the system distributes dissipation between different processes. For our analysis, we choose to adopt the material system view, which considers radiation simply as a <italic>reversible</italic> external source of heat, meaning that the entropic contribution from the interaction between photons and matter will not be taken into account. Not including radiation in the internal production allows one to focus on the water cycle and fluid dynamical processes <xref ref-type="bibr" rid="bib1.bibx63" id="paren.18"/>. In particular, this translates into considering radiative cooling simply as an external heat sink for the system.</p>
      <p id="d2e433">For a mixture of ideal gases heated reversibly by radiation, we may write a local entropy budget for the fluid as <xref ref-type="bibr" rid="bib1.bibx63" id="paren.19"/>,

              <disp-formula specific-use="align" content-type="numbered"><mml:math id="M10" display="block"><mml:mtable displaystyle="true"><mml:mtr><mml:mtd><mml:mstyle class="stylechange" displaystyle="true"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mo>∂</mml:mo><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi>s</mml:mi></mml:mrow><mml:mrow><mml:mo>∂</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>+</mml:mo><mml:mi mathvariant="bold">∇</mml:mi><mml:mo>⋅</mml:mo><mml:mo>(</mml:mo><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="bold-italic">v</mml:mi><mml:mi>s</mml:mi><mml:mo>)</mml:mo><mml:mo>+</mml:mo><mml:mi mathvariant="bold">∇</mml:mi><mml:mo>⋅</mml:mo><mml:mfenced open="(" close=")"><mml:mrow><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">u</mml:mi></mml:msub></mml:mrow><mml:mi>T</mml:mi></mml:mfrac></mml:mstyle><mml:mo>+</mml:mo><mml:munder><mml:mo movablelimits="false">∑</mml:mo><mml:mi>x</mml:mi></mml:munder><mml:msub><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">x</mml:mi></mml:msub><mml:msub><mml:mi>s</mml:mi><mml:mi>x</mml:mi></mml:msub></mml:mrow></mml:mfenced></mml:mrow></mml:mtd></mml:mtr><mml:mlabeledtr id="Ch1.E3"><mml:mtd><mml:mtext>3</mml:mtext></mml:mtd><mml:mtd><mml:mstyle class="stylechange" displaystyle="true"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:mo>-</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mi mathvariant="italic">ρ</mml:mi><mml:msub><mml:mover accent="true"><mml:mi>q</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mtext>rad</mml:mtext></mml:msub></mml:mrow><mml:mi>T</mml:mi></mml:mfrac></mml:mstyle><mml:mo>=</mml:mo><mml:mi mathvariant="italic">ρ</mml:mi><mml:msubsup><mml:mover accent="true"><mml:mi>s</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">i</mml:mi><mml:mtext>mat</mml:mtext></mml:msubsup><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula>

        where <inline-formula><mml:math id="M11" display="inline"><mml:mrow><mml:msup><mml:mover accent="true"><mml:mrow><mml:msub><mml:mi>s</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub></mml:mrow><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mtext>mat</mml:mtext></mml:msup></mml:mrow></mml:math></inline-formula> represents the internal specific production of entropy. This equation contains bulk fluid quantities, such as the density <inline-formula><mml:math id="M12" display="inline"><mml:mi mathvariant="italic">ρ</mml:mi></mml:math></inline-formula>, the entropy density <inline-formula><mml:math id="M13" display="inline"><mml:mi>s</mml:mi></mml:math></inline-formula>, the fluid velocity vector <inline-formula><mml:math id="M14" display="inline"><mml:mi mathvariant="bold-italic">v</mml:mi></mml:math></inline-formula>, its temperature <inline-formula><mml:math id="M15" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>, and the radiative heating rate <inline-formula><mml:math id="M16" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>q</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mtext>rad</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>. We then have the diffusive fluxes of sensible heat <inline-formula><mml:math id="M17" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">u</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and of species <inline-formula><mml:math id="M18" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi>x</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, each carrying its entropy density <inline-formula><mml:math id="M19" display="inline"><mml:mrow><mml:msub><mml:mi>s</mml:mi><mml:mi>x</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <xref ref-type="bibr" rid="bib1.bibx23" id="paren.20"/>. Here <inline-formula><mml:math id="M20" display="inline"><mml:mi>x</mml:mi></mml:math></inline-formula> represents dry air, water vapor and liquid water.</p>
      <p id="d2e666">To study the total entropy production in the system, we integrate Eq. (<xref ref-type="disp-formula" rid="Ch1.E3"/>) over the system's volume <inline-formula><mml:math id="M21" display="inline"><mml:mi mathvariant="normal">Ω</mml:mi></mml:math></inline-formula>, defined as the atmospheric layer from the ocean surface up to just above the inversion. Formally, the balance between total internal production and external export can be then written as

              <disp-formula id="Ch1.E4" content-type="numbered"><label>4</label><mml:math id="M22" display="block"><mml:mstyle displaystyle="true" class="stylechange"/><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:munder><mml:mo movablelimits="false">∫</mml:mo><mml:mi mathvariant="normal">Ω</mml:mi></mml:munder><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mo>∂</mml:mo><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi>s</mml:mi></mml:mrow><mml:mrow><mml:mo>∂</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>+</mml:mo><mml:munder><mml:mo movablelimits="false">∫</mml:mo><mml:mi mathvariant="normal">Ω</mml:mi></mml:munder><mml:mi mathvariant="italic">ρ</mml:mi><mml:mover accent="true"><mml:mi>s</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:msub><mml:mo>|</mml:mo><mml:mtext>subs</mml:mtext></mml:msub><mml:mo>+</mml:mo><mml:munder><mml:mo movablelimits="false">∫</mml:mo><mml:mrow><mml:mo>∂</mml:mo><mml:mi mathvariant="normal">Ω</mml:mi></mml:mrow></mml:munder><mml:msub><mml:mi>F</mml:mi><mml:mtext>ext</mml:mtext></mml:msub><mml:mo>+</mml:mo><mml:munder><mml:mo movablelimits="false">∫</mml:mo><mml:mi mathvariant="normal">Ω</mml:mi></mml:munder><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mi mathvariant="italic">ρ</mml:mi><mml:msub><mml:mover accent="true"><mml:mi>q</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mtext>rad</mml:mtext></mml:msub></mml:mrow><mml:mi>T</mml:mi></mml:mfrac></mml:mstyle><mml:mo>=</mml:mo><mml:munder><mml:mo movablelimits="false">∫</mml:mo><mml:mi mathvariant="normal">Ω</mml:mi></mml:munder><mml:mi mathvariant="italic">ρ</mml:mi><mml:msubsup><mml:mover accent="true"><mml:mi>s</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">i</mml:mi><mml:mtext>mat</mml:mtext></mml:msubsup><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>

        On the left-hand side are the total tendency together with the entropy fluxes into the system <inline-formula><mml:math id="M23" display="inline"><mml:mrow><mml:msub><mml:mi>F</mml:mi><mml:mtext>ext</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>. These fluxes include that owing to large-scale subsidence, the surface sensible heat flux, and mass fluxes associated with evaporation and precipitation. Subsidence is implemented in the model as a direct tendency on temperature and humidity that together gives a tendency of entropy <inline-formula><mml:math id="M24" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>s</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mtext>subs</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>, which we integrate over the domain. The divergence in Eq. (<xref ref-type="disp-formula" rid="Ch1.E3"/>) gives rise to the surface fluxes of sensible heat, evaporation and precipitation, entering the domain at the surface temperature. Unlike in RCE <xref ref-type="bibr" rid="bib1.bibx51 bib1.bibx63" id="paren.21"/>, surface evaporation and precipitation are not in balance, meaning that the mass fluxes cannot be expressed simply in terms of the latent heat flux. Radiative cooling is incorporated by the last term on the left-hand side.  While often considered as an external flux, entrainment across the inversion is treated here as an internal process since its effects, turbulent mixing and drying, occur within the system's volume.</p>
      <p id="d2e814">In our stratocumulus simulations the storage term has a substantial contribution and cannot be ignored. This also complicates the interpretation of the external fluxes, particularly because individual terms depend on the chosen reference point for the entropy computation. Furthermore, given the small magnitude of the overall internal entropy production (Fig. <xref ref-type="fig" rid="F2"/>), the external export, as written (left-hand side of Eq. <xref ref-type="disp-formula" rid="Ch1.E4"/>), cannot be relied on to provide an estimate of the internal production. Our chosen LES model, the System for Atmospheric Modeling (SAM) <xref ref-type="bibr" rid="bib1.bibx35" id="paren.22"/>, has not been formulated to consistently treat entropy sources and sinks. For these reasons, we decided to focus directly on computing and studying the internal production, without trying to diagnose it via external fluxes.</p>
      <p id="d2e824">To do so, we divide the internal specific production into the following components:

              <disp-formula id="Ch1.E5" content-type="numbered"><label>5</label><mml:math id="M25" display="block"><mml:mstyle class="stylechange" displaystyle="true"/><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:msup><mml:mover accent="true"><mml:mrow><mml:msub><mml:mi>s</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub></mml:mrow><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mtext>mat</mml:mtext></mml:msup><mml:mo>=</mml:mo><mml:msup><mml:mover accent="true"><mml:mrow><mml:msub><mml:mi>s</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub></mml:mrow><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mtext>fric</mml:mtext></mml:msup><mml:mo>+</mml:mo><mml:msup><mml:mover accent="true"><mml:mrow><mml:msub><mml:mi>s</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub></mml:mrow><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mtext>heat</mml:mtext></mml:msup><mml:mo>+</mml:mo><mml:msup><mml:mover accent="true"><mml:mrow><mml:msub><mml:mi>s</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub></mml:mrow><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mtext>chem</mml:mtext></mml:msup><mml:mo>+</mml:mo><mml:msup><mml:mover accent="true"><mml:mrow><mml:msub><mml:mi>s</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub></mml:mrow><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mtext>mix</mml:mtext></mml:msup><mml:mo>+</mml:mo><mml:msup><mml:mover accent="true"><mml:mrow><mml:msub><mml:mi>s</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub></mml:mrow><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mtext>sed</mml:mtext></mml:msup><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>

        The first two terms represent entropy production associated with the fluid mixture as a whole,

              <disp-formula specific-use="align" content-type="numbered"><mml:math id="M26" display="block"><mml:mtable displaystyle="true"><mml:mlabeledtr id="Ch1.E6"><mml:mtd><mml:mtext>6</mml:mtext></mml:mtd><mml:mtd><mml:mstyle displaystyle="true" class="stylechange"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mi mathvariant="italic">ρ</mml:mi><mml:msubsup><mml:mover accent="true"><mml:mi>s</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">i</mml:mi><mml:mtext>fric</mml:mtext></mml:msubsup><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi mathvariant="italic">ϵ</mml:mi></mml:mrow><mml:mi>T</mml:mi></mml:mfrac></mml:mstyle><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E7"><mml:mtd><mml:mtext>7</mml:mtext></mml:mtd><mml:mtd><mml:mstyle class="stylechange" displaystyle="true"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:mi mathvariant="italic">ρ</mml:mi><mml:msubsup><mml:mover accent="true"><mml:mi>s</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">i</mml:mi><mml:mtext>heat</mml:mtext></mml:msubsup><mml:mo>=</mml:mo><mml:mo>-</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">u</mml:mi></mml:msub><mml:mi mathvariant="bold">∇</mml:mi><mml:mi>T</mml:mi></mml:mrow><mml:mrow><mml:msup><mml:mi>T</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula>

        where <inline-formula><mml:math id="M27" display="inline"><mml:mi mathvariant="italic">ϵ</mml:mi></mml:math></inline-formula> is the frictional dissipation due to viscosity at the end of the turbulent cascade, while <inline-formula><mml:math id="M28" display="inline"><mml:mrow><mml:msup><mml:mover accent="true"><mml:mrow><mml:msub><mml:mi>s</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub></mml:mrow><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mtext>heat</mml:mtext></mml:msup></mml:mrow></mml:math></inline-formula> represents irreversibility associated with the diffusion of sensible heat. We then have the terms that are due to the active components in the mixture,

              <disp-formula specific-use="align" content-type="numbered"><mml:math id="M29" display="block"><mml:mtable displaystyle="true"><mml:mlabeledtr id="Ch1.E8"><mml:mtd><mml:mtext>8</mml:mtext></mml:mtd><mml:mtd><mml:mstyle class="stylechange" displaystyle="true"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mi mathvariant="italic">ρ</mml:mi><mml:msubsup><mml:mover accent="true"><mml:mi>s</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">i</mml:mi><mml:mtext>chem</mml:mtext></mml:msubsup><mml:mo>=</mml:mo><mml:mo>-</mml:mo><mml:mi>e</mml:mi><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:mi>ln⁡</mml:mi><mml:mo>(</mml:mo><mml:mi>R</mml:mi><mml:mo>)</mml:mo><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E9"><mml:mtd><mml:mtext>9</mml:mtext></mml:mtd><mml:mtd><mml:mstyle class="stylechange" displaystyle="true"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:mi mathvariant="italic">ρ</mml:mi><mml:msubsup><mml:mover accent="true"><mml:mi>s</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">i</mml:mi><mml:mtext>mix</mml:mtext></mml:msubsup><mml:mo>≈</mml:mo><mml:mo>-</mml:mo><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:msub><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:mi mathvariant="bold">∇</mml:mi><mml:mi>ln⁡</mml:mi><mml:mfenced close=")" open="("><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:mfrac></mml:mstyle></mml:mfenced><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E10"><mml:mtd><mml:mtext>10</mml:mtext></mml:mtd><mml:mtd><mml:mstyle displaystyle="true" class="stylechange"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mi mathvariant="italic">ρ</mml:mi><mml:msubsup><mml:mover accent="true"><mml:mi>s</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">i</mml:mi><mml:mtext>sed</mml:mtext></mml:msubsup><mml:mo>=</mml:mo><mml:mo>-</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi>q</mml:mi><mml:mi>p</mml:mi></mml:msub><mml:msub><mml:mi>v</mml:mi><mml:mi mathvariant="normal">t</mml:mi></mml:msub></mml:mrow><mml:mi>T</mml:mi></mml:mfrac></mml:mstyle><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mo>∂</mml:mo><mml:mi>p</mml:mi></mml:mrow><mml:mrow><mml:mo>∂</mml:mo><mml:mi>z</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>.</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula>

        The first term, <inline-formula><mml:math id="M30" display="inline"><mml:mrow><mml:msup><mml:mover accent="true"><mml:mrow><mml:msub><mml:mi>s</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub></mml:mrow><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mtext>chem</mml:mtext></mml:msup></mml:mrow></mml:math></inline-formula>, corresponds to the contribution from non-equilibrium phase changes, where <inline-formula><mml:math id="M31" display="inline"><mml:mi>e</mml:mi></mml:math></inline-formula> is the evaporation rate, <inline-formula><mml:math id="M32" display="inline"><mml:mrow><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the specific gas constant of water vapor, and <inline-formula><mml:math id="M33" display="inline"><mml:mi>R</mml:mi></mml:math></inline-formula> is the relative humidity. Since there is no solid condensate in our domain, we do not account for contributions from phase changes involving solid water. The irreversible diffusion of substances in the fluid is counted in the second term, <inline-formula><mml:math id="M34" display="inline"><mml:mrow><mml:msup><mml:mover accent="true"><mml:mrow><mml:msub><mml:mi>s</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub></mml:mrow><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mtext>mix</mml:mtext></mml:msup></mml:mrow></mml:math></inline-formula>, for which the diffusion of water vapor is the dominant term <xref ref-type="bibr" rid="bib1.bibx52" id="paren.23"/>. Here, <inline-formula><mml:math id="M35" display="inline"><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> represents the partial vapor pressure, while <inline-formula><mml:math id="M36" display="inline"><mml:mrow><mml:msub><mml:mi>p</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is the reference point used for the entropy computation. Following previous studies <xref ref-type="bibr" rid="bib1.bibx51 bib1.bibx63" id="paren.24"/>, we will refer to the sum of <inline-formula><mml:math id="M37" display="inline"><mml:mrow><mml:msup><mml:mover accent="true"><mml:mrow><mml:msub><mml:mi>s</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub></mml:mrow><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mtext>chem</mml:mtext></mml:msup></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M38" display="inline"><mml:mrow><mml:msup><mml:mover accent="true"><mml:mrow><mml:msub><mml:mi>s</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub></mml:mrow><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mtext>mix</mml:mtext></mml:msup></mml:mrow></mml:math></inline-formula> collectively as the contribution from <italic>moist processes</italic>. Finally, <inline-formula><mml:math id="M39" display="inline"><mml:mrow><mml:msup><mml:mover accent="true"><mml:mrow><mml:msub><mml:mi>s</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub></mml:mrow><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mtext>sed</mml:mtext></mml:msup></mml:mrow></mml:math></inline-formula> represents the frictional effects on falling hydrometeors <xref ref-type="bibr" rid="bib1.bibx54" id="paren.25"/>, where with <inline-formula><mml:math id="M40" display="inline"><mml:mrow><mml:msub><mml:mi>v</mml:mi><mml:mi mathvariant="normal">t</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> we indicate their terminal velocity.</p>
      <p id="d2e1352">In the following work, we will focus on estimating the total averaged internal material entropy production

              <disp-formula id="Ch1.E11" content-type="numbered"><label>11</label><mml:math id="M41" display="block"><mml:mstyle class="stylechange" displaystyle="true"/><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mfenced open="〈" close="〉"><mml:mrow><mml:msubsup><mml:mover accent="true"><mml:mi>S</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">i</mml:mi><mml:mtext>mat</mml:mtext></mml:msubsup></mml:mrow></mml:mfenced><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mi>A</mml:mi></mml:mfrac></mml:mstyle><mml:munder><mml:mo movablelimits="false">∫</mml:mo><mml:mi mathvariant="normal">Ω</mml:mi></mml:munder><mml:mfenced open="〈" close="〉"><mml:mrow><mml:mi mathvariant="italic">ρ</mml:mi><mml:msubsup><mml:mover accent="true"><mml:mi>s</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">i</mml:mi><mml:mtext>mat</mml:mtext></mml:msubsup></mml:mrow></mml:mfenced><mml:mi mathvariant="normal">d</mml:mi><mml:mi>V</mml:mi><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>

        where <inline-formula><mml:math id="M42" display="inline"><mml:mrow><mml:mfenced close="〉" open="〈"><mml:mo>.</mml:mo></mml:mfenced></mml:mrow></mml:math></inline-formula> represents the time-average over a period for which the system can be considered to be approximately steady, such that the results can be considered representative for the case under study. We express the entropy production per unit surface area by dividing by the domain area <inline-formula><mml:math id="M43" display="inline"><mml:mi>A</mml:mi></mml:math></inline-formula>.</p>
</sec>
<sec id="Ch1.S3">
  <label>3</label><title>Simulations</title>
      <p id="d2e1433">To compute all the components of the entropy production in Eq. (<xref ref-type="disp-formula" rid="Ch1.E5"/>), we build upon an existing ensemble of Large Eddy Simulations run with SAM <xref ref-type="bibr" rid="bib1.bibx35" id="paren.26"/>. The dataset, first presented in <xref ref-type="bibr" rid="bib1.bibx19" id="text.27"/>, consists of 191 nocturnal stratocumulus simulations designed to explore cloud variability under controlled environmental conditions. The nocturnal setup was chosen to avoid the complexity of diurnal cycle forcing, allowing the system to equilibrate into a simpler quasi-steady state.</p>
      <p id="d2e1444">Each simulation is conducted on a <inline-formula><mml:math id="M44" display="inline"><mml:mrow><mml:mn mathvariant="normal">48</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow><mml:mo>×</mml:mo><mml:mn mathvariant="normal">48</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow><mml:mo>×</mml:mo><mml:mn mathvariant="normal">2</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:mrow></mml:math></inline-formula> domain with 200 <inline-formula><mml:math id="M45" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> horizontal and 10 <inline-formula><mml:math id="M46" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> vertical grid spacing. The model is run for a total duration of 12 <inline-formula><mml:math id="M47" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:math></inline-formula>. Simulations use constant surface fluxes, and a large-scale subsidence profile derived from a constant large-scale divergence, representative of typical marine stratocumulus conditions. SAM is configured to prognose supersaturation and employs a bin-emulating two-moment microphysics scheme that tracks both mass and number concentrations of cloud and rain droplets <xref ref-type="bibr" rid="bib1.bibx69" id="paren.28"/>.</p>
      <p id="d2e1502">Initial conditions were generated using a maximin Latin hypercube design <xref ref-type="bibr" rid="bib1.bibx43" id="paren.29"/> in a six-dimensional parameter space: mixed layer values of liquid water potential temperature (<inline-formula><mml:math id="M48" display="inline"><mml:mrow><mml:mn mathvariant="normal">284</mml:mn><mml:mo>&lt;</mml:mo><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">l</mml:mi></mml:msub><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mo>(</mml:mo><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow><mml:mo>)</mml:mo><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">294</mml:mn></mml:mrow></mml:math></inline-formula>), total water mixing ratio (<inline-formula><mml:math id="M49" display="inline"><mml:mrow><mml:mn mathvariant="normal">6.5</mml:mn><mml:mo>&lt;</mml:mo><mml:msub><mml:mi>q</mml:mi><mml:mi mathvariant="normal">t</mml:mi></mml:msub><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mo>(</mml:mo><mml:mrow class="unit"><mml:mi mathvariant="normal">g</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">kg</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow><mml:mo>)</mml:mo><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">10.5</mml:mn></mml:mrow></mml:math></inline-formula>), and aerosol concentration (<inline-formula><mml:math id="M50" display="inline"><mml:mrow><mml:mn mathvariant="normal">30</mml:mn><mml:mo>&lt;</mml:mo><mml:msub><mml:mi>N</mml:mi><mml:mi mathvariant="normal">a</mml:mi></mml:msub><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mo>(</mml:mo><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">cm</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow><mml:mo>)</mml:mo><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">500</mml:mn></mml:mrow></mml:math></inline-formula>), as well as the initial mixed layer height (<inline-formula><mml:math id="M51" display="inline"><mml:mrow><mml:mn mathvariant="normal">500</mml:mn><mml:mo>&lt;</mml:mo><mml:msub><mml:mi>H</mml:mi><mml:mtext>mix</mml:mtext></mml:msub><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mo>(</mml:mo><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi></mml:mrow><mml:mo>)</mml:mo><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">1300</mml:mn></mml:mrow></mml:math></inline-formula>) and inversion jumps in temperature and moisture (<inline-formula><mml:math id="M52" display="inline"><mml:mrow><mml:mn mathvariant="normal">6</mml:mn><mml:mo>&lt;</mml:mo><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">l</mml:mi></mml:msub><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mo>(</mml:mo><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow><mml:mo>)</mml:mo><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">10</mml:mn></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M53" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">10</mml:mn><mml:mo>&lt;</mml:mo><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>q</mml:mi><mml:mi mathvariant="normal">t</mml:mi></mml:msub><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mo>(</mml:mo><mml:mrow class="unit"><mml:mi mathvariant="normal">g</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">kg</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow><mml:mo>)</mml:mo><mml:mo>&lt;</mml:mo><mml:mo>-</mml:mo><mml:mn mathvariant="normal">6</mml:mn></mml:mrow></mml:math></inline-formula>) <xref ref-type="bibr" rid="bib1.bibx19" id="paren.30"/>. Following <xref ref-type="bibr" rid="bib1.bibx19" id="text.31"/>, we exclude cases that fail to sustain clouds or that produce precipitation within the first hour, leaving 159 simulations. The former correspond to lifting condensation levels above the inversion, while early precipitation cases exhibit rapid, non-physical dissipation of the cloud layer immediately after the 2 <inline-formula><mml:math id="M54" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:math></inline-formula> spin-up. To avoid integrating over the model's sponge layer (starting at 1600 <inline-formula><mml:math id="M55" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>), we additionally exclude cases with boundary layer depth exceeding 1500 <inline-formula><mml:math id="M56" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>. The final dataset thus comprises 155 simulations, with 131 closed-cell and 24 open-cell cases.</p>
      <p id="d2e1735">The original ensemble does not include all diagnostics required for an accurate computation of the entropy production. To address this, we extend two representative cases by one additional hour, saving all relevant fields (see Sect. <xref ref-type="sec" rid="Ch1.S3.SS1"/>) at 5 <inline-formula><mml:math id="M57" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">min</mml:mi></mml:mrow></mml:math></inline-formula> intervals. The selected cases capture the two characteristic cellular morphologies: one dominated by open cellular convection, the other by closed cells. These simulations were chosen based on their relatively small tendencies in key domain-mean quantities, such as liquid water path and droplet number concentration, indicating quasi-steady conditions (see Fig. <xref ref-type="fig" rid="F1"/>). Although the boundary layer continues to evolve slowly, with non-zero tendencies in inversion height, the system remains sufficiently steady to permit reliable budget diagnostics.</p>

      <fig id="F1" specific-use="star"><label>Figure 1</label><caption><p id="d2e1753">Detailed stratocumulus large-eddy simulations used for the entropy production analysis. <bold>(a–c)</bold> Open-cell and <bold>(d–f)</bold> closed-cell case with <bold>(a, d)</bold> 1 <inline-formula><mml:math id="M58" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:math></inline-formula> time-averaged vertical temperature structure and total water mixing ratio <inline-formula><mml:math id="M59" display="inline"><mml:mrow><mml:msub><mml:mi>q</mml:mi><mml:mi mathvariant="normal">t</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> profile, <bold>(b, e)</bold> time series of domain-mean <inline-formula><mml:math id="M60" display="inline"><mml:mi>L</mml:mi></mml:math></inline-formula> (liquid water path) and <inline-formula><mml:math id="M61" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> (droplet number concentration), and <bold>(c, f)</bold>, snapshot of cloud albedo from the final timestep, highlighting the distinct morphology and fine-scale cellular patterns resolved by the LES. The cloud layer is indicated by the gray shaded region in panel <bold>(d)</bold>, where it is well-defined in the homogeneous closed-cell case. In <bold>(b, e)</bold> light lines correspond to the original 12 <inline-formula><mml:math id="M62" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:math></inline-formula> simulation, while solid lines indicate the 1 <inline-formula><mml:math id="M63" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:math></inline-formula> equilibrated extension used for the entropy budget analysis.</p></caption>
        <graphic xlink:href="https://acp.copernicus.org/articles/26/9337/2026/acp-26-9337-2026-f01.png"/>

      </fig>


<sec id="Ch1.S3.SS1">
  <label>3.1</label><title>Entropy budget computation for LES</title>
      <p id="d2e1843">All diagnostics are computed on the native LES grid using full 3D fields, prior to any spatial or temporal averaging. This is necessary because of the strong spatial variability of the boundary layer and the nonlinear nature of several terms in the entropy budget.</p>
      <p id="d2e1846">The viscous dissipation <inline-formula><mml:math id="M64" display="inline"><mml:mi mathvariant="italic">ϵ</mml:mi></mml:math></inline-formula> is taken directly from the subgrid-scale turbulent kinetic energy dissipation field, representing the local rate of conversion from mechanical energy to heat. Consistent with the LES formulation, diffusive fluxes are derived using the subgrid-scale eddy diffusivity and the model's 3D diffusion scheme. The condensation–evaporation rate <inline-formula><mml:math id="M65" display="inline"><mml:mi>e</mml:mi></mml:math></inline-formula> represents the net rate of phase change between water vapor and condensed water as diagnosed by the LES microphysics scheme. Finally, hydrometeor sedimentation is computed using terminal velocities from the LES microphysics scheme, diagnosed from droplet mean radius. With this approach, each term in Eq. (<xref ref-type="disp-formula" rid="Ch1.E5"/>) is computed consistently within the LES framework.</p>
</sec>
</sec>
<sec id="Ch1.S4">
  <label>4</label><title>Moisture dominates the stratocumulus irreversibility</title>
      <p id="d2e1874">In Fig. <xref ref-type="fig" rid="F2"/> we present the decomposition of the internal entropy production for the two open- and closed-cell cases. Each entropy production term is integrated over the domain, averaged over the final hour and expressed per unit surface area of the model domain, following Eq. (<xref ref-type="disp-formula" rid="Ch1.E11"/>).</p>

      <fig id="F2" specific-use="star"><label>Figure 2</label><caption><p id="d2e1883">Internal entropy budget for <bold>(a)</bold> open-cell and <bold>(b)</bold> closed-cell stratocumulus. Variables on the <inline-formula><mml:math id="M66" display="inline"><mml:mi>x</mml:mi></mml:math></inline-formula> axis correspond to the terms in Eq. (<xref ref-type="disp-formula" rid="Ch1.E5"/>). Whiskers indicate one standard deviation over time. The budget is integrated over the full simulation domain up to <inline-formula><mml:math id="M67" display="inline"><mml:mrow><mml:msub><mml:mi>z</mml:mi><mml:mtext>max</mml:mtext></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1500</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M68" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> and normalized by the domain surface area</p></caption>
        <graphic xlink:href="https://acp.copernicus.org/articles/26/9337/2026/acp-26-9337-2026-f02.png"/>

      </fig>

      <p id="d2e1931">We first note that the total entropy production differs markedly between the two morphologies: the closed-cell case produces more than twice as much dissipation as the open-cell case. This arises because the closed-cell simulation exhibits stronger rates of radiative cooling and subsidence drying at lower effective temperatures (Fig. <xref ref-type="fig" rid="FA1"/>), which increases entropy export and therefore requires higher internal production (Eq. <xref ref-type="disp-formula" rid="Ch1.E3"/>).</p>
      <p id="d2e1939">While total entropy production is an indication of the degree of irreversibility generated, the specific decomposition of such dissipation is usually more informative for understanding the system's dynamics and self organization <xref ref-type="bibr" rid="bib1.bibx68" id="paren.32"/>. We decompose the sources of entropy production following Eq. (<xref ref-type="disp-formula" rid="Ch1.E5"/>) and compare them with aggregated RCE results (Table <xref ref-type="table" rid="T1"/>). Consistent with earlier RCE findings by <xref ref-type="bibr" rid="bib1.bibx52" id="text.33"/> and <xref ref-type="bibr" rid="bib1.bibx63" id="text.34"/>, we observe how moist processes dominate entropy production in stratocumulus clouds as well. We intentionally do not subdivide these contributions into diffusional and evaporation–condensation production, as the distinction is somewhat artificial and depends heavily on how the subgrid and microphysical processes are parameterized in the model. It can be shown that the entropy production due to the irreversible evaporation of liquid water at a relative humidity <inline-formula><mml:math id="M69" display="inline"><mml:mi>R</mml:mi></mml:math></inline-formula> is effectively the same as the production due to reversible evaporation at saturation followed by  diffusion of water vapor down a vapor pressure gradient to the same value of relative humidity <xref ref-type="bibr" rid="bib1.bibx52" id="paren.35"/>.</p>

<table-wrap id="T1" specific-use="star"><label>Table 1</label><caption><p id="d2e1969">Comparison of the (internal) entropy production due to different processes between open stratocumulus, closed stratocumulus, and aggregated RCE. Values for RCE are taken from <xref ref-type="bibr" rid="bib1.bibx63" id="text.36"/>. Open- and closed-cell results are averaged over the last hour of simulation.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="4">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:thead>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">Open</oasis:entry>
         <oasis:entry colname="col3">Closed</oasis:entry>
         <oasis:entry colname="col4">RCE (agg.)</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">Entropy Production</oasis:entry>
         <oasis:entry colname="col2">1.9 <inline-formula><mml:math id="M70" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mW</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">K</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">4.2 <inline-formula><mml:math id="M71" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mW</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">K</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">34.9 <inline-formula><mml:math id="M72" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mW</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">K</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Frictional Dissipation</oasis:entry>
         <oasis:entry colname="col2">5 <inline-formula><mml:math id="M73" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">6 <inline-formula><mml:math id="M74" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">7 <inline-formula><mml:math id="M75" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Moist processes</oasis:entry>
         <oasis:entry colname="col2">58 <inline-formula><mml:math id="M76" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">89 <inline-formula><mml:math id="M77" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">67 <inline-formula><mml:math id="M78" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Precipitation</oasis:entry>
         <oasis:entry colname="col2">34 <inline-formula><mml:math id="M79" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">0 <inline-formula><mml:math id="M80" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4">26 <inline-formula><mml:math id="M81" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Heat diffusion</oasis:entry>
         <oasis:entry colname="col2">3 <inline-formula><mml:math id="M82" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">5 <inline-formula><mml:math id="M83" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M84" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.03 <inline-formula><mml:math id="M85" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p id="d2e2249">In the non-precipitating closed-cell case, moist processes account for approximately <inline-formula><mml:math id="M86" display="inline"><mml:mrow><mml:mn mathvariant="normal">90</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:mrow></mml:math></inline-formula> of the total entropy production, overwhelmingly outweighing frictional dissipation. This reflects the unique role of water vapor which, despite accounting for less than <inline-formula><mml:math id="M87" display="inline"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:mrow></mml:math></inline-formula> of the domain mass, is the only constituent able to undergo phase changes.</p>
      <p id="d2e2276">In the precipitating (open-cell) case, a substantial part of the dissipation appears to shift from moist processes to hydrometeor friction. Roughly one-third of total dissipation is attributed to precipitation drag, even more than in previous RCE simulations. At first glance, this result may seem counterintuitive, since frictional heating from falling hydrometeors is typically neglected in the energy budget of LES formulations such as SAM. This is often well justified, given that said frictional heating accounts for a minor source of heat, orders of magnitude less than radiative or surface fluxes <xref ref-type="bibr" rid="bib1.bibx31" id="paren.37"/>. However, all of this heating is irreversibly dissipated, corresponding to a significant entropy source.</p>
      <p id="d2e2282">As a final contributor to internal entropy production, we find heat diffusion to be a non-negligible positive term. This contribution arises primarily from strong vertical gradients near the surface and at cloud top. While part of this diffusion is a model artifact due to the limited vertical resolution, we retain it for consistency with the model treatment. In contrast, previous RCE studies <xref ref-type="bibr" rid="bib1.bibx51 bib1.bibx63" id="paren.38"/> found heat diffusion to be a minor term, and showing a negative sign. This apparent violation of the second law arises from how LES models handle subgrid-scale heat transport. As noted by <xref ref-type="bibr" rid="bib1.bibx21" id="text.39"/>, <xref ref-type="bibr" rid="bib1.bibx58" id="text.40"/>, <xref ref-type="bibr" rid="bib1.bibx16" id="text.41"/>, parametrized turbulent heat fluxes do not always produce entropy in the same way as molecular diffusion. The second law is preserved by recognizing that turbulent heat transport and kinetic energy dissipation are part of the same cascade, so it is the total entropy production from all turbulent processes that must remain positive <xref ref-type="bibr" rid="bib1.bibx63" id="paren.42"/>. However, given the strong differences in vertical resolution and model details between the two setups, we remark that a direct quantitative comparison of this term should be treated with caution.</p>
      <p id="d2e2301">Finally, we examine the relative contributions of horizontal and vertical components of the diffusion terms. Despite both closed and open cells exhibiting highly heterogeneous horizontal structures, both below and in cloud, nearly all of the entropy production from sensible heat and vapor diffusion (over 97 <inline-formula><mml:math id="M88" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula>) arises from vertical gradients (Fig. <xref ref-type="fig" rid="FA2"/>). We verified this result by rescaling to an isotropic grid, given the strong difference in horizontal and vertical grid spacing. While open cells show a stronger contribution from horizontal gradients in water vapor mixing, diffusion remains dominated by vertical gradients.</p>
      <p id="d2e2314">In terms of magnitude, the overall internal entropy production is low in both stratocumulus cases when compared to previous results in RCE simulations <xref ref-type="bibr" rid="bib1.bibx51 bib1.bibx52 bib1.bibx62 bib1.bibx63" id="paren.43"/>. The comparison is presented in Table <xref ref-type="table" rid="T1"/>. We believe this discrepancy, exceeding one order of magnitude, can be attributed to the scale difference between systems. While the idealized RCE simulations typically involve deep convective clouds several kilometers deep (<inline-formula><mml:math id="M89" display="inline"><mml:mrow><mml:mo>≈</mml:mo><mml:mn mathvariant="normal">10</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M90" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>), stratocumulus feature much shallower inversion heights, on the order of 1–2 <inline-formula><mml:math id="M91" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> <xref ref-type="bibr" rid="bib1.bibx55" id="paren.44"/>. Since entropy is an extensive quantity, it is unsurprising that deeper layers result in greater overall production. From an external perspective, a deeper layer translates to a bigger temperature difference across the layer (see Fig. <xref ref-type="fig" rid="FA3"/>), which allows for a larger difference between the input and output of entropy across the boundaries. An order of magnitude smaller vertical extent and temperature difference between stratocumulus and RCE translates to approximately an order of magnitude smaller total entropy production.</p>
</sec>
<sec id="Ch1.S5">
  <label>5</label><title>Moist production mirrors regime-specific processes</title>
      <p id="d2e2363">We now focus on moist processes, which represent the dominant contribution to the internal entropy production in both regimes. Not only does the share of moist production differ between the closed- and open-cell simulations, but the origin of this production also differs, directly reflecting the distinct physical drivers in each morphology.</p>
      <p id="d2e2366">In the closed-cell regime, moist entropy production is almost entirely driven by cloud-top entrainment, quantified by the entrainment velocity

              <disp-formula id="Ch1.E12" content-type="numbered"><label>12</label><mml:math id="M92" display="block"><mml:mstyle class="stylechange" displaystyle="true"/><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:mi>w</mml:mi><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mi mathvariant="normal">d</mml:mi><mml:msub><mml:mi>z</mml:mi><mml:mtext>inv</mml:mtext></mml:msub></mml:mrow><mml:mrow><mml:mi mathvariant="normal">d</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>-</mml:mo><mml:msub><mml:mi>w</mml:mi><mml:mtext>subs</mml:mtext></mml:msub><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>

        estimated from the deepening of the boundary layer, where <inline-formula><mml:math id="M93" display="inline"><mml:mrow><mml:msub><mml:mi>z</mml:mi><mml:mtext>inv</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> is the inversion height and <inline-formula><mml:math id="M94" display="inline"><mml:mrow><mml:msub><mml:mi>w</mml:mi><mml:mtext>subs</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> the large-scale subsidence velocity. While some lateral mixing does occur, particularly at the boundaries between individual cells, the bulk of the moist production is strongly localized near the cloud top (Fig. <xref ref-type="fig" rid="FA5"/>). This is because closed-cell stratocumulus typically have intense vertical gradients in thermodynamic properties at the top of the boundary layer and relative horizontal homogeneity within the cloud deck <xref ref-type="bibr" rid="bib1.bibx70" id="paren.45"/>. As a result, we find that the intensity of cloud-top entrainment scales with the total moist entropy production, as illustrated in Fig. <xref ref-type="fig" rid="F3"/>. This highlights the fundamental role of cloud-top entrainment as a crucial driver of the organization and temporal evolution of closed stratocumulus decks <xref ref-type="bibr" rid="bib1.bibx70 bib1.bibx34 bib1.bibx20" id="paren.46"/>.</p>

      <fig id="F3" specific-use="star"><label>Figure 3</label><caption><p id="d2e2440">Regime dependencies of dominant moist processes. The left panels show a vertical cross-section of the moist entropy production at the last time-step. For open cells (row <bold>a</bold>), light shading highlights regions containing rain water, defined as locations where the rain water mixing ratio exceeds 0.01 <inline-formula><mml:math id="M95" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">g</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">kg</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>. For closed cells (row <bold>b</bold>), shading indicates regions with cloud water mixing ratio above the same threshold. Only values of entropy production exceeding 0.001 <inline-formula><mml:math id="M96" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mW</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">K</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> are shown for clarity. The right panels show the correlation between the domain-mean moist entropy production <inline-formula><mml:math id="M97" display="inline"><mml:mrow><mml:msubsup><mml:mover accent="true"><mml:mi>S</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">i</mml:mi><mml:mtext>moist</mml:mtext></mml:msubsup></mml:mrow></mml:math></inline-formula> and the relevant thermodynamic variable: for open cells, the surface equivalent potential temperature anomaly conditioned on cold-pool regions (<inline-formula><mml:math id="M98" display="inline"><mml:mover accent="true"><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">e</mml:mi><mml:mo>′</mml:mo></mml:msubsup><mml:mo>&lt;</mml:mo><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.5</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:mrow><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula>); for closed cells, the domain-mean entrainment velocity. Dashed lines indicate the linear regression, with the Pearson correlation coefficient reported in the legend.</p></caption>
        <graphic xlink:href="https://acp.copernicus.org/articles/26/9337/2026/acp-26-9337-2026-f03.png"/>

      </fig>

      <p id="d2e2542">In contrast, open-cell moist entropy production is governed by a completely different mechanism. Although cloud-top entrainment is still present, it plays a relatively minor role in the overall entropy budget. Similar to closed cells, a part of moist entropy production is localized near the surface due to strong vertical diffusion driven by surface fluxes. However, most of the entropy production originates from non-equilibrium phase changes in rainy columns (Fig. <xref ref-type="fig" rid="FA4"/>). In particular, rain evaporation is the dominant contributor, leading to the widespread formation of cold pools. These cold pools generate strong, sustained downdrafts near the centers of cells. When they collide with those from neighboring cells, they trigger new convective updrafts at cell boundaries, perpetuating the open-cell pattern <xref ref-type="bibr" rid="bib1.bibx69 bib1.bibx18" id="paren.47"/>.</p>
      <p id="d2e2550">Because cold pools are driven by evaporative cooling, they are a direct dynamical manifestation of moist entropy production. This evaporative cooling represents thermodynamic entropy production associated with phase change in sub-saturated conditions. To quantify cold pool activity, we use the surface equivalent potential temperature anomaly <xref ref-type="bibr" rid="bib1.bibx1" id="paren.48"/>, <inline-formula><mml:math id="M99" display="inline"><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">e</mml:mi><mml:mo>′</mml:mo></mml:msubsup></mml:mrow></mml:math></inline-formula>, conditioned on cold pool regions defined by <inline-formula><mml:math id="M100" display="inline"><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">e</mml:mi><mml:mo>′</mml:mo></mml:msubsup><mml:mo>&lt;</mml:mo><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.5</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:mrow></mml:math></inline-formula>. The domain-mean value of this conditioned anomaly serves as our cold pool strength metric. As with closed cells, a significant relationship emerges between total moist entropy production and cold pool activity in the open-cell regime (see Fig. <xref ref-type="fig" rid="F3"/>).</p>
</sec>
<sec id="Ch1.S6">
  <label>6</label><title>The remarkable inefficiency of stratocumulus</title>
      <p id="d2e2602">The stratocumulus-topped boundary layer is, as discussed earlier, shallow, with clouds that are an order of magnitude thinner than those in deep convective systems. This limited vertical extent translates directly into an order-of-magnitude smaller entropy production. Despite their shallow vertical extent, stratocumulus layers still exchange substantial energy across their boundaries, on the order of <inline-formula><mml:math id="M101" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">100</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M102" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">Wm</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> <xref ref-type="bibr" rid="bib1.bibx66 bib1.bibx32 bib1.bibx19" id="paren.49"/>. To balance these inputs, the system releases energy primarily through strong radiative cooling, reaching values of <inline-formula><mml:math id="M103" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">100</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M104" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">Kd</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in the dense closed-cell state. Interestingly, boundary fluxes of a similar magnitude are found in idealized RCE setups, despite the large difference in vertical scale <xref ref-type="bibr" rid="bib1.bibx51 bib1.bibx63" id="paren.50"/>. Why is stratocumulus convection then so weak compared to the vigorous updrafts in RCE?</p>
      <p id="d2e2662">A useful lens is the mechanical efficiency of the system. Classically, efficiency describes how effectively a heat engine converts heat input into useful work. By analogy, the atmosphere can also be viewed as a heat engine, though with an important caveat: unlike a conventional engine, the atmosphere does not perform work on an external body. Instead, we can think of its useful work as the generation of kinetic energy through wind motions, <inline-formula><mml:math id="M105" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>W</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">K</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, which is ultimately dissipated internally via turbulence and friction <xref ref-type="bibr" rid="bib1.bibx57 bib1.bibx41" id="paren.51"/>. Following earlier work <xref ref-type="bibr" rid="bib1.bibx51 bib1.bibx63" id="paren.52"/>, we define the mechanical efficiency of the atmosphere as

              <disp-formula id="Ch1.E13" content-type="numbered"><label>13</label><mml:math id="M106" display="block"><mml:mstyle displaystyle="true" class="stylechange"/><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mi mathvariant="italic">η</mml:mi><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mo>〈</mml:mo><mml:msub><mml:mover accent="true"><mml:mi>W</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">K</mml:mi></mml:msub><mml:mo>〉</mml:mo></mml:mrow><mml:mrow><mml:mo>|</mml:mo><mml:mo>〈</mml:mo><mml:msub><mml:mover accent="true"><mml:mi>Q</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mtext>in</mml:mtext></mml:msub><mml:mo>〉</mml:mo><mml:mo>|</mml:mo></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>

        where <inline-formula><mml:math id="M107" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>Q</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mtext>in</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> is the rate of energy input and angle brackets denote time averaging. In steady state, <inline-formula><mml:math id="M108" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>W</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">K</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> can be approximated with the turbulent dissipation rate <xref ref-type="bibr" rid="bib1.bibx51" id="paren.53"/>, which includes the contribution from surface friction. For <inline-formula><mml:math id="M109" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>Q</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mtext>in</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>, previous studies use the vertically integrated radiative cooling, which naturally balances the surface fluxes. In stratocumulus, however, subsidence warming and drying contribute substantially to the energy balance. This makes the choice of <inline-formula><mml:math id="M110" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>Q</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mtext>in</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> less straightforward than in RCE, where radiative cooling cleanly balances the surface fluxes and therefore provides an unambiguous measure of the heat input. In our simulations, radiative cooling and large-scale subsidence jointly act as a net energy sink for the boundary layer, while the only imposed energy input at the lower, warmer boundary is the prescribed surface sensible (<inline-formula><mml:math id="M111" display="inline"><mml:mrow><mml:msub><mml:mi>F</mml:mi><mml:mtext>sh</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>) and latent <inline-formula><mml:math id="M112" display="inline"><mml:mrow><mml:mo>(</mml:mo><mml:msub><mml:mi>F</mml:mi><mml:mtext>lh</mml:mtext></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> heat fluxes (Fig. <xref ref-type="fig" rid="FA6"/>). We therefore define

              <disp-formula id="Ch1.E14" content-type="numbered"><label>14</label><mml:math id="M113" display="block"><mml:mstyle class="stylechange" displaystyle="true"/><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:msub><mml:mover accent="true"><mml:mi>Q</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mtext>in</mml:mtext></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi>F</mml:mi><mml:mtext>sh</mml:mtext></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>F</mml:mi><mml:mtext>lh</mml:mtext></mml:msub><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>

        This choice also reflects the fixed-flux boundary condition of our ensemble of simulations.</p>
      <p id="d2e2852">The resulting efficiencies for the open- and closed-cell simulations (Table <xref ref-type="table" rid="T2"/>) are low compared with typical RCE values <xref ref-type="bibr" rid="bib1.bibx51 bib1.bibx63" id="paren.54"/>. The higher turbulent kinetic energy dissipation in closed cells, relative to open cells, appears to result from their stronger cloud-top entrainment (see Appendix <xref ref-type="sec" rid="App1.Ch1.S1"/>). There are two competing effects that reduce the efficiency of stratocumulus convection. First, the maximum theoretical work available to the system is strongly constrained. The shallow vertical extent of the system severely limits the available temperature gradient, which in turn constrains the maximum work that could be generated from a given set of boundary fluxes and effective temperatures <xref ref-type="bibr" rid="bib1.bibx51" id="paren.55"/>. Even if the system were to operate as an idealized heat engine, the small vertical scale alone strongly limits the amount of extractable work. The strong subsidence that characterizes stratocumulus regions acts as a mechanical lid, forcing the system to be confined to a shallow boundary layer with minimal temperature gradients <xref ref-type="bibr" rid="bib1.bibx70" id="paren.56"/>. Furthermore, as argued by <xref ref-type="bibr" rid="bib1.bibx49" id="text.57"/>, the relative humidity at which the system operates also has an impact on the maximum amount of work, with drier systems being less efficient than moister ones. A thermodynamic cycle operating in a partially saturated environment has a maximum efficiency that increases with the degree of saturation, approaching the Carnot limit only in the fully saturated case. The departure from full saturation of the stratocumulus mixed layer therefore provides an additional constraint on the maximum extractable work.</p>

<table-wrap id="T2" specific-use="star"><label>Table 2</label><caption><p id="d2e2876">Summary of the energy input rate, frictional dissipation, and thermodynamic efficiency across different configurations. The RCE values for the disaggregated and aggregated states are taken from <xref ref-type="bibr" rid="bib1.bibx63" id="text.58"/> and correspond to two regimes of the same simulation. In all cases, the energy input is defined as the sum of the surface sensible and latent heat fluxes. Reported values are averaged over the approximately steady periods selected for the analysis.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="4">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">Energy input</oasis:entry>
         <oasis:entry colname="col3">Frictional Dissipation</oasis:entry>
         <oasis:entry colname="col4">Efficiency</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M114" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M115" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mW</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">K</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col4"><inline-formula><mml:math id="M116" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">Open</oasis:entry>
         <oasis:entry colname="col2">109</oasis:entry>
         <oasis:entry colname="col3">0.084</oasis:entry>
         <oasis:entry colname="col4">0.02</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Closed</oasis:entry>
         <oasis:entry colname="col2">109</oasis:entry>
         <oasis:entry colname="col3">0.237</oasis:entry>
         <oasis:entry colname="col4">0.06</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">RCE (disagg.)</oasis:entry>
         <oasis:entry colname="col2">106.4</oasis:entry>
         <oasis:entry colname="col3">6.0</oasis:entry>
         <oasis:entry colname="col4">1.5</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">RCE (agg.)</oasis:entry>
         <oasis:entry colname="col2">122.5</oasis:entry>
         <oasis:entry colname="col3">2.4</oasis:entry>
         <oasis:entry colname="col4">0.5</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p id="d2e3035">Second, only a fraction of this already limited maximum work is realized as kinetic energy. As in moist RCE, this is because moist processes dominate the dissipation budget. The presence of active moisture redirects much of the available energy into compensating irreversible phase changes, leaving relatively little to sustain atmospheric circulation.</p>
      <p id="d2e3038">Beyond the inefficient generation of kinetic energy, stratocumulus perform substantial work in lifting water within the domain against the large-scale subsidence, which we estimate as

              <disp-formula id="Ch1.E15" content-type="numbered"><label>15</label><mml:math id="M117" display="block"><mml:mstyle displaystyle="true" class="stylechange"/><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mo>〈</mml:mo><mml:msub><mml:mover accent="true"><mml:mi>W</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi>q</mml:mi></mml:msub><mml:mo>〉</mml:mo><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mi>A</mml:mi></mml:mfrac></mml:mstyle><mml:munder><mml:mo movablelimits="false">∫</mml:mo><mml:mi mathvariant="normal">Ω</mml:mi></mml:munder><mml:mo>〈</mml:mo><mml:mi mathvariant="italic">ρ</mml:mi><mml:mi>g</mml:mi><mml:mi>w</mml:mi><mml:msub><mml:mi>q</mml:mi><mml:mi mathvariant="normal">t</mml:mi></mml:msub><mml:mo>〉</mml:mo><mml:mi mathvariant="normal">d</mml:mi><mml:mi>V</mml:mi><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>

        where <inline-formula><mml:math id="M118" display="inline"><mml:mrow><mml:msub><mml:mi>q</mml:mi><mml:mi mathvariant="normal">t</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the total water mixing ratio and <inline-formula><mml:math id="M119" display="inline"><mml:mi>w</mml:mi></mml:math></inline-formula> the resolved vertical velocity. Time-averaged values for <inline-formula><mml:math id="M120" display="inline"><mml:mrow><mml:mo>〈</mml:mo><mml:msub><mml:mover accent="true"><mml:mi>W</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi>q</mml:mi></mml:msub><mml:mo>〉</mml:mo></mml:mrow></mml:math></inline-formula> are 258 and <inline-formula><mml:math id="M121" display="inline"><mml:mrow><mml:mn mathvariant="normal">486</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mrow class="unit"><mml:mi mathvariant="normal">mW</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:mrow></mml:math></inline-formula> for the open- and closed-cell cases respectively, largely exceeding <inline-formula><mml:math id="M122" display="inline"><mml:mrow><mml:mo>〈</mml:mo><mml:msub><mml:mover accent="true"><mml:mi>W</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">K</mml:mi></mml:msub><mml:mo>〉</mml:mo></mml:mrow></mml:math></inline-formula> (24 and <inline-formula><mml:math id="M123" display="inline"><mml:mrow><mml:mn mathvariant="normal">68</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mrow class="unit"><mml:mi mathvariant="normal">mW</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:mrow></mml:math></inline-formula>). In RCE, at steady-state this work is balanced by the dissipation of kinetic energy by falling hydrometeors within the domain <xref ref-type="bibr" rid="bib1.bibx51" id="paren.59"/>. This balance does not hold in our simulations: open cells dissipate only approximately <inline-formula><mml:math id="M124" display="inline"><mml:mrow><mml:mn mathvariant="normal">183</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mrow class="unit"><mml:mi mathvariant="normal">mW</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:mrow></mml:math></inline-formula> through precipitation, while the non-drizzling closed-cell case has negligible precipitation dissipation. In the real atmosphere, the water removed by subsidence would eventually precipitate in other regions, where the associated dissipation would occur. However, since this process does not happen inside our simulation domain, the associated dissipation is not accounted for in our entropy budget.</p>
</sec>
<sec id="Ch1.S7">
  <label>7</label><title>An ensemble perspective</title>
      <p id="d2e3225">The two detailed simulations analyzed so far provide a thorough understanding of how entropy is produced in each morphology. We now ask whether these behaviors are representative for the two states. Extending the budget analysis to the ensemble tests the robustness of our findings and highlights the systems' variability under transient behavior. Many simulations in the ensemble are not fully equilibrated, exhibiting non-negligible temporal tendencies in key variables (such as <inline-formula><mml:math id="M125" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M126" display="inline"><mml:mi>L</mml:mi></mml:math></inline-formula>, and <inline-formula><mml:math id="M127" display="inline"><mml:mrow><mml:msub><mml:mi>z</mml:mi><mml:mtext>inv</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>), which can influence their entropy production. As mentioned earlier, the absence of full 3D fields limits our ability to compute all terms directly. Here we develop approximate formulas to estimate the entropy production using only horizontally averaged variables.</p>
      <p id="d2e3253">For the case of frictional dissipation and sedimentation, we find that simply replacing each variable in Eqs. (<xref ref-type="disp-formula" rid="Ch1.E6"/>) and (<xref ref-type="disp-formula" rid="Ch1.E10"/>) with their corresponding horizontally averaged values provides a very good estimate of the total entropy production. Water vapor diffusion is also reasonably well represented using horizontally averaged fluxes and fields. Heat diffusion in the closed-cell regime is less well captured, but given its low absolute contribution to the total entropy production, the resulting error does not significantly affect the overall budget. The dominant source of uncertainty is irreversible entropy production due to phase change.</p>
      <p id="d2e3260">To address this, we first separate the chemical term (Eq. <xref ref-type="disp-formula" rid="Ch1.E8"/>) into its condensation and evaporation parts. Condensation occurs entirely at or slightly above saturation, resulting in evaporation being the dominant contribution. We then follow <xref ref-type="bibr" rid="bib1.bibx62" id="text.60"/> and construct an effective relative humidity profile weighted by the evaporation field,

              <disp-formula id="Ch1.E16" content-type="numbered"><label>16</label><mml:math id="M128" display="block"><mml:mstyle class="stylechange" displaystyle="true"/><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:msub><mml:mover accent="true"><mml:mrow><mml:mi>ln⁡</mml:mi><mml:mo>(</mml:mo><mml:mi>R</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mtext>eff</mml:mtext></mml:msub><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mo>∫</mml:mo><mml:mi>A</mml:mi></mml:msub><mml:mi>ln⁡</mml:mi><mml:mo>(</mml:mo><mml:mi>R</mml:mi><mml:mo>)</mml:mo><mml:mi>E</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="normal">d</mml:mi><mml:mi>x</mml:mi><mml:mi mathvariant="normal">d</mml:mi><mml:mi>y</mml:mi></mml:mrow><mml:mrow><mml:msub><mml:mo>∫</mml:mo><mml:mi>A</mml:mi></mml:msub><mml:mi>E</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="normal">d</mml:mi><mml:mi>x</mml:mi><mml:mi mathvariant="normal">d</mml:mi><mml:mi>y</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mo>∫</mml:mo><mml:mi>A</mml:mi></mml:msub><mml:mi>ln⁡</mml:mi><mml:mo>(</mml:mo><mml:mi>R</mml:mi><mml:mo>)</mml:mo><mml:mi>E</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="normal">d</mml:mi><mml:mi>x</mml:mi><mml:mi mathvariant="normal">d</mml:mi><mml:mi>y</mml:mi></mml:mrow><mml:mover accent="true"><mml:mi>E</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:mfrac></mml:mstyle><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>

        with <inline-formula><mml:math id="M129" display="inline"><mml:mi>E</mml:mi></mml:math></inline-formula> the 3D evaporation field. The overbar indicates that the quantity is a vertical profile, result of horizontal averaging. With this, we can write the full chemical entropy production term as

              <disp-formula specific-use="align" content-type="numbered"><mml:math id="M130" display="block"><mml:mtable displaystyle="true"><mml:mtr><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:munder><mml:mo movablelimits="false">∫</mml:mo><mml:mi mathvariant="normal">Ω</mml:mi></mml:munder><mml:mi mathvariant="italic">ρ</mml:mi><mml:msubsup><mml:mover accent="true"><mml:mi>s</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">i</mml:mi><mml:mtext>chem</mml:mtext></mml:msubsup></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mo>=</mml:mo><mml:mo>-</mml:mo><mml:munder><mml:mo movablelimits="false">∫</mml:mo><mml:mi mathvariant="normal">Ω</mml:mi></mml:munder><mml:mi>e</mml:mi><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:mi>ln⁡</mml:mi><mml:mo>(</mml:mo><mml:mi>R</mml:mi><mml:mo>)</mml:mo><mml:mo>≈</mml:mo><mml:mo>-</mml:mo><mml:munder><mml:mo movablelimits="false">∫</mml:mo><mml:mi mathvariant="normal">Ω</mml:mi></mml:munder><mml:mi>E</mml:mi><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:mi>ln⁡</mml:mi><mml:mo>(</mml:mo><mml:mi>R</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:mtd></mml:mtr><mml:mlabeledtr id="Ch1.E17"><mml:mtd><mml:mtext>17</mml:mtext></mml:mtd><mml:mtd><mml:mstyle class="stylechange" displaystyle="true"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:mo>=</mml:mo><mml:mo>-</mml:mo><mml:munder><mml:mo movablelimits="false">∫</mml:mo><mml:mrow><mml:msub><mml:mi mathvariant="normal">Ω</mml:mi><mml:mi>z</mml:mi></mml:msub></mml:mrow></mml:munder><mml:mover accent="true"><mml:mi>E</mml:mi><mml:mo mathvariant="normal">¯</mml:mo></mml:mover><mml:msub><mml:mi>R</mml:mi><mml:mi mathvariant="normal">v</mml:mi></mml:msub><mml:msub><mml:mover accent="true"><mml:mrow><mml:mi>ln⁡</mml:mi><mml:mo>(</mml:mo><mml:mi>R</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mtext>eff</mml:mtext></mml:msub><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="normal">d</mml:mi><mml:mi>z</mml:mi><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula>

        which requires only vertical profiles to be computed. By doing this, we shift the burden of knowing the 3D fields of both evaporation and relative humidity to the requirement of obtaining the horizontally averaged profile of the effective relative humidity.</p>
      <p id="d2e3513">When evaporation stems mainly from precipitation, as is the case for RCE or stratocumulus open cells, the effective relative humidity field is only slightly higher than the horizontal mean <xref ref-type="bibr" rid="bib1.bibx62" id="paren.61"/>. For open-cell cases, we find that using Eq. (<xref ref-type="disp-formula" rid="Ch1.E16"/>) with the domain-mean <inline-formula><mml:math id="M131" display="inline"><mml:mover accent="true"><mml:mi>R</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula> provides a reasonable approximation of the condensation-evaporation contribution. In closed cells, however, all the moist production happens in the inversion layer, where sharp gradients make the relation between the effective relative humidity and the mean one non-trivial. We utilize the detailed closed-cell simulation to parameterize <inline-formula><mml:math id="M132" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mrow><mml:mi>ln⁡</mml:mi><mml:mo>(</mml:mo><mml:mi>R</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mtext>eff</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>, in order for it to be reconstructed using only the information available in all the simulations, i.e. vertical profiles.</p>
      <p id="d2e3553">Comparison of effective and mean profiles in the detailed run shows that the difference between them is confined to the entrainment layer, where the effective term remains higher well above cloud-top (see Fig. <xref ref-type="fig" rid="FA7"/>). This is due to the strong spatial correlation between the relative humidity and evaporation combined with the sharp inversion, which makes local spatial features stand out. Since the difference between the effective relative humidity and the spatial mean relative humidity is localized around the inversion, we parameterise this difference with a pulse-like function centered on the inversion. We find that the function's parameters can be easily tied to key physical quantities of the system, such as inversion height, cloud-top height, and inversion strength. For full details on the reconstruction, see Appendix <xref ref-type="sec" rid="App1.Ch1.S2"/>.</p>
      <p id="d2e3560">This approach allows a rough but practical parameterization of the effective field based on general boundary layer features and vertical profiles, which are available for all simulations in the ensemble. In this way, we can reconstruct the effective relative humidity profile, and therefore the moist production, using a minimal approach that allows us to take into account the variability between different ensemble members. Compared with directly using the mean vertical humidity profile, this procedure reduces the estimated moist entropy production by roughly <inline-formula><mml:math id="M133" display="inline"><mml:mrow><mml:mn mathvariant="normal">40</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:mrow></mml:math></inline-formula> (Fig. <xref ref-type="fig" rid="FA7"/>). While we cannot validate the procedure for all closed-cell runs, the behavior of the reconstructed moist production profiles across the ensemble matches what is observed in the detailed simulation (Fig. <xref ref-type="fig" rid="FA8"/>). This method provides a sufficient estimate of the domain-mean moist production, and a reasonable ensemble-averaged value, particularly given the large number (<inline-formula><mml:math id="M134" display="inline"><mml:mrow><mml:mo>&gt;</mml:mo><mml:mn mathvariant="normal">100</mml:mn></mml:mrow></mml:math></inline-formula>) of closed-cell cases available.</p>
      <p id="d2e3590">Applying this reconstruction procedure, we estimate the internal entropy production across the ensemble (Fig. <xref ref-type="fig" rid="F4"/>, Table <xref ref-type="table" rid="T3"/>). As for the detailed cases, we find that, on average, closed-cell simulations exhibit a larger total production than open cells, driven by the strong cloud-top entrainment that dominates irreversibility in closed cells. The few open-cell outliers with unusually high values correspond to unsteady runs with strong negative tendencies in their entropy production. The detailed closed-cell case proves to be representative of the ensemble, while the detailed open-cell case lies at the lower end of the distribution. Both morphologies show considerable spread, reflecting the non-equilibrated nature of the simulations, and possible sensitivities to droplet number concentrations. Although liquid water path is nearly stabilized, droplet number concentration and inversion height still evolve substantially.</p>

      <fig id="F4" specific-use="star"><label>Figure 4</label><caption><p id="d2e3599">Ensemble projection of entropy production. Panel <bold>(a)</bold> shows the reconstruction of the total, time- and domain-averaged entropy production for the full LES ensemble, computed over the last hour of each simulation. Each point represents the domain-mean values of <inline-formula><mml:math id="M135" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> (droplet number concentration) and <inline-formula><mml:math id="M136" display="inline"><mml:mi>L</mml:mi></mml:math></inline-formula> (liquid water path), averaged over that last hour, with the color indicating the corresponding total internal entropy production. The light blue shaded region in the background represents the <inline-formula><mml:math id="M137" display="inline"><mml:mi>L</mml:mi></mml:math></inline-formula> steady-state, extracted from the ensemble using Gaussian emulation <xref ref-type="bibr" rid="bib1.bibx20 bib1.bibx30 bib1.bibx7" id="paren.62"/>. Panel <bold>(b)</bold> shows the distributions of the internal entropy production for the open- and closed-cell states, computed as in panel <bold>(a)</bold>.</p></caption>
        <graphic xlink:href="https://acp.copernicus.org/articles/26/9337/2026/acp-26-9337-2026-f04.png"/>

      </fig>

<table-wrap id="T3" specific-use="star"><label>Table 3</label><caption><p id="d2e3645">Entropy production and efficiency approximation for the full LES ensemble. Values represent the median across the whole ensemble of simulations, computed from spatially averaged fields over the domain and temporally averaged over the final simulation hour. Values in brackets indicate the 25th–75th percentiles.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="3">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:thead>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">Open</oasis:entry>
         <oasis:entry colname="col3">Closed</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">Entropy Production (<inline-formula><mml:math id="M138" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mW</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">K</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">3.4 [2.4–4.9]</oasis:entry>
         <oasis:entry colname="col3">5.2 [3.8–6.5]</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Frictional Dissipation (<inline-formula><mml:math id="M139" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">3 [3–4]</oasis:entry>
         <oasis:entry colname="col3">5 [5–6]</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Moist processes (<inline-formula><mml:math id="M140" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">72 [66–76]</oasis:entry>
         <oasis:entry colname="col3">87 [86–88]</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Precipitation (<inline-formula><mml:math id="M141" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">23 [18–28]</oasis:entry>
         <oasis:entry colname="col3">0 [0–0]</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Heat Diffusion (<inline-formula><mml:math id="M142" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">2 [1–2]</oasis:entry>
         <oasis:entry colname="col3">8 [7–8]</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Efficiency (<inline-formula><mml:math id="M143" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">0.03 [0.02–0.04]</oasis:entry>
         <oasis:entry colname="col3">0.07 [0.05–0.08]</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p id="d2e3816">The term-by-term breakdown is summarized in Table <xref ref-type="table" rid="T3"/>. These ensemble results confirm the main findings from the detailed, single-case analyses: moist processes dominate the total dissipation, frictional dissipation remains small, and closed cells have a higher efficiency than open cells.</p>
      <p id="d2e3821">Furthermore, both morphologies show, on average, a higher share of entropy production attributable to moist processes compared to previous RCE results <xref ref-type="bibr" rid="bib1.bibx51 bib1.bibx63" id="paren.63"/>. This is consistent with previous work of <xref ref-type="bibr" rid="bib1.bibx50" id="text.64"/>, who extracted thermodynamic cycles of different depths from RCE convection and found that shallower cycles show a higher share of moist processes compared to deeper ones. Together with the results presented in this paper, this supports the relative importance of moist processes scaling inversely with the depth of the thermodynamic cycle.</p>
</sec>
<sec id="Ch1.S8" sec-type="conclusions">
  <label>8</label><title>Discussion and Conclusion</title>
      <p id="d2e3838">In this work we analyzed the internal entropy production of stratocumulus clouds, applying the entropy budget formalism that has so far been established for and applied to deep convection to both the open- and closed-cell morphologies. Our results reveal substantial differences in the partitioning of the entropy budget between the two states. As in earlier work on Radiative Convective Equilibrium <xref ref-type="bibr" rid="bib1.bibx51 bib1.bibx52 bib1.bibx62 bib1.bibx63" id="paren.65"/>, moist processes dominate the total production in both regimes. We further identified how this dominant term reflects regime-specific processes: cloud-top entrainment in closed cells and cold-pool dynamics in open cells.</p>
      <p id="d2e3844">Unlike in RCE, stratocumulus exhibit an exceptionally small total dissipation. This limitation can be traced to their shallow vertical development, which constrains the available temperature gradient and thereby the maximum possible work. However, we note how, inside the stratocumulus regimes, the dissipation does not scale trivially with system size (e.g. inversion height), but instead depends on the specific organization of the cloud field and its properties (such as effective temperatures of energy exchange). This explains why stratocumulus convection remains mechanically weak, despite strong boundary fluxes, and why the system is characterized by such a low thermodynamic efficiency.</p>
      <p id="d2e3847">Recent work <xref ref-type="bibr" rid="bib1.bibx63" id="paren.66"/> suggests that convective organization itself modulates efficiency. In RCE, long integrations often exhibit self-aggregation <xref ref-type="bibr" rid="bib1.bibx4 bib1.bibx10" id="paren.67"/>, which reshapes the balance between frictional dissipation and moist processes. Stratocumulus, by contrast, represents a highly regular, space-filling form of organization <xref ref-type="bibr" rid="bib1.bibx18" id="paren.68"/>. In closed-cell states, nearly the entire domain experiences cloud-top drying, with cloud fraction close to unity. This results from the absence of precipitation, which otherwise would break up cloud cover. Interestingly, while moist processes dominate the entropy budget far more strongly than in RCE, the lack of precipitation still leaves a relatively large share for kinetic dissipation, comparable to aggregated RCE <xref ref-type="bibr" rid="bib1.bibx63" id="paren.69"/>. Open-cell organization, driven by precipitation, also shows a comparable fraction, only slightly lower than that in closed cells, relative to its total entropy production. This suggests that using the entropy budget to constrain dissipation can be difficult, since systems with vastly different dynamics and irreversible mechanisms can exhibit similar total frictional dissipation.</p>
      <p id="d2e3862">A key aspect of our analysis is the ensemble perspective. Mesoscale Stratocumulus boundary layers are never in steady-state. While liquid water path can relax on relatively short timescales <xref ref-type="bibr" rid="bib1.bibx61 bib1.bibx5" id="paren.70"/>, droplet number concentration and inversion height often evolve on timescales comparable to those of the large-scale cloud controlling variables <xref ref-type="bibr" rid="bib1.bibx9" id="paren.71"/>. In such situations, a single simulation cannot be considered representative, since the system's trajectory strongly depends on its initial conditions. By utilizing a large ensemble, we are able to extract robust statistics. While the median total entropy production differs between the two morphologies, the considerable overlap between the two distributions suggests that entropy production alone is not sufficient to cleanly distinguish between open- and closed-cell convection.</p>
      <p id="d2e3872">The transient nature of our simulations, however, still poses some limitations. While the terms analyzed in this study can be considered steady on the timescale analyzed, the system still contains strong internal tendencies. This is the main reason why we chose to focus on the internal production directly, and did not try to diagnose it by means of the external export (see Eq. <xref ref-type="disp-formula" rid="Ch1.E4"/>). While the external view can provide important insights into how the system exchanges energy and mass at its boundary, in our case it is of limited applicability.</p>
      <p id="d2e3877">Our results also provide insights into the relationship between multistability and entropy production. For non-equilibrium systems, much work has been devoted to characterizing how nature selects the fate of a system, especially when there may be multiple possible steady states. Theories exist for linear systems close to equilibrium <xref ref-type="bibr" rid="bib1.bibx45 bib1.bibx56" id="paren.72"/>, but for systems far from equilibrium, there is currently no consensus on how and if the long-term evolution of the system can be predicted without explicit simulation of its temporal trajectory. One hypothesis is the maximum entropy production principle <xref ref-type="bibr" rid="bib1.bibx48 bib1.bibx47 bib1.bibx36" id="paren.73"/>, which suggests that systems select states that maximize dissipation, though its validity remains debated. In multi-stable situations, it has been recently argued that nature selects the state that dissipates the most <xref ref-type="bibr" rid="bib1.bibx11" id="paren.74"/>, with the principle formulated probabilistically, relating total dissipation to stability.</p>
      <p id="d2e3889">In our stratocumulus case, we find that, although the median internal entropy production differs between the open- and closed-cell states, their distributions largely overlap. A stochastic analysis of our LES ensemble shows that the probabilistic landscape is not symmetric, with the open-cell state being the more stable of the two <xref ref-type="bibr" rid="bib1.bibx25" id="paren.75"/>. Therefore, the total irreversible entropy production does not appear to select the observed state, and the open-cell configuration, contrary to a maximum entropy production expectation, instead has a lower median dissipation. Both stable states exhibit similar entropy production magnitudes but are governed by different feedbacks and dynamics.</p>
</sec>

      
      </body>
    <back><app-group>

<app id="App1.Ch1.S1">
  <label>Appendix A</label><title>Subgrid-scale turbulent kinetic energy budget</title>
      <p id="d2e3906">To understand differences in turbulent kinetic energy (TKE) dissipation between open and closed cells, we analyze the subgrid-scale (sgs) TKE budget, which can formally be written as

              <disp-formula id="App1.Ch1.S1.E18" content-type="numbered"><label>A1</label><mml:math id="M144" display="block"><mml:mstyle displaystyle="true" class="stylechange"/><mml:mrow><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mo>∂</mml:mo><mml:mi>e</mml:mi></mml:mrow><mml:mrow><mml:mo>∂</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>=</mml:mo><mml:msub><mml:mi>P</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>P</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:mi>T</mml:mi><mml:mo>-</mml:mo><mml:mi mathvariant="italic">ϵ</mml:mi><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>

        where <inline-formula><mml:math id="M145" display="inline"><mml:mi>e</mml:mi></mml:math></inline-formula> is the sgs TKE. The right-hand side consists of shear production <inline-formula><mml:math id="M146" display="inline"><mml:mrow><mml:msub><mml:mi>P</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, buoyancy production <inline-formula><mml:math id="M147" display="inline"><mml:mrow><mml:msub><mml:mi>P</mml:mi><mml:mi mathvariant="normal">b</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, transport <inline-formula><mml:math id="M148" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula>, and sgs dissipation <inline-formula><mml:math id="M149" display="inline"><mml:mi mathvariant="italic">ϵ</mml:mi></mml:math></inline-formula>, which contributes to the frictional dissipation in Eq. (<xref ref-type="disp-formula" rid="Ch1.E5"/>). When spatially integrated over the domain, the transport term vanishes.</p>
      <p id="d2e3998">Figure <xref ref-type="fig" rid="FA9"/> shows the integrated sgs budget for the two runs. We observe how, after a brief equilibration, dissipation is almost completely dominated by shear production,

              <disp-formula id="App1.Ch1.S1.E19" content-type="numbered"><label>A2</label><mml:math id="M150" display="block"><mml:mstyle class="stylechange" displaystyle="true"/><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:munder><mml:mo movablelimits="false">∫</mml:mo><mml:mi mathvariant="normal">Ω</mml:mi></mml:munder><mml:mi mathvariant="italic">ϵ</mml:mi><mml:mi mathvariant="normal">d</mml:mi><mml:mi>V</mml:mi><mml:mo>≈</mml:mo><mml:munder><mml:mo movablelimits="false">∫</mml:mo><mml:mi mathvariant="normal">Ω</mml:mi></mml:munder><mml:msub><mml:mi>P</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mi mathvariant="normal">d</mml:mi><mml:mi>V</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula>

        Shear production is notably higher in closed cells, primarily due to strong cloud-top entrainment characteristic of stratocumulus. As seen in Fig. <xref ref-type="fig" rid="FA10"/>, the largest contributions occur at the entrainment layer, where the sgs shear is strongest. These differences are robust across the ensemble, explaining why closed cells generally experience higher frictional dissipation and, consequently, a higher mechanical efficiency than open cells.</p>

      <fig id="FA1"><label>Figure A1</label><caption><p id="d2e4044">Energy export for the detailed open cell and closed cell runs. For both scenarios, both energy fluxes act as net sinks for the system. The temperatures reported are effective temperatures, computed by weighting the respective heating tendency over the whole domain, following <xref ref-type="bibr" rid="bib1.bibx63" id="text.76"/>. The values here reported have been averaged in time over the last simulation hour.</p></caption>
        <graphic xlink:href="https://acp.copernicus.org/articles/26/9337/2026/acp-26-9337-2026-f05.png"/>

      </fig>

<fig id="FA2"><label>Figure A2</label><caption><p id="d2e4060">Comparison of horizontal and vertical diffusion contributions. Time-averaged horizontal and vertical contributions to the entropy production from diffusion of water vapor (Eq. <xref ref-type="disp-formula" rid="Ch1.E9"/>) and sensible heat (Eq. <xref ref-type="disp-formula" rid="Ch1.E7"/>) for the open- <bold>(a)</bold> and closed- <bold>(b)</bold> cell cases. The terms are integrated up to <inline-formula><mml:math id="M151" display="inline"><mml:mrow><mml:msub><mml:mi>z</mml:mi><mml:mtext>max</mml:mtext></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1500</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:mrow></mml:math></inline-formula> and normalized by the domain surface area. Values are averaged over the last simulation hour, with whiskers indicating <inline-formula><mml:math id="M152" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula> standard deviation over time. Horizontal contributions account for approximately <inline-formula><mml:math id="M153" display="inline"><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M154" display="inline"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:mrow></mml:math></inline-formula> of the total for water vapor mixing in the open- and closed-cell cases respectively, and less than <inline-formula><mml:math id="M155" display="inline"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mrow class="unit"><mml:mi mathvariant="normal">%</mml:mi></mml:mrow></mml:mrow></mml:math></inline-formula> for sensible heat in both cases.</p></caption>
        
        <graphic xlink:href="https://acp.copernicus.org/articles/26/9337/2026/acp-26-9337-2026-f06.png"/>

      </fig>

      <fig id="FA3"><label>Figure A3</label><caption><p id="d2e4149">Comparison of system scales between RCE and stratocumulus clouds. The RCE temperature profile (dashed line) is taken from the moist RCE simulation in <xref ref-type="bibr" rid="bib1.bibx63" id="text.77"/>. For the stratocumulus cases, the darker line corresponds to the detailed closed-cell simulation, while the lighter line corresponds to the detailed open-cell simulation. The inset shows a zoomed-in view of the vertical temperature structure for the stratocumulus cases.</p></caption>
        
        <graphic xlink:href="https://acp.copernicus.org/articles/26/9337/2026/acp-26-9337-2026-f07.png"/>

      </fig>

<fig id="FA4"><label>Figure A4</label><caption><p id="d2e4166">Moist production in open cells. Panel <bold>(a)</bold> shows the time series of domain-mean moist entropy production <inline-formula><mml:math id="M156" display="inline"><mml:mrow><mml:msubsup><mml:mover accent="true"><mml:mi>S</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">i</mml:mi><mml:mtext>moist</mml:mtext></mml:msubsup></mml:mrow></mml:math></inline-formula> and the surface equivalent potential temperature anomaly, conditioned on cold-pool regions (<inline-formula><mml:math id="M157" display="inline"><mml:mrow><mml:mover accent="true"><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">θ</mml:mi><mml:mi mathvariant="normal">e</mml:mi><mml:mo>′</mml:mo></mml:msubsup><mml:mo>&lt;</mml:mo><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.5</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:mrow><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>. Panel <bold>(b)</bold> shows the moist entropy production, separated into contributions from rainy (Precipitating) and non-rainy (Non-precipitating) columns, using a total rain water threshold of 1 <inline-formula><mml:math id="M158" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">g</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">kg</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>.</p></caption>
        
        <graphic xlink:href="https://acp.copernicus.org/articles/26/9337/2026/acp-26-9337-2026-f08.png"/>

      </fig>

      <fig id="FA5"><label>Figure A5</label><caption><p id="d2e4247">Moist production in closed cells. Panel <bold>(a)</bold> shows the time series of domain-mean moist entropy production <inline-formula><mml:math id="M159" display="inline"><mml:mrow><mml:msubsup><mml:mover accent="true"><mml:mi>S</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">i</mml:mi><mml:mtext>moist</mml:mtext></mml:msubsup></mml:mrow></mml:math></inline-formula> together with the domain-mean entrainment velocity. Panel <bold>(b)</bold> displays the horizontally averaged moist production profile, with each column rescaled and centered around the cloud-top height on the vertical axis.</p></caption>
        
        <graphic xlink:href="https://acp.copernicus.org/articles/26/9337/2026/acp-26-9337-2026-f09.png"/>

      </fig>

<fig id="FA6"><label>Figure A6</label><caption><p id="d2e4284">Energy balance for <bold>(a)</bold> open-cell and <bold>(b)</bold> closed-cell stratocumulus. The columns represent, respectively: radiative cooling, surface fluxes (<inline-formula><mml:math id="M160" display="inline"><mml:mrow><mml:msub><mml:mi>F</mml:mi><mml:mtext>sh</mml:mtext></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>F</mml:mi><mml:mtext>lh</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>), subsidence, total tendency and residual. Whiskers indicate one standard deviation over time. The terms are integrated over the full simulation domain up to <inline-formula><mml:math id="M161" display="inline"><mml:mrow><mml:msub><mml:mi>z</mml:mi><mml:mtext>max</mml:mtext></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1500</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M162" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> and normalized by the domain surface area. The values here reported have been averaged in time over the last simulation hour.</p></caption>
        
        <graphic xlink:href="https://acp.copernicus.org/articles/26/9337/2026/acp-26-9337-2026-f10.png"/>

      </fig>

      <fig id="FA7"><label>Figure A7</label><caption><p id="d2e4344">Reconstruction of effective relative humidity. Panel <bold>(a)</bold> shows the fit to the difference between the time averaged effective and actual relative humidity. Panel <bold>(b)</bold> shows the time averaged profiles of the actual, effective, and reconstructed relative humidity using Eq. (<xref ref-type="disp-formula" rid="App1.Ch1.S2.E21"/>). Panel <bold>(c)</bold> shows the estimated entropy production from non-equilibrium phase changes when the effective humidity of evaporation is estimated using the full 3D data (<inline-formula><mml:math id="M163" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mrow><mml:mi>log⁡</mml:mi><mml:mo>(</mml:mo><mml:mi>R</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mtext>eff</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>), the horizontal-mean relative humidity (<inline-formula><mml:math id="M164" display="inline"><mml:mover accent="true"><mml:mrow><mml:mi>log⁡</mml:mi><mml:mo>(</mml:mo><mml:mi>R</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula>), and the reconstructed relative humidity based on Eq. (<xref ref-type="disp-formula" rid="App1.Ch1.S2.E20"/>) (<inline-formula><mml:math id="M165" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mrow><mml:mi>log⁡</mml:mi><mml:mo>(</mml:mo><mml:mi>R</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mtext>rec</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>). Whiskers show one standard deviation in time.</p></caption>
        
        <graphic xlink:href="https://acp.copernicus.org/articles/26/9337/2026/acp-26-9337-2026-f11.png"/>

      </fig>

<fig id="FA8"><label>Figure A8</label><caption><p id="d2e4431">Reconstruction procedure for an ensemble member. Panel <bold>(a)</bold> shows the profile of the moist entropy production for the full closed-cell detailed simulation, for which the exact computation of the effective relative humidity field is possible, following Eq. (<xref ref-type="disp-formula" rid="App1.Ch1.S2.E20"/>). In panel <bold>(b)</bold> we show the reconstruction for a random closed-cell ensemble member.</p></caption>
        
        <graphic xlink:href="https://acp.copernicus.org/articles/26/9337/2026/acp-26-9337-2026-f12.png"/>

      </fig>

      <fig id="FA9"><label>Figure A9</label><caption><p id="d2e4452">Subgrid-scale TKE budget.  Panel <bold>(a)</bold> shows results for the closed-cell detailed case, and panel <bold>(b)</bold> for the detailed open-cell case. All terms are spatially averaged.</p></caption>
        
        <graphic xlink:href="https://acp.copernicus.org/articles/26/9337/2026/acp-26-9337-2026-f13.png"/>

      </fig>

<fig id="FA10"><label>Figure A10</label><caption><p id="d2e4473">Vertical profiles of subgrid-scale TKE shear production. Panels <bold>(a)</bold> and <bold>(b)</bold> show profiles for the detailed simulations, averaged over the last 1 <inline-formula><mml:math id="M166" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:math></inline-formula>. Panel <bold>(a)</bold> shows the slab-averaged vertical distribution (tendency), while panel <bold>(b)</bold> shows the slab-averaged cumulative vertical integral.</p></caption>
        
        <graphic xlink:href="https://acp.copernicus.org/articles/26/9337/2026/acp-26-9337-2026-f14.png"/>

      </fig>

</app>

<app id="App1.Ch1.S2">
  <label>Appendix B</label><title>Reconstruction of effective relative humidity</title>
      <p id="d2e4512">Here we describe how we estimate the irreversible entropy production associated with evaporation using only horizontally averaged variables, since we have access to the full 3D fields for only two simulations in the ensemble. To do so, we must estimate the effective relative humidity of evaporation <inline-formula><mml:math id="M167" display="inline"><mml:mrow><mml:msub><mml:mi>R</mml:mi><mml:mtext>eff</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> defined in Eq. (<xref ref-type="disp-formula" rid="Ch1.E16"/>). A starting point is to use the horizontally averaged mean relative humidity profile <inline-formula><mml:math id="M168" display="inline"><mml:mover accent="true"><mml:mi>R</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula>. However, as shown in Fig. <xref ref-type="fig" rid="FA7"/>, this produces a substantial under estimate of the relative humidity at which evaporation occurs in the entrainment layer just above the cloud top. Instead, we perform a simple fitting procedure for the difference between the <inline-formula><mml:math id="M169" display="inline"><mml:mover accent="true"><mml:mi>R</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula> and <inline-formula><mml:math id="M170" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>R</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mtext>eff</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> that depends on the inversion height and strength. Specifically, we define a reconstructed relative humidity <inline-formula><mml:math id="M171" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mi>R</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mtext>rec</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> so that

              <disp-formula id="App1.Ch1.S2.E20" content-type="numbered"><label>B1</label><mml:math id="M172" display="block"><mml:mstyle class="stylechange" displaystyle="true"/><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:msub><mml:mover accent="true"><mml:mrow><mml:mi>log⁡</mml:mi><mml:mo>(</mml:mo><mml:mi>R</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mtext>rec</mml:mtext></mml:msub><mml:mo>=</mml:mo><mml:mover accent="true"><mml:mrow><mml:mi>log⁡</mml:mi><mml:mo>(</mml:mo><mml:mi>R</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mo>+</mml:mo><mml:mi>A</mml:mi><mml:mi>exp⁡</mml:mi><mml:mo mathsize="2.5em">[</mml:mo><mml:mo>-</mml:mo><mml:mo mathsize="1.5em">(</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mi>z</mml:mi><mml:mo>-</mml:mo><mml:msub><mml:mi>z</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow><mml:mi>w</mml:mi></mml:mfrac></mml:mstyle><mml:msup><mml:mo mathsize="1.5em">)</mml:mo><mml:mi>n</mml:mi></mml:msup><mml:mo mathsize="2.5em">]</mml:mo><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>

        with fitting parameters approximated by

              <disp-formula specific-use="align" content-type="numbered"><mml:math id="M173" display="block"><mml:mtable displaystyle="true"><mml:mlabeledtr id="App1.Ch1.S2.E21"><mml:mtd><mml:mtext>B2</mml:mtext></mml:mtd><mml:mtd><mml:mstyle class="stylechange" displaystyle="true"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:msub><mml:mi>z</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi>z</mml:mi><mml:mtext>inv</mml:mtext></mml:msub><mml:mo>+</mml:mo><mml:mo mathsize="1.1em">(</mml:mo><mml:msub><mml:mi>z</mml:mi><mml:mtext>inv</mml:mtext></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi>z</mml:mi><mml:mtext>ct</mml:mtext></mml:msub><mml:mo mathsize="1.1em">)</mml:mo><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="App1.Ch1.S2.E22"><mml:mtd><mml:mtext>B3</mml:mtext></mml:mtd><mml:mtd><mml:mstyle class="stylechange" displaystyle="true"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mi>w</mml:mi><mml:mo>=</mml:mo><mml:msub><mml:mi>z</mml:mi><mml:mtext>inv</mml:mtext></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi>z</mml:mi><mml:mtext>ct</mml:mtext></mml:msub><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="App1.Ch1.S2.E23"><mml:mtd><mml:mtext>B4</mml:mtext></mml:mtd><mml:mtd><mml:mstyle displaystyle="true" class="stylechange"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:mi>A</mml:mi><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">2</mml:mn><mml:mn mathvariant="normal">3</mml:mn></mml:mfrac></mml:mstyle><mml:mi mathvariant="normal">Δ</mml:mi><mml:mover accent="true"><mml:mrow><mml:mi>log⁡</mml:mi><mml:mo>(</mml:mo><mml:mi>R</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula>

        
        where <inline-formula><mml:math id="M174" display="inline"><mml:mrow><mml:msub><mml:mi>z</mml:mi><mml:mtext>inv</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M175" display="inline"><mml:mrow><mml:msub><mml:mi>z</mml:mi><mml:mtext>ct</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> are the inversion height and cloud-top height, respectively, and <inline-formula><mml:math id="M176" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mover accent="true"><mml:mrow><mml:mi>log⁡</mml:mi><mml:mo>(</mml:mo><mml:mi>R</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:mrow></mml:math></inline-formula> is the jump in <inline-formula><mml:math id="M177" display="inline"><mml:mover accent="true"><mml:mrow><mml:mi>log⁡</mml:mi><mml:mo>(</mml:mo><mml:mi>R</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula> at the inversion. We find that approximating <inline-formula><mml:math id="M178" display="inline"><mml:mrow><mml:msub><mml:mi>z</mml:mi><mml:mtext>inv</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> with the middle point in the inversion jump for the relative humidity profile works best for the reconstruction. The exponent <inline-formula><mml:math id="M179" display="inline"><mml:mi>n</mml:mi></mml:math></inline-formula> is fixed at 2.7, and the fit is obtained via a least-squares procedure.</p>
      <p id="d2e4843">Using <inline-formula><mml:math id="M180" display="inline"><mml:mrow><mml:msub><mml:mover accent="true"><mml:mrow><mml:mi>log⁡</mml:mi><mml:mo>(</mml:mo><mml:mi>R</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mtext>rec</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>, we now estimate the entropy production associated with evaporation as

              <disp-formula id="App1.Ch1.S2.E24" content-type="numbered"><label>B5</label><mml:math id="M181" display="block"><mml:mstyle class="stylechange" displaystyle="true"/><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:msubsup><mml:mover accent="true"><mml:mi>s</mml:mi><mml:mo mathvariant="normal">˙</mml:mo></mml:mover><mml:mi mathvariant="normal">i</mml:mi><mml:mtext>evap</mml:mtext></mml:msubsup><mml:mo>=</mml:mo><mml:munder><mml:mo movablelimits="false">∫</mml:mo><mml:mi>z</mml:mi></mml:munder><mml:mover accent="true"><mml:mi>E</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msub><mml:mover accent="true"><mml:mrow><mml:mi>log⁡</mml:mi><mml:mo>(</mml:mo><mml:mi>R</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mtext>rec</mml:mtext></mml:msub><mml:mi mathvariant="normal">d</mml:mi><mml:mi>z</mml:mi></mml:mrow></mml:math></disp-formula></p>
      <p id="d2e4916">This equation depends only on horizontally averaged terms, and therefore may be calculated for all ensemble members.</p>
      <p id="d2e4919">Figure <xref ref-type="fig" rid="FA7"/> illustrates this reconstruction for the detailed closed-cell simulation, showing the quality of the fit and of the reconstruction. In Fig. <xref ref-type="fig" rid="FA8"/> we show the procedure applied to a random ensemble member, for which 3D output is not available.</p>
</app>
  </app-group><notes notes-type="codedataavailability"><title>Code and data availability</title>

      <p id="d2e4930">The data and analysis notebooks required to reproduce the figures in the main text are archived in a public repository (<ext-link xlink:href="https://doi.org/10.5281/zenodo.18662163" ext-link-type="DOI">10.5281/zenodo.18662163</ext-link>, <xref ref-type="bibr" rid="bib1.bibx24" id="altparen.78"/>). Input files and the model code for reproducing the simulation data of this study are available from the authors upon request.</p>
  </notes><notes notes-type="authorcontribution"><title>Author contributions</title>

      <p id="d2e4942">FG and MSS conceived the study. BH carried out the analysis and wrote the initial draft. TY and GF provided the data. All authors interpreted the results and revised the manuscript.</p>
  </notes><notes notes-type="competinginterests"><title>Competing interests</title>

      <p id="d2e4949">At least one of the (co-)authors is a member of the editorial board of <italic>Atmospheric Chemistry and Physics</italic>. The peer-review process was guided by an independent editor, and the authors also have no other competing interests to declare.</p>
  </notes><notes notes-type="disclaimer"><title>Disclaimer</title>

      <p id="d2e4958">Views and opinions expressed are however those of the authors only and do not necessarily reflect those of the European Union or the European Research Council Executive Agency. Neither the European Union nor the granting authority can be held responsible for them.Publisher's note: Copernicus Publications remains neutral with regard to jurisdictional claims made in the text, published maps, institutional affiliations, or any other geographical representation in this paper. The authors bear the ultimate responsibility for providing appropriate place names. Views expressed in the text are those of the authors and do not necessarily reflect the views of the publisher.</p>
  </notes><ack><title>Acknowledgements</title><p id="d2e4967">We thank Olivier Pauluis and the two anonymous reviewers for their helpful and constructive comments. Generative AI tools were used for grammar and spell checking, minor text revisions, and for debugging parts of the analysis code. All text and code were reviewed and tested by the authors, who take full responsibility for the results and conclusions.</p></ack><notes notes-type="financialsupport"><title>Financial support</title>

      <p id="d2e4972">BH and FG acknowledge support from The Branco Weiss Fellowship  –  Society in Science, administered by ETH Zurich. FG also acknowledges support by the European Union (ERC, MesoClou, 101117462).  MS acknowledges funding from the Australian Research Council under grants CE230100012 and DP230102077. TY and GF received support from the US Department of Energy (DOE), Office of Science, Office of Biological and Environmental Research, Atmospheric System Research (ASR) program (Interagency Award Number 89243023SSC000114), the US Department of Commerce (DOC), National Oceanic and Atmospheric Administration (NOAA) Climate Program Office as part of the Earth's Radiation Budget (ERB) program (award no. 03-01-07-001), and NOAA cooperative agreement (grant no. NA22OAR4320151).</p>
  </notes><notes notes-type="reviewstatement"><title>Review statement</title>

      <p id="d2e4978">This paper was edited by Thijs Heus and reviewed by Olivier Pauluis and three anonymous referees.</p>
  </notes><ref-list>
    <title>References</title>

      <ref id="bib1.bibx1"><label>Alinaghi et al.(2025)</label><mixed-citation>Alinaghi, P., Janssens, M., and Jansson, F.: Warming from cold pools: a pathway for mesoscale organization to alter Earth's radiation budget, P. Natl. Acad. Sci. USA USA, 122, e2513699122, <ext-link xlink:href="https://doi.org/10.1073/pnas.2513699122" ext-link-type="DOI">10.1073/pnas.2513699122</ext-link>, 2025.</mixed-citation></ref>
      <ref id="bib1.bibx2"><label>Baker and Charlson(1990)</label><mixed-citation>Baker, M. B. and Charlson, R. J.: Bistability of CCN concentrations and thermodynamics in the cloud-topped boundary layer, Nature, 345, 142–145, <ext-link xlink:href="https://doi.org/10.1038/345142a0" ext-link-type="DOI">10.1038/345142a0</ext-link>, 1990.</mixed-citation></ref>
      <ref id="bib1.bibx3"><label>Bony and Dufresne(2005)</label><mixed-citation>Bony, S. and Dufresne, J.-L.: Marine boundary layer clouds at the heart of tropical cloud feedback uncertainties in climate models, Geophys. Res. Lett., 32, L20806, <ext-link xlink:href="https://doi.org/10.1029/2005GL023851" ext-link-type="DOI">10.1029/2005GL023851</ext-link>, 2005.</mixed-citation></ref>
      <ref id="bib1.bibx4"><label>Bretherton et al.(2005)</label><mixed-citation>Bretherton, C. S., Blossey, P. N., and Khairoutdinov, M.: An Energy-balance analysis of deep convective self-aggregation above uniform SST, J. Atmos. Sci., 62, 4273–4292, <ext-link xlink:href="https://doi.org/10.1175/JAS3614.1" ext-link-type="DOI">10.1175/JAS3614.1</ext-link>, 2005.</mixed-citation></ref>
      <ref id="bib1.bibx5"><label>Bretherton et al.(2010)</label><mixed-citation>Bretherton, C. S., Uchida, J., and Blossey, P. N.: Slow manifolds and multiple equilibria in stratocumulus-capped boundary layers, J. Adv. Model. Earth Sy., 2, 14, <ext-link xlink:href="https://doi.org/10.3894/JAMES.2010.2.14" ext-link-type="DOI">10.3894/JAMES.2010.2.14</ext-link>, 2010.</mixed-citation></ref>
      <ref id="bib1.bibx6"><label>Ceppi et al.(2024)</label><mixed-citation>Ceppi, P., Myers, T. A., Nowack, P., Wall, C. J., and Zelinka, M. D.: Implications of a pervasive climate model bias for low-cloud feedback, Geophys. Res. Lett., 51, e2024GL110525, <ext-link xlink:href="https://doi.org/10.1029/2024GL110525" ext-link-type="DOI">10.1029/2024GL110525</ext-link>, 2024.</mixed-citation></ref>
      <ref id="bib1.bibx7"><label>Chen et al.(2025)</label><mixed-citation>Chen, Y.-S., Prabhakaran, P., Hoffmann, F., Kazil, J., Yamaguchi, T., and Feingold, G.: Magnitude and timescale of liquid water path adjustments to cloud droplet number concentration perturbations for nocturnal non-precipitating marine stratocumulus, Atmos. Chem. Phys., 25, 6141–6159, <ext-link xlink:href="https://doi.org/10.5194/acp-25-6141-2025" ext-link-type="DOI">10.5194/acp-25-6141-2025</ext-link>, 2025.</mixed-citation></ref>
      <ref id="bib1.bibx8"><label>de Groot and Mazur(2013)</label><mixed-citation> de Groot, S. R. and Mazur, P.: Non-Equilibrium Thermodynamics, Courier Corporation, ISBN 9780486153506, 2013.</mixed-citation></ref>
      <ref id="bib1.bibx9"><label>Eastman et al.(2016)</label><mixed-citation>Eastman, R., Wood, R., and Bretherton, C. S.: Time scales of clouds and cloud-controlling variables in subtropical stratocumulus from a Lagrangian perspective, J. Atmos. Sci., 73, 3079–3091, <ext-link xlink:href="https://doi.org/10.1175/JAS-D-16-0050.1" ext-link-type="DOI">10.1175/JAS-D-16-0050.1</ext-link>, 2016.</mixed-citation></ref>
      <ref id="bib1.bibx10"><label>Emanuel et al.(2014)</label><mixed-citation>Emanuel, K., Wing, A. A., and Vincent, E. M.: Radiative-convective instability, J. Adv. Model. Earth Sy., 6, 75–90, <ext-link xlink:href="https://doi.org/10.1002/2013MS000270" ext-link-type="DOI">10.1002/2013MS000270</ext-link>, 2014.</mixed-citation></ref>
      <ref id="bib1.bibx11"><label>Endres(2017)</label><mixed-citation>Endres, R. G.: Entropy production selects nonequilibrium states in multistable systems, Sci. Rep., 7, 14437, <ext-link xlink:href="https://doi.org/10.1038/s41598-017-14485-8" ext-link-type="DOI">10.1038/s41598-017-14485-8</ext-link>, 2017.</mixed-citation></ref>
      <ref id="bib1.bibx12"><label>Fang et al.(2017)</label><mixed-citation>Fang, J., Pauluis, O., and Zhang, F.: Isentropic Analysis on the intensification of hurricane Edouard (2014), J. Atmos. Sci., 74, 4177–4197, <ext-link xlink:href="https://doi.org/10.1175/JAS-D-17-0092.1" ext-link-type="DOI">10.1175/JAS-D-17-0092.1</ext-link>, 2017.</mixed-citation></ref>
      <ref id="bib1.bibx13"><label>Feingold et al.(2015)</label><mixed-citation>Feingold, G., Koren, I., Yamaguchi, T., and Kazil, J.: On the reversibility of transitions between closed and open cellular convection, Atmos. Chem. Phys., 15, 7351–7367, <ext-link xlink:href="https://doi.org/10.5194/acp-15-7351-2015" ext-link-type="DOI">10.5194/acp-15-7351-2015</ext-link>, 2015.</mixed-citation></ref>
      <ref id="bib1.bibx14"><label>Fiévet et al.(2023)</label><mixed-citation>Fiévet, R., Meyer, B., and Haerter, J. O.: On the sensitivity of convective cold pools to mesh resolution, J. Adv. Model. Earth Sy., 15, e2022MS003382, <ext-link xlink:href="https://doi.org/10.1029/2022MS003382" ext-link-type="DOI">10.1029/2022MS003382</ext-link>, 2023.</mixed-citation></ref>
      <ref id="bib1.bibx15"><label>Gaspard(2022)</label><mixed-citation>Gaspard, P.: The Statistical Mechanics of Irreversible Phenomena, Cambridge University Press, Cambridge, <ext-link xlink:href="https://doi.org/10.1017/9781108563055" ext-link-type="DOI">10.1017/9781108563055</ext-link>, 2022.</mixed-citation></ref>
      <ref id="bib1.bibx16"><label>Gassmann and Herzog(2015)</label><mixed-citation>Gassmann, A. and Herzog, H.-J.: How is local material entropy production represented in a numerical model?, Q. J. Roy. Meteor. Soc., 141, 854–869, <ext-link xlink:href="https://doi.org/10.1002/qj.2404" ext-link-type="DOI">10.1002/qj.2404</ext-link>, 2015.</mixed-citation></ref>
      <ref id="bib1.bibx17"><label>Gibbins and Haigh(2020)</label><mixed-citation>Gibbins, G. and Haigh, J. D.: Entropy production rates of the climate, J. Atmos. Sci., 77, 3551–3566, <ext-link xlink:href="https://doi.org/10.1175/JAS-D-19-0294.1" ext-link-type="DOI">10.1175/JAS-D-19-0294.1</ext-link>, 2020.</mixed-citation></ref>
      <ref id="bib1.bibx18"><label>Glassmeier and Feingold(2017)</label><mixed-citation>Glassmeier, F. and Feingold, G.: Network approach to patterns in stratocumulus clouds, P. Natl. Acad. Sci. USA, 114, 10578–10583, <ext-link xlink:href="https://doi.org/10.1073/pnas.1706495114" ext-link-type="DOI">10.1073/pnas.1706495114</ext-link>, 2017.</mixed-citation></ref>
      <ref id="bib1.bibx19"><label>Glassmeier et al.(2019)</label><mixed-citation>Glassmeier, F., Hoffmann, F., Johnson, J. S., Yamaguchi, T., Carslaw, K. S., and Feingold, G.: An emulator approach to stratocumulus susceptibility, Atmos. Chem. Phys., 19, 10191–10203, <ext-link xlink:href="https://doi.org/10.5194/acp-19-10191-2019" ext-link-type="DOI">10.5194/acp-19-10191-2019</ext-link>, 2019.</mixed-citation></ref>
      <ref id="bib1.bibx20"><label>Glassmeier et al.(2021)</label><mixed-citation>Glassmeier, F., Hoffmann, F., Johnson, J. S., Yamaguchi, T., Carslaw, K. S., and Feingold, G.: Aerosol-cloud-climate cooling overestimated by ship-track data, Science, 371, 485–489, <ext-link xlink:href="https://doi.org/10.1126/science.abd3980" ext-link-type="DOI">10.1126/science.abd3980</ext-link>, 2021.</mixed-citation></ref>
      <ref id="bib1.bibx21"><label>Goody(2000)</label><mixed-citation>Goody, R.: Sources and sinks of climate entropy, Q. J. Roy. Meteor. Soc., 126, 1953–1970, <ext-link xlink:href="https://doi.org/10.1002/qj.49712656619" ext-link-type="DOI">10.1002/qj.49712656619</ext-link>, 2000.</mixed-citation></ref>
      <ref id="bib1.bibx22"><label>Hahn and Warren(2007)</label><mixed-citation>Hahn, C. and Warren, S.: A Gridded Climatology of Clouds over Land (1971–1996) and Ocean (1954–2008) from Surface Observations Worldwide (NDP–026E), Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory [data set], <ext-link xlink:href="https://doi.org/10.3334/CDIAC/CLI.NDP026E" ext-link-type="DOI">10.3334/CDIAC/CLI.NDP026E</ext-link>, 2007.</mixed-citation></ref>
      <ref id="bib1.bibx23"><label>Hauf and Höller(1987)</label><mixed-citation>Hauf, T. and Höller, H.: Entropy and potential temperature, J. Atmos. Sci., 44, 2887–2901, <ext-link xlink:href="https://doi.org/10.1175/1520-0469(1987)044&lt;2887:EAPT&gt;2.0.CO;2" ext-link-type="DOI">10.1175/1520-0469(1987)044&lt;2887:EAPT&gt;2.0.CO;2</ext-link>, 1987.</mixed-citation></ref>
      <ref id="bib1.bibx24"><label>Hernandez(2026)</label><mixed-citation>Hernandez, B.: HernandezBen/Code_Data_Entropy_ACP: Entropy_Production_ACP (Entropy_production_stratocumulus_ACP), Zenodo, <ext-link xlink:href="https://doi.org/10.5281/zenodo.18662163" ext-link-type="DOI">10.5281/zenodo.18662163</ext-link>, 2026.</mixed-citation></ref>
      <ref id="bib1.bibx25"><label>Hernandez and Glassmeier(2026)</label><mixed-citation>Hernandez, B. and Glassmeier, F.: Aerosol memory in stratocumulus clouds leads to noise-induced patterns and non-ergodic sampling, arXiv [preprint], <ext-link xlink:href="https://doi.org/10.48550/arXiv.2605.04002" ext-link-type="DOI">10.48550/arXiv.2605.04002</ext-link>, 2026.</mixed-citation></ref>
      <ref id="bib1.bibx26"><label>Hirt et al.(2020)</label><mixed-citation>Hirt, M., Craig, G. C., Schäfer, S. A. K., Savre, J., and Heinze, R.: Cold-pool-driven convective initiation: using causal graph analysis to determine what convection-permitting models are missing, Q. J. Roy. Meteor. Soc., 146, 2205–2227, <ext-link xlink:href="https://doi.org/10.1002/qj.3788" ext-link-type="DOI">10.1002/qj.3788</ext-link>, 2020.</mixed-citation></ref>
      <ref id="bib1.bibx27"><label>Hoffmann and Feingold(2019)</label><mixed-citation>Hoffmann, F. and Feingold, G.: Entrainment and mixing in stratocumulus: effects of a new explicit subgrid-scale scheme for large-eddy simulations with particle-based microphysics, J. Atmos. Sci., 76, 1955–1973, <ext-link xlink:href="https://doi.org/10.1175/JAS-D-18-0318.1" ext-link-type="DOI">10.1175/JAS-D-18-0318.1</ext-link>, 2019.</mixed-citation></ref>
      <ref id="bib1.bibx28"><label>Hoffmann et al.(2020)</label><mixed-citation>Hoffmann, F., Glassmeier, F., Yamaguchi, T., and Feingold, G.: Liquid water path steady states in stratocumulus: insights from process-level emulation and mixed-layer theory, J. Atmos. Sci., 77, 2203–2215, <ext-link xlink:href="https://doi.org/10.1175/JAS-D-19-0241.1" ext-link-type="DOI">10.1175/JAS-D-19-0241.1</ext-link>, 2020.</mixed-citation></ref>
      <ref id="bib1.bibx29"><label>Hoffmann et al.(2024)</label><mixed-citation>Hoffmann, F., Glassmeier, F., and Feingold, G.: The impact of aerosol on cloud water: a heuristic perspective, Atmos. Chem. Phys., 24, 13403–13412, <ext-link xlink:href="https://doi.org/10.5194/acp-24-13403-2024" ext-link-type="DOI">10.5194/acp-24-13403-2024</ext-link>, 2024.</mixed-citation></ref>
      <ref id="bib1.bibx30"><label>Hoffmann et al.(2025)</label><mixed-citation>Hoffmann, F., Chen, Y.-S., and Feingold, G.: On the processes determining the slope of cloud water adjustments in weakly and non-precipitating stratocumulus, Atmos. Chem. Phys., 25, 8657–8670, <ext-link xlink:href="https://doi.org/10.5194/acp-25-8657-2025" ext-link-type="DOI">10.5194/acp-25-8657-2025</ext-link>, 2025.</mixed-citation></ref>
      <ref id="bib1.bibx31"><label>Igel and Igel(2018)</label><mixed-citation>Igel, M. R. and Igel, A. L.: The energetics and magnitude of hydrometeor friction in clouds, J. Atmos. Sci., 75, 1343–1350, <ext-link xlink:href="https://doi.org/10.1175/JAS-D-17-0285.1" ext-link-type="DOI">10.1175/JAS-D-17-0285.1</ext-link>, 2018.</mixed-citation></ref>
      <ref id="bib1.bibx32"><label>Kalmus et al.(2014)</label><mixed-citation>Kalmus, P., Lebsock, M., and Teixeira, J.: Observational boundary layer energy and water budgets of the stratocumulus-to-cumulus transition, J. Climate, 27, 9155–9170, <ext-link xlink:href="https://doi.org/10.1175/JCLI-D-14-00242.1" ext-link-type="DOI">10.1175/JCLI-D-14-00242.1</ext-link>, 2014.</mixed-citation></ref>
      <ref id="bib1.bibx33"><label>Kato and Rose(2020)</label><mixed-citation>Kato, S. and Rose, F. G.: Global and regional entropy production by radiation estimated from satellite observations, J. Climate, 33, 2985–3000, <ext-link xlink:href="https://doi.org/10.1175/JCLI-D-19-0596.1" ext-link-type="DOI">10.1175/JCLI-D-19-0596.1</ext-link>, 2020.</mixed-citation></ref>
      <ref id="bib1.bibx34"><label>Kazil et al.(2017)</label><mixed-citation>Kazil, J., Yamaguchi, T., and Feingold, G.: Mesoscale organization, entrainment, and the properties of a closed-cell stratocumulus cloud, J. Adv. Model. Earth Sy., 9, 2214–2229, <ext-link xlink:href="https://doi.org/10.1002/2017MS001072" ext-link-type="DOI">10.1002/2017MS001072</ext-link>, 2017.</mixed-citation></ref>
      <ref id="bib1.bibx35"><label>Khairoutdinov and Randall(2003)</label><mixed-citation>Khairoutdinov, M. F. and Randall, D. A.: Cloud resolving modeling of the ARM Summer 1997 IOP: model formulation, results, uncertainties, and sensitivities, J. Atmos. Sci., 60, 607–625, <ext-link xlink:href="https://doi.org/10.1175/1520-0469(2003)060&lt;0607:CRMOTA&gt;2.0.CO;2" ext-link-type="DOI">10.1175/1520-0469(2003)060&lt;0607:CRMOTA&gt;2.0.CO;2</ext-link>, 2003.</mixed-citation></ref>
      <ref id="bib1.bibx36"><label>Kleidon(2004)</label><mixed-citation>Kleidon, A.: Beyond Gaia: thermodynamics of life and earth system functioning, Climatic Change, 66, 271–319, <ext-link xlink:href="https://doi.org/10.1023/B:CLIM.0000044616.34867.ec" ext-link-type="DOI">10.1023/B:CLIM.0000044616.34867.ec</ext-link>, 2004.</mixed-citation></ref>
      <ref id="bib1.bibx37"><label>Koren and Feingold(2011)</label><mixed-citation>Koren, I. and Feingold, G.: Aerosol–cloud–precipitation system as a predator-prey problem, P. Natl. Acad. Sci. USA, 108, 12227–12232, <ext-link xlink:href="https://doi.org/10.1073/pnas.1101777108" ext-link-type="DOI">10.1073/pnas.1101777108</ext-link>, 2011.</mixed-citation></ref>
      <ref id="bib1.bibx38"><label>Koren and Feingold(2013)</label><mixed-citation>Koren, I. and Feingold, G.: Adaptive behavior of marine cellular clouds, Sci. Rep., 3, 2507, <ext-link xlink:href="https://doi.org/10.1038/srep02507" ext-link-type="DOI">10.1038/srep02507</ext-link>, 2013.</mixed-citation></ref>
      <ref id="bib1.bibx39"><label>Laliberté et al.(2015)</label><mixed-citation>Laliberté, F., Zika, J., Mudryk, L., Kushner, P. J., Kjellsson, J., and Döös, K.: Constrained work output of the moist atmospheric heat engine in a warming climate, Science, 347, 540–543, <ext-link xlink:href="https://doi.org/10.1126/science.1257103" ext-link-type="DOI">10.1126/science.1257103</ext-link>, 2015.</mixed-citation></ref>
      <ref id="bib1.bibx40"><label>Lilly(1968)</label><mixed-citation>Lilly, D. K.: Models of cloud-topped mixed layers under a strong inversion, Q. J. Roy. Meteor. Soc., 94, 292–309, <ext-link xlink:href="https://doi.org/10.1002/qj.49709440106" ext-link-type="DOI">10.1002/qj.49709440106</ext-link>, 1968.</mixed-citation></ref>
      <ref id="bib1.bibx41"><label>Lucarini(2009)</label><mixed-citation>Lucarini, V.: Thermodynamic efficiency and entropy production in the climate system, Phys. Rev. E, 80, 021118, <ext-link xlink:href="https://doi.org/10.1103/PhysRevE.80.021118" ext-link-type="DOI">10.1103/PhysRevE.80.021118</ext-link>, 2009.</mixed-citation></ref>
      <ref id="bib1.bibx42"><label>Lucarini et al.(2010)</label><mixed-citation>Lucarini, V., Fraedrich, K., and Lunkeit, F.: Thermodynamic analysis of snowball Earth hysteresis experiment: efficiency, entropy production and irreversibility, Q. J. Roy. Meteor. Soc., 136, 2–11, <ext-link xlink:href="https://doi.org/10.1002/qj.543" ext-link-type="DOI">10.1002/qj.543</ext-link>, 2010.</mixed-citation></ref>
      <ref id="bib1.bibx43"><label>Morris and Mitchell(1995)</label><mixed-citation>Morris, M. D. and Mitchell, T. J.: Exploratory designs for computational experiments, J. Stat. Plann. Inference, 43, 381–402, <ext-link xlink:href="https://doi.org/10.1016/0378-3758(94)00035-T" ext-link-type="DOI">10.1016/0378-3758(94)00035-T</ext-link>, 1995.</mixed-citation></ref>
      <ref id="bib1.bibx44"><label>Myers et al.(2021)</label><mixed-citation>Myers, T. A., Scott, R. C., Zelinka, M. D., Klein, S. A., Norris, J. R., and Caldwell, P. M.: Observational constraints on low cloud feedback reduce uncertainty of climate sensitivity, Nat. Clim. Change, 11, 501–507, <ext-link xlink:href="https://doi.org/10.1038/s41558-021-01039-0" ext-link-type="DOI">10.1038/s41558-021-01039-0</ext-link>, 2021.</mixed-citation></ref>
      <ref id="bib1.bibx45"><label>Onsager(1931)</label><mixed-citation>Onsager, L.: Reciprocal relations in irreversible processes. II., Phys. Rev., 38, 2265–2279, <ext-link xlink:href="https://doi.org/10.1103/PhysRev.38.2265" ext-link-type="DOI">10.1103/PhysRev.38.2265</ext-link>, 1931.</mixed-citation></ref>
      <ref id="bib1.bibx46"><label>Ozawa and Shimokawa(2015)</label><mixed-citation>Ozawa, H. and Shimokawa, S.: Thermodynamics of a tropical cyclone: generation and dissipation of mechanical energy in a self-driven convection system, Tellus A, 67, 24216, <ext-link xlink:href="https://doi.org/10.3402/tellusa.v67.24216" ext-link-type="DOI">10.3402/tellusa.v67.24216</ext-link>, 2015.</mixed-citation></ref>
      <ref id="bib1.bibx47"><label>Ozawa et al.(2003)</label><mixed-citation>Ozawa, H., Ohmura, A., Lorenz, R. D., and Pujol, T.: The second law of thermodynamics and the global climate system: a review of the maximum entropy production principle, Rev. Geophys., 41, 1018, <ext-link xlink:href="https://doi.org/10.1029/2002RG000113" ext-link-type="DOI">10.1029/2002RG000113</ext-link>, 2003.</mixed-citation></ref>
      <ref id="bib1.bibx48"><label>Paltridge(1975)</label><mixed-citation>Paltridge, G. W.: Global dynamics and climate – a system of minimum entropy exchange, Q. J. Roy. Meteor. Soc., 101, 475–484, <ext-link xlink:href="https://doi.org/10.1002/qj.49710142906" ext-link-type="DOI">10.1002/qj.49710142906</ext-link>, 1975.</mixed-citation></ref>
      <ref id="bib1.bibx49"><label>Pauluis(2011)</label><mixed-citation>Pauluis, O.: Water vapor and mechanical work: a comparison of carnot and steam cycles, J. Atmos. Sci., 68, 91–102, <ext-link xlink:href="https://doi.org/10.1175/2010JAS3530.1" ext-link-type="DOI">10.1175/2010JAS3530.1</ext-link>, 2011.</mixed-citation></ref>
      <ref id="bib1.bibx50"><label>Pauluis(2016)</label><mixed-citation>Pauluis, O. M.: The mean air flow as Lagrangian dynamics approximation and its application to moist convection, J. Atmos. Sci., 73, 4407–4425, <ext-link xlink:href="https://doi.org/10.1175/JAS-D-15-0284.1" ext-link-type="DOI">10.1175/JAS-D-15-0284.1</ext-link>, 2016.</mixed-citation></ref>
      <ref id="bib1.bibx51"><label>Pauluis and Held(2002a)</label><mixed-citation>Pauluis, O. and Held, I. M.: Entropy budget of an atmosphere in radiative–convective equilibrium. Part I: Maximum work and frictional dissipation, J. Atmos. Sci., 59, 125–139, <ext-link xlink:href="https://doi.org/10.1175/1520-0469(2002)059&lt;0125:EBOAAI&gt;2.0.CO;2" ext-link-type="DOI">10.1175/1520-0469(2002)059&lt;0125:EBOAAI&gt;2.0.CO;2</ext-link>, 2002a.</mixed-citation></ref>
      <ref id="bib1.bibx52"><label>Pauluis and Held(2002b)</label><mixed-citation>Pauluis, O. and Held, I. M.: Entropy budget of an atmosphere in radiative–convective equilibrium. Part II: Latent heat transport and moist processes, J. Atmos. Sci., 59, 140–149, <ext-link xlink:href="https://doi.org/10.1175/1520-0469(2002)059&lt;0140:EBOAAI&gt;2.0.CO;2" ext-link-type="DOI">10.1175/1520-0469(2002)059&lt;0140:EBOAAI&gt;2.0.CO;2</ext-link>, 2002b.</mixed-citation></ref>
      <ref id="bib1.bibx53"><label>Pauluis and Zhang(2017)</label><mixed-citation>Pauluis, O. M. and Zhang, F.: Reconstruction of thermodynamic cycles in a high-resolution simulation of a hurricane, J. Atmos. Sci., 74, 3367–3381, <ext-link xlink:href="https://doi.org/10.1175/JAS-D-16-0353.1" ext-link-type="DOI">10.1175/JAS-D-16-0353.1</ext-link>, 2017.</mixed-citation></ref>
      <ref id="bib1.bibx54"><label>Pauluis et al.(2000)</label><mixed-citation>Pauluis, O., Balaji, V., and Held, I. M.: Frictional Dissipation in a Precipitating Atmosphere, J. Atmos. Sci., 57, 989–994, <ext-link xlink:href="https://doi.org/10.1175/1520-0469(2000)057&lt;0989:FDIAPA&gt;2.0.CO;2" ext-link-type="DOI">10.1175/1520-0469(2000)057&lt;0989:FDIAPA&gt;2.0.CO;2</ext-link>, 2000.</mixed-citation></ref>
      <ref id="bib1.bibx55"><label>Possner et al.(2020)</label><mixed-citation>Possner, A., Eastman, R., Bender, F., and Glassmeier, F.: Deconvolution of boundary layer depth and aerosol constraints on cloud water path in subtropical stratocumulus decks, Atmos. Chem. Phys., 20, 3609–3621, <ext-link xlink:href="https://doi.org/10.5194/acp-20-3609-2020" ext-link-type="DOI">10.5194/acp-20-3609-2020</ext-link>, 2020.</mixed-citation></ref>
      <ref id="bib1.bibx56"><label>Prigogine(1968)</label><mixed-citation> Prigogine, I.: Introduction to Thermodynamics of Irreversible Processes, Wiley, 3rd edn., ISBN 9780470699287, 1968.</mixed-citation></ref>
      <ref id="bib1.bibx57"><label>Rennó and Ingersoll(1996)</label><mixed-citation>Rennó, N. O. and Ingersoll, A. P.: Natural convection as a heat engine: a theory for CAPE, J. Atmos. Sci., 53, 572–585, <ext-link xlink:href="https://doi.org/10.1175/1520-0469(1996)053&lt;0572:NCAAHE&gt;2.0.CO;2" ext-link-type="DOI">10.1175/1520-0469(1996)053&lt;0572:NCAAHE&gt;2.0.CO;2</ext-link>, 1996.</mixed-citation></ref>
      <ref id="bib1.bibx58"><label>Romps(2008)</label><mixed-citation>Romps, D. M.: The dry-entropy budget of a moist atmosphere, J. Atmos. Sci., 65, 3779–3799, <ext-link xlink:href="https://doi.org/10.1175/2008JAS2679.1" ext-link-type="DOI">10.1175/2008JAS2679.1</ext-link>, 2008.</mixed-citation></ref>
      <ref id="bib1.bibx59"><label>Régibeau-Rockett et al.(2023)</label><mixed-citation>Régibeau-Rockett, L., Pauluis, O. M., and O'Neill, M. E.: Investigating the relationship between sea surface temperature and the mechanical efficiency of tropical cyclones, J. Climate, 37, 439–456, <ext-link xlink:href="https://doi.org/10.1175/JCLI-D-22-0877.1" ext-link-type="DOI">10.1175/JCLI-D-22-0877.1</ext-link>, 2023.</mixed-citation></ref>
      <ref id="bib1.bibx60"><label>Savic-Jovcic and Stevens(2008)</label><mixed-citation>Savic-Jovcic, V. and Stevens, B.: The structure and mesoscale organization of precipitating stratocumulus, J. Atmos. Sci., 65, 1587–1605, <ext-link xlink:href="https://doi.org/10.1175/2007JAS2456.1" ext-link-type="DOI">10.1175/2007JAS2456.1</ext-link>, 2008. </mixed-citation></ref>
      <ref id="bib1.bibx61"><label>Schubert et al.(1979)</label><mixed-citation>Schubert, W. H., Wakefield, J. S., Steiner, E. J., and Cox, S. K.: Marine stratocumulus convection. Part II: Horizontally inhomogeneous solutions, J. Atmos. Sci., 36, 1308–1324, <ext-link xlink:href="https://doi.org/10.1175/1520-0469(1979)036&lt;1308:MSCPIH&gt;2.0.CO;2" ext-link-type="DOI">10.1175/1520-0469(1979)036&lt;1308:MSCPIH&gt;2.0.CO;2</ext-link>, 1979.</mixed-citation></ref>
      <ref id="bib1.bibx62"><label>Singh and O'Gorman(2016)</label><mixed-citation>Singh, M. S. and O'Gorman, P. A.: Scaling of the entropy budget with surface temperature in radiative-convective equilibrium, J. Adv. Model. Earth Sy., 8, 1132–1150, <ext-link xlink:href="https://doi.org/10.1002/2016MS000673" ext-link-type="DOI">10.1002/2016MS000673</ext-link>, 2016.</mixed-citation></ref>
      <ref id="bib1.bibx63"><label>Singh and O'Neill(2022)</label><mixed-citation>Singh, M. S. and O'Neill, M. E.: The climate system and the second law of thermodynamics, Rev. Mod. Phys., 94, 015001, <ext-link xlink:href="https://doi.org/10.1103/RevModPhys.94.015001" ext-link-type="DOI">10.1103/RevModPhys.94.015001</ext-link>, 2022.</mixed-citation></ref>
      <ref id="bib1.bibx64"><label>Stephens and Greenwald(1991)</label><mixed-citation>Stephens, G. L. and Greenwald, T. J.: The Earth's radiation budget and its relation to atmospheric hydrology: 2. Observations of cloud effects, J. Geophys. Res.-Atmos., 96, 15325–15340, <ext-link xlink:href="https://doi.org/10.1029/91JD00972" ext-link-type="DOI">10.1029/91JD00972</ext-link>, 1991.</mixed-citation></ref>
      <ref id="bib1.bibx65"><label>Stephens and O'Brien(1993)</label><mixed-citation>Stephens, G. L. and O'Brien, D. M.: Entropy and climate. I: ERBE observations of the entropy production of the earth, Q. J. Roy. Meteor. Soc., 119, 121–152, <ext-link xlink:href="https://doi.org/10.1002/qj.49711950906" ext-link-type="DOI">10.1002/qj.49711950906</ext-link>, 1993.</mixed-citation></ref>
      <ref id="bib1.bibx66"><label>Stevens et al.(2005)</label><mixed-citation>Stevens, B., Moeng, C.-H., Ackerman, A. S., Bretherton, C. S., Chlond, A., de Roode, S., Edwards, J., Golaz, J.-C., Jiang, H., Khairoutdinov, M., Kirkpatrick, M. P., Lewellen, D. C., Lock, A., Müller, F., Stevens, D. E., Whelan, E., and Zhu, P.: Evaluation of large-eddy simulations via observations of nocturnal marine stratocumulus, Mon. Weather Rev., 133, 1443–1462, <ext-link xlink:href="https://doi.org/10.1175/MWR2930.1" ext-link-type="DOI">10.1175/MWR2930.1</ext-link>, 2005.</mixed-citation></ref>
      <ref id="bib1.bibx67"><label>Stevens and Bretherton(1999)</label><mixed-citation>Stevens, D. E. and Bretherton, C. S.: Effects of resolution on the simulation of stratocumulus entrainment, Q. J. Roy. Meteor. Soc., 125, 425–439, <ext-link xlink:href="https://doi.org/10.1002/qj.49712555403" ext-link-type="DOI">10.1002/qj.49712555403</ext-link>, 1999.</mixed-citation></ref>
      <ref id="bib1.bibx68"><label>Volk and Pauluis(2010)</label><mixed-citation>Volk, T. and Pauluis, O.: It is not the entropy you produce, rather, how you produce it, Phil. Trans. R. Soc. Lond. B, 365, 1317–1322, <ext-link xlink:href="https://doi.org/10.1098/rstb.2010.0019" ext-link-type="DOI">10.1098/rstb.2010.0019</ext-link>, 2010.</mixed-citation></ref>
      <ref id="bib1.bibx69"><label>Wang and Feingold(2009)</label><mixed-citation>Wang, H. and Feingold, G.: Modeling mesoscale cellular structures and drizzle in marine stratocumulus. Part I: Impact of drizzle on the formation and evolution of open cells, J. Atmos. Sci., 66, 3237–3256, <ext-link xlink:href="https://doi.org/10.1175/2009JAS3022.1" ext-link-type="DOI">10.1175/2009JAS3022.1</ext-link>, 2009.</mixed-citation></ref>
      <ref id="bib1.bibx70"><label>Wood(2012)</label><mixed-citation>Wood, R.: Stratocumulus clouds, Mon. Weather Rev., 140, 2373–2423, <ext-link xlink:href="https://doi.org/10.1175/MWR-D-11-00121.1" ext-link-type="DOI">10.1175/MWR-D-11-00121.1</ext-link>, 2012.</mixed-citation></ref>
      <ref id="bib1.bibx71"><label>Xue et al.(2008)</label><mixed-citation>Xue, H., Feingold, G., and Stevens, B.: Aerosol effects on clouds, precipitation, and the organization of shallow cumulus convection, J. Atmos. Sci., 65, 392–406, <ext-link xlink:href="https://doi.org/10.1175/2007JAS2428.1" ext-link-type="DOI">10.1175/2007JAS2428.1</ext-link>, 2008.</mixed-citation></ref>

  </ref-list></back>
    <!--<article-title-html>The remarkable inefficiency of stratocumulus</article-title-html>
<abstract-html/>
<ref-html id="bib1.bib1"><label>Alinaghi et al.(2025)</label><mixed-citation>
       Alinaghi, P., Janssens, M., and Jansson, F.: Warming from cold pools: a pathway for mesoscale organization to alter Earth's radiation budget, P. Natl. Acad. Sci. USA USA, 122, e2513699122, <a href="https://doi.org/10.1073/pnas.2513699122" target="_blank">https://doi.org/10.1073/pnas.2513699122</a>, 2025.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib2"><label>Baker and Charlson(1990)</label><mixed-citation>
       Baker, M. B. and Charlson, R. J.: Bistability of CCN concentrations and thermodynamics in the cloud-topped boundary layer, Nature, 345, 142–145, <a href="https://doi.org/10.1038/345142a0" target="_blank">https://doi.org/10.1038/345142a0</a>, 1990.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib3"><label>Bony and Dufresne(2005)</label><mixed-citation>
       Bony, S. and Dufresne, J.-L.: Marine boundary layer clouds at the heart of tropical cloud feedback uncertainties in climate models, Geophys. Res. Lett., 32, L20806, <a href="https://doi.org/10.1029/2005GL023851" target="_blank">https://doi.org/10.1029/2005GL023851</a>, 2005.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib4"><label>Bretherton et al.(2005)</label><mixed-citation>
       Bretherton, C. S., Blossey, P. N., and Khairoutdinov, M.: An Energy-balance analysis of deep convective self-aggregation above uniform SST, J. Atmos. Sci., 62, 4273–4292, <a href="https://doi.org/10.1175/JAS3614.1" target="_blank">https://doi.org/10.1175/JAS3614.1</a>, 2005.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib5"><label>Bretherton et al.(2010)</label><mixed-citation>
       Bretherton, C. S., Uchida, J., and Blossey, P. N.: Slow manifolds and multiple equilibria in stratocumulus-capped boundary layers, J. Adv. Model. Earth Sy., 2, 14, <a href="https://doi.org/10.3894/JAMES.2010.2.14" target="_blank">https://doi.org/10.3894/JAMES.2010.2.14</a>, 2010.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib6"><label>Ceppi et al.(2024)</label><mixed-citation>
       Ceppi, P., Myers, T. A., Nowack, P., Wall, C. J., and Zelinka, M. D.: Implications of a pervasive climate model bias for low-cloud feedback, Geophys. Res. Lett., 51, e2024GL110525, <a href="https://doi.org/10.1029/2024GL110525" target="_blank">https://doi.org/10.1029/2024GL110525</a>, 2024.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib7"><label>Chen et al.(2025)</label><mixed-citation>
       Chen, Y.-S., Prabhakaran, P., Hoffmann, F., Kazil, J., Yamaguchi, T., and Feingold, G.: Magnitude and timescale of liquid water path adjustments to cloud droplet number concentration perturbations for nocturnal non-precipitating marine stratocumulus, Atmos. Chem. Phys., 25, 6141–6159, <a href="https://doi.org/10.5194/acp-25-6141-2025" target="_blank">https://doi.org/10.5194/acp-25-6141-2025</a>, 2025.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib8"><label>de Groot and Mazur(2013)</label><mixed-citation>
       de Groot, S. R. and Mazur, P.: Non-Equilibrium Thermodynamics, Courier Corporation, ISBN 9780486153506, 2013.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib9"><label>Eastman et al.(2016)</label><mixed-citation>
       Eastman, R., Wood, R., and Bretherton, C. S.: Time scales of clouds and cloud-controlling variables in subtropical stratocumulus from a Lagrangian perspective, J. Atmos. Sci., 73, 3079–3091, <a href="https://doi.org/10.1175/JAS-D-16-0050.1" target="_blank">https://doi.org/10.1175/JAS-D-16-0050.1</a>, 2016.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib10"><label>Emanuel et al.(2014)</label><mixed-citation>
       Emanuel, K., Wing, A. A., and Vincent, E. M.: Radiative-convective instability, J. Adv. Model. Earth Sy., 6, 75–90, <a href="https://doi.org/10.1002/2013MS000270" target="_blank">https://doi.org/10.1002/2013MS000270</a>, 2014.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib11"><label>Endres(2017)</label><mixed-citation>
       Endres, R. G.: Entropy production selects nonequilibrium states in multistable systems, Sci. Rep., 7, 14437, <a href="https://doi.org/10.1038/s41598-017-14485-8" target="_blank">https://doi.org/10.1038/s41598-017-14485-8</a>, 2017.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib12"><label>Fang et al.(2017)</label><mixed-citation>
       Fang, J., Pauluis, O., and Zhang, F.: Isentropic Analysis on the intensification of hurricane Edouard (2014), J. Atmos. Sci., 74, 4177–4197, <a href="https://doi.org/10.1175/JAS-D-17-0092.1" target="_blank">https://doi.org/10.1175/JAS-D-17-0092.1</a>, 2017.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib13"><label>Feingold et al.(2015)</label><mixed-citation>
       Feingold, G., Koren, I., Yamaguchi, T., and Kazil, J.: On the reversibility of transitions between closed and open cellular convection, Atmos. Chem. Phys., 15, 7351–7367, <a href="https://doi.org/10.5194/acp-15-7351-2015" target="_blank">https://doi.org/10.5194/acp-15-7351-2015</a>, 2015.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib14"><label>Fiévet et al.(2023)</label><mixed-citation>
       Fiévet, R., Meyer, B., and Haerter, J. O.: On the sensitivity of convective cold pools to mesh resolution, J. Adv. Model. Earth Sy., 15, e2022MS003382, <a href="https://doi.org/10.1029/2022MS003382" target="_blank">https://doi.org/10.1029/2022MS003382</a>, 2023.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib15"><label>Gaspard(2022)</label><mixed-citation>
       Gaspard, P.: The Statistical Mechanics of Irreversible Phenomena, Cambridge University Press, Cambridge, <a href="https://doi.org/10.1017/9781108563055" target="_blank">https://doi.org/10.1017/9781108563055</a>, 2022.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib16"><label>Gassmann and Herzog(2015)</label><mixed-citation>
       Gassmann, A. and Herzog, H.-J.: How is local material entropy production represented in a numerical model?, Q. J. Roy. Meteor. Soc., 141, 854–869, <a href="https://doi.org/10.1002/qj.2404" target="_blank">https://doi.org/10.1002/qj.2404</a>, 2015.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib17"><label>Gibbins and Haigh(2020)</label><mixed-citation>
       Gibbins, G. and Haigh, J. D.: Entropy production rates of the climate, J. Atmos. Sci., 77, 3551–3566, <a href="https://doi.org/10.1175/JAS-D-19-0294.1" target="_blank">https://doi.org/10.1175/JAS-D-19-0294.1</a>, 2020.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib18"><label>Glassmeier and Feingold(2017)</label><mixed-citation>
       Glassmeier, F. and Feingold, G.: Network approach to patterns in stratocumulus clouds, P. Natl. Acad. Sci. USA, 114, 10578–10583, <a href="https://doi.org/10.1073/pnas.1706495114" target="_blank">https://doi.org/10.1073/pnas.1706495114</a>, 2017.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib19"><label>Glassmeier et al.(2019)</label><mixed-citation>
       Glassmeier, F., Hoffmann, F., Johnson, J. S., Yamaguchi, T., Carslaw, K. S., and Feingold, G.: An emulator approach to stratocumulus susceptibility, Atmos. Chem. Phys., 19, 10191–10203, <a href="https://doi.org/10.5194/acp-19-10191-2019" target="_blank">https://doi.org/10.5194/acp-19-10191-2019</a>, 2019.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib20"><label>Glassmeier et al.(2021)</label><mixed-citation>
       Glassmeier, F., Hoffmann, F., Johnson, J. S., Yamaguchi, T., Carslaw, K. S., and Feingold, G.: Aerosol-cloud-climate cooling overestimated by ship-track data, Science, 371, 485–489, <a href="https://doi.org/10.1126/science.abd3980" target="_blank">https://doi.org/10.1126/science.abd3980</a>, 2021.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib21"><label>Goody(2000)</label><mixed-citation>
       Goody, R.: Sources and sinks of climate entropy, Q. J. Roy. Meteor. Soc., 126, 1953–1970, <a href="https://doi.org/10.1002/qj.49712656619" target="_blank">https://doi.org/10.1002/qj.49712656619</a>, 2000.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib22"><label>Hahn and Warren(2007)</label><mixed-citation>
       Hahn, C. and Warren, S.: A Gridded Climatology of Clouds over Land (1971–1996) and Ocean (1954–2008) from Surface Observations Worldwide (NDP–026E), Carbon Dioxide Information Analysis Center, Oak Ridge National Laboratory [data set], <a href="https://doi.org/10.3334/CDIAC/CLI.NDP026E" target="_blank">https://doi.org/10.3334/CDIAC/CLI.NDP026E</a>, 2007.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib23"><label>Hauf and Höller(1987)</label><mixed-citation>
       Hauf, T. and Höller, H.: Entropy and potential temperature, J. Atmos. Sci., 44, 2887–2901, <a href="https://doi.org/10.1175/1520-0469(1987)044&lt;2887:EAPT&gt;2.0.CO;2" target="_blank">https://doi.org/10.1175/1520-0469(1987)044&lt;2887:EAPT&gt;2.0.CO;2</a>, 1987.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib24"><label>Hernandez(2026)</label><mixed-citation>
      
Hernandez, B.: HernandezBen/Code_Data_Entropy_ACP: Entropy_Production_ACP (Entropy_production_stratocumulus_ACP), Zenodo, <a href="https://doi.org/10.5281/zenodo.18662163" target="_blank">https://doi.org/10.5281/zenodo.18662163</a>, 2026.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib25"><label>Hernandez and Glassmeier(2026)</label><mixed-citation>
       Hernandez, B. and Glassmeier, F.: Aerosol memory in stratocumulus clouds leads to noise-induced patterns and non-ergodic sampling, arXiv [preprint], <a href="https://doi.org/10.48550/arXiv.2605.04002" target="_blank">https://doi.org/10.48550/arXiv.2605.04002</a>, 2026.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib26"><label>Hirt et al.(2020)</label><mixed-citation>
       Hirt, M., Craig, G. C., Schäfer, S. A. K., Savre, J., and Heinze, R.: Cold-pool-driven convective initiation: using causal graph analysis to determine what convection-permitting models are missing, Q. J. Roy. Meteor. Soc., 146, 2205–2227, <a href="https://doi.org/10.1002/qj.3788" target="_blank">https://doi.org/10.1002/qj.3788</a>, 2020.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib27"><label>Hoffmann and Feingold(2019)</label><mixed-citation>
       Hoffmann, F. and Feingold, G.: Entrainment and mixing in stratocumulus: effects of a new explicit subgrid-scale scheme for large-eddy simulations with particle-based microphysics, J. Atmos. Sci., 76, 1955–1973, <a href="https://doi.org/10.1175/JAS-D-18-0318.1" target="_blank">https://doi.org/10.1175/JAS-D-18-0318.1</a>, 2019.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib28"><label>Hoffmann et al.(2020)</label><mixed-citation>
       Hoffmann, F., Glassmeier, F., Yamaguchi, T., and Feingold, G.: Liquid water path steady states in stratocumulus: insights from process-level emulation and mixed-layer theory, J. Atmos. Sci., 77, 2203–2215, <a href="https://doi.org/10.1175/JAS-D-19-0241.1" target="_blank">https://doi.org/10.1175/JAS-D-19-0241.1</a>, 2020.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib29"><label>Hoffmann et al.(2024)</label><mixed-citation>
       Hoffmann, F., Glassmeier, F., and Feingold, G.: The impact of aerosol on cloud water: a heuristic perspective, Atmos. Chem. Phys., 24, 13403–13412, <a href="https://doi.org/10.5194/acp-24-13403-2024" target="_blank">https://doi.org/10.5194/acp-24-13403-2024</a>, 2024.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib30"><label>Hoffmann et al.(2025)</label><mixed-citation>
       Hoffmann, F., Chen, Y.-S., and Feingold, G.: On the processes determining the slope of cloud water adjustments in weakly and non-precipitating stratocumulus, Atmos. Chem. Phys., 25, 8657–8670, <a href="https://doi.org/10.5194/acp-25-8657-2025" target="_blank">https://doi.org/10.5194/acp-25-8657-2025</a>, 2025.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib31"><label>Igel and Igel(2018)</label><mixed-citation>
       Igel, M. R. and Igel, A. L.: The energetics and magnitude of hydrometeor friction in clouds, J. Atmos. Sci., 75, 1343–1350, <a href="https://doi.org/10.1175/JAS-D-17-0285.1" target="_blank">https://doi.org/10.1175/JAS-D-17-0285.1</a>, 2018.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib32"><label>Kalmus et al.(2014)</label><mixed-citation>
       Kalmus, P., Lebsock, M., and Teixeira, J.: Observational boundary layer energy and water budgets of the stratocumulus-to-cumulus transition, J. Climate, 27, 9155–9170, <a href="https://doi.org/10.1175/JCLI-D-14-00242.1" target="_blank">https://doi.org/10.1175/JCLI-D-14-00242.1</a>, 2014.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib33"><label>Kato and Rose(2020)</label><mixed-citation>
       Kato, S. and Rose, F. G.: Global and regional entropy production by radiation estimated from satellite observations, J. Climate, 33, 2985–3000, <a href="https://doi.org/10.1175/JCLI-D-19-0596.1" target="_blank">https://doi.org/10.1175/JCLI-D-19-0596.1</a>, 2020.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib34"><label>Kazil et al.(2017)</label><mixed-citation>
       Kazil, J., Yamaguchi, T., and Feingold, G.: Mesoscale organization, entrainment, and the properties of a closed-cell stratocumulus cloud, J. Adv. Model. Earth Sy., 9, 2214–2229, <a href="https://doi.org/10.1002/2017MS001072" target="_blank">https://doi.org/10.1002/2017MS001072</a>, 2017.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib35"><label>Khairoutdinov and Randall(2003)</label><mixed-citation>
       Khairoutdinov, M. F. and Randall, D. A.: Cloud resolving modeling of the ARM Summer 1997 IOP: model formulation, results, uncertainties, and sensitivities, J. Atmos. Sci., 60, 607–625, <a href="https://doi.org/10.1175/1520-0469(2003)060&lt;0607:CRMOTA&gt;2.0.CO;2" target="_blank">https://doi.org/10.1175/1520-0469(2003)060&lt;0607:CRMOTA&gt;2.0.CO;2</a>, 2003.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib36"><label>Kleidon(2004)</label><mixed-citation>
       Kleidon, A.: Beyond Gaia: thermodynamics of life and earth system functioning, Climatic Change, 66, 271–319, <a href="https://doi.org/10.1023/B:CLIM.0000044616.34867.ec" target="_blank">https://doi.org/10.1023/B:CLIM.0000044616.34867.ec</a>, 2004.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib37"><label>Koren and Feingold(2011)</label><mixed-citation>
       Koren, I. and Feingold, G.: Aerosol–cloud–precipitation system as a predator-prey problem, P. Natl. Acad. Sci. USA, 108, 12227–12232, <a href="https://doi.org/10.1073/pnas.1101777108" target="_blank">https://doi.org/10.1073/pnas.1101777108</a>, 2011.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib38"><label>Koren and Feingold(2013)</label><mixed-citation>
       Koren, I. and Feingold, G.: Adaptive behavior of marine cellular clouds, Sci. Rep., 3, 2507, <a href="https://doi.org/10.1038/srep02507" target="_blank">https://doi.org/10.1038/srep02507</a>, 2013.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib39"><label>Laliberté et al.(2015)</label><mixed-citation>
       Laliberté, F., Zika, J., Mudryk, L., Kushner, P. J., Kjellsson, J., and Döös, K.: Constrained work output of the moist atmospheric heat engine in a warming climate, Science, 347, 540–543, <a href="https://doi.org/10.1126/science.1257103" target="_blank">https://doi.org/10.1126/science.1257103</a>, 2015.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib40"><label>Lilly(1968)</label><mixed-citation>
       Lilly, D. K.: Models of cloud-topped mixed layers under a strong inversion, Q. J. Roy. Meteor. Soc., 94, 292–309, <a href="https://doi.org/10.1002/qj.49709440106" target="_blank">https://doi.org/10.1002/qj.49709440106</a>, 1968.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib41"><label>Lucarini(2009)</label><mixed-citation>
       Lucarini, V.: Thermodynamic efficiency and entropy production in the climate system, Phys. Rev. E, 80, 021118, <a href="https://doi.org/10.1103/PhysRevE.80.021118" target="_blank">https://doi.org/10.1103/PhysRevE.80.021118</a>, 2009.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib42"><label>Lucarini et al.(2010)</label><mixed-citation>
       Lucarini, V., Fraedrich, K., and Lunkeit, F.: Thermodynamic analysis of snowball Earth hysteresis experiment: efficiency, entropy production and irreversibility, Q. J. Roy. Meteor. Soc., 136, 2–11, <a href="https://doi.org/10.1002/qj.543" target="_blank">https://doi.org/10.1002/qj.543</a>, 2010.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib43"><label>Morris and Mitchell(1995)</label><mixed-citation>
       Morris, M. D. and Mitchell, T. J.: Exploratory designs for computational experiments, J. Stat. Plann. Inference, 43, 381–402, <a href="https://doi.org/10.1016/0378-3758(94)00035-T" target="_blank">https://doi.org/10.1016/0378-3758(94)00035-T</a>, 1995.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib44"><label>Myers et al.(2021)</label><mixed-citation>
       Myers, T. A., Scott, R. C., Zelinka, M. D., Klein, S. A., Norris, J. R., and Caldwell, P. M.: Observational constraints on low cloud feedback reduce uncertainty of climate sensitivity, Nat. Clim. Change, 11, 501–507, <a href="https://doi.org/10.1038/s41558-021-01039-0" target="_blank">https://doi.org/10.1038/s41558-021-01039-0</a>, 2021.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib45"><label>Onsager(1931)</label><mixed-citation>
       Onsager, L.: Reciprocal relations in irreversible processes. II., Phys. Rev., 38, 2265–2279, <a href="https://doi.org/10.1103/PhysRev.38.2265" target="_blank">https://doi.org/10.1103/PhysRev.38.2265</a>, 1931.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib46"><label>Ozawa and Shimokawa(2015)</label><mixed-citation>
       Ozawa, H. and Shimokawa, S.: Thermodynamics of a tropical cyclone: generation and dissipation of mechanical energy in a self-driven convection system, Tellus A, 67, 24216, <a href="https://doi.org/10.3402/tellusa.v67.24216" target="_blank">https://doi.org/10.3402/tellusa.v67.24216</a>, 2015.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib47"><label>Ozawa et al.(2003)</label><mixed-citation>
       Ozawa, H., Ohmura, A., Lorenz, R. D., and Pujol, T.: The second law of thermodynamics and the global climate system: a review of the maximum entropy production principle, Rev. Geophys., 41, 1018, <a href="https://doi.org/10.1029/2002RG000113" target="_blank">https://doi.org/10.1029/2002RG000113</a>, 2003.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib48"><label>Paltridge(1975)</label><mixed-citation>
       Paltridge, G. W.: Global dynamics and climate – a system of minimum entropy exchange, Q. J. Roy. Meteor. Soc., 101, 475–484, <a href="https://doi.org/10.1002/qj.49710142906" target="_blank">https://doi.org/10.1002/qj.49710142906</a>, 1975.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib49"><label>Pauluis(2011)</label><mixed-citation>
       Pauluis, O.: Water vapor and mechanical work: a comparison of carnot and steam cycles, J. Atmos. Sci., 68, 91–102, <a href="https://doi.org/10.1175/2010JAS3530.1" target="_blank">https://doi.org/10.1175/2010JAS3530.1</a>, 2011.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib50"><label>Pauluis(2016)</label><mixed-citation>
       Pauluis, O. M.: The mean air flow as Lagrangian dynamics approximation and its application to moist convection, J. Atmos. Sci., 73, 4407–4425, <a href="https://doi.org/10.1175/JAS-D-15-0284.1" target="_blank">https://doi.org/10.1175/JAS-D-15-0284.1</a>, 2016.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib51"><label>Pauluis and Held(2002a)</label><mixed-citation>
       Pauluis, O. and Held, I. M.: Entropy budget of an atmosphere in radiative–convective equilibrium. Part I: Maximum work and frictional dissipation, J. Atmos. Sci., 59, 125–139, <a href="https://doi.org/10.1175/1520-0469(2002)059&lt;0125:EBOAAI&gt;2.0.CO;2" target="_blank">https://doi.org/10.1175/1520-0469(2002)059&lt;0125:EBOAAI&gt;2.0.CO;2</a>, 2002a.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib52"><label>Pauluis and Held(2002b)</label><mixed-citation>
       Pauluis, O. and Held, I. M.: Entropy budget of an atmosphere in radiative–convective equilibrium. Part II: Latent heat transport and moist processes, J. Atmos. Sci., 59, 140–149, <a href="https://doi.org/10.1175/1520-0469(2002)059&lt;0140:EBOAAI&gt;2.0.CO;2" target="_blank">https://doi.org/10.1175/1520-0469(2002)059&lt;0140:EBOAAI&gt;2.0.CO;2</a>, 2002b.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib53"><label>Pauluis and Zhang(2017)</label><mixed-citation>
       Pauluis, O. M. and Zhang, F.: Reconstruction of thermodynamic cycles in a high-resolution simulation of a hurricane, J. Atmos. Sci., 74, 3367–3381, <a href="https://doi.org/10.1175/JAS-D-16-0353.1" target="_blank">https://doi.org/10.1175/JAS-D-16-0353.1</a>, 2017.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib54"><label>Pauluis et al.(2000)</label><mixed-citation>
       Pauluis, O., Balaji, V., and Held, I. M.: Frictional Dissipation in a Precipitating Atmosphere, J. Atmos. Sci., 57, 989–994, <a href="https://doi.org/10.1175/1520-0469(2000)057&lt;0989:FDIAPA&gt;2.0.CO;2" target="_blank">https://doi.org/10.1175/1520-0469(2000)057&lt;0989:FDIAPA&gt;2.0.CO;2</a>, 2000.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib55"><label>Possner et al.(2020)</label><mixed-citation>
       Possner, A., Eastman, R., Bender, F., and Glassmeier, F.: Deconvolution of boundary layer depth and aerosol constraints on cloud water path in subtropical stratocumulus decks, Atmos. Chem. Phys., 20, 3609–3621, <a href="https://doi.org/10.5194/acp-20-3609-2020" target="_blank">https://doi.org/10.5194/acp-20-3609-2020</a>, 2020.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib56"><label>Prigogine(1968)</label><mixed-citation>
       Prigogine, I.: Introduction to Thermodynamics of Irreversible Processes, Wiley, 3rd edn., ISBN 9780470699287, 1968.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib57"><label>Rennó and Ingersoll(1996)</label><mixed-citation>
       Rennó, N. O. and Ingersoll, A. P.: Natural convection as a heat engine: a theory for CAPE, J. Atmos. Sci., 53, 572–585, <a href="https://doi.org/10.1175/1520-0469(1996)053&lt;0572:NCAAHE&gt;2.0.CO;2" target="_blank">https://doi.org/10.1175/1520-0469(1996)053&lt;0572:NCAAHE&gt;2.0.CO;2</a>, 1996.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib58"><label>Romps(2008)</label><mixed-citation>
       Romps, D. M.: The dry-entropy budget of a moist atmosphere, J. Atmos. Sci., 65, 3779–3799, <a href="https://doi.org/10.1175/2008JAS2679.1" target="_blank">https://doi.org/10.1175/2008JAS2679.1</a>, 2008.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib59"><label>Régibeau-Rockett et al.(2023)</label><mixed-citation>
       Régibeau-Rockett, L., Pauluis, O. M., and O'Neill, M. E.: Investigating the relationship between sea surface temperature and the mechanical efficiency of tropical cyclones, J. Climate, 37, 439–456, <a href="https://doi.org/10.1175/JCLI-D-22-0877.1" target="_blank">https://doi.org/10.1175/JCLI-D-22-0877.1</a>, 2023.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib60"><label>Savic-Jovcic and Stevens(2008)</label><mixed-citation>
       Savic-Jovcic, V. and Stevens, B.: The structure and mesoscale organization of precipitating stratocumulus, J. Atmos. Sci., 65, 1587–1605, <a href="https://doi.org/10.1175/2007JAS2456.1" target="_blank">https://doi.org/10.1175/2007JAS2456.1</a>, 2008.


    </mixed-citation></ref-html>
<ref-html id="bib1.bib61"><label>Schubert et al.(1979)</label><mixed-citation>
       Schubert, W. H., Wakefield, J. S., Steiner, E. J., and Cox, S. K.: Marine stratocumulus convection. Part II: Horizontally inhomogeneous solutions, J. Atmos. Sci., 36, 1308–1324, <a href="https://doi.org/10.1175/1520-0469(1979)036&lt;1308:MSCPIH&gt;2.0.CO;2" target="_blank">https://doi.org/10.1175/1520-0469(1979)036&lt;1308:MSCPIH&gt;2.0.CO;2</a>, 1979.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib62"><label>Singh and O'Gorman(2016)</label><mixed-citation>
       Singh, M. S. and O'Gorman, P. A.: Scaling of the entropy budget with surface temperature in radiative-convective equilibrium, J. Adv. Model. Earth Sy., 8, 1132–1150, <a href="https://doi.org/10.1002/2016MS000673" target="_blank">https://doi.org/10.1002/2016MS000673</a>, 2016.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib63"><label>Singh and O'Neill(2022)</label><mixed-citation>
       Singh, M. S. and O'Neill, M. E.: The climate system and the second law of thermodynamics, Rev. Mod. Phys., 94, 015001, <a href="https://doi.org/10.1103/RevModPhys.94.015001" target="_blank">https://doi.org/10.1103/RevModPhys.94.015001</a>, 2022.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib64"><label>Stephens and Greenwald(1991)</label><mixed-citation>
       Stephens, G. L. and Greenwald, T. J.: The Earth's radiation budget and its relation to atmospheric hydrology: 2. Observations of cloud effects, J. Geophys. Res.-Atmos., 96, 15325–15340, <a href="https://doi.org/10.1029/91JD00972" target="_blank">https://doi.org/10.1029/91JD00972</a>, 1991.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib65"><label>Stephens and O'Brien(1993)</label><mixed-citation>
       Stephens, G. L. and O'Brien, D. M.: Entropy and climate. I: ERBE observations of the entropy production of the earth, Q. J. Roy. Meteor. Soc., 119, 121–152, <a href="https://doi.org/10.1002/qj.49711950906" target="_blank">https://doi.org/10.1002/qj.49711950906</a>, 1993.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib66"><label>Stevens et al.(2005)</label><mixed-citation>
       Stevens, B., Moeng, C.-H., Ackerman, A. S., Bretherton, C. S., Chlond, A., de Roode, S., Edwards, J., Golaz, J.-C., Jiang, H., Khairoutdinov, M., Kirkpatrick, M. P., Lewellen, D. C., Lock, A., Müller, F., Stevens, D. E., Whelan, E., and Zhu, P.: Evaluation of large-eddy simulations via observations of nocturnal marine stratocumulus, Mon. Weather Rev., 133, 1443–1462, <a href="https://doi.org/10.1175/MWR2930.1" target="_blank">https://doi.org/10.1175/MWR2930.1</a>, 2005.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib67"><label>Stevens and Bretherton(1999)</label><mixed-citation>
       Stevens, D. E. and Bretherton, C. S.: Effects of resolution on the simulation of stratocumulus entrainment, Q. J. Roy. Meteor. Soc., 125, 425–439, <a href="https://doi.org/10.1002/qj.49712555403" target="_blank">https://doi.org/10.1002/qj.49712555403</a>, 1999.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib68"><label>Volk and Pauluis(2010)</label><mixed-citation>
       Volk, T. and Pauluis, O.: It is not the entropy you produce, rather, how you produce it, Phil. Trans. R. Soc. Lond. B, 365, 1317–1322, <a href="https://doi.org/10.1098/rstb.2010.0019" target="_blank">https://doi.org/10.1098/rstb.2010.0019</a>, 2010.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib69"><label>Wang and Feingold(2009)</label><mixed-citation>
       Wang, H. and Feingold, G.: Modeling mesoscale cellular structures and drizzle in marine stratocumulus. Part I: Impact of drizzle on the formation and evolution of open cells, J. Atmos. Sci., 66, 3237–3256, <a href="https://doi.org/10.1175/2009JAS3022.1" target="_blank">https://doi.org/10.1175/2009JAS3022.1</a>, 2009.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib70"><label>Wood(2012)</label><mixed-citation>
       Wood, R.: Stratocumulus clouds, Mon. Weather Rev., 140, 2373–2423, <a href="https://doi.org/10.1175/MWR-D-11-00121.1" target="_blank">https://doi.org/10.1175/MWR-D-11-00121.1</a>, 2012.

    </mixed-citation></ref-html>
<ref-html id="bib1.bib71"><label>Xue et al.(2008)</label><mixed-citation>
       Xue, H., Feingold, G., and Stevens, B.: Aerosol effects on clouds, precipitation, and the organization of shallow cumulus convection, J. Atmos. Sci., 65, 392–406, <a href="https://doi.org/10.1175/2007JAS2428.1" target="_blank">https://doi.org/10.1175/2007JAS2428.1</a>, 2008.

    </mixed-citation></ref-html>--></article>
