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  <front>
    <journal-meta><journal-id journal-id-type="publisher">ACP</journal-id><journal-title-group>
    <journal-title>Atmospheric Chemistry and Physics</journal-title>
    <abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">Atmos. Chem. Phys.</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">1680-7324</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/acp-25-18549-2025</article-id><title-group><article-title>Influence of secondary ice formation on tropical deep convective clouds simulated by the Unified Model</article-title><alt-title>Secondary ice impacts on tropical deep convection</alt-title>
      </title-group>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1">
          <name><surname>Sun</surname><given-names>Mengyu</given-names></name>
          <email>mengyu.sun@manchester.ac.uk</email>
        <ext-link>https://orcid.org/0000-0002-3545-3187</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Connolly</surname><given-names>Paul J.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2 aff3">
          <name><surname>Field</surname><given-names>Paul R.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3 aff4">
          <name><surname>Finney</surname><given-names>Declan L.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-3334-6935</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff4 aff3">
          <name><surname>Blyth</surname><given-names>Alan M.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-7115-2587</ext-link></contrib>
        <aff id="aff1"><label>1</label><institution>Department of Earth and Environmental Sciences, University of Manchester, Manchester, UK</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Met Office, Exeter, UK</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>Institute for Climate and Atmospheric Science, School of Earth and Environment, University of Leeds, Leeds, UK</institution>
        </aff>
        <aff id="aff4"><label>4</label><institution>National Centre for Atmospheric Science, Leeds, UK</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Mengyu Sun (mengyu.sun@manchester.ac.uk)</corresp></author-notes><pub-date><day>19</day><month>December</month><year>2025</year></pub-date>
      
      <volume>25</volume>
      <issue>24</issue>
      <fpage>18549</fpage><lpage>18569</lpage>
      <history>
        <date date-type="received"><day>2</day><month>July</month><year>2025</year></date>
           <date date-type="rev-request"><day>22</day><month>August</month><year>2025</year></date>
           <date date-type="rev-recd"><day>10</day><month>November</month><year>2025</year></date>
           <date date-type="accepted"><day>30</day><month>November</month><year>2025</year></date>
      </history>
      <permissions>
        <copyright-statement>Copyright: © 2025 Mengyu Sun et al.</copyright-statement>
        <copyright-year>2025</copyright-year>
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://acp.copernicus.org/articles/25/18549/2025/acp-25-18549-2025.html">This article is available from https://acp.copernicus.org/articles/25/18549/2025/acp-25-18549-2025.html</self-uri><self-uri xlink:href="https://acp.copernicus.org/articles/25/18549/2025/acp-25-18549-2025.pdf">The full text article is available as a PDF file from https://acp.copernicus.org/articles/25/18549/2025/acp-25-18549-2025.pdf</self-uri>
      <abstract><title>Abstract</title>

      <p id="d2e140">Secondary ice production (SIP) plays an important role in tropical deep convection. This study implements multiple SIP mechanisms, including droplet fragmentation and ice–ice collisional breakup, into the CASIM microphysics scheme of the UK Met Office Unified Model, and evaluates their impacts through a real-case simulation of a Hector thunderstorm. SIP enhances ice number concentration in upper cloud layers, with values up to 3 orders of magnitude higher than the no-SIP case, particularly above <inline-formula><mml:math id="M1" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>10 <inline-formula><mml:math id="M2" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>. Ice water content (IWC) increases by a factor of 3–5 in the anvil region, contributing to more extensive upper-level cloud coverage. These microphysical changes reduce outgoing longwave radiation (OLR) by <inline-formula><mml:math id="M3" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3.2 <inline-formula><mml:math id="M4" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> (1.3 %) and increase outgoing shortwave radiation (OSR) by <inline-formula><mml:math id="M5" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 4.5 <inline-formula><mml:math id="M6" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> (1.8 %) over a 6 <inline-formula><mml:math id="M7" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:math></inline-formula> analysis period and a 110 <inline-formula><mml:math id="M8" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M9" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 110 <inline-formula><mml:math id="M10" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> domain. SIP modifies precipitation spatially, yielding a more localized, compact rainfall pattern near the convective core, while reducing domain-averaged precipitation by <inline-formula><mml:math id="M11" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 8 %. Peak rainfall rates remain only slightly affected, consistent with the minor changes (<inline-formula><mml:math id="M12" display="inline"><mml:mo lspace="0mm">&lt;</mml:mo></mml:math></inline-formula> 1 <inline-formula><mml:math id="M13" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">s</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>) in maximum updraft velocity. Among the tested mechanisms, ice–ice collisional breakup shows negligible impact on simulated ice concentration, consistent with limited graupel-involved collision energetics under warm profiles. Ensemble experiments confirm that these effects are robust and exceed the influence of meteorological variability. These results highlight the importance of representing SIP processes in cloud-resolving models of tropical convection and accounting for their environmental dependence.</p>
  </abstract>
    
<funding-group>
<award-group id="gs1">
<funding-source>Natural Environment Research Council</funding-source>
<award-id>NE/T006420/1</award-id>
</award-group>
<award-group id="gs2">
<funding-source>HORIZON EUROPE Framework Programme</funding-source>
<award-id>No. 101137680</award-id>
</award-group>
</funding-group>
</article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <label>1</label><title>Introduction</title>
      <p id="d2e281">The formation of ice particles in mixed-phase and deep convective clouds plays a central role in cloud microphysics, precipitation processes, and cloud–radiation interactions. Observational studies have consistently shown that the number concentrations of ice particles in clouds often exceed that explained by primary ice nucleation alone (Hallett et al., 1978; Hobbs and Rangno, 1985; Cantrell and Heymsfield, 2005; Korolev et al., 2022). This discrepancy has been widely attributed to secondary ice production (SIP) processes (Field et al., 2017; Korolev et al., 2020), which generate additional ice particles from existing hydrometeors through mechanisms such as rime splintering (Hallett and Mossop, 1974), droplet shattering during freezing (Dye and Hobbs, 1968; Keinert et al., 2020; James et al., 2021), and ice–ice collisional breakup (Vardiman, 1978; Takahashi et al., 1995; Grzegorczyk et al., 2023; Gautam et al., 2024; Yadav et al., 2025). SIP primarily occurs in the mixed-phase region of clouds. It can significantly enhance upper-level ice crystal concentrations, alter the hydrometeor size distribution, and affect cloud lifetime, precipitation efficiency, and radiative fluxes at the top of the atmosphere (Lohmann, 2006; Kudzotsa et al., 2016; Han et al., 2024; Waman et al., 2025). Understanding and quantifying the effects of SIP using cloud-resolving models is crucial for improving the simulation of convective cloud systems and their feedback in the climate system.</p>
      <p id="d2e284">Despite significant progress in identifying and parameterizing SIP processes the application of parameterizations across different cloud regimes remains uncertain. Most existing SIP schemes were originally developed based on midlatitude stratiform or polar mixed-phase clouds, where environmental conditions such as temperature, liquid water content, and hydrometeor types differ markedly from those in tropical deep convection (Phillips et al., 2017a; Zhao et al., 2021). In deep tropical convection, warmer and more humid profiles, elevated freezing levels, and less abundant graupel may inhibit the activation of certain SIP mechanisms. For example, the classic rime-splintering mechanism (Hallett and Mossop, 1974) requires a narrow temperature window (<inline-formula><mml:math id="M14" display="inline"><mml:mo lspace="0mm">-</mml:mo></mml:math></inline-formula>3 to <inline-formula><mml:math id="M15" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>8 <inline-formula><mml:math id="M16" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>) and the co-existence of supercooled cloud droplets and graupel. These conditions may occur under favorable thermodynamic environments (Bazantay et al., 2025), but are not always present in tropical convective updrafts (Field et al., 2017; Huang et al., 2022). Moreover, recent laboratory studies found no experimental evidence of efficient rime-splintering under convective conditions (Seidel et al., 2024), suggesting that the relevance of this process and its parameterization remain uncertain. Other processes such as raindrop freezing fragmentation (Mode 1), drop–ice collisions with splashing/shedding (Mode 2), and ice–ice collisional breakup (BR) also exhibit strong environmental dependencies related to turbulence intensity, hydrometeor interactions, and liquid water availability (Lauber et al., 2018; Phillips et al., 2018; Korolev et al., 2020). While all these mechanisms have been implemented in various model microphysics schemes, few studies have systematically compared them in a unified framework (e.g., Hawker et al., 2021a, b). Consequently, their relative contributions and possible interactions remain poorly understood, limiting the physical realism and environmental adaptability of current SIP parameterizations (Han et al., 2024; Grzegorczyk et al., 2025a).</p>
      <p id="d2e311">Beyond its role in modulating cloud microphysics, SIP may also have important impacts on precipitation structure and radiative fluxes, especially in tropical convective systems. By altering the number and type of ice-phase particles aloft, SIP can influence cloud development and precipitation formation (Qu et al., 2022; Waman et al., 2022). For instance, some studies have suggested that SIP enhances localized precipitation near convective cores (e.g., Sullivan et al., 2018), while others have reported reductions in domain-averaged rainfall linked to reduced warm-rain contributions (Han et al., 2024; Grzegorczyk et al., 2025b, c). However, these effects appear to be highly sensitive to the specific SIP mechanisms involved, and the underlying thermodynamic environment. Moreover, the importance of different SIP mechanisms may also be modulated by the availability and properties of ice-nucleating particles (INPs), which affect primary ice formation and the conditions favoring SIP activation (Hawker et al., 2021a, b).</p>
      <p id="d2e314">At the same time, SIP-induced changes to ice particle concentration and distribution, particularly in the upper-levels, can modify anvil cloud optical thickness, thereby influencing top-of-atmosphere radiative fluxes (Young et al., 2019; Zhao and Liu, 2021). Increased ice loading and the expansion of anvil cloud area may lower outgoing longwave radiation (OLR) due to colder and more extensive cloud tops, while enhanced shortwave reflectivity (i.e., outgoing shortwave radiation, OSR) may result from higher concentrations of small ice crystals (McKim et al., 2024; Finney et al., 2025). Despite these potential impacts, few modeling studies have explicitly evaluated how SIP mechanisms affect both precipitation and radiation in a coupled manner. Given the prominence of deep convection in the tropical energy budget and climate system, a more integrated assessment of SIP-driven changes to precipitation efficiency and radiative transfer is urgently needed.</p>
      <p id="d2e318">To address these uncertainties, this study implements multiple SIP mechanisms, including droplet-freezing fragmentation (Mode 1 and Mode 2) and ice–ice collisional breakup, into the double-moment cloud microphysics scheme (CASIM) of the Unified Model (UM), which already includes rime splintering by default. A Hector-type tropical convective system (Crook, 2001; Connolly et al., 2006) is simulated, and multi-source observational datasets are used to benchmark the model outputs.</p>
      <p id="d2e321">We begin by examining how SIP modifies the storm's radiative and dynamical characteristics, including OLR, OSR, and upper-level anvil development. Next, we assess SIP-induced changes in the spatial distribution and intensity of precipitation. Finally, we analyze the microphysical pathways by comparing vertical profiles of ice-phase hydrometeors, enabling us to interpret the macro-scale responses in terms of specific SIP mechanisms. A set of sensitivity experiments is conducted to assess the effects of individual and combined SIP processes under tropical convective conditions. The model setup, experiment design, and evaluation metrics are described in the following sections.</p>
</sec>
<sec id="Ch1.S2">
  <label>2</label><title>Methodology</title>
<sec id="Ch1.S2.SS1">
  <label>2.1</label><title>Model description</title>
      <p id="d2e339">We use the Met Office Unified Model (UM) to conduct simulations of Hector thunderstorms over the Darwin region, during research as part of the ACTIVE campaign. The UM can be applied at a range of scales and geographical regions for weather forecasting.</p>
      <p id="d2e342">The UM uses the ENDGame semi-Lagrangian dynamical formulation to solve the non-hydrostatic equations of motion (Wood et al., 2014). For regional-scale modeling at resolutions of order 1 <inline-formula><mml:math id="M17" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> presented there is no parameterized convection. The SOCRATES scheme (Manners et al., 2025) is used for radiative transfer based on Edwards and Slingo (1996). Boundary layer turbulence is represented with a “blended”, three-dimensional turbulent mixing scheme. This boundary-layer parameterization (Boutle et al., 2014; Bush et al., 2023) includes any non-local contribution from the scheme of Lock et al. (2000).</p>
      <p id="d2e353">Cloud microphysics is described by the Cloud-AeroSol Interacting Microphysics (CASIM) module (Miltenberger et al., 2020; Field et al., 2023). CASIM is a multi-moment bulk scheme, which in this study is configured to be double moment. It can predict the mass and number of five hydrometeors species (cloud droplets, raindrops, ice crystals, graupel, and snow) prognostically. The size distribution of different species is assumed to be a generalized gamma distribution. Specific hydrometeor parameters including the terminal fall speed velocities, shape and mass dimension are shown in Table A1 of Field et al. (2023). In our configuration, the ice-cloud optical properties used by SOCRATES (Manners et al., 2025) are diagnosed consistently from the CASIM-predicted ice water content and ice-phase number concentrations, so changes in ice amount and size distribution associated with different SIP mechanisms tend to be reflected in the simulated radiative fluxes. In CASIM, the cloud droplet number concentration (<inline-formula><mml:math id="M18" display="inline"><mml:mrow><mml:msub><mml:mi>N</mml:mi><mml:mi mathvariant="normal">d</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) can be either diagnosed from background aerosol via explicit cloud condensation nuclei (CCN) activation or prescribed as a fixed droplet number. To isolate and examine SIP-induced responses, we adopt a fixed <inline-formula><mml:math id="M19" display="inline"><mml:mrow><mml:msub><mml:mi>N</mml:mi><mml:mi mathvariant="normal">d</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M20" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 400 <inline-formula><mml:math id="M21" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">cm</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in this study. This value falls within the CCN activation range reported for Hector storms in the pre-monsoon period (Connolly et al., 2013) and gives the best overall agreement with the available observations in this case (figures not shown). CASIM considers homogeneous freezing of cloud droplets, heterogeneous freezing, aggregation of ice crystals, sedimentation of ice-phase hydrometeors, and rime splintering. Homogeneous freezing of cloud droplets happens when temperatures is below the temperature threshold (<inline-formula><mml:math id="M22" display="inline"><mml:mo lspace="0mm">-</mml:mo></mml:math></inline-formula>38 <inline-formula><mml:math id="M23" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>) and cloud water mass exceeds 10<sup>−6</sup> <inline-formula><mml:math id="M25" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">g</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">kg</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, following Jeffery and Austin (1997). The parameterization of heterogeneous ice nucleation given by Cooper (1986) is used in this study. It is independent of the aerosol concentration and calculates the freezing rate based on temperature. Heterogeneous freezing of rain is represented following Bigg (1953). SIP from riming-splintering is parameterized following Hallett and Mossop (1974). We describe this together with other newly implemented SIP processes in Sect. <xref ref-type="sec" rid="Ch1.S2.SS2"/>.</p>
</sec>
<sec id="Ch1.S2.SS2">
  <label>2.2</label><title>Implementation of secondary ice production in the CASIM</title>
      <p id="d2e456">In addition to the existing SIP process (i.e., riming splintering), we have implemented three new SIP mechanisms in the CASIM, including ice–ice collisional breakup, droplet shattering during symmetrical freezing, and droplet shattering during asymmetrical freezing, based on previous laboratory and theoretical research (Phillips et al., 2017a, 2018; James et al., 2021, 2023). The corresponding equations are reproduced below to explicitly show the parameterizations applied in our simulations.</p>
<sec id="Ch1.S2.SS2.SSS1">
  <label>2.2.1</label><title>Rime splintering</title>
      <p id="d2e466">CASIM microphysics already includes the ice splinter production through riming (RS), which is known as the Hallett-Mossop process. The number and mass of secondary ice particles are produced during the accretion of water droplets by graupel and snow. The ice production rate is based on a triangular function (Hallett and Mossop, 1974):

              <disp-formula id="Ch1.E1" content-type="numbered"><label>1</label><mml:math id="M26" display="block"><mml:mrow><mml:msub><mml:mi>P</mml:mi><mml:mi mathvariant="normal">ihal</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">3.5</mml:mn><mml:mo>×</mml:mo><mml:msup><mml:mn mathvariant="normal">10</mml:mn><mml:mn mathvariant="normal">8</mml:mn></mml:msup><mml:msub><mml:mi>M</mml:mi><mml:mrow><mml:mi mathvariant="normal">I</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi>P</mml:mi><mml:mi mathvariant="normal">gacw</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>P</mml:mi><mml:mi mathvariant="normal">sacw</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:msub><mml:mi>f</mml:mi><mml:mi mathvariant="normal">RS</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>T</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></disp-formula>

            where <inline-formula><mml:math id="M27" display="inline"><mml:mrow><mml:msub><mml:mi>P</mml:mi><mml:mi mathvariant="normal">ihal</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the splinter production rate (units: <inline-formula><mml:math id="M28" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">number</mml:mi><mml:mspace width="0.25em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">kg</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">s</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>), <inline-formula><mml:math id="M29" display="inline"><mml:mrow><mml:msub><mml:mi>P</mml:mi><mml:mi mathvariant="normal">gacw</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M30" display="inline"><mml:mrow><mml:msub><mml:mi>P</mml:mi><mml:mi mathvariant="normal">sacw</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> are the riming rate of cloud droplets by graupel and snow, respectively, and <inline-formula><mml:math id="M31" display="inline"><mml:mrow><mml:msub><mml:mi>M</mml:mi><mml:mrow><mml:mi mathvariant="normal">I</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> is the mass of each splinter. The temperature-dependent function, <inline-formula><mml:math id="M32" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mi mathvariant="normal">RS</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>T</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, has a maximum value of 100 % at <inline-formula><mml:math id="M33" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M34" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M35" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>5 <inline-formula><mml:math id="M36" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> and falls off linearly to zero at <inline-formula><mml:math id="M37" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M38" display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M39" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>2.5 <inline-formula><mml:math id="M40" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> or <inline-formula><mml:math id="M41" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M42" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M43" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>7.5 <inline-formula><mml:math id="M44" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>. A maximum splinter production per rimed ice is set at 3.5 <inline-formula><mml:math id="M45" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<sup>8</sup> fragments kg<sup>−1</sup> at <inline-formula><mml:math id="M48" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>5 <inline-formula><mml:math id="M49" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>, based on laboratory experiments (Hallett and Mossop, 1974; Mossop, 1985).</p>

<table-wrap id="T1" specific-use="star"><label>Table 1</label><caption><p id="d2e762">List of experiments.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="5">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:colspec colnum="3" colname="col3" align="left"/>
     <oasis:colspec colnum="4" colname="col4" align="left"/>
     <oasis:colspec colnum="5" colname="col5" align="left"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry rowsep="1" namest="col2" nameend="col5" align="center">Type of secondary ice production </oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">Rime splintering</oasis:entry>
         <oasis:entry colname="col3">Droplet shattering</oasis:entry>
         <oasis:entry colname="col4">Droplet shattering</oasis:entry>
         <oasis:entry colname="col5">Ice–ice collisional</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2"/>
         <oasis:entry colname="col3">(Mode 1)</oasis:entry>
         <oasis:entry colname="col4">(Mode 2)</oasis:entry>
         <oasis:entry colname="col5">breakup</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">all-SIP</oasis:entry>
         <oasis:entry colname="col2">Hallett and Mossop (1974)</oasis:entry>
         <oasis:entry colname="col3">Phillips et al. (2018)</oasis:entry>
         <oasis:entry colname="col4">Phillips et al. (2018)</oasis:entry>
         <oasis:entry colname="col5">Phillips et al. (2017a)</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">RS</oasis:entry>
         <oasis:entry colname="col2">Hallett and Mossop (1974)</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">–</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">RS <inline-formula><mml:math id="M50" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M1</oasis:entry>
         <oasis:entry colname="col2">Hallett and Mossop (1974)</oasis:entry>
         <oasis:entry colname="col3">Phillips et al. (2018)</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">–</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">RS <inline-formula><mml:math id="M51" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M2</oasis:entry>
         <oasis:entry colname="col2">Hallett and Mossop (1974)</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">Phillips et al. (2018)</oasis:entry>
         <oasis:entry colname="col5">–</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">RS <inline-formula><mml:math id="M52" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> BR</oasis:entry>
         <oasis:entry colname="col2">Hallett and Mossop (1974)</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">Phillips et al. (2017a)</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">no-SIP</oasis:entry>
         <oasis:entry colname="col2">–</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
         <oasis:entry colname="col4">–</oasis:entry>
         <oasis:entry colname="col5">–</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table><table-wrap-foot><p id="d2e765">Note: Mode 1 (M1) represents fragmentation during spherical drop freezing, and Mode 2 (M2) represents collisions of supercooled raindrops with more massive ice (Phillips et al., 2018).</p></table-wrap-foot></table-wrap>

</sec>
<sec id="Ch1.S2.SS2.SSS2">
  <label>2.2.2</label><title>Ice–ice collisional breakup</title>
      <p id="d2e969">Parameterization of ice–ice collisional breakup (BR) is based on energy conservation principle (Phillips et al., 2017a), in which collision kinetic energy (CKE) is the fundamental governing variable of fragmentation in collisions of microphysical species (e.g., ice crystals, graupel, snow, or freezing drops). The production rate of ice particles number concentration (<inline-formula><mml:math id="M53" display="inline"><mml:mrow><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mrow><mml:mo>∂</mml:mo><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mo>∂</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:msub><mml:mi mathvariant="normal">|</mml:mi><mml:mi mathvariant="normal">CB</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, units: <inline-formula><mml:math id="M54" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">number</mml:mi><mml:mspace linebreak="nobreak" width="0.25em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">s</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>) is calculated as follows:

              <disp-formula id="Ch1.E2" content-type="numbered"><label>2</label><mml:math id="M55" display="block"><mml:mtable rowspacing="0.2ex" class="split" displaystyle="true" columnalign="right left"><mml:mtr><mml:mtd><mml:mrow><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mo>∂</mml:mo><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mo>∂</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:msub><mml:mi mathvariant="normal">|</mml:mi><mml:mi mathvariant="normal">CB</mml:mi></mml:msub></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mspace width="0.25em" linebreak="nobreak"/><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mi mathvariant="italic">π</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mfrac></mml:mstyle><mml:mi>E</mml:mi><mml:msubsup><mml:mo>∬</mml:mo><mml:mn mathvariant="normal">0</mml:mn><mml:mi mathvariant="normal">∞</mml:mi></mml:msubsup><mml:msub><mml:mi>N</mml:mi><mml:mi mathvariant="normal">CB</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub><mml:mo>,</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mo>)</mml:mo><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:msup><mml:mo>)</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd/><mml:mtd><mml:mrow><mml:mspace linebreak="nobreak" width="0.25em"/><mml:mo>×</mml:mo><mml:mi mathvariant="normal">|</mml:mi><mml:mi>v</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub><mml:mo>)</mml:mo><mml:mo>-</mml:mo><mml:mi>v</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mo>)</mml:mo><mml:mi mathvariant="normal">|</mml:mi><mml:mi>f</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub><mml:mo>)</mml:mo><mml:mi>f</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mo>)</mml:mo><mml:mi mathvariant="normal">d</mml:mi><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub><mml:mi mathvariant="normal">d</mml:mi><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mtr></mml:mtable></mml:math></disp-formula>

            where <inline-formula><mml:math id="M56" display="inline"><mml:mi>E</mml:mi></mml:math></inline-formula> is the collisional efficiency (assumed constant), <inline-formula><mml:math id="M57" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M58" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> represent the diameters of the colliding ice-phase particles (ice crystals, snow, or graupel), and <inline-formula><mml:math id="M59" display="inline"><mml:mrow><mml:mi>v</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M60" display="inline"><mml:mrow><mml:mi>v</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> are the fall speeds of these particles with diameters <inline-formula><mml:math id="M61" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M62" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>. The functions <inline-formula><mml:math id="M63" display="inline"><mml:mrow><mml:mi>f</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>) and <inline-formula><mml:math id="M64" display="inline"><mml:mrow><mml:mi>f</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>) denote the size distributions, defined as <inline-formula><mml:math id="M65" display="inline"><mml:mrow><mml:mi>f</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mrow><mml:mi>d</mml:mi><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mi>d</mml:mi><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:mfrac></mml:mstyle></mml:mrow></mml:math></inline-formula>, and similarly for <inline-formula><mml:math id="M66" display="inline"><mml:mrow><mml:mi>f</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>). <inline-formula><mml:math id="M67" display="inline"><mml:mrow><mml:msub><mml:mi>N</mml:mi><mml:mi mathvariant="normal">CB</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> represents the breakup number of fragments per collision and is calculated as follows:

              <disp-formula id="Ch1.E3" content-type="numbered"><label>3</label><mml:math id="M68" display="block"><mml:mrow><mml:msub><mml:mi>N</mml:mi><mml:mi mathvariant="normal">CB</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mi mathvariant="italic">α</mml:mi><mml:mi>A</mml:mi><mml:mfenced open="(" close=")"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:mi>exp⁡</mml:mi><mml:mfenced close="}" open="{"><mml:mrow><mml:mo>-</mml:mo><mml:msup><mml:mfenced open="[" close="]"><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mtext>CK</mml:mtext><mml:mrow><mml:mn mathvariant="normal">0</mml:mn><mml:mo>(</mml:mo><mml:mtext>CB</mml:mtext><mml:mo>)</mml:mo></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:mi mathvariant="italic">α</mml:mi><mml:mi>A</mml:mi></mml:mrow></mml:mfrac></mml:mstyle></mml:mfenced><mml:mi mathvariant="italic">γ</mml:mi></mml:msup></mml:mrow></mml:mfenced></mml:mrow></mml:mfenced></mml:mrow></mml:math></disp-formula>

            in which <inline-formula><mml:math id="M69" display="inline"><mml:mrow><mml:mi mathvariant="italic">α</mml:mi><mml:mo>=</mml:mo><mml:mi mathvariant="italic">π</mml:mi><mml:msup><mml:mi>D</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> is the equivalent spherical area of the colliding particle, <inline-formula><mml:math id="M70" display="inline"><mml:mi>A</mml:mi></mml:math></inline-formula> is the number density of the breakable asperities in the contact region, <inline-formula><mml:math id="M71" display="inline"><mml:mi>C</mml:mi></mml:math></inline-formula> is the asperity-fragility coefficient, and <inline-formula><mml:math id="M72" display="inline"><mml:mi mathvariant="italic">γ</mml:mi></mml:math></inline-formula> is a parameter of riming intensity. <inline-formula><mml:math id="M73" display="inline"><mml:mrow><mml:msub><mml:mi>K</mml:mi><mml:mrow><mml:mn mathvariant="normal">0</mml:mn><mml:mo>(</mml:mo><mml:mtext>CB</mml:mtext><mml:mo>)</mml:mo></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> represents the CKE between two colliding ice particles and is calculated as follows:

              <disp-formula id="Ch1.E4" content-type="numbered"><label>4</label><mml:math id="M74" display="block"><mml:mrow><mml:msub><mml:mi>K</mml:mi><mml:mrow><mml:mn mathvariant="normal">0</mml:mn><mml:mo>(</mml:mo><mml:mtext>CB</mml:mtext><mml:mo>)</mml:mo></mml:mrow></mml:msub><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mn mathvariant="normal">2</mml:mn></mml:mfrac></mml:mstyle><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi>m</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub><mml:msub><mml:mi>m</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mi>m</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>m</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>(</mml:mo><mml:msub><mml:mi>v</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi>v</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:msup><mml:mo>)</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>

            where <inline-formula><mml:math id="M75" display="inline"><mml:mrow><mml:msub><mml:mi>m</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> (and <inline-formula><mml:math id="M76" display="inline"><mml:mrow><mml:msub><mml:mi>m</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>), <inline-formula><mml:math id="M77" display="inline"><mml:mrow><mml:msub><mml:mi>v</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> (and <inline-formula><mml:math id="M78" display="inline"><mml:mrow><mml:msub><mml:mi>v</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>) are the mass and fall speeds of both. Three broad types of collisions are categorized in Phillips et al. (2017a), in which Type I represents the collision of graupel with other graupel, Type II is the collision of ice crystals or snow with graupel, and Type III is the collision of crystals or snow with other crystals/snow. The parameters <inline-formula><mml:math id="M79" display="inline"><mml:mi>A</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M80" display="inline"><mml:mi>C</mml:mi></mml:math></inline-formula> and <inline-formula><mml:math id="M81" display="inline"><mml:mi mathvariant="italic">γ</mml:mi></mml:math></inline-formula> depend on the collisional type. Further details are provided in Table <xref ref-type="table" rid="T1"/> and the Appendix of Phillips et al. (2017a). This parameterization is related to CKE, rimed fraction, temperature, and size of ice particles. For collisions without graupel (e.g., ice–ice and ice–snow), we prescribe a representative rime fraction of 0.1 based on ACTIVE observations; collisions involving graupel follow Phillips et al. (2017a) Table <xref ref-type="table" rid="T1"/> and are independent of rime fraction. In addition, numerical simulations indicate that snow–graupel collisions account for the majority of breakup fragments under convective conditions (Phillips et al., 2017b). The integral is evaluated online using a numerical integration routine within the CASIM scheme, and the collection efficiencies and terminal fall-speed parameters are given in Field et al. (2023), Appendix A, Tables A3 and A1, respectively.</p>
</sec>
<sec id="Ch1.S2.SS2.SSS3">
  <label>2.2.3</label><title>Droplet shattering during rain freezing</title>
      <p id="d2e1631">Ice multiplication during fragmentation of freezing raindrops has also been implemented in the CASIM, using the parameterization proposed by Phillips et al. (2018). Two modes of droplet shattering were identified based on the relative weight of raindrops and ice particles.</p>
      <p id="d2e1634">In Mode 1 (M1), raindrops freeze due to immersion INPs and then shatter into smaller ice fragments. These drops are typically more massive than the ice particles they collide with. The predicted fragment numbers are significantly enhanced near <inline-formula><mml:math id="M82" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>15 <inline-formula><mml:math id="M83" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>. By fitting the Lorentzian distribution to the laboratory data, the number of total (<inline-formula><mml:math id="M84" display="inline"><mml:mrow><mml:msub><mml:mi>N</mml:mi><mml:mrow><mml:mi mathvariant="normal">M</mml:mi><mml:mn mathvariant="normal">1</mml:mn><mml:mi mathvariant="normal">T</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>) and large (<inline-formula><mml:math id="M85" display="inline"><mml:mrow><mml:msub><mml:mi>N</mml:mi><mml:mrow><mml:mi mathvariant="normal">M</mml:mi><mml:mn mathvariant="normal">1</mml:mn><mml:mi mathvariant="normal">L</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>) fragments are given as:

                  <disp-formula specific-use="gather" content-type="numbered"><mml:math id="M86" display="block"><mml:mtable displaystyle="true"><mml:mlabeledtr id="Ch1.E5"><mml:mtd><mml:mtext>5</mml:mtext></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:msub><mml:mi>N</mml:mi><mml:mrow><mml:mi mathvariant="normal">M</mml:mi><mml:mn mathvariant="normal">1</mml:mn><mml:mi mathvariant="normal">T</mml:mi></mml:mrow></mml:msub><mml:mo>=</mml:mo><mml:mi>F</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mi mathvariant="normal">Ω</mml:mi><mml:mo>(</mml:mo><mml:mi>T</mml:mi><mml:mo>)</mml:mo><mml:mfenced close="]" open="["><mml:mrow><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mi mathvariant="italic">ζ</mml:mi><mml:msup><mml:mi mathvariant="italic">η</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow><mml:mrow><mml:mo>(</mml:mo><mml:mi>T</mml:mi><mml:mo>-</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:msup><mml:mo>)</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>+</mml:mo><mml:msup><mml:mi mathvariant="italic">η</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>+</mml:mo><mml:mi mathvariant="italic">β</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:mfenced><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E6"><mml:mtd><mml:mtext>6</mml:mtext></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:msub><mml:mi>N</mml:mi><mml:mrow><mml:mi mathvariant="normal">M</mml:mi><mml:mn mathvariant="normal">1</mml:mn><mml:mi mathvariant="normal">L</mml:mi></mml:mrow></mml:msub><mml:mo>=</mml:mo><mml:mo movablelimits="false">min⁡</mml:mo><mml:mfenced close="}" open="{"><mml:mrow><mml:mi>F</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mi mathvariant="normal">Ω</mml:mi><mml:mo>(</mml:mo><mml:mi>T</mml:mi><mml:mo>)</mml:mo><mml:mfenced close="]" open="["><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ζ</mml:mi><mml:mi mathvariant="normal">B</mml:mi></mml:msub><mml:msubsup><mml:mi mathvariant="italic">η</mml:mi><mml:mi mathvariant="normal">B</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msubsup></mml:mrow><mml:mrow><mml:mo>(</mml:mo><mml:mi>T</mml:mi><mml:mo>-</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mrow><mml:mi mathvariant="normal">B</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:msub><mml:msup><mml:mo>)</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>+</mml:mo><mml:msubsup><mml:mi mathvariant="italic">η</mml:mi><mml:mi mathvariant="normal">B</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msubsup></mml:mrow></mml:mfrac></mml:mstyle></mml:mfenced><mml:mo>,</mml:mo><mml:msub><mml:mi>N</mml:mi><mml:mi mathvariant="normal">T</mml:mi></mml:msub></mml:mrow></mml:mfenced><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula>

            where the parameters <inline-formula><mml:math id="M87" display="inline"><mml:mi mathvariant="italic">ζ</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M88" display="inline"><mml:mi mathvariant="italic">η</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M89" display="inline"><mml:mi mathvariant="italic">β</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M90" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ζ</mml:mi><mml:mi mathvariant="normal">B</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M91" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M92" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mrow><mml:mi mathvariant="normal">B</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> are derived from Phillips et al. (2018). The onset functions for fragmentation are defined as <inline-formula><mml:math id="M93" display="inline"><mml:mrow><mml:mi>F</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:msubsup><mml:mi mathvariant="normal">Δ</mml:mi><mml:mn mathvariant="normal">0</mml:mn><mml:mn mathvariant="normal">1</mml:mn></mml:msubsup><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>+</mml:mo><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) and <inline-formula><mml:math id="M94" display="inline"><mml:mrow><mml:mi mathvariant="normal">Ω</mml:mi><mml:mo>(</mml:mo><mml:mi>T</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:msubsup><mml:mi mathvariant="normal">Δ</mml:mi><mml:mn mathvariant="normal">0</mml:mn><mml:mn mathvariant="normal">1</mml:mn></mml:msubsup><mml:mo>(</mml:mo><mml:mo>-</mml:mo><mml:mi>T</mml:mi><mml:mo>-</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">c</mml:mi></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">c</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, where<inline-formula><mml:math id="M95" display="inline"><mml:mi>F</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M96" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0 for sizes below <inline-formula><mml:math id="M97" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M98" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 50 <inline-formula><mml:math id="M99" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M100" display="inline"><mml:mi>F</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M101" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 1 above <inline-formula><mml:math id="M102" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>+</mml:mo><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>D</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M103" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 60 <inline-formula><mml:math id="M104" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">µ</mml:mi><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>; similarly, <inline-formula><mml:math id="M105" display="inline"><mml:mi mathvariant="normal">Ω</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M106" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0 for <inline-formula><mml:math id="M107" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M108" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M109" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">c</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M110" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M111" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>3 <inline-formula><mml:math id="M112" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M113" display="inline"><mml:mi mathvariant="normal">Ω</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M114" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 1 if <inline-formula><mml:math id="M115" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M116" display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M117" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">c</mml:mi></mml:msub><mml:mo>-</mml:mo><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M118" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M119" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>6 <inline-formula><mml:math id="M120" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>. Here, <inline-formula><mml:math id="M121" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the drop diameter just before freezing, and <inline-formula><mml:math id="M122" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> is the freezing temperature of the raindrop. More details are provided in Table B1 and Appendix B of Phillips et al. (2018).</p>
      <p id="d2e2281">The total rate of secondary ice production due to M1 (<inline-formula><mml:math id="M123" display="inline"><mml:mrow><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mrow><mml:mo>∂</mml:mo><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mo>∂</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:msub><mml:mi mathvariant="normal">|</mml:mi><mml:mrow><mml:mi mathvariant="normal">M</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, units: <inline-formula><mml:math id="M124" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">number</mml:mi><mml:mspace linebreak="nobreak" width="0.25em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">s</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>) includes two contributions. The first term represents the freezing of supercooled raindrops via heterogeneous nucleation and the subsequent generation of fragments from each freezing event. The second term accounts for the collisional breakup between falling raindrops and less massive ice crystals, given as follows:

                  <disp-formula specific-use="gather" content-type="numbered"><mml:math id="M125" display="block"><mml:mtable displaystyle="true"><mml:mlabeledtr id="Ch1.E7"><mml:mtd><mml:mtext>7</mml:mtext></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mo>∂</mml:mo><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mo>∂</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:msub><mml:mi mathvariant="normal">|</mml:mi><mml:mrow><mml:mtext>M1</mml:mtext><mml:mo>,</mml:mo><mml:mi mathvariant="normal">f</mml:mi></mml:mrow></mml:msub><mml:mo>=</mml:mo><mml:msubsup><mml:mo>∫</mml:mo><mml:mn mathvariant="normal">0</mml:mn><mml:mi mathvariant="normal">∞</mml:mi></mml:msubsup><mml:mo>(</mml:mo><mml:msub><mml:mi>N</mml:mi><mml:mrow><mml:mi mathvariant="normal">M</mml:mi><mml:mn mathvariant="normal">1</mml:mn><mml:mi mathvariant="normal">T</mml:mi></mml:mrow></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>N</mml:mi><mml:mrow><mml:mi mathvariant="normal">M</mml:mi><mml:mn mathvariant="normal">1</mml:mn><mml:mi mathvariant="normal">L</mml:mi></mml:mrow></mml:msub><mml:mo>)</mml:mo><mml:mi>f</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mi mathvariant="normal">d</mml:mi><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E8"><mml:mtd><mml:mtext>8</mml:mtext></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mtable rowspacing="0.2ex" class="split" displaystyle="true" columnalign="right left"><mml:mtr><mml:mtd><mml:mrow><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mo>∂</mml:mo><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mo>∂</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:msub><mml:mi mathvariant="normal">|</mml:mi><mml:mrow><mml:mtext>M1</mml:mtext><mml:mo>,</mml:mo><mml:mi mathvariant="normal">c</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mspace linebreak="nobreak" width="0.25em"/><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mi mathvariant="italic">π</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mfrac></mml:mstyle><mml:mi>E</mml:mi><mml:msubsup><mml:mo>∫</mml:mo><mml:mn mathvariant="normal">0</mml:mn><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mrow><mml:mi mathvariant="normal">i</mml:mi><mml:mo>,</mml:mo><mml:mtext>thresh</mml:mtext></mml:mrow></mml:msub></mml:mrow></mml:msubsup><mml:msubsup><mml:mo>∫</mml:mo><mml:mn mathvariant="normal">0</mml:mn><mml:mi mathvariant="normal">∞</mml:mi></mml:msubsup><mml:mo>(</mml:mo><mml:msub><mml:mi>N</mml:mi><mml:mrow><mml:mi mathvariant="normal">M</mml:mi><mml:mn mathvariant="normal">1</mml:mn><mml:mi mathvariant="normal">T</mml:mi></mml:mrow></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>N</mml:mi><mml:mrow><mml:mi mathvariant="normal">M</mml:mi><mml:mn mathvariant="normal">1</mml:mn><mml:mi mathvariant="normal">L</mml:mi></mml:mrow></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd/><mml:mtd><mml:mrow><mml:mspace linebreak="nobreak" width="0.25em"/><mml:mo>×</mml:mo><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub><mml:msup><mml:mo>)</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mi mathvariant="normal">|</mml:mi><mml:mi>v</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>-</mml:mo><mml:mi>v</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mi mathvariant="normal">|</mml:mi></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd/><mml:mtd><mml:mrow><mml:mspace linebreak="nobreak" width="0.25em"/><mml:mo>×</mml:mo><mml:mi>f</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mi>f</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mi mathvariant="normal">d</mml:mi><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub><mml:mi mathvariant="normal">d</mml:mi><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mtr></mml:mtable></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E9"><mml:mtd><mml:mtext>9</mml:mtext></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mo>∂</mml:mo><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mo>∂</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:msub><mml:mi mathvariant="normal">|</mml:mi><mml:mrow><mml:mi mathvariant="normal">M</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msub><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mo>∂</mml:mo><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mo>∂</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:msub><mml:mi mathvariant="normal">|</mml:mi><mml:mrow><mml:mtext>M1</mml:mtext><mml:mo>,</mml:mo><mml:mi mathvariant="normal">f</mml:mi></mml:mrow></mml:msub><mml:mo>+</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mo>∂</mml:mo><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mo>∂</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:msub><mml:mi mathvariant="normal">|</mml:mi><mml:mrow><mml:mtext>M1</mml:mtext><mml:mo>,</mml:mo><mml:mi mathvariant="normal">c</mml:mi></mml:mrow></mml:msub><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula>

            where <inline-formula><mml:math id="M126" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M127" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> are the diameters of raindrops and ice particles, <inline-formula><mml:math id="M128" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mrow><mml:mi mathvariant="normal">i</mml:mi><mml:mo>,</mml:mo><mml:mtext>thresh</mml:mtext></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> denotes the diameter of an ice particle whose mass equals that of the colliding raindrop, <inline-formula><mml:math id="M129" display="inline"><mml:mrow><mml:mi>v</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M130" display="inline"><mml:mrow><mml:mi>v</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> are the fall speeds, and <inline-formula><mml:math id="M131" display="inline"><mml:mrow><mml:mi>f</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M132" display="inline"><mml:mrow><mml:mi>f</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> represent size distributions of freezing raindrops and ice particles, respectively. A corresponding equation for the secondary ice mass production rate has the same structure but integrates the fragment mass. These are calculated numerically in CASIM.</p>
      <p id="d2e2831">For Mode 2 (M2), a theoretical approach is taken to consider the collisions of supercooled raindrops with more massive ice. By assuming the fragmentation is controlled by the ratio of initial CKE and surface energy, the number of fragments generated due to M2 is given as follows:

              <disp-formula id="Ch1.E10" content-type="numbered"><label>10</label><mml:math id="M133" display="block"><mml:mrow><mml:msub><mml:mi>N</mml:mi><mml:mrow><mml:mi mathvariant="normal">M</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">3</mml:mn><mml:mi mathvariant="normal">Φ</mml:mi><mml:mo>(</mml:mo><mml:mi>T</mml:mi><mml:mo>)</mml:mo><mml:mo>×</mml:mo><mml:mfenced open="[" close="]"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:mi>f</mml:mi><mml:mo>(</mml:mo><mml:mi>T</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:mfenced><mml:mo>×</mml:mo><mml:mtext>max</mml:mtext><mml:mo>(</mml:mo><mml:mtext>DE</mml:mtext><mml:mo>-</mml:mo><mml:msub><mml:mtext>DE</mml:mtext><mml:mi mathvariant="normal">crit</mml:mi></mml:msub><mml:mo>,</mml:mo><mml:mn mathvariant="normal">0</mml:mn><mml:mo>)</mml:mo><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>

            where <inline-formula><mml:math id="M134" display="inline"><mml:mi mathvariant="normal">Φ</mml:mi></mml:math></inline-formula> is the empirical fraction of the drop fragments from the splash contain ice. Following James et al. (2021), a value <inline-formula><mml:math id="M135" display="inline"><mml:mi mathvariant="normal">Φ</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M136" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.3 is used in this study. The function <inline-formula><mml:math id="M137" display="inline"><mml:mrow><mml:mi>f</mml:mi><mml:mo>(</mml:mo><mml:mi>T</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> represents the mass fraction of drop frozen and is given as:

              <disp-formula id="Ch1.E11" content-type="numbered"><label>11</label><mml:math id="M138" display="block"><mml:mrow><mml:mi>f</mml:mi><mml:mo>(</mml:mo><mml:mi>T</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mo>-</mml:mo><mml:msub><mml:mi>c</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub><mml:mi>T</mml:mi></mml:mrow><mml:mrow><mml:msub><mml:mi>L</mml:mi><mml:mi mathvariant="normal">f</mml:mi></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>

            where <inline-formula><mml:math id="M139" display="inline"><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M140" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 4200 <inline-formula><mml:math id="M141" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">J</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">kg</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">K</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> is the specific heat capacity of liquid water, and <inline-formula><mml:math id="M142" display="inline"><mml:mrow><mml:msub><mml:mi>L</mml:mi><mml:mi mathvariant="normal">f</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:mn mathvariant="normal">3.3</mml:mn><mml:mo>×</mml:mo><mml:msup><mml:mn mathvariant="normal">10</mml:mn><mml:mn mathvariant="normal">5</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M143" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">J</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">kg</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> is the specific latent heat of freezing. DE is dimensionless energy and is calculated as:

                  <disp-formula specific-use="align" content-type="numbered"><mml:math id="M144" display="block"><mml:mtable displaystyle="true"><mml:mlabeledtr id="Ch1.E12"><mml:mtd><mml:mtext>12</mml:mtext></mml:mtd><mml:mtd><mml:mstyle displaystyle="true" class="stylechange"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:mtext>DE</mml:mtext><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi>K</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr><mml:mlabeledtr id="Ch1.E13"><mml:mtd><mml:mtext>13</mml:mtext></mml:mtd><mml:mtd><mml:mstyle displaystyle="true" class="stylechange"/></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:msub><mml:mi>S</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi mathvariant="italic">γ</mml:mi><mml:mi mathvariant="normal">liq</mml:mi></mml:msub><mml:mi mathvariant="italic">π</mml:mi><mml:msubsup><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msubsup><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mlabeledtr></mml:mtable></mml:math></disp-formula>

            where <inline-formula><mml:math id="M145" display="inline"><mml:mrow><mml:msub><mml:mi>K</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is the initial CKE defined in the preceding sections, <inline-formula><mml:math id="M146" display="inline"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the surface energy, with <inline-formula><mml:math id="M147" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">γ</mml:mi><mml:mi mathvariant="normal">liq</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M148" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.073  <inline-formula><mml:math id="M149" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">J</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> being the surface tension of liquid water, and <inline-formula><mml:math id="M150" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> the drop diameter. <inline-formula><mml:math id="M151" display="inline"><mml:mrow><mml:msub><mml:mtext>DE</mml:mtext><mml:mi mathvariant="normal">crit</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the critical value of DE for onset of splashing on impact and is set to be 0.2 (Phillips et al., 2018).</p>
      <p id="d2e3204">The corresponding secondary ice production rate due to M2 (<inline-formula><mml:math id="M152" display="inline"><mml:mrow><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mrow><mml:mo>∂</mml:mo><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mo>∂</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:msub><mml:mi mathvariant="normal">|</mml:mi><mml:mrow><mml:mi mathvariant="normal">M</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, units: <inline-formula><mml:math id="M153" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">number</mml:mi><mml:mspace width="0.25em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">s</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>) is calculated as:

              <disp-formula id="Ch1.E14" content-type="numbered"><label>14</label><mml:math id="M154" display="block"><mml:mrow><mml:mtable rowspacing="0.2ex" class="split" displaystyle="true" columnalign="right left"><mml:mtr><mml:mtd><mml:mrow><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mo>∂</mml:mo><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mo>∂</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:msub><mml:mi mathvariant="normal">|</mml:mi><mml:mrow><mml:mi mathvariant="normal">M</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mspace width="0.25em" linebreak="nobreak"/><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mi mathvariant="italic">π</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:mfrac></mml:mstyle><mml:mi>E</mml:mi><mml:msubsup><mml:mo>∫</mml:mo><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mrow><mml:mi mathvariant="normal">i</mml:mi><mml:mo>,</mml:mo><mml:mtext>thresh</mml:mtext></mml:mrow></mml:msub></mml:mrow><mml:mi mathvariant="normal">∞</mml:mi></mml:msubsup><mml:msubsup><mml:mo>∫</mml:mo><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mrow><mml:mi mathvariant="normal">R</mml:mi><mml:mo>,</mml:mo><mml:mtext>thresh</mml:mtext></mml:mrow></mml:msub></mml:mrow><mml:mi mathvariant="normal">∞</mml:mi></mml:msubsup><mml:msub><mml:mi>N</mml:mi><mml:mrow><mml:mi mathvariant="normal">M</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub><mml:mo>+</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub><mml:msup><mml:mo>)</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd/><mml:mtd><mml:mrow><mml:mspace linebreak="nobreak" width="0.25em"/><mml:mo>×</mml:mo><mml:mi mathvariant="normal">|</mml:mi><mml:mi>v</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>-</mml:mo><mml:mi>v</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mi mathvariant="normal">|</mml:mi><mml:mi>f</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mi>f</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub><mml:mo>)</mml:mo><mml:mo>,</mml:mo><mml:mi mathvariant="normal">d</mml:mi><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub><mml:mi mathvariant="normal">d</mml:mi><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mtr></mml:mtable></mml:mrow></mml:math></disp-formula>

            where <inline-formula><mml:math id="M155" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mrow><mml:mi mathvariant="normal">R</mml:mi><mml:mo>,</mml:mo><mml:mtext>thresh</mml:mtext></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M156" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.15 <inline-formula><mml:math id="M157" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi></mml:mrow></mml:math></inline-formula> is the minimum raindrop diameter for Mode 2 (Phillips et al., 2018). This integral is evaluated numerically using the CASIM (Field et al., 2023). It accounts for collisions between raindrops and ice particles, where the ice category includes cloud ice, snow, and graupel. All other variables have been defined above.</p>
</sec>
</sec>
<sec id="Ch1.S2.SS3">
  <label>2.3</label><title>Observation and case description</title>
      <p id="d2e3502">In this study, we focus on the Hector thunderstorms observed during the Aerosol and Chemical Transport in tropIcal conVEction (ACTIVE) campaign (Vaughan et al., 2008). Hector is an isolated maritime continental thunderstorm that occurs regularly over the Tiwi Islands, north of Darwin, Australia (Fig. <xref ref-type="fig" rid="F1"/>), during the pre-monsoon wet season. These tropical deep convective storms are primarily triggered by cold air pool interactions and the convergence of penetrating sea-breeze flows, making them some of the deepest convective systems observed globally (Connolly et al., 2013). The repeatable occurrence of Hector, featuring extensive mixed-phase cloud structure, supported by multi-platform observations from ACTIVE, provides a controlled setting to evaluate SIP processes. For this study, we selected the severe Hector thunderstorm that developed on 30 November 2005, coinciding with the early phase of the ACTIVE campaign. The 00:00 UTC Darwin sounding (Fig. <xref ref-type="fig" rid="F2"/>) indicates a low lifted condensation level (LCL) near 900 <inline-formula><mml:math id="M158" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula> and high convective available potential energy (CAPE) of <inline-formula><mml:math id="M159" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2590 <inline-formula><mml:math id="M160" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">J</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">kg</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, with cloud tops extending above 200 <inline-formula><mml:math id="M161" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">hPa</mml:mi></mml:mrow></mml:math></inline-formula>.</p>

      <fig id="F1"><label>Figure 1</label><caption><p id="d2e3552">Overview of the model orography (terrain height, unit: m) and the domains used to generate radar and satellite datasets. The simulated area is a square domain centered at (12.4° S, 130.8° E) with a side length of 1350 <inline-formula><mml:math id="M162" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>. In this panel, we only show the analysis domain for the radar data and simulated results (white box). The radar range is represented by the circle centered at (12.25° S, 131.05° E).</p></caption>
          <graphic xlink:href="https://acp.copernicus.org/articles/25/18549/2025/acp-25-18549-2025-f01.png"/>

        </fig>

      <fig id="F2"><label>Figure 2</label><caption><p id="d2e3571">Sounding profiles from Darwin Airport station (12.42° S, 130.89° E) at 00:00 UTC on 1 December 2005. The red and green solid lines represent temperature and dew point, and the blue line represents the parcel lapse rate.</p></caption>
          <graphic xlink:href="https://acp.copernicus.org/articles/25/18549/2025/acp-25-18549-2025-f02.png"/>

        </fig>

      <p id="d2e3581">The radar reflectivity data were obtained from a C-band polarimetric (CPOL) radar, which was located at Gunn Point (12.25° S, 131.05° E) and updated every 10 <inline-formula><mml:math id="M163" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">min</mml:mi></mml:mrow></mml:math></inline-formula>. Figure <xref ref-type="fig" rid="F1"/> illustrates its position relative to the Tiwi Islands, with the circle indicating its coverage range. The vertical and horizontal resolutions are 0.5 and 2.5 <inline-formula><mml:math id="M164" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, respectively. To compare with the model, we utilized the “Statistical Coverage Product”, which represents the time-height distribution of the fraction of a defined domain exceeding a threshold of 10 <inline-formula><mml:math id="M165" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">dBZ</mml:mi></mml:mrow></mml:math></inline-formula> (May et al., 2008). This threshold was selected to capture the overall precipitation distribution, and the analysis domain is shown in Fig. <xref ref-type="fig" rid="F1"/>. The rainfall data at 10 <inline-formula><mml:math id="M166" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">min</mml:mi></mml:mrow></mml:math></inline-formula> intervals was also derived from CPOL radar with a horizontal resolution of 1 <inline-formula><mml:math id="M167" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>. CPOL-based quantitative precipitation estimates are considered reliable for tropical rainfall, with residual uncertainties arising from reflectivity/differential-reflectivity calibration and C-band attenuation (Louf et al., 2019; Jackson et al., 2021). The equivalent Outgoing Longwave Radiation (OLR) was calculated from the Multifunctional Transport Satellites (MTSAT) channel 1 brightness temperature, at 1.25 <inline-formula><mml:math id="M168" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> horizontal and 30 <inline-formula><mml:math id="M169" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">min</mml:mi></mml:mrow></mml:math></inline-formula> temporal resolution.</p>
</sec>
<sec id="Ch1.S2.SS4">
  <label>2.4</label><title>Model configuration and sensitivity experiments</title>
      <p id="d2e3653">The regional simulations presented have a horizontal grid spacing of 1.5 <inline-formula><mml:math id="M170" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> (900 <inline-formula><mml:math id="M171" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 900 grid points), centered over the Darwin region (12.4° S, 130.8° E). There are 90 levels in the vertical stretched to 40 <inline-formula><mml:math id="M172" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> (52 levels below 10 <inline-formula><mml:math id="M173" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, 33 levels below 4 <inline-formula><mml:math id="M174" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, and 16 levels below 1 <inline-formula><mml:math id="M175" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>). The simulations began at 00:00 UTC on 30 November 2005 and were integrated for 36 <inline-formula><mml:math id="M176" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:math></inline-formula>. The initial and lateral boundary conditions are from European Centre for Medium-range Weather Forecasts (ECMWF) reanalysis data at 6 <inline-formula><mml:math id="M177" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:math></inline-formula> intervals. The spin-up period is approximately 3 <inline-formula><mml:math id="M178" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:math></inline-formula> and the time step is 75 <inline-formula><mml:math id="M179" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">s</mml:mi></mml:mrow></mml:math></inline-formula>. We utilize Shuttle Radar Topography Mission (SRTM) dataset as ancillary input to improve terrain representation. For analysis, we select an approximately 1° <inline-formula><mml:math id="M180" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 1° latitude-longitude domain over the Tiwi Islands (white box in Fig. <xref ref-type="fig" rid="F1"/>) to avoid analyzing data influenced by boundary effects.</p>
      <p id="d2e3746">A detailed description of the model sensitivity experiments and the included SIP mechanisms is provided in Table <xref ref-type="table" rid="T1"/>. The all-SIP experiment incorporates all SIP mechanisms, while additional experiments isolate specific combinations or exclude SIP entirely to evaluate their individual and collective effects. For example, the RS, RS <inline-formula><mml:math id="M181" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M1, RS <inline-formula><mml:math id="M182" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M2, and RS <inline-formula><mml:math id="M183" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> BR experiments activate subsets of SIP processes, whereas the no-SIP configuration disables all SIP processes. These simulations aim to quantify how different SIP pathways influence cloud microphysics, convective dynamics, and precipitation. For each simulation, a time-lagged ensemble of four members with different initial conditions was performed. The simulations were initialized at 00:00, 06:00, 12:00, and 18:00 UTC on 30 November 2005 (hereafter referred to as T00, T06, T12, and T18), to ensure the resulting differences can be attributed to the SIP processes rather than model perturbations (Mittermaier, 2007; Miltenberger and Field, 2021). The ensemble mean and standard deviation were then calculated for each case. Observational data from field campaigns are used to evaluate and validate the model outputs.</p>

      <fig id="F3" specific-use="star"><label>Figure 3</label><caption><p id="d2e3774">MTSAT visible channel images at <bold>(a)</bold> 05:30 UTC, <bold>(d)</bold> 06:30 UTC and <bold>(g)</bold> 08:30 UTC, and simulated outgoing longwave radiation (OLR, unit: <inline-formula><mml:math id="M184" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>) of the <bold>(b, e, h)</bold>  all-SIP and <bold>(c, f, i)</bold> no-SIP experiments at 04:30 UTC, 05:30 UTC, and 07:30 UTC on 1 December 2005. The simulated convection was earlier than the observation by about 1 <inline-formula><mml:math id="M185" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:math></inline-formula>. All panels share an identical color scale. The rectangle in panel <bold>(e)</bold> denotes the region where the results are analyzed.</p></caption>
          <graphic xlink:href="https://acp.copernicus.org/articles/25/18549/2025/acp-25-18549-2025-f03.png"/>

        </fig>

</sec>
</sec>
<sec id="Ch1.S3">
  <label>3</label><title>Results</title>
<sec id="Ch1.S3.SS1">
  <label>3.1</label><title>Model evaluation: storm evolution and radiation</title>
      <p id="d2e3843">To evaluate the model performance in simulating the Hector thunderstorm, Fig. <xref ref-type="fig" rid="F3"/> compares visible satellite imagery from MTSAT and simulated outgoing longwave radiation (OLR) at different times during the storm's evolution. In the initial stage, shallow convective clouds are triggered along the sea-breeze fronts over the Tiwi Islands, consistent with the Hector initiation described by Connolly et al. (2013). As convection intensifies, multiple convective cells develop and begin to merge, resulting in the rapid growth of the storm and the formation of a deep convective core (Fig. <xref ref-type="fig" rid="F3"/>a, d, and g). The model reproduces the organization of convective cells and captures the timing and location of the primary updrafts, as indicated by the observed cloud fields.</p>
      <p id="d2e3850">During the mature stage, the storm exhibits a well-developed anvil outflow, with the all-SIP simulation capturing the spatial coverage of deep convection more realistically (Fig. <xref ref-type="fig" rid="F3"/>d and e). This is reflected in the broader area of cold cloud tops and extensive low-OLR regions. In contrast, even when the no-SIP experiment produces its most organized cloud system, it remains smaller and less persistent compared to the all-SIP case, with reduced anvil coverage and duration (Fig. <xref ref-type="fig" rid="F3"/>f). As the storm decays, both simulations show gradual reduced cloud coverage. However, the all-SIP simulation maintains a more extensive anvil cloud during the late stage, in better agreement with observations. Overall, these results demonstrate that including SIP processes improves the model ability to capture the initiation, intensification, and full life cycle of the Hector storm, especially the spatial and temporal evolution of its convective and anvil cloud components.</p>

      <fig id="F4"><label>Figure 4</label><caption><p id="d2e3859">Comparisons between the observation and simulations for radar reflectivity. Panels <bold>(a)</bold>, <bold>(c)</bold>, and <bold>(d)</bold> show the time-height plots of CFADs (fraction of radar reflectivity <inline-formula><mml:math id="M186" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 5 <inline-formula><mml:math id="M187" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">dBZ</mml:mi></mml:mrow></mml:math></inline-formula>): derived from observation, all-SIP, and no-SIP simulations. Panel <bold>(b)</bold> shows the vertical profiles of averaged radar reflectivity during 05:00–07:00 UTC (04:00–06:00 UTC for simulations), 1 December 2005. Shaded areas in panel <bold>(b)</bold> show the standard error of each parameter. The 0, <inline-formula><mml:math id="M188" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>20, <inline-formula><mml:math id="M189" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>40, and <inline-formula><mml:math id="M190" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>60 <inline-formula><mml:math id="M191" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> isotherms are shown by the dashed lines in panels <bold>(c)</bold> and <bold>(d)</bold>.</p></caption>
          <graphic xlink:href="https://acp.copernicus.org/articles/25/18549/2025/acp-25-18549-2025-f04.png"/>

        </fig>

      <p id="d2e3938">We further compared the Contoured Frequency by Altitude Diagram (CFAD) of radar reflectivity derived from CPOL radar observations and simulations, as shown in Fig. <xref ref-type="fig" rid="F4"/>. CFAD represents a time–height plot of the fraction of a defined domain that has a radar reflectivity exceeding a certain threshold (5 <inline-formula><mml:math id="M192" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">dBZ</mml:mi></mml:mrow></mml:math></inline-formula> in this paper; Connolly et al., 2013). The domain used to calculate the statistical coverage is shown in Fig. <xref ref-type="fig" rid="F1"/>. The observed CFAD (Fig. <xref ref-type="fig" rid="F4"/>a) is characterized by a distinct convective core below <inline-formula><mml:math id="M193" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 8 <inline-formula><mml:math id="M194" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> and a broad distribution in upper levels, which is associated with the extensive anvil outflow typical of Hector storms. This anvil region indicates a large amount of ice particles spreading horizontally between 10 and 16 <inline-formula><mml:math id="M195" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>.</p>
      <p id="d2e3979">The all-SIP simulation (Fig. <xref ref-type="fig" rid="F4"/>c) captures both the vertical extent and horizontal spread of the anvil, showing a broader and more persistent layer of weak reflectivity aloft, consistent with observations. This indicates that the inclusion of multiple SIP processes enhances the generation and lofting of small ice crystals, which are lifted to the higher levels and contribute to the development of an extensive anvil. In contrast, the no-SIP simulation (Fig. <xref ref-type="fig" rid="F4"/>d) exhibits a much weaker anvil layer, with lower frequencies of reflectivity above 10 <inline-formula><mml:math id="M196" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, suggesting a limited ice production and upward ice transport. In this case, SIP yields a higher cloud top and closer agreement with observations, consistent with previous simulations (e.g., Qu et al., 2022). Cloud top responses can vary across configurations. For example, an idealized single cloud study reported lower tops when SIP produced small ice that depleted cloud droplets and limited upper-level ice formation (Grzegorczyk et al., 2025b).</p>
      <p id="d2e3994">The comparison of vertical profiles of average radar reflectivity is shown in Fig. <xref ref-type="fig" rid="F4"/>b. It demonstrates that the inclusion of SIP leads to a reduction in mean reflectivity values in middle levels, which can be explained by the presence of more numerous small ice-phase particles aloft. Ice particles formed by primary freezing are expected to grow at comparable rates when ice–ice collisional breakup is inefficient, and the additional SIP-generated ice particles shift the overall size distribution toward smaller diameters, leading to weaker reflectivity. In our simulations, the all-SIP experiment exhibits averaged values that are <inline-formula><mml:math id="M197" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2 <inline-formula><mml:math id="M198" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">dBZ</mml:mi></mml:mrow></mml:math></inline-formula> lower than those in the no-SIP one between 5 and 12 <inline-formula><mml:math id="M199" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>. The lower reflectivity in the all-SIP case, together with the extensive anvil region above 10 <inline-formula><mml:math id="M200" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, highlights the role of SIP in controlling the microphysical properties and spatial extent of the anvil cloud, which is consistent with findings in previous studies (Connolly et al., 2013; Qu et al., 2022). Below 3 <inline-formula><mml:math id="M201" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, the model underestimates the frequency of reflectivity values exceeding 5 <inline-formula><mml:math id="M202" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">dBZ</mml:mi></mml:mrow></mml:math></inline-formula> (Fig. <xref ref-type="fig" rid="F4"/>c and d). This likely reflects uncertainties in the representation of warm-rain processes, including cloud-to-rain autoconversion, accretion of cloud water by rain, rain evaporation, and the assumed particle size distributions. Differences between the model reflectivity diagnostic and the observational product near the melting layer could also contribute to the underestimation. The bias is similar in the SIP and no-SIP experiments and therefore does not affect the SIP-related conclusions. Nonetheless, the simulated precipitation totals later in the storm evolution are broadly consistent with observations.</p>

      <fig id="F5" specific-use="star"><label>Figure 5</label><caption><p id="d2e4051">Time evolutions of averaged <bold>(a–e)</bold> outgoing longwave radiation (OLR, unit: <inline-formula><mml:math id="M203" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>) and <bold>(f–j)</bold> outgoing shortwave radiation (OSR, unit: <inline-formula><mml:math id="M204" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>) for noSIP (dash-dotted) and each SIP configuration (colored), on 1 December 2005. The solid lines denote the ensemble means, and the shaded envelopes show the standard error of each parameter. All values are calculated over the 4-member ensemble.</p></caption>
          <graphic xlink:href="https://acp.copernicus.org/articles/25/18549/2025/acp-25-18549-2025-f05.png"/>

        </fig>

<table-wrap id="T2"><label>Table 2</label><caption><p id="d2e4103">Comparison of radiation under different SIP configurations.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="5">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:thead>
       <oasis:row>
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">Mean OLR</oasis:entry>
         <oasis:entry colname="col3">Min OLR</oasis:entry>
         <oasis:entry colname="col4">Mean OSR</oasis:entry>
         <oasis:entry colname="col5">Max OSR</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">(<inline-formula><mml:math id="M205" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col3">(<inline-formula><mml:math id="M206" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col4">(<inline-formula><mml:math id="M207" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col5">(<inline-formula><mml:math id="M208" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>)</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">all-SIP</oasis:entry>
         <oasis:entry colname="col2">236.20</oasis:entry>
         <oasis:entry colname="col3">198.39</oasis:entry>
         <oasis:entry colname="col4">250.95</oasis:entry>
         <oasis:entry colname="col5">353.58</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">RS</oasis:entry>
         <oasis:entry colname="col2">239.99</oasis:entry>
         <oasis:entry colname="col3">205.27</oasis:entry>
         <oasis:entry colname="col4">245.39</oasis:entry>
         <oasis:entry colname="col5">346.60</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">RS <inline-formula><mml:math id="M209" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M1</oasis:entry>
         <oasis:entry colname="col2">237.36</oasis:entry>
         <oasis:entry colname="col3">199.96</oasis:entry>
         <oasis:entry colname="col4">248.45</oasis:entry>
         <oasis:entry colname="col5">348.52</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">RS <inline-formula><mml:math id="M210" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M2</oasis:entry>
         <oasis:entry colname="col2">240.66</oasis:entry>
         <oasis:entry colname="col3">205.85</oasis:entry>
         <oasis:entry colname="col4">243.18</oasis:entry>
         <oasis:entry colname="col5">341.29</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">RS <inline-formula><mml:math id="M211" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> BR</oasis:entry>
         <oasis:entry colname="col2">239.94</oasis:entry>
         <oasis:entry colname="col3">205.41</oasis:entry>
         <oasis:entry colname="col4">244.45</oasis:entry>
         <oasis:entry colname="col5">340.60</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">no-SIP</oasis:entry>
         <oasis:entry colname="col2">239.36</oasis:entry>
         <oasis:entry colname="col3">202.92</oasis:entry>
         <oasis:entry colname="col4">246.47</oasis:entry>
         <oasis:entry colname="col5">339.54</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table><table-wrap-foot><p id="d2e4106"> Note: All values are calculated over the analysis region shown in Fig. <xref ref-type="fig" rid="F1"/>, during 02:30–08:30 UTC on 1 December 2005.</p></table-wrap-foot></table-wrap>

      <p id="d2e4367">The impact of SIP on the top-of-atmosphere radiative fluxes is shown in Fig. <xref ref-type="fig" rid="F5"/>, which includes the time series of domain-averaged OLR and OSR for various simulations. The inclusion of SIP processes leads to a marked reduction in OLR during the mature stage of convection (Fig. <xref ref-type="fig" rid="F5"/>a), corresponding to the development of extensive and optically thick anvil clouds. The enhanced ice particle number concentration generated by SIP produces more persistent and horizontally widespread anvil clouds, which efficiently reduces outgoing longwave radiation and results in colder OLR signals. For the analysis region shown in Fig. <xref ref-type="fig" rid="F1"/> during 02:30–08:30 UTC on 1 December 2005, the mean OLR in the all-SIP simulation is reduced to 236.2 <inline-formula><mml:math id="M212" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, compared to 239.4 <inline-formula><mml:math id="M213" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in the no-SIP case, indicating a decrease of 1.3 %. Similarly, the minimum OLR is 198.4 <inline-formula><mml:math id="M214" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in the all-SIP simulation and 202.9 <inline-formula><mml:math id="M215" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in the no-SIP case, as illustrated in Table <xref ref-type="table" rid="T2"/>.</p>
      <p id="d2e4447">Meanwhile, SIP also has a significant influence on OSR (Fig. <xref ref-type="fig" rid="F5"/>f). As highlighted in Finney et al. (2025), the cloud albedo and thus OSR, are highly sensitive to microphysical properties such as ice particle number and size. The increase in small ice particle number concentration within the anvil leads to greater cloud optical thickness and higher shortwave reflectivity. Accordingly, the all-SIP simulation yields a mean OSR of 250.9 <inline-formula><mml:math id="M216" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, higher than the no-SIP value of 246.5 <inline-formula><mml:math id="M217" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, representing an increase of 1.8 %. The peak OSR also rises, from 339.5 <inline-formula><mml:math id="M218" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in the no-SIP case to 353.6 <inline-formula><mml:math id="M219" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in the all-SIP simulation. It should be noted that these changes in radiation could arise from a combination of factors, such as variations in cloud area or cloud top temperature. Nonetheless, the overall changes in OLR and OSR remain consistent across SIP simulations, suggesting a substantial influence of SIP on the radiative characteristics of tropical convective systems.</p>

      <fig id="F6" specific-use="star"><label>Figure 6</label><caption><p id="d2e4522">Panels <bold>(a)</bold>–<bold>(c)</bold> show the spatial distribution of accumulated precipitation (unit: <inline-formula><mml:math id="M220" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi></mml:mrow></mml:math></inline-formula>) in the <bold>(a)</bold> observation, <bold>(b)</bold> all-SIP, and <bold>(c)</bold> no-SIP simulations during 03:30–09:30 UTC (02:30–08:30 UTC for simulations). Black contours in panels <bold>(b)</bold> and <bold>(c)</bold> show areas with accumulated rainfall <inline-formula><mml:math id="M221" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 40 <inline-formula><mml:math id="M222" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi></mml:mrow></mml:math></inline-formula>. Panel <bold>(d)</bold> shows the difference (all-SIP minus no-SIP) in accumulated precipitation between the simulations.</p></caption>
          <graphic xlink:href="https://acp.copernicus.org/articles/25/18549/2025/acp-25-18549-2025-f06.png"/>

        </fig>

</sec>
<sec id="Ch1.S3.SS2">
  <label>3.2</label><title>Impacts of SIP on precipitation</title>
      <p id="d2e4587">Figure <xref ref-type="fig" rid="F6"/> presents the spatial distribution of accumulated precipitation during the simulation period, alongside radar-based observations. The observed precipitation field is characterized by an intense convective core over the Tiwi Islands, with accumulated rainfall exceeding 60 <inline-formula><mml:math id="M223" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi></mml:mrow></mml:math></inline-formula>, surrounded by weaker stratiform precipitation extending northeastward. Both simulations reproduce the main features of this structure to varying degrees. The no-SIP simulation produces a broader and more diffuse precipitation field, with rainfall spread over a wider area (Fig. <xref ref-type="fig" rid="F6"/>c). For spatial diagnostics, we define a heavy-rainfall region as the area with accumulated rainfall <inline-formula><mml:math id="M224" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 40 <inline-formula><mml:math id="M225" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi></mml:mrow></mml:math></inline-formula> (black contours in Fig. <xref ref-type="fig" rid="F6"/>b and c; Grzegorczyk et al., 2025b). This heavy-rainfall region is more spread out in the no-SIP than in the all-SIP case. In contrast, the all-SIP simulation shows a more localized and compact precipitation field that better matches the observed spatial pattern (Fig. <xref ref-type="fig" rid="F6"/>b), although both simulations underestimate the observed surface precipitation amount and areal coverage. Several aspects of the configuration may contribute, including km-scale grid spacing (1.5 <inline-formula><mml:math id="M226" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>), parameter choices in the bulk microphysics scheme, and uncertainties in the environmental forcing. On the observational side, CPOL-based precipitation data also carry documented uncertainties (see Sect. <xref ref-type="sec" rid="Ch1.S2.SS3"/>). Nevertheless, our analysis focuses on the contrasts between SIP and no-SIP runs, which remain robust across the sensitivity tests. Comparing the two simulations, the no-SIP case yields a slightly higher domain-averaged accumulated precipitation than the all-SIP one (Fig. <xref ref-type="fig" rid="F6"/>d). Relative to no-SIP, all-SIP run encloses a smaller area within the 40 <inline-formula><mml:math id="M227" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi></mml:mrow></mml:math></inline-formula> contour and features fewer, more compact heavy-rainfall regions (Fig. <xref ref-type="fig" rid="F6"/>b and c), indicating a more localized precipitation pattern.</p>

      <fig id="F7" specific-use="star"><label>Figure 7</label><caption><p id="d2e4647">The left column shows the spatial distribution of accumulated precipitation (unit: <inline-formula><mml:math id="M228" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi></mml:mrow></mml:math></inline-formula>) during 02:30–08:30 UTC in the simulations: <bold>(a)</bold> RS, <bold>(c)</bold> RS <inline-formula><mml:math id="M229" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M1, <bold>(e)</bold> RS <inline-formula><mml:math id="M230" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M2, and <bold>(g)</bold> RS <inline-formula><mml:math id="M231" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> BR. Black contours show areas with accumulated rainfall <inline-formula><mml:math id="M232" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 40 <inline-formula><mml:math id="M233" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi></mml:mrow></mml:math></inline-formula>. The right column shows the deviations of accumulated precipitation (unit: <inline-formula><mml:math id="M234" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi></mml:mrow></mml:math></inline-formula>) between four of the simulations with the SIP parameterizations in place, and the no-SIP simulation.</p></caption>
          <graphic xlink:href="https://acp.copernicus.org/articles/25/18549/2025/acp-25-18549-2025-f07.png"/>

        </fig>

      <p id="d2e4721">Figure <xref ref-type="fig" rid="F7"/> presents the spatial distribution of accumulated precipitation for the different SIP combinations and the corresponding deviations from the no-SIP simulation. The RS simulation produces a precipitation pattern broadly similar to the no-SIP case, with relatively small deviations (Fig. <xref ref-type="fig" rid="F7"/>a and b). Adding the Mode 1 process (RS <inline-formula><mml:math id="M235" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M1) yields increases within and adjacent to the convective core, including the northeastern band (Fig. <xref ref-type="fig" rid="F7"/>c and d). The <inline-formula><mml:math id="M236" display="inline"><mml:mo>≥</mml:mo></mml:math></inline-formula> 40 <inline-formula><mml:math id="M237" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi></mml:mrow></mml:math></inline-formula> contour indicates a more compact heavy-rainfall region than in the RS case. The RS <inline-formula><mml:math id="M238" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M2 experiment produces localized enhancement that are more fragmented and slightly displaced downwind compared with RS <inline-formula><mml:math id="M239" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M1 (Fig. <xref ref-type="fig" rid="F7"/>e and f). The heavy-rainfall region (<inline-formula><mml:math id="M240" display="inline"><mml:mo lspace="0mm">≥</mml:mo></mml:math></inline-formula> 40 <inline-formula><mml:math id="M241" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi></mml:mrow></mml:math></inline-formula>) appears as separate areas along the band. Including ice–ice collisional breakup (RS <inline-formula><mml:math id="M242" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> BR) forms a narrow zone of increased heavy precipitation without obvious suppression in the surroundings (Fig. <xref ref-type="fig" rid="F7"/>g and h). Overall, the deviation maps show that individual SIP pathways modify rainfall differently: rime splintering alone has a limited impact, whereas adding Mode 1, Mode 2, or collisional breakup introduces stronger localized increases and primarily reorganizes the spatial distribution.</p>
      <p id="d2e4795">The domain-averaged precipitation time series in Fig. <xref ref-type="fig" rid="F8"/>a complements the spatial distributions shown in Fig. <xref ref-type="fig" rid="F7"/>, providing additional context for the impact of different SIP mechanisms on total rainfall. During 03:00–07:00 UTC, RS <inline-formula><mml:math id="M243" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M2 and RS <inline-formula><mml:math id="M244" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> BR maintain higher domain-averaged rainfall, yielding larger increases in total precipitation (Fig. <xref ref-type="fig" rid="F8"/>a). The RS <inline-formula><mml:math id="M245" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> BR simulation shows the highest total amount, suggesting that ice–ice collisional breakup has a comparatively strong effect on overall rain production among the SIP mechanisms tested. The all-SIP simulation produces the lowest domain-averaged precipitation among all experiments, as shown in Fig. <xref ref-type="fig" rid="F8"/>a. Its time-averaged precipitation rate is 0.63 <inline-formula><mml:math id="M246" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">h</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, approximately 8 % lower than the 0.69 <inline-formula><mml:math id="M247" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">h</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in the no-SIP case over the same period (03:00–07:00 UTC). This result underscores the non-linear interactions among SIP pathways in deep convection. When multiple SIP processes act simultaneously, the resulting increase in upper-level ice particle concentration may suppress warm-rain production by diverting condensate into small ice particles that are less likely to precipitate efficiently. Additionally, enhanced ice aloft can inhibit the growth of larger rimed hydrometeors and reduce the mass flux toward the surface (Dedekind et al., 2021; Grzegorczyk et al., 2025c). Together, these factors help explain why the all-SIP simulation yields less total rainfall than cases with only one or two active SIP mechanisms. This is consistent with previous studies that emphasized the complex and sometimes competing roles of SIP in cloud microphysics and precipitation efficiency (e.g., Han et al., 2024; Grzegorczyk et al., 2025b, c).</p>

      <fig id="F8"><label>Figure 8</label><caption><p id="d2e4864">Time evolution of <bold>(a)</bold> domain-averaged precipitation rate, and <bold>(b)</bold> domain-maximum precipitation rate (unit: <inline-formula><mml:math id="M248" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">h</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>) from CPOL observations and model simulations. For simulations, the solid line represents the ensemble mean, and the shaded area indicates the standard error of each parameter across the 4-member ensemble. The gray dashed line in panel <bold>(a)</bold> shows a fitted curve to the observations. To facilitate comparison, the time axis for the observations has been shifted by 1 <inline-formula><mml:math id="M249" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:math></inline-formula> to align with the simulation results.</p></caption>
          <graphic xlink:href="https://acp.copernicus.org/articles/25/18549/2025/acp-25-18549-2025-f08.png"/>

        </fig>

      <p id="d2e4907">Figure <xref ref-type="fig" rid="F8"/>b shows the time series of the domain-maximum precipitation rate, representing the evolution of localized extreme rainfall events. All simulations, including no-SIP and those with various SIP mechanisms, produce similar peak magnitudes and timing. The peak rate reaches 199.6 <inline-formula><mml:math id="M250" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">h</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in the no-SIP and 186.6 <inline-formula><mml:math id="M251" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">h</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in the all-SIP case. The RS <inline-formula><mml:math id="M252" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M2 and RS <inline-formula><mml:math id="M253" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> BR experiments produce slightly higher maxima near 04:00 UTC, but the differences among all cases are relatively small and within modelling variability. In this case, SIP has limited impact on the domain-maximum precipitation rates. While certain SIP processes slightly enhance localized intensities, their effect on the most extreme point-scale rainfall events remains modest. This contrasts with the more substantial differences seen in accumulated precipitation fields and deviation maps (Fig. <xref ref-type="fig" rid="F7"/>, right column), suggesting that SIP more strongly modifies spatial distribution and total precipitation amount rather than intensifying single-point extremes. It is worth noting that previous studies have reported varying impacts of SIP on precipitation intensity. For example, Grzegorczyk et al. (2025b, c) found that SIP can reduce heavy rainfall (<inline-formula><mml:math id="M254" display="inline"><mml:mo lspace="0mm">&gt;</mml:mo></mml:math></inline-formula> 40 <inline-formula><mml:math id="M255" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi></mml:mrow></mml:math></inline-formula>), whereas Sullivan et al. (2018) reported localized enhancement of convective regions.</p>

      <fig id="F9" specific-use="star"><label>Figure 9</label><caption><p id="d2e4980">Vertical profiles of horizontally averaged number concentration of <bold>(a)</bold> ice crystals (<inline-formula><mml:math id="M256" display="inline"><mml:mrow><mml:msub><mml:mi>N</mml:mi><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>), <bold>(b)</bold> graupel (<inline-formula><mml:math id="M257" display="inline"><mml:mrow><mml:msub><mml:mi>N</mml:mi><mml:mi mathvariant="normal">graupel</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>), <bold>(c)</bold> ice-phase particles (<inline-formula><mml:math id="M258" display="inline"><mml:mrow><mml:msub><mml:mi>N</mml:mi><mml:mrow><mml:mi mathvariant="normal">ice</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="normal">particles</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>; sum of ice crystals and graupel), <bold>(d)</bold> snow (<inline-formula><mml:math id="M259" display="inline"><mml:mrow><mml:msub><mml:mi>N</mml:mi><mml:mi mathvariant="normal">snow</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>), and <bold>(e)</bold> total ice-phase particles (<inline-formula><mml:math id="M260" display="inline"><mml:mrow><mml:msub><mml:mi>N</mml:mi><mml:mrow><mml:mi mathvariant="normal">ice</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="normal">particles</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>; sum of ice crystals, graupel, and snow) from the all-SIP, no-SIP, RS, RS <inline-formula><mml:math id="M261" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M1, RS <inline-formula><mml:math id="M262" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M2, and RS <inline-formula><mml:math id="M263" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> BR experiments. All values are averaged over regions with IWC <inline-formula><mml:math id="M264" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 0.01 <inline-formula><mml:math id="M265" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">g</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> during 02:30–08:30 UTC on 1 December 2005. The solid line represents the ensemble mean, and the shaded area indicates the standard error of each parameter across the 4-member ensemble. Dashed lines indicate the 0, <inline-formula><mml:math id="M266" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>20, <inline-formula><mml:math id="M267" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>40, and <inline-formula><mml:math id="M268" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>60 <inline-formula><mml:math id="M269" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> isotherms.</p></caption>
          <graphic xlink:href="https://acp.copernicus.org/articles/25/18549/2025/acp-25-18549-2025-f09.png"/>

        </fig>

</sec>
<sec id="Ch1.S3.SS3">
  <label>3.3</label><title>Impacts of SIP on microphysical properties</title>
<sec id="Ch1.S3.SS3.SSS1">
  <label>3.3.1</label><title>Ice number concentration</title>
      <p id="d2e5163">Figure <xref ref-type="fig" rid="F9"/>a shows the vertical profiles of horizontally averaged ice crystal number concentration (<inline-formula><mml:math id="M270" display="inline"><mml:mrow><mml:msub><mml:mi>N</mml:mi><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) from various sensitivity experiments. The averages are calculated over grid boxes within the analysis region (Fig. <xref ref-type="fig" rid="F1"/>) where IWC <inline-formula><mml:math id="M271" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 0.01 <inline-formula><mml:math id="M272" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">g</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>. The all-SIP simulation exhibits peak values of <inline-formula><mml:math id="M273" display="inline"><mml:mrow><mml:msub><mml:mi>N</mml:mi><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> at approximately 8 <inline-formula><mml:math id="M274" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, where the temperature <inline-formula><mml:math id="M275" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M276" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M277" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>20 <inline-formula><mml:math id="M278" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>. At <inline-formula><mml:math id="M279" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M280" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M281" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>5 <inline-formula><mml:math id="M282" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> (around 6 <inline-formula><mml:math id="M283" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>), <inline-formula><mml:math id="M284" display="inline"><mml:mrow><mml:msub><mml:mi>N</mml:mi><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> reaches <inline-formula><mml:math id="M285" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1.5 <inline-formula><mml:math id="M286" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">L</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, compared to 0.5 <inline-formula><mml:math id="M287" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<sup>−3</sup> <inline-formula><mml:math id="M289" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">L</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in the no-SIP case over regions with IWC <inline-formula><mml:math id="M290" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 0.01 <inline-formula><mml:math id="M291" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">g</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, representing an increase of more than 3 orders of magnitude. This enhancement reflects the cumulative contribution of multiple SIP mechanisms in generating secondary ice particles aloft.</p>
      <p id="d2e5387">Among the individual SIP experiments, RS <inline-formula><mml:math id="M292" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M1 simulation (which includes rime splintering and Mode 1 droplet fragmentation) shows an increase in <inline-formula><mml:math id="M293" display="inline"><mml:mrow><mml:msub><mml:mi>N</mml:mi><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> between 8 and 10 <inline-formula><mml:math id="M294" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, reaching <inline-formula><mml:math id="M295" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 49 % of the all-SIP values. At <inline-formula><mml:math id="M296" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M297" display="inline"><mml:mo>≈</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M298" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>20 <inline-formula><mml:math id="M299" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>, the RS <inline-formula><mml:math id="M300" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M1 simulation exceeds the no-SIP case by <inline-formula><mml:math id="M301" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2 orders of magnitude, with peak enhancements of <inline-formula><mml:math id="M302" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 150 times. The RS <inline-formula><mml:math id="M303" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M2 simulation (rime splintering and Mode 2 droplet-ice collisions) also increases <inline-formula><mml:math id="M304" display="inline"><mml:mrow><mml:msub><mml:mi>N</mml:mi><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> relative to no-SIP, with the enhancement mainly between 6 and 8 <inline-formula><mml:math id="M305" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> (around <inline-formula><mml:math id="M306" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M307" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M308" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>5 <inline-formula><mml:math id="M309" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>), consistent with the expected activation of Mode 2 in lower layers where supercooled raindrops are more abundant. Its peak at 6 <inline-formula><mml:math id="M310" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> exceeds 2 <inline-formula><mml:math id="M311" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">L</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, more than 3 orders of magnitude above the no-SIP case at the same level. By contrast, the RS <inline-formula><mml:math id="M312" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> BR experiment (including ice–ice collisional breakup) differs little from the RS-only case across the column: the profiles are nearly identical and fall within the ensemble spread (Fig. <xref ref-type="fig" rid="F9"/>a and e). This indicates a limited contribution from breakup under the present conditions. A further contribution may arise once concentrations are elevated by other SIP processes. As shown in Fig. <xref ref-type="fig" rid="F9"/>b, graupel number concentrations below 8 <inline-formula><mml:math id="M313" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math id="M314" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> 1–10 <inline-formula><mml:math id="M315" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">L</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>) fall within the spread reported by convection-permitting studies (e.g., Phillips et al., 2017b), but are on the high side of aircraft-based observations for tropical convection (e.g., Lasher-Trapp et al., 2016). Higher graupel number generally implies smaller mean size and reduced fall-speed differences, which lowers the graupel-involved collisional kinetic energy and likely explains the limited breakup in this case (Phillips et al., 2017b).</p>
      <p id="d2e5598">Figure <xref ref-type="fig" rid="F9"/>c further illustrates the combined number concentration of ice crystals and graupel. The SIP-induced increases in ice number remain evident at <inline-formula><mml:math id="M316" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M317" display="inline"><mml:mo>≈</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M318" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>20 <inline-formula><mml:math id="M319" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>, with all-SIP and RS <inline-formula><mml:math id="M320" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M1 cases showing clear separation from the no-SIP simulation. For example, at <inline-formula><mml:math id="M321" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 8.5 <inline-formula><mml:math id="M322" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, the all-SIP reaches a peak value approximately 20 <inline-formula><mml:math id="M323" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">L</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, while RS <inline-formula><mml:math id="M324" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M1 yields about 2.5 <inline-formula><mml:math id="M325" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">L</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, both higher than the no-SIP case (<inline-formula><mml:math id="M326" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> 0.5 <inline-formula><mml:math id="M327" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">L</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>) in regions with IWC <inline-formula><mml:math id="M328" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 0.01 <inline-formula><mml:math id="M329" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">g</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>. This indicates that SIP processes not only enhance ice particle production but also help maintain elevated ice amounts at upper levels (see Fig. S1 in the Supplement), consistent with the extensive anvil clouds in Fig. <xref ref-type="fig" rid="F3"/>.</p>
      <p id="d2e5740">In contrast, snow number concentration (Fig. <xref ref-type="fig" rid="F9"/>d) exhibits limited sensitivity to SIP processes. Snow is produced mainly between 8 and 12 <inline-formula><mml:math id="M330" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, and the differences among experiments are minimal, indicating that snow production is dominated by aggregation rather than SIP-induced ice multiplication. Because snow varies little across experiments, snow-involved breakup is likely similar in magnitude across runs and cannot explain the contrasts in ice number. Under warm profiles, graupel-involved collisions exhibit limited energetics, with smaller mean sizes and weaker mass-weighted fall-speed contrasts, which reduces the collisional kinetic energy required for efficient breakup (Phillips et al., 2017b). Consistent with this, the simulation with breakup enabled (RS <inline-formula><mml:math id="M331" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> BR) shows ice-number profiles similar to the RS-only run (Fig. <xref ref-type="fig" rid="F9"/>a and e). Figure <xref ref-type="fig" rid="F9"/>e summarizes the total ice-phase particle number concentration (sum of ice crystals, graupel, and snow). Although including snow reduces the relative difference between SIP and no-SIP experiments, the all-SIP case (<inline-formula><mml:math id="M332" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> 20 <inline-formula><mml:math id="M333" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">L</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>) remains up to 5 times higher than the no-SIP simulation (<inline-formula><mml:math id="M334" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> 4 <inline-formula><mml:math id="M335" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">L</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>) at 8 <inline-formula><mml:math id="M336" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, owing to sustained enhancements in ice and graupel. Overall, under the present convective conditions, SIP processes, particularly those involving drop fragmentation (Mode 1 and Mode 2), play the dominant role in increasing ice crystal number, whereas collisional breakup contributes little. These changes in ice particle populations modify the cloud microphysics and can influence cloud dynamics and radiative properties. Consistent with this, the reflectivity decrease in Fig. <xref ref-type="fig" rid="F4"/> is mainly associated with the increase in small ice crystal number; graupel contributes minor changes relative to crystals, whereas snow remains weakly sensitive to SIP.</p>

      <fig id="F10" specific-use="star"><label>Figure 10</label><caption><p id="d2e5820">Vertical profiles of <bold>(a)</bold> ice water content (IWC) from the combinations of ice crystals and graupel, <bold>(b)</bold> IWC including ice crystals, graupel, and snow, and <bold>(c)</bold> maximum updraft velocity (<inline-formula><mml:math id="M337" display="inline"><mml:mrow><mml:msub><mml:mi>W</mml:mi><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>). Profiles are calculated from 02:30 to 08:30 UTC, 1 December 2005. Panels <bold>(a)</bold> and <bold>(b)</bold> show horizontal averages calculated over regions with IWC <inline-formula><mml:math id="M338" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 0.01 <inline-formula><mml:math id="M339" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">g</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, and panel <bold>(c)</bold> depicts the domain-wide horizontal maximum at each height level. Solid lines represent the ensemble means, with the shaded areas indicate the standard error across the 4-member ensemble. The dashed lines represent isotherms of 0, <inline-formula><mml:math id="M340" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>20, <inline-formula><mml:math id="M341" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>40, and <inline-formula><mml:math id="M342" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>60 <inline-formula><mml:math id="M343" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>.</p></caption>
            <graphic xlink:href="https://acp.copernicus.org/articles/25/18549/2025/acp-25-18549-2025-f10.png"/>

          </fig>

</sec>
<sec id="Ch1.S3.SS3.SSS2">
  <label>3.3.2</label><title>Ice water content and updraft velocity</title>
      <p id="d2e5923">Figure <xref ref-type="fig" rid="F10"/> presents the vertical profiles of horizontally averaged ice water content (IWC) and maximum updraft velocity from the different SIP sensitivity experiments.</p>
      <p id="d2e5928">Figure <xref ref-type="fig" rid="F10"/>a shows IWC including ice crystals and graupel. The all-SIP simulation exhibits the highest IWC values at <inline-formula><mml:math id="M344" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 8 <inline-formula><mml:math id="M345" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math id="M346" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M347" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M348" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>20 <inline-formula><mml:math id="M349" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>), with a clear enhancement compared to the no-SIP case. This enhancement explains the improved representation of radar reflectivity compared to observations, particularly above 6 <inline-formula><mml:math id="M350" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> (Fig. <xref ref-type="fig" rid="F4"/>). The IWC in the all-SIP run is approximately 0.16 <inline-formula><mml:math id="M351" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">g</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, compared to 0.03 <inline-formula><mml:math id="M352" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">g</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in the no-SIP case, reflecting a more than 400 % increase. Among the individual SIP experiments, RS <inline-formula><mml:math id="M353" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M1 shows IWC levels similar to all-SIP between 8 and 11 <inline-formula><mml:math id="M354" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, indicating the strong role of Mode 1 droplet fragmentation in enhancing upper-level ice mass. At 9 <inline-formula><mml:math id="M355" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, the IWC in RS <inline-formula><mml:math id="M356" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M1 reaches <inline-formula><mml:math id="M357" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.10 <inline-formula><mml:math id="M358" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">g</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, over 3 times higher than the no-SIP value. The RS <inline-formula><mml:math id="M359" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M2 case also increases IWC relative to no-SIP but with a more confined impact between 6 and 10 <inline-formula><mml:math id="M360" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>. Its peak IWC near 7 <inline-formula><mml:math id="M361" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math id="M362" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> 0.12 <inline-formula><mml:math id="M363" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">g</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>) lies between RS <inline-formula><mml:math id="M364" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M1 and all-SIP, suggesting that Mode 2 is particularly effective in the lower region. In contrast, RS <inline-formula><mml:math id="M365" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> BR and RS-only experiments produce nearly overlapping IWC profiles throughout the column, with values at 7 <inline-formula><mml:math id="M366" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> remaining below 0.06 <inline-formula><mml:math id="M367" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">g</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, suggesting that ice–ice collisional breakup remains inactive under the present conditions.</p>
      <p id="d2e6167">When snow is included (Fig. <xref ref-type="fig" rid="F10"/>b), column IWC increases across all simulations, with the largest enhancements above <inline-formula><mml:math id="M368" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 9 <inline-formula><mml:math id="M369" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math id="M370" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M371" display="inline"><mml:mo>≈</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M372" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>20 <inline-formula><mml:math id="M373" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>) where snow dominates the mass budget. In this layer, snow is both more numerous than graupel (Fig. <xref ref-type="fig" rid="F9"/>b and d) and larger in size than ice crystals, so it contributes a greater share of IWC. Once snow is accounted for, the inter-experiment differences that mainly arise from crystals are partly diluted (Fig. <xref ref-type="fig" rid="F10"/>a and b), as graupel remains limited. Even so, SIP still yields a net IWC increase between 8 and 12 <inline-formula><mml:math id="M374" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>. At 10 <inline-formula><mml:math id="M375" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, all-SIP reaches 0.43 <inline-formula><mml:math id="M376" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">g</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> compared to 0.39 <inline-formula><mml:math id="M377" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">g</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in no-SIP (<inline-formula><mml:math id="M378" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula>  <inline-formula><mml:math id="M379" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> 10 %), with differences of 5 %–15 % across 8–12 <inline-formula><mml:math id="M380" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> despite the mitigating effect of snow.</p>
      <p id="d2e6296">These patterns are consistent with the number concentration profiles (Fig. <xref ref-type="fig" rid="F9"/>d and e). SIP substantially increases ice crystal numbers (and to a lesser extent graupel) in the upper troposphere and anvil, whereas snow shows weak sensitivity to SIP. Consequently, adding snow reduces the contrast among experiments, yet the SIP-driven shift toward more numerous small crystals remains evident, explaining the decrease in mean reflectivity aloft (Fig. <xref ref-type="fig" rid="F4"/>b).</p>
      <p id="d2e6304">The differences in IWC are accompanied by variations in updraft velocity, as shown in Fig. <xref ref-type="fig" rid="F10"/>c. Figure <xref ref-type="fig" rid="F10"/>c presents the vertical profiles of the domain-maximum updraft velocity (<inline-formula><mml:math id="M381" display="inline"><mml:mrow><mml:msub><mml:mi>W</mml:mi><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>). Above 9 <inline-formula><mml:math id="M382" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, all SIP experiments have <inline-formula><mml:math id="M383" display="inline"><mml:mrow><mml:msub><mml:mi>W</mml:mi><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M384" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 10 % higher than the no-SIP simulation, with the largest enhancements in the all-SIP and RS <inline-formula><mml:math id="M385" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M1 cases, particularly between 10–12 <inline-formula><mml:math id="M386" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>. This enhancement can be attributed to the increased ice crystal number concentrations induced by SIP processes (Fig. <xref ref-type="fig" rid="F9"/>a), which promote more efficient depositional growth and freezing of supercooled water in the upper layers. These processes enhance latent heat release, thereby reinforcing local buoyancy and supporting stronger updrafts (Qu et al., 2022; Grzegorczyk et al., 2025b). Below 8 <inline-formula><mml:math id="M387" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, the differences among experiments are minimal, which is likely because the low-level updrafts are primarily driven by dynamical processes such as boundary-layer convergence and cold pool outflows, and are therefore less sensitive to microphysical modifications induced by SIP. Given the km-scale grid (1.5 <inline-formula><mml:math id="M388" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>) used here, the peak vertical velocities are smaller than in higher-resolution large-eddy simulations (e.g., <inline-formula><mml:math id="M389" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 100 <inline-formula><mml:math id="M390" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula>; Dauhut et al., 2015). This likely reflects resolution effects that weaken intense updrafts, for example through numerical diffusion and subgrid-scale treatment. The contrasts between SIP and no-SIP simulations remain robust, as demonstrated by the sensitivity experiments.</p>
      <p id="d2e6398">Overall, these results demonstrate that SIP processes, particularly those involving droplet fragmentation (Mode 1 and Mode 2), substantially enhance ice mass and ice crystal number concentration in the upper troposphere and anvil region. While the inclusion of snow reduces the relative difference between SIP and no-SIP cases, the enhancement of ice-phase particles by SIP remains evident, highlighting its important role in modifying cloud microphysical structure in the convective and anvil regions.</p>
</sec>
</sec>
</sec>
<sec id="Ch1.S4">
  <label>4</label><title>Discussion</title>
      <p id="d2e6411">Based on model simulations, our results demonstrate that SIP processes significantly enhance both the ice particle population and IWC in the upper cloud layers (Figs. <xref ref-type="fig" rid="F9"/> and <xref ref-type="fig" rid="F10"/>). For instance, at <inline-formula><mml:math id="M391" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>5 <inline-formula><mml:math id="M392" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math id="M393" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> 6 <inline-formula><mml:math id="M394" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>), the ice crystal number concentration increases from 0.5 <inline-formula><mml:math id="M395" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<sup>−3</sup> <inline-formula><mml:math id="M397" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">L</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in the no-SIP case to 1.5 <inline-formula><mml:math id="M398" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">L</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in the all-SIP simulation, representing an enhancement of over 3 orders of magnitude. At <inline-formula><mml:math id="M399" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 8.5 <inline-formula><mml:math id="M400" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, all-SIP and RS <inline-formula><mml:math id="M401" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M1 cases reach peak values of 11.5 and 2.5 <inline-formula><mml:math id="M402" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">L</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, compared to 0.86 <inline-formula><mml:math id="M403" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">L</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in the no-SIP case. The RS <inline-formula><mml:math id="M404" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M2 increases ice number concentrations primarily between 6 and 8 <inline-formula><mml:math id="M405" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math id="M406" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M407" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M408" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>5 <inline-formula><mml:math id="M409" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>), consistent with Mode 2 activation in regions rich in supercooled raindrops. For the IWC, SIP processes increase values at 8–9 <inline-formula><mml:math id="M410" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> from 0.03 <inline-formula><mml:math id="M411" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">g</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in the no-SIP case to 0.10 <inline-formula><mml:math id="M412" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">g</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in RS <inline-formula><mml:math id="M413" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M1, and 0.16 <inline-formula><mml:math id="M414" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">g</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in the all-SIP simulation, representing an enhancement of over 400 %. These results highlight the dominant role of SIP, especially Mode 1 and Mode 2 droplet fragmentation, in generating high concentrations of small ice particles and increased IWC in the upper troposphere.</p>
      <p id="d2e6663">These microphysical changes lead to modifications in radiative fluxes. The reduced OLR is mainly attributed to the colder and more optically thick cloud tops. With higher concentration of small ice particles (Fig. <xref ref-type="fig" rid="F4"/>b), OSR is enhanced due to the increased shortwave scattering and cloud reflectivity. The mean OLR decreases from 239.4 <inline-formula><mml:math id="M415" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in the no-SIP case to 236.2 <inline-formula><mml:math id="M416" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in the all-SIP simulation, with a minimum as low as 198.4 <inline-formula><mml:math id="M417" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>. Similarly, OSR increases from a mean of 246.5 <inline-formula><mml:math id="M418" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in no-SIP to 250.9 <inline-formula><mml:math id="M419" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in all-SIP, with a peak value of 353.6 <inline-formula><mml:math id="M420" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>. As emphasized by Finney et al. (2025), even a 1 %–3 % increase in high cloud albedo can produce substantial radiative feedback. While we do not explicitly calculate cloud albedo, the observed changes in longwave and shortwave reflectivity suggest that SIP could play an important role in modulating the radiative forcing of convective systems, potentially influencing regional and large-scale climate feedback. Further work evaluating these effects across different events and environments, and using long integrations with parameterized SIP, would be helpful for quantifying their climate relevance.</p>

      <fig id="F11" specific-use="star"><label>Figure 11</label><caption><p id="d2e6773">Relative change (%) between the SIP-included and no-SIP simulations for different variables: outgoing longwave radiation (OLR), outgoing shortwave radiation (OSR), domain-averaged and -maximum precipitation rate (Precip_avg, Precip_max), domain-maximum updraft velocity (<inline-formula><mml:math id="M421" display="inline"><mml:mrow><mml:msub><mml:mi>W</mml:mi><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>), ice water content (IWC, including ice crystals, graupel, and snow), and total ice-phase particles number (<inline-formula><mml:math id="M422" display="inline"><mml:mrow><mml:msub><mml:mi>N</mml:mi><mml:mrow><mml:mi mathvariant="normal">ice</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="normal">particles</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>). Results are shown for 4 ensemble members initialized at different times (T18, T12, T06, and T00). For each member, the relative change was estimated using 1000 bootstrap samples. Gray and blue bars show the overall relative change for each variable; with <inline-formula><mml:math id="M423" display="inline"><mml:mrow><mml:msub><mml:mi>N</mml:mi><mml:mrow><mml:mi mathvariant="normal">ice</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="normal">particles</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> plotted against the right <inline-formula><mml:math id="M424" display="inline"><mml:mi>y</mml:mi></mml:math></inline-formula> axis. Red dashed lines indicate the <inline-formula><mml:math id="M425" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 1<inline-formula><mml:math id="M426" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula> ensemble spread, computed as the average standard deviation of the bootstrap samples across all members.</p></caption>
        <graphic xlink:href="https://acp.copernicus.org/articles/25/18549/2025/acp-25-18549-2025-f11.png"/>

      </fig>

      <p id="d2e6848">SIP processes, particularly those involving droplet fragmentation (Mode 1 and Mode 2), also affect precipitation structure in the Hector storm. By increasing ice crystal concentrations and IWC in the upper levels, SIP promotes more localized, compact heavy-rainfall region near the main convective zone (Fig. <xref ref-type="fig" rid="F6"/>). However, the domain-averaged precipitation rate is reduced (Fig. <xref ref-type="fig" rid="F8"/>a), with the all-SIP case producing 0.63 <inline-formula><mml:math id="M427" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">h</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, about 8 % lower than the 0.69 <inline-formula><mml:math id="M428" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">h</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in no-SIP simulation. These results are similar to the findings from Han et al. (2024) and Grzegorczyk et al. (2025b, c), suggesting that in the mixed-phase region and above, SIP shifts more condensate from warm-rain processes toward ice-phase pathways, producing less surface precipitation. Additional losses may arise from sublimation of small ice particles before reaching the ground. In the RS case (rime-splintering only), changes to surface rainfall are small, consistent with limited graupel growth and the narrow temperature window for HM activation. Adding Mode 1 produces numerous small ice particles at relatively higher levels (<inline-formula><mml:math id="M429" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M430" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>15 to <inline-formula><mml:math id="M431" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>25 <inline-formula><mml:math id="M432" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>; Fig. <xref ref-type="fig" rid="F9"/>a), which likely shifts condensate from warm-rain processes and places much of the newly formed ice farther from the melting layer. Aggregation and/or riming therefore tend to occur later, and sublimation during descent can limit increase in surface rainfall. Mode 2 generates secondary ice closer to the melting level (<inline-formula><mml:math id="M433" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M434" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>5 <inline-formula><mml:math id="M435" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>), often within regions of higher liquid water content, which can accelerate riming to snow/graupel. The shorter distance to the surface can reduce sublimation losses and raise the domain-mean precipitation. Including ice–ice collisional breakup (BR) produces additional fragments within the mixed-phase layer that are likely to be incorporated into ongoing riming, reinforcing a narrow band of enhancement near the convective region and yielding increased surface rainfall, despite <inline-formula><mml:math id="M436" display="inline"><mml:mrow><mml:msub><mml:mi>N</mml:mi><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> remaining close to RS. When multiple SIP processes act together (all-SIP), the increase in small ice aloft tends to reduce the liquid water available for warm-rain collection and riming, helping to explain why total rainfall can be lower than in cases with only one or two mechanisms, even though precipitation is more localized (Figs. <xref ref-type="fig" rid="F6"/> and <xref ref-type="fig" rid="F8"/>). In contrast, peak rainfall rates change little (Fig. <xref ref-type="fig" rid="F8"/>b): the all-SIP simulation peak is 186.6 <inline-formula><mml:math id="M437" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">h</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, slightly lower than 199.6 <inline-formula><mml:math id="M438" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">h</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> in the no-SIP, and all simulations underestimate the observed peak (<inline-formula><mml:math id="M439" display="inline"><mml:mo lspace="0mm">&gt;</mml:mo></mml:math></inline-formula> 250 <inline-formula><mml:math id="M440" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">h</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>). This indicates that the most extreme precipitation events are primarily driven by dynamical forcings, such as boundary-layer convergence and cold pool outflows, rather than microphysical variations alone (Connolly et al., 2013). While SIP may enhance upper-level buoyancy through latent heat release from depositional growth and freezing, the updraft velocity (<inline-formula><mml:math id="M441" display="inline"><mml:mrow><mml:msub><mml:mi>W</mml:mi><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) increases by <inline-formula><mml:math id="M442" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 10 % (Fig. <xref ref-type="fig" rid="F10"/>c), which is measurable but has limited impact on peak rainfall metrics in this case. Previous studies reported varied impacts of SIP on precipitation intensity: reductions in the heavy rainfall (e.g., <inline-formula><mml:math id="M443" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 40 <inline-formula><mml:math id="M444" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi></mml:mrow></mml:math></inline-formula>) have been documented (Grzegorczyk et al., 2025b, c), whereas localized enhancements within convective regions have also been reported (Sullivan et al., 2018). The effectiveness of such cold-phase invigoration mechanisms remains uncertain, with some studies suggesting that the added buoyancy may be offset by the increased mass loading from ice particles (Grabowski and Morrison, 2020; Varble et al., 2023). Overall in this case, SIP mainly reshapes the spatial distribution and partitioning/yield of surface rainfall, with limited impact on the intensity of localized extreme events.</p>
      <p id="d2e7060">To assess the robustness of SIP-induced signals relative to natural meteorological variability, we compared the differences between SIP and no-SIP simulations against the ensemble spread from four members initialized at different times (Fig. <xref ref-type="fig" rid="F11"/>). Overall, the changes caused by SIP in cloud properties (e.g., IWC and ice number concentration) and radiation (OLR) are both systematic and statistically significant, with magnitudes exceeding the <inline-formula><mml:math id="M445" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 1<inline-formula><mml:math id="M446" display="inline"><mml:mi mathvariant="italic">σ</mml:mi></mml:math></inline-formula> ensemble spread across all members. For example, while the ensemble spread in domain-averaged OLR is <inline-formula><mml:math id="M447" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1 %, the SIP-induced reduction exceeds 1.3 %. For IWC and ice number concentration, the differences exceed ensemble variability by more than a factor of two. Other variables, such as OSR and domain-averaged precipitation, show consistent SIP-related responses across ensemble members, but the magnitudes fall closer to the spread, indicating weaker but still coherent signals. In contrast, maximum precipitation rates show little sensitivity to SIP and lie within ensemble spread, suggesting that extremes are highly influenced by meteorological variability. These results suggest that, while natural variability modulates the amplitude of individual responses, the key signals induced by SIP, especially in cloud and radiative properties, are physically robust and statistically significant.</p>
      <p id="d2e7086">Unlike studies that reported strong ice–ice collisional breakup (e.g., Sullivan et al., 2018; Grzegorczyk et al., 2025a), our case shows no clear BR signal (Fig. <xref ref-type="fig" rid="F9"/>). Near <inline-formula><mml:math id="M448" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 8 <inline-formula><mml:math id="M449" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, graupel number concentrations peak at <inline-formula><mml:math id="M450" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1–10 <inline-formula><mml:math id="M451" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">L</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> (Fig. <xref ref-type="fig" rid="F9"/>b). BR remains weak because graupel-involved collision energetics are limited under warm profiles. At comparable IWC, a higher graupel number implies smaller mean size and weaker mass-weighted fall speed contrasts, which reduces the collisional kinetic energy that controls breakup efficiency as formulated by Phillips et al. (2017a). Numerical experiments suggest that graupel–snow interactions provide the major source of breakup fragments under convective conditions (Phillips et al., 2017b). Therefore, the overall BR contribution remains small when graupel-involved collision energetics are limited. These results likely highlight the environmental dependence of ice–ice breakup, which appears less effective in tropical deep convection with warm, moist profiles and limited graupel growth (e.g., Phillips et al., 2017a; Korolev et al., 2020; Huang et al., 2022). In light of this, the existing SIP parameterizations, many of which were developed in mid-latitude cloud environments, should be applied with caution in tropical settings. To improve model performance, future schemes may need to better account for environmental factors, such as graupel abundance, temperature profiles, and convective intensity. Moreover, the interactions between SIP and aerosol conditions remain poorly constrained and deserve further investigation, given their potential influence on cloud microphysics and storm development in tropical regions (e.g., Sun et al., 2021, 2024).</p>
      <p id="d2e7130">This study focuses on a single Hector storm case. While the ensemble results provide insights into SIP impacts in tropical deep convection, the findings should be interpreted cautiously before generalized to other storm types or regions. In addition, SIP parameterization remains poorly constrained despite recent advances (e.g., James et al., 2021). More systematic laboratory and field investigations are needed to improve its quantification. Future work should involve multi-case, multi-region simulations and integrate observational constraints to evaluate SIP processes more comprehensively.</p>
</sec>
<sec id="Ch1.S5" sec-type="conclusions">
  <label>5</label><title>Conclusion</title>
      <p id="d2e7143">In this study, we first implemented secondary ice production (SIP) parameterizations into the double-moment cloud microphysics scheme of Unified Model (UM-CASIM), including droplet shattering (Mode 1 and Mode 2) and ice–ice collisional breakup. These schemes were applied to a real-case simulation of a Hector tropical deep convective storm to assess their impacts on cloud microphysics, radiative fluxes, precipitation, and storm dynamics. To complement the sensitivity experiments, we conducted a time-lagged ensemble with varied initial times to evaluate the robustness of SIP-induced signals. The changes caused by SIP in cloud properties (e.g., IWC and ice number concentration), radiative fluxes (OLR), and domain-averaged precipitation were generally larger than or comparable to the ensemble spread, indicating that the signals are systematic and not dominated by internal meteorological variability. While OSR showed less consistent significance, the overall patterns support that the microphysical and radiative responses to SIP are physically robust.</p>
      <p id="d2e7146">Our results demonstrate that SIP, particularly droplet fragmentation processes including Mode 1 and Mode 2, can substantially enhance ice crystal number concentrations and upper-level ice water content (IWC), especially in the anvil region. These microphysical changes modify cloud radiative properties, leading to reduced outgoing longwave radiation (OLR) and increased outgoing shortwave radiation (OSR) at the top of the atmosphere, resulting in better agreement with satellite observations.</p>
      <p id="d2e7149">SIP also reshapes precipitation characteristics by promoting a more localized, compact rainfall pattern near the main convective zone, while reducing domain-averaged precipitation. This reduction exceeds the ensemble spread and is consistent with a shift from warm-rain to ice-phase growth, accompanied by in-transit losses from sedimentation and sublimation and yielding less surface rainfall. In contrast, peak rainfall rates across the domain remain largely unaffected and fall within ensemble variability, consistent with the minimal changes in maximum updraft velocity (<inline-formula><mml:math id="M452" display="inline"><mml:mrow><mml:msub><mml:mi>W</mml:mi><mml:mi mathvariant="normal">max</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>). These results suggest that SIP primarily modulates the pattern and efficiency of rainfall rather than intensifying extreme convective events.</p>
      <p id="d2e7163">Among the SIP mechanisms examined, ice–ice collisional breakup had limited influence in this case, likely due to the warm, moist environment and insufficient graupel production. This highlights the environmental dependence of SIP efficiency in tropical convection. These findings suggest that existing parameterizations may need to be adapted when applied to warmer convective conditions. While this study provides new insights into SIP behavior in tropical settings, further works are needed to explore how these processes vary across different storm types and environmental conditions.</p>
</sec>

      
      </body>
    <back><app-group>

<app id="App1.Ch1.S1">
  <label>Appendix A</label><title/>

<table-wrap id="TA1"><label>Table A1</label><caption><p id="d2e7181">List of symbols.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="3">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:colspec colnum="3" colname="col3" align="left"/>
     <oasis:thead>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Symbol</oasis:entry>
         <oasis:entry colname="col2">Description</oasis:entry>
         <oasis:entry colname="col3">Value and units</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M453" display="inline"><mml:mi>A</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Number density of the breakable asperities in the contact region</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M454" display="inline"><mml:mi>C</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Asperity-fragility coefficient</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M455" display="inline"><mml:mrow><mml:msub><mml:mi>c</mml:mi><mml:mi mathvariant="normal">w</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Specific heat capacity of liquid water</oasis:entry>
         <oasis:entry colname="col3">4200 <inline-formula><mml:math id="M456" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">J</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">kg</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">K</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M457" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M458" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Diameters of the colliding ice-phase particles in ice–ice collisional breakup</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M459" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">DE</oasis:entry>
         <oasis:entry colname="col2">Dimensionless energy</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M460" display="inline"><mml:mrow><mml:msub><mml:mtext>DE</mml:mtext><mml:mi mathvariant="normal">crit</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Critical value of dimensionless energy for onset of splashing</oasis:entry>
         <oasis:entry colname="col3">0.2</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M461" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Diameter of ice particles in Mode 1 and Mode 2</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M462" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M463" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Diameters of raindrops in Mode 1 and Mode 2</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M464" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M465" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mrow><mml:mi mathvariant="normal">i</mml:mi><mml:mo>,</mml:mo><mml:mtext>thresh</mml:mtext></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Diameter of an ice particle whose mass equals that of the colliding raindrop</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M466" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M467" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mrow><mml:mi mathvariant="normal">R</mml:mi><mml:mo>,</mml:mo><mml:mtext>thresh</mml:mtext></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Minimum raindrop diameter for Mode 2</oasis:entry>
         <oasis:entry colname="col3">0.15 <inline-formula><mml:math id="M468" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">mm</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M469" display="inline"><mml:mi>F</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Interpolation function for the onset of fragmentation</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M470" display="inline"><mml:mrow><mml:mi>f</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M471" display="inline"><mml:mrow><mml:mi>f</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Size distribution functions at diameters <inline-formula><mml:math id="M472" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M473" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M474" display="inline"><mml:mrow><mml:mi>f</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M475" display="inline"><mml:mrow><mml:mi>f</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Size distribution functions at diameters <inline-formula><mml:math id="M476" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M477" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M478" display="inline"><mml:mrow><mml:mi>f</mml:mi><mml:mo>(</mml:mo><mml:mi>T</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Mass fraction of drop frozen in Mode 2</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M479" display="inline"><mml:mrow><mml:msub><mml:mi>f</mml:mi><mml:mi mathvariant="normal">RS</mml:mi></mml:msub><mml:mo>(</mml:mo><mml:mi>T</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Temperature-dependent function of rime splintering</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M480" display="inline"><mml:mrow><mml:msub><mml:mi>K</mml:mi><mml:mrow><mml:mn mathvariant="normal">0</mml:mn><mml:mo>(</mml:mo><mml:mi>C</mml:mi><mml:mi>B</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Collisional kinetic energy at impact</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M481" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">J</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M482" display="inline"><mml:mrow><mml:msub><mml:mi>L</mml:mi><mml:mi mathvariant="normal">f</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Specific latent heat of freezing</oasis:entry>
         <oasis:entry colname="col3">3.3 <inline-formula><mml:math id="M483" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<sup>5</sup> <inline-formula><mml:math id="M485" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">J</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">kg</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M486" display="inline"><mml:mrow><mml:msub><mml:mi>m</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M487" display="inline"><mml:mrow><mml:msub><mml:mi>m</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Mass of colliding ice particles</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M488" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">kg</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M489" display="inline"><mml:mrow><mml:msub><mml:mi>M</mml:mi><mml:mrow><mml:mi mathvariant="normal">I</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Mass of each splinter</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M490" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">kg</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M491" display="inline"><mml:mrow><mml:msub><mml:mi>N</mml:mi><mml:mi mathvariant="normal">CB</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Number of ice particles due to ice–ice collisional breakup</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M492" display="inline"><mml:mrow><mml:msub><mml:mi>N</mml:mi><mml:mrow><mml:mi mathvariant="normal">M</mml:mi><mml:mn mathvariant="normal">1</mml:mn><mml:mi mathvariant="normal">L</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Total number of large ice particles due to Mode 1</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M493" display="inline"><mml:mrow><mml:msub><mml:mi>N</mml:mi><mml:mrow><mml:mi mathvariant="normal">M</mml:mi><mml:mn mathvariant="normal">1</mml:mn><mml:mi mathvariant="normal">T</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Total number of ice particles due to Mode 1</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M494" display="inline"><mml:mrow><mml:msub><mml:mi>P</mml:mi><mml:mi mathvariant="normal">gacw</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Riming rate of cloud droplets by graupel</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M495" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">number</mml:mi><mml:mspace linebreak="nobreak" width="0.25em"/><mml:msup><mml:mi mathvariant="normal">kg</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">s</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M496" display="inline"><mml:mrow><mml:msub><mml:mi>P</mml:mi><mml:mi mathvariant="normal">ihal</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Splinter production rate</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M497" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">number</mml:mi><mml:mspace linebreak="nobreak" width="0.25em"/><mml:msup><mml:mi mathvariant="normal">kg</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">s</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M498" display="inline"><mml:mrow><mml:msub><mml:mi>P</mml:mi><mml:mi mathvariant="normal">sacw</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Riming rate of cloud droplets by snow</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M499" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">number</mml:mi><mml:mspace width="0.25em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">kg</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">s</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M500" display="inline"><mml:mrow><mml:msub><mml:mi>S</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Surface energy</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M501" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">J</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M502" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Freezing temperature of water drop</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M503" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M504" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Time</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M505" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">s</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M506" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Value of <inline-formula><mml:math id="M507" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> at maximum of Lorentzian function for Eq. (<xref ref-type="disp-formula" rid="Ch1.E5"/>)</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M508" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M509" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mrow><mml:mi mathvariant="normal">B</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Value of <inline-formula><mml:math id="M510" display="inline"><mml:mi>T</mml:mi></mml:math></inline-formula> at maximum of Lorentzian function for Eq. (<xref ref-type="disp-formula" rid="Ch1.E6"/>)</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M511" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M512" display="inline"><mml:mrow><mml:mi>v</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M513" display="inline"><mml:mrow><mml:mi>v</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col2">Fall speed of ice particles with diameters <inline-formula><mml:math id="M514" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M515" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>; denoted <inline-formula><mml:math id="M516" display="inline"><mml:mrow><mml:msub><mml:mi>v</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M517" display="inline"><mml:mrow><mml:msub><mml:mi>v</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> for the colliding particles</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M518" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">s</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M519" display="inline"><mml:mrow><mml:mi>v</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M520" display="inline"><mml:mrow><mml:mi>v</mml:mi><mml:mo>(</mml:mo><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Fall speed of raindrops and ice particles with diameters <inline-formula><mml:math id="M521" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">R</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M522" display="inline"><mml:mrow><mml:msub><mml:mi>D</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M523" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">m</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">s</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M524" display="inline"><mml:mi mathvariant="italic">α</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Equivalent spherical area of the colliding particle</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M525" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M526" display="inline"><mml:mi mathvariant="italic">β</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Parameter in Eq. (<xref ref-type="disp-formula" rid="Ch1.E5"/>)</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M527" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">K</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M528" display="inline"><mml:mi mathvariant="italic">γ</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Parameter of riming intensity</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M529" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">γ</mml:mi><mml:mi mathvariant="normal">liq</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Surface tension of liquid water</oasis:entry>
         <oasis:entry colname="col3">0.073<inline-formula><mml:math id="M530" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">J</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M531" display="inline"><mml:mi mathvariant="italic">ζ</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Intensity of Lorentzian function in Eq. (<xref ref-type="disp-formula" rid="Ch1.E5"/>)</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M532" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ζ</mml:mi><mml:mi mathvariant="normal">B</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Intensity of Lorentzian function in Eq. (<xref ref-type="disp-formula" rid="Ch1.E6"/>)</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M533" display="inline"><mml:mi mathvariant="italic">η</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Half-width of Lorentzian function in Eq. (<xref ref-type="disp-formula" rid="Ch1.E5"/>)</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M534" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M535" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">η</mml:mi><mml:mi mathvariant="normal">B</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Half-width of Lorentzian function in Eq. (<xref ref-type="disp-formula" rid="Ch1.E6"/>)</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M536" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">°</mml:mi><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M537" display="inline"><mml:mi mathvariant="normal">Φ</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Probability of any drop in Mode 2 containing ice</oasis:entry>
         <oasis:entry colname="col3">0.3</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M538" display="inline"><mml:mi mathvariant="normal">Ω</mml:mi></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Interpolating function for the onset of fragmentation</oasis:entry>
         <oasis:entry colname="col3">–</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M539" display="inline"><mml:mrow><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mrow><mml:mo>∂</mml:mo><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mo>∂</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:msub><mml:mi mathvariant="normal">|</mml:mi><mml:mi mathvariant="normal">CB</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Production rate of ice particles due to ice–ice collisional breakup</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M540" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">number</mml:mi><mml:mspace width="0.25em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">s</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M541" display="inline"><mml:mrow><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mrow><mml:mo>∂</mml:mo><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mo>∂</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:msub><mml:mi mathvariant="normal">|</mml:mi><mml:mrow><mml:mtext>M1</mml:mtext><mml:mo>,</mml:mo><mml:mi mathvariant="normal">c</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Production rate of ice particles from raindrop–ice collisional breakup in Mode 1</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M542" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">number</mml:mi><mml:mspace linebreak="nobreak" width="0.25em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">s</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M543" display="inline"><mml:mrow><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mrow><mml:mo>∂</mml:mo><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mo>∂</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:msub><mml:mi mathvariant="normal">|</mml:mi><mml:mrow><mml:mtext>M1</mml:mtext><mml:mo>,</mml:mo><mml:mi mathvariant="normal">f</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Production rate of ice particles from freezing droplet shattering in Mode 1</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M544" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">number</mml:mi><mml:mspace width="0.25em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">s</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M545" display="inline"><mml:mrow><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mrow><mml:mo>∂</mml:mo><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mo>∂</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:msub><mml:mi mathvariant="normal">|</mml:mi><mml:mrow><mml:mi mathvariant="normal">M</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Production rate of ice particles due to Mode 1</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M546" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">number</mml:mi><mml:mspace linebreak="nobreak" width="0.25em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">s</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M547" display="inline"><mml:mrow><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mrow><mml:mo>∂</mml:mo><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">ice</mml:mi></mml:msub></mml:mrow><mml:mrow><mml:mo>∂</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:msub><mml:mi mathvariant="normal">|</mml:mi><mml:mrow><mml:mi mathvariant="normal">M</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Production rate of ice particles due to Mode 2</oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M548" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">number</mml:mi><mml:mspace linebreak="nobreak" width="0.25em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">s</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>


</app>
  </app-group><notes notes-type="dataavailability"><title>Data availability</title>

      <p id="d2e8956">The model output in this study is archived on the UK Met Office MASS system (suite ID: u-dp252) and accessible via the JASMIN platform (<uri>http://www.jasmin.ac.uk/</uri>, last access: 10 November 2025). The CASIM microphysics code, including the newly implemented SIP schemes, is available on the Met Office Science Repository Service (MOSRS): <uri>https://code.metoffice.gov.uk/trac/monc/log/casim/branches/dev/mengyusun/r10208_SIP_rep</uri> (last access: 10 November 2025). Specific SIP configurations are stored under revisions: rev11607 (all-SIP), rev11609 (no-SIP), rev11678 (RS), rev11679 (RS <inline-formula><mml:math id="M549" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M1), rev11680 (RS <inline-formula><mml:math id="M550" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> M2), and rev11677 (RS <inline-formula><mml:math id="M551" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> BR).</p>
  </notes><app-group>
        <supplementary-material position="anchor"><p id="d2e8986">The supplement related to this article is available online at <inline-supplementary-material xlink:href="https://doi.org/10.5194/acp-25-18549-2025-supplement" xlink:title="pdf">https://doi.org/10.5194/acp-25-18549-2025-supplement</inline-supplementary-material>.</p></supplementary-material>
        </app-group><notes notes-type="authorcontribution"><title>Author contributions</title>

      <p id="d2e8995">MS and PJC conceptualized the study and designed the experiments. PJC led the implementation of the SIP parameterizations in CASIM, with assistance from MS. PRF contributed to the UM setup and advised on the CASIM code and ensemble methodology. MS carried out the simulations and formal analysis and wrote the paper, with support from PJC, PRF, DLF, and AMB. AMB supervised the project and acquired funding.</p>
  </notes><notes notes-type="competinginterests"><title>Competing interests</title>

      <p id="d2e9001">The contact author has declared that none of the authors has any competing interests.</p>
  </notes><notes notes-type="disclaimer"><title>Disclaimer</title>

      <p id="d2e9007">Publisher's note: Copernicus Publications remains neutral with regard to jurisdictional claims made in the text, published maps, institutional affiliations, or any other geographical representation in this paper. While Copernicus Publications makes every effort to include appropriate place names, the final responsibility lies with the authors. Views expressed in the text are those of the authors and do not necessarily reflect the views of the publisher.</p>
  </notes><ack><title>Acknowledgements</title><p id="d2e9013">We thank the Met Office and NERC for access to the Monsoon high-performance computing system, and the UK Centre for Environmental Data Analysis (CEDA) for data storage and processing via the JASMIN infrastructure (<ext-link xlink:href="https://doi.org/10.1109/BigData.2013.6691556" ext-link-type="DOI">10.1109/BigData.2013.6691556</ext-link>).</p></ack><notes notes-type="financialsupport"><title>Financial support</title>

      <p id="d2e9021">This research has been supported by the Natural Environment Research Council (grant no. NE/T006420/1) and the HORIZON EUROPE European Research Council (grant no. 101137680).</p>
  </notes><notes notes-type="reviewstatement"><title>Review statement</title>

      <p id="d2e9027">This paper was edited by Jianzhong Ma and reviewed by Pierre Grzegorczyk and two anonymous referees.</p>
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