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<!DOCTYPE article PUBLIC "-//NLM//DTD Journal Publishing with OASIS Tables v3.0 20080202//EN" "journalpub-oasis3.dtd">
<article xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:oasis="http://docs.oasis-open.org/ns/oasis-exchange/table" xml:lang="en" dtd-version="3.0" article-type="review-article"><?xmltex \makeatother\@nolinetrue\makeatletter?>
  <front>
    <journal-meta><journal-id journal-id-type="publisher">ACP</journal-id><journal-title-group>
    <journal-title>Atmospheric Chemistry and Physics</journal-title>
    <abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">Atmos. Chem. Phys.</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">1680-7324</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/acp-21-9887-2021</article-id><title-group><article-title><inline-formula><mml:math id="M1" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalence metrics for surface albedo change based on the radiative forcing concept: a critical review</article-title><alt-title><inline-formula><mml:math id="M2" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalence metrics for surface albedo change</alt-title>
      </title-group><?xmltex \runningtitle{{$\chem{CO_{{2}}}$}-equivalence metrics for surface albedo change}?><?xmltex \runningauthor{R.~M.~Bright and M.~T.~Lund}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1">
          <name><surname>Bright</surname><given-names>Ryan M.</given-names></name>
          <email>ryan.bright@nibio.no</email>
        <ext-link>https://orcid.org/0000-0001-8553-5570</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Lund</surname><given-names>Marianne T.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-9911-4160</ext-link></contrib>
        <aff id="aff1"><label>1</label><institution>Department of Forest and Climate, Norwegian Institute of Bioeconomy Research (NIBIO), P.O. Box 115, 1431-Ås, Norway</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Centre for International Climate Research (CICERO), 0349 Oslo, Norway</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Ryan M. Bright (ryan.bright@nibio.no)</corresp></author-notes><pub-date><day>1</day><month>July</month><year>2021</year></pub-date>
      
      <volume>21</volume>
      <issue>12</issue>
      <fpage>9887</fpage><lpage>9907</lpage>
      <history>
        <date date-type="received"><day>23</day><month>October</month><year>2020</year></date>
           <date date-type="accepted"><day>4</day><month>June</month><year>2021</year></date>
           <date date-type="rev-recd"><day>3</day><month>June</month><year>2021</year></date>
           <date date-type="rev-request"><day>10</day><month>December</month><year>2020</year></date>
      </history>
      <permissions>
        <copyright-statement>Copyright: © 2021 </copyright-statement>
        <copyright-year>2021</copyright-year>
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://acp.copernicus.org/articles/.html">This article is available from https://acp.copernicus.org/articles/.html</self-uri><self-uri xlink:href="https://acp.copernicus.org/articles/.pdf">The full text article is available as a PDF file from https://acp.copernicus.org/articles/.pdf</self-uri>
      <abstract><title>Abstract</title>
    <p id="d1e116">Management of Earth's surface albedo is increasingly viewed as an important climate change mitigation strategy both on (Seneviratne et al., 2018)
and off (Field et al., 2018; Kravitz et al., 2018) the land. Assessing the impact of a surface albedo change involves employing a measure like
radiative forcing (RF) which can be challenging to digest for decision-makers who deal in the currency of <inline-formula><mml:math id="M3" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent
emissions. As a result, many researchers express albedo change (<inline-formula><mml:math id="M4" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>) RFs in terms of their <inline-formula><mml:math id="M5" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent effects,
despite the lack of a standard method for doing so, such as there is for emissions of well-mixed greenhouse gases (WMGHGs; e.g., IPCC AR5, Myhre
et al., 2013). A major challenge for converting <inline-formula><mml:math id="M6" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> RFs into their <inline-formula><mml:math id="M7" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent effects in a manner consistent
with current IPCC emission metric approaches stems from the lack of a universal time dependency following the perturbation (perturbation
“lifetime”). Here, we review existing methodologies based on the RF concept with the goal of highlighting the context(s) in which the
resulting <inline-formula><mml:math id="M8" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent metrics may or may not have merit. To our knowledge this is the first review dedicated entirely to the topic
since the first <inline-formula><mml:math id="M9" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> metric for <inline-formula><mml:math id="M10" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> surfaced 20 years ago. We find that, although there are some methods that sufficiently
address the time-dependency issue, none address or sufficiently account for the spatial disparity between the climate response to <inline-formula><mml:math id="M11" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>
emissions and <inline-formula><mml:math id="M12" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> – a major critique of <inline-formula><mml:math id="M13" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> metrics based on the RF concept (Jones et al., 2013). We conclude that
considerable research efforts are needed to build consensus surrounding the RF “efficacy” of various surface forcing types associated
with <inline-formula><mml:math id="M14" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> (e.g., crop change, forest harvest), and the degree to which these are sensitive to the spatial pattern, extent, and
magnitude of the underlying surface forcings.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <label>1</label><title>Introduction</title>
      <p id="d1e262">The albedo at Earth's surface helps to govern the amount of solar energy absorbed by the Earth system and is thus a relevant physical property shaping
weather and climate (Cess, 1978; Hansen et al., 1984; Pielke Sr. et al., 1998). On average, Earth reflects about 30 % of the energy it receives
from the sun, of which about 13 % may be attributed to the surface albedo (Stephens et al., 2015; Donohoe and Battisti, 2011). In recent years it
has become the subject of increasing research interest amongst the scientific community, as measures to increase Earth's surface albedo are
increasingly viewed as an integral component of climate change mitigation and adaptation, both on (Seneviratne et al., 2018) and off (Field et al.,
2018; Kravitz et al., 2018) the land. Surface albedo modifications associated with large-scale carbon dioxide removal (CDR) like re-/afforestation can
detract from the effectiveness of such mitigation strategies (Boysen et al., 2016), given that such modifications generally serve to increase Earth's
solar radiation budget, resulting in warming. Like emissions of GHGs and aerosols, perturbations to the planetary albedo via perturbations to the
surface albedo represent true external forcings of the climate system and can be measured in terms of changes to Earth's radiative balance – or
radiative forcings (Houghton et al., 1995). The radiative forcing (RF) concept provides a first-order means to compare surface albedo changes
(henceforth <inline-formula><mml:math id="M15" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>) to other perturbation types, thus enabling a more comprehensive evaluation of human activities altering Earth's surface
(Houghton et al., 1995; Pielke Sr. et al., 2002).</p>
      <p id="d1e275">Radiative forcing is a standard measure of the effects of various emissions or perturbations on climate and can be used to compare the
effect of changes between any two points in time. It is a backward-looking measure accounting for the impact up to the given point and does not express
the actual temperature response to the perturbation. To enable aggregation of emissions of different gases to a common scale, the concept of
<inline-formula><mml:math id="M16" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent emissions is commonly used in assessments, decision making, and policy frameworks. While initially introduced to illustrate
the difficulties related to comparing the climate impacts of different gases, the field of emission metrics – i.e., the methods to convert
non-<inline-formula><mml:math id="M17" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> radiative constituents into their <inline-formula><mml:math id="M18" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent effects – has evolved and presently includes a suite of alternative
formulations, including the global warming potential (GWP) adopted by the UNFCCC (O'Neill, 2000; Fuglestvedt et al., 2003; Fuglestvedt et al.,
2010). Today, <inline-formula><mml:math id="M19" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalency metrics form an integral part of UNFCC emission reporting and climate agreements (e.g. the Kyoto Protocol) –
in addition to the fields of life cycle assessment (Heijungs and Guineév, 2012) and integrated assessment modeling (O'Neill et al., 2016) –
despite much debate around GWP as the metric of choice (Denison et al., 2019). As such, many researchers seek to convert RF from
<inline-formula><mml:math id="M20" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> into a <inline-formula><mml:math id="M21" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent effect, which is particularly useful in land use forcing research when perturbations to terrestrial
carbon cycling often accompany the <inline-formula><mml:math id="M22" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>. Although seemingly straightforward at the surface, the procedure is complicated by two key
fundamental differences between <inline-formula><mml:math id="M23" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M24" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>: additional <inline-formula><mml:math id="M25" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> becomes well-mixed within the atmosphere upon emission,
and the resulting atmospheric perturbation persists over millennia and cannot be fully reversed by human interventions. In other words,
<inline-formula><mml:math id="M26" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>'s RF is both temporally and spatially extensive, with the ensuring climate response being independent of the location of
emission, whereas the RF and ensuing climate response following <inline-formula><mml:math id="M27" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> are more localized and can be fully reversed on short timescales.</p>
      <p id="d1e408">These challenges have led researchers to adapt a variety of diverging methods for converting albedo change RFs (henceforth
<inline-formula><mml:math id="M28" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>) into <inline-formula><mml:math id="M29" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> equivalence. Unlike for conventional GHGs, however, there has been little concerted effort by the
climate metric science community to build consensus or formalize a standard methodology for <inline-formula><mml:math id="M30" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> (as evidenced by IPCC AR4 and
AR5). Here, we review existing <inline-formula><mml:math id="M31" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent metrics for <inline-formula><mml:math id="M32" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> and their underlying methods based on the RF concept. To
our knowledge this is the first review dedicated to the topic since the first <inline-formula><mml:math id="M33" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> metric surfaced 20 years ago. Herein, we compare and
contrast existing metrics both quantitatively and qualitatively, with the main goal of providing added clarity surrounding the context in which the
proposed metrics have (de)merits. We start in Sect. 2 by providing an overview of the methods conventionally applied in the climate metric context for
estimating radiative forcings following <inline-formula><mml:math id="M34" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> emissions and surface albedo change. We then present the reviewed <inline-formula><mml:math id="M35" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> metrics in
Sect. 3 and systematically evaluate them quantitatively in Sect. 4 and qualitatively in Sect. 5. In Sect. 6 we review and evaluate a relatively new
usage of the GWP metric previously unapplied as a <inline-formula><mml:math id="M36" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> metric – termed <inline-formula><mml:math id="M37" display="inline"><mml:mrow><mml:msup><mml:mtext>GWP</mml:mtext><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> – while in Sect. 7 we review the interpretation
challenges of a <inline-formula><mml:math id="M38" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> measure for <inline-formula><mml:math id="M39" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> based on the RF concept. We conclude in Sect. 8 with a discussion about the
limitations and uncertainties of the reviewed metrics, while providing recommendations and guidance for future application.</p>
</sec>
<sec id="Ch1.S2">
  <label>2</label><?xmltex \opttitle{Radiative forcings from {$\protect\chem{CO_{{2}}}$} emissions and surface albedo change}?><title>Radiative forcings from <inline-formula><mml:math id="M40" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> emissions and surface albedo change</title>
      <p id="d1e572">IPCC emission metrics are based on the stratospherically adjusted RF at the tropopause in which the stratosphere is allowed to relax to the
thermal steady state (Myhre et al., 2013; IPCC, 2001). Estimates of the stratospheric RF for <inline-formula><mml:math id="M41" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> (henceforth
<inline-formula><mml:math id="M42" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>) are derived from atmospheric concentration changes imposed in global radiative transfer models (Myhre et al., 1998;
Etminan et al., 2016). For shortwave RFs there is no evidence to suggest that the stratospheric temperature adjusts to a surface albedo
change (at least for land use and land cover change, LULCC; Smith et al., 2020; Hansen et al., 2005; Huang et al. 2020), and thus the instantaneous
shortwave flux change at the top of the atmosphere (TOA) is typically taken as <inline-formula><mml:math id="M43" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, consistent with Myhre et al. (2013).</p>
      <p id="d1e615">One of the major critiques of the instantaneous or stratospherically adjusted RF is that it may be inadequate as a predictor of the climate
response (i.e., changes to near-surface air temperatures, precipitation). The climate may respond differently to different perturbation types
despite similar RF magnitudes – or in other words – feedbacks are not independent of the perturbation type (Hansen et al., 1997; Joshi
et al., 2003). Alternative RF definitions that include tropospheric adjustments (Shine et al., 2003) or even land surface temperature
adjustments (Hansen et al., 2005) have been proposed with the argument that such adjustments are more indicative of the type and magnitude of
feedbacks underlying the climate response (Sherwood et al., 2015; Myhre et al., 2013). These alternatives – referred to as “effective radiative
forcings (ERF)” – may be preferred when they differ notably from the instantaneous or stratospherically adjusted RF, in which
case their use might be preferred in metric calculations. Alternatively, climate “efficacies” can be applied to adjust instantaneous or
stratospherically adjusted RF – where efficacy is defined as the temperature response to some perturbation type relative to that of
<inline-formula><mml:math id="M44" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>. The implications of applying efficacies for spatially heterogenous perturbations like <inline-formula><mml:math id="M45" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> are discussed further in Sect. 7.</p>
<sec id="Ch1.S2.SS1">
  <label>2.1</label><?xmltex \opttitle{{$\protect\chem{CO_{{2}}}$} radiative forcings}?><title><inline-formula><mml:math id="M46" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> radiative forcings</title>
      <p id="d1e657">Simplified expressions for the global mean <inline-formula><mml:math id="M47" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> (in <inline-formula><mml:math id="M48" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>) due to a perturbation to the atmospheric <inline-formula><mml:math id="M49" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>
concentration are based on curve fits of radiative transfer model outputs (Myhre et al., 1998, 2013):
<?xmltex \hack{\newpage}?>
            <disp-formula id="Ch1.E1" content-type="numbered"><label>1</label><mml:math id="M50" display="block"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>C</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mn mathvariant="normal">5.35</mml:mn><mml:mi>ln⁡</mml:mi><mml:mfenced close=")" open="("><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub><mml:mo>+</mml:mo><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>C</mml:mi></mml:mrow><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:mfrac></mml:mstyle></mml:mfenced><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where <inline-formula><mml:math id="M51" display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is the initial concentration and <inline-formula><mml:math id="M52" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>C</mml:mi></mml:mrow></mml:math></inline-formula> is the concentration change. Because of the logarithmic relationship between RF and
<inline-formula><mml:math id="M53" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> concentration, <inline-formula><mml:math id="M54" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>'s radiative efficiency – or the radiative forcing per unit change in concentration over a given background
concentration – decreases with increasing background concentrations. When <inline-formula><mml:math id="M55" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>C</mml:mi></mml:mrow></mml:math></inline-formula> is 1 <inline-formula><mml:math id="M56" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">ppm</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M57" display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is the current concentration, we
may then refer to the solution of Eq. (<xref ref-type="disp-formula" rid="Ch1.E1"/>) as <inline-formula><mml:math id="M58" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>'s current global mean radiative efficiency – or <inline-formula><mml:math id="M59" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>
(in <inline-formula><mml:math id="M60" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">ppm</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>).</p>
      <p id="d1e885">Updates to the <inline-formula><mml:math id="M61" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> function (Eq. <xref ref-type="disp-formula" rid="Ch1.E1"/>) were given in Etminan et al. (2016) where the constant 5.35 (or
<inline-formula><mml:math id="M62" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mo>×</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:mrow></mml:msub><mml:mo>/</mml:mo><mml:mi>ln⁡</mml:mi><mml:mo>[</mml:mo><mml:mn mathvariant="normal">2</mml:mn><mml:mo>]</mml:mo></mml:mrow></mml:math></inline-formula>) was replaced by an explicit function of <inline-formula><mml:math id="M63" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M64" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CH</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, and <inline-formula><mml:math id="M65" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">N</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>
concentrations. However, this update is only important for very large <inline-formula><mml:math id="M66" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> perturbations and is unnecessary to consider for emission metrics
that utilize radiative efficiencies for small perturbations around present-day concentrations (Etminan et al., 2016).</p>
      <p id="d1e982">For emission metrics, it is more convenient to express <inline-formula><mml:math id="M67" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>'s radiative efficiency in terms of a mass-based concentration increase:
            <disp-formula id="Ch1.E2" content-type="numbered"><label>2</label><mml:math id="M68" display="block"><mml:mrow><mml:msub><mml:mi>k</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:msub><mml:mi mathvariant="italic">ε</mml:mi><mml:mtext>air</mml:mtext></mml:msub><mml:msup><mml:mn mathvariant="normal">10</mml:mn><mml:mn mathvariant="normal">6</mml:mn></mml:msup></mml:mrow><mml:mrow><mml:msub><mml:mi mathvariant="italic">ε</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:msub><mml:mi>M</mml:mi><mml:mtext>atm</mml:mtext></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where <inline-formula><mml:math id="M69" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> is the radiative efficiency per 1 <inline-formula><mml:math id="M70" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">ppm</mml:mi></mml:mrow></mml:math></inline-formula> concentration increase, <inline-formula><mml:math id="M71" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ε</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> is the molecular
weight of <inline-formula><mml:math id="M72" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> (44.01 <inline-formula><mml:math id="M73" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">kg</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">kmol</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>), <inline-formula><mml:math id="M74" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ε</mml:mi><mml:mtext>air</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> is the molecular weight of air (28.97 <inline-formula><mml:math id="M75" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">kg</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">kmol</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>), and
<inline-formula><mml:math id="M76" display="inline"><mml:mrow><mml:msub><mml:mi>M</mml:mi><mml:mtext>atm</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> is the mass of the atmosphere (5.14 <inline-formula><mml:math id="M77" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M78" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">18</mml:mn></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M79" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">kg</mml:mi></mml:mrow></mml:math></inline-formula>). The solution of Eq. (<xref ref-type="disp-formula" rid="Ch1.E2"/>) thus yields <inline-formula><mml:math id="M80" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>'s
global mean radiative efficiency with units of <inline-formula><mml:math id="M81" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">kg</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>.</p>
      <p id="d1e1223">The global mean radiative forcing over time following a 1 <inline-formula><mml:math id="M82" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">kg</mml:mi></mml:mrow></mml:math></inline-formula> pulse emission of <inline-formula><mml:math id="M83" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> can be estimated with an impulse response
function describing atmospheric <inline-formula><mml:math id="M84" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> removal in time by Earth's ocean and terrestrial <inline-formula><mml:math id="M85" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> sinks:
            <disp-formula id="Ch1.E3" content-type="numbered"><label>3</label><mml:math id="M86" display="block"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:msub><mml:mi>k</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:munderover><mml:mo movablelimits="false">∫</mml:mo><mml:mrow><mml:mi>t</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow><mml:mi>t</mml:mi></mml:munderover><mml:msub><mml:mi>y</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo><mml:mi mathvariant="normal">d</mml:mi><mml:mi>t</mml:mi><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where <inline-formula><mml:math id="M87" display="inline"><mml:mrow><mml:msub><mml:mi>y</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> is a model describing the decay of <inline-formula><mml:math id="M88" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> in the atmosphere over time. In AR5 <inline-formula><mml:math id="M89" display="inline"><mml:mrow><mml:msub><mml:mi>y</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> is based on the
multi-model mean <inline-formula><mml:math id="M90" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> impulse response function described in Joos et al. (2013) and Myhre et al. (2013) for a <inline-formula><mml:math id="M91" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> background
concentration of 389 <inline-formula><mml:math id="M92" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">ppmv</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M93" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> is the time step, and <inline-formula><mml:math id="M94" display="inline"><mml:mrow><mml:msub><mml:mi>k</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> is the radiative efficiency per kilogram of <inline-formula><mml:math id="M95" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> emitted upon the
same background concentration (i.e., 1.76 <inline-formula><mml:math id="M96" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M97" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">15</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M98" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">kg</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>), which is assumed constant and time-invariant for small
perturbations and for the calculation of emission metrics (Joos et al., 2013; Myhre et al., 2013). The pulse response function (<inline-formula><mml:math id="M99" display="inline"><mml:mrow><mml:msub><mml:mi>y</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>)
comprises four carbon pools representing the combined effect of several carbon cycle mechanisms rather than directly corresponding to individual
physical processes. Although considered ideal for metric calculations in IPCC AR5, state-dependent alternatives exist in which the carbon cycle
response is affected by rising temperature or <inline-formula><mml:math id="M100" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> accumulation in the atmosphere (Millar et al., 2017).</p>
      <p id="d1e1511">For an emission (or removal) scenario, <inline-formula><mml:math id="M101" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> is estimated from changes to atmospheric <inline-formula><mml:math id="M102" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> abundance computed as a
convolution integral between emissions (or removals) and the <inline-formula><mml:math id="M103" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> impulse response function:
            <disp-formula id="Ch1.E4" content-type="numbered"><label>4</label><mml:math id="M104" display="block"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:msub><mml:mi>k</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:munderover><mml:mo movablelimits="false">∫</mml:mo><mml:mrow><mml:msup><mml:mi>t</mml:mi><mml:mo>′</mml:mo></mml:msup><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow><mml:mi>t</mml:mi></mml:munderover><mml:mi>e</mml:mi><mml:mo>(</mml:mo><mml:msup><mml:mi>t</mml:mi><mml:mo>′</mml:mo></mml:msup><mml:mo>)</mml:mo><mml:msub><mml:mi>y</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>-</mml:mo><mml:msup><mml:mi>t</mml:mi><mml:mo>′</mml:mo></mml:msup><mml:mo>)</mml:mo><mml:mi mathvariant="normal">d</mml:mi><mml:msup><mml:mi>t</mml:mi><mml:mo>′</mml:mo></mml:msup><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where <inline-formula><mml:math id="M105" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> is the time dimension, <inline-formula><mml:math id="M106" display="inline"><mml:mrow><mml:msup><mml:mi>t</mml:mi><mml:mo>′</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> is the integration variable, and <inline-formula><mml:math id="M107" display="inline"><mml:mrow><mml:mi>e</mml:mi><mml:mo>(</mml:mo><mml:msup><mml:mi>t</mml:mi><mml:mo>′</mml:mo></mml:msup><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> is the <inline-formula><mml:math id="M108" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> emission (or removal) rate (in kilograms).</p>
</sec>
<sec id="Ch1.S2.SS2">
  <label>2.2</label><title>Shortwave radiative forcings from surface albedo change</title>
      <p id="d1e1703">The time step of Eq. (<xref ref-type="disp-formula" rid="Ch1.E3"/>) is typically 1 year; thus it is convenient to utilize an annually averaged <inline-formula><mml:math id="M109" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> when deriving
a <inline-formula><mml:math id="M110" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent metric. Given the asymmetry between solar irradiance and the seasonal cycle of surface albedo in many extra-tropical
regions, a more precise estimate of the annual <inline-formula><mml:math id="M111" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> is one based on the monthly (or even daily) <inline-formula><mml:math id="M112" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> (Bernier et al.,
2011).</p>
      <p id="d1e1757">The local annual mean instantaneous <inline-formula><mml:math id="M113" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> (in <inline-formula><mml:math id="M114" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>) following monthly surface albedo changes (unitless) can be
estimated with radiative kernels derived from global climate models (e.g., Soden et al., 2008; Pendergrass et al., 2018; Block and Mauritsen, 2014;
Smith et al., 2018), although it should be pointed out that kernels are model- and state-dependent. Bright and O'Halloran (2019) recently presented
a simplified <inline-formula><mml:math id="M115" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> model allowing greater flexibility surrounding the prescribed atmospheric state, given as
            <disp-formula id="Ch1.E5" content-type="numbered"><label>5</label><mml:math id="M116" display="block"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mn mathvariant="normal">12</mml:mn></mml:mfrac></mml:mstyle><mml:msubsup><mml:mo>∑</mml:mo><mml:mrow><mml:mi>m</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow><mml:mn mathvariant="normal">12</mml:mn></mml:msubsup><mml:mo>-</mml:mo><mml:msubsup><mml:mtext>SW</mml:mtext><mml:mrow><mml:mo>↓</mml:mo><mml:mo>,</mml:mo><mml:mi>m</mml:mi><mml:mo>,</mml:mo><mml:mi>t</mml:mi></mml:mrow><mml:mtext>sfc</mml:mtext></mml:msubsup><mml:msqrt><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mrow><mml:mi>m</mml:mi><mml:mo>,</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:msqrt><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mrow><mml:mi>m</mml:mi><mml:mo>,</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:msub><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
          where <inline-formula><mml:math id="M117" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mrow><mml:mi>m</mml:mi><mml:mo>,</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> is a surface albedo change in month <inline-formula><mml:math id="M118" display="inline"><mml:mi>m</mml:mi></mml:math></inline-formula> and year <inline-formula><mml:math id="M119" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M120" display="inline"><mml:mrow><mml:msubsup><mml:mtext>SW</mml:mtext><mml:mo>↓</mml:mo><mml:mtext>sfc</mml:mtext></mml:msubsup></mml:mrow></mml:math></inline-formula> is the incoming solar radiation
flux incident at surface level in month <inline-formula><mml:math id="M121" display="inline"><mml:mi>m</mml:mi></mml:math></inline-formula> and year <inline-formula><mml:math id="M122" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula>, and <inline-formula><mml:math id="M123" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mrow><mml:mi>m</mml:mi><mml:mo>,</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> is the all-sky monthly mean clearness index (or
<inline-formula><mml:math id="M124" display="inline"><mml:mrow><mml:msubsup><mml:mtext>SW</mml:mtext><mml:mo>↓</mml:mo><mml:mtext>sfc</mml:mtext></mml:msubsup><mml:mo>/</mml:mo><mml:msubsup><mml:mtext>SW</mml:mtext><mml:mo>↓</mml:mo><mml:mtext>toa</mml:mtext></mml:msubsup></mml:mrow></mml:math></inline-formula>; unitless) in month <inline-formula><mml:math id="M125" display="inline"><mml:mi>m</mml:mi></mml:math></inline-formula> and year <inline-formula><mml:math id="M126" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula>.</p>
      <p id="d1e2003">It is important to reiterate that the <inline-formula><mml:math id="M127" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> defined with either Eq. (<xref ref-type="disp-formula" rid="Ch1.E5"/>) or kernels based on global climate models (GCMs) strictly represents the
instantaneous shortwave flux change at TOA and is not directly comparable to other definitions of RF based on net (downward) radiative flux
changes at TOA following atmospheric adjustments. A perturbation to <inline-formula><mml:math id="M128" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> will result in a modification to the turbulent heat fluxes, leading
to radiative adjustments in the troposphere (Laguë et al., 2019; Huang et al., 2020; Chen and Dirmeyer, 2020). However, in the context of emission
metrics, both <inline-formula><mml:math id="M129" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M130" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> have merit given that they do not require coupled climate model runs of
several years to compute.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1" specific-use="star"><?xmltex \currentcnt{1}?><label>Table 1</label><caption><p id="d1e2065">Studies included in this review.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="3">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="justify" colwidth="15mm"/>
     <oasis:colspec colnum="3" colname="col3" align="left"/>
     <oasis:thead>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Study</oasis:entry>
         <oasis:entry colname="col2">Metric</oasis:entry>
         <oasis:entry colname="col3">Notes</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">Betts (2000)</oasis:entry>
         <oasis:entry colname="col2">EESF</oasis:entry>
         <oasis:entry colname="col3">AF <inline-formula><mml:math id="M134" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.5</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Akbari et al. (2009)</oasis:entry>
         <oasis:entry colname="col2">EESF</oasis:entry>
         <oasis:entry colname="col3">AF <inline-formula><mml:math id="M135" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.55</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Montenegro et al. (2009)</oasis:entry>
         <oasis:entry colname="col2">EESF</oasis:entry>
         <oasis:entry colname="col3">AF <inline-formula><mml:math id="M136" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.5</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Thompson et al. (2009a)</oasis:entry>
         <oasis:entry colname="col2">EESF</oasis:entry>
         <oasis:entry colname="col3">AF <inline-formula><mml:math id="M137" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.5</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Thompson et al. (2009b)</oasis:entry>
         <oasis:entry colname="col2">EESF</oasis:entry>
         <oasis:entry colname="col3">AF <inline-formula><mml:math id="M138" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.5</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Muñoz et al. (2010)</oasis:entry>
         <oasis:entry colname="col2">EESF</oasis:entry>
         <oasis:entry colname="col3">AF based on C-cycle model and TH <inline-formula><mml:math id="M139" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 20, 100, and 500 years</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Menon et al. (2010)</oasis:entry>
         <oasis:entry colname="col2">EESF</oasis:entry>
         <oasis:entry colname="col3">AF <inline-formula><mml:math id="M140" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.55</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Georgscu et al. (2011)</oasis:entry>
         <oasis:entry colname="col2">EESF</oasis:entry>
         <oasis:entry colname="col3">AF <inline-formula><mml:math id="M141" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.50</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Cherubini et al. (2012)</oasis:entry>
         <oasis:entry colname="col2">GWP</oasis:entry>
         <oasis:entry colname="col3">Based on effective RF estimated with a climate efficacy of 1.94<inline-formula><mml:math id="M142" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">b</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Bright et al. (2012)</oasis:entry>
         <oasis:entry colname="col2">GWP</oasis:entry>
         <oasis:entry colname="col3">TH <inline-formula><mml:math id="M143" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 20; 100; 500 years.</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Susca, T. (2012b)</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M144" display="inline"><mml:mo>∑</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M145" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M146" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">a</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Susca, T. (2012a)</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M147" display="inline"><mml:mo>∑</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M148" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M149" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">a</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Guest et al. (2013)</oasis:entry>
         <oasis:entry colname="col2">GWP</oasis:entry>
         <oasis:entry colname="col3"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Zhao and Jackson (2014)</oasis:entry>
         <oasis:entry colname="col2">EESF</oasis:entry>
         <oasis:entry colname="col3">AF <inline-formula><mml:math id="M150" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.5; Based on effective RF estimated with a climate efficacy of 0.52<inline-formula><mml:math id="M151" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Caiazzo et al. (2014)</oasis:entry>
         <oasis:entry colname="col2">EESF</oasis:entry>
         <oasis:entry colname="col3">AF based on C-cycle model and TH <inline-formula><mml:math id="M152" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 100 years</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Singh et al. (2014)</oasis:entry>
         <oasis:entry colname="col2">GWP</oasis:entry>
         <oasis:entry colname="col3">TH <inline-formula><mml:math id="M153" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 100 years</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Bright et al. (2016)</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M154" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula>; <inline-formula><mml:math id="M155" display="inline"><mml:mrow><mml:mo>∑</mml:mo><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Mykleby et al. (2017)</oasis:entry>
         <oasis:entry colname="col2">EESF</oasis:entry>
         <oasis:entry colname="col3">AF based on C-cycle model and TH <inline-formula><mml:math id="M156" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 80 years</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Fortier et al. (2017)</oasis:entry>
         <oasis:entry colname="col2">EESF</oasis:entry>
         <oasis:entry colname="col3">AF based on C-cycle model and TH <inline-formula><mml:math id="M157" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 100 years</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Carrer et al. (2018)</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M158" display="inline"><mml:mrow><mml:mtext>EESF</mml:mtext><mml:mo>/</mml:mo><mml:mtext>TH</mml:mtext></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">AF based on C-cycle model and TH <inline-formula><mml:math id="M159" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 100 years</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Carrer et al. (2018)</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M160" display="inline"><mml:mrow><mml:mtext>GWP</mml:mtext><mml:mo>/</mml:mo><mml:mtext>TH</mml:mtext></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">TH <inline-formula><mml:math id="M161" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 100 years</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Favero et al. (2018)</oasis:entry>
         <oasis:entry colname="col2">EESF</oasis:entry>
         <oasis:entry colname="col3">AF based on C-cycle model and TH <inline-formula><mml:math id="M162" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 100 years</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Sieber et al. (2019)</oasis:entry>
         <oasis:entry colname="col2">GWP</oasis:entry>
         <oasis:entry colname="col3">TH <inline-formula><mml:math id="M163" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 100 years</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Sieber et al. (2020)</oasis:entry>
         <oasis:entry colname="col2">GWP</oasis:entry>
         <oasis:entry colname="col3">TH <inline-formula><mml:math id="M164" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 100 years</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Genesio et al. (2020)</oasis:entry>
         <oasis:entry colname="col2">EESF</oasis:entry>
         <oasis:entry colname="col3">AF <inline-formula><mml:math id="M165" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.47</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Sciusco et al. (2020)</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M166" display="inline"><mml:mrow><mml:mtext>EESF</mml:mtext><mml:mo>/</mml:mo><mml:mtext>TH</mml:mtext></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">AF based on C-cycle model and TH <inline-formula><mml:math id="M167" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 100 years</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Bright et al. (2020)</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M168" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula>; <inline-formula><mml:math id="M169" display="inline"><mml:mrow><mml:mo>∑</mml:mo><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Lugato et al. (2020)</oasis:entry>
         <oasis:entry colname="col2">GWP</oasis:entry>
         <oasis:entry colname="col3">TH <inline-formula><mml:math id="M170" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 84 years</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table><table-wrap-foot><p id="d1e2068"><inline-formula><mml:math id="M131" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">a</mml:mi></mml:msup></mml:math></inline-formula> Referred to as “time-dependent emission”. <inline-formula><mml:math id="M132" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">b</mml:mi></mml:msup></mml:math></inline-formula> From idealized climate model simulations of Arctic snow albedo change (Bellouin and Boucher, 2010). <inline-formula><mml:math id="M133" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">c</mml:mi></mml:msup></mml:math></inline-formula> From idealized climate model simulations of global LULCC (Davin et al., 2007).</p></table-wrap-foot></table-wrap>

</sec>
</sec>
<sec id="Ch1.S3">
  <label>3</label><?xmltex \opttitle{Overview of {$\protect\chem{CO_{{2}}}$}-equivalent metrics for $\mathbf{R}\mathbf{F}_{{\mathbf{\Delta\alpha}}}$}?><title>Overview of <inline-formula><mml:math id="M171" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent metrics for <inline-formula><mml:math id="M172" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="bold">RF</mml:mi><mml:mrow><mml:mi mathvariant="bold">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula></title>
      <p id="d1e2807">Over the past 20 years, a variety of metrics and their permutations have been employed to express <inline-formula><mml:math id="M173" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> as
<inline-formula><mml:math id="M174" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> equivalence, as evidenced from the 27 studies included in this review (Table 1).</p>
      <p id="d1e2835">Chiefly differentiating the methods behind the metrics shown in Table 1 – described henceforth – is how time is represented with respect to both the
<inline-formula><mml:math id="M175" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> and the reference gas (i.e., <inline-formula><mml:math id="M176" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>) perturbations. Among the most common approaches is to relate <inline-formula><mml:math id="M177" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> to
the RF following a <inline-formula><mml:math id="M178" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> emission imposed on some atmospheric <inline-formula><mml:math id="M179" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> concentration background, but with a fraction of the
emission instantaneously removed by Earth's ocean and terrestrial <inline-formula><mml:math id="M180" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> sinks by an amount defined by 1 minus the so-called “airborne
fraction” (AF) – or the growth in atmospheric <inline-formula><mml:math id="M181" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> relative to anthropogenic <inline-formula><mml:math id="M182" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> emissions (Forster et al., 2007).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1" specific-use="star"><?xmltex \currentcnt{1}?><?xmltex \def\figurename{Figure}?><label>Figure 1</label><caption><p id="d1e2931">The 1959–2018 airborne fraction (AF), defined here as the growth in atmospheric <inline-formula><mml:math id="M183" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> – or the atmospheric <inline-formula><mml:math id="M184" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> remaining after removals by ocean and terrestrial sinks – relative to anthropogenic <inline-formula><mml:math id="M185" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> emissions (fossil fuels and LULCC). “Uncertainty” is defined as AF <inline-formula><mml:math id="M186" display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M187" display="inline"><mml:mi mathvariant="normal">|</mml:mi></mml:math></inline-formula> BI <inline-formula><mml:math id="M188" display="inline"><mml:mrow><mml:mi mathvariant="normal">|</mml:mi><mml:mo>/</mml:mo><mml:mi>E</mml:mi></mml:mrow></mml:math></inline-formula>, where <inline-formula><mml:math id="M189" display="inline"><mml:mi>E</mml:mi></mml:math></inline-formula> is total anthropogenic <inline-formula><mml:math id="M190" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> emissions and BI is the budget imbalance – or <inline-formula><mml:math id="M191" display="inline"><mml:mi>E</mml:mi></mml:math></inline-formula> minus the sum of atmospheric <inline-formula><mml:math id="M192" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> growth and <inline-formula><mml:math id="M193" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> sinks. Underlying data are from the Global Carbon Project (Friedlingstein et al., 2019).</p></caption>
        <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://acp.copernicus.org/articles/21/9887/2021/acp-21-9887-2021-f01.png"/>

      </fig>

      <p id="d1e3048">This method – or the “emissions equivalent of shortwave forcing (EESF)” – was first introduced by Betts (2000) and may be expressed
(in <inline-formula><mml:math id="M194" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">kg</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>) as
          <disp-formula id="Ch1.E6" content-type="numbered"><label>6</label><mml:math id="M195" display="block"><mml:mrow><mml:mtext>EESF</mml:mtext><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:msub><mml:mi>k</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:msub><mml:mi>A</mml:mi><mml:mi mathvariant="normal">E</mml:mi></mml:msub><mml:mtext>AF</mml:mtext></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
        where <inline-formula><mml:math id="M196" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> is the local annual mean instantaneous RF from a monthly <inline-formula><mml:math id="M197" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> scenario
(in <inline-formula><mml:math id="M198" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>), <inline-formula><mml:math id="M199" display="inline"><mml:mrow><mml:msub><mml:mi>k</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> is the global mean radiative efficiency of <inline-formula><mml:math id="M200" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> (e.g., Eq. <xref ref-type="disp-formula" rid="Ch1.E2"/>;
in <inline-formula><mml:math id="M201" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">kg</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>), <inline-formula><mml:math id="M202" display="inline"><mml:mrow><mml:msub><mml:mi>A</mml:mi><mml:mi mathvariant="normal">E</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is Earth's surface area (5.1 <inline-formula><mml:math id="M203" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M204" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">14</mml:mn></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M205" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula>), and AF is the airborne
fraction. Because AF appears in the denominator in Eq. (<xref ref-type="disp-formula" rid="Ch1.E6"/>), the <inline-formula><mml:math id="M206" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent estimate will be highly sensitive to the
choice of AF. Figure 1 plots AF since 1959 which, as can be seen, can fluctuate considerably over short time periods, ranging from a
high of 0.81 in 1987 to a low of 0.20 in 1992.</p>
      <p id="d1e3268">More importantly, use of AF in Eq. (<xref ref-type="disp-formula" rid="Ch1.E6"/>) means that time-dependent atmospheric <inline-formula><mml:math id="M207" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> removal processes following emissions are
not explicitly represented. However, using the AF may be justifiable in some contexts – such as when <inline-formula><mml:math id="M208" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> has no time dependency
(on inter-annual scales). For example, the pioneering study by Betts (2000) – to which almost all <inline-formula><mml:math id="M209" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> literature for <inline-formula><mml:math id="M210" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> may
be traced (Table 1) – made use of AF when estimating <inline-formula><mml:math id="M211" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> equivalence of <inline-formula><mml:math id="M212" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> because the research objective
was to compare an albedo contrast between a fully grown forest and a cropland (i.e, <inline-formula><mml:math id="M213" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>) to the stock of <inline-formula><mml:math id="M214" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> in the forest – a
stock that had been assumed to accumulate over 80 years, which is the approximate time frame over which Earth's <inline-formula><mml:math id="M215" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> sinks function to
remove atmospheric <inline-formula><mml:math id="M216" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> to a level conveniently represented by the chosen AF. Had a transient or interannual <inline-formula><mml:math id="M217" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> scenario
been modeled, however, applying the EESF method at each time step of the scenario would have severely overestimated <inline-formula><mml:math id="M218" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent
emissions.</p>
      <p id="d1e3412">For this reason, Bright et al. (2016) argued that for time-dependent <inline-formula><mml:math id="M219" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> scenarios (i.e., when <inline-formula><mml:math id="M220" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> evolves over interannual timescales), the time dependency of <inline-formula><mml:math id="M221" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> removal processes (atmospheric decay) following emissions should be taken explicitly into account when
estimating the effect characterized in terms of <inline-formula><mml:math id="M222" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent emissions (or removals), thus proposing an alternate metric termed
“time-dependent emissions equivalence” – or <inline-formula><mml:math id="M223" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula>:
          <disp-formula id="Ch1.E7" content-type="numbered"><label>7</label><mml:math id="M224" display="block"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mo>=</mml:mo><mml:msubsup><mml:mi>A</mml:mi><mml:mi mathvariant="normal">E</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msubsup><mml:msubsup><mml:mi>k</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msubsup><mml:msubsup><mml:mi mathvariant="bold">Y</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msubsup><mml:mi mathvariant="bold-italic">R</mml:mi><mml:msubsup><mml:mi mathvariant="bold-italic">F</mml:mi><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow><mml:mo>∗</mml:mo></mml:msubsup><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
        where <inline-formula><mml:math id="M225" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> is a column vector of <inline-formula><mml:math id="M226" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent emission (or removal) pulses (i.e., one-offs) with length defined by the number of time steps (e.g., years)
included in the <inline-formula><mml:math id="M227" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> time series (in <inline-formula><mml:math id="M228" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">kg</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">yr</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>), <inline-formula><mml:math id="M229" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">R</mml:mi><mml:msubsup><mml:mi mathvariant="bold-italic">F</mml:mi><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow><mml:mo>∗</mml:mo></mml:msubsup></mml:mrow></mml:math></inline-formula> is a column vector of the
local annual mean instantaneous <inline-formula><mml:math id="M230" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> (in <inline-formula><mml:math id="M231" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>) corresponding to the <inline-formula><mml:math id="M232" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> time series (or
<inline-formula><mml:math id="M233" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>), and <inline-formula><mml:math id="M234" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="bold">Y</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> is a lower triangular matrix with column (row) elements being the atmospheric
<inline-formula><mml:math id="M235" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> fraction decreasing (increasing) with time (i.e., <inline-formula><mml:math id="M236" display="inline"><mml:mrow><mml:msub><mml:mi>y</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>). The elements in vector <inline-formula><mml:math id="M237" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> thus give the
<inline-formula><mml:math id="M238" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent series of emission (or removal) pulses in time yielding the instantaneous <inline-formula><mml:math id="M239" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> time profile
(<inline-formula><mml:math id="M240" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>) corresponding to the temporally explicit <inline-formula><mml:math id="M241" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> scenario (<inline-formula><mml:math id="M242" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>). Summing all elements in
<inline-formula><mml:math id="M243" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> (i.e., <inline-formula><mml:math id="M244" display="inline"><mml:mrow><mml:mo>∑</mml:mo><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula>) gives a measure of the accumulated <inline-formula><mml:math id="M245" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> emissions (removals) over time. The <inline-formula><mml:math id="M246" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> approach
is conceptually similar to the <inline-formula><mml:math id="M247" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-forcing-equivalence (<inline-formula><mml:math id="M248" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-fe) approach (Jenkins et al., 2018; Zickfeld et al., 2009)
building on the notion of a “forcing equivalent” index (Wigley, 1998).</p>
      <p id="d1e3911">Time-dependent metrics like the well-known global warming potential (GWP) (Shine et al., 1990; Rogers and Stephens, 1988) have also been
applied to characterize <inline-formula><mml:math id="M249" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, which accumulates <inline-formula><mml:math id="M250" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> over time (temporally discretized) up to some policy or
metric time horizon (TH), which is then normalized to the temporally accumulated radiative forcing following a unit pulse <inline-formula><mml:math id="M251" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>
emission over the same TH:
          <disp-formula id="Ch1.E8" content-type="numbered"><label>8</label><mml:math id="M252" display="block"><mml:mrow><mml:msub><mml:mtext>GWP</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>T</mml:mi><mml:mi>H</mml:mi><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msubsup><mml:mo>∑</mml:mo><mml:mn mathvariant="normal">0</mml:mn><mml:mrow><mml:mi>t</mml:mi><mml:mo>=</mml:mo><mml:mtext>TH</mml:mtext></mml:mrow></mml:msubsup><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mrow><mml:msub><mml:mi>A</mml:mi><mml:mi mathvariant="normal">E</mml:mi></mml:msub><mml:msub><mml:mi>k</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:msubsup><mml:mo>∑</mml:mo><mml:mn mathvariant="normal">0</mml:mn><mml:mrow><mml:mi>t</mml:mi><mml:mo>=</mml:mo><mml:mtext>TH</mml:mtext></mml:mrow></mml:msubsup><mml:msub><mml:mi>y</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
        where TH is the temporal accumulation or metric time horizon. Because it is a cumulative measure, studies making use of GWP often
divide by the number of time steps (TH) to approximate an annual <inline-formula><mml:math id="M253" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> flux (e.g., Carrer et al., 2018). The result of
Eq. (<xref ref-type="disp-formula" rid="Ch1.E8"/>) can be interpreted as an equivalent pulse of <inline-formula><mml:math id="M254" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> (in <inline-formula><mml:math id="M255" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">kg</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>) at <inline-formula><mml:math id="M256" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M257" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0 giving the same
time-integrated RF at TH as that following a 1 <inline-formula><mml:math id="M258" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">kg</mml:mi></mml:mrow></mml:math></inline-formula> pulse of <inline-formula><mml:math id="M259" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>.</p>
<sec id="Ch1.S3.SS1">
  <label>3.1</label><title>Metric permutations</title>
      <p id="d1e4153">Some studies have applied various permutations of the three metrics presented above. For instance, some have applied definitions of the airborne
fraction (AF) based on <inline-formula><mml:math id="M260" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>'s pulse response function (i.e., <inline-formula><mml:math id="M261" display="inline"><mml:mrow><mml:msub><mml:mi>y</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>) when estimating EESF on the grounds
that the analysis required a long and forward-looking time perspective (Caiazzo et al., 2014; Favero et al., 2018; Mykleby et al., 2017; Muñoz
et al., 2010; Sciusco et al., 2020). A consequence is that the magnitude of the <inline-formula><mml:math id="M262" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> calculation is highly sensitive to the subjective
choice of the TH chosen as the basis for the AF (typically taken as the mean atmospheric fraction for the period up to
TH – or <inline-formula><mml:math id="M263" display="inline"><mml:mrow><mml:msup><mml:mtext>TH</mml:mtext><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:msubsup><mml:mo>∫</mml:mo><mml:mrow><mml:mi>t</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow><mml:mrow><mml:mi>t</mml:mi><mml:mo>=</mml:mo><mml:mtext>TH</mml:mtext></mml:mrow></mml:msubsup><mml:msub><mml:mi>y</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo><mml:mi mathvariant="normal">d</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:math></inline-formula>). Other permutations include the normalization of
EESF or GWP(TH) by TH to arrive at a uniform time series of <inline-formula><mml:math id="M264" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> pulses (Carrer et al., 2018) or the summing
of <inline-formula><mml:math id="M265" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> up to TH to obtain a <inline-formula><mml:math id="M266" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> stock perturbation measure (Bright et al., 2020, 2016).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2"><?xmltex \currentcnt{2}?><?xmltex \def\figurename{Figure}?><label>Figure 2</label><caption><p id="d1e4306">Decision tree for <inline-formula><mml:math id="M267" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> metrics applied in the literature included in this review.</p></caption>
          <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://acp.copernicus.org/articles/21/9887/2021/acp-21-9887-2021-f02.png"/>

        </fig>

</sec>
<sec id="Ch1.S3.SS2">
  <label>3.2</label><title>Metric decision tree</title>
      <p id="d1e4333">Their relative merits and drawbacks (further discussed in Sects. 4 and 5) notwithstanding, Fig. 2 presents a decision tree for differentiating between
the reviewed <inline-formula><mml:math id="M268" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> metrics presented heretofore.</p>
      <p id="d1e4346">A principle differentiator after the time-dependency distinction is whether <inline-formula><mml:math id="M269" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> equivalence corresponds to a single emission (removal) pulse
or a time series of multiple <inline-formula><mml:math id="M270" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent emission (removal) pulses. For the time-dependent metrics (Fig. 2, right branch), further
distinction can be made according to whether the <inline-formula><mml:math id="M271" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent effect is an instantaneous effect (in the case of the time series measures)
and whether IPCC compatibility is desired by the practitioner (in the case of the single pulse measures). By “IPCC compatibility”, we mean that the
metric computation and physical interpretation align with emission metrics presented in previous IPCC climate assessment reports and IPCC good
practice guidelines for national emission inventory reporting. A second or alternate distinction can be made for the time-dependent and single pulse
measures according to whether the <inline-formula><mml:math id="M272" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent effect corresponds to the present (<inline-formula><mml:math id="M273" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M274" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0) or the future (<inline-formula><mml:math id="M275" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M276" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> TH).</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T2" specific-use="star"><?xmltex \currentcnt{2}?><label>Table 2</label><caption><p id="d1e4425">Important decisions required by the practitioner to obtain a <inline-formula><mml:math id="M277" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> metric for <inline-formula><mml:math id="M278" display="inline"><mml:mrow><mml:mi mathvariant="bold">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> (based on RF) relative to conventional <inline-formula><mml:math id="M279" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-normalized emission metrics of the IPCC (i.e., GWP).</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="5">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:colspec colnum="3" colname="col3" align="justify" colwidth="25mm"/>
     <oasis:colspec colnum="4" colname="col4" align="justify" colwidth="22mm"/>
     <oasis:colspec colnum="5" colname="col5" align="left"/>
     <oasis:thead>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Radiative forcing agent</oasis:entry>
         <oasis:entry colname="col2">RF metric</oasis:entry>
         <oasis:entry colname="col3">Initial perturbation<?xmltex \hack{\hfill\break}?>(emission or <inline-formula><mml:math id="M280" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>)</oasis:entry>
         <oasis:entry colname="col4">Perturbation<?xmltex \hack{\hfill\break}?>time dependency</oasis:entry>
         <oasis:entry colname="col5">RF model</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">GWP</oasis:entry>
         <oasis:entry colname="col2">Unit pulse</oasis:entry>
         <oasis:entry colname="col3">IPCC</oasis:entry>
         <oasis:entry colname="col4">IPCC</oasis:entry>
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M281" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>, time-dependent</oasis:entry>
         <oasis:entry colname="col2">TDEE; GWP</oasis:entry>
         <oasis:entry colname="col3">User defined</oasis:entry>
         <oasis:entry colname="col4">User defined</oasis:entry>
         <oasis:entry colname="col5">User defined</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M282" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>, time-independent</oasis:entry>
         <oasis:entry colname="col2">EESF</oasis:entry>
         <oasis:entry colname="col3">User defined</oasis:entry>
         <oasis:entry colname="col4">None</oasis:entry>
         <oasis:entry colname="col5">User defined</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

</sec>
<sec id="Ch1.S3.SS3">
  <label>3.3</label><?xmltex \opttitle{$\Delta\alpha$ vs. emission metrics}?><title><inline-formula><mml:math id="M283" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> vs. emission metrics</title>
      <p id="d1e4610">All metric application entails subjective user decisions, such as type of metric (i.e., instantaneous vs. accumulative; scalar vs. time series) and
time horizon for impact evaluation. <inline-formula><mml:math id="M284" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> metrics for <inline-formula><mml:math id="M285" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> require additional decisions by the practitioner affecting both their
transparency and uncertainty, which are highlighted in Table 2.</p>
      <p id="d1e4640">First among these is the need to quantify the initial physical perturbation (i.e., <inline-formula><mml:math id="M286" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>), which is irrelevant for IPCC emission metrics where
the initial perturbation is a unit pulse emission. For <inline-formula><mml:math id="M287" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> metrics, uncertainty surrounding estimates of the initial (or reference) and
perturbed albedo states is introduced. Second, for the time-dependent metrics (Table 2, second row) additional uncertainty is
introduced by the metric practitioner when defining the time dependency of the <inline-formula><mml:math id="M288" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> perturbation, which may be contrasted to IPCC emission
metrics where the temporal evolution of the perturbation (i.e., atmospheric concentration change) is predefined (or rather, lifetimes and decay
functions of the various forcing agents). Likewise, the RF models employed to give radiative efficiencies for various forcing agents are
predefined by the IPCC – models having origins linked to standardized experiments employing rigorously evaluated radiative transfer and/or climate
models, which may be contrasted to the models applied to estimate <inline-formula><mml:math id="M289" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, which can vary widely in their complexity and uncertainty
(for a brief review of these, see Bright and O'Halloran, 2019).</p>
</sec>
</sec>
<sec id="Ch1.S4">
  <label>4</label><title>Quantitative metric evaluation</title>
      <p id="d1e4696">The metrics presented in Sect. 3 are systematically compared quantitatively henceforth by deriving them for a set of common cases, starting first with
the metrics applied to yield a series of <inline-formula><mml:math id="M290" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> pulse emissions (or removals) in time. For all calculations, the assumed climate
“efficacy” (Hansen et al., 2005) – or the global climate sensitivity of <inline-formula><mml:math id="M291" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> relative to <inline-formula><mml:math id="M292" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> – is 1.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3" specific-use="star"><?xmltex \currentcnt{3}?><?xmltex \def\figurename{Figure}?><label>Figure 3</label><caption><p id="d1e4747">Example application of metrics yielding a complete time series of <inline-formula><mml:math id="M293" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> pulse emissions or removals. <bold>(a)</bold> Time-dependent local <inline-formula><mml:math id="M294" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> scenario (“<inline-formula><mml:math id="M295" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>” <inline-formula><mml:math id="M296" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M297" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mtext>new</mml:mtext></mml:msub><mml:mo>-</mml:mo><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mtext>old</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>). <bold>(b)</bold> The corresponding local annual mean instantaneous shortwave radiative forcing over time (<inline-formula><mml:math id="M298" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>). <bold>(c)</bold> The derived metrics <inline-formula><mml:math id="M299" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula>, GWP(100) <inline-formula><mml:math id="M300" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> 100, and EESF <inline-formula><mml:math id="M301" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> 100 for a range of airborne fractions (AF). <bold>(d)</bold> The reconstructed local annual mean <inline-formula><mml:math id="M302" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> based on the values shown in panel <bold>(c)</bold> and Eq. (<xref ref-type="disp-formula" rid="Ch1.E4"/>). Note that the legend in panel <bold>(d)</bold> also applies to panel <bold>(c)</bold>.</p></caption>
        <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://acp.copernicus.org/articles/21/9887/2021/acp-21-9887-2021-f03.png"/>

      </fig>

<sec id="Ch1.S4.SS1">
  <label>4.1</label><?xmltex \opttitle{{$\protect\chem{CO_{{2}}\text{-}eq.}$} pulse time series measures}?><title><inline-formula><mml:math id="M303" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> pulse time series measures</title>
      <p id="d1e4936">Let us first consider a geoengineering case where 1 <inline-formula><mml:math id="M304" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> of a rooftop is painted white during the first year of a 100-year simulation, which
increases the annual mean surface albedo (Fig. 3a) for the full simulation period, resulting in a constant negative <inline-formula><mml:math id="M305" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>
(Fig. 3b). The objective is to estimate a series of <inline-formula><mml:math id="M306" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> fluxes associated with the local <inline-formula><mml:math id="M307" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>.</p>
      <p id="d1e5001">Figure 3c presents the results after applying the relevant metrics to the common <inline-formula><mml:math id="M308" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> and time-dependent <inline-formula><mml:math id="M309" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>
scenario. To assess their fidelity or “accuracy”, the resulting <inline-formula><mml:math id="M310" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> series of annual <inline-formula><mml:math id="M311" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> pulses (in this case removals) are
used with Eq. (<xref ref-type="disp-formula" rid="Ch1.E4"/>) to re-construct the <inline-formula><mml:math id="M312" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> time profile (Fig. 3b). Unsurprisingly, annual <inline-formula><mml:math id="M313" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> removals
estimated with the <inline-formula><mml:math id="M314" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> approach (Fig. 3c) reproduce <inline-formula><mml:math id="M315" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> exactly, and thus the two red curves shown in Fig. 3b and d
are identical (note the difference in scale). Figure 3c illustrates the sensitivity of the EESF-based measure derived using an AF of
0.47 (mean of the last 7 years based on the most recent global carbon budget; e.g., Friedlingstein et al., 2019; Fig. 1) relative to a broad range
of AF values (note that the result obtained using AF <inline-formula><mml:math id="M316" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 1 is referred to as the time-independent emissions equivalent
(TIEE) presented in Bright et al., 2016). Irrespective of the AF value that is chosen, when applied in a forward-looking analysis
utilizing a time-dependent <inline-formula><mml:math id="M317" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> scenario with a time horizon of 100 years, the EESF approach underestimates the magnitude of the
annual <inline-formula><mml:math id="M318" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> pulse occurring in the short term relative to <inline-formula><mml:math id="M319" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> (Fig. 3c) and hence also <inline-formula><mml:math id="M320" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> in the
short term (Fig. 3b and d). This is because the <inline-formula><mml:math id="M321" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> forcing represented as <inline-formula><mml:math id="M322" display="inline"><mml:mrow><mml:msup><mml:mtext>TH</mml:mtext><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:msub><mml:mi>k</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:mtext>AF</mml:mtext></mml:mrow></mml:math></inline-formula> with the
EESF approach is weaker than the <inline-formula><mml:math id="M323" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> forcing represented as <inline-formula><mml:math id="M324" display="inline"><mml:mrow><mml:msub><mml:mi>k</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:msubsup><mml:mo>∑</mml:mo><mml:mrow><mml:mi>t</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow><mml:mrow><mml:mi>t</mml:mi><mml:mo>=</mml:mo><mml:mtext>TH</mml:mtext></mml:mrow></mml:msubsup><mml:msub><mml:mi>y</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> with the <inline-formula><mml:math id="M325" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> approach in the short term. For higher AF values, annual <inline-formula><mml:math id="M326" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> removals estimated
using the EESF-based approach will underestimate the <inline-formula><mml:math id="M327" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> at each time step (Fig. 3d), despite the higher-magnitude
<inline-formula><mml:math id="M328" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> estimate (relative to <inline-formula><mml:math id="M329" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula>) seen in the longer term (Fig. 3c). This is owed to the lower atmospheric
<inline-formula><mml:math id="M330" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent abundance that is accumulated over the period when the series of annual <inline-formula><mml:math id="M331" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> fluxes are reduced to compensate
for the higher AF.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4"><?xmltex \currentcnt{4}?><?xmltex \def\figurename{Figure}?><label>Figure 4</label><caption><p id="d1e5383">Magnitude of the annual <inline-formula><mml:math id="M332" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> emission (removal) pulse as a function of the metric TH for the EESF and GWP measures relative to <inline-formula><mml:math id="M333" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula>, which is insensitive to TH.</p></caption>
          <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://acp.copernicus.org/articles/21/9887/2021/acp-21-9887-2021-f04.png"/>

        </fig>

      <p id="d1e5424">For TH <inline-formula><mml:math id="M334" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 100 years, the EESF-based estimate will always be lower in magnitude in the short term and higher in magnitude in the
longer term relative to <inline-formula><mml:math id="M335" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> (Fig. 3c). The same is also true for the annual GWP-based <inline-formula><mml:math id="M336" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> estimate, although at least
the reconstructed <inline-formula><mml:math id="M337" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> value at <inline-formula><mml:math id="M338" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M339" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> TH will always be identical to the actual <inline-formula><mml:math id="M340" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> value at
<inline-formula><mml:math id="M341" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M342" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> TH (Fig. 3d). In general, EESF- and GWP-based estimates of annualized <inline-formula><mml:math id="M343" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> emissions (or removals)
are sensitive to the chosen TH and will always exceed (in magnitude) estimates based on <inline-formula><mml:math id="M344" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula>. This is demonstrated in Fig. 4.</p>
      <p id="d1e5553">The EESF-based estimate in this example is higher (in magnitude) than the GWP-based estimate because the assumed AF of 0.47 is lower
than the mean atmospheric fraction following pulse emissions (i.e., <inline-formula><mml:math id="M345" display="inline"><mml:mrow><mml:msub><mml:mi>y</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>) over the range of time horizons shown (the mean
atmospheric fraction at TH <inline-formula><mml:math id="M346" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 100 when applying the Joos et al. (2013) function is 0.53). In contrast to the EESF- and
GWP-based approaches, the magnitude of the annual <inline-formula><mml:math id="M347" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> removals estimated with <inline-formula><mml:math id="M348" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> is insensitive to the chosen
TH.</p>
</sec>
<sec id="Ch1.S4.SS2">
  <label>4.2</label><?xmltex \opttitle{Single {$\protect\chem{CO_{{2}}\text{-}eq.}$} pulse measures}?><title>Single <inline-formula><mml:math id="M349" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> pulse measures</title>
      <p id="d1e5642">Turning our attention to measures yielding a single <inline-formula><mml:math id="M350" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> emission or removal pulse, let us now consider a forest management case
where managers are considering harvesting a deciduous broadleaved forest to plant a more productive evergreen needleleaved tree species. It is known
that when the evergreen needleleaved forest matures in 80 years its mean annual surface albedo will be about 2 % lower than the deciduous
broadleaved forest. The corresponding annual local <inline-formula><mml:math id="M351" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> at year 80 is 1.8 <inline-formula><mml:math id="M352" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, and we wish to associate a
<inline-formula><mml:math id="M353" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> equivalence with this value in order to weigh it against an estimate of the total <inline-formula><mml:math id="M354" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> stock difference between the two forests
after 80 years (i.e., TH <inline-formula><mml:math id="M355" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 80). Assuming we have no information about how the albedo evolves a priori in the two forests before year
80, we have no choice but to apply the EESF measure.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5"><?xmltex \currentcnt{5}?><?xmltex \def\figurename{Figure}?><label>Figure 5</label><caption><p id="d1e5725">Sensitivity of EESF to the airborne fraction (AF).</p></caption>
          <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://acp.copernicus.org/articles/21/9887/2021/acp-21-9887-2021-f05.png"/>

        </fig>

      <p id="d1e5734">Figure 5 presents the <inline-formula><mml:math id="M356" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> estimate based on EESF for an AF range of 0.1–1, shown together with an estimate in which
the AF is obtained using the mean fraction of <inline-formula><mml:math id="M357" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> remaining in the atmosphere at 80 years following an emission pulse, obtained
from the latest IPCC impulse response function (<inline-formula><mml:math id="M358" display="inline"><mml:mrow><mml:msub><mml:mi>y</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>), and with the highest and lowest airborne fractions of the last 7 years.</p>
      <p id="d1e5787">Figure 5 illustrates EESF's sensitivity to the assumed AF. For instance, EESF with AF <inline-formula><mml:math id="M359" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.3 is double that
estimated with AF <inline-formula><mml:math id="M360" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0.6 – a normal AF range for the past 60 years (Fig. 1). EESF estimated using AF from
2015 (Fig. 5, green diamond) is 44 % lower than EESF using AF from the previous year (Fig. 5, magenta diamond). If surface
albedo is ever to be included in forestry decision making – as some have proposed (Thompson et al., 2009a; Lutz and Howarth, 2014) – the subjective
choice of the AF becomes problematic given this large sensitivity. For instance, if the decision-making basis in this example depends on the
net of the <inline-formula><mml:math id="M361" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> of <inline-formula><mml:math id="M362" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> and a difference in forest <inline-formula><mml:math id="M363" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> stock of 4.5 <inline-formula><mml:math id="M364" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">kg</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, adopting an
AF of 0.5 might lead to a decision to plant the new tree species given that the stock difference would exceed the EESF estimate
(i.e., <inline-formula><mml:math id="M365" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> sinks dominate), whereas adopting an AF of 0.4 might lead to a decision to forego the planting given that the
<inline-formula><mml:math id="M366" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> of <inline-formula><mml:math id="M367" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> would exceed the stock difference (i.e., surface albedo dominates).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F6" specific-use="star"><?xmltex \currentcnt{6}?><?xmltex \def\figurename{Figure}?><label>Figure 6</label><caption><p id="d1e5906">Example application of metrics yielding a single <inline-formula><mml:math id="M368" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> emission (or removal) pulse following a hypothetical forest tree species conversion. <bold>(a)</bold> <inline-formula><mml:math id="M369" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> and corresponding <inline-formula><mml:math id="M370" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> (left <inline-formula><mml:math id="M371" display="inline"><mml:mi>y</mml:mi></mml:math></inline-formula> axis, blue curves) and the temporally accumulated <inline-formula><mml:math id="M372" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> normalized to Earth's surface area (solid red, right <inline-formula><mml:math id="M373" display="inline"><mml:mi>y</mml:mi></mml:math></inline-formula> axis) and temporally accumulated <inline-formula><mml:math id="M374" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> (dashed red, right <inline-formula><mml:math id="M375" display="inline"><mml:mi>y</mml:mi></mml:math></inline-formula> axis) following a 1 <inline-formula><mml:math id="M376" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">kg</mml:mi></mml:mrow></mml:math></inline-formula> pulse emission. <bold>(b)</bold> EESF estimated for the <inline-formula><mml:math id="M377" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> (and <inline-formula><mml:math id="M378" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>) occurring at TH <inline-formula><mml:math id="M379" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 80 shown in relation to GWP(TH) – or the ratio of two red curves shown in panel <bold>(a)</bold> – and <inline-formula><mml:math id="M380" display="inline"><mml:mrow><mml:mo>∑</mml:mo><mml:mtext>TDEE</mml:mtext></mml:mrow></mml:math></inline-formula> estimated at all THs.</p></caption>
          <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://acp.copernicus.org/articles/21/9887/2021/acp-21-9887-2021-f06.png"/>

        </fig>

      <p id="d1e6088">Now let us assume the metric user <italic>does</italic> have insight into how the surface albedos of both forest types will evolve over the full rotation
period. In this new example, harvesting the deciduous broadleaf forest to plant an evergreen needleleaf species will first increase the surface albedo
in the short term, yet as the evergreen needleleaf forest grows and tree canopies begin to close and mask the surface, the albedo difference
(<inline-formula><mml:math id="M381" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>) reverts to negative and stays negative for the remainder of the rotation. This results in an annual mean local
<inline-formula><mml:math id="M382" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> profile that is first negative and then positive, which is depicted in Fig. 6a (blue solid curve, left <inline-formula><mml:math id="M383" display="inline"><mml:mi>y</mml:mi></mml:math></inline-formula> axis).</p>
      <p id="d1e6131">Converting the <inline-formula><mml:math id="M384" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> time profile first to a time series of <inline-formula><mml:math id="M385" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> emission/removal pulses (i.e., <inline-formula><mml:math id="M386" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula>,
Fig. 6 A, dashed blue curve) and then summing to year 80 gives a measure of the total quantity of <inline-formula><mml:math id="M387" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> emitted (or removed) at year 80 – or
<inline-formula><mml:math id="M388" display="inline"><mml:mrow><mml:mo>∑</mml:mo><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> (Fig. 6b, blue curve). <inline-formula><mml:math id="M389" display="inline"><mml:mrow><mml:mo>∑</mml:mo><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> thus “remembers” the negative <inline-formula><mml:math id="M390" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> in the early phases of the rotation period
(short-term), leading to a lower <inline-formula><mml:math id="M391" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> estimate at year 80 relative to EESF estimates computed with airborne fractions of 0.66
and lower. Similarly, the GWP-based estimate remembers the negative <inline-formula><mml:math id="M392" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> occurring in the short term; however, GWP is
a normalized measure, meaning that the time-evolving radiative effects of <inline-formula><mml:math id="M393" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M394" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> are first computed independently from each
other prior to the <inline-formula><mml:math id="M395" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalence calculation, whereas for <inline-formula><mml:math id="M396" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> (and hence <inline-formula><mml:math id="M397" display="inline"><mml:mrow><mml:mo>∑</mml:mo><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula>) <inline-formula><mml:math id="M398" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> equivalence depends
<italic>directly</italic> on the time-evolving radiative effect of <inline-formula><mml:math id="M399" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>. Framed differently, <inline-formula><mml:math id="M400" display="inline"><mml:mrow><mml:mo>∑</mml:mo><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> remembers prior
<inline-formula><mml:math id="M401" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> fluxes yielding the radiatively equivalent effect of the time-dependent <inline-formula><mml:math id="M402" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> scenario, whereas the “memories” of
<inline-formula><mml:math id="M403" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M404" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> underlying the GWP-based <inline-formula><mml:math id="M405" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent estimate are first considered in
isolation (Fig. 6a, red curves). Hence the GWP-based <inline-formula><mml:math id="M406" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> estimate in this example is much lower than the <inline-formula><mml:math id="M407" display="inline"><mml:mrow><mml:mo>∑</mml:mo><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula>-based
estimate since the temporally accumulated <inline-formula><mml:math id="M408" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> following a unit pulse emission at <inline-formula><mml:math id="M409" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M410" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 0 (or
<inline-formula><mml:math id="M411" display="inline"><mml:mrow><mml:mi mathvariant="normal">Σ</mml:mi><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, also known as the absolute GWP or <inline-formula><mml:math id="M412" display="inline"><mml:mrow><mml:mi>A</mml:mi><mml:mi>G</mml:mi><mml:mi>W</mml:mi><mml:msub><mml:mi>P</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>; Fig. 6a dashed red curve) is significantly larger than
the temporally accumulated <inline-formula><mml:math id="M413" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> (or <inline-formula><mml:math id="M414" display="inline"><mml:mrow><mml:mi mathvariant="normal">Σ</mml:mi><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>) representing brief periods of both positive and negative
<inline-formula><mml:math id="M415" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>. Comparing brief or “short-lived” RFs with <inline-formula><mml:math id="M416" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> RFs using GWP has been heavily
criticized for reasons we discuss further in Sect. 6.</p>
      <p id="d1e6600">When scalar metrics are required, Fig. 6 illustrates the large inherent risk of applying a static measure like EESF to characterize
<inline-formula><mml:math id="M417" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> in dynamic systems. Moreover, for dynamic systems in which <inline-formula><mml:math id="M418" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>'s time dependency is defined a priori, Fig. 6 illustrates
the importance of clearly defining the time horizon at which the physical effects of <inline-formula><mml:math id="M419" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M420" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> are to be compared: GWP
gives an effect measured in terms of a present-day <inline-formula><mml:math id="M421" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> emission (or removal) pulse, while <inline-formula><mml:math id="M422" display="inline"><mml:mrow><mml:mo>∑</mml:mo><mml:mtext>TDEE</mml:mtext></mml:mrow></mml:math></inline-formula> gives an effect measured in
terms of a future <inline-formula><mml:math id="M423" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> emission (or removal). In other words, internal consistency between the ecological and metric time horizons is relaxed
with GWP but preserved with <inline-formula><mml:math id="M424" display="inline"><mml:mrow><mml:mo>∑</mml:mo><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula>.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T3" specific-use="star"><?xmltex \currentcnt{3}?><label>Table 3</label><caption><p id="d1e6697">Overview of distinguishing attributes, methodological differences, drawbacks, and merits of the six <inline-formula><mml:math id="M425" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> metrics applied in the scientific literature included in this review.</p></caption><oasis:table frame="topbot"><?xmltex \begin{scaleboxenv}{.98}[.98]?><oasis:tgroup cols="5">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="justify" colwidth="28mm"/>
     <oasis:colspec colnum="3" colname="col3" align="justify" colwidth="22mm"/>
     <oasis:colspec colnum="4" colname="col4" align="justify" colwidth="40mm"/>
     <oasis:colspec colnum="5" colname="col5" align="justify" colwidth="47mm"/>
     <oasis:thead>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"><inline-formula><mml:math id="M431" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> metric</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M432" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> equivalence<?xmltex \hack{\hfill\break}?>interpretation</oasis:entry>
         <oasis:entry colname="col3">Time-dependent<?xmltex \hack{\hfill\break}?> <inline-formula><mml:math id="M433" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> scenario</oasis:entry>
         <oasis:entry colname="col4">Drawbacks</oasis:entry>
         <oasis:entry colname="col5">Merits</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">EESF</oasis:entry>
         <oasis:entry colname="col2">Single pulse</oasis:entry>
         <oasis:entry colname="col3">No</oasis:entry>
         <oasis:entry colname="col4">Sensitive to choice of airborne fraction (AF)<?xmltex \hack{\hfill\break}?>Not forward-looking<?xmltex \hack{\hfill\break}?>No carbon cycle dynamics</oasis:entry>
         <oasis:entry colname="col5">Easy to apply; no need to define a <inline-formula><mml:math id="M434" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> scenario a priori</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M435" display="inline"><mml:mrow><mml:mtext>EESF</mml:mtext><mml:mo>/</mml:mo><mml:mtext>TH</mml:mtext></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Series of uniform<?xmltex \hack{\hfill\break}?>pulses</oasis:entry>
         <oasis:entry colname="col3">No</oasis:entry>
         <oasis:entry colname="col4">Same as above<?xmltex \hack{\hfill\break}?> <inline-formula><mml:math id="M436" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> series does not reproduce <inline-formula><mml:math id="M437" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula><inline-formula><mml:math id="M438" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">a</mml:mi></mml:msup></mml:math></inline-formula><?xmltex \hack{\hfill\break}?>Sensitive to TH</oasis:entry>
         <oasis:entry colname="col5">Easy to apply</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M439" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Series of non-uniform<?xmltex \hack{\hfill\break}?>pulses</oasis:entry>
         <oasis:entry colname="col3">Yes</oasis:entry>
         <oasis:entry colname="col4">Not scalar</oasis:entry>
         <oasis:entry colname="col5"><inline-formula><mml:math id="M440" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> series reproduces <inline-formula><mml:math id="M441" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula><?xmltex \hack{\hfill\break}?>Can be compared to an emission scenario<?xmltex \hack{\hfill\break}?>Insensitive to TH</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M442" display="inline"><mml:mrow><mml:mi mathvariant="normal">Σ</mml:mi><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Accumulation of<?xmltex \hack{\hfill\break}?>a series of<?xmltex \hack{\hfill\break}?>non-uniform pulses</oasis:entry>
         <oasis:entry colname="col3">Yes</oasis:entry>
         <oasis:entry colname="col4">Cannot be compared to a <inline-formula><mml:math id="M443" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> pulse of the present</oasis:entry>
         <oasis:entry colname="col5">Compatible with policy targets based on cumulative emissions<?xmltex \hack{\hfill\break}?>Insensitive to TH</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">GWP</oasis:entry>
         <oasis:entry colname="col2">Single pulse</oasis:entry>
         <oasis:entry colname="col3">Yes</oasis:entry>
         <oasis:entry colname="col4">Sensitive to TH<?xmltex \hack{\hfill\break}?>May be a poor indicator of impact when <inline-formula><mml:math id="M444" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> is shorter than TH</oasis:entry>
         <oasis:entry colname="col5">Well-known; IPCC conformity<?xmltex \hack{\hfill\break}?>Compatible with IPCC assessments and UNFCCC accounting conventions</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1"><inline-formula><mml:math id="M445" display="inline"><mml:mrow><mml:mtext>GWP(TH)</mml:mtext><mml:mo>/</mml:mo><mml:mtext>TH</mml:mtext></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col2">Series of uniform<?xmltex \hack{\hfill\break}?>pulses</oasis:entry>
         <oasis:entry colname="col3">Yes</oasis:entry>
         <oasis:entry colname="col4">Sensitive to TH<?xmltex \hack{\hfill\break}?> <inline-formula><mml:math id="M446" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> series does not reproduce <inline-formula><mml:math id="M447" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> except at <inline-formula><mml:math id="M448" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M449" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> TH</oasis:entry>
         <oasis:entry colname="col5">GWP method is well-known</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup><?xmltex \end{scaleboxenv}?></oasis:table><?xmltex \begin{scaleboxenv}{.98}[.98]?><table-wrap-foot><p id="d1e6710"><inline-formula><mml:math id="M426" display="inline"><mml:msup><mml:mi/><mml:mi mathvariant="normal">a</mml:mi></mml:msup></mml:math></inline-formula> The exception is at <inline-formula><mml:math id="M427" display="inline"><mml:mi>t</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M428" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> TH when AF <inline-formula><mml:math id="M429" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M430" display="inline"><mml:mrow><mml:msup><mml:mtext>TH</mml:mtext><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:msubsup><mml:mo>∫</mml:mo><mml:mrow><mml:mi>t</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow><mml:mrow><mml:mi>t</mml:mi><mml:mo>=</mml:mo><mml:mtext>TH</mml:mtext></mml:mrow></mml:msubsup><mml:msub><mml:mi>y</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo><mml:mi mathvariant="normal">d</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:math></inline-formula>.</p></table-wrap-foot><?xmltex \end{scaleboxenv}?></table-wrap>

</sec>
</sec>
<sec id="Ch1.S5">
  <label>5</label><title>Qualitative metric evaluation</title>
      <p id="d1e7227">The reviewed metrics and underlying methods for converting shortwave radiative forcings from <inline-formula><mml:math id="M450" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> (i.e., <inline-formula><mml:math id="M451" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>) into
their <inline-formula><mml:math id="M452" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent effects – summarized in Table 3 – can primarily be differentiated by the physical
interpretation of the derived measure and by whether or not a time dependency (inter-annual) for <inline-formula><mml:math id="M453" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> was defined a priori.</p>
      <p id="d1e7275">For cases when <inline-formula><mml:math id="M454" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>'s time dependency is not known or defined a priori, the EESF measure is the only applicable measure of those
reviewed, although it was shown here to be highly sensitive to the value chosen to represent <inline-formula><mml:math id="M455" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>'s airborne fraction (AF;
Fig. 5) – a key input variable taking on a wide range of values depending on how it was defined. In general, when AF is defined according to
historical accounts of global carbon cycling, its value is prone to large fluctuations across short timescales (Fig. 1) due to natural variability in
the global carbon cycle (Ciais et al., 2013). When defined as the fraction of <inline-formula><mml:math id="M456" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> remaining in the atmosphere following a pulse emission –
as would be obtained from a simple carbon cycle model (i.e., a <inline-formula><mml:math id="M457" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> impulse response function) – its value depends on the time horizon
chosen and underlying model representation of atmospheric removal processes (i.e., time constants). Use of the latter definition of AF
affixes a forward-looking time dependency to the EESF measure, which is inconsistent with the definition of <inline-formula><mml:math id="M458" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> and adds
subjectivity (i.e., the choice in TH). Basing the AF on global carbon budget reconstructions would at least preserve some element of
objectivity, although given the measure's sensitivity to AF it would be prudent to compute the measure for a range of AFs (i.e., as
constrained by the observational record) in an effort to boost transparency. Forgoing the use of an AF altogether would eliminate all
subjectivity, as has been suggested elsewhere (Bright et al., 2016).</p>
      <p id="d1e7331">For cases involving a time-dependent <inline-formula><mml:math id="M459" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> scenario that is defined a priori, forward-looking measures are identified whose methodological
differences give rise to different interpretations of <inline-formula><mml:math id="M460" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> equivalence (Table 3). For example, the GWP
measure can be interpreted as <inline-formula><mml:math id="M461" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> pulse emitted at present yielding the accumulated radiative forcing of the <inline-formula><mml:math id="M462" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> scenario at
TH years into the future. GWP has merit from the standpoint that it is easy to apply and conforms to established reporting methods,
accounting standards, or decision-support tools such as life cycle assessment (e.g., Cherubini et al., 2012; Sieber et al., 2020). Scientifically,
however, there are important limitations to GWP when the forcing (i.e., <inline-formula><mml:math id="M463" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>) is short-lived or temporary (Allen et al., 2016;
Pierrehumbert, 2014; Allen et al., 2018; Lynch et al., 2020; Cain et al., 2019). The <inline-formula><mml:math id="M464" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> measure, on the other hand, can be interpreted as a
complete time series of <inline-formula><mml:math id="M465" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> emission pulses (i.e., a complete emission scenario) yielding the instantaneous radiative forcing of the
<inline-formula><mml:math id="M466" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> scenario. When summed to TH, the latter (as <inline-formula><mml:math id="M467" display="inline"><mml:mi mathvariant="normal">Σ</mml:mi></mml:math></inline-formula><inline-formula><mml:math id="M468" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula>) provides a clearer indication of the radiative impact
incurred up to TH, thus having greater scientific merit as an indicator of future warming.</p>
      <p id="d1e7448">The permutations of GWP and EESF applied to arrive at a time series of <inline-formula><mml:math id="M469" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> pulses –
GWP(TH) <inline-formula><mml:math id="M470" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> TH and EESF <inline-formula><mml:math id="M471" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> TH – have little merit on the grounds that the resulting series does not
reproduce <inline-formula><mml:math id="M472" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> (Fig. 3d). The <inline-formula><mml:math id="M473" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> approach was proposed to overcome this limitation, although it should be stressed
that – like GWP(TH) <inline-formula><mml:math id="M474" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> TH – its derivation requires that a time-dependent <inline-formula><mml:math id="M475" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> scenario be defined a priori,
which adds uncertainty and may not always be possible.</p>
</sec>
<sec id="Ch1.S6">
  <label>6</label><?xmltex \opttitle{$\text{GWP}^{{*}}$ and $\Delta\alpha$}?><title><inline-formula><mml:math id="M476" display="inline"><mml:mrow><mml:msup><mml:mtext>GWP</mml:mtext><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M477" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula></title>
      <p id="d1e7562">It is well known that the conventional usage of GWP does not adequately capture different behaviors of short-and long-lived climate
pollutants or their impact on global mean surface temperatures (Pierrehumbert, 2014; Allen et al., 2016; Shine et al., 2003; Fuglestvedt et al.,
2010). Some have proposed an alternative usage of GWP – denoted <inline-formula><mml:math id="M478" display="inline"><mml:mrow><mml:msup><mml:mtext>GWP</mml:mtext><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> (Allen et al., 2018) – which overcomes this problem by
equating an increase in the emission rate of a short-lived climate pollutant (or radiative forcing agent) with a one-off “pulse” <inline-formula><mml:math id="M479" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>
emission. <inline-formula><mml:math id="M480" display="inline"><mml:mrow><mml:msup><mml:mtext>GWP</mml:mtext><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> recognizes that a pulse emission of <inline-formula><mml:math id="M481" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> and a sudden step change in the sustained rate of emission of a
short-lived climate pollutant (SLCP) both give near-constant radiative forcing. Or, alternately, that a progressive linear increase (or decrease) in
the rate of an SLCP emission is approximately equivalent to a sustained step change in the emission rate of <inline-formula><mml:math id="M482" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>. As such, <inline-formula><mml:math id="M483" display="inline"><mml:mrow><mml:msup><mml:mtext>GWP</mml:mtext><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula>
is considered to have greater “environmental integrity” than the conventional GWP metric (Allen et al., 2018), as it is better fit to serve
the purpose of a measure of progress towards a global temperature-oriented climate goal (i.e., limit warming to “well below
2 <inline-formula><mml:math id="M484" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula>”). Compared to conventional GWP, cumulative <inline-formula><mml:math id="M485" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> emissions based on <inline-formula><mml:math id="M486" display="inline"><mml:mrow><mml:msup><mml:mtext>GWP</mml:mtext><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> provide a
clearer indication of future warming, and future <inline-formula><mml:math id="M487" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> emission rates better indicate future warming rates. <inline-formula><mml:math id="M488" display="inline"><mml:mrow><mml:msup><mml:mtext>GWP</mml:mtext><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> thus
better relates all climate pollutants in a common cumulative emission (or emission budget) framework, making it easier to formulate mitigation
strategies that provide a more accurate indication of progress towards climate stabilization.</p>
      <p id="d1e7700">Among one of the more distinguishing features of <inline-formula><mml:math id="M489" display="inline"><mml:mrow><mml:msup><mml:mtext>GWP</mml:mtext><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> is that, when applied to radiative forcings rather than pulse emissions, information
about the time dependency of the perturbation (i.e., the lifetimes of “climate pollutants” or forcing agents) is not required (Lee et al., 2021;
Cain et al., 2019; Allen et al., 2018), making it an attractive alternative to EESF. In other words, a GWP estimate of the
“short-lived” forcing agent under scope – which requires such information to be known or defined a priori – is unnecessary in its
calculation. Only the rate of change of the forcing is required, scaled by TH <inline-formula><mml:math id="M490" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M491" display="inline"><mml:mrow><mml:msub><mml:mtext>AGWP(TH)</mml:mtext><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> as follows (Lee et al.,
2021; Allen et al., 2018):
          <disp-formula id="Ch1.E9" content-type="numbered"><label>9</label><mml:math id="M492" display="block"><mml:mrow><mml:msub><mml:mi>E</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:msup><mml:mo>.</mml:mo><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:msub><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mtext>TH</mml:mtext><mml:mrow><mml:msub><mml:mtext>AGWP(TH)</mml:mtext><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mfenced close=")" open="("><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle></mml:mfenced><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
        where TH is the time horizon, <inline-formula><mml:math id="M493" display="inline"><mml:mrow><mml:msub><mml:mtext>AGWP(TH)</mml:mtext><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> is <inline-formula><mml:math id="M494" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>'s AGWP at the same TH (i.e.,
9.2 <inline-formula><mml:math id="M495" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M496" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">14</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M497" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">W</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="normal">yr</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">kg</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> when TH <inline-formula><mml:math id="M498" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 100 years), <inline-formula><mml:math id="M499" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:math></inline-formula> is the
time step change, and <inline-formula><mml:math id="M500" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> is the time differential of <inline-formula><mml:math id="M501" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> over the step
change. <inline-formula><mml:math id="M502" display="inline"><mml:mrow><mml:msub><mml:mi>E</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:msup><mml:mo>.</mml:mo><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> thus represents the <inline-formula><mml:math id="M503" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> emission pulse for the step change and will equal EESF when
the AF (in Eq. 6 denominator) corresponds to the mean of <inline-formula><mml:math id="M504" display="inline"><mml:mrow><mml:msub><mml:mi>y</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> over the TH (i.e., <inline-formula><mml:math id="M505" display="inline"><mml:mrow><mml:mi>T</mml:mi><mml:msup><mml:mi>H</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:msubsup><mml:mo>∫</mml:mo><mml:mrow><mml:mi>t</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0</mml:mn></mml:mrow><mml:mrow><mml:mi>t</mml:mi><mml:mo>=</mml:mo><mml:mtext>TH</mml:mtext></mml:mrow></mml:msubsup><mml:msub><mml:mi>y</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo><mml:mi mathvariant="normal">d</mml:mi><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>. A TH of 100 years is typically applied in Eq. (<xref ref-type="disp-formula" rid="Ch1.E9"/>), which is justified when it exceeds the
lifetime of the SLCP or when the time-integrated radiative forcing of the forcing agent (i.e, <inline-formula><mml:math id="M506" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>) becomes a constant at this timescale,
since the time-integrated radiative forcing of the reference gas (i.e., <inline-formula><mml:math id="M507" display="inline"><mml:mrow><mml:msub><mml:mtext>AGWP</mml:mtext><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>) increases linearly with TH. In other
words, the TH dependence cancels out in the calculation of <inline-formula><mml:math id="M508" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:msup><mml:mo>.</mml:mo><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula>, rendering <inline-formula><mml:math id="M509" display="inline"><mml:mrow><mml:msup><mml:mtext>GWP</mml:mtext><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> insensitive to the choice in
TH, which contrasts with the conventional GWP (Allen et al., 2016, 2018). The step change <inline-formula><mml:math id="M510" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:math></inline-formula> for which <inline-formula><mml:math id="M511" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mtext>RF</mml:mtext></mml:mrow></mml:math></inline-formula> is
calculated is typically taken as 20 years to “reduce the volatility of <inline-formula><mml:math id="M512" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:msup><mml:mo>.</mml:mo><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> emissions in response to variations in SLCP emission
rates” (Allen et al. 2018; Cain et al. 2019), although comprehensive investigations into the appropriateness of this choice when applied to a wide
variety of time-varying SLCP emission (radiative forcing) scenarios are lacking. We note that more recent works (Cain et al., 2019; Lee et al.,
2021) employed weighting-based modifications to Eq. (<xref ref-type="disp-formula" rid="Ch1.E9"/>) in an effort to better account for the
longer-term temperature equilibration to past forcing changes:
          <disp-formula id="Ch1.E10" content-type="numbered"><label>10</label><mml:math id="M513" display="block"><mml:mtable rowspacing="0.2ex" class="split" displaystyle="true" columnalign="right left"><mml:mtr><mml:mtd><mml:mrow><mml:msub><mml:mi>E</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:msup><mml:mo>.</mml:mo><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:msub><mml:mo>=</mml:mo></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mspace linebreak="nobreak" width="0.25em"/><mml:mfenced open="[" close="]"><mml:mrow><mml:mo>(</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:mi>s</mml:mi><mml:mo>)</mml:mo><mml:msub><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mtext>TH</mml:mtext><mml:mtext>AGWP(TH)</mml:mtext></mml:mfrac></mml:mstyle><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:mfenced><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd/><mml:mtd><mml:mrow><mml:mo>+</mml:mo><mml:mi>s</mml:mi><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mover accent="true"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow><mml:mo mathvariant="normal">‾</mml:mo></mml:mover><mml:mrow><mml:msub><mml:mtext>AGWP(TH)</mml:mtext><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mtr></mml:mtable></mml:math></disp-formula>
        where <inline-formula><mml:math id="M514" display="inline"><mml:mi>s</mml:mi></mml:math></inline-formula> is a factor weighting the delayed response by global mean temperature to the radiative forcing history, represented here (following Lee
et al., 2021) as the mean forcing over the period <inline-formula><mml:math id="M515" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:math></inline-formula> – or
<inline-formula><mml:math id="M516" display="inline"><mml:mover accent="true"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula>. Note that <inline-formula><mml:math id="M517" display="inline"><mml:mi>s</mml:mi></mml:math></inline-formula> is analogous to the “<inline-formula><mml:math id="M518" display="inline"><mml:mi mathvariant="italic">α</mml:mi></mml:math></inline-formula>” term seen in Eq. (<xref ref-type="disp-formula" rid="Ch1.E1"/>) of Lee
et al. (2021) and that the factor <inline-formula><mml:math id="M519" display="inline"><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>-</mml:mo><mml:mi>s</mml:mi></mml:mrow></mml:math></inline-formula> is analogous to the rate contribution weight denoted as
“<inline-formula><mml:math id="M520" display="inline"><mml:mi>r</mml:mi></mml:math></inline-formula>” in Eq. (S1) of Cain et al. (2019). Like the choice of <inline-formula><mml:math id="M521" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:math></inline-formula>, however, few investigations have been carried out to assess the
appropriateness of weight sizes applied in Eq. (<xref ref-type="disp-formula" rid="Ch1.E10"/>) for different SLCP emission (radiative forcing) scenarios having widely varying temporal
dynamics.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F7" specific-use="star"><?xmltex \currentcnt{7}?><?xmltex \def\figurename{Figure}?><label>Figure 7</label><caption><p id="d1e8338">Performance of <inline-formula><mml:math id="M522" display="inline"><mml:mrow><mml:msup><mml:mtext>GWP</mml:mtext><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> computed for three stylized scenarios of surface-albedo-change-driven radiative forcing using Eq. (<xref ref-type="disp-formula" rid="Ch1.E10"/>) with nine different parameter sets. <bold>(a)</bold> Local radiative forcing of one permanent and two temporally evolving surface albedo change scenarios. <bold>(b–d)</bold> The corresponding global mean temperature response <inline-formula><mml:math id="M523" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula> to the radiative forcing relative to that which has been reconstructed using the <inline-formula><mml:math id="M524" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> emission (removal) time series computed with <inline-formula><mml:math id="M525" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M526" display="inline"><mml:mrow><mml:msup><mml:mtext>GWP</mml:mtext><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> under the assumption that <inline-formula><mml:math id="M527" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi mathvariant="italic">α</mml:mi><mml:mrow><mml:mi>t</mml:mi><mml:mo>+</mml:mo><mml:mi>n</mml:mi><mml:mo>-</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> is known. <inline-formula><mml:math id="M528" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula> in panels <bold>(b–d)</bold> is estimated with a temperature impulse response function following Boucher and Reddy (2008) and Myhre et al. (2013) having a climate sensitivity of 1.06 <inline-formula><mml:math id="M529" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mo>(</mml:mo><mml:mi mathvariant="normal">W</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">m</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup><mml:msup><mml:mo>)</mml:mo><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, which is equivalent to a 3.9 <inline-formula><mml:math id="M530" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">K</mml:mi></mml:mrow></mml:math></inline-formula> equilibrium climate response to an abrupt <inline-formula><mml:math id="M531" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> concentration doubling.</p></caption>
        <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://acp.copernicus.org/articles/21/9887/2021/acp-21-9887-2021-f07.png"/>

      </fig>

      <p id="d1e8505">We explore the sensitivity of the choice in both <inline-formula><mml:math id="M532" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M533" display="inline"><mml:mi>s</mml:mi></mml:math></inline-formula> on <inline-formula><mml:math id="M534" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> emissions (removals) estimated with the modified
<inline-formula><mml:math id="M535" display="inline"><mml:mrow><mml:msup><mml:mtext>GWP</mml:mtext><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> approach (Eq. <xref ref-type="disp-formula" rid="Ch1.E10"/>) for three hypothetical local <inline-formula><mml:math id="M536" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> scenarios presented in Fig. 7. The first scenario – or Scenario A – is identical to the forest management scenario plotted in Fig. 6 and extended by 20 years, which is characterized by a
negative RF in the short term and positive RF in the longer term (Fig. 7a, blue). In the second scenario, or Scenario B, <inline-formula><mml:math id="M537" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>
corresponds to a linearly increasing <inline-formula><mml:math id="M538" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> trend which is loosely analogous to incremental deforestation occurring on a regional scale
(Fig. 7a, red). The third scenario, or Scenario C, resembles a permanent albedo decrease, analogous to urban expansion into a cropland (Fig. 7a, yellow).</p>
      <p id="d1e8606">We then reconstruct the global mean temperature response (<inline-formula><mml:math id="M539" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula>) of the <inline-formula><mml:math id="M540" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:msup><mml:mo>.</mml:mo><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> emission (removal) scenario under varying
assumptions surrounding the size of <inline-formula><mml:math id="M541" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:math></inline-formula> and the weighting factor <inline-formula><mml:math id="M542" display="inline"><mml:mi>s</mml:mi></mml:math></inline-formula> (shown in Fig. 7b legend), which is then compared to the
<inline-formula><mml:math id="M543" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>-based <inline-formula><mml:math id="M544" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula> and the <inline-formula><mml:math id="M545" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula> reconstructed using the <inline-formula><mml:math id="M546" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> emission (removal) scenario based on the
<inline-formula><mml:math id="M547" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> approach (Fig. 7b–d). For Scenario A (Fig. 7b), we find no obvious parameter set that outperforms any other in terms of the faithfulness
by which the <inline-formula><mml:math id="M548" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:msup><mml:mo>.</mml:mo><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> emission (removal) scenario reproduces <inline-formula><mml:math id="M549" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula> across the full time horizon. There appears to be a trade-off
between the near- and long-term reproduction accuracy of different parameter sets: a 20-year <inline-formula><mml:math id="M550" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:math></inline-formula> with no weighting (Fig. 7b, solid green
curve) better reproduces the <inline-formula><mml:math id="M551" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula> response seen in the short term (<inline-formula><mml:math id="M552" display="inline"><mml:mi mathvariant="italic">≲</mml:mi></mml:math></inline-formula> 20 years) as well as the <inline-formula><mml:math id="M553" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula> seen at the end of the
scenario time horizon (year 100), whereas a 10-year <inline-formula><mml:math id="M554" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:math></inline-formula> with no weighting (Fig. 7b, solid purple curve) better reproduces the <inline-formula><mml:math id="M555" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula>
response seen in the longer term (from <inline-formula><mml:math id="M556" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 60–90 years). An increase in the weighting factor <inline-formula><mml:math id="M557" display="inline"><mml:mi>s</mml:mi></mml:math></inline-formula> serves to dampen the amplitude between the
maximum cooling and warming seen in the short and longer term, respectively (Fig. 7b, spread between like-colored curves). As for Scenario B
representing a linear increase in RF, the reconstructed <inline-formula><mml:math id="M558" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula> is insensitive to <inline-formula><mml:math id="M559" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:math></inline-formula> and thus only results for a 1-year <inline-formula><mml:math id="M560" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:math></inline-formula> are computed and presented in Fig. 7c. Although a weighting factor of 0.2 is most accurate for the first <inline-formula><mml:math id="M561" display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 50 years, a weight of 0.1 gives
a more faithful <inline-formula><mml:math id="M562" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula> reproduction for the full time period. As for Scenario C representing a step change in RF (Fig. 7d), again we find
no obvious parameter set that yields a faithful <inline-formula><mml:math id="M563" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula> reproduction across the full time period. High <inline-formula><mml:math id="M564" display="inline"><mml:mi>s</mml:mi></mml:math></inline-formula> weights overpredict <inline-formula><mml:math id="M565" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula> in the
medium term but reproduce <inline-formula><mml:math id="M566" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula> best in the longer term (Fig. 7d, solid curves), while a <inline-formula><mml:math id="M567" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:math></inline-formula> larger than 10 years appears to result in
large underpredictions in the short term (i.e., <inline-formula><mml:math id="M568" display="inline"><mml:mi mathvariant="italic">≲</mml:mi></mml:math></inline-formula> 20 years; Fig. 7d, green curves).</p>
      <p id="d1e8928">Unsurprisingly, <inline-formula><mml:math id="M569" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula> reconstructed using the <inline-formula><mml:math id="M570" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> emission (removal) scenario estimated with the <inline-formula><mml:math id="M571" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> approach exactly
reproduces the RF-based <inline-formula><mml:math id="M572" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula>, and thus these two estimates are plotted jointly as a single curve in Fig. 7b–d (wider solid
curves). Thus, when future surface albedo changes are defined a priori (i.e., when the <inline-formula><mml:math id="M573" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> perturbation “lifetime” is known or
estimated), a <inline-formula><mml:math id="M574" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> emission (removal) time series quantified with <inline-formula><mml:math id="M575" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> is far superior to one based on <inline-formula><mml:math id="M576" display="inline"><mml:mrow><mml:msup><mml:mtext>GWP</mml:mtext><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula>
irrespective of the choice in <inline-formula><mml:math id="M577" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:math></inline-formula> or weight sizes applied, making it the better <inline-formula><mml:math id="M578" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> measure of progress towards global
temperature stabilization.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T4" specific-use="star"><?xmltex \currentcnt{4}?><label>Table 4</label><caption><p id="d1e9065">Differences in surface property and flux perturbations between geoengineering-type forcings involving non-vegetative solar radiation management (SRM) and forcings from LULCC, land management change (LMC), or forest management change (FMC). <inline-formula><mml:math id="M579" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>r</mml:mi><mml:mi mathvariant="normal">a</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>: change to bulk aerodynamic resistance; <inline-formula><mml:math id="M580" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>r</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>: change to bulk surface resistance; <inline-formula><mml:math id="M581" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>(</mml:mo><mml:mi>E</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>: latent heat flux change from a change to evaporation; <inline-formula><mml:math id="M582" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>(</mml:mo><mml:mi>E</mml:mi><mml:mo>+</mml:mo><mml:mi>T</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>: latent heat flux change from a change to both evaporation and transpiration; <inline-formula><mml:math id="M583" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>H</mml:mi></mml:mrow></mml:math></inline-formula>: sensible heat flux change.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="3">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:colspec colnum="3" colname="col3" align="left"/>
     <oasis:thead>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Forcing type</oasis:entry>
         <oasis:entry colname="col2">Surface property perturbation</oasis:entry>
         <oasis:entry colname="col3">Surface flux perturbation</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">Geoengineering (non-veg. SRM)</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M584" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M585" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>(</mml:mo><mml:mi>E</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M586" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>H</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">LULCC; LMC; FMC</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M587" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M588" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>r</mml:mi><mml:mi mathvariant="normal">a</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M589" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>r</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><inline-formula><mml:math id="M590" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">λ</mml:mi><mml:mo>(</mml:mo><mml:mi>E</mml:mi><mml:mo>+</mml:mo><mml:mi>T</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M591" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>H</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

</sec>
<sec id="Ch1.S7">
  <label>7</label><?xmltex \opttitle{Spatial disparity in climate response between {$\protect\chem{CO_{{2}}}$} emissions and $\mathbf{\Delta\alpha}$ perturbations}?><title>Spatial disparity in climate response between <inline-formula><mml:math id="M592" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> emissions and <inline-formula><mml:math id="M593" display="inline"><mml:mrow><mml:mi mathvariant="bold">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> perturbations</title>
      <p id="d1e9317">The climate (i.e., temperature) response to a <inline-formula><mml:math id="M594" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> perturbation either isolated (e.g., Jacobson and Ten Hoeve, 2012) or as part of LULCC
(e.g., Pongratz et al., 2010; Betts, 2001) is highly heterogeneous in space, the magnitude and extent of which depends on its location (Brovkin
et al., 2013; de Noblet-Ducoudré et al., 2012). This is because the response pattern of climate feedbacks has a strong spatial dependency –
feedbacks are generally larger at higher latitudes due to higher energy budget sensitivity to clouds, water vapor, and surface albedo, which generally
increases the effectiveness of RF in those regions (Shindell et al., 2015). This is in contrast to <inline-formula><mml:math id="M595" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> emissions where both
RF and the temperature response are more homogeneous in space (Hansen and Nazarenko, 2004; Hansen et al., 2005; Myhre et al., 2013). This has
caused some researchers to question the utility of a <inline-formula><mml:math id="M596" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> measure for <inline-formula><mml:math id="M597" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> (Jones et al., 2013) or encouraged others to look
for solutions or further methodological refinements. For instance, some researchers (e.g., Cherubini et al., 2012; Zhao and Jackson, 2014) have
applied climate efficacies – or the climate sensitivity of a forcing agent relative to <inline-formula><mml:math id="M598" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> (Joshi et al., 2003; Hansen et al., 2005) –
to adjust <inline-formula><mml:math id="M599" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> prior to the <inline-formula><mml:math id="M600" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> calculation. Such adjustments recognize that the temperature response to
RF depends on the geographic location, extent, and type of underlying forcing associated with the <inline-formula><mml:math id="M601" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> (e.g., land use and land cover
change (LULCC), white-roofing), which can be co-associated with other perturbations (Table 4) like those arising from
changes to vegetative physical properties (for the LULCC case) which can modify the partitioning of turbulent heat fluxes above and beyond the purely
radiatively driven change (Davin et al., 2007; Bright et al., 2017).</p>
      <p id="d1e9421">Using a climate efficacy to adjust <inline-formula><mml:math id="M602" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, however, is not without its drawbacks. A first and obvious drawback is that efficacies
are climate model dependent (Hansen et al., 2005; Smith et al., 2020; Richardson et al., 2019). Climate models vary in their underlying physics, which
is evidenced by the large spread in <inline-formula><mml:math id="M603" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>'s climate sensitivity across CMIP6 models (Meehl et al., 2020; Zelinka et al., 2020). A second
drawback is that climate sensitivities for certain forcing agents like <inline-formula><mml:math id="M604" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> are tied to experiments that differ largely in the way forcings
have been imposed in time and space. Both drawbacks contribute to large uncertainties in the choice of efficacy for <inline-formula><mml:math id="M605" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>. The latter
drawback is especially problematic since the <inline-formula><mml:math id="M606" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> perturbation is often accompanied by perturbations to other surface properties and fluxes
(Table 4) having large spatial and temporal dependencies. The turbulent heat flux perturbations that accompany a net
radiative flux change at the surface affect atmospheric temperature and humidity profiles (Bala et al., 2008; Modak et al., 2016; Schmidt et al.,
2012; Kravitz et al., 2013), causing the atmosphere to adjust to a new state, resulting in a net radiative flux change at TOA that extends beyond the
instantaneous shortwave radiative flux change (i.e., <inline-formula><mml:math id="M607" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>).</p>
      <p id="d1e9494">For example, the efficacy of LULCC forcing across the six studies reviewed by Bright et al. (2015) ranged from 0.5 to 1.02 owing to differences in
model set-up (e.g., fixed SST vs. slab vs. dynamic ocean), differences in the spatial extent and magnitude of the imposed LULCC forcing (e.g.,
historical transient vs. idealized time slice), and the LULCC definition (i.e., the type of LULCC that was included in the study such as only
afforestation/deforestation vs. all LULCC). Even when controlling for differences in experimental design (e.g., CMIP protocols), the climate efficacy
of historical LULCC has been found to vary considerably in both sign and magnitude (see Fig. 8, Richardson et al. 2019), which is more likely
attributed to the larger spread in effective radiative forcing (ERF) for LULCC than for <inline-formula><mml:math id="M608" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>. For instance, Smith et al. (2020)
report a standard deviation of 6 % in the ERF of <inline-formula><mml:math id="M609" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> (4<inline-formula><mml:math id="M610" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> abrupt) across 17 GCMs and Earth system models (ESMs) participating in RFMIP in
contrast to 175 % for LULCC, although it should be kept in mind that the ERF is weak for LULCC and thus relative differences become large.</p>
      <p id="d1e9527">An additional drawback and source of uncertainty underlying efficacies is related to differences in their definition. Differences in definition can
stem from either different definitions of RF itself or differences in the definition of the temperature response per unit RF
(Richardson et al., 2019; Hansen et al., 2005). Regarding the latter, most base the temperature response for <inline-formula><mml:math id="M611" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> on the equilibrium climate
sensitivity (ECS) for a <inline-formula><mml:math id="M612" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> doubling, although good arguments have been made for using the transient climate response (TCR) instead,
particularly for short-lived forcing agents (Marvel et al., 2016; Shindell, 2014). The temperature response for the forcing agent of interest is
rarely taken as the equilibrium response although there are some exceptions (e.g. “<inline-formula><mml:math id="M613" display="inline"><mml:mrow><mml:msub><mml:mi>E</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>” in Richardson et al., 2019, which is based on climate
feedback parameters obtained from ordinary least-square regressions). Efficacies are also sensitive to the definition of RF (Richardson
et al., 2019; Hansen et al., 2005). For example, the efficacy of sulfate forcing (5 <inline-formula><mml:math id="M614" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M615" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">SO</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>) has recently been shown to vary from
0.94 to 2.97 depending on whether RF is based on the net radiative flux change at TOA from fixed SST experiments or the instantaneous
shortwave flux change at the tropopause (Richardson et al., 2019).</p>
      <p id="d1e9581">Ideally, <inline-formula><mml:math id="M616" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> metrics based on the RF concept should be based on an RF definition yielding efficacies approaching unity
for a broad range of forcing types. Although there is currently no consensus here, strong arguments have been made for RF definitions based
on the net radiative flux change at TOA resulting from fixed SST experiments with GCMs and ESMs (i.e., “<inline-formula><mml:math id="M617" display="inline"><mml:mrow><mml:msub><mml:mi>F</mml:mi><mml:mi>s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>” in Hansen et al. 2005;
“<inline-formula><mml:math id="M618" display="inline"><mml:mrow><mml:msub><mml:mtext>ERF</mml:mtext><mml:mtext>SST</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>” in Richardson et al. 2019), since such definitions yield efficacies approaching unity for a broad range of forcing
types. However, for most <inline-formula><mml:math id="M619" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> metric practitioners it is not feasible to quantify atmospheric adjustments and hence the
ERF. Efficacies compatible with <inline-formula><mml:math id="M620" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> (instantaneous <inline-formula><mml:math id="M621" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mtext>SW</mml:mtext></mml:mrow></mml:math></inline-formula> at TOA) could be the more feasible option for
metric calculations, but broad consensus surrounding appropriate efficacy values for different forcing types
associated with the <inline-formula><mml:math id="M622" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> perturbation would need to be established first (Table 4). This is especially true for forcings involving changes to the
biophysical properties of vegetation – such as LULCC, forestry, etc. – since these are constructs representing a seemingly myriad combination of perturbations acting on non-radiative controls (i.e., <inline-formula><mml:math id="M623" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>r</mml:mi><mml:mi mathvariant="normal">a</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M624" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>r</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) of the surface energy
balance. Building consensus for efficacies applicable to geoengineering-type forcings where the only physical property perturbed is the surface albedo
(e.g., white roofing, sea ice brightening) would be less challenging since the confounding perturbations to <inline-formula><mml:math id="M625" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>r</mml:mi><mml:mi mathvariant="normal">a</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M626" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>r</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and hence to the partitioning of the turbulent heat fluxes are removed. Nevertheless, irrespective of whether broad scientific consensus can be reached
surrounding efficacies suitable for <inline-formula><mml:math id="M627" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> metrics, additional responsibility would always be imposed on the metric practitioner to ensure
that the chosen efficacy aligns with the forcing type underlying the <inline-formula><mml:math id="M628" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>.</p>
</sec>
<sec id="Ch1.S8" sec-type="conclusions">
  <label>8</label><title>Discussion</title>
<sec id="Ch1.S8.SS1">
  <label>8.1</label><title>Summary of merits</title>
      <p id="d1e9760">In this review, we quantitatively and qualitatively reviewed metrics (methods) to characterize <inline-formula><mml:math id="M629" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> in terms of a
<inline-formula><mml:math id="M630" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent effect. We note that while many metrics exist, none are true “equivalents” to <inline-formula><mml:math id="M631" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> due to its unique behavior. The
climate effects of the calculated <inline-formula><mml:math id="M632" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> emissions should ideally be the same regardless of the mix of forcing agents – including
<inline-formula><mml:math id="M633" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>. However, different forcing agents have different physical properties, and a metric that establishes equivalence with regard to one
effect cannot guarantee equivalence with regard to other effects and over extended time periods.</p>
      <p id="d1e9826">Differences among the reviewed <inline-formula><mml:math id="M634" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> metrics
could be attributed to the different ways of dealing with the time dependency of <inline-formula><mml:math id="M635" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, which to a large extent was determined
by whether a time dependency was defined for the <inline-formula><mml:math id="M636" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> perturbation. When the <inline-formula><mml:math id="M637" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> perturbation was assumed to have no
time dependency, as was the case for the EESF metric, uncertainties arose from the choice of AF, giving a mere snapshot in time of
the <inline-formula><mml:math id="M638" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> perturbation. For metrics like GWP and <inline-formula><mml:math id="M639" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> that explicitly account for the time dependency of
<inline-formula><mml:math id="M640" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, the need to define a time dependency for <inline-formula><mml:math id="M641" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> a priori introduces uncertainty owing to the reversible nature
of <inline-formula><mml:math id="M642" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>. Unlike most climate pollutants having standardized perturbation lifetimes determined by the physics of the Earth system, the
perturbation lifetime of <inline-formula><mml:math id="M643" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> is tied to a parcel of land and dictated by future anthropogenic activities occurring on that land. Users
should strive to be aware of the limitations and caveats of the reviewed <inline-formula><mml:math id="M644" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> metrics – defining a <inline-formula><mml:math id="M645" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> time dependency might
improve the precision of the <inline-formula><mml:math id="M646" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">eq</mml:mi><mml:mo>.</mml:mo></mml:mrow></mml:math></inline-formula> estimate but not necessarily its accuracy if the future (historical) <inline-formula><mml:math id="M647" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> cannot be
confidently projected (re-constructed). Application of EESF to <inline-formula><mml:math id="M648" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> perturbations in dynamic systems (i.e., systems
in which <inline-formula><mml:math id="M649" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> exhibits large variation over shorter timescales), on the other hand, opens up the risk for grossly mis-characterizing the system, particularly
when the chosen <inline-formula><mml:math id="M650" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> is not representative of the mean <inline-formula><mml:math id="M651" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> of the system under scope (e.g., Fig. 6b).</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T5" specific-use="star"><?xmltex \currentcnt{5}?><label>Table 5</label><caption><p id="d1e10037">Comparison of future <inline-formula><mml:math id="M652" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula> (global mean) from the <inline-formula><mml:math id="M653" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> scenarios shown in Fig. 7a reconstructed using <inline-formula><mml:math id="M654" display="inline"><mml:mrow><mml:mtext>GWP</mml:mtext><mml:mn mathvariant="normal">100</mml:mn></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M655" display="inline"><mml:mrow><mml:msubsup><mml:mo>∑</mml:mo><mml:mn mathvariant="normal">0</mml:mn><mml:mn mathvariant="normal">100</mml:mn></mml:msubsup><mml:mtext>TDEE</mml:mtext></mml:mrow></mml:math></inline-formula>.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="4">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="justify" colwidth="40mm"/>
     <oasis:colspec colnum="3" colname="col3" align="justify" colwidth="50mm"/>
     <oasis:colspec colnum="4" colname="col4" align="justify" colwidth="50mm"/>
     <oasis:thead>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1"/>
         <oasis:entry colname="col2">Actual <inline-formula><mml:math id="M656" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula> at TH <inline-formula><mml:math id="M657" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 100 years, <inline-formula><mml:math id="M658" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">Reconstructed <inline-formula><mml:math id="M659" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula> at TH <inline-formula><mml:math id="M660" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 100 years using <inline-formula><mml:math id="M661" display="inline"><mml:mrow><mml:mtext>GWP</mml:mtext><mml:mn mathvariant="normal">100</mml:mn></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M662" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> (% of actual)</oasis:entry>
         <oasis:entry colname="col4">Reconstructed <inline-formula><mml:math id="M663" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula> at TH <inline-formula><mml:math id="M664" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 100 using <inline-formula><mml:math id="M665" display="inline"><mml:mrow><mml:msubsup><mml:mo>∑</mml:mo><mml:mn mathvariant="normal">0</mml:mn><mml:mn mathvariant="normal">100</mml:mn></mml:msubsup><mml:mtext>TDEE</mml:mtext></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M666" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup><mml:mi mathvariant="normal">C</mml:mi></mml:mrow></mml:math></inline-formula> (% of actual)</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">Scenario A</oasis:entry>
         <oasis:entry colname="col2"><?xmltex \hack{\hfill}?>2.52 <inline-formula><mml:math id="M667" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M668" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">15</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><?xmltex \hack{\hfill}?>5.25 <inline-formula><mml:math id="M669" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M670" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">16</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (21)</oasis:entry>
         <oasis:entry colname="col4"><?xmltex \hack{\hfill}?>2.03 <inline-formula><mml:math id="M671" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M672" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">15</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (80)</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Scenario B</oasis:entry>
         <oasis:entry colname="col2"><?xmltex \hack{\hfill}?><inline-formula><mml:math id="M673" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.30 <inline-formula><mml:math id="M674" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M675" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">15</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><?xmltex \hack{\hfill}?><inline-formula><mml:math id="M676" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>6.22 <inline-formula><mml:math id="M677" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M678" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">16</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (48)</oasis:entry>
         <oasis:entry colname="col4"><?xmltex \hack{\hfill}?><inline-formula><mml:math id="M679" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.19 <inline-formula><mml:math id="M680" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M681" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">15</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (91)</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Scenario C</oasis:entry>
         <oasis:entry colname="col2"><?xmltex \hack{\hfill}?>7.47 <inline-formula><mml:math id="M682" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M683" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">16</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3"><?xmltex \hack{\hfill}?>6.16 <inline-formula><mml:math id="M684" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M685" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">16</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (82)</oasis:entry>
         <oasis:entry colname="col4"><?xmltex \hack{\hfill}?>7.21 <inline-formula><mml:math id="M686" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M687" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">16</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (97)</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p id="d1e10481">Although not applied as a <inline-formula><mml:math id="M688" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> metric in the studies we included in our review, our review of <inline-formula><mml:math id="M689" display="inline"><mml:mrow><mml:msup><mml:mtext>GWP</mml:mtext><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> (Sect. 6) suggests that it is
inferior to <inline-formula><mml:math id="M690" display="inline"><mml:mrow><mml:mi mathvariant="bold-italic">T</mml:mi><mml:mi mathvariant="bold-italic">D</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi><mml:mi mathvariant="bold-italic">E</mml:mi></mml:mrow></mml:math></inline-formula> as an indicator of future warming when the future time dependency or “lifetime” of <inline-formula><mml:math id="M691" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> is known or defined
a priori (Fig. 7b). However, for cases when <inline-formula><mml:math id="M692" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> is unknown or deemed too uncertain, one could argue that – as a scalar
metric – <inline-formula><mml:math id="M693" display="inline"><mml:mrow><mml:msup><mml:mtext>GWP</mml:mtext><mml:mo>*</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> has greater scientific merit than EESF when applied to step changes in <inline-formula><mml:math id="M694" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> from the
standpoint that <inline-formula><mml:math id="M695" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>'s atmospheric time dependency is taken explicitly into account. GWP – also a scalar metric – has some merit
from the standpoint that it is well-known, although scientifically its merits fade when the forcing agent is short-lived (Allen et al., 2018; Lee
et al., 2021; Lynch et al., 2020) – as is often the case for <inline-formula><mml:math id="M696" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>. As a scalar metric that accounts for <inline-formula><mml:math id="M697" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> 's time dependency,
we deem <inline-formula><mml:math id="M698" display="inline"><mml:mrow><mml:mi mathvariant="normal">Σ</mml:mi><mml:mtext>TDEE</mml:mtext></mml:mrow></mml:math></inline-formula> to have greater scientific merit than GWP because it is a better indicator of future warming, which is supported
quantitatively by the <inline-formula><mml:math id="M699" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula> reconstructions highlighted in Table 5, based on the <inline-formula><mml:math id="M700" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub><mml:mo>(</mml:mo><mml:mi>t</mml:mi><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula> scenarios
presented in Fig. 7a.</p>
      <p id="d1e10637">Although this review has provided needed guidance for choosing appropriate <inline-formula><mml:math id="M701" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> metrics according to the context in which they have merit,
users should always be mindful that <inline-formula><mml:math id="M702" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M703" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> are not necessarily additive. The global mean
temperature may respond differently to identical RFs, although there are ways to deal with this discrepancy – either by using
ERFs directly in the metric calculation or by adjusting RFs with appropriate efficacy factors. Such approaches require additional
modeling tools, which introduces additional uncertainties (Sect. 7). Efficacies for inhomogeneous forcings like <inline-formula><mml:math id="M704" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> are
spatial-pattern- and scale-dependent (Shindell et al., 2015) and are sensitive to the climate model set-up and experimental conditions (i.e., how,
where, and when <inline-formula><mml:math id="M705" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> is imposed in the model). Moreover, efficacies are forcing-type-dependent; that is, the forcing signal driving the
underlying temperature response may depend on multiple additional perturbations at the surface that are co-associated with <inline-formula><mml:math id="M706" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>. A good
example is LULCC, which perturbs a suite of additional biogeophysical properties affecting surface fluxes (Table 4), some of
which result in atmospheric feedbacks (or adjustments) that can counteract the <inline-formula><mml:math id="M707" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> -driven signal (Laguë et al., 2019). Since LULCC
represents a broad range of land-based forcings, each of which in turn represent a myriad combination of surface biogeophysical property
perturbations, the risk of misapplication of efficacies derived from climate modeling simulations of LULCC is inherently large.</p>
</sec>
<sec id="Ch1.S8.SS2">
  <label>8.2</label><title>Research roadmap</title>
      <p id="d1e10732">Research efforts directed towards building a scientific consensus surrounding the most appropriate <inline-formula><mml:math id="M708" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> estimation method (or
model) for use in metric computation would serve to enhance metric transparency and facilitate comparability across studies. Given the ease and
efficiency of applying radiative kernels for <inline-formula><mml:math id="M709" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> calculations, such efforts might entail systematic evaluations and
benchmarking of radiative kernels (e.g., as in Kramer et al., 2019) for <inline-formula><mml:math id="M710" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>.</p>
      <p id="d1e10773">Reducing uncertainty surrounding the efficacy of <inline-formula><mml:math id="M711" display="inline"><mml:mrow><mml:msub><mml:mtext>RF</mml:mtext><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> associated with a variety of underlying surface forcing types (i.e.,
specific LULCC conversions, geoengineering methods) is paramount to reducing the “additivity” uncertainty (Jones et al., 2013) of
RF-based metrics for <inline-formula><mml:math id="M712" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>. This can be achieved through extending existing climate modeling experimental protocols (e.g., LUMIP,
GeoMIP, RFMIP) or by creating new protocols that seek to systematically quantify the sensitivity of the global mean temperature response to variations
in the spatial pattern, extent, and magnitude of surface and TOA radiative forcings associated with <inline-formula><mml:math id="M713" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>.</p>
      <p id="d1e10810">Research is also needed to examine the relevance of accounting for the climate–carbon feedback in <inline-formula><mml:math id="M714" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> metrics, given that such feedback is
implicitly included in <inline-formula><mml:math id="M715" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>'s impulse response function (Gasser et al., 2017). Such research should be mindful of the regional climate
response patterns of the various surface forcing types associated with <inline-formula><mml:math id="M716" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> and how regional <inline-formula><mml:math id="M717" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> sinks are affected in turn by
the regional response patterns.</p>
      <p id="d1e10855">Finally, while not a research need per se, a discussion between metric scientists and users/policy makers is needed surrounding three topics (Myhre
et al., 2013): (i) useful applications, (ii) comprehensiveness, and (iii) the value of simplicity and transparency. The first involves identifying
which application(s) a particular <inline-formula><mml:math id="M718" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> metric is meant to serve. We have already shown for instance that the EESF metric is not
ideal for characterizing dynamic systems. As for comprehensiveness, from a scientific point of view we would ideally wish to be informed about the
totality of climate impacts of a <inline-formula><mml:math id="M719" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> perturbation at multiple scales (i.e, at both the local and global levels). But a user may often need
to aggregate this information, which necessitates trade-offs between impacts at different points in space, between impacts at different points in
time, and even between the choice of metric indicator (e.g., RF vs. <inline-formula><mml:math id="M720" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula>). Related to the value of simplicity and transparency is the
question of whether more complex (yet less transparent) model-based metrics (e.g., those based on ERF) are valued by users over simple and
more transparent metrics based on analytical formulations. The discussion here should weigh their trade-offs: the former may be more cumbersome to
apply or more easily misused, whereas the latter may inadequately capture important physical effects or system dynamics.</p>
</sec>
<sec id="Ch1.S8.SS3">
  <label>8.3</label><title>Concluding remarks</title>
      <p id="d1e10896">For the past several decades, emission metrics have proven useful in enabling users or decision makers to quickly perform calculations of the climate
impact of GHG emissions. Their common <inline-formula><mml:math id="M721" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent scale has provided flexibility in emissions trading schemes and international climate
policy agreements like the Kyoto Protocol. With the advent of the Paris Agreement and a broadened emphasis (Article 4) to include both emissions
<italic>and</italic> removals, more attention to land-based mitigation seems likely, and the need for a way to compare albedo and <inline-formula><mml:math id="M722" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> on an
equivalent scale may increase. This obliges the scientific community to provide users with better tools to do so.</p>
      <p id="d1e10924">This review has highlighted many of challenges associated with quantifying and interpreting <inline-formula><mml:math id="M723" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-equivalent metrics for <inline-formula><mml:math id="M724" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula> based
on the RF concept. A variety of metric alternatives exist, each with their own set of merits and uncertainties depending on the context in
which they are applied. The application of metrics always entails user choices, and while some are scientific, others – such as time frame – are
policy-related and cannot be informed by science alone. This review has provided guidance to practitioners for choosing a metric with maximum
scientific merit and minimum uncertainty according to the specific application context. Going forward, practitioners should always be mindful of the
inherent limitations of RF-based measures for <inline-formula><mml:math id="M725" display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi mathvariant="italic">α</mml:mi></mml:mrow></mml:math></inline-formula>, carefully weighing these against the uncertainties of metrics based on impacts
further down the cause–effect chain – such as a change in temperature.</p>
</sec>
</sec>

      
      </body>
    <back><notes notes-type="codeavailability"><title>Code availability</title>

      <p id="d1e10963">MATLAB code for the production of figures and tables may be made available upon request to the corresponding author.</p>
  </notes><notes notes-type="dataavailability"><title>Data availability</title>

      <p id="d1e10969">Global Carbon Budget data are freely accessible at  <ext-link xlink:href="https://doi.org/10.18160/gcp-2019" ext-link-type="DOI">10.18160/gcp-2019</ext-link> (Global Carbon Project, 2019).</p>
  </notes><notes notes-type="authorcontribution"><title>Author contributions</title>

      <p id="d1e10978">RMB conceived and wrote the original paper, produced all figures and tables, and carried out the formal analysis. MTL and RMB reviewed and edited the final paper.</p>
  </notes><notes notes-type="competinginterests"><title>Competing interests</title>

      <p id="d1e10985">The authors declare that they have no conflict of interest.</p>
  </notes><notes notes-type="disclaimer"><title>Disclaimer</title>

      <p id="d1e10991">Publisher’s note: Copernicus Publications remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.</p>
  </notes><ack><title>Acknowledgements</title><p id="d1e10997">We are grateful for comments and feedback provided by our colleague Gunnar Myhre and the two anonymous reviewers.</p></ack><notes notes-type="financialsupport"><title>Financial support</title>

      <p id="d1e11002">This research has been supported by the Norges Forskningsråd (grant no. 254966).</p>
  </notes><notes notes-type="reviewstatement"><title>Review statement</title>

      <p id="d1e11008">This paper was edited by Philip Stier and reviewed by two anonymous referees.</p>
  </notes><ref-list>
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    <!--<article-title-html>CO<sub>2</sub>-equivalence metrics for surface albedo change based on the radiative forcing concept: a critical review</article-title-html>
<abstract-html><p>Management of Earth's surface albedo is increasingly viewed as an important climate change mitigation strategy both on (Seneviratne et al., 2018)
and off (Field et al., 2018; Kravitz et al., 2018) the land. Assessing the impact of a surface albedo change involves employing a measure like
radiative forcing (<span style="" class="text">RF</span>) which can be challenging to digest for decision-makers who deal in the currency of CO<sub>2</sub>-equivalent
emissions. As a result, many researchers express albedo change (Δ<i>α</i>) <span style="" class="text">RF</span>s in terms of their CO<sub>2</sub>-equivalent effects,
despite the lack of a standard method for doing so, such as there is for emissions of well-mixed greenhouse gases (WMGHGs; e.g., IPCC AR5, Myhre
et al., 2013). A major challenge for converting Δ<i>α</i> <span style="" class="text">RF</span>s into their CO<sub>2</sub>-equivalent effects in a manner consistent
with current IPCC emission metric approaches stems from the lack of a universal time dependency following the perturbation (perturbation
<q>lifetime</q>). Here, we review existing methodologies based on the <span style="" class="text">RF</span> concept with the goal of highlighting the context(s) in which the
resulting CO<sub>2</sub>-equivalent metrics may or may not have merit. To our knowledge this is the first review dedicated entirely to the topic
since the first CO<sub>2</sub>-eq.  metric for Δ<i>α</i> surfaced 20 years ago. We find that, although there are some methods that sufficiently
address the time-dependency issue, none address or sufficiently account for the spatial disparity between the climate response to CO<sub>2</sub>
emissions and Δ<i>α</i> – a major critique of Δ<i>α</i> metrics based on the <span style="" class="text">RF</span> concept (Jones et al., 2013). We conclude that
considerable research efforts are needed to build consensus surrounding the <span style="" class="text">RF</span> <q>efficacy</q> of various surface forcing types associated
with Δ<i>α</i> (e.g., crop change, forest harvest), and the degree to which these are sensitive to the spatial pattern, extent, and
magnitude of the underlying surface forcings.</p></abstract-html>
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