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  <front>
    <journal-meta><journal-id journal-id-type="publisher">ACP</journal-id><journal-title-group>
    <journal-title>Atmospheric Chemistry and Physics</journal-title>
    <abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">Atmos. Chem. Phys.</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">1680-7324</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/acp-21-617-2021</article-id><title-group><article-title>Record low ozone values over the Arctic in<?xmltex \hack{\break}?>
boreal spring 2020</article-title><alt-title>Record low ozone values over the Arctic</alt-title>
      </title-group><?xmltex \runningtitle{Record low ozone values over the Arctic}?><?xmltex \runningauthor{M.~Dameris et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1">
          <name><surname>Dameris</surname><given-names>Martin</given-names></name>
          <email>martin.dameris@dlr.de</email>
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Loyola</surname><given-names>Diego G.</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-8547-9350</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Nützel</surname><given-names>Matthias</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Coldewey-Egbers</surname><given-names>Melanie</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-9275-498X</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3">
          <name><surname>Lerot</surname><given-names>Christophe</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Romahn</surname><given-names>Fabian</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3">
          <name><surname>van Roozendael</surname><given-names>Michel</given-names></name>
          
        </contrib>
        <aff id="aff1"><label>1</label><institution>Deutsches Zentrum für Luft- und Raumfahrt, Institut für Physik der Atmosphäre,<?xmltex \hack{\break}?>
Oberpfaffenhofen, Germany</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Deutsches Zentrum für Luft- und Raumfahrt, Institut für
Methodik der Fernerkundung,<?xmltex \hack{\break}?>
Oberpfaffenhofen, Germany</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>Royal Belgian Institute for Space Aeronomy (BIRA-IASB), Brussels, Belgium</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Martin Dameris (martin.dameris@dlr.de)</corresp></author-notes><pub-date><day>18</day><month>January</month><year>2021</year></pub-date>
      
      <volume>21</volume>
      <issue>2</issue>
      <fpage>617</fpage><lpage>633</lpage>
      <history>
        <date date-type="received"><day>21</day><month>July</month><year>2020</year></date>
           <date date-type="rev-request"><day>21</day><month>July</month><year>2020</year></date>
           <date date-type="rev-recd"><day>13</day><month>November</month><year>2020</year></date>
           <date date-type="accepted"><day>16</day><month>November</month><year>2020</year></date>
      </history>
      <permissions>
        <copyright-statement>Copyright: © 2021 Martin Dameris et al.</copyright-statement>
        <copyright-year>2021</copyright-year>
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://acp.copernicus.org/articles/21/617/2021/acp-21-617-2021.html">This article is available from https://acp.copernicus.org/articles/21/617/2021/acp-21-617-2021.html</self-uri><self-uri xlink:href="https://acp.copernicus.org/articles/21/617/2021/acp-21-617-2021.pdf">The full text article is available as a PDF file from https://acp.copernicus.org/articles/21/617/2021/acp-21-617-2021.pdf</self-uri>
      <abstract><title>Abstract</title>
    <p id="d1e154">Ozone data derived from the Tropospheric Monitoring Instrument
(TROPOMI) sensor on board the Sentinel-5 Precursor satellite show
exceptionally low total ozone columns in the polar region of the Northern Hemisphere (Arctic) in spring 2020. Minimum total ozone column values around
or below 220 Dobson units (DU) were seen over the Arctic for 5 weeks in
March and early April 2020. Usually the persistence of such low total ozone
column values in spring is only observed in the polar Southern Hemisphere (Antarctic) and not over the Arctic. These record low total
ozone columns were caused by a particularly strong polar vortex in the
stratosphere with a persistent cold stratosphere at higher latitudes, a
prerequisite for ozone depletion through heterogeneous chemistry. Based on
the ERA5, which is the fifth generation of the European Centre for
Medium-Range Weather Forecasts (ECMWF) atmospheric reanalysis, the Northern
Hemisphere winter 2019/2020 (from December to March) showed minimum polar cap
temperatures consistently below 195 K around 20 km altitude, which enabled
enhanced formation of polar stratospheric clouds. The special situation in
spring 2020 is compared and discussed in context with two other Northern Hemisphere spring seasons, namely those in 1997 and 2011, which also
displayed relatively low total ozone column values. However, during these
years, total ozone columns below 220 DU over several consecutive days were
not observed in spring. The similarities and differences of the atmospheric
conditions of these three events and possible explanations for the observed
features are presented and discussed. It becomes apparent that the monthly
mean of the minimum total ozone column value for March 2020 (221 DU) was
clearly below the respective values found in March 1997 (267 DU) and 2011
(252 DU), which highlights the special evolution of the polar stratospheric
ozone layer in the Northern Hemisphere in spring 2020. A comparison with a
typical ozone hole over the Antarctic (e.g., in 2016) indicates that although
the Arctic spring 2020 situation is remarkable, with total ozone column
values around or below 220 DU observed over a considerable area (up to 0.9 million km<inline-formula><mml:math id="M1" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>), the Antarctic ozone hole shows total ozone columns
typically below 150 DU over a much larger area (of the order of 20 million km<inline-formula><mml:math id="M2" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>). Furthermore, total ozone columns below 220 DU are typically
observed over the Antarctic for about 4 months.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <label>1</label><title>Introduction</title>
      <p id="d1e184">Today's operating satellite instruments produce a reliable picture of the
Earth's atmosphere and its chemical composition. These instruments monitor,
for example, the evolution of the stratospheric ozone layer (e.g., Loyola et
al., 2009), which is important for life on Earth. Unusually low ozone values
can occur in the polar regions if chemical and dynamical processes interact
in a specific way. A long-lived polar vortex with low stratospheric
temperatures can support significant ozone depletion, and a strong polar
vortex<?pagebreak page618?> itself can hamper meridional transport of ozone-rich air from lower
latitudes (e.g., Solomon, 1999; Solomon et al., 2014).
The largest concentrations of atmospheric ozone are found in the
stratospheric ozone layer, with about 90 % of the atmosphere's ozone
located at altitudes between 15 and 30 km (e.g., Langematz, 2019). The
Dobson unit (DU) – named after Gordon Dobson (1889–1976), who devised the
first instrument for measuring atmospheric ozone content – is used to
describe the total amount of ozone found in the atmosphere above a specific
location. Typically, an ozone hole in the Antarctic is defined as the area
where the total ozone column (TOC) is less than 220 DU (e.g., WMO, 2018). In
the Southern Hemisphere (SH) polar region (Antarctic) a TOC below 220 DU is
about 30 % under the climatological mean ozone value in austral spring,
which was determined for the years before 1980 (e.g., Chap. 4 in WMO,
1999; Chap. 3 in WMO, 2003). Climatological mean TOCs averaged over the
Northern Hemisphere (NH) polar region (Arctic) in boreal spring are higher
(<inline-formula><mml:math id="M3" display="inline"><mml:mo lspace="0mm">∼</mml:mo></mml:math></inline-formula> 400–450 DU; e.g., Dameris, 2010). Therefore, the decrease
of TOC below 220 DU during this period indicates a reduction of total ozone
in the order of 50 %. We note that NH winters with reduced wave activity
could be related to reduced transport of ozone into the stratospheric polar
vortex and to stronger ozone depletion in the lower stratosphere because of
lower temperatures (e.g., Tegtmeier et al., 2008). Additionally, a shift of
the tropopause to higher altitudes and a colder tropopause could lead in the
same direction (e.g., Manney et al., 2011).</p>
      <p id="d1e194">The south polar lower stratosphere cools significantly more in winter
(June–August) than the north polar lower stratosphere (December–February).
In the cold polar lower stratosphere in winter, polar stratospheric clouds
(PSCs) form during polar night. PSCs develop at temperatures below 195 K or
188 K at 50 hPa, which are approximate values that depend on HNO<inline-formula><mml:math id="M4" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula> and
H<inline-formula><mml:math id="M5" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O concentrations (see, for instance, Fig. 4-1 of Chap. 4 in WMO,
2018). Under these conditions, nitric acid trihydrate crystals (NAT:
HNO<inline-formula><mml:math id="M6" display="inline"><mml:mrow><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mo>×</mml:mo></mml:mrow></mml:math></inline-formula> 3H<inline-formula><mml:math id="M7" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>O; so-called NAT-PSCs) or ice PSCs are formed in
the following days or weeks, respectively. PSC particles allow heterogeneous
reactions to take place on their surfaces, which enable halogen compounds
(chlorine and bromine) to be released from reservoir compounds (e.g.,
ClONO<inline-formula><mml:math id="M8" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>, HCl) and then be converted to an active form. When the sun
returns in polar spring, active molecules, such as Cl<inline-formula><mml:math id="M9" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula> or HOCl, are
converted into reactive Cl and ClO. Ozone depletion follows via catalytic
photochemical reaction cycles. More details can be found in the review
article by Solomon (1999).</p>
      <p id="d1e256">Due to the prohibition of the production and usage of ozone-depleting
substances (among others CFCs, chlorofluorocarbons) in response to the
international activities to protect the ozone layer (Montreal Protocol,
1987, and its amendments), atmospheric concentrations of these chemical
substances (particularly CFCs) and their products have been reduced over the
last 20 years by about 15 % (Chap. 1 in WMO, 2018). Nevertheless, the
current atmospheric burden of CFCs is still enhanced with respect to 1980s
values as CFCs have lifetimes of several decades (SPARC, 2013).
Consequently, the chlorine concentration in the stratosphere is still high.
Based on the current scientific understanding, the chlorine content is
expected to reach pre-CFC-era conditions (i.e., levels similar to the ones
before 1980) around the middle of this century, and we can therefore expect
a return to pre-CFC values of the ozone layer in the next 30 to 40 years
(see Chaps. 3 and 4 in WMO, 2018).</p>
      <p id="d1e259">Notwithstanding the Montreal Protocol and the projected recovery of the
ozone layer, very low TOC values over the polar cap can occur not only in
the SH, but also in the NH. For instance, as shown in Fig. 1, in March and
early April 2020, very low TOC values were measured in the Arctic, although
the stratospheric chlorine content in 2020 was known to be lower than in
previous years (Chap. 1 in WMO, 2018).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1" specific-use="star"><?xmltex \currentcnt{1}?><label>Figure 1</label><caption><p id="d1e265">Total ozone column over the Northern Hemisphere on 5, 12,
19, and 28 March and 7 April 2020 measured by the TROPOMI instrument on board the
Sentinel-5 Precursor (S5P) satellite. The color scale shows Dobson units
(DU). The area with total ozone column values below 220 DU is denoted by
the white color. Grey areas near the North Pole indicate missing data during
polar night.</p></caption>
        <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://acp.copernicus.org/articles/21/617/2021/acp-21-617-2021-f01.png"/>

      </fig>

      <p id="d1e274">The dynamical conditions of the stratosphere as observed in the NH spring
2020 were unusual, showing an undisturbed polar stratospheric vortex with
low temperatures, as will be seen in the upcoming analysis. Comparable
dynamical conditions in the NH stratosphere in spring were noted in the
literature for 1997 (e.g., Coy et al., 1997; Manney et al., 1997;
Lefèvre et al., 1998; Hansen and Chipperfield, 1999) and 2011 (e.g.,
Manney et al., 2011; Sinnhuber et al., 2011; Kuttippurath et al., 2012;
Hommel et al., 2014). TOC values were low for an extended time period in
spring in these 2 years, but TOC values below 220 DU were not observed.
Although the dynamical conditions in winter and spring 2019/2020 were
unusual, they lie in the natural range of stratospheric dynamical
fluctuations in NH winter and early spring (e.g., Langematz et al., 2014).
The importance of stratospheric dynamics causing low TOC has been discussed
in detail in the last decades (e.g., Chaps. 4 and 12 in WMO, 1999; Chap. 3 in WMO, 2003; Chap. 3 in WMO, 2014; Solomon, 1999; Petzoldt, 1999; Rex et al., 2004; Tilmes et al., 2006; Kivi et al., 2007; Tegtmeier et al., 2008; Harris et al., 2010).</p>
      <p id="d1e277">Considering the dynamical conditions, it was not unexpected to measure low
TOC values within the polar vortex in NH spring 2020. However, as indicated
in Fig. 1, it is still noteworthy that the TOC values were below the
typical ozone hole threshold of 220 DU for about 5 weeks, despite the
reduced chlorine content in the stratosphere. The occurrence of TOC values
below 220 DU in March 2020 derived from satellite instrument measurements is
confirmed by ground-based measurements at different NH stations, in
particular at stations in Canada (e.g., Alert, Eureka, and Resolute). The
ozone data are available, for instance, at
<uri>http://www.temis.nl/uvradiation/UVarchive/stations_uv.html</uri>
(last access: 13 January 2021; van Geffen et al., 2017). Additional ozonesonde profiles are discussed in
detail by Wohltmann et al. (2020) and Bernhard et al. (2020).</p>
      <p id="d1e283">This study provides a description of the dynamical situation in NH winter
and spring 2019/2020, which for the first<?pagebreak page619?> time led to TOC values below 220 DU in larger areas of the polar vortex for an extended time period over the
Arctic. We compare winter 2019/2020 to winters with similar dynamical
conditions in Arctic spring but which did not show TOC values below 220 DU over the polar NH in spring over an extended time period. Further, we also
demonstrate that the low TOC values over the Arctic observed in spring 2020
are far from the conditions usually observed in the Antarctic ozone hole.</p>
      <p id="d1e286">In the next section (Sect. 2) the data sets used are introduced, including a
short description of the performed data processing. In Sect. 3 the special
situation in NH winter and spring 2019/2020 is presented in detail, and in
Sect. 4 it is compared with two NH winter and spring seasons, namely
1996/1997 and 2010/2011, where similar polar stratospheric conditions –
including low TOC values – have been observed. In addition, the
observations in Arctic winter and spring 2019/2020 are compared to a typical
Antarctic ozone hole as detected in 2016 and to the small Antarctic ozone
hole observed in 2019. The discussion of results and the conclusions are
presented in Sects. 5 and 6, respectively.</p>
</sec>
<sec id="Ch1.S2">
  <label>2</label><title>Data and data processing</title>
<sec id="Ch1.S2.SS1">
  <label>2.1</label><title>Meteorological data</title>
      <p id="d1e304">In this study the presented dynamical analyses are based on meteorological
data derived from the European Centre for Medium-Range Weather Forecasts'
(ECMWF's) most recent atmospheric reanalysis, ERA5, i.e., the fifth
generation (Hersbach et al., 2019b, 2020). The ERA5 data used in this study
cover the period from 1979 to 2020. For our investigations ERA5 temperature
and wind data were used at the provided 0.25<inline-formula><mml:math id="M10" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M11" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 0.25<inline-formula><mml:math id="M12" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> resolution. Daily mean data are calculated for the presentations of the
respective meteorological situations from the ERA5 hourly data on pressure
levels (Hersbach et al., 2018). Monthly mean values are obtained from the
monthly mean data at pressure levels (Hersbach et al., 2019a). In addition,
daily potential vorticity (PV) fields on isentropes have been derived from
hourly PV data on isentropes, which were obtained from the full ERA5 data
set (Copernicus Climate Change Service (C3S), 2017) and regridded to a
regular latitude longitude grid (of roughly 0.28<inline-formula><mml:math id="M13" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M14" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 0.28<inline-formula><mml:math id="M15" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>). ERA5 (raw) data are publicly available. For details, see the Data Availability section.</p>
</sec>
<sec id="Ch1.S2.SS2">
  <label>2.2</label><title>Ozone data</title>
      <p id="d1e366">Ozone data from July 2019 to April 2020 from the Tropospheric Monitoring
Instrument (TROPOMI) sensor on board the EU/ESA Copernicus Sentinel-5
Precursor satellite are scientifically used for the first time in
combination with the long-term ozone data set from the European satellite
data record GOME-type Total Ozone Essential Climate Variable (GTO-ECV) from
July 1995 to June 2019 (Coldewey-Egbers et al., 2015). The publicly
available (Level 2) TOC data for July 2019 to April 2020 are derived from the
TROPOMI sensor using the GODFIT algorithm (Lerot et al., 2014). The
estimated mean magnitude of the bias of the TROPOMI TOC compared with
ground-based measurements is less than 1 %,<?pagebreak page620?> with a mean standard deviation
of up to 2.5 % (Garane et al., 2019). An initial comparison of TOCs from
TROPOMI and the Ozone Monitoring Instrument (OMI) on board the NASA Aura
spacecraft indicated that TROPOMI TOCs are slightly smaller (<inline-formula><mml:math id="M16" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula> %) than OMI TOCs. A similar difference is thus expected with respect to
GTO-ECV since OMI provides the reference basis for the combined record (see
next paragraph). The TROPOMI TOC images presented for the first time in this
study are based on daily mean data regridded to 1<inline-formula><mml:math id="M17" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M18" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 1<inline-formula><mml:math id="M19" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> resolution to facilitate the comparison with the GTO-ECV data. For details, see the Data Availability section.</p>
      <p id="d1e407">GTO-ECV has been developed in the framework of the European Space Agency's
Climate Change Initiative ozone project and is based on observations from
different satellite sensors: the Global Ozone Monitoring Experiment on board
the second European Remote Sensing satellite (GOME/ERS-2), the Scanning
Imaging Absorption Spectrometer for Atmospheric Chartography on board the
Environmental Satellite (SCIAMACHY/ENVISAT), the Ozone Monitoring Instrument
on board the Aura satellite (OMI/Aura), and the Global Ozone Monitoring
Experiment second generation on board the MetOp satellite (GOME-2/MetOp),
covering the time period from July 1995 to June 2019 (Coldewey-Egbers et
al., 2015). As for TROPOMI, the retrieval algorithm GODFIT (Lerot et al.,
2014) is used to derive TOCs from the measurements of the individual
satellite sensors. Before the separate data records are merged into one
single product, adjustments are applied in order to minimize possible
inter-sensor biases and/or drifts. If not accounted for, such discrepancies
can introduce unwanted discontinuities or artificial trends in the combined
record. Due to its notable temporal stability, OMI was selected to serve as
a reference for the other instruments. The data are then adjusted by using a
correction that depends on latitude and time. The agreement between GTO-ECV
and ground-based observations is 0.5 %–1.5 % peak-to-peak amplitude with
a negligible long-term drift in the NH (Garane et al., 2018), and the
difference between GTO-ECV and an “adjusted” TOC data set based on
reanalysis data is between <inline-formula><mml:math id="M20" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.5</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mo>±</mml:mo><mml:mspace linebreak="nobreak" width="0.125em"/></mml:mrow></mml:math></inline-formula>1.7 % and <inline-formula><mml:math id="M21" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1.0</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mo>±</mml:mo><mml:mspace width="0.125em" linebreak="nobreak"/></mml:mrow></mml:math></inline-formula>1.1 %
(for details, see Coldewey-Egbers et al., 2020). In particular, the excellent
temporal stability makes the GTO-ECV data record suitable and useful for
applications related to long-term investigations of the ozone layer. In this
study we use the daily mean data product at 1<inline-formula><mml:math id="M22" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M23" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 1<inline-formula><mml:math id="M24" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> resolution to analyze minimum ozone columns in the NH polar region during
the past 24 years. During polar night, the satellite sensors used cannot
provide measurements. For instance, in December, north of about
70<inline-formula><mml:math id="M25" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, no observations are available. With returning sunlight, the
coverage in the NH high-latitude regions improves, and global coverage
resumes around 20 March.</p>
</sec>
</sec>
<sec id="Ch1.S3">
  <label>3</label><title>Situation in Northern Hemisphere winter and spring 2019/2020</title>
      <p id="d1e482">Arctic winter and early spring 2019/2020 showed a persistent stratospheric
polar vortex with strong zonal winds from mid-December until early April.
Figure 2 presents the potential vorticity (PV) field of ERA5 in the NH at
the isentropic surface of 475 K (around 20 km altitude) and shows the
position and strength of the polar vortex. The region of strong PV
gradients, which is represented here by the contour line of 36 PV units
(e.g., Wohltmann et al., 2020), indicates the edge of the polar vortex. The
figure illustrates that the polar vortex is strong in March and early April
and that the position of the polar vortex coincides with the region of low
TOC values (Fig. 1). Figure 3 shows strong zonal mean zonal wind speeds at
60<inline-formula><mml:math id="M26" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 10 hPa (about 30 km altitude) in the ERA5 data (magenta
line and dots in the figure), which are higher than the monthly mean values
for the time period from 1979/1980 to 2019/2020 (see grey dots in the
figure). This finding is in line with a similar analysis by Lawrence et al. (2020), who used Modern-Era Retrospective analysis for Research and
Applications version 2 (MERRA-2) data. In addition, Lawrence et al. (2020)
showed that the polar vortex was generally stronger than usual (with respect
to the climatological mean) in the polar stratosphere from November to
April. Further, their analysis showed the height dependence of the zonal
mean zonal wind anomalies, and it was found that the anomalies in NH spring
are most pronounced around 10 hPa (and above). Smaller dynamical
fluctuations were detected in winter 2019/2020, which were caused by
planetary wave activity (Lawrence et al., 2020; for additional information,
see <uri>https://acd-ext.gsfc.nasa.gov/Data_services/met/ann_data.html</uri>, last access: 13 January 2021; or
<uri>https://ozonewatch.gsfc.nasa.gov/</uri>, last access: 13 January 2021; a key reference for such analyses is
Newman et al., 2001). No minor or major warmings of the polar stratosphere
were observed (see below), and the polar vortex was mostly undisturbed and
showed a circular shape, except for the period from mid-January to beginning
of February 2020, as can be seen from Fig. 3. These results are in
agreement with Lawrence et al. (2020). In Fig. 4 the ERA5 monthly mean
zonal winds derived for the NH in January, February, and March 2020 indicate
a persistent strong polar vortex, with maximum zonal wind speeds up to 118 m s<inline-formula><mml:math id="M27" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> at 10 hPa in January.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2" specific-use="star"><?xmltex \currentcnt{2}?><label>Figure 2</label><caption><p id="d1e514">Potential vorticity (PV) on the 475 K isentropic surface over the
Northern Hemisphere on 5, 12, 19, 28 March and 7 April 2020 based on ERA5.
The color scale shows potential vorticity units (PVUs); 1 PVU is
10<inline-formula><mml:math id="M28" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">6</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> m<inline-formula><mml:math id="M29" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> s<inline-formula><mml:math id="M30" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> K kg<inline-formula><mml:math id="M31" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>. The grey contour highlights
the 36 PVU. Red contour lines indicate the polar temperature field,
with values ranging from 210 to 195 K; the distance of isolines is 5 K.</p></caption>
        <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://acp.copernicus.org/articles/21/617/2021/acp-21-617-2021-f02.png"/>

      </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3"><?xmltex \currentcnt{3}?><label>Figure 3</label><caption><p id="d1e573">Daily (lines) and monthly (dots; in the center of each month) mean
zonal mean zonal wind (in m s<inline-formula><mml:math id="M32" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>) at 10 hPa (about 30 km altitude): the
Northern Hemisphere winters 1996/1997, 2010/2011, 2018/2019, and 2019/2020 at
60<inline-formula><mml:math id="M33" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N from 1 December to 30 April based on ERA5 data are displayed
in blue, green, brown, and magenta (lines and dots); the Southern Hemisphere
winters 2016 and 2019 at 60<inline-formula><mml:math id="M34" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S from 1 June to 1 November
(attention: the respective data are shifted by 6 months) based on ERA5
data are displayed in red and purple (lines and dots with crosses).
Additional monthly means for the Northern Hemisphere winters from 1979/1980
to 2019/2020 are shown as grey dots in the center of each month. For
simplicity, the leap day in 2020 (29 February) was neglected in the daily
time series.</p></caption>
        <?xmltex \igopts{width=213.395669pt}?><graphic xlink:href="https://acp.copernicus.org/articles/21/617/2021/acp-21-617-2021-f03.png"/>

      </fig>

      <?xmltex \floatpos{tp}?><fig id="Ch1.F4" specific-use="star"><?xmltex \currentcnt{4}?><label>Figure 4</label><caption><p id="d1e615">ERA5 monthly mean wind at 10 hPa (about 30 km altitude), showing a
strong vortex in the north polar region, with speeds of up to 118, 103, and 89 m s<inline-formula><mml:math id="M35" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> for January to March 2020
respectively.</p></caption>
        <?xmltex \igopts{width=426.791339pt}?><graphic xlink:href="https://acp.copernicus.org/articles/21/617/2021/acp-21-617-2021-f04.png"/>

      </fig>

      <p id="d1e636">The dynamical conditions in winter 2019/2020 with low planetary wave
activity result in very low temperatures in the polar lower stratosphere
during polar night, especially in January, February, and March, which cause a
strong polar vortex as a response. In the following, our analyses of lower
stratospheric temperatures focus on the 50 hPa pressure level (about 20 km
altitude), which is within the height range important for ozone depletion.
Figure 5 shows that the monthly mean temperatures in January, February, and
March 2020 were very low in comparison with the respective mean<?pagebreak page621?> values
calculated for the last 4 decades (1979/1980–2019/2020). In March 2020 the
calculated maximum temperature difference with respect to the long-term mean
was <inline-formula><mml:math id="M36" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>23.8 K. In Fig. 6 (magenta line) minimum polar temperatures below
195 K at 50 hPa are detected in the polar cap region (50–90<inline-formula><mml:math id="M37" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N) from the beginning of December until the end of March.
Further analyses of the temperature field at 50 hPa indicate large areas
below 195 K. This result agrees with the analyses by Lawrence et al. (2020)
based on MERRA-2 and by Wohltmann et al. (2020) based on ERA5. As indicated
in Fig. 7 (dotted magenta line), the maximum daily mean area of
temperatures below 195 K is 13 <inline-formula><mml:math id="M38" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M39" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">12</mml:mn></mml:msup></mml:math></inline-formula> m<inline-formula><mml:math id="M40" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>, found at the end
of January. At the end of March, the daily cumulative area below 195 K, i.e., the sum of the daily areas below 195 K up to the respective date, results in
about 920 <inline-formula><mml:math id="M41" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M42" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">12</mml:mn></mml:msup></mml:math></inline-formula> m<inline-formula><mml:math id="M43" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>. This led to conditions allowing for
the formation of NAT-PSCs at 50 hPa for about 3.5 months (see Figs. 6 and
7). Our results are supported by Lawrence et al. (2020) and Wohltmann et al. (2020), who among others analyzed the volume of PSCs (see also Manney et
al., 2020). When the sun rises in spring, sunlight delivers the energy
required for starting a chemical depletion process of ozone (e.g., Solomon,
1999). In spring 2020 record low Arctic TOC values below 220 DU developed
within the boundaries of the strong polar vortex for 8 continuous days
from 12 to 19 March (see Fig. 1 and also the magenta line in Fig. 8). A
region of significantly reduced TOC values inside the polar vortex was
observed over the polar cap from the beginning of March until early April 2020 (Fig. 1).</p>

      <?xmltex \floatpos{tp}?><fig id="Ch1.F5" specific-use="star"><?xmltex \currentcnt{5}?><label>Figure 5</label><caption><p id="d1e708">ERA5 monthly mean temperature at 50 hPa (about 20 km altitude) for
January to March (columns 1 to 3) for year 2020 <bold>(a–c)</bold> and the
corresponding temperature anomalies <bold>(d–f)</bold> with respect to the average
from 1979–2019, showing negative differences of up to <inline-formula><mml:math id="M44" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>9.93 K in January,
<inline-formula><mml:math id="M45" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>18.44 K in February, and <inline-formula><mml:math id="M46" display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>23.83 K in March 2020.</p></caption>
        <?xmltex \igopts{width=426.791339pt}?><graphic xlink:href="https://acp.copernicus.org/articles/21/617/2021/acp-21-617-2021-f05.png"/>

      </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F6"><?xmltex \currentcnt{6}?><label>Figure 6</label><caption><p id="d1e746">Minimum values of daily (lines) and of monthly (dots; in the
center of each month) mean temperatures (in K) at 50 hPa (about 20 km altitude): the Northern Hemisphere winters 1996/1997, 2010/2011, 2018/2019,
and 2019/2020 for 50–90<inline-formula><mml:math id="M47" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N from 1 December to 30 April
based on ERA5 data are displayed by blue, green, brown, and magenta (lines
and dots); the Southern Hemisphere winters 2016 and 2019 for 50–90<inline-formula><mml:math id="M48" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N from 1 June to 1 November based on ERA5 data are displayed
in red and purple (lines and dots with crosses). The Southern Hemisphere
data are shifted by 6 months. Additionally, the minima of the monthly mean
temperature data for the Northern Hemisphere winters from 1979/1980 to
2019/2020 are shown as grey dots in the center of each month. For
simplicity, the leap day in 2020 (29 February) was neglected in the daily
time series. The dashed dark green horizontal lines at 195 and 188 K
mark the thresholds for the formation of NAT-PSCs and ice PSCs, respectively
(see text).</p></caption>
        <?xmltex \igopts{width=213.395669pt}?><graphic xlink:href="https://acp.copernicus.org/articles/21/617/2021/acp-21-617-2021-f06.png"/>

      </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F7"><?xmltex \currentcnt{7}?><label>Figure 7</label><caption><p id="d1e776">Daily area (in 10<inline-formula><mml:math id="M49" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">12</mml:mn></mml:msup></mml:math></inline-formula> m<inline-formula><mml:math id="M50" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>) with temperature less than 195 K
at 50 hPa (about 20 km altitude) in the region 50–90<inline-formula><mml:math id="M51" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N from 1 December to 30 April based on ERA5 data (solid lines). Daily
cumulative values are indicated as faint lines. The Northern Hemisphere
winters 1996/1997, 2010/2011, 2018/2019, and 2019/2020 are displayed by blue,
green, brown, and magenta lines, respectively. For simplicity, the leap day
in 2020 (29 February) was neglected in the daily time series.</p></caption>
        <?xmltex \igopts{width=213.395669pt}?><graphic xlink:href="https://acp.copernicus.org/articles/21/617/2021/acp-21-617-2021-f07.png"/>

      </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F8"><?xmltex \currentcnt{8}?><label>Figure 8</label><caption><p id="d1e814">Annual cycle of the minimum total column ozone values (in Dobson
Units, DU) in the north polar region between 50 and
90<inline-formula><mml:math id="M52" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N and in the south polar region between 50 and
90<inline-formula><mml:math id="M53" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S derived from the European satellite data record GOME-type
Total Ozone Essential Climate Variable (GTO-ECV) from July 1995 to June 2019
and TROPOMI data from July 2019 to April 2020. The thick black line shows
the GTO-ECV mean annual cycle in the north polar region, with the lowest ozone
values in the fall season (October, November) and the highest ozone values in late
spring (April, May). The thin black lines indicate the maximum and minimum
values for the complete time period of satellite measurements starting in
1995. The light grey shading denotes the 10th percentile and the
90th percentile, and the dark grey shading denotes the 30th
percentile and the 70th percentile, respectively. The magenta line
shows the minimum values for the TROPOMI total ozone in the 2019/2020
season. The blue and green lines show the minimum values for the total ozone
in the years 1996/1997 and 2010/2011, respectively. For comparison, the
annual cycle of the minimum total column ozone values in the south polar
region is shown in the years 2016 (red line) and 2019 (purple line). The
Southern Hemisphere data are shifted by 6 months.</p></caption>
        <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://acp.copernicus.org/articles/21/617/2021/acp-21-617-2021-f08.png"/>

      </fig>

      <p id="d1e841">In Figs. 3 and 6, corresponding values of mean zonal winds and minimum
polar cap temperatures over the Antarctic are shown. In particular, a
typical, undisturbed SH situation in 2016 (red lines) and the situation in
2019 (purple lines) with a dynamically disturbed spring season are
presented. It becomes evident that in winter the zonal mean zonal winds (at
60<inline-formula><mml:math id="M54" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S, 10 hPa) are stronger (by about 30 m s<inline-formula><mml:math id="M55" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>), and the
minimum temperatures (polar cap, 50 hPa) are much lower (about 10 K) than in the Arctic (see also Wargan et al., 2020).</p>
      <p id="d1e865">The temporal evolution of minimum TROPOMI TOC values north of 50<inline-formula><mml:math id="M56" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N from July 2019 until April 2020 is presented in Fig. 8 (magenta line)
and compared with historical values from the GTO-ECV data record (see
Sect. 2 for details). In winter 2019/2020 ozone values were slightly below
mean conditions most of the time until the end of February with respect to
mean minimum TOC values (Fig. 8; magenta line vs. thick black line). There
were however several short-term deviations towards even lower TOC, during
so-called ozone mini-hole events (e.g., Millán and Manney, 2017, and
references therein). The most noteworthy<?pagebreak page622?> examples occurred in early December 2019 (3 and 4 December), the beginning of January 2020 (4–8 January), and the end of January (25–27 January). Ozone mini-holes are synoptic-scale features (with a
high-pressure system in the troposphere below the stratospheric polar
vortex, i.e., a low-pressure area) with significantly reduced TOC values. It
is well understood that ozone mini-holes primarily result from dynamical
processes (e.g., Millán and Manney, 2017). The positions of the
mini-holes correlate well with minima of potential vorticity near the
tropopause (Peters et al., 1995; James and Peters, 2002). Hoinka et al. (1996) found that about 50 % of short-term TOC fluctuations in the NH can
be explained by variations of the tropopause pressure (see also Manney et
al., 2011). Furthermore, Steinbrecht et al. (1998) showed that an increase
of tropopause height by 1 km is connected with a reduction of TOC
by 16 DU. Figure 8 illustrates that such mini-hole events occur regularly
(the lower light grey line) during NH winter. The ozone mini-holes very
commonly develop in the North Atlantic region and then often drift
eastward towards northern Europe within a few days (James, 1998). This was
also the case for the three examples seen in winter 2019/2020, with minimum
TOC found over northern Europe (not shown). Since the polar vortex already
existed in late November and early December 2019 (Lawrence et al., 2020)
with lower than usual TOC, the ozone mini-hole, for instance on 3
and 4 December, showed very low TOC values (170 DU; Fig. 8) at 65<inline-formula><mml:math id="M57" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N,
northeast of United Kingdom and west of Scandinavia.</p>
      <p id="d1e886">Because the polar vortex was persistent and strong since the beginning of
the Arctic winter 2019/2020, reduced TOC values inside the polar vortex and
higher TOC values outside were observed from January 2020 onwards but with
TOC values clearly above 220 DU inside the vortex. As indicated in Fig. 4,
the polar vortex with persistent strong zonal winds and strong PV gradients
(see Fig. 2) prevented the meridional transport of ozone-rich air from
lower latitudes towards the NH polar region. Lawrence et al. (2020) showed
that the undisturbed polar vortex acted as a strong transport barrier. This
is, among others, indicated by ozonesonde and ground-based measurements at
different NH stations, with lower TOC values in the inner part of the polar
vortex and higher TOC values outside. Respective ozone data are available at
<uri>http://www.temis.nl/uvradiation/UVarchive/stations_uv.html</uri>
(last access: 13 January 2021; van Geffen et al., 2017) and also available at
<uri>https://woudc.org/data/explore.php</uri> (last access: 13 January 2021) and at <uri>https://www.ndacc.org</uri> (last access: 13 January 2021; see also Wohltmann et al., 2020 and Bernhard et al., 2020). After mid-February, low TOC values inside the polar vortex can be identified also in the TROPOMI
data (not shown), which is indicated by a strong horizontal ozone gradient
in the vicinity of the polar jet with the strongest zonal winds.</p>
      <?pagebreak page624?><p id="d1e899">Remarkable deviations from normal Arctic conditions were found starting in
early March 2020 until early April, when low TOC values in the north polar
region were detected (magenta line in Fig. 8): the long period of
unusually low TOC started in early March 2020, falling below 220 DU for the
first time on 2 March, and continued with similarly low TOC – including a
period of 8 consecutive days with minimum TOCs below 220 DU – until 7 April. For the first time TOC values near or below 220 DU unrelated to ozone
mini-hole events were observed for a period of about 5 weeks,
corresponding to new record low values for this time of the year. The
maximum area with TOC below 220 DU was 0.9 million km<inline-formula><mml:math id="M58" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> (<inline-formula><mml:math id="M59" display="inline"><mml:mrow><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0.9</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mo>×</mml:mo><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mn mathvariant="normal">10</mml:mn><mml:mn mathvariant="normal">12</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> m<inline-formula><mml:math id="M60" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>) on 12 March (Fig. 1). For 12 March, the
size of the polar vortex is 21.75 million km<inline-formula><mml:math id="M61" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> (Fig. 2). This is in
the order of 4 % of the polar vortex area at the 475 K isentropic surface
inside the 36 PV unit contour (Wohltmann et al., 2020). In comparison with
corresponding values of a typical ozone hole in the Antarctic (here 2016; Fig. 8, red line; Fig. 9d) the area of low TOC (below 220 DU) is much smaller, and the minimum TOC is clearly higher. The Antarctic
ozone hole in spring 2016 showed minimum TOC clearly below 150 DU, and TOC
values below 220 DU were found for a period of about 4 months. The maximum
area of the ozone hole was in the order of 20 million km<inline-formula><mml:math id="M62" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> (Fig. 9d). Even the maximum area of record low TOC values (below 220 DU),
detected in the Arctic in spring 2020 (Fig. 9a), is just about
10 % of the exceptionally small Antarctic ozone hole observed in SH spring 2019; see Wargan et al. (2020), who reported an ozone hole area of roughly 5–10 million km<inline-formula><mml:math id="M63" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> during September and October 2019 (see also Fig. 9e).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F9" specific-use="star"><?xmltex \currentcnt{9}?><label>Figure 9</label><caption><p id="d1e969">Monthly mean total ozone columns over the Northern Hemisphere in
March 1997 <bold>(a)</bold>, 2011 <bold>(b)</bold>, and 2020 <bold>(c)</bold> and the Southern Hemisphere in October 2016 <bold>(d)</bold>
and 2019 <bold>(e)</bold>. The plot for March 1997 is based on GOME/ERS-2 data
with a limited spatial sampling, which induces the orbit structures on the
monthly mean values; the plots from 2011 and 2016 are based on GTO-ECV; and
the plots from 2019 and 2020 are based on TROPOMI/S5P. Grey areas near the
poles indicate missing data during polar night.</p></caption>
        <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://acp.copernicus.org/articles/21/617/2021/acp-21-617-2021-f09.png"/>

      </fig>

</sec>
<sec id="Ch1.S4">
  <label>4</label><title>Situations in Northern Hemisphere winter and spring 1996/1997 and
2010/2011</title>
      <p id="d1e1001">There are two other prominent spring seasons in the NH, which showed
similarly strong and cold stratospheric polar vortices. In particular,
comparable dynamical conditions in the NH stratosphere were observed in
February and March 1997 (e.g., Coy et al., 1997; Manney et al., 1997;
Lefèvre et al., 1998; Hansen and Chipperfield, 1999) and 2011 (e.g.,
Manney et al., 2011; Sinnhuber et al., 2011; Kuttippurath et al., 2012;
Hommel et al., 2014). We note that the characteristics of the polar vortex –
which in turn have direct or indirect consequences for the TOC, either by
chemical ozone depletion or (meridional) transport of air masses –<?pagebreak page625?> vary in
different NH winters (e.g., Petzoldt, 1999; Tegtmeier et al., 2008; see also
Manney et al., 2011).</p>
      <p id="d1e1004">In Fig. 3 the temporal evolution of the two stratospheric polar vortices
in the NH in 1996/1997 (blue line) and 2010/2011 (green line) is indicated
by the zonal mean zonal wind speed at 60<inline-formula><mml:math id="M64" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 10 hPa. In comparison
with the dynamical situation in January, February, and March 2020 (magenta
line in Fig. 3), the respective time periods in 1997 and 2011 also showed
a persistent polar vortex with high zonal wind speeds, which reached values
of up to more than 50 m s<inline-formula><mml:math id="M65" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>. These values are higher than the long-term
mean values, which show an increase up to 40 m s<inline-formula><mml:math id="M66" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> until the beginning
of January and a decrease thereafter (see also Fig. 1 in Lee and Butler,
2020). While the temporal evolution of the dynamical situation in Arctic
spring 2011 was very similar to that of 2020 with a persistent polar vortex
and high zonal wind speeds until mid-March, the period of strong zonal winds
in 1997 continued until April. The polar vortex in December 1996 was
weak, and therefore polar temperatures were relatively high (higher than 195 K; see next paragraph). The evolution of the winter vortices in December 2010 and 2019 is similar, reaching zonal wind speeds of about 40 m s<inline-formula><mml:math id="M67" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>
in mid-December. Similar values were shown by Lawrence et al. (2020), who
looked at MERRA-2 data. In this context, Manney et al. (2011) showed that in
2011 the meridional transport was weak at the edge of the polar vortex (i.e., a strong barrier) throughout the winter. Less ozone was transported from
lower latitudes to higher latitudes. The meridional transport was enhanced
in 1997 because the polar vortex was weaker in December and January (Manney
et al., 2011).</p>
      <p id="d1e1052">In all 3 years, February and March dynamical conditions led to low
stratospheric temperatures in the polar cap region (50–90<inline-formula><mml:math id="M68" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N). The temporal evolution of the observed daily minimum
temperatures at 50 hPa is shown in Fig. 6. The minimum temperatures were
below the threshold temperature for the formation of NAT-PSCs (195 K) in
February and March of all 3 years. Minimum temperatures at 50 hPa in
December 2019 and January 2020 most of the time were slightly lower than the
minimum temperatures in December/January 2010/2011. In turn, the minimum
temperatures in December/January are clearly higher in 1996/1997 than in
2010/2011 and 2019/2020. The minimum values of the monthly mean temperatures
are given in Table 1, indicating low temperatures in December 2019 and
January and February 2020 (see also the colored dots in Fig. 6).</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1" specific-use="star"><?xmltex \currentcnt{1}?><label>Table 1</label><caption><p id="d1e1068">Minimum temperatures (in kelvin) of the polar cap region
(50–90<inline-formula><mml:math id="M69" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N) at 50 hPa (about 20 km altitude) based on
the monthly mean temperatures from ERA5 in December, January, February, and
March of 1996/1997, 2010/2011, and 2019/2020 and the long-term mean values
(1979/1980–2019/2020), respectively.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="5">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:thead>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">Min. temp. 50 hPa</oasis:entry>
         <oasis:entry colname="col2">December</oasis:entry>
         <oasis:entry colname="col3">January</oasis:entry>
         <oasis:entry colname="col4">February</oasis:entry>
         <oasis:entry colname="col5">March</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">1996/1997</oasis:entry>
         <oasis:entry colname="col2">201.3</oasis:entry>
         <oasis:entry colname="col3">196.5</oasis:entry>
         <oasis:entry colname="col4">191.8</oasis:entry>
         <oasis:entry colname="col5">192.7</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2010/2011</oasis:entry>
         <oasis:entry colname="col2">195.6</oasis:entry>
         <oasis:entry colname="col3">194.2</oasis:entry>
         <oasis:entry colname="col4">191.2</oasis:entry>
         <oasis:entry colname="col5">194.7</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2019/2020</oasis:entry>
         <oasis:entry colname="col2">194.3</oasis:entry>
         <oasis:entry colname="col3">190.7</oasis:entry>
         <oasis:entry colname="col4">190.8</oasis:entry>
         <oasis:entry colname="col5">194.6</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">Long-term means (1979/1980–</oasis:entry>
         <oasis:entry colname="col2">197.0</oasis:entry>
         <oasis:entry colname="col3">195.6</oasis:entry>
         <oasis:entry colname="col4">199.5</oasis:entry>
         <oasis:entry colname="col5">205.5</oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">2019/2020)</oasis:entry>
         <oasis:entry colname="col2"/>
         <oasis:entry colname="col3"/>
         <oasis:entry colname="col4"/>
         <oasis:entry colname="col5"/>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p id="d1e1206">A series of studies published in the past highlight the differences of the
two winters 1996/1997 and 2010/2011, in particular regarding polar chemical
processes (e.g., Manney et al., 2011; Kuttippurath et al., 2012; Chap. 3
in WMO, 2014). Severe chemical ozone loss was observed in spring 2011
(Manney et al., 2011). In spring 1997 the chemical ozone loss was only
moderate (Manney et al., 1997; Tegtmeier et al., 2008). The most important
reason according to these studies was the late development of the polar
vortex and late drop of temperatures below PSC thresholds in winter
1996/1997<?pagebreak page626?> (see also Table 1 and Figs. 6 and 7). Recent studies found that
the maximum ozone loss in spring 2020 was similar to that of spring 2011
(e.g., Manney et al., 2020; Wohltmann et al., 2020; Grooß and
Müller, 2020). These papers also found that TOC values were lower in
2020 because chemical loss started earlier and because of less horizontal
mixing due to a permanent strong vortex.</p>
      <p id="d1e1209">As demonstrated in Fig. 7, the daily areas with temperatures below 195 K
at the 50 hPa pressure level are obviously larger in 2019/2020 (magenta
line) than in 1996/1997 (blue line) and 2010/2011 (green line). In
particular, the cumulative areas with temperatures below 195 K at 50 hPa are
markedly different: whereas in 2019/2020 the cumulative area was about
920 <inline-formula><mml:math id="M70" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M71" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">12</mml:mn></mml:msup></mml:math></inline-formula> m<inline-formula><mml:math id="M72" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>, in 1996/1997 it was about 370 <inline-formula><mml:math id="M73" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M74" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">12</mml:mn></mml:msup></mml:math></inline-formula> m<inline-formula><mml:math id="M75" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>, and in 2010/2011 it was about 650 <inline-formula><mml:math id="M76" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M77" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">12</mml:mn></mml:msup></mml:math></inline-formula> m<inline-formula><mml:math id="M78" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>. Furthermore, in the last week of January 2020 the temperatures at
50 hPa went below 188 K (magenta line in Fig. 6), the typical ice PSC
threshold (PSC type 2, ice PSCs; see, for instance, Fig. 4-1 of Chap. 4 in
WMO, 2018). The maximum daily area with temperatures below 188 K at 50 hPa
was 2.8 <inline-formula><mml:math id="M79" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M80" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">12</mml:mn></mml:msup></mml:math></inline-formula> m<inline-formula><mml:math id="M81" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> on 30 January, and the cumulative area
with temperatures below 188 K at 50 hPa reached its maximum of 18 <inline-formula><mml:math id="M82" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M83" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">12</mml:mn></mml:msup></mml:math></inline-formula> m<inline-formula><mml:math id="M84" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> on 2 March 2020. While the threshold for ice PSCs was not
reached in 1996/1997, in 2010/2011 the cumulative area with temperatures
below 188 K at 50 hPa was estimated to be 4.3 <inline-formula><mml:math id="M85" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M86" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">12</mml:mn></mml:msup></mml:math></inline-formula> m<inline-formula><mml:math id="M87" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>.</p>
      <p id="d1e1365">To summarize, in all 3 years the temperatures in the lower stratosphere
in February and March were in a similar range, showing colder conditions
than usual. December 2019 and January 2020 were also clearly colder than the
long-term mean conditions (Table 1). Winter 2019/2020 showed a larger
area below the formation temperature of PSCs than the other two NH winters
for an extended period of time (see Fig. 7). Permanent presence of PSCs
over about 4 months enabled efficient chlorine activation. Additionally,
PSCs supported strong denitrification of the lower stratosphere by
irreversible removal of total reactive nitrogen (NO<inline-formula><mml:math id="M88" display="inline"><mml:msub><mml:mi/><mml:mi>y</mml:mi></mml:msub></mml:math></inline-formula>), in particular
HNO<inline-formula><mml:math id="M89" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>, by uptake of NO<inline-formula><mml:math id="M90" display="inline"><mml:msub><mml:mi/><mml:mi>y</mml:mi></mml:msub></mml:math></inline-formula> on the surface of PSCs, followed by
sedimentation of PSC particles (Fahey et al., 1990). This ultimately enabled
a period of chemical ozone depletion that was longer than usual (e.g., Fahey
et al., 1990; Rex et al., 1999; Pommereau et al., 2018). Manney et al. (2020) analyzed the data of the spaceborne Microwave Limb Sounder (MLS)
instrument, indicating that denitrification was stronger in 2020 than in
2011. Further, in Manney et al. (2011) it was shown that denitrification was
clearly stronger in 2011 than in 1997.</p>
      <p id="d1e1395">The seasonal evolution of minimum TOC values north of 50<inline-formula><mml:math id="M91" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N
between July 1996 and June 1997 (blue line in Fig. 8) and between July 2010 and June 2011 (green line in Fig. 8) indicates normal or slightly
enhanced ozone values until February with respect to the long-term mean
value (thick black line in Fig. 8). The long-term mean value is based on
satellite observations from 1995 to 2019. Typical features of a strong polar
vortex can be observed in February 1997 and February 2011, with low TOC
values in the polar vortex and relatively high TOC values in the collar
region of the polar vortex (not shown). Around the beginning of March 1997
and March 2011 the TOC values declined, and low TOC values were detected in
both years until early April. In spring 1997 the dynamical conditions led to
frequent ozone mini-holes (Coy et al., 1997) and to a higher tropopause that
obviously contributed to lower TOC values via dynamical processes (Manney et
al., 2011).</p>
      <p id="d1e1407">Figure 9a–c show the TOC monthly means for March 1997, 2011, and
2020. Low TOC values over the polar cap can be seen in all three cases. The
lowest Arctic TOC values are detected in boreal spring 2020. In spring 1997
and 2011 TOC values below 220 DU were not detected over larger areas and
over several consecutive days. The monthly mean minimum TOC value for March 2020, which is 221 DU, is much lower compared to the monthly mean minimum
TOCs for March 1997 (267 DU) and for March 2011 (252 DU). The temporal
evolution of minimum Antarctic TOC values south of 50<inline-formula><mml:math id="M92" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S (the red
and purple line in Fig. 8 for 2016 and 2019, respectively) and the TOC
monthly means for October 2016 and 2019 (Fig. 9d and e) show that the
size and strength of the Antarctic ozone hole are much larger than the
corresponding values detected for the Arctic in spring 2020.</p>
</sec>
<?pagebreak page627?><sec id="Ch1.S5">
  <label>5</label><title>Discussion</title>
      <p id="d1e1428">In recent decades, Arctic and Antarctic winter and early spring TOC
variability reflects in large parts the natural fluctuations of the
stratospheric dynamics of the respective hemispheres (e.g., Chap. 4 in
WMO, 2018). In particular, dynamical conditions of the NH stratosphere at
higher latitudes in winter can range from a very disturbed polar vortex
(i.e., by strong planetary wave activity), which could lead to high
stratospheric temperatures, to conditions with a persistent strong polar
vortex (i.e., by low planetary wave activity), which could create low
stratospheric temperatures (e.g., Chap. 4 in WMO, 2018).</p>
      <p id="d1e1431">The NH winter season of 2019/2020 presented a situation with significantly
suppressed meridional air mass exchange and transport into the polar vortex
area in combination with enhanced ozone depletion by heterogeneous chemical
processes inside the polar vortex (Manney et al., 2020), which causes a
clear reduction of TOC. Winter 2019/2020 shows an extraordinary
dynamical situation, with an unusual persistent strong and cold polar vortex
over the season compared to the last 4 decades (the period of the ERA5
data set used in this study). There is some evidence that a similar dynamical
event did not occur in the period from 1955 to 1980, i.e., before the
starting point of our analyses based on ERA5. An analysis of historical data
was provided by the Stratospheric Research Group at FU Berlin. In Labitzke
and Naujokat (2000) it was stated that “the spring of 1997 was the coldest
within our series of 45 winters”; the Berlin time series ranges from 1955
to 2000. Among others, they compared the monthly mean North Pole
temperatures at 30 hPa in all years and found that February 1997 (190 K)
and March 1997 (194 K) were clearly colder than all other years. The second
coldest spring was detected in 1967 (February: 195 K; March: 201 K).
Temperatures in January 1997 were near the climatological mean value. This
suggests that the dynamical situation of winter and spring 2019/2020
has stood out since the beginning of the monitoring of the stratosphere in the
1950s. Although the historical Berlin data set does not have the same
quality as ERA5, it is suitable for a qualitative evaluation of the
respective dynamical situations of NH winter and spring seasons. Lawrence et al. (2020) looked at the Japanese Meteorological Agency's 55-year reanalysis
(JRA-55), which goes back to winter 1958/1959. Based on the zonal mean
zonal wind at 60<inline-formula><mml:math id="M93" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 10 hPa, they found that winter 2019/2020
ranked third. The two winters of 1966/1967 and 1975/1976 (which are
indicated as moderate cold winters in the Berlin analysis) were the
strongest on record with respect to the zonal mean wind (mean from December
to March). The slightly different order regarding record years indicates
that the results depend on the considered meteorological variable as well as
the altitude and latitude region. It is clear that the data before 1980
(pre-satellite era) are more uncertain. Nevertheless, it is obvious that
winter 2019/2020 was one of the coldest winters in the last 65 years and
that it showed an exceptionally persistent strong polar vortex.</p>
      <p id="d1e1443">The stratospheric dynamical conditions were completely different in the NH
winter 2018/2019 (brown line in Fig. 3) compared to 2019/2020 (magenta
line in Fig. 3). In NH winter 2018/2019 a sudden major stratospheric
warming event began in late December 2018. This strong disturbance of the
polar vortex by planetary waves led to a pronounced warming of the lower
stratosphere (e.g., Lee and Butler, 2020), indicating minimum temperatures
in the polar cap region at 50 hPa, which were clearly above the threshold
for the formation of NAT-PSCs (195 K) for the complete winter season (brown
line in Fig. 6). Consequently, TOC values similar to the long-term mean in
the Arctic region were found from late winter to early spring (not shown).</p>
      <p id="d1e1446">The SH spring seasons of 2002 and 2019 provide two additional examples of
the importance of stratospheric dynamics in the development of low TOC
values. In September 2002 a sudden major stratospheric warming in connection
with a breakdown of the polar vortex was detected, which led to a split of
the ozone hole (Sinnhuber et al., 2003; Allen et al., 2003; Hoppel et al.,
2003; Stolarski et al., 2005). In September 2019 the polar vortex was also
significantly disturbed (Wargan et al., 2020; Lim et al., 2020; see purple
lines in Figs. 3 and 6). The minimum TOC values in the Antarctic were
noticeably higher in 2019 than in previous years (Wargan et al., 2020; see
the purple line in Fig. 8). Nevertheless, it is obvious that the small
ozone hole in Antarctic spring 2019 is still much larger than the area with
record low TOC values detected in Arctic spring 2020 (see also Fig. 9).</p>
      <p id="d1e1450">The Arctic observations in winter and spring 2019/2020 are consistent with
our expectation that Arctic ozone reductions in spring are largest after
stratospheric winters with a strong, circular polar vortex in connection
with low polar lower stratospheric temperatures (Chap. 4 in WMO, 2018).
However, as can be seen in Fig. 6, the temperatures in the Antarctic are
considerably lower than in the Arctic (even for 2019/2020), and the period of
low temperatures is much longer in the Antarctic. As a result, the record
low Arctic TOC values are much higher than the TOC values observed in the
Antarctic. This is also the case for the small ozone hole in Antarctic
spring 2019, as indicated in Fig. 8.</p>
      <p id="d1e1453">The dynamical conditions in the Arctic stratosphere in February and March 2020 were similar to the conditions in early spring 1997 and 2011. All 3 years showed low TOCs in March (Fig. 8). Minimum TOC values were below 220 DU for several days in March 2020, which was not the case for March 1997 nor
2011, although the stratospheric chlorine content was higher in 1997 (about
15 %) and slightly higher in 2011 (Chap. 1 in WMO, 2018). Especially in
December 2019 and January 2020 the area of temperatures below 195 K in the
lower stratosphere was larger than in the two other years discussed here
(see Fig. 7). In 2019/2020 the minimum polar cap temperatures at 50 hPa
were below 195 K (the threshold for formation of NAT-PSCs) in<?pagebreak page628?> December,
January, February, and the beginning of March (Fig. 6). In this context,
Manney et al. (2020) identified an activation of chlorine already in the
beginning of December. The daily areas allowing for the formation of PSCs at
50 hPa were clearly larger in 2019/2020 in comparison with the winters
1996/1997 and 2010/2011. This finding is in line with the results presented
by Lawrence et al. (2020). The ERA5 data set also indicates minimum
temperature values in winter 2019/2020, which were slightly above or below
188 K for a week (in particular at the end of January 2020), providing
conditions for the formation of ice PSCs (see also Manney et al., 2020).</p>
      <p id="d1e1456">The observed minimum TOC values in March 2020, with new low TOC records for
the NH polar cap, are related to substantial ozone depletion in spring
(Manney et al., 2020; Wohltmann et al., 2020). Since the polar vortex in
winter and spring 2019/2020 provided continuous conditions for the formation
of PSCs, significant denitrification of the stratosphere occurred (Manney et
al., 2020). This contributed to the 5-week period of significant TOC
reduction by an extended phase of active stratospheric chlorine (Manney et
al., 2011). Here, we note again that 2020 also started with lower base values
of TOC (inside the polar vortex; see Fig. 8), which might have been caused
by a reduced meridional transport of ozone from lower to higher latitudes
due to the strong polar vortex during this winter. This might have also
contributed to the fact that the spring TOC values in the Arctic region in
2020 were clearly lower than those found in 1997 and 2011.</p>
      <p id="d1e1459">Record low stratospheric ozone values over the Arctic in 2020 are not an
unequivocal result of climate change. The dynamical situations in February
and March of 1997, 2011, and 2020 were similar. The cold stratosphere in
December 2019 and January 2020 as a single event does not point towards
climate change due to increasing greenhouse gas concentrations. The NH
winter 2019/2020 is a perfect showcase for a NH winter with low planetary
wave activity and for a persistent strong vortex with low temperatures.
This could be a sign of climate change if similar conditions were to occur
more regularly in the next years. Although the stratosphere is cooling due
to increasing greenhouse gas concentrations (Maycock et al., 2018; Steiner
et al., 2020), consequences for stratospheric dynamics, particularly in
winter and ozone depletion in spring, are still under debate (e.g., Bednarz
et al., 2016; Ivy et al., 2016; Pommereau et al., 2018). For instance, the
empirical quantification of the relation between winter–spring loss of
Arctic ozone and changes in stratospheric climate by Rex et al. (2004)
showed that cold (NH) winters may possibly get colder in the future. The
investigations by Wohltmann et al. (2020) seem to support this hypothesis.
It is possible that the cooling of the (lower) stratosphere could delay the
recovery of the ozone layer (Pommereau et al., 2018). However, this
statement is in contradiction with results derived from chemistry–climate
model predictions (e.g., Dhomse et al., 2018), indicating that climate change
in the NH will accelerate stratospheric ozone recovery instead of delaying
it (see also Chaps. 3 and 4 in WMO, 2018). Since the changes of
stratospheric temperature are affected not only by radiative cooling due to
enhanced greenhouse gas concentrations, but also by atmospheric circulation
changes (e.g., Langematz et al., 2014), the quantitative determination of
the net effect on ozone still remains a challenge. Furthermore, model
calculations by Waibel et al. (1999) more than 20 years ago showed that
higher degrees of Arctic denitrification in future, related to stratospheric
cooling by enhanced greenhouse gas concentrations, could lead to larger
seasonal ozone depletion despite the projected decline in inorganic
chlorine.</p>
      <p id="d1e1462">Finally, based on our current knowledge, we deem it unlikely that the
observed enhanced CFC-11 emissions in recent years (Montzka et al., 2018)
have significantly influenced the strength of ozone depletion in the NH in
2020 (Dameris et al., 2019; Fleming et al., 2020; Keeble et al., 2020).</p>
</sec>
<sec id="Ch1.S6" sec-type="conclusions">
  <label>6</label><title>Conclusions</title>
      <p id="d1e1473">This study presents a description of the NH winter and spring season
2019/2020 and considers the dynamical situation of the stratosphere and the
evolution of the ozone layer in the Arctic region. Record low TOC values
around 220 DU were detected over a large area (up to 0.9 million km<inline-formula><mml:math id="M94" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula>)
as well as for an extended time period (of about 5 weeks). The situation
in 2019/2020 is compared with other years which showed similar
stratospheric dynamics in spring. We have used recent meteorological data
from ERA5 and TOC data from GTO-ECV (based on the satellite sensors
GOME/ERS-2, SCIAMACHY/ENVISAT, OMI/Aura, and GOME-2/MetOp) in combination
with recent TOC data from TROPOMI (on board Sentinel-5P). The detected Arctic
area of record low TOC values is much smaller in comparison with a typical
Antarctic ozone hole, which is of the order of about 20 to 25 million km<inline-formula><mml:math id="M95" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:math></inline-formula> from early September until mid-October and shows TOC values below
220 DU for up to about 4 months (WMO, 2018). The Arctic TOC observations
in spring 2020 were extraordinary because TOC values below 220 DU were not
observed in previous years over a period of 5 weeks in the Arctic. The
persistent strong polar vortex in 2019/2020 (from mid-December to early
April) led to particularly cold stratospheric conditions throughout the
complete winter and early spring season, which likely supported enhanced
ozone depletion compared to other years (Manney et al., 2020; Wohltmann et
al., 2020). The special dynamical situation in winter 2019/2020 is the cause
for the significant reduction of the TOC in spring 2020.</p>
      <p id="d1e1494">We note that numerous studies of the 2019/2020 winter season can be found in
a special issue of Geophysical Research Letters and Journal of Geophysical
Research: Atmospheres (e.g., Manney et al., 2020; Wohltmann et al., 2020;
Lawrence et al., 2020; Grooß and Müller, 2020; Inness et<?pagebreak page629?> al., 2020;
Bernhard et al., 2020), which are based on observational, reanalysis, and
modeling data. Our results agree with these published studies about the
Arctic winter season 2019/2020.</p>
      <p id="d1e1497">If the regulations of the Montreal Protocol regarding the prohibition of
CFCs are strictly implemented, one can expect a full recovery of the ozone
layer including the polar regions by the middle of this century (Chaps. 3
and 4 in WMO, 2018). In recent years, the beginning of ozone recovery has
already been detected (e.g., Solomon et al., 2016; Weber et al., 2018). However,
in winters with a cold and strong polar stratospheric vortex, a persistent
region of low TOC might also develop again in the NH in the future. The
recovery of the ozone layer and its interactions with climate change must be
watched carefully, as discussed for instance by Dameris and Loyola (2011).
Continued monitoring of stratospheric ozone with a suite of instruments will
be key to understand the future development of Arctic ozone. This capability
is crucial to allow for an evaluation of specific events in the light of the
Montreal Protocol.</p>
</sec>

      
      </body>
    <back><notes notes-type="dataavailability"><title>Data availability</title>

      <p id="d1e1504">Meteorological data are based on ERA5 from ECMWF (<uri>https://cds.climate.copernicus.eu//#!/search?text=ERA5&amp;type=dataset</uri>, last access: 1 October 2020; Copernicus Climate Change Service, 2017),
which is available at the Climate Data Store (CDS). This work contains
modified Copernicus Climate Change Service information (Copernicus Climate
Change Service (C3S), 2017; Hersbach et al., 2018, 2019a). Neither the
European Commission nor ECMWF is responsible for any use that may be made of
the Copernicus information or data it contains. In particular, subsets, i.e., wind and temperature data, from the pressure level data sets of monthly
averaged data (Hersbach et al., 2019a) and hourly reanalysis data (Hersbach
et al., 2018) have been used. Daily mean data are produced using hourly data
on pressure levels and using CDO (Climate Data Operators; <ext-link xlink:href="https://doi.org/10.5281/zenodo.2558193" ext-link-type="DOI">10.5281/zenodo.2558193</ext-link>; Schulzweida,
2019) command “daymean” to produce daily means from the hourly data.
Analogously, hourly PV data on isentropes from the full ERA5 data set
(Copernicus Climate Change Service (C3S), 2017) have been exploited and
regridded to a regular grid using CDO. We thank the ECMWF for producing ERA5
data and making them available through the CDS. The data used contain
modified Copernicus Climate Change Service information, in particular with
respect to Figs. 2–7 and Table 1. Please note that the
data used here may also contain “preliminary” ERA-5 data (see Hersbach et
al., 2020).</p>

      <p id="d1e1513">The GTO-ECV Climate Research Data Package is available at <uri>http://cci.esa.int/ozone/</uri> (last access: 13 January 2021; ESA, 2021); detailed information
about this data record can be found at
<ext-link xlink:href="https://doi.org/10.5194/amt-8-3923-2015" ext-link-type="DOI">10.5194/amt-8-3923-2015</ext-link> (Coldewey-Egbers et al., 2015).
This data source is used here, in particular with respect to the preparation
of Figs. 8 and 9.</p>

      <p id="d1e1522">The (Level 2) TROPOMI total ozone column data (TROPOMI OFFL TOC; Copernicus Sentinel-5P, 2018) are freely available at <ext-link xlink:href="https://doi.org/10.5270/S5P-fqouvyz" ext-link-type="DOI">10.5270/S5P-fqouvyz</ext-link> (see also  <uri>https://s5phub.copernicus.eu/</uri>, last access: 18 May 2020; <uri>https://s5pexp.copernicus.eu/</uri>, last access: 18 May 2020). This paper contains modified Copernicus Sentinel-5 Precursor data
processed by DLR/BIRA/ESA. These data are used here, in particular with
respect to Figs. 1, 8, and 9.</p>
  </notes><notes notes-type="authorcontribution"><title>Author contributions</title>

      <p id="d1e1537">MD structured and composed the paper. MD, DGL, MCE, and MN jointly analyzed
the different data sets and compiled the results, including the preparation
of the figures. MD, DGL, MCE, and MN contributed to the writing of the
paper. MCE, DGL, CL, and MvR generated the GTO-ECV data in the ESA
project Ozone_cci<inline-formula><mml:math id="M96" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> and the EU/ECMWF project
C3S_312b. CL, FR, DGL, and MvR are responsible for the
TROPOMI TOC Level 2 data in the ESA project S5P-MPC.</p>
  </notes><notes notes-type="competinginterests"><title>Competing interests</title>

      <p id="d1e1550">The authors declare that they have no conflict of interest.</p>
  </notes><ack><title>Acknowledgements</title><p id="d1e1556">First, we would like to thank Birgit Hassler for an internal review of the
first draft of the paper. We would like to thank the three referees for
their helpful comments and suggestions. In particular we appreciate the
personal commitment of Gloria Manney and Ingo Wohltmann, which helped to
improve the paper. The NCAR Command Language (NCL,
2018) was used for data analysis and to create some of the figures in this
study. NCL is developed by UCAR/NCAR/CISL/TDD and is available online at
<ext-link xlink:href="https://doi.org/10.5065/D6WD3XH5" ext-link-type="DOI">10.5065/D6WD3XH5</ext-link> (NCL, 2018). CDO (Climate Data Operators; Schulzweida,
2019) was employed for processing the data.</p></ack><notes notes-type="financialsupport"><title>Financial support</title>

      <p id="d1e1564">The work for this study was supported under the umbrella of the DLR-project MABAK (Innovative Methoden zur Analyse und Bewertung von Veränderungen der Atmosphäre und des Klimasystems). The work described in this paper has also received funding from the ESA-projects “Ozone_cci” and “Ozone_cci<inline-formula><mml:math id="M97" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>” (as part of the ESA Climate Change Initiative (CCI) program) and the Initiative and Networking Fund of the Helmholtz Association through the “Advanced Earth System Modelling Capacity (ESM)” project.<?xmltex \hack{\newline}?><?xmltex \hack{\newline}?> The article processing charges for this open-access <?xmltex \hack{\newline}?> publication  were covered by a Research <?xmltex \hack{\newline}?> Centre of the Helmholtz Association.</p>
  </notes><notes notes-type="reviewstatement"><title>Review statement</title>

      <p id="d1e1584">This paper was edited by Farahnaz Khosrawi and reviewed by Ingo Wohltmann, Gloria Manney, and one anonymous referee.</p>
  </notes><ref-list>
    <title>References</title>

      <ref id="bib1.bib1"><label>1</label><?label 1?><mixed-citation>Allen, D. R., Bevilacqua, R. M., Nedoluha, G., Randall, C. E., and Manney,
G. L.: Unusual stratospheric transport and mixing during the 2002 Antarctic
winter, Geophys. Res. Lett., 30, 1599, <ext-link xlink:href="https://doi.org/10.1029/2003GL017117" ext-link-type="DOI">10.1029/2003GL017117</ext-link>, 2003.</mixed-citation></ref>
      <?pagebreak page630?><ref id="bib1.bib2"><label>2</label><?label 1?><mixed-citation>Bednarz, E. M., Maycock, A. C., Abraham, N. L., Braesicke, P., Dessens, O., and Pyle, J. A.: Future Arctic ozone recovery: the importance of chemistry and dynamics, Atmos. Chem. Phys., 16, 12159–12176, <ext-link xlink:href="https://doi.org/10.5194/acp-16-12159-2016" ext-link-type="DOI">10.5194/acp-16-12159-2016</ext-link>, 2016.</mixed-citation></ref>
      <ref id="bib1.bib3"><label>3</label><?label 1?><mixed-citation>Bernhard, G. H., Fioletov, V. E., Grooß, J.-U., Ialongo, I., Johnsen,
B., Lakkala, K., Manney, G. L., Müller, R., and Svendby, T.:
Record-breaking increases in Arctic solar ultraviolet radiation caused by
exceptionally large ozone depletion in 2020, Geophys. Res. Lett., 47, e2020GL090844, <ext-link xlink:href="https://doi.org/10.1029/2020GL090844" ext-link-type="DOI">10.1029/2020GL090844</ext-link>, 2020.</mixed-citation></ref>
      <ref id="bib1.bib4"><label>4</label><?label 1?><mixed-citation>Coldewey-Egbers, M., Loyola, D. G., Koukouli, M., Balis, D., Lambert, J.-C., Verhoelst, T., Granville, J., van Roozendael, M., Lerot, C., Spurr, R., Frith, S. M., and Zehner, C.: The GOME-type Total Ozone Essential Climate Variable (GTO-ECV) data record from the ESA Climate Change Initiative, Atmos. Meas. Tech., 8, 3923–3940, <ext-link xlink:href="https://doi.org/10.5194/amt-8-3923-2015" ext-link-type="DOI">10.5194/amt-8-3923-2015</ext-link>, 2015.</mixed-citation></ref>
      <ref id="bib1.bib5"><label>5</label><?label 1?><mixed-citation>Coldewey-Egbers, M., Loyola, D. G., Labow, G., and Frith, S. M.: Comparison of GTO-ECV and adjusted MERRA-2 total ozone columns from the last 2 decades and assessment of interannual variability, Atmos. Meas. Tech., 13, 1633–1654, <ext-link xlink:href="https://doi.org/10.5194/amt-13-1633-2020" ext-link-type="DOI">10.5194/amt-13-1633-2020</ext-link>, 2020.</mixed-citation></ref>
      <ref id="bib1.bib6"><label>6</label><?label 1?><mixed-citation>Copernicus Climate Change Service (C3S): Fifth generation of ECMWF
atmospheric reanalyses of the global climate, ERA5, Copernicus Climate Change
Service Climate Data Store (CDS), available at: <uri>https://cds.climate.copernicus.eu//#!/search?text=ERA5&amp;type=dataset</uri>, (last access: 1 October 2020), 2017.</mixed-citation></ref>
      <ref id="bib1.bib7"><label>7</label><?label 1?><mixed-citation>Copernicus Sentinel-5P: (processed by ESA), TROPOMI Level 2 Ozone Total Column products, Version 01, European Space Agency, <ext-link xlink:href="https://doi.org/10.5270/S5P-fqouvyz" ext-link-type="DOI">10.5270/S5P-fqouvyz</ext-link> (last access: 13 January 2021), 2018.</mixed-citation></ref>
      <ref id="bib1.bib8"><label>8</label><?label 1?><mixed-citation>Coy, L., Nash, E. R., and Newman, P. A.: Meteorology of the polar vortex: Spring 1997, Geophys. Res. Lett., 24, 2693–2696, <ext-link xlink:href="https://doi.org/10.1029/97GL52832" ext-link-type="DOI">10.1029/97GL52832</ext-link>, 1997.</mixed-citation></ref>
      <ref id="bib1.bib9"><label>9</label><?label 1?><mixed-citation>Dameris, M.: Climate change and atmospheric chemistry: How will the
stratospheric ozone layer develop?, Angew. Chem. Int. Edit., 49, 8092–8102,
<ext-link xlink:href="https://doi.org/10.1002/anie.201001643" ext-link-type="DOI">10.1002/anie.201001643</ext-link>, 2010.</mixed-citation></ref>
      <ref id="bib1.bib10"><label>10</label><?label 1?><mixed-citation>Dameris M. and Loyola, D. G.: “Chemistry-Climate Connections – Interaction
of Physical, Dynamical, and Chemical Processes in Earth Atmosphere”, in:
Climate Change – Geophysical Foundations and Ecological Effects, edited by: Blanco, J. and Kheradmand, H., InTech, London, UK, 1–26 pp., <ext-link xlink:href="https://doi.org/10.5772/24210" ext-link-type="DOI">10.5772/24210</ext-link>, 2011.</mixed-citation></ref>
      <ref id="bib1.bib11"><label>11</label><?label 1?><mixed-citation>Dameris, M., Jöckel, P., and Nützel, M.: Possible implications of enhanced chlorofluorocarbon-11 concentrations on ozone, Atmos. Chem. Phys., 19, 13759–13771, <ext-link xlink:href="https://doi.org/10.5194/acp-19-13759-2019" ext-link-type="DOI">10.5194/acp-19-13759-2019</ext-link>, 2019.</mixed-citation></ref>
      <ref id="bib1.bib12"><label>12</label><?label 1?><mixed-citation>Dhomse, S. S., Kinnison, D., Chipperfield, M. P., Salawitch, R. J., Cionni, I., Hegglin, M. I., Abraham, N. L., Akiyoshi, H., Archibald, A. T., Bednarz, E. M., Bekki, S., Braesicke, P., Butchart, N., Dameris, M., Deushi, M., Frith, S., Hardiman, S. C., Hassler, B., Horowitz, L. W., Hu, R.-M., Jöckel, P., Josse, B., Kirner, O., Kremser, S., Langematz, U., Lewis, J., Marchand, M., Lin, M., Mancini, E., Marécal, V., Michou, M., Morgenstern, O., O'Connor, F. M., Oman, L., Pitari, G., Plummer, D. A., Pyle, J. A., Revell, L. E., Rozanov, E., Schofield, R., Stenke, A., Stone, K., Sudo, K., Tilmes, S., Visioni, D., Yamashita, Y., and Zeng, G.: Estimates of ozone return dates from Chemistry-Climate Model Initiative simulations, Atmos. Chem. Phys., 18, 8409–8438, <ext-link xlink:href="https://doi.org/10.5194/acp-18-8409-2018" ext-link-type="DOI">10.5194/acp-18-8409-2018</ext-link>, 2018.</mixed-citation></ref>
      <ref id="bib1.bib13"><label>13</label><?label 1?><mixed-citation>ESA: The GTO-ECV Climate Research Data Package, European Space Agency, available at: <uri>http://cci.esa.int/ozone/</uri>, last access: 13 January 2021.</mixed-citation></ref>
      <ref id="bib1.bib14"><label>14</label><?label 1?><mixed-citation>
Fahey, D. W., Solomon, S., Kawa, S. R., Loewenstein, M., Podolske, J. R.,
Strahan S. E., and Chan, K. R.: A diagnostic for denitrification in the
winter polar stratospheres, Nature, 345, 698–702, 1990.</mixed-citation></ref>
      <ref id="bib1.bib15"><label>15</label><?label 1?><mixed-citation>Fleming, E. L., Newman, P. A., Liang, Q., and Daniel, J. S.: The impact of
continuing CFC-11 emissions on stratospheric ozone, J. Geophys. Res., 125,
e2019JD031849, <ext-link xlink:href="https://doi.org/10.1029/2019JD031849" ext-link-type="DOI">10.1029/2019JD031849</ext-link>, 2020.</mixed-citation></ref>
      <ref id="bib1.bib16"><label>16</label><?label 1?><mixed-citation>Garane, K., Lerot, C., Coldewey-Egbers, M., Verhoelst, T., Koukouli, M. E., Zyrichidou, I., Balis, D. S., Danckaert, T., Goutail, F., Granville, J., Hubert, D., Keppens, A., Lambert, J.-C., Loyola, D., Pommereau, J.-P., Van Roozendael, M., and Zehner, C.: Quality assessment of the Ozone_cci Climate Research Data Package (release 2017) – Part 1: Ground-based validation of total ozone column data products, Atmos. Meas. Tech., 11, 1385–1402, <ext-link xlink:href="https://doi.org/10.5194/amt-11-1385-2018" ext-link-type="DOI">10.5194/amt-11-1385-2018</ext-link>, 2018.</mixed-citation></ref>
      <ref id="bib1.bib17"><label>17</label><?label 1?><mixed-citation>Garane, K., Koukouli, M.-E., Verhoelst, T., Lerot, C., Heue, K.-P., Fioletov, V., Balis, D., Bais, A., Bazureau, A., Dehn, A., Goutail, F., Granville, J., Griffin, D., Hubert, D., Keppens, A., Lambert, J.-C., Loyola, D., McLinden, C., Pazmino, A., Pommereau, J.-P., Redondas, A., Romahn, F., Valks, P., Van Roozendael, M., Xu, J., Zehner, C., Zerefos, C., and Zimmer, W.: TROPOMI/S5P total ozone column data: global ground-based validation and consistency with other satellite missions, Atmos. Meas. Tech., 12, 5263–5287, <ext-link xlink:href="https://doi.org/10.5194/amt-12-5263-2019" ext-link-type="DOI">10.5194/amt-12-5263-2019</ext-link>, 2019.</mixed-citation></ref>
      <ref id="bib1.bib18"><label>18</label><?label 1?><mixed-citation>Grooß, J.-U. and Müller, R.: Simulation of the record Arctic
stratospheric ozone depletion in 2020, J. Geophys. Res.,
<ext-link xlink:href="https://doi.org/10.1002/essoar.10503569.1" ext-link-type="DOI">10.1002/essoar.10503569.1</ext-link>, submitted, 2020.</mixed-citation></ref>
      <ref id="bib1.bib19"><label>19</label><?label 1?><mixed-citation>
Hansen, G. and Chipperfield, M. P.: Ozone depletion at the edge of the
Arctic polar vortex 1996/1997, J. Geophys. Res., 104, 1837–1845, 1999.</mixed-citation></ref>
      <ref id="bib1.bib20"><label>20</label><?label 1?><mixed-citation>Harris, N. R. P., Lehmann, R., Rex, M., and von der Gathen, P.: A closer look at Arctic ozone loss and polar stratospheric clouds, Atmos. Chem. Phys., 10, 8499–8510, <ext-link xlink:href="https://doi.org/10.5194/acp-10-8499-2010" ext-link-type="DOI">10.5194/acp-10-8499-2010</ext-link>, 2010.</mixed-citation></ref>
      <ref id="bib1.bib21"><label>21</label><?label 1?><mixed-citation>Hersbach, H., Bell, B., Berrisford, P., Horányi, A., Muñoz Sabater,
J., Nicolas, J., Radu, R., Schepers, D., Simmons, A., Soci, C., and Dee, D.:
ERA5 hourly data on pressure levels from 1979 to present, Copernicus Climate
Change Service (C3S) Climate Data Store (CDS), <ext-link xlink:href="https://doi.org/10.24381/cds.bd0915c6" ext-link-type="DOI">10.24381/cds.bd0915c6</ext-link>, 2018.</mixed-citation></ref>
      <ref id="bib1.bib22"><label>22</label><?label 1?><mixed-citation>Hersbach, H., Bell, B., Berrisford, P., Horányi, A., Muñoz Sabater,
J., Nicolas, J., Radu, R., Schepers, D., Simmons, A., Soci, C., and Dee, D.:
ERA5 monthly averaged data on pressure levels from 1979 to present,
Copernicus Climate Change Service (C3S) Climate Data Store (CDS),
<ext-link xlink:href="https://doi.org/10.24381/cds.6860a573" ext-link-type="DOI">10.24381/cds.6860a573</ext-link>, 2019a.</mixed-citation></ref>
      <ref id="bib1.bib23"><label>23</label><?label 1?><mixed-citation>Hersbach, H., Bell, B., Berrisford, P., Horányi, A., Sabater, J. M.,
Nicolas, J., Radu, R., Schepers, D., Simmons, A., Soci, C., and Dee, D.:
Global reanalysis: goodbye ERA-Interim, hello ERA5, ECMWF Newsletter, 159,
17–24, <ext-link xlink:href="https://doi.org/10.21957/vf291hehd7" ext-link-type="DOI">10.21957/vf291hehd7</ext-link>, 2019b.</mixed-citation></ref>
      <ref id="bib1.bib24"><label>24</label><?label 1?><mixed-citation>Hersbach, H., Bell, B., Berrisford, P., Hirahara, S., Horányi, A.,
Muñoz-Sabater, J., Nicolas, J., Peubey, C., Radu, R., Schepers, D.,
Simmons, A., Soci, C., Abdalla, S., Abellan, X., Balsamo<?pagebreak page631?>, G., Bechtold, P.,
Biavati, G., Bidlot, J., Bonavita, M., De Chiara, G., Dahlgren, P., Dee, D.,
Diamantakis, M., Dragani, R., Flemming, J., Forbes, R., Fuentes, M., Geer,
A., Haimberger, L., Healy, S., Hogan, R.J., Hólm, E., Janisková, M.,
Keeley, S., Laloyaux, P., Lopez, P., Lupu, C., Radnoti, G., de Rosnay, P.,
Rozum, I., Vamborg, F., Villaume, S., and Thépaut, J.-N.: The ERA5 Global
Reanalysis, Q. J. Roy. Meteor. Soc., 146, 1999–2049,
<ext-link xlink:href="https://doi.org/10.1002/qj.3803" ext-link-type="DOI">10.1002/qj.3803</ext-link>, 2020.</mixed-citation></ref>
      <ref id="bib1.bib25"><label>25</label><?label 1?><mixed-citation>
Hoinka, K. P., Claude, H., and Köhler, U.: On the correlation between
tropopause pressure and ozone above central Europe, Geophys. Res. Lett., 23,
1753–1756, 1996.</mixed-citation></ref>
      <ref id="bib1.bib26"><label>26</label><?label 1?><mixed-citation>Hommel, R., Eichmann, K.-U., Aschmann, J., Bramstedt, K., Weber, M., von Savigny, C., Richter, A., Rozanov, A., Wittrock, F., Khosrawi, F., Bauer, R., and Burrows, J. P.: Chemical ozone loss and ozone mini-hole event during the Arctic winter 2010/2011 as observed by SCIAMACHY and GOME-2, Atmos. Chem. Phys., 14, 3247–3276, <ext-link xlink:href="https://doi.org/10.5194/acp-14-3247-2014" ext-link-type="DOI">10.5194/acp-14-3247-2014</ext-link>, 2014.</mixed-citation></ref>
      <ref id="bib1.bib27"><label>27</label><?label 1?><mixed-citation>Hoppel, K., Bevilacqua, R., Allen, D., and Nedoluha, G.: POAM III
observations of the anomalous 2002 Antarctic ozone hole, Geophys. Res.
Lett., 30, 1394, <ext-link xlink:href="https://doi.org/10.1029/2003GL016899" ext-link-type="DOI">10.1029/2003GL016899</ext-link> 2003GL016899, 2003.</mixed-citation></ref>
      <ref id="bib1.bib28"><label>28</label><?label 1?><mixed-citation>Inness, A., Chabrillat, S., Flemming, J., Huijnen, V., Langenrock, B.,
Nicolas, J., Polichtchouk, I., and Razinger, M.: Exceptionally Low Arctic Stratospheric Ozone in Spring 2020 as Seen in the CAMS Reanalysis, J. Geophys. Res.-Atmos., 125, e2020JD033563, <ext-link xlink:href="https://doi.org/10.1029/2020JD033563" ext-link-type="DOI">10.1029/2020JD033563</ext-link>, 2020.</mixed-citation></ref>
      <ref id="bib1.bib29"><label>29</label><?label 1?><mixed-citation>Ivy, D. J., Solomon, S., and Rieder, H. E.: Radiative and dynamical influences on polar stratospheric temperature trends, J. Climate, 29, 4927–4938, <ext-link xlink:href="https://doi.org/10.1175/JCLI-D-15-0503.1" ext-link-type="DOI">10.1175/JCLI-D-15-0503.1</ext-link>, 2016.</mixed-citation></ref>
      <ref id="bib1.bib30"><label>30</label><?label 1?><mixed-citation>James, P. M.: A climatology of ozone mini-holes over the northern
hemisphere, Int. J. Climatol., 18, 1287–1303,
<ext-link xlink:href="https://doi.org/10.1002/(SICI)1097-0088(1998100)18:12&lt;1287::AID-JOC315&gt;3.0.CO;2-4" ext-link-type="DOI">10.1002/(SICI)1097-0088(1998100)18:12&lt;1287::AID-JOC315&gt;3.0.CO;2-4</ext-link>, 1998.</mixed-citation></ref>
      <ref id="bib1.bib31"><label>31</label><?label 1?><mixed-citation>James, P. M. and Peters, D.: The Lagrangian structure of ozone mini-holes and potential vorticity anomalies in the Northern Hemisphere, Ann. Geophys., 20, 835–846, <ext-link xlink:href="https://doi.org/10.5194/angeo-20-835-2002" ext-link-type="DOI">10.5194/angeo-20-835-2002</ext-link>, 2002.</mixed-citation></ref>
      <ref id="bib1.bib32"><label>32</label><?label 1?><mixed-citation>Keeble, J., Abraham, N. L., Archibald, A. T., Chipperfield, M. P., Dhomse, S., Griffiths, P. T., and Pyle, J. A.: Modelling the potential impacts of the recent, unexpected increase in CFC-11 emissions on total column ozone recovery, Atmos. Chem. Phys., 20, 7153–7166, <ext-link xlink:href="https://doi.org/10.5194/acp-20-7153-2020" ext-link-type="DOI">10.5194/acp-20-7153-2020</ext-link>, 2020.</mixed-citation></ref>
      <ref id="bib1.bib33"><label>33</label><?label 1?><mixed-citation>Kivi, R., Kyrö, E., Turunen, T., Harris, N. R. P., von der Gathen, P.,
Rex, M., Andersen, S. B., and Wohltmann, I.: Ozonesonde observations in the
Arctic during 1989–2003: Ozone variability and trends in the lower
stratosphere and free troposphere, J. Geophys. Res., 112, D08306, <ext-link xlink:href="https://doi.org/10.1029/2006JD007271" ext-link-type="DOI">10.1029/2006JD007271</ext-link>, 2007.</mixed-citation></ref>
      <ref id="bib1.bib34"><label>34</label><?label 1?><mixed-citation>Kuttippurath, J., Godin-Beekmann, S., Lefèvre, F., Nikulin, G., Santee, M. L., and Froidevaux, L.: Record-breaking ozone loss in the Arctic winter 2010/2011: comparison with 1996/1997, Atmos. Chem. Phys., 12, 7073–7085, <ext-link xlink:href="https://doi.org/10.5194/acp-12-7073-2012" ext-link-type="DOI">10.5194/acp-12-7073-2012</ext-link>, 2012.</mixed-citation></ref>
      <ref id="bib1.bib35"><label>35</label><?label 1?><mixed-citation>
Labitzke, K. and Naujokat, B.: The lower arctic stratosphere in winter
since 1952, SPARC Newsletter No. 15, 11–14, 2000.</mixed-citation></ref>
      <ref id="bib1.bib36"><label>36</label><?label 1?><mixed-citation>Langematz, U.: Stratospheric ozone: down and up through the Anthropocene,
ChemTexts, 5, 12, <ext-link xlink:href="https://doi.org/10.1007/s40828-019-0082-7" ext-link-type="DOI">10.1007/s40828-019-0082-7</ext-link>, 2019.</mixed-citation></ref>
      <ref id="bib1.bib37"><label>37</label><?label 1?><mixed-citation>Langematz, U., Meul, S., Grunow, K., Romanowsky, E., Oberländer, S.,
Abalichin, J., and Kubin, A.: Future Arctic temperature and ozone: The role
of stratospheric composition changes, J. Geophys. Res., 119, 2092–2112, <ext-link xlink:href="https://doi.org/10.1002/2013JD021100" ext-link-type="DOI">10.1002/2013JD021100</ext-link>, 2014.</mixed-citation></ref>
      <ref id="bib1.bib38"><label>38</label><?label 1?><mixed-citation>Lawrence, Z. D., Perlwitz, J., Butler, A. H., Manney, G. L., Newman, P. A.,
Lee, S. H., and Nash, E. R.: The remarkable strong Arctic stratospheric polar
vortex of winter 2020: links to record-breaking Arctic oscillation and ozone
loss, J. Geophys. Res.-Atmos., 125, e2020JD033271, <ext-link xlink:href="https://doi.org/10.1029/2020JD033271" ext-link-type="DOI">10.1029/2020JD033271</ext-link>, 2020.</mixed-citation></ref>
      <ref id="bib1.bib39"><label>39</label><?label 1?><mixed-citation>Lee, S. H. and Butler, A. H.: The 2018–2019 Arctic stratospheric polar
vortex, Weather, 75, 52–57, <ext-link xlink:href="https://doi.org/10.1002/wea.3643" ext-link-type="DOI">10.1002/wea.3643</ext-link>, 2020.</mixed-citation></ref>
      <ref id="bib1.bib40"><label>40</label><?label 1?><mixed-citation>
Lefèvre, F., Figarol, F., Carslaw, K. S., and Peter, T.: The 1997 Arctic
ozone depletion quantified from three-dimensional model simulations,
Geophys. Res. Lett., 25, 2425–2428, 1998.</mixed-citation></ref>
      <ref id="bib1.bib41"><label>41</label><?label 1?><mixed-citation>Lerot C., van Roozendael, M., Spurr, R., Loyola, D. G., Coldewey-Egbers, M.,
Kochenova, S., van Gent, J., Koukouli, M.-E., Balis, D., Lambert, J.-C.,
Granville, J., and Zehner, C.: Homogenized total ozone data records from the
European sensors GOME/ERS-2, SCIAMACHY/Envisat, and GOME-2/MetOp-A,  J. Geophys. Res. Atmos., 119, 1639–1662, <ext-link xlink:href="https://doi.org/10.1002/2013JD020831" ext-link-type="DOI">10.1002/2013JD020831</ext-link>, 2014.</mixed-citation></ref>
      <ref id="bib1.bib42"><label>42</label><?label 1?><mixed-citation>
Lim, E.-P., Hendon, H. H., Butler, A. H., Garreaud, R. D., Polichtchouk, I.,
Shepherd, T. G., Scaife, A., Comer, R., Coy, L., Newman, P. A., Thompson, D.
W. J., and Nakamura, H.: The 2019 Antarctic sudden stratospheric warming,
SPARC-Newsletter, 54, 10–13, 2020.</mixed-citation></ref>
      <ref id="bib1.bib43"><label>43</label><?label 1?><mixed-citation>Loyola, D. G., Coldewey-Egbers, M., Dameris, M., Garny, H., Stenke, A., van Roozendael, M., Lerot, C., Balis, D., and Koukouli, M.: Global long-term
monitoring of the ozone layer – a prerequisite for predictions,
Int. J. Remote Sens., 30, 4295–4318,
<ext-link xlink:href="https://doi.org/10.1080/01431160902825016" ext-link-type="DOI">10.1080/01431160902825016</ext-link>, 2009.</mixed-citation></ref>
      <ref id="bib1.bib44"><label>44</label><?label 1?><mixed-citation>Manney, G. L., Froidevaux, L., Santee, M. L., Zurek, R. W., and Waters, J. W.: MLS observations of Arctic ozone loss in 1996–97, Geophys. Res. Lett., 24, 2967–2700, <ext-link xlink:href="https://doi.org/10.1029/97GL52827" ext-link-type="DOI">10.1029/97GL52827</ext-link>, 1997.</mixed-citation></ref>
      <ref id="bib1.bib45"><label>45</label><?label 1?><mixed-citation>Manney, G. L., Santee, M. L., Rex, M., Livesey, N. J., Pitts, M. C.,
Veefkind, P., Nash, E. R., Wohltmann, I., Lehmann, R., Froidevaux, L.,
Poole, L. R., Schoeberl, M. R., Haffner, D. P., Davies, J., Dorokhov, V.,
Gernandt, H., Johnson, B., Kivi, R., Kyrö, E., Larsen, N., Levelt, P.
F., Makshtas, A., McElroy, C. T., Nakajima, H., Parrondo, M. C., Tarasick,
D. W., von der Gathen, P., Walker, K. A., and Zinoviev, N. S.: Unprecedented
Arctic ozone loss in 2011, Nature, 478, 469–475, <ext-link xlink:href="https://doi.org/10.1038/nature10556" ext-link-type="DOI">10.1038/nature10556</ext-link>, 2011.</mixed-citation></ref>
      <ref id="bib1.bib46"><label>46</label><?label 1?><mixed-citation>Manney, G. L., Livesey, N. J., Santee, M. L., Froidevaux, L., Lambert, A.,
Lawrence, Z. D., Millán, L. F., Neu, J. L., Read, W. G., Schwartz, M.
J., and Fuller, R. A.: Record-low Arctic stratospheric ozone in 2020: MLS
observations of chemical processes and comparisons with previous extreme
winters, Geophys. Res. Lett., 47, e2020GL089063, <ext-link xlink:href="https://doi.org/10.1029/2020GL089063" ext-link-type="DOI">10.1029/2020GL089063</ext-link>, 2020.</mixed-citation></ref>
      <ref id="bib1.bib47"><label>47</label><?label 1?><mixed-citation>Maycock, A. C., Randel, W. J., Steiner, A. K., Karpechko, A. Y., Christy,
J., Saunders, R., Thompson, D. W. J., Zou<?pagebreak page632?>, C.-Z., Chrysanthou, A., Abraham,
N. L., Akiyoshi, H., Archibald, A. T., Butchart, N., Chipperfield, M.,
Dameris, M., Deushi, M., Dhomse, S., Di Genova, G., Jöckel, P.,
Kinnison, D. E., Kirner, O., Ladstaedter, F., Michou, M., Morgenstern, O.,
O'Connor, F., Oman, L., Pitari, G., Plummer, D. A., Revell,
L. E., Rozanov, E., Stenke, A., Visioni, D., Yamashita, Y., and Zeng, G.:
Revisiting the mystery of recent stratospheric temperature trends, Geophys.
Res. Lett., 45, 9919–9933, <ext-link xlink:href="https://doi.org/10.1029/2018GL078035" ext-link-type="DOI">10.1029/2018GL078035</ext-link>, 2018.</mixed-citation></ref>
      <ref id="bib1.bib48"><label>48</label><?label 1?><mixed-citation>Millán, L. F. and Manney, G. L.: An assessment of ozone mini-hole representation in reanalyses over the Northern Hemisphere, Atmos. Chem. Phys., 17, 9277–9289, <ext-link xlink:href="https://doi.org/10.5194/acp-17-9277-2017" ext-link-type="DOI">10.5194/acp-17-9277-2017</ext-link>, 2017.</mixed-citation></ref>
      <ref id="bib1.bib49"><label>49</label><?label 1?><mixed-citation>Montzka, S. A., Dutton, R., Yu, P., Ray, E., Portmann, R. W., Daniel, J. S.,
Kuijpers, L., Hall, B. D., Mondeel, D., Siso, C., Nance, D. J., Rigby, M.,
Manning, A. J., Hu, L., Moore, F., Miller, B. R., and Elkins, J. W.: A
persistent and unexpected increase in global emissions of ozone-depleting
CFC-11, Nature, 557, 413–417, <ext-link xlink:href="https://doi.org/10.1038/s41586-018-0106-2" ext-link-type="DOI">10.1038/s41586-018-0106-2</ext-link>,
2018.</mixed-citation></ref>
      <ref id="bib1.bib50"><label>50</label><?label 1?><mixed-citation>NCL, The NCAR Command Language (Version 6.5.0) [Software], Boulder,
Colorado, UCAR/NCAR/CISL/TDD, <ext-link xlink:href="https://doi.org/10.5065/D6WD3XH5" ext-link-type="DOI">10.5065/D6WD3XH5</ext-link>, 2018.</mixed-citation></ref>
      <ref id="bib1.bib51"><label>51</label><?label 1?><mixed-citation>
Newman, P. A., Nash, E. R., and Rosenfield, J. E.: What controls the temperature
of the Arctic stratosphere during the spring?, J. Geophys. Res., 106,
19999–20010, 2001.</mixed-citation></ref>
      <ref id="bib1.bib52"><label>52</label><?label 1?><mixed-citation>Peters, D., Egger, J., and Entzian, G.: Dynamical aspects of ozone mini-hole
formation, Meteorol. Atmos. Phys., 55, 205–214,
<ext-link xlink:href="https://doi.org/10.1007/BF01029827" ext-link-type="DOI">10.1007/BF01029827</ext-link>, 1995.</mixed-citation></ref>
      <ref id="bib1.bib53"><label>53</label><?label 1?><mixed-citation>Petzoldt, K.: The role of dynamics in total ozone deviations from their long-term mean over the Northern Hemisphere, Ann. Geophys., 17, 231–241, <ext-link xlink:href="https://doi.org/10.1007/s00585-999-0231-1" ext-link-type="DOI">10.1007/s00585-999-0231-1</ext-link>, 1999.</mixed-citation></ref>
      <ref id="bib1.bib54"><label>54</label><?label 1?><mixed-citation>Pommereau J.-P., Goutail, F., Pazmino, A., Lefèvre, F., Chipperfield, M.
P., Feng, W., van Roozendael, M., Jepsen, N., Hansen, G., Kivi, R., Bognar,
K., Strong, K., Walker, K., Kuzmichev, A., Khattatov, S., and Sitnikova, V.:
Recent Arctic ozone depletion: Is there an impact of climate change? Comptes
Rendus Géoscience, Elsevier Masson, 350, 347–353, <ext-link xlink:href="https://doi.org/10.1016/j.crte.2018.07.009" ext-link-type="DOI">10.1016/j.crte.2018.07.009</ext-link>, 2018.</mixed-citation></ref>
      <ref id="bib1.bib55"><label>55</label><?label 1?><mixed-citation>
Rex, M., Salawitch, R. J., Toon, G. C., Sen, B., Margitan, J. J., Osterman,
G. B., Blavier, J.-F., Gao, R. S., Donnelly, S., Keim, E., Neuman, J.,
Fahey, D. W., Webster, C. R., Scott, D.C., Herman, R. L., May, R. D., Moyer,
E. J., Gunson, M. R., Irion, F. W., Chang, A. Y., Rinsland, C. P., and Bui,
T. P.: Subsidence, mixing, and denitrification of Arctic polar vortex air
measured During POLARIS, J. Geophys. Res., 104, 26611–26623, 1999.</mixed-citation></ref>
      <ref id="bib1.bib56"><label>56</label><?label 1?><mixed-citation>Rex, M., Salawitch, R. J., von der Gathen, P., Harris, N. R. P.,
Chipperfield, M. P., and Naujokat, B.: Arctic ozone loss and climate change,
Geophys. Res. Lett., 31, L04116, <ext-link xlink:href="https://doi.org/10.1029/2003GL018844" ext-link-type="DOI">10.1029/2003GL018844</ext-link>, 2004.</mixed-citation></ref>
      <ref id="bib1.bib57"><label>57</label><?label 1?><mixed-citation>Schulzweida, U.: CDO User Guide (Version 1.9.6),
<ext-link xlink:href="https://doi.org/10.5281/zenodo.2558193" ext-link-type="DOI">10.5281/zenodo.2558193</ext-link>, 2019.</mixed-citation></ref>
      <ref id="bib1.bib58"><label>58</label><?label 1?><mixed-citation>
Sinnhuber, B.-M., Weber, M., Amankwah, A., and Burrows, J. P.: Total ozone
during the unusual Antarctic winter of 2002, Geophys. Res. Lett., 30,
1580–1584, 2003.</mixed-citation></ref>
      <ref id="bib1.bib59"><label>59</label><?label 1?><mixed-citation>Sinnhuber, B.-M., Stiller, G., Ruhnke, R., von Clarmann, T., Kellmann, S.,
and Aschmann, J.: Arctic winter 2010/2011 at the brink of an ozone hole,
Geophys. Res. Lett., 38, L24814, <ext-link xlink:href="https://doi.org/10.1029/2011GL049784" ext-link-type="DOI">10.1029/2011GL049784</ext-link>, 2011.</mixed-citation></ref>
      <ref id="bib1.bib60"><label>60</label><?label 1?><mixed-citation>
Solomon, S.: Stratospheric ozone depletion: a review of concepts and
history, Rev. Geophys., 37, 275–316, 1999.</mixed-citation></ref>
      <ref id="bib1.bib61"><label>61</label><?label 1?><mixed-citation>Solomon, S., Haskins, J., Ivy, D. J., and Min, F.: Fundamental differences
between Arctic and Antarctic ozone depletion, P. Natl. Acad. Sci. USA, 111, 6220–6225,
<ext-link xlink:href="https://doi.org/10.1073/pnas.1319307111" ext-link-type="DOI">10.1073/pnas.1319307111</ext-link>, 2014.</mixed-citation></ref>
      <ref id="bib1.bib62"><label>62</label><?label 1?><mixed-citation>Solomon, S., Ivy, D. J., Kinnison, D., Mills, M. J., Neely III, R. R., and
Schmidt, A.: Emergence of healing in the Antarctic ozone layer, Science,
353, 269–274, <ext-link xlink:href="https://doi.org/10.1126/science.aae0061" ext-link-type="DOI">10.1126/science.aae0061</ext-link>, 2016.</mixed-citation></ref>
      <ref id="bib1.bib63"><label>63</label><?label 1?><mixed-citation>SPARC: SPARC Report on the Lifetimes of Stratospheric Ozone-Depleting
Substances, Their Replacements, and Related Species, edited by: Ko, M., Newman, P., Reimann, S., and Strahan, S., SPARC Report No. 6, WCRP-15/2013, available at: <uri>https://www.sparc-climate.org/publications/sparc-reports/sparc-report-no-6/</uri> (last access: 15 January 2021), 2013.</mixed-citation></ref>
      <ref id="bib1.bib64"><label>64</label><?label 1?><mixed-citation>
Steinbrecht, W., Claude, H., Köhler, U., and Hoinka, K. P.: Correlations
between tropopause height and total ozone: Implications for long-term
changes, J. Geophys. Res., 103, 19183–19192, 1998.</mixed-citation></ref>
      <ref id="bib1.bib65"><label>65</label><?label 1?><mixed-citation>Steiner, A. K., Ladstädter, F., Randel, W. J., Maycock, A. C., Fu, Q.,
Claud, C., Gleisner, H., Haimberger, L., Ho, S.-P., Keckhut, P., Leblanc,
T., Mears, C., Polvani, L. M., Santer, B. D., Schmidt, T., Sofieva, V.,
Wing, R., and Zou, C.-Z.: Observed temperature changes in the troposphere
and stratosphere from 1979 to 2018, J. Climate, 33, 8165–8194, <ext-link xlink:href="https://doi.org/10.1175/JCLI-D-19-0998.1" ext-link-type="DOI">10.1175/JCLI-D-19-0998.1</ext-link>, 2020.</mixed-citation></ref>
      <ref id="bib1.bib66"><label>66</label><?label 1?><mixed-citation>
Stolarski, R.S., McPeters, R. D., and Newman, P. A.: The Ozone hole of 2002
as measured by TOMS, J. Atmos. Sci., 62, 716–720, 2005.</mixed-citation></ref>
      <ref id="bib1.bib67"><label>67</label><?label 1?><mixed-citation>Tegtmeier, S., Rex, M., Wohltmann, I., and Krüger, K.: Relative
importance of dynamical and chemical contributions to Arctic wintertime
ozone, Geophys. Res. Lett., 35, L17801
<ext-link xlink:href="https://doi.org/10.1029/2008GL034250" ext-link-type="DOI">10.1029/2008GL034250</ext-link>, 2008.</mixed-citation></ref>
      <ref id="bib1.bib68"><label>68</label><?label 1?><mixed-citation>Tilmes, S., Müller, R., Engel, A., Rex, M., and Russell III, J. M.:
Chemical ozone loss in the Arctic and Antarctic stratosphere between 1992
and 2005, Geophys. Res. Lett.. 33, L20812,
<ext-link xlink:href="https://doi.org/10.1029/2006GL026925" ext-link-type="DOI">10.1029/2006GL026925</ext-link>, 2006.</mixed-citation></ref>
      <ref id="bib1.bib69"><label>69</label><?label 1?><mixed-citation>Van Geffen, J., Van Weele, M., Allaart, M. and Van der A, R.: TEMIS UV index
and UV dose operational data products, version 2, dataset, Royal Netherlands
Meteorological Institute (KNMI), <ext-link xlink:href="https://doi.org/10.21944/temis-uv-oper-v2" ext-link-type="DOI">10.21944/temis-uv-oper-v2</ext-link>, 2017.</mixed-citation></ref>
      <ref id="bib1.bib70"><label>70</label><?label 1?><mixed-citation>
Waibel, A. E., Peter, T., Carslaw, K. S., Oelhaf, H., Wetzel, G., Crutzen,
P. J., Poeschl, U., Tsias, A., Reimer, E., and Fischer, H.: Arctic ozone
loss due to denitrification, Science, 283, 2064–2069, 1999.</mixed-citation></ref>
      <ref id="bib1.bib71"><label>71</label><?label 1?><mixed-citation>Wargan, K., Weir, B., Manney, G. L., Cohn, S., and Livesey, N. J.: The anomalous 2019 Antarctic ozone hole in the GEOS Constituent Data Assimilation System with MLS observations, J. Geophys. Res.-Atmos., 125, e2020JD033335, <ext-link xlink:href="https://doi.org/10.1029/2020JD033335" ext-link-type="DOI">10.1029/2020JD033335</ext-link>, 2020.</mixed-citation></ref>
      <ref id="bib1.bib72"><label>72</label><?label 1?><mixed-citation>Weber, M., Coldewey-Egbers, M., Fioletov, V. E., Frith, S. M., Wild, J. D., Burrows, J. P., Long, C. S., and Loyola, D.: Total ozone trends from 1979 to 2016 derived from five merged observational datasets – the emergence into ozone recovery, Atmos. Chem. Phys., 18, 2097–2117, <ext-link xlink:href="https://doi.org/10.5194/acp-18-2097-2018" ext-link-type="DOI">10.5194/acp-18-2097-2018</ext-link>, 2018.</mixed-citation></ref>
      <ref id="bib1.bib73"><label>73</label><?label 1?><mixed-citation>
WMO (World Meteorological Organization): Scientific Assessment of Ozone
Depletion: 1998, Global Ozone Research and Monitoring Project-Report No.
44, Geneva, Switzerland, 558 pp., 1999.</mixed-citation></ref>
      <ref id="bib1.bib74"><label>74</label><?label 1?><mixed-citation>
WMO (World Meteorological Organization): Scientific Assessment of Ozone
Depletion: 2002, Global Ozone Research an<?pagebreak page633?>d Monitoring Project-Report No.
47, 498 pp., Geneva, Switzerland, 2003.</mixed-citation></ref>
      <ref id="bib1.bib75"><label>75</label><?label 1?><mixed-citation>
WMO (World Meteorological Organization): Scientific Assessment of Ozone
Depletion: 2014, Global Ozone Research and Monitoring Project-Report No. 55,
416 pp., Geneva, Switzerland, 2014.</mixed-citation></ref>
      <ref id="bib1.bib76"><label>76</label><?label 1?><mixed-citation>WMO (World Meteorological Organization): Scientific Assessment of Ozone
Depletion: 2018, Global Ozone Research and Monitoring Project-Report No.
58, 588 pp., Geneva, Switzerland, 2018.
 </mixed-citation></ref><?xmltex \hack{\newpage}?>
      <ref id="bib1.bib77"><label>77</label><?label 1?><mixed-citation>Wohltmann, I., von der Gathen, P., Lehmann, R., Maturilli, M., Deckelmann,
H., Manney, G. L., Davis, J., Tarasick, D., Jepsen, N., Kivi, R., Lyall, N.,
and Rex, M.: Near complete local reduction of Arctic stratospheric ozone by
severe chemical loss in spring 2020, Geophys. Res. Lett., 47, e2020GL089547, <ext-link xlink:href="https://doi.org/10.1029/2020GL089547" ext-link-type="DOI">10.1029/2020GL089547</ext-link>, 2020.</mixed-citation></ref>

  </ref-list></back>
    <!--<article-title-html>Record low ozone values over the Arctic in boreal spring 2020</article-title-html>
<abstract-html><p>Ozone data derived from the Tropospheric Monitoring Instrument
(TROPOMI) sensor on board the Sentinel-5 Precursor satellite show
exceptionally low total ozone columns in the polar region of the Northern Hemisphere (Arctic) in spring 2020. Minimum total ozone column values around
or below 220 Dobson units (DU) were seen over the Arctic for 5 weeks in
March and early April 2020. Usually the persistence of such low total ozone
column values in spring is only observed in the polar Southern Hemisphere (Antarctic) and not over the Arctic. These record low total
ozone columns were caused by a particularly strong polar vortex in the
stratosphere with a persistent cold stratosphere at higher latitudes, a
prerequisite for ozone depletion through heterogeneous chemistry. Based on
the ERA5, which is the fifth generation of the European Centre for
Medium-Range Weather Forecasts (ECMWF) atmospheric reanalysis, the Northern
Hemisphere winter 2019/2020 (from December to March) showed minimum polar cap
temperatures consistently below 195&thinsp;K around 20&thinsp;km altitude, which enabled
enhanced formation of polar stratospheric clouds. The special situation in
spring 2020 is compared and discussed in context with two other Northern Hemisphere spring seasons, namely those in 1997 and 2011, which also
displayed relatively low total ozone column values. However, during these
years, total ozone columns below 220&thinsp;DU over several consecutive days were
not observed in spring. The similarities and differences of the atmospheric
conditions of these three events and possible explanations for the observed
features are presented and discussed. It becomes apparent that the monthly
mean of the minimum total ozone column value for March 2020 (221&thinsp;DU) was
clearly below the respective values found in March 1997 (267&thinsp;DU) and 2011
(252&thinsp;DU), which highlights the special evolution of the polar stratospheric
ozone layer in the Northern Hemisphere in spring 2020. A comparison with a
typical ozone hole over the Antarctic (e.g., in 2016) indicates that although
the Arctic spring 2020 situation is remarkable, with total ozone column
values around or below 220&thinsp;DU observed over a considerable area (up to 0.9 million&thinsp;km<sup>2</sup>), the Antarctic ozone hole shows total ozone columns
typically below 150&thinsp;DU over a much larger area (of the order of 20 million&thinsp;km<sup>2</sup>). Furthermore, total ozone columns below 220&thinsp;DU are typically
observed over the Antarctic for about 4 months.</p></abstract-html>
<ref-html id="bib1.bib1"><label>1</label><mixed-citation>
Allen, D. R., Bevilacqua, R. M., Nedoluha, G., Randall, C. E., and Manney,
G. L.: Unusual stratospheric transport and mixing during the 2002 Antarctic
winter, Geophys. Res. Lett., 30, 1599, <a href="https://doi.org/10.1029/2003GL017117" target="_blank">https://doi.org/10.1029/2003GL017117</a>, 2003.
</mixed-citation></ref-html>
<ref-html id="bib1.bib2"><label>2</label><mixed-citation>
Bednarz, E. M., Maycock, A. C., Abraham, N. L., Braesicke, P., Dessens, O., and Pyle, J. A.: Future Arctic ozone recovery: the importance of chemistry and dynamics, Atmos. Chem. Phys., 16, 12159–12176, <a href="https://doi.org/10.5194/acp-16-12159-2016" target="_blank">https://doi.org/10.5194/acp-16-12159-2016</a>, 2016.
</mixed-citation></ref-html>
<ref-html id="bib1.bib3"><label>3</label><mixed-citation>
Bernhard, G. H., Fioletov, V. E., Grooß, J.-U., Ialongo, I., Johnsen,
B., Lakkala, K., Manney, G. L., Müller, R., and Svendby, T.:
Record-breaking increases in Arctic solar ultraviolet radiation caused by
exceptionally large ozone depletion in 2020, Geophys. Res. Lett., 47, e2020GL090844, <a href="https://doi.org/10.1029/2020GL090844" target="_blank">https://doi.org/10.1029/2020GL090844</a>, 2020.
</mixed-citation></ref-html>
<ref-html id="bib1.bib4"><label>4</label><mixed-citation>
Coldewey-Egbers, M., Loyola, D. G., Koukouli, M., Balis, D., Lambert, J.-C., Verhoelst, T., Granville, J., van Roozendael, M., Lerot, C., Spurr, R., Frith, S. M., and Zehner, C.: The GOME-type Total Ozone Essential Climate Variable (GTO-ECV) data record from the ESA Climate Change Initiative, Atmos. Meas. Tech., 8, 3923–3940, <a href="https://doi.org/10.5194/amt-8-3923-2015" target="_blank">https://doi.org/10.5194/amt-8-3923-2015</a>, 2015.
</mixed-citation></ref-html>
<ref-html id="bib1.bib5"><label>5</label><mixed-citation>
Coldewey-Egbers, M., Loyola, D. G., Labow, G., and Frith, S. M.: Comparison of GTO-ECV and adjusted MERRA-2 total ozone columns from the last 2 decades and assessment of interannual variability, Atmos. Meas. Tech., 13, 1633–1654, <a href="https://doi.org/10.5194/amt-13-1633-2020" target="_blank">https://doi.org/10.5194/amt-13-1633-2020</a>, 2020.
</mixed-citation></ref-html>
<ref-html id="bib1.bib6"><label>6</label><mixed-citation>
Copernicus Climate Change Service (C3S): Fifth generation of ECMWF
atmospheric reanalyses of the global climate, ERA5, Copernicus Climate Change
Service Climate Data Store (CDS), available at: <a href="https://cds.climate.copernicus.eu//#!/search?text=ERA5&amp;type=dataset" target="_blank"/>, (last access: 1 October 2020), 2017.
</mixed-citation></ref-html>
<ref-html id="bib1.bib7"><label>7</label><mixed-citation>
Copernicus Sentinel-5P: (processed by ESA), TROPOMI Level 2 Ozone Total Column products, Version 01, European Space Agency, <a href="https://doi.org/10.5270/S5P-fqouvyz" target="_blank">https://doi.org/10.5270/S5P-fqouvyz</a> (last access: 13 January 2021), 2018.
</mixed-citation></ref-html>
<ref-html id="bib1.bib8"><label>8</label><mixed-citation>
Coy, L., Nash, E. R., and Newman, P. A.: Meteorology of the polar vortex: Spring 1997, Geophys. Res. Lett., 24, 2693–2696, <a href="https://doi.org/10.1029/97GL52832" target="_blank">https://doi.org/10.1029/97GL52832</a>, 1997.
</mixed-citation></ref-html>
<ref-html id="bib1.bib9"><label>9</label><mixed-citation>
Dameris, M.: Climate change and atmospheric chemistry: How will the
stratospheric ozone layer develop?, Angew. Chem. Int. Edit., 49, 8092–8102,
<a href="https://doi.org/10.1002/anie.201001643" target="_blank">https://doi.org/10.1002/anie.201001643</a>, 2010.
</mixed-citation></ref-html>
<ref-html id="bib1.bib10"><label>10</label><mixed-citation>
Dameris M. and Loyola, D. G.: “Chemistry-Climate Connections – Interaction
of Physical, Dynamical, and Chemical Processes in Earth Atmosphere”, in:
Climate Change – Geophysical Foundations and Ecological Effects, edited by: Blanco, J. and Kheradmand, H., InTech, London, UK, 1–26 pp., <a href="https://doi.org/10.5772/24210" target="_blank">https://doi.org/10.5772/24210</a>, 2011.
</mixed-citation></ref-html>
<ref-html id="bib1.bib11"><label>11</label><mixed-citation>
Dameris, M., Jöckel, P., and Nützel, M.: Possible implications of enhanced chlorofluorocarbon-11 concentrations on ozone, Atmos. Chem. Phys., 19, 13759–13771, <a href="https://doi.org/10.5194/acp-19-13759-2019" target="_blank">https://doi.org/10.5194/acp-19-13759-2019</a>, 2019.
</mixed-citation></ref-html>
<ref-html id="bib1.bib12"><label>12</label><mixed-citation>
Dhomse, S. S., Kinnison, D., Chipperfield, M. P., Salawitch, R. J., Cionni, I., Hegglin, M. I., Abraham, N. L., Akiyoshi, H., Archibald, A. T., Bednarz, E. M., Bekki, S., Braesicke, P., Butchart, N., Dameris, M., Deushi, M., Frith, S., Hardiman, S. C., Hassler, B., Horowitz, L. W., Hu, R.-M., Jöckel, P., Josse, B., Kirner, O., Kremser, S., Langematz, U., Lewis, J., Marchand, M., Lin, M., Mancini, E., Marécal, V., Michou, M., Morgenstern, O., O'Connor, F. M., Oman, L., Pitari, G., Plummer, D. A., Pyle, J. A., Revell, L. E., Rozanov, E., Schofield, R., Stenke, A., Stone, K., Sudo, K., Tilmes, S., Visioni, D., Yamashita, Y., and Zeng, G.: Estimates of ozone return dates from Chemistry-Climate Model Initiative simulations, Atmos. Chem. Phys., 18, 8409–8438, <a href="https://doi.org/10.5194/acp-18-8409-2018" target="_blank">https://doi.org/10.5194/acp-18-8409-2018</a>, 2018.
</mixed-citation></ref-html>
<ref-html id="bib1.bib13"><label>13</label><mixed-citation>
ESA: The GTO-ECV Climate Research Data Package, European Space Agency, available at: <a href="http://cci.esa.int/ozone/" target="_blank"/>, last access: 13 January 2021.
</mixed-citation></ref-html>
<ref-html id="bib1.bib14"><label>14</label><mixed-citation>
Fahey, D. W., Solomon, S., Kawa, S. R., Loewenstein, M., Podolske, J. R.,
Strahan S. E., and Chan, K. R.: A diagnostic for denitrification in the
winter polar stratospheres, Nature, 345, 698–702, 1990.
</mixed-citation></ref-html>
<ref-html id="bib1.bib15"><label>15</label><mixed-citation>
Fleming, E. L., Newman, P. A., Liang, Q., and Daniel, J. S.: The impact of
continuing CFC-11 emissions on stratospheric ozone, J. Geophys. Res., 125,
e2019JD031849, <a href="https://doi.org/10.1029/2019JD031849" target="_blank">https://doi.org/10.1029/2019JD031849</a>, 2020.
</mixed-citation></ref-html>
<ref-html id="bib1.bib16"><label>16</label><mixed-citation>
Garane, K., Lerot, C., Coldewey-Egbers, M., Verhoelst, T., Koukouli, M. E., Zyrichidou, I., Balis, D. S., Danckaert, T., Goutail, F., Granville, J., Hubert, D., Keppens, A., Lambert, J.-C., Loyola, D., Pommereau, J.-P., Van Roozendael, M., and Zehner, C.: Quality assessment of the Ozone_cci Climate Research Data Package (release 2017) – Part 1: Ground-based validation of total ozone column data products, Atmos. Meas. Tech., 11, 1385–1402, <a href="https://doi.org/10.5194/amt-11-1385-2018" target="_blank">https://doi.org/10.5194/amt-11-1385-2018</a>, 2018.
</mixed-citation></ref-html>
<ref-html id="bib1.bib17"><label>17</label><mixed-citation>
Garane, K., Koukouli, M.-E., Verhoelst, T., Lerot, C., Heue, K.-P., Fioletov, V., Balis, D., Bais, A., Bazureau, A., Dehn, A., Goutail, F., Granville, J., Griffin, D., Hubert, D., Keppens, A., Lambert, J.-C., Loyola, D., McLinden, C., Pazmino, A., Pommereau, J.-P., Redondas, A., Romahn, F., Valks, P., Van Roozendael, M., Xu, J., Zehner, C., Zerefos, C., and Zimmer, W.: TROPOMI/S5P total ozone column data: global ground-based validation and consistency with other satellite missions, Atmos. Meas. Tech., 12, 5263–5287, <a href="https://doi.org/10.5194/amt-12-5263-2019" target="_blank">https://doi.org/10.5194/amt-12-5263-2019</a>, 2019.
</mixed-citation></ref-html>
<ref-html id="bib1.bib18"><label>18</label><mixed-citation>
Grooß, J.-U. and Müller, R.: Simulation of the record Arctic
stratospheric ozone depletion in 2020, J. Geophys. Res.,
<a href="https://doi.org/10.1002/essoar.10503569.1" target="_blank">https://doi.org/10.1002/essoar.10503569.1</a>, submitted, 2020.
</mixed-citation></ref-html>
<ref-html id="bib1.bib19"><label>19</label><mixed-citation>
Hansen, G. and Chipperfield, M. P.: Ozone depletion at the edge of the
Arctic polar vortex 1996/1997, J. Geophys. Res., 104, 1837–1845, 1999.
</mixed-citation></ref-html>
<ref-html id="bib1.bib20"><label>20</label><mixed-citation>
Harris, N. R. P., Lehmann, R., Rex, M., and von der Gathen, P.: A closer look at Arctic ozone loss and polar stratospheric clouds, Atmos. Chem. Phys., 10, 8499–8510, <a href="https://doi.org/10.5194/acp-10-8499-2010" target="_blank">https://doi.org/10.5194/acp-10-8499-2010</a>, 2010.
</mixed-citation></ref-html>
<ref-html id="bib1.bib21"><label>21</label><mixed-citation>
Hersbach, H., Bell, B., Berrisford, P., Horányi, A., Muñoz Sabater,
J., Nicolas, J., Radu, R., Schepers, D., Simmons, A., Soci, C., and Dee, D.:
ERA5 hourly data on pressure levels from 1979 to present, Copernicus Climate
Change Service (C3S) Climate Data Store (CDS), <a href="https://doi.org/10.24381/cds.bd0915c6" target="_blank">https://doi.org/10.24381/cds.bd0915c6</a>, 2018.
</mixed-citation></ref-html>
<ref-html id="bib1.bib22"><label>22</label><mixed-citation>
Hersbach, H., Bell, B., Berrisford, P., Horányi, A., Muñoz Sabater,
J., Nicolas, J., Radu, R., Schepers, D., Simmons, A., Soci, C., and Dee, D.:
ERA5 monthly averaged data on pressure levels from 1979 to present,
Copernicus Climate Change Service (C3S) Climate Data Store (CDS),
<a href="https://doi.org/10.24381/cds.6860a573" target="_blank">https://doi.org/10.24381/cds.6860a573</a>, 2019a.
</mixed-citation></ref-html>
<ref-html id="bib1.bib23"><label>23</label><mixed-citation>
Hersbach, H., Bell, B., Berrisford, P., Horányi, A., Sabater, J. M.,
Nicolas, J., Radu, R., Schepers, D., Simmons, A., Soci, C., and Dee, D.:
Global reanalysis: goodbye ERA-Interim, hello ERA5, ECMWF Newsletter, 159,
17–24, <a href="https://doi.org/10.21957/vf291hehd7" target="_blank">https://doi.org/10.21957/vf291hehd7</a>, 2019b.
</mixed-citation></ref-html>
<ref-html id="bib1.bib24"><label>24</label><mixed-citation>
Hersbach, H., Bell, B., Berrisford, P., Hirahara, S., Horányi, A.,
Muñoz-Sabater, J., Nicolas, J., Peubey, C., Radu, R., Schepers, D.,
Simmons, A., Soci, C., Abdalla, S., Abellan, X., Balsamo, G., Bechtold, P.,
Biavati, G., Bidlot, J., Bonavita, M., De Chiara, G., Dahlgren, P., Dee, D.,
Diamantakis, M., Dragani, R., Flemming, J., Forbes, R., Fuentes, M., Geer,
A., Haimberger, L., Healy, S., Hogan, R.J., Hólm, E., Janisková, M.,
Keeley, S., Laloyaux, P., Lopez, P., Lupu, C., Radnoti, G., de Rosnay, P.,
Rozum, I., Vamborg, F., Villaume, S., and Thépaut, J.-N.: The ERA5 Global
Reanalysis, Q. J. Roy. Meteor. Soc., 146, 1999–2049,
<a href="https://doi.org/10.1002/qj.3803" target="_blank">https://doi.org/10.1002/qj.3803</a>, 2020.
</mixed-citation></ref-html>
<ref-html id="bib1.bib25"><label>25</label><mixed-citation>
Hoinka, K. P., Claude, H., and Köhler, U.: On the correlation between
tropopause pressure and ozone above central Europe, Geophys. Res. Lett., 23,
1753–1756, 1996.
</mixed-citation></ref-html>
<ref-html id="bib1.bib26"><label>26</label><mixed-citation>
Hommel, R., Eichmann, K.-U., Aschmann, J., Bramstedt, K., Weber, M., von Savigny, C., Richter, A., Rozanov, A., Wittrock, F., Khosrawi, F., Bauer, R., and Burrows, J. P.: Chemical ozone loss and ozone mini-hole event during the Arctic winter 2010/2011 as observed by SCIAMACHY and GOME-2, Atmos. Chem. Phys., 14, 3247–3276, <a href="https://doi.org/10.5194/acp-14-3247-2014" target="_blank">https://doi.org/10.5194/acp-14-3247-2014</a>, 2014.
</mixed-citation></ref-html>
<ref-html id="bib1.bib27"><label>27</label><mixed-citation>
Hoppel, K., Bevilacqua, R., Allen, D., and Nedoluha, G.: POAM III
observations of the anomalous 2002 Antarctic ozone hole, Geophys. Res.
Lett., 30, 1394, <a href="https://doi.org/10.1029/2003GL016899" target="_blank">https://doi.org/10.1029/2003GL016899</a> 2003GL016899, 2003.
</mixed-citation></ref-html>
<ref-html id="bib1.bib28"><label>28</label><mixed-citation>
Inness, A., Chabrillat, S., Flemming, J., Huijnen, V., Langenrock, B.,
Nicolas, J., Polichtchouk, I., and Razinger, M.: Exceptionally Low Arctic Stratospheric Ozone in Spring 2020 as Seen in the CAMS Reanalysis, J. Geophys. Res.-Atmos., 125, e2020JD033563, <a href="https://doi.org/10.1029/2020JD033563" target="_blank">https://doi.org/10.1029/2020JD033563</a>, 2020.
</mixed-citation></ref-html>
<ref-html id="bib1.bib29"><label>29</label><mixed-citation>
Ivy, D. J., Solomon, S., and Rieder, H. E.: Radiative and dynamical influences on polar stratospheric temperature trends, J. Climate, 29, 4927–4938, <a href="https://doi.org/10.1175/JCLI-D-15-0503.1" target="_blank">https://doi.org/10.1175/JCLI-D-15-0503.1</a>, 2016.
</mixed-citation></ref-html>
<ref-html id="bib1.bib30"><label>30</label><mixed-citation>
James, P. M.: A climatology of ozone mini-holes over the northern
hemisphere, Int. J. Climatol., 18, 1287–1303,
<a href="https://doi.org/10.1002/(SICI)1097-0088(1998100)18:12&lt;1287::AID-JOC315&gt;3.0.CO;2-4" target="_blank">https://doi.org/10.1002/(SICI)1097-0088(1998100)18:12&lt;1287::AID-JOC315&gt;3.0.CO;2-4</a>, 1998.
</mixed-citation></ref-html>
<ref-html id="bib1.bib31"><label>31</label><mixed-citation>
James, P. M. and Peters, D.: The Lagrangian structure of ozone mini-holes and potential vorticity anomalies in the Northern Hemisphere, Ann. Geophys., 20, 835–846, <a href="https://doi.org/10.5194/angeo-20-835-2002" target="_blank">https://doi.org/10.5194/angeo-20-835-2002</a>, 2002.
</mixed-citation></ref-html>
<ref-html id="bib1.bib32"><label>32</label><mixed-citation>
Keeble, J., Abraham, N. L., Archibald, A. T., Chipperfield, M. P., Dhomse, S., Griffiths, P. T., and Pyle, J. A.: Modelling the potential impacts of the recent, unexpected increase in CFC-11 emissions on total column ozone recovery, Atmos. Chem. Phys., 20, 7153–7166, <a href="https://doi.org/10.5194/acp-20-7153-2020" target="_blank">https://doi.org/10.5194/acp-20-7153-2020</a>, 2020.
</mixed-citation></ref-html>
<ref-html id="bib1.bib33"><label>33</label><mixed-citation>
Kivi, R., Kyrö, E., Turunen, T., Harris, N. R. P., von der Gathen, P.,
Rex, M., Andersen, S. B., and Wohltmann, I.: Ozonesonde observations in the
Arctic during 1989–2003: Ozone variability and trends in the lower
stratosphere and free troposphere, J. Geophys. Res., 112, D08306, <a href="https://doi.org/10.1029/2006JD007271" target="_blank">https://doi.org/10.1029/2006JD007271</a>, 2007.
</mixed-citation></ref-html>
<ref-html id="bib1.bib34"><label>34</label><mixed-citation>
Kuttippurath, J., Godin-Beekmann, S., Lefèvre, F., Nikulin, G., Santee, M. L., and Froidevaux, L.: Record-breaking ozone loss in the Arctic winter 2010/2011: comparison with 1996/1997, Atmos. Chem. Phys., 12, 7073–7085, <a href="https://doi.org/10.5194/acp-12-7073-2012" target="_blank">https://doi.org/10.5194/acp-12-7073-2012</a>, 2012.
</mixed-citation></ref-html>
<ref-html id="bib1.bib35"><label>35</label><mixed-citation>
Labitzke, K. and Naujokat, B.: The lower arctic stratosphere in winter
since 1952, SPARC Newsletter No. 15, 11–14, 2000.
</mixed-citation></ref-html>
<ref-html id="bib1.bib36"><label>36</label><mixed-citation>
Langematz, U.: Stratospheric ozone: down and up through the Anthropocene,
ChemTexts, 5, 12, <a href="https://doi.org/10.1007/s40828-019-0082-7" target="_blank">https://doi.org/10.1007/s40828-019-0082-7</a>, 2019.
</mixed-citation></ref-html>
<ref-html id="bib1.bib37"><label>37</label><mixed-citation>
Langematz, U., Meul, S., Grunow, K., Romanowsky, E., Oberländer, S.,
Abalichin, J., and Kubin, A.: Future Arctic temperature and ozone: The role
of stratospheric composition changes, J. Geophys. Res., 119, 2092–2112, <a href="https://doi.org/10.1002/2013JD021100" target="_blank">https://doi.org/10.1002/2013JD021100</a>, 2014.
</mixed-citation></ref-html>
<ref-html id="bib1.bib38"><label>38</label><mixed-citation>
Lawrence, Z. D., Perlwitz, J., Butler, A. H., Manney, G. L., Newman, P. A.,
Lee, S. H., and Nash, E. R.: The remarkable strong Arctic stratospheric polar
vortex of winter 2020: links to record-breaking Arctic oscillation and ozone
loss, J. Geophys. Res.-Atmos., 125, e2020JD033271, <a href="https://doi.org/10.1029/2020JD033271" target="_blank">https://doi.org/10.1029/2020JD033271</a>, 2020.
</mixed-citation></ref-html>
<ref-html id="bib1.bib39"><label>39</label><mixed-citation>
Lee, S. H. and Butler, A. H.: The 2018–2019 Arctic stratospheric polar
vortex, Weather, 75, 52–57, <a href="https://doi.org/10.1002/wea.3643" target="_blank">https://doi.org/10.1002/wea.3643</a>, 2020.
</mixed-citation></ref-html>
<ref-html id="bib1.bib40"><label>40</label><mixed-citation>
Lefèvre, F., Figarol, F., Carslaw, K. S., and Peter, T.: The 1997 Arctic
ozone depletion quantified from three-dimensional model simulations,
Geophys. Res. Lett., 25, 2425–2428, 1998.
</mixed-citation></ref-html>
<ref-html id="bib1.bib41"><label>41</label><mixed-citation>
Lerot C., van Roozendael, M., Spurr, R., Loyola, D. G., Coldewey-Egbers, M.,
Kochenova, S., van Gent, J., Koukouli, M.-E., Balis, D., Lambert, J.-C.,
Granville, J., and Zehner, C.: Homogenized total ozone data records from the
European sensors GOME/ERS-2, SCIAMACHY/Envisat, and GOME-2/MetOp-A,  J. Geophys. Res. Atmos., 119, 1639–1662, <a href="https://doi.org/10.1002/2013JD020831" target="_blank">https://doi.org/10.1002/2013JD020831</a>, 2014.
</mixed-citation></ref-html>
<ref-html id="bib1.bib42"><label>42</label><mixed-citation>
Lim, E.-P., Hendon, H. H., Butler, A. H., Garreaud, R. D., Polichtchouk, I.,
Shepherd, T. G., Scaife, A., Comer, R., Coy, L., Newman, P. A., Thompson, D.
W. J., and Nakamura, H.: The 2019 Antarctic sudden stratospheric warming,
SPARC-Newsletter, 54, 10–13, 2020.
</mixed-citation></ref-html>
<ref-html id="bib1.bib43"><label>43</label><mixed-citation>
Loyola, D. G., Coldewey-Egbers, M., Dameris, M., Garny, H., Stenke, A., van Roozendael, M., Lerot, C., Balis, D., and Koukouli, M.: Global long-term
monitoring of the ozone layer – a prerequisite for predictions,
Int. J. Remote Sens., 30, 4295–4318,
<a href="https://doi.org/10.1080/01431160902825016" target="_blank">https://doi.org/10.1080/01431160902825016</a>, 2009.
</mixed-citation></ref-html>
<ref-html id="bib1.bib44"><label>44</label><mixed-citation>
Manney, G. L., Froidevaux, L., Santee, M. L., Zurek, R. W., and Waters, J. W.: MLS observations of Arctic ozone loss in 1996–97, Geophys. Res. Lett., 24, 2967–2700, <a href="https://doi.org/10.1029/97GL52827" target="_blank">https://doi.org/10.1029/97GL52827</a>, 1997.
</mixed-citation></ref-html>
<ref-html id="bib1.bib45"><label>45</label><mixed-citation>
Manney, G. L., Santee, M. L., Rex, M., Livesey, N. J., Pitts, M. C.,
Veefkind, P., Nash, E. R., Wohltmann, I., Lehmann, R., Froidevaux, L.,
Poole, L. R., Schoeberl, M. R., Haffner, D. P., Davies, J., Dorokhov, V.,
Gernandt, H., Johnson, B., Kivi, R., Kyrö, E., Larsen, N., Levelt, P.
F., Makshtas, A., McElroy, C. T., Nakajima, H., Parrondo, M. C., Tarasick,
D. W., von der Gathen, P., Walker, K. A., and Zinoviev, N. S.: Unprecedented
Arctic ozone loss in 2011, Nature, 478, 469–475, <a href="https://doi.org/10.1038/nature10556" target="_blank">https://doi.org/10.1038/nature10556</a>, 2011.
</mixed-citation></ref-html>
<ref-html id="bib1.bib46"><label>46</label><mixed-citation>
Manney, G. L., Livesey, N. J., Santee, M. L., Froidevaux, L., Lambert, A.,
Lawrence, Z. D., Millán, L. F., Neu, J. L., Read, W. G., Schwartz, M.
J., and Fuller, R. A.: Record-low Arctic stratospheric ozone in 2020: MLS
observations of chemical processes and comparisons with previous extreme
winters, Geophys. Res. Lett., 47, e2020GL089063, <a href="https://doi.org/10.1029/2020GL089063" target="_blank">https://doi.org/10.1029/2020GL089063</a>, 2020.
</mixed-citation></ref-html>
<ref-html id="bib1.bib47"><label>47</label><mixed-citation>
Maycock, A. C., Randel, W. J., Steiner, A. K., Karpechko, A. Y., Christy,
J., Saunders, R., Thompson, D. W. J., Zou, C.-Z., Chrysanthou, A., Abraham,
N. L., Akiyoshi, H., Archibald, A. T., Butchart, N., Chipperfield, M.,
Dameris, M., Deushi, M., Dhomse, S., Di Genova, G., Jöckel, P.,
Kinnison, D. E., Kirner, O., Ladstaedter, F., Michou, M., Morgenstern, O.,
O'Connor, F., Oman, L., Pitari, G., Plummer, D. A., Revell,
L. E., Rozanov, E., Stenke, A., Visioni, D., Yamashita, Y., and Zeng, G.:
Revisiting the mystery of recent stratospheric temperature trends, Geophys.
Res. Lett., 45, 9919–9933, <a href="https://doi.org/10.1029/2018GL078035" target="_blank">https://doi.org/10.1029/2018GL078035</a>, 2018.
</mixed-citation></ref-html>
<ref-html id="bib1.bib48"><label>48</label><mixed-citation>
Millán, L. F. and Manney, G. L.: An assessment of ozone mini-hole representation in reanalyses over the Northern Hemisphere, Atmos. Chem. Phys., 17, 9277–9289, <a href="https://doi.org/10.5194/acp-17-9277-2017" target="_blank">https://doi.org/10.5194/acp-17-9277-2017</a>, 2017.
</mixed-citation></ref-html>
<ref-html id="bib1.bib49"><label>49</label><mixed-citation>
Montzka, S. A., Dutton, R., Yu, P., Ray, E., Portmann, R. W., Daniel, J. S.,
Kuijpers, L., Hall, B. D., Mondeel, D., Siso, C., Nance, D. J., Rigby, M.,
Manning, A. J., Hu, L., Moore, F., Miller, B. R., and Elkins, J. W.: A
persistent and unexpected increase in global emissions of ozone-depleting
CFC-11, Nature, 557, 413–417, <a href="https://doi.org/10.1038/s41586-018-0106-2" target="_blank">https://doi.org/10.1038/s41586-018-0106-2</a>,
2018.
</mixed-citation></ref-html>
<ref-html id="bib1.bib50"><label>50</label><mixed-citation>
NCL, The NCAR Command Language (Version 6.5.0) [Software], Boulder,
Colorado, UCAR/NCAR/CISL/TDD, <a href="https://doi.org/10.5065/D6WD3XH5" target="_blank">https://doi.org/10.5065/D6WD3XH5</a>, 2018.
</mixed-citation></ref-html>
<ref-html id="bib1.bib51"><label>51</label><mixed-citation>
Newman, P. A., Nash, E. R., and Rosenfield, J. E.: What controls the temperature
of the Arctic stratosphere during the spring?, J. Geophys. Res., 106,
19999–20010, 2001.
</mixed-citation></ref-html>
<ref-html id="bib1.bib52"><label>52</label><mixed-citation>
Peters, D., Egger, J., and Entzian, G.: Dynamical aspects of ozone mini-hole
formation, Meteorol. Atmos. Phys., 55, 205–214,
<a href="https://doi.org/10.1007/BF01029827" target="_blank">https://doi.org/10.1007/BF01029827</a>, 1995.
</mixed-citation></ref-html>
<ref-html id="bib1.bib53"><label>53</label><mixed-citation>
Petzoldt, K.: The role of dynamics in total ozone deviations from their long-term mean over the Northern Hemisphere, Ann. Geophys., 17, 231–241, <a href="https://doi.org/10.1007/s00585-999-0231-1" target="_blank">https://doi.org/10.1007/s00585-999-0231-1</a>, 1999.
</mixed-citation></ref-html>
<ref-html id="bib1.bib54"><label>54</label><mixed-citation>
Pommereau J.-P., Goutail, F., Pazmino, A., Lefèvre, F., Chipperfield, M.
P., Feng, W., van Roozendael, M., Jepsen, N., Hansen, G., Kivi, R., Bognar,
K., Strong, K., Walker, K., Kuzmichev, A., Khattatov, S., and Sitnikova, V.:
Recent Arctic ozone depletion: Is there an impact of climate change? Comptes
Rendus Géoscience, Elsevier Masson, 350, 347–353, <a href="https://doi.org/10.1016/j.crte.2018.07.009" target="_blank">https://doi.org/10.1016/j.crte.2018.07.009</a>, 2018.
</mixed-citation></ref-html>
<ref-html id="bib1.bib55"><label>55</label><mixed-citation>
Rex, M., Salawitch, R. J., Toon, G. C., Sen, B., Margitan, J. J., Osterman,
G. B., Blavier, J.-F., Gao, R. S., Donnelly, S., Keim, E., Neuman, J.,
Fahey, D. W., Webster, C. R., Scott, D.C., Herman, R. L., May, R. D., Moyer,
E. J., Gunson, M. R., Irion, F. W., Chang, A. Y., Rinsland, C. P., and Bui,
T. P.: Subsidence, mixing, and denitrification of Arctic polar vortex air
measured During POLARIS, J. Geophys. Res., 104, 26611–26623, 1999.
</mixed-citation></ref-html>
<ref-html id="bib1.bib56"><label>56</label><mixed-citation>
Rex, M., Salawitch, R. J., von der Gathen, P., Harris, N. R. P.,
Chipperfield, M. P., and Naujokat, B.: Arctic ozone loss and climate change,
Geophys. Res. Lett., 31, L04116, <a href="https://doi.org/10.1029/2003GL018844" target="_blank">https://doi.org/10.1029/2003GL018844</a>, 2004.
</mixed-citation></ref-html>
<ref-html id="bib1.bib57"><label>57</label><mixed-citation>
Schulzweida, U.: CDO User Guide (Version 1.9.6),
<a href="https://doi.org/10.5281/zenodo.2558193" target="_blank">https://doi.org/10.5281/zenodo.2558193</a>, 2019.
</mixed-citation></ref-html>
<ref-html id="bib1.bib58"><label>58</label><mixed-citation>
Sinnhuber, B.-M., Weber, M., Amankwah, A., and Burrows, J. P.: Total ozone
during the unusual Antarctic winter of 2002, Geophys. Res. Lett., 30,
1580–1584, 2003.
</mixed-citation></ref-html>
<ref-html id="bib1.bib59"><label>59</label><mixed-citation>
Sinnhuber, B.-M., Stiller, G., Ruhnke, R., von Clarmann, T., Kellmann, S.,
and Aschmann, J.: Arctic winter 2010/2011 at the brink of an ozone hole,
Geophys. Res. Lett., 38, L24814, <a href="https://doi.org/10.1029/2011GL049784" target="_blank">https://doi.org/10.1029/2011GL049784</a>, 2011.
</mixed-citation></ref-html>
<ref-html id="bib1.bib60"><label>60</label><mixed-citation>
Solomon, S.: Stratospheric ozone depletion: a review of concepts and
history, Rev. Geophys., 37, 275–316, 1999.
</mixed-citation></ref-html>
<ref-html id="bib1.bib61"><label>61</label><mixed-citation>
Solomon, S., Haskins, J., Ivy, D. J., and Min, F.: Fundamental differences
between Arctic and Antarctic ozone depletion, P. Natl. Acad. Sci. USA, 111, 6220–6225,
<a href="https://doi.org/10.1073/pnas.1319307111" target="_blank">https://doi.org/10.1073/pnas.1319307111</a>, 2014.
</mixed-citation></ref-html>
<ref-html id="bib1.bib62"><label>62</label><mixed-citation>
Solomon, S., Ivy, D. J., Kinnison, D., Mills, M. J., Neely III, R. R., and
Schmidt, A.: Emergence of healing in the Antarctic ozone layer, Science,
353, 269–274, <a href="https://doi.org/10.1126/science.aae0061" target="_blank">https://doi.org/10.1126/science.aae0061</a>, 2016.
</mixed-citation></ref-html>
<ref-html id="bib1.bib63"><label>63</label><mixed-citation>
SPARC: SPARC Report on the Lifetimes of Stratospheric Ozone-Depleting
Substances, Their Replacements, and Related Species, edited by: Ko, M., Newman, P., Reimann, S., and Strahan, S., SPARC Report No. 6, WCRP-15/2013, available at: <a href="https://www.sparc-climate.org/publications/sparc-reports/sparc-report-no-6/" target="_blank"/> (last access: 15 January 2021), 2013.
</mixed-citation></ref-html>
<ref-html id="bib1.bib64"><label>64</label><mixed-citation>
Steinbrecht, W., Claude, H., Köhler, U., and Hoinka, K. P.: Correlations
between tropopause height and total ozone: Implications for long-term
changes, J. Geophys. Res., 103, 19183–19192, 1998.
</mixed-citation></ref-html>
<ref-html id="bib1.bib65"><label>65</label><mixed-citation>
Steiner, A. K., Ladstädter, F., Randel, W. J., Maycock, A. C., Fu, Q.,
Claud, C., Gleisner, H., Haimberger, L., Ho, S.-P., Keckhut, P., Leblanc,
T., Mears, C., Polvani, L. M., Santer, B. D., Schmidt, T., Sofieva, V.,
Wing, R., and Zou, C.-Z.: Observed temperature changes in the troposphere
and stratosphere from 1979 to 2018, J. Climate, 33, 8165–8194, <a href="https://doi.org/10.1175/JCLI-D-19-0998.1" target="_blank">https://doi.org/10.1175/JCLI-D-19-0998.1</a>, 2020.
</mixed-citation></ref-html>
<ref-html id="bib1.bib66"><label>66</label><mixed-citation>
Stolarski, R.S., McPeters, R. D., and Newman, P. A.: The Ozone hole of 2002
as measured by TOMS, J. Atmos. Sci., 62, 716–720, 2005.
</mixed-citation></ref-html>
<ref-html id="bib1.bib67"><label>67</label><mixed-citation>
Tegtmeier, S., Rex, M., Wohltmann, I., and Krüger, K.: Relative
importance of dynamical and chemical contributions to Arctic wintertime
ozone, Geophys. Res. Lett., 35, L17801
<a href="https://doi.org/10.1029/2008GL034250" target="_blank">https://doi.org/10.1029/2008GL034250</a>, 2008.
</mixed-citation></ref-html>
<ref-html id="bib1.bib68"><label>68</label><mixed-citation>
Tilmes, S., Müller, R., Engel, A., Rex, M., and Russell III, J. M.:
Chemical ozone loss in the Arctic and Antarctic stratosphere between 1992
and 2005, Geophys. Res. Lett.. 33, L20812,
<a href="https://doi.org/10.1029/2006GL026925" target="_blank">https://doi.org/10.1029/2006GL026925</a>, 2006.
</mixed-citation></ref-html>
<ref-html id="bib1.bib69"><label>69</label><mixed-citation>
Van Geffen, J., Van Weele, M., Allaart, M. and Van der A, R.: TEMIS UV index
and UV dose operational data products, version 2, dataset, Royal Netherlands
Meteorological Institute (KNMI), <a href="https://doi.org/10.21944/temis-uv-oper-v2" target="_blank">https://doi.org/10.21944/temis-uv-oper-v2</a>, 2017.
</mixed-citation></ref-html>
<ref-html id="bib1.bib70"><label>70</label><mixed-citation>
Waibel, A. E., Peter, T., Carslaw, K. S., Oelhaf, H., Wetzel, G., Crutzen,
P. J., Poeschl, U., Tsias, A., Reimer, E., and Fischer, H.: Arctic ozone
loss due to denitrification, Science, 283, 2064–2069, 1999.
</mixed-citation></ref-html>
<ref-html id="bib1.bib71"><label>71</label><mixed-citation>
Wargan, K., Weir, B., Manney, G. L., Cohn, S., and Livesey, N. J.: The anomalous 2019 Antarctic ozone hole in the GEOS Constituent Data Assimilation System with MLS observations, J. Geophys. Res.-Atmos., 125, e2020JD033335, <a href="https://doi.org/10.1029/2020JD033335" target="_blank">https://doi.org/10.1029/2020JD033335</a>, 2020.
</mixed-citation></ref-html>
<ref-html id="bib1.bib72"><label>72</label><mixed-citation>
Weber, M., Coldewey-Egbers, M., Fioletov, V. E., Frith, S. M., Wild, J. D., Burrows, J. P., Long, C. S., and Loyola, D.: Total ozone trends from 1979 to 2016 derived from five merged observational datasets – the emergence into ozone recovery, Atmos. Chem. Phys., 18, 2097–2117, <a href="https://doi.org/10.5194/acp-18-2097-2018" target="_blank">https://doi.org/10.5194/acp-18-2097-2018</a>, 2018.
</mixed-citation></ref-html>
<ref-html id="bib1.bib73"><label>73</label><mixed-citation>
WMO (World Meteorological Organization): Scientific Assessment of Ozone
Depletion: 1998, Global Ozone Research and Monitoring Project-Report No.
44, Geneva, Switzerland, 558 pp., 1999.
</mixed-citation></ref-html>
<ref-html id="bib1.bib74"><label>74</label><mixed-citation>
WMO (World Meteorological Organization): Scientific Assessment of Ozone
Depletion: 2002, Global Ozone Research and Monitoring Project-Report No.
47, 498 pp., Geneva, Switzerland, 2003.
</mixed-citation></ref-html>
<ref-html id="bib1.bib75"><label>75</label><mixed-citation>
WMO (World Meteorological Organization): Scientific Assessment of Ozone
Depletion: 2014, Global Ozone Research and Monitoring Project-Report No. 55,
416 pp., Geneva, Switzerland, 2014.
</mixed-citation></ref-html>
<ref-html id="bib1.bib76"><label>76</label><mixed-citation>
WMO (World Meteorological Organization): Scientific Assessment of Ozone
Depletion: 2018, Global Ozone Research and Monitoring Project-Report No.
58, 588 pp., Geneva, Switzerland, 2018.

</mixed-citation></ref-html>
<ref-html id="bib1.bib77"><label>77</label><mixed-citation>
Wohltmann, I., von der Gathen, P., Lehmann, R., Maturilli, M., Deckelmann,
H., Manney, G. L., Davis, J., Tarasick, D., Jepsen, N., Kivi, R., Lyall, N.,
and Rex, M.: Near complete local reduction of Arctic stratospheric ozone by
severe chemical loss in spring 2020, Geophys. Res. Lett., 47, e2020GL089547, <a href="https://doi.org/10.1029/2020GL089547" target="_blank">https://doi.org/10.1029/2020GL089547</a>, 2020.
</mixed-citation></ref-html>--></article>
