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<article xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:oasis="http://docs.oasis-open.org/ns/oasis-exchange/table" xml:lang="en" dtd-version="3.0" article-type="research-article">
  <front>
    <journal-meta><journal-id journal-id-type="publisher">ACP</journal-id><journal-title-group>
    <journal-title>Atmospheric Chemistry and Physics</journal-title>
    <abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title><abbrev-journal-title abbrev-type="nlm-ta">Atmos. Chem. Phys.</abbrev-journal-title>
  </journal-title-group><issn pub-type="epub">1680-7324</issn><publisher>
    <publisher-name>Copernicus Publications</publisher-name>
    <publisher-loc>Göttingen, Germany</publisher-loc>
  </publisher></journal-meta>
    <article-meta>
      <article-id pub-id-type="doi">10.5194/acp-21-11927-2021</article-id><title-group><article-title>The sporadic sodium layer: a possible tracer for the conjunction between the upper and lower atmospheres</article-title><alt-title>Sporadic sodium layer</alt-title>
      </title-group><?xmltex \runningtitle{Sporadic sodium layer}?><?xmltex \runningauthor{S.~Qiu~et~al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1 aff2 aff3">
          <name><surname>Qiu</surname><given-names>Shican</given-names></name>
          <email>scq@ustc.edu.cn</email>
        <ext-link>https://orcid.org/0000-0001-7936-7574</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1 aff4 aff5">
          <name><surname>Wang</surname><given-names>Ning</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff6 aff7">
          <name><surname>Soon</surname><given-names>Willie</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Lu</surname><given-names>Gaopeng</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-4523-0144</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2 aff3">
          <name><surname>Jia</surname><given-names>Mingjiao</given-names></name>
          
        <ext-link>https://orcid.org/0000-0003-4392-4900</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2 aff3">
          <name><surname>Wang</surname><given-names>Xingjin</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2 aff3">
          <name><surname>Xue</surname><given-names>Xianghui</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2 aff3">
          <name><surname>Li</surname><given-names>Tao</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-5100-4429</ext-link></contrib>
        <contrib contrib-type="author" corresp="yes" rid="aff2 aff3">
          <name><surname>Dou</surname><given-names>Xiankang</given-names></name>
          <email>dou@ustc.edu.cn</email>
        </contrib>
        <aff id="aff1"><label>1</label><institution>Department of Geophysics, College of the Geology Engineering and Geomatics, Chang'an University, Xi'an, 710054, China</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Key Laboratory of Geospace Environment, Chinese Academy of Sciences, University of Science &amp; Technology of China, Hefei, Anhui, 230026, China</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>Mengcheng National Geophysical Observatory, School of Earth and Space Sciences,<?xmltex \hack{\break}?> University of Science and Technology of China, Hefei, Anhui, 230026, China</institution>
        </aff>
        <aff id="aff4"><label>4</label><institution>Department of Geophysics, Gravity &amp; Magnetic Institute of Chang'an University, Xi'an, 710054, China</institution>
        </aff>
        <aff id="aff5"><label>5</label><institution>Key Laboratory of Western China's Mineral Resources and Geological Engineering, China Ministry of Education,<?xmltex \hack{\break}?> Xi'an, 710054, China</institution>
        </aff>
        <aff id="aff6"><label>6</label><institution>Center for Environmental Research and Earth Sciences (CERES), Salem, MA 01970, USA</institution>
        </aff>
        <aff id="aff7"><label>7</label><institution>Institute of Earth Physics and Space Science (ELKH EPSS), 9400, Sopron, Hungary</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Shican Qiu (scq@ustc.edu.cn) and Xiankang Dou (dou@ustc.edu.cn)</corresp></author-notes><pub-date><day>10</day><month>August</month><year>2021</year></pub-date>
      
      <volume>21</volume>
      <issue>15</issue>
      <fpage>11927</fpage><lpage>11940</lpage>
      <history>
        <date date-type="received"><day>16</day><month>October</month><year>2020</year></date>
           <date date-type="accepted"><day>7</day><month>July</month><year>2021</year></date>
           <date date-type="rev-recd"><day>2</day><month>July</month><year>2021</year></date>
           <date date-type="rev-request"><day>29</day><month>December</month><year>2020</year></date>
      </history>
      <permissions>
        <copyright-statement>Copyright: © 2021 </copyright-statement>
        <copyright-year>2021</copyright-year>
      <license license-type="open-access"><license-p>This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/4.0/">https://creativecommons.org/licenses/by/4.0/</ext-link></license-p></license></permissions><self-uri xlink:href="https://acp.copernicus.org/articles/.html">This article is available from https://acp.copernicus.org/articles/.html</self-uri><self-uri xlink:href="https://acp.copernicus.org/articles/.pdf">The full text article is available as a PDF file from https://acp.copernicus.org/articles/.pdf</self-uri>
      <abstract><title>Abstract</title>
    <p id="d1e202">In this research, we reveal the inter-connection between lightning strokes, reversal of the electric field, ionospheric disturbances, and a sodium
layer (<inline-formula><mml:math id="M1" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>), based on the joint observations by a temperature/wind (<inline-formula><mml:math id="M2" display="inline"><mml:mrow><mml:mi>T</mml:mi><mml:mo>/</mml:mo><mml:mi>W</mml:mi></mml:mrow></mml:math></inline-formula>, where the slash means “and”) lidar, an ionosonde, an atmospheric electric mill, a fluxgate
magnetometer, and the World Wide Lightning Location Network (WWLLN). Our results suggest that lightning strokes could trigger or amplify the
formation of an <inline-formula><mml:math id="M3" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> layer in a descending sporadic E layer (E<inline-formula><mml:math id="M4" display="inline"><mml:msub><mml:mi/><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:math></inline-formula>), through a mechanism that involves the overturning of the electric
field. A conjunction between the lower and upper atmospheres could be established as follows by these inter-connected phenomena, and the key processes could be suggested to be: lightning strokes <inline-formula><mml:math id="M5" display="inline"><mml:mo>→</mml:mo></mml:math></inline-formula> overturning of the electric field <inline-formula><mml:math id="M6" display="inline"><mml:mo>→</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M7" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> generating <inline-formula><mml:math id="M8" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <label>1</label><title>Introduction</title>
      <p id="d1e294">The upper mesosphere–lower thermosphere (MLT) is the interface region for momentum and energy exchanges between the Earth's low atmosphere and outer
space. However, on account of the limitations of detection methods, this region remains the least known part of our planet's atmosphere (Wang, 2010).
Fortunately, the metal layers (especially the sodium layer), which is located between about 80–110 <inline-formula><mml:math id="M9" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, could possibly act as a window to detect the MLT parameters by means of fluorescence resonance lidars (Gardner et al., 1986; Gong
et al., 2002, 1997). With an active chemical property, a large resonant backscatter cross section, and a high abundance of sodium atoms, the sodium
layer has been widely observed and studied all over the world (Marsh et al., 2013; Collins et al., 2002; Plane, 2003, 1999). The sporadic sodium layer
(SSL or <inline-formula><mml:math id="M10" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>), with a neutral sodium density that could double within several minutes, is the most fantastic phenomenon observed in the
sodium layer. Since first reported in 1978 (Clemesha et al., 1978), many mechanisms, involving meteor injection (Clemesha et al., 1980), a dust
reservoir (von Zahn et al., 1987), recombination of ions and electrons in sporadic E layer (<inline-formula><mml:math id="M11" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) (Cox and Plane, 1998), and high-temperature
theory (Zhou et al., 1993), have all been proposed. Because the <inline-formula><mml:math id="M12" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is suggested to have a connection to so many atmospheric parameters, the
metric or phenomenon could be appropriate in acting as a tracer for studying the inter-connection between the middle and upper atmospheres. Up to now, a
large number of observations have reported a diversity of <inline-formula><mml:math id="M13" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> features, but the exact mechanism for <inline-formula><mml:math id="M14" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is<?pagebreak page11928?> probably still uncertain
(Collins et al., 2002; Cox et al., 1993; Daire et al., 2002; Gardner et al., 1995; Qiu et al., 2015; Zhou and Mathews, 1995; Zhou et al., 1993).</p>
      <p id="d1e361">Among all the proposed mechanisms, the <inline-formula><mml:math id="M15" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> theory is supported by abundant observations and results from numerical simulations (Cox and
Plane, 1998; Daire et al., 2002; Dou et al., 2009, 2010; Gardner et al., 1993; Gong et al., 2002; Kane et al., 2001; Kane et al., 1993, 1991; Kirkwood
and Nilsson, 2000; Kwon et al., 1988; Mathews et al., 1993; Miyagawa et al., 1999; Nagasawa and Abo, 1995; Nesse et al., 2008; Shibata et al., 2006;
Williams et al., 2006). The key process of <inline-formula><mml:math id="M16" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> theory is the recombination of ions and electrons in the <inline-formula><mml:math id="M17" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> layer while descending
to lower altitudes (Cox and Plane, 1998; Daire et al., 2002). The <inline-formula><mml:math id="M18" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> layer is mainly influenced by the vertical wind shear (Abdu et al.,
2003; Clemesha et al., 1998; Haldoupis et al., 2004; Mathews, 1998; Šauli and Bourdillon, 2008; Wakabayashi and Ono, 2005), the geomagnetic field
(Resende et al., 2013; Resende and Denardini, 2012; Zhang et al., 2015; Denardini et al., 2016), and the electric field (Abdu et al., 2003; Damtie
et al., 2003; Haldoupis et al., 2004; Kirkwood and Nilsson, 2000; Kirkwood and von Zahn, 1991; Macdougall and Jayachandran, 2005; Matuura et al.,
2013; Nygren et al., 2006; Parkinson et al., 1998; Takahashi et al., 2015; Voiculescu et al., 2006; Wakabayashi and Ono, 2005; Wan et al., 2001;
Wilkinson et al., 1992). In the Northern Hemisphere, the <inline-formula><mml:math id="M19" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> layer would descend to a lower
altitude in a southward electric field (Abdu et al., 2003; Damtie et al., 2003; Haldoupis et al., 2004; Kirkwood and Nilsson, 2000; Kirkwood and von
Zahn, 1991; Macdougall and Jayachandran, 2005; Nygrén et al., 2006; Parkinson et al., 1998; Takahashi et al., 2015; Voiculescu et al., 2006;
Wakabayashi and Ono, 2005; Wan et al., 2001; Wilkinson et al., 1992), and observations in the polar
cap suggest that the electric field reversal has an influence on the probability of <inline-formula><mml:math id="M20" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> occurrences (Macdougall and Jayachandran, 2005).</p>
      <p id="d1e431">On the other hand, the atmospheric electric circuit is a closed loop (Driscoll et al., 1992; Jánský and Pasko, 2014; Lv et al., 2004; Roble
and Hays, 1979; Rycroft and Harrison, 2012; Rycroft et al., 2000; Suparta and Fraser, 2012; Tinsley, 2000), like a capacitor with a positive plate
(e.g., the ionosphere) and a negative plate (e.g., the ground) and a dielectric medium between them (e.g., the neutral atmosphere). Then the global
atmospheric electric circuit formed in the capacitor, with the lightning phenomena generating an upward current (with the atmospheric electric field
intensity <inline-formula><mml:math id="M21" display="inline"><mml:mi>E</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M22" display="inline"><mml:mo>&lt;</mml:mo></mml:math></inline-formula> 0) and returning a downward current (<inline-formula><mml:math id="M23" display="inline"><mml:mi>E</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M24" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 0) under fair-weather conditions. Nowadays increasing and emerging evidence is pointing to the close link between the upper atmosphere (e.g., the positive plate) and lower atmosphere (e.g., the negative plate) (Harrison et al.,
2010; Rycroft, 2006). For example, a thunderstorm occurring in the lower atmosphere is suggested to have a direct impact on the <inline-formula><mml:math id="M25" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> layer based
on recent observational results (Bortnik et al., 2006; Christos, 2018; Cummer et al., 2009; Curtius et al., 2006; Davis and Johnson, 2005; Davis and
Lo, 2008; England et al., 2006; Fukunishi et al., 1996; Girish and Eapen, 2008; Haldoupis et al., 2012; Immel et al., 2013; Kumar et al., 2009; Kuo
and Lee, 2015; Lay et al., 2015; Mangla et al., 2016; Maruyama, 2006; Pasko et al., 2002; Rodger et al., 2001; Rycroft, 2006; Sátori et al., 2013;
Sentman and Wescott, 1995; Shao et al., 2013; Sharma et al., 2004; Su et al., 2003; Surkov et al., 2006; Yu et al., 2015) or even on the sodium layer (Yu
et al., 2017). The possible carriers or phenomena connecting the thunderstorm to the upper atmosphere are suggested to be atmospheric tides (England
et al., 2006; Haldoupis et al., 2004; Immel et al., 2013), planetary waves (Lv et al., 2004), gravity waves (Davis and Johnson, 2005; Kumar et al.,
2009; Lay et al., 2015; Shao et al., 2013), transient luminous events (TLEs) (Cummer et al., 2009; Fukunishi et al., 1996; Haldoupis et al., 2012;
Pasko, 2008; Pasko et al., 2002; Sentman and Wescott, 1995; Sharma et al., 2004; Su et al., 2003), the solar activity (Zhang et al., 2020), and also electric fields (Bortnik et al., 2006; Davis and Johnson, 2005; Davis and Lo, 2008; Immel et al., 2013; Kuo and Lee, 2015; Maruyama, 2006;
Rycroft, 2006; Sátori et al., 2013; Shao et al., 2013).</p>
      <p id="d1e473">In this research, we apply five joint observations for our case studies and statistical work: (1) one temperature/wind (<inline-formula><mml:math id="M26" display="inline"><mml:mrow><mml:mi>T</mml:mi><mml:mo>/</mml:mo><mml:mi>W</mml:mi></mml:mrow></mml:math></inline-formula>, where the slash means “and”) lidar at Hefei (31.8<inline-formula><mml:math id="M27" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N,
117.2<inline-formula><mml:math id="M28" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E), providing observations of sodium density, mesopause temperature, and zonal wind; (2) an ionosonde in Wuhan (30.5<inline-formula><mml:math id="M29" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N,
114.6<inline-formula><mml:math id="M30" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E), detecting the <inline-formula><mml:math id="M31" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and ionospheric echoes in different modes; (3) an atmospheric electric mill (30.5<inline-formula><mml:math id="M32" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N,
114.5<inline-formula><mml:math id="M33" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E), giving simultaneous electric field variations; (4) a fluxgate magnetometer (30.5<inline-formula><mml:math id="M34" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 114.5<inline-formula><mml:math id="M35" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E), probing the H,
D, and Z magnetic field components; and (5) the World Wide Lightning Location Network (WWLLN), observing the location and power of a lightning
stroke. The purpose of this study is to examine the possibility of <inline-formula><mml:math id="M36" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> acting as a practical, robust tracer for the conjunction between the
upper and lower atmospheres. Our results suggest that lightning strokes may have an influence on the lower ionosphere, leading to the occurrence of
<inline-formula><mml:math id="M37" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>, with the atmospheric electric field probably playing an important role.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1"><?xmltex \currentcnt{1}?><?xmltex \def\figurename{Figure}?><label>Figure 1</label><caption><p id="d1e598">Observations on 3 June 2013, by the <inline-formula><mml:math id="M38" display="inline"><mml:mrow><mml:mi>T</mml:mi><mml:mo>/</mml:mo><mml:mi>W</mml:mi></mml:mrow></mml:math></inline-formula> lidar of the University of Science &amp; Technology of China (USTC). <bold>(a)</bold> The sodium density profile of the west beam by the <inline-formula><mml:math id="M39" display="inline"><mml:mrow><mml:mi>T</mml:mi><mml:mo>/</mml:mo><mml:mi>W</mml:mi></mml:mrow></mml:math></inline-formula> lidar. A moderate increase in sodium density appears at about 13:20 UT, while the largest intensity of sodium enhancement begins at about 14:20 UT. The sodium density peaks at 14:37 UT around 97.65 <inline-formula><mml:math id="M40" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>. <bold>(b)</bold> Temperature profile observed by the <inline-formula><mml:math id="M41" display="inline"><mml:mrow><mml:mi>T</mml:mi><mml:mo>/</mml:mo><mml:mi>W</mml:mi></mml:mrow></mml:math></inline-formula> lidar, showing a cold region where the <inline-formula><mml:math id="M42" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> occurs. <bold>(c)</bold> The zonal wind detected by the <inline-formula><mml:math id="M43" display="inline"><mml:mrow><mml:mi>T</mml:mi><mml:mo>/</mml:mo><mml:mi>W</mml:mi></mml:mrow></mml:math></inline-formula> lidar, exhibiting a suitable wind shear for the creation or formation of <inline-formula><mml:math id="M44" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>.</p></caption>
        <?xmltex \igopts{width=199.169291pt}?><graphic xlink:href="https://acp.copernicus.org/articles/21/11927/2021/acp-21-11927-2021-f01.png"/>

      </fig>

</sec>
<sec id="Ch1.S2">
  <label>2</label><title>Observations and results</title>
<sec id="Ch1.S2.SS1">
  <label>2.1</label><?xmltex \opttitle{An {$\protect\chem{Na_{{S}}}$} event during the overturning of the electric field}?><title>An <inline-formula><mml:math id="M45" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> event during the overturning of the electric field</title>
      <p id="d1e722">A sporadic sodium layer is detected on the night of 3 June 2013, by the <inline-formula><mml:math id="M46" display="inline"><mml:mrow><mml:mi>T</mml:mi><mml:mo>/</mml:mo><mml:mi>W</mml:mi></mml:mrow></mml:math></inline-formula> lidar (Li et al., 2012). The peak density observed by the west beam of
the <inline-formula><mml:math id="M47" display="inline"><mml:mrow><mml:mi>T</mml:mi><mml:mo>/</mml:mo><mml:mi>W</mml:mi></mml:mrow></mml:math></inline-formula> lidar is 8650 <inline-formula><mml:math id="M48" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">cm</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>. This <inline-formula><mml:math id="M49" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> event occurs much higher above the centroid height of the sodium layer (normally at about
92 <inline-formula><mml:math id="M50" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>) (Qiu et al., 2016). Figure 1a shows that the sodium density begins to increase at about 13:20 UT, while the largest intensity of<?pagebreak page11929?> sodium
enhancement occurs from about 14:20 UT, with a peak density located around 97.65 <inline-formula><mml:math id="M51" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> at 14:37 UT. The simultaneous temperature observation by
the <inline-formula><mml:math id="M52" display="inline"><mml:mrow><mml:mi>T</mml:mi><mml:mo>/</mml:mo><mml:mi>W</mml:mi></mml:mrow></mml:math></inline-formula> lidar reveals that this <inline-formula><mml:math id="M53" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> occurs in a cold region (Fig. 1b), so the high-temperature mechanism appears to be inapplicable for this
event.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2"><?xmltex \currentcnt{2}?><?xmltex \def\figurename{Figure}?><label>Figure 2</label><caption><p id="d1e816">Sporadic E layers observed by the ionosonde at Wuhan (30.5<inline-formula><mml:math id="M54" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 114.6<inline-formula><mml:math id="M55" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E). <bold>(a)</bold> The time series of the critical frequency for <inline-formula><mml:math id="M56" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math id="M57" display="inline"><mml:mrow><mml:mi mathvariant="italic">fo</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:mrow></mml:math></inline-formula>). The <inline-formula><mml:math id="M58" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> layers travel/propagate downward starting around 06:30 UT and decreases to a minimum value at about 13:20 UT. <bold>(b)</bold> The visual height of <inline-formula><mml:math id="M59" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math id="M60" display="inline"><mml:mrow><mml:msup><mml:mi>h</mml:mi><mml:mo>′</mml:mo></mml:msup><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:mrow></mml:math></inline-formula>). The blue dotted vertical line shows the beginning of the <inline-formula><mml:math id="M61" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> around 13:20 UT, and the red dashed vertical line indicates the time when the most intense sodium enhancement starts at 14:20 UT.</p></caption>
          <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://acp.copernicus.org/articles/21/11927/2021/acp-21-11927-2021-f02.png"/>

        </fig>

      <p id="d1e925">On the other hand, the zonal wind exhibits a suitable wind shear for creating those sporadic E layers, with a westward wind above and an eastward wind
below (Fig. 1c). The <inline-formula><mml:math id="M62" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> layer is predicted to form around the border of the wind shear. Observations by the ionosonde at Wuhan indeed show
active sporadic E layers on that day (Fig. 2a and b). The <inline-formula><mml:math id="M63" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> series keep traveling/propagating downward starting around 06:30 UT and
decreases to a minimum value while the <inline-formula><mml:math id="M64" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> occurs coincidently at about 13:20 UT. Thus this <inline-formula><mml:math id="M65" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is better explained by the
<inline-formula><mml:math id="M66" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> mechanism, in accordance with our previous study which shows that an <inline-formula><mml:math id="M67" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> higher than 96 <inline-formula><mml:math id="M68" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> tends to be controlled by the
<inline-formula><mml:math id="M69" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> mechanism (Qiu et al., 2016). Although the content of sodium ions in <inline-formula><mml:math id="M70" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> layers seemed to have insufficient concentration (von
Zahn et al., 1989), it has also been proposed that the ions could be effectively concentrated by the wind shear (Clemesha et al., 1999; Cox and Plane,
1998; Nesse et al., 2008). On the other hand, laboratory results show that the ligand complexes of <inline-formula><mml:math id="M71" display="inline"><mml:mrow><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mi mathvariant="normal" class="Radical">⚫</mml:mi><mml:mi>X</mml:mi></mml:mrow></mml:math></inline-formula> would form and thus speed up
the recombination of ions in mesopause conditions (Collins et al., 2002; Cox and Plane, 1998; Daire et al., 2002). The calculated reaction rate
suggests that the formation of cluster ions is enhanced at lower temperatures, in accordance with the cold region observed in Fig. 1c where the sporadic
sodium layer occurs.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3"><?xmltex \currentcnt{3}?><?xmltex \def\figurename{Figure}?><label>Figure 3</label><caption><p id="d1e1044">Observations of some atmospheric parameters and some deduced results. <bold>(a)</bold> Time series of sodium density variations at peak height 97.65 <inline-formula><mml:math id="M72" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, observed by the west beam of the <inline-formula><mml:math id="M73" display="inline"><mml:mrow><mml:mi>T</mml:mi><mml:mo>/</mml:mo><mml:mi>W</mml:mi></mml:mrow></mml:math></inline-formula> lidar. The sodium density begins to increase at about 14:20 UT. <bold>(b)</bold> Atmospheric electric field variations, exhibiting a synchronous overturning from 14:20 UT with the enhancement of sodium density (also indicated by the red dashed vertical line). Note that there is another overturning peaking at 15:15 UT, without another <inline-formula><mml:math id="M74" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> being produced, which could be explained by a depletion of ions in the <inline-formula><mml:math id="M75" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. The electric field recovers at about 15:30 UT. <bold>(c)</bold> Horizontal magnetic field observed by the fluxgate magnetometer. <bold>(d)</bold> The deduced magnetic induction intensity from observations of <inline-formula><mml:math id="M76" display="inline"><mml:mi>H</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M77" display="inline"><mml:mi>D</mml:mi></mml:math></inline-formula>, and <inline-formula><mml:math id="M78" display="inline"><mml:mi>Z</mml:mi></mml:math></inline-formula> components by the fluxgate magnetometer (<inline-formula><mml:math id="M79" display="inline"><mml:mrow><mml:mi>B</mml:mi><mml:mo>=</mml:mo><mml:msqrt><mml:mrow><mml:msup><mml:mi>H</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>+</mml:mo><mml:msup><mml:mi>D</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>+</mml:mo><mml:msup><mml:mi>Z</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:msqrt></mml:mrow></mml:math></inline-formula>).</p></caption>
          <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://acp.copernicus.org/articles/21/11927/2021/acp-21-11927-2021-f03.png"/>

        </fig>

      <?pagebreak page11930?><p id="d1e1161">More details about the atmospheric parameters are shown in Fig. 3. The time series of sodium density on the peak height display a sharp enhancement
from 14:20 UT (marked by the red dashed vertical line in Fig. 3a). The atmospheric electric field detected by the mill exhibits an overturning at
around 14:20 UT, alternating from a downward direction to upward (Fig. 3b). It can be clearly observed that the enhancement of sodium density occurs
coincidentally with the overturning of the electric field, as highlighted by the red dashed vertical line in Fig. 3. A nearby fluxgate magnetometer
provides the horizontal magnetic field <inline-formula><mml:math id="M80" display="inline"><mml:mi>H</mml:mi></mml:math></inline-formula> (nT) (Fig. 3c), showing disturbances at 14:15 UT. The total magnetic intensity <inline-formula><mml:math id="M81" display="inline"><mml:mi>B</mml:mi></mml:math></inline-formula> could be deduced by the
<inline-formula><mml:math id="M82" display="inline"><mml:mi>H</mml:mi></mml:math></inline-formula>, <inline-formula><mml:math id="M83" display="inline"><mml:mi>Z</mml:mi></mml:math></inline-formula>, and <inline-formula><mml:math id="M84" display="inline"><mml:mi>D</mml:mi></mml:math></inline-formula> components (<inline-formula><mml:math id="M85" display="inline"><mml:mi>B</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M86" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M87" display="inline"><mml:msqrt><mml:mrow><mml:msup><mml:mi>H</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>+</mml:mo><mml:msup><mml:mi>D</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>+</mml:mo><mml:msup><mml:mi>Z</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:msqrt></mml:math></inline-formula>) from fluxgate magnetometer observations (the calculated values are plotted in
Fig. 3d).</p>
      <p id="d1e1240">It is worth noting that the overturning of atmospheric electric field discussed here is theoretically rough, since the electric field at the lower
ionosphere will be modulated as well (e.g., with a value of several mV m<inline-formula><mml:math id="M88" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>; Seyler et al., 2004). Nevertheless, model simulations from the
electrodynamics show that the upward electric field in the upper atmosphere is proportional to the source current in the troposphere (Driscoll et al.,
1992) and that the upward current would continue transmitting to the heights of 100–130 <inline-formula><mml:math id="M89" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> of the dynamo region where <inline-formula><mml:math id="M90" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> occurs most frequently (Rycroft et al., 2012). The model, based on rocket observations, shows that
the atmospheric electric field has a similar scale and the same polarity from the ground to the altitude of the ionosphere (Abdu et al., 2003). Thus, the
electric field detected by a ground-based mill could reasonably be a reflection of the actual situation in the lower ionosphere, at least for the
trends and tendencies of variations.</p>
</sec>
<sec id="Ch1.S2.SS2">
  <label>2.2</label><title>Possible influences by the atmospheric electric circuit</title>
      <p id="d1e1282">The atmospheric electric circuit is formed by the ionosphere and ground surface with the dielectric medium (e.g., the neutral atmosphere) sandwiched
between them (Driscoll et al., 1992; Harrison, 2020; Jánský and Pasko, 2014; Lv et al., 2004; Roble and Hays, 1979; Rycroft and Harrison,
2012; Rycroft et al., 2000, 2012, 2007; Suparta and Fraser, 2012; Tinsley, 2000). The lightning phenomena and thunderstorms, acting as the electric
generator for the circuit, drive an upward current to the ionosphere. In a fair-weather regime, the electric field is directed downward to the earth surface
(<inline-formula><mml:math id="M91" display="inline"><mml:mi>E</mml:mi></mml:math></inline-formula> <inline-formula><mml:math id="M92" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 0), making a closed global electric circuit (see Fig. A1 in the Appendix). The electric field could vary through
two distinct ways as follows. The first one is the changing magnetic field explained by Faraday's law (e.g., <inline-formula><mml:math id="M93" display="inline"><mml:mrow><mml:mi mathvariant="normal">∇</mml:mi><mml:mo>⋅</mml:mo><mml:mover><mml:mi>E</mml:mi><mml:mo>→</mml:mo></mml:mover><mml:mo>=</mml:mo><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mo>-</mml:mo><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mrow><mml:mo>∂</mml:mo><mml:mover><mml:mi>B</mml:mi><mml:mo>→</mml:mo></mml:mover></mml:mrow><mml:mrow><mml:mo>∂</mml:mo><mml:mi>t</mml:mi></mml:mrow></mml:mfrac></mml:mstyle></mml:mrow></mml:math></inline-formula>). However, observations by the fluxgate magnetometer show that
there is just a small disturbance of the magnetic field during the overturning of the electric field. The other way is the electrostatic induction following Coulomb's law (<inline-formula><mml:math id="M94" display="inline"><mml:mrow><mml:mover><mml:mi>E</mml:mi><mml:mo>→</mml:mo></mml:mover><mml:mo>=</mml:mo><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mn mathvariant="normal">1</mml:mn><mml:mrow><mml:mn mathvariant="normal">4</mml:mn><mml:mi mathvariant="italic">π</mml:mi><mml:msub><mml:mi mathvariant="italic">ε</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mi>Q</mml:mi><mml:mrow><mml:msup><mml:mi>r</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:mfrac></mml:mstyle><mml:mover accent="true"><mml:mi>r</mml:mi><mml:mo mathvariant="normal" stretchy="false">^</mml:mo></mml:mover></mml:mrow></mml:math></inline-formula>). The connection between the lightning stroke and
the overturning of the electric field could be explained by the classic thunderstorm charge model through the electric imaging method based on Coulomb's
law (i.e., this model could be supported by the classic electrodynamics textbook written by  Griffiths, 1999). A typical thundercloud (e.g., pairs
of (<inline-formula><mml:math id="M95" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M96" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:msub><mml:mi>Q</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>) or (<inline-formula><mml:math id="M97" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:msub><mml:mi>Q</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M98" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>) in Fig. A1), with a dipole of positive charge located above a negative charge part, which would produce an
upward electric field toward the ionosphere (see more details in Appendix A).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4"><?xmltex \currentcnt{4}?><?xmltex \def\figurename{Figure}?><label>Figure 4</label><caption><p id="d1e1427">The lightning strokes are detected by WWLLN. The continuously strongest lightnings with a power larger than 10<inline-formula><mml:math id="M99" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">4</mml:mn></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M100" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">kW</mml:mi></mml:mrow></mml:math></inline-formula> occur from 13:19 to 15:43 UT, mainly concentrated around areas within 35.8<inline-formula><mml:math id="M101" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 118.1<inline-formula><mml:math id="M102" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E and 25.1<inline-formula><mml:math id="M103" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 113.8<inline-formula><mml:math id="M104" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E.</p></caption>
          <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://acp.copernicus.org/articles/21/11927/2021/acp-21-11927-2021-f04.png"/>

        </fig>

      <p id="d1e1490">According to the observations from WWLLN, we find two regions (red ovals A and B in Fig. 4) with heavy lightning activities during the period of the
<inline-formula><mml:math id="M105" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. Before the <inline-formula><mml:math id="M106" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> occurrences, there were only a few powerful lightnings detected within about 25.1–35.8<inline-formula><mml:math id="M107" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N and 113.8–118.1<inline-formula><mml:math id="M108" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E during the period of 12:00 to 13:15 UT (just one strong stroke with a power of 43 720.25 <inline-formula><mml:math id="M109" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">kW</mml:mi></mml:mrow></mml:math></inline-formula> happening at 12:17 UT, at
25.7229<inline-formula><mml:math id="M110" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N and 117.3955<inline-formula><mml:math id="M111" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E). The continuously strongest lightnings with a power larger than 10<inline-formula><mml:math id="M112" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">4</mml:mn></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M113" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">kW</mml:mi></mml:mrow></mml:math></inline-formula> occur from 13:19 to
15:43 UT, mainly concentrating in two areas centered around 35.8<inline-formula><mml:math id="M114" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 118.1<inline-formula><mml:math id="M115" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E and 25.1<inline-formula><mml:math id="M116" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 113.8<inline-formula><mml:math id="M117" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E. After
15:45 UT, no strong strokes were detected again within this area. Thus, the pairs of (<inline-formula><mml:math id="M118" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M119" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:msub><mml:mi>Q</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>) and (<inline-formula><mml:math id="M120" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:msub><mml:mi>Q</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M121" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>) could<?pagebreak page11931?> refer to
the lightning area of part A and B in Fig. 4. Since thunderstorms could trigger the breakdown process within a rather large area (Leblanc et al.,
2008) and influence the ionosphere with around more than 800 <inline-formula><mml:math id="M122" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> range horizontally away from the lightning center (Johnson and Davis, 2006;
Johnson et al., 1999), the whole area above might undergo a breakdown easily around <inline-formula><mml:math id="M123" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>–<inline-formula><mml:math id="M124" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> (e.g., the whole shadow zone in Fig. 4, involving the two strongest lightning areas and the two observing stations).</p>
      <p id="d1e1694">In previous studies, lightning strokes in the lower atmosphere were reported to cause a reduction of electrons of the ionosphere (Shao et al., 2013) and conversely an enhancement of sodium density in the metal layer (Yu et al., 2017). Those two scenarios are in accordance with our current results presented
above, i.e., with a depletion of <inline-formula><mml:math id="M125" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> at 13:20 UT and a consequential occurrence of <inline-formula><mml:math id="M126" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. Although such an idea/picture was proposed a long time ago
(Griffiths, 1999), this is the first time that one can apply the imaging method for observing thunderstorms to explain the link between upper and
lower atmospheres through an overturning of the upward electric field.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5" specific-use="star"><?xmltex \currentcnt{5}?><?xmltex \def\figurename{Figure}?><label>Figure 5</label><caption><p id="d1e1721">Extraordinary echoes by the Wuhan ionosonde in different modes. <bold>(a–c)</bold> From 13:15 to 13:45 UT, the echoes gradually increase. Note that the powerful lightning period begins at 13:15 UT as well, with the sodium density enhancement and the <inline-formula><mml:math id="M127" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> depletion occurring at about 13:20 UT. <bold>(d–g)</bold> The most intense echo signals occur during 14:00 to 14:45 UT, while the largest intensity of sodium enhancement begins at 14:20 UT and the sodium density peaks at 14:40 UT. The overturning of the electric field also occurs at 14:20 UT. <bold>(h–j)</bold> From 15:00 to 15:30 UT, the signals weaken gradually. <bold>(k–l)</bold> The echoes vanish after 15:45 UT. Afterwards, no strong stroke is detected again within the discussed area. Meanwhile, the ionospheric echoes diminish after 15:45 UT, and the overturning of the electric field also recovers at about 15:30 UT.</p></caption>
          <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://acp.copernicus.org/articles/21/11927/2021/acp-21-11927-2021-f05.png"/>

        </fig>

      <p id="d1e1753">Furthermore, the results from different channels of the Wuhan ionosonde exhibit extraordinary echoes in different modes during the lightning period
(Fig. 5a–l). Figure 5a–c show that, from 13:15 to 13:45 UT, the echoes gradually increase. Note that the
powerful lightning period begins at 13:15 UT as well, with the sodium density enhancement occurring at about 13:20 UT. Figure 5d–g show that the most intense echo signals occur during 14:00 to 14:45 UT, while the largest intensity of sodium enhancement
begins at 14:20 UT and the sodium density peaks at 14:40 UT. The overturning of the electric field also occurs at
14:20 UT. Figure 5h–j show that, from 15:00 UT to 15:30 UT, the signals weaken gradually; Fig. 5k
and l show that, the echoes vanish after 15:45 UT. Afterwards, no strong stroke is detected again in the
discussed area. Meanwhile, the ionospheric echoes diminish after 15:45 UT, and the overturning of the electric field also recovers at about
15:30 UT. Thus, in this case the ionospheric echoes and the lightning activities exhibit an obvious synchronous behavior.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1" specific-use="star"><?xmltex \currentcnt{1}?><label>Table 1</label><caption><p id="d1e1759">Ion–molecule reaction rate coefficients for Na summarized from previous reports (Cox and Plane, 1998; Jiao et al., 2017; Plane et al., 2015, 2004; Yuan et al., 2019).</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="3">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:colspec colnum="3" colname="col3" align="left"/>
     <oasis:thead>
       <oasis:row rowsep="1">
         <oasis:entry colname="col1">No.</oasis:entry>
         <oasis:entry colname="col2">Reaction</oasis:entry>
         <oasis:entry colname="col3">Rate coefficient<inline-formula><mml:math id="M131" display="inline"><mml:msup><mml:mi/><mml:mo>*</mml:mo></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>
         <oasis:entry colname="col1">R1</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M132" display="inline"><mml:mrow><mml:mrow class="chem"><mml:mi mathvariant="normal">Na</mml:mi></mml:mrow><mml:mo>+</mml:mo><mml:mrow class="chem"><mml:msubsup><mml:mi mathvariant="normal">O</mml:mi><mml:mn mathvariant="normal">2</mml:mn><mml:mo>+</mml:mo></mml:msubsup></mml:mrow><mml:mo>→</mml:mo><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>+</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">2.7 <inline-formula><mml:math id="M133" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M134" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">9</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">R2</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M135" display="inline"><mml:mrow><mml:mrow class="chem"><mml:mi mathvariant="normal">Na</mml:mi></mml:mrow><mml:mo>+</mml:mo><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">NO</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>→</mml:mo><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>+</mml:mo><mml:mrow class="chem"><mml:mi mathvariant="normal">NO</mml:mi></mml:mrow></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">8.0 <inline-formula><mml:math id="M136" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M137" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">10</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">R3</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M138" display="inline"><mml:mrow><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>+</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">N</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>(</mml:mo><mml:mo>+</mml:mo><mml:mi>M</mml:mi><mml:mo>=</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">N</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">&amp;</mml:mi><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>)</mml:mo><mml:mo>→</mml:mo><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>⋅</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">N</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">4.8 <inline-formula><mml:math id="M139" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M140" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">30</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M141" display="inline"><mml:mrow class="unit"><mml:mo>(</mml:mo><mml:mi mathvariant="normal">T</mml:mi><mml:mo>/</mml:mo><mml:mn mathvariant="normal">200</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="normal">K</mml:mi><mml:msup><mml:mo>)</mml:mo><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2.2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">R4</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M142" display="inline"><mml:mrow><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>+</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>(</mml:mo><mml:mo>+</mml:mo><mml:mi>M</mml:mi><mml:mo>)</mml:mo><mml:mo>→</mml:mo><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>⋅</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">3.7 <inline-formula><mml:math id="M143" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M144" display="inline"><mml:mrow><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">29</mml:mn></mml:mrow></mml:msup><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mrow class="unit"><mml:mo>(</mml:mo><mml:mi mathvariant="normal">T</mml:mi><mml:mo>/</mml:mo><mml:mn mathvariant="normal">200</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="normal">K</mml:mi><mml:msup><mml:mo>)</mml:mo><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2.84</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">R5</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M145" display="inline"><mml:mrow><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>⋅</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">N</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>+</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>→</mml:mo><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>⋅</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>+</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">N</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">6.0 <inline-formula><mml:math id="M146" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M147" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">10</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">R6</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M148" display="inline"><mml:mrow><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>⋅</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">N</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>+</mml:mo><mml:mrow class="chem"><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mo>→</mml:mo><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">NaO</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>+</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">N</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">4.0 <inline-formula><mml:math id="M149" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M150" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">10</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">R7</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M151" display="inline"><mml:mrow><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">NaO</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>+</mml:mo><mml:mrow class="chem"><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mo>→</mml:mo><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>+</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">1.0 <inline-formula><mml:math id="M152" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M153" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">11</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">R8</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M154" display="inline"><mml:mrow><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">NaO</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>+</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">N</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>→</mml:mo><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>⋅</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">N</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>+</mml:mo><mml:mrow class="chem"><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">1.0 <inline-formula><mml:math id="M155" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M156" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">12</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">R9</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M157" display="inline"><mml:mrow><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">NaO</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>+</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>→</mml:mo><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>+</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:mrow></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">5.0 <inline-formula><mml:math id="M158" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M159" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">12</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">R10</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M160" display="inline"><mml:mrow><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">NaO</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>+</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>→</mml:mo><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>⋅</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>+</mml:mo><mml:mrow class="chem"><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">6.0 <inline-formula><mml:math id="M161" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M162" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">10</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>
         <oasis:entry colname="col1">R11</oasis:entry>
         <oasis:entry colname="col2"><inline-formula><mml:math id="M163" display="inline"><mml:mrow><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>⋅</mml:mo><mml:mrow class="chem"><mml:mi mathvariant="normal">X</mml:mi></mml:mrow><mml:mo>(</mml:mo><mml:mrow class="chem"><mml:mi mathvariant="normal">X</mml:mi></mml:mrow><mml:mo>=</mml:mo><mml:mrow class="chem"><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mo>,</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">N</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>,</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>)</mml:mo><mml:mo>+</mml:mo><mml:msup><mml:mi>e</mml:mi><mml:mo>-</mml:mo></mml:msup><mml:mo>→</mml:mo><mml:mrow class="chem"><mml:mi mathvariant="normal">Na</mml:mi></mml:mrow><mml:mo>+</mml:mo><mml:mrow class="chem"><mml:mi mathvariant="normal">X</mml:mi></mml:mrow></mml:mrow></mml:math></inline-formula></oasis:entry>
         <oasis:entry colname="col3">1.0 <inline-formula><mml:math id="M164" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M165" display="inline"><mml:mrow><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">6</mml:mn></mml:mrow></mml:msup><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mrow class="unit"><mml:mo>(</mml:mo><mml:mn mathvariant="normal">200</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="normal">K</mml:mi><mml:mo>/</mml:mo><mml:mi mathvariant="normal">T</mml:mi><mml:msup><mml:mo>)</mml:mo><mml:mn mathvariant="normal">0.5</mml:mn></mml:msup></mml:mrow></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table><table-wrap-foot><p id="d1e1762"><inline-formula><mml:math id="M128" display="inline"><mml:msup><mml:mi/><mml:mo>*</mml:mo></mml:msup></mml:math></inline-formula> Units: bimolecular reactions, <inline-formula><mml:math id="M129" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">cm</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msup><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">molecule</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">s</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>; termolecular reactions, <inline-formula><mml:math id="M130" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">cm</mml:mi><mml:mn mathvariant="normal">6</mml:mn></mml:msup><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">molecule</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">s</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>.</p></table-wrap-foot></table-wrap>

      <?xmltex \floatpos{p}?><fig id="Ch1.F6"><?xmltex \currentcnt{6}?><?xmltex \def\figurename{Figure}?><label>Figure 6</label><caption><p id="d1e2725">WACCM-Na model simulation results, with the <inline-formula><mml:math id="M166" display="inline"><mml:mi>x</mml:mi></mml:math></inline-formula> axis in logarithmic coordinates. <bold>(a)</bold> Constituents of the species used for calculating <inline-formula><mml:math id="M167" display="inline"><mml:mi>k</mml:mi></mml:math></inline-formula> (<inline-formula><mml:math id="M168" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M169" display="inline"><mml:mo>→</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M170" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Na</mml:mi></mml:mrow></mml:math></inline-formula>). The number densities of <inline-formula><mml:math id="M171" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M172" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M173" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">O</mml:mi></mml:mrow></mml:math></inline-formula>, the total atmosphere density <inline-formula><mml:math id="M174" display="inline"><mml:mi>M</mml:mi></mml:math></inline-formula>, and <inline-formula><mml:math id="M175" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">N</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M176" display="inline"><mml:mo>≈</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M177" display="inline"><mml:mrow><mml:mo>[</mml:mo><mml:mi>M</mml:mi><mml:mo>]</mml:mo><mml:mo>-</mml:mo><mml:mo>[</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>]</mml:mo><mml:mo>-</mml:mo><mml:mo>[</mml:mo><mml:mrow class="chem"><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mo>]</mml:mo></mml:mrow></mml:math></inline-formula> are derived from Yuan et al. (2019). The number density of electrons is equal to <inline-formula><mml:math id="M178" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M179" display="inline"><mml:mo>≈</mml:mo></mml:math></inline-formula> 124 <inline-formula><mml:math id="M180" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M181" display="inline"><mml:mrow><mml:msup><mml:mi/><mml:mn mathvariant="normal">4</mml:mn></mml:msup><mml:mi mathvariant="italic">fo</mml:mi><mml:msup><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M182" display="inline"><mml:mrow class="unit"><mml:mo>(</mml:mo><mml:msup><mml:mi mathvariant="normal">cm</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>. <bold>(b)</bold> The calculated first-order rate coefficient <inline-formula><mml:math id="M183" display="inline"><mml:mi>k</mml:mi></mml:math></inline-formula> (<inline-formula><mml:math id="M184" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M185" display="inline"><mml:mo>→</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M186" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Na</mml:mi></mml:mrow></mml:math></inline-formula>), indicating much more efficient recombination below about 100 <inline-formula><mml:math id="M187" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>.</p></caption>
          <?xmltex \igopts{width=184.942913pt}?><graphic xlink:href="https://acp.copernicus.org/articles/21/11927/2021/acp-21-11927-2021-f06.png"/>

        </fig>

</sec>
</sec>
<sec id="Ch1.S3">
  <label>3</label><title>Discussions</title>
      <?pagebreak page11932?><p id="d1e2986">Normally, the midlatitude <inline-formula><mml:math id="M188" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> layers would be brought down gradually by tidal fluctuations (Mathews, 1998). The <inline-formula><mml:math id="M189" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> theory predicts
that when a series of <inline-formula><mml:math id="M190" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> layers descend below 100 <inline-formula><mml:math id="M191" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, metal ions will be depleted through many chemical reactions involving ions and
electrons (Cox and Plane, 1998). The main chemical reactions and corresponding rate coefficients for the sodium species under mesopause conditions are summarized in Table 1 (Cox and Plane, 1998; Jiao et al., 2017; Plane et al., 2015; Plane, 2004; Yuan et al., 2019). The application of reaction
branching probabilities to Reactions (R3) to (R11) yields the following first-order rate coefficients for the neutralization rates of <inline-formula><mml:math id="M192" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> ions
(Plane, 2004):
          <disp-formula id="Ch1.E1" content-type="numbered"><label>1</label><mml:math id="M193" display="block"><mml:mrow><?xmltex \hack{\hbox\bgroup\fontsize{7.5}{7.5}\selectfont$\displaystyle}?><mml:mtable rowspacing="0.2ex" class="split" displaystyle="true" columnalign="right left"><mml:mtr><mml:mtd/><mml:mtd><mml:mrow><mml:mi>k</mml:mi><mml:mo>(</mml:mo><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>→</mml:mo><mml:mrow class="chem"><mml:mi mathvariant="normal">Na</mml:mi></mml:mrow><mml:mo>)</mml:mo><mml:mo>=</mml:mo><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msub><mml:mo>[</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">N</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>]</mml:mo><mml:mo>[</mml:mo><mml:mi>M</mml:mi><mml:mo>]</mml:mo><mml:mo>⋅</mml:mo><mml:mtext>Pr</mml:mtext><mml:mo>(</mml:mo><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>⋅</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">N</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>→</mml:mo><mml:mrow class="chem"><mml:mi mathvariant="normal">Na</mml:mi></mml:mrow><mml:mo>)</mml:mo><mml:mo>+</mml:mo><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:msub><mml:mo>[</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>]</mml:mo><mml:mo>[</mml:mo><mml:mi>M</mml:mi><mml:mo>]</mml:mo></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd/><mml:mtd><mml:mrow><mml:mo>=</mml:mo><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msub><mml:mo>[</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">N</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>]</mml:mo><mml:mo>[</mml:mo><mml:mi>M</mml:mi><mml:mo>]</mml:mo><mml:mfenced open="(" close=")"><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">11</mml:mn></mml:msub><mml:mo>[</mml:mo><mml:msup><mml:mi>e</mml:mi><mml:mo>-</mml:mo></mml:msup><mml:mo>]</mml:mo><mml:mo>+</mml:mo><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">5</mml:mn></mml:msub><mml:mo>[</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>]</mml:mo></mml:mrow><mml:mtable class="array" columnalign="center"><mml:mtr><mml:mtd><mml:mrow><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">11</mml:mn></mml:msub><mml:mo>[</mml:mo><mml:msup><mml:mi>e</mml:mi><mml:mo>-</mml:mo></mml:msup><mml:mo>]</mml:mo><mml:mo>+</mml:mo><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">5</mml:mn></mml:msub><mml:mo>[</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>]</mml:mo></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd><mml:mrow><mml:mo>+</mml:mo><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">6</mml:mn></mml:msub><mml:mo>[</mml:mo><mml:mrow class="chem"><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mo>]</mml:mo><mml:mo>⋅</mml:mo><mml:mtext>Pr</mml:mtext><mml:mo>(</mml:mo><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">NaO</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>→</mml:mo><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow><mml:mo>)</mml:mo></mml:mrow></mml:mtd></mml:mtr></mml:mtable></mml:mfrac></mml:mstyle></mml:mfenced><mml:mo>+</mml:mo><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:msub><mml:mo>[</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>]</mml:mo><mml:mo>[</mml:mo><mml:mi>M</mml:mi><mml:mo>]</mml:mo></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd/><mml:mtd><mml:mrow><mml:mo>=</mml:mo><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">3</mml:mn></mml:msub><mml:mo>[</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">N</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>]</mml:mo><mml:mo>[</mml:mo><mml:mi>M</mml:mi><mml:mo>]</mml:mo><mml:mfenced close=")" open="("><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">11</mml:mn></mml:msub><mml:mo>[</mml:mo><mml:msup><mml:mi>e</mml:mi><mml:mo>-</mml:mo></mml:msup><mml:mo>]</mml:mo><mml:mo>+</mml:mo><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">5</mml:mn></mml:msub><mml:mo>[</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>]</mml:mo></mml:mrow><mml:mtable class="array" columnalign="center"><mml:mtr><mml:mtd><mml:mrow><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">11</mml:mn></mml:msub><mml:mo>[</mml:mo><mml:msup><mml:mi>e</mml:mi><mml:mo>-</mml:mo></mml:msup><mml:mo>]</mml:mo><mml:mo>+</mml:mo><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">5</mml:mn></mml:msub><mml:mo>[</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>]</mml:mo></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd><mml:mrow><mml:mo>+</mml:mo><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">6</mml:mn></mml:msub><mml:mo>[</mml:mo><mml:mrow class="chem"><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mo>]</mml:mo><mml:mfenced close=")" open="("><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mrow><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">7</mml:mn></mml:msub><mml:mo>[</mml:mo><mml:mrow class="chem"><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mo>]</mml:mo><mml:mo>+</mml:mo><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">9</mml:mn></mml:msub><mml:mo>[</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>]</mml:mo></mml:mrow><mml:mrow><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">6</mml:mn></mml:msub><mml:mo>[</mml:mo><mml:mrow class="chem"><mml:mi mathvariant="normal">O</mml:mi></mml:mrow><mml:mo>]</mml:mo><mml:mo>+</mml:mo><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">8</mml:mn></mml:msub><mml:mo>[</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">N</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>]</mml:mo><mml:mo>+</mml:mo><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">9</mml:mn></mml:msub><mml:mo>[</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>]</mml:mo><mml:mo>+</mml:mo><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">10</mml:mn></mml:msub><mml:mo>[</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>]</mml:mo><mml:mo>+</mml:mo><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">11</mml:mn></mml:msub><mml:mo>[</mml:mo><mml:msup><mml:mi>e</mml:mi><mml:mo>-</mml:mo></mml:msup><mml:mo>]</mml:mo></mml:mrow></mml:mfrac></mml:mstyle></mml:mfenced></mml:mrow></mml:mtd></mml:mtr></mml:mtable></mml:mfrac></mml:mstyle></mml:mfenced></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd/><mml:mtd><mml:mrow><mml:mspace linebreak="nobreak" width="1em"/><mml:mo>+</mml:mo><mml:msub><mml:mi>k</mml:mi><mml:mn mathvariant="normal">4</mml:mn></mml:msub><mml:mo>[</mml:mo><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mo>]</mml:mo><mml:mo>[</mml:mo><mml:mi>M</mml:mi><mml:mo>]</mml:mo><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mtr></mml:mtable><?xmltex \hack{$\egroup}?></mml:mrow></mml:math></disp-formula>
        where Pr denotes the branching probability. The first-order conversion rate of <inline-formula><mml:math id="M194" display="inline"><mml:mi>k</mml:mi></mml:math></inline-formula> (<inline-formula><mml:math id="M195" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M196" display="inline"><mml:mo>→</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M197" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Na</mml:mi></mml:mrow></mml:math></inline-formula>) can be computed as a
function of height using typical values for <inline-formula><mml:math id="M198" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">N</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M199" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">O</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, O, and <inline-formula><mml:math id="M200" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">CO</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> from Whole Atmosphere Community
Climate Model with Na chemistry (WACCM-Na) (Yuan et al., 2019). The results are
given in Fig. 6. The simulation results show that an inflection point of <inline-formula><mml:math id="M201" display="inline"><mml:mi>k</mml:mi></mml:math></inline-formula> (<inline-formula><mml:math id="M202" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M203" display="inline"><mml:mo>→</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M204" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Na</mml:mi></mml:mrow></mml:math></inline-formula>) comes out at around 100 <inline-formula><mml:math id="M205" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, and
below that altitude, the sodium ions would recombine with electrons efficiently through cycling chemical reactions under a large <inline-formula><mml:math id="M206" display="inline"><mml:mi>k</mml:mi></mml:math></inline-formula> value. Then the
production rate of Na could be obtained from <inline-formula><mml:math id="M207" display="inline"><mml:mrow><mml:mi mathvariant="normal">d</mml:mi><mml:mo>[</mml:mo><mml:mrow class="chem"><mml:mi mathvariant="normal">Na</mml:mi></mml:mrow><mml:mo>]</mml:mo><mml:mo>/</mml:mo><mml:mi mathvariant="normal">d</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M208" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M209" display="inline"><mml:mi>k</mml:mi></mml:math></inline-formula> (<inline-formula><mml:math id="M210" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M211" display="inline"><mml:mo>→</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M212" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Na</mml:mi></mml:mrow></mml:math></inline-formula>)[<inline-formula><mml:math id="M213" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula>] (Plane,
2004). The number density of electrons <inline-formula><mml:math id="M214" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> could be retrieved through <inline-formula><mml:math id="M215" display="inline"><mml:mrow><mml:mi mathvariant="italic">fo</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow><mml:mo>=</mml:mo><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ω</mml:mi><mml:mtext>pe</mml:mtext></mml:msub></mml:mrow><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:mi mathvariant="italic">π</mml:mi></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>=</mml:mo><mml:msup><mml:mfenced open="(" close=")"><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub><mml:msup><mml:mi>e</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow><mml:mrow><mml:mn mathvariant="normal">4</mml:mn><mml:msup><mml:mi mathvariant="italic">π</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:msub><mml:mi>m</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub><mml:msub><mml:mi mathvariant="italic">ε</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:mfrac></mml:mstyle></mml:mfenced><mml:mfrac><mml:mn mathvariant="normal">1</mml:mn><mml:mn mathvariant="normal">2</mml:mn></mml:mfrac></mml:msup><mml:mo>≈</mml:mo><mml:mn mathvariant="normal">9</mml:mn><mml:msqrt><mml:mrow><mml:msup><mml:mn mathvariant="normal">10</mml:mn><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">6</mml:mn></mml:mrow></mml:msup><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:msqrt></mml:mrow></mml:math></inline-formula>, with
<inline-formula><mml:math id="M216" display="inline"><mml:mrow><mml:mi mathvariant="italic">fo</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:mrow></mml:math></inline-formula> in MHz and <inline-formula><mml:math id="M217" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> in cubic centimeters (Bittencourt, 2004). The <inline-formula><mml:math id="M218" display="inline"><mml:mrow><mml:mi mathvariant="italic">fo</mml:mi><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:mrow></mml:math></inline-formula> observed at 14:45 UT
is equal to 5.75 <inline-formula><mml:math id="M219" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">MHz</mml:mi></mml:mrow></mml:math></inline-formula>, indicating <inline-formula><mml:math id="M220" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub><mml:mo>≈</mml:mo><mml:mn mathvariant="normal">1.24</mml:mn><mml:mo>×</mml:mo><mml:msup><mml:mn mathvariant="normal">10</mml:mn><mml:mn mathvariant="normal">4</mml:mn></mml:msup><mml:mi mathvariant="italic">fo</mml:mi><mml:msup><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M221" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> 4.1 <inline-formula><mml:math id="M222" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M223" display="inline"><mml:mrow><mml:msup><mml:mi/><mml:mn mathvariant="normal">5</mml:mn></mml:msup><mml:mo>(</mml:mo><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">cm</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow><mml:mo>)</mml:mo></mml:mrow></mml:math></inline-formula>. If the positive ions are mostly composed of metal ions, with an observed ratio of [<inline-formula><mml:math id="M224" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula>] of 7.41 <inline-formula><mml:math id="M225" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M226" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>
(Kopp, 1997), the estimated [<inline-formula><mml:math id="M227" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula>] equates to 3.03 <inline-formula><mml:math id="M228" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M229" display="inline"><mml:msup><mml:mi/><mml:mn mathvariant="normal">4</mml:mn></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M230" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">cm</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>. The approximate value of <inline-formula><mml:math id="M231" display="inline"><mml:mi>k</mml:mi></mml:math></inline-formula> (<inline-formula><mml:math id="M232" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M233" display="inline"><mml:mo>→</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M234" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Na</mml:mi></mml:mrow></mml:math></inline-formula>) below 100 <inline-formula><mml:math id="M235" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> is equal to <inline-formula><mml:math id="M236" display="inline"><mml:mrow><mml:msup><mml:mn mathvariant="normal">10</mml:mn><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">4</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M237" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">s</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>. Then the production rate of Na
<inline-formula><mml:math id="M238" display="inline"><mml:mrow><mml:mi mathvariant="normal">d</mml:mi><mml:mo>[</mml:mo><mml:mrow class="chem"><mml:mi mathvariant="normal">Na</mml:mi></mml:mrow><mml:mo>]</mml:mo><mml:mo>/</mml:mo><mml:mi mathvariant="normal">d</mml:mi><mml:mi>t</mml:mi></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M239" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M240" display="inline"><mml:mi>k</mml:mi></mml:math></inline-formula> (<inline-formula><mml:math id="M241" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M242" display="inline"><mml:mo>→</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M243" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Na</mml:mi></mml:mrow></mml:math></inline-formula>)[<inline-formula><mml:math id="M244" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula>] is equal to 3.03 <inline-formula><mml:math id="M245" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">cm</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">s</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>, in accordance with
the required source strength of sodium atoms of 3 <inline-formula><mml:math id="M246" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">sodium</mml:mi><mml:mspace width="0.33em" linebreak="nobreak"/><mml:mi mathvariant="normal">atoms</mml:mi><mml:mspace linebreak="nobreak" width="0.33em"/><mml:msup><mml:mi mathvariant="normal">cm</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">3</mml:mn></mml:mrow></mml:msup><mml:mspace width="0.125em" linebreak="nobreak"/><mml:msup><mml:mi mathvariant="normal">s</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> for the formation of <inline-formula><mml:math id="M247" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> (Cox et al., 1993).</p>
      <?pagebreak page11933?><p id="d1e4253">Overall, this <inline-formula><mml:math id="M248" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> mechanism is most widely accepted. Figure 2b shows <inline-formula><mml:math id="M249" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> descending near 100 <inline-formula><mml:math id="M250" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula> at about 13:20 UT. Then the
<inline-formula><mml:math id="M251" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is depleted, and a moderate enhancement of Na occurs from 13:30 to 14:00 UT (shown in Figs. 1a and 3a). This increase in sodium density
exhibits no obvious peak, which could probably be in accordance with a normally descending <inline-formula><mml:math id="M252" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> governed by tides. In comparison, the peak profile
of the <inline-formula><mml:math id="M253" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> shows intense enhancement and a sharp peak, indicating a distinct mechanism.</p>
      <p id="d1e4320">On the other hand, a link between the reverse electric field and <inline-formula><mml:math id="M254" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> variations could be established through the acceleration of
electrons. In classical electromagnetism, positive particles will move along the direction of the electric field, and negative particles do the opposite
(Griffiths, 1999). Since metal ions are much heavier than electrons, the ions would drag electrons to move/drift together; a process known as the
bipolar diffusion (Griffiths, 1999). So during the initial phase under quasi-equilibrium conditions, the ions and electrons would co-move downward
together along a southward electric field. In a partially ionized plasma, the characteristic frequencies for ions and electrons are associated with
the collisions of the plasma particles with stationary neutrals (e.g., the electron–neutral collision frequency <inline-formula><mml:math id="M255" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ν</mml:mi><mml:mtext>en</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> and the
ion–neutral collision frequency <inline-formula><mml:math id="M256" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ν</mml:mi><mml:mtext>in</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula>). The collision frequency <inline-formula><mml:math id="M257" display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ν</mml:mi><mml:mtext>sn</mml:mtext></mml:msub></mml:mrow></mml:math></inline-formula> for scattering of the plasma species <inline-formula><mml:math id="M258" display="inline"><mml:mi>s</mml:mi></mml:math></inline-formula> by the
neutrals is (Shukla and Mamun, 2002)
          <disp-formula id="Ch1.Ex1"><mml:math id="M259" display="block"><mml:mrow><mml:msub><mml:mi mathvariant="italic">ν</mml:mi><mml:mtext>sn</mml:mtext></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">n</mml:mi></mml:msub><mml:msubsup><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">s</mml:mi><mml:mi>n</mml:mi></mml:msubsup><mml:msub><mml:mi>V</mml:mi><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi>s</mml:mi></mml:msub></mml:mrow></mml:msub><mml:mo>,</mml:mo></mml:mrow></mml:math></disp-formula>
        where <inline-formula><mml:math id="M260" display="inline"><mml:mrow><mml:msub><mml:mi>n</mml:mi><mml:mi mathvariant="normal">n</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is the neutral number density, <inline-formula><mml:math id="M261" display="inline"><mml:mrow><mml:msubsup><mml:mi mathvariant="italic">σ</mml:mi><mml:mi mathvariant="normal">s</mml:mi><mml:mi>n</mml:mi></mml:msubsup></mml:mrow></mml:math></inline-formula> is the scattering cross section (which is typically of the order of
5 <inline-formula><mml:math id="M262" display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 10<inline-formula><mml:math id="M263" display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">15</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> <inline-formula><mml:math id="M264" display="inline"><mml:mrow class="unit"><mml:msup><mml:mi mathvariant="normal">cm</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula> and depends weakly on the temperature <inline-formula><mml:math id="M265" display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi>s</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) and <inline-formula><mml:math id="M266" display="inline"><mml:mrow><mml:msub><mml:mi>V</mml:mi><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi>s</mml:mi></mml:msub></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M267" display="inline"><mml:mo>=</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M268" display="inline"><mml:mrow><mml:mo>(</mml:mo><mml:msub><mml:mi>k</mml:mi><mml:mi mathvariant="normal">B</mml:mi></mml:msub><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:mo>/</mml:mo><mml:msub><mml:mi>m</mml:mi><mml:mi mathvariant="normal">s</mml:mi></mml:msub><mml:msup><mml:mo>)</mml:mo><mml:mrow><mml:mn mathvariant="normal">1</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula> is the thermal speed
of the species <inline-formula><mml:math id="M269" display="inline"><mml:mi>s</mml:mi></mml:math></inline-formula>.</p>
      <p id="d1e4541">Then under a nonequilibrium phase (e.g., at the point of the electric field overturning), each plasma species has a different relaxation time <inline-formula><mml:math id="M270" display="inline"><mml:mrow><mml:mi mathvariant="italic">τ</mml:mi><mml:mo>=</mml:mo><mml:mstyle displaystyle="false"><mml:mfrac style="text"><mml:mn mathvariant="normal">1</mml:mn><mml:mi mathvariant="italic">ν</mml:mi></mml:mfrac></mml:mstyle></mml:mrow></mml:math></inline-formula> (the time needed for reestablishing equilibrium again through collisions). The relaxation<?pagebreak page11934?> time for ions and electrons would be quite
different in a partially ionized plasma with the electrons responding much faster than the heavier sodium ions do (since <inline-formula><mml:math id="M271" display="inline"><mml:mrow><mml:msub><mml:mi>m</mml:mi><mml:mi mathvariant="normal">i</mml:mi></mml:msub><mml:mo>≫</mml:mo><mml:msub><mml:mi>m</mml:mi><mml:mi mathvariant="normal">e</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>). This discrepancy would cause a charge separation temporarily. The single electrons move opposite along the electric field, which means in the upward electric field they would be rapidly accelerated downward, while the ions could be regarded as essentially remaining
unchanged. The electrons would reverse rapidly before the ions can respond similarly to the velocity overshoot effect for electrons. During the
relaxation phase, the recombination between electrons and ions would probably be triggered through collisions because the relative impact velocity
increases and the long-range attraction between the ion and electron becomes less effective.</p>
      <p id="d1e4579">Based on the above results, a possible mechanism for <inline-formula><mml:math id="M272" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> could be suggested by the following four steps: (1) strong lightning strokes
produce an upward atmospheric electric field toward the ionosphere; (2) the reverse of the electric field would cause a temporary charge separation,
leading to a trigger of recombination between electrons and ions; (3) when the <inline-formula><mml:math id="M273" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> descends below about 100 <inline-formula><mml:math id="M274" display="inline"><mml:mrow class="unit"><mml:mi mathvariant="normal">km</mml:mi></mml:mrow></mml:math></inline-formula>, the sodium ions would
recombine with electrons much more efficiently through cycling chemical reactions under a large <inline-formula><mml:math id="M275" display="inline"><mml:mi>k</mml:mi></mml:math></inline-formula> (<inline-formula><mml:math id="M276" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M277" display="inline"><mml:mo>→</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M278" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Na</mml:mi></mml:mrow></mml:math></inline-formula>) value; (4) the
<inline-formula><mml:math id="M279" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> layers generate the formation of <inline-formula><mml:math id="M280" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. Thus, we propose that there would probably be a connection between the lightning strokes,
the overturning of the electric field, ionospheric disturbances, and also the <inline-formula><mml:math id="M281" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. A link between the lower and upper atmospheres could be
established by carefully studying and examining these phenomena. However, we caution that the key processes for our proposed step (2) still remain quite uncertain. A more in-depth modeling study concerning both plasma and neutral molecules is needed in the future.</p>
</sec>
<sec id="Ch1.S4" sec-type="conclusions">
  <label>4</label><title>Conclusions</title>
      <p id="d1e4687">In this research, we study the conjunction between the lower and upper atmospheres, through the phenomena and processes of lightning strokes,
the overturning of the atmospheric electric field, ionospheric disturbance, plasma drift velocity reversal, and the formation and dissipation of sporadic
sodium layer. The main findings of our results are summarized as follows:
<?xmltex \hack{\newpage}?>
<list list-type="order"><list-item>
      <p id="d1e4694">The <inline-formula><mml:math id="M282" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> event discussed in the present case study shows a close relationship with <inline-formula><mml:math id="M283" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> activities rather than conforming to the prescriptions from the competing high-temperature theory.</p></list-item><list-item>
      <p id="d1e4720">The atmospheric electric field exhibits an overturning, opposite to the fair-weather downward field in the global circuit, coincident with
the depletion of <inline-formula><mml:math id="M284" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and the consequent production of <inline-formula><mml:math id="M285" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>.</p></list-item><list-item>
      <p id="d1e4746">A typical thunderstorm, with a positive charge located above a negative charge layer, is shown to produce an upward electric field toward the
ionosphere. Two regions with heavy lightning activities nearby are found during the overturning of the atmospheric electric field.</p></list-item><list-item>
      <p id="d1e4750">Observations by the ionosonde exhibit extraordinary echoes during the lightning period, and the temporal property of the echoes behaved
synchronously with lightning activities.</p></list-item><list-item>
      <p id="d1e4754">WACCM-Na model simulation results show that the calculated first-order rate coefficient <inline-formula><mml:math id="M286" display="inline"><mml:mi>k</mml:mi></mml:math></inline-formula> (<inline-formula><mml:math id="M287" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M288" display="inline"><mml:mo>→</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M289" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Na</mml:mi></mml:mrow></mml:math></inline-formula>) could probably
explain the efficient recombination of <inline-formula><mml:math id="M290" display="inline"><mml:mrow class="chem"><mml:msup><mml:mi mathvariant="normal">Na</mml:mi><mml:mo>+</mml:mo></mml:msup></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M291" display="inline"><mml:mo>→</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M292" display="inline"><mml:mrow class="chem"><mml:mi mathvariant="normal">Na</mml:mi></mml:mrow></mml:math></inline-formula> in this <inline-formula><mml:math id="M293" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> case study.</p></list-item></list></p>
      <p id="d1e4828">Our results support a physical connection between the lightning strokes, the overturning of the electric field, ionospheric disturbances, and possibly the
<inline-formula><mml:math id="M294" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> phenomenon as well. A link between the lower and upper atmospheres could be established as follows by the monitoring of <inline-formula><mml:math id="M295" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and related phenomena: lightning strokes <inline-formula><mml:math id="M296" display="inline"><mml:mo>→</mml:mo></mml:math></inline-formula>overturning of the electric field <inline-formula><mml:math id="M297" display="inline"><mml:mo>→</mml:mo></mml:math></inline-formula><inline-formula><mml:math id="M298" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">E</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> generating <inline-formula><mml:math id="M299" display="inline"><mml:mrow class="chem"><mml:msub><mml:mi mathvariant="normal">Na</mml:mi><mml:mi mathvariant="normal">S</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>.</p><?xmltex \hack{\clearpage}?>
</sec>

      
      </body>
    <back><app-group>

<?pagebreak page11935?><app id="App1.Ch1.S1">
  <?xmltex \currentcnt{A}?><label>Appendix A</label><title>Calculations for the induced upward electric field in the global electric circuit</title>
      <p id="d1e4901">Suppose there is positive charge <inline-formula><mml:math id="M300" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> at the top of a thunderstorm, with a distance of <inline-formula><mml:math id="M301" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> above the ground and a negative charge <inline-formula><mml:math id="M302" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> at
the bottom with a distance of <inline-formula><mml:math id="M303" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>. Since the ground surface could be regarded as an infinite conducting plane, it would generate an induced
charge. The boundary condition here is

              <disp-formula specific-use="align"><mml:math id="M304" display="block"><mml:mtable displaystyle="true"><mml:mtr><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mi>U</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0</mml:mn><mml:mspace linebreak="nobreak" width="1em"/></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mstyle displaystyle="true" class="stylechange"/><mml:mtext>at</mml:mtext><mml:mspace width="1em" linebreak="nobreak"/><mml:mi>z</mml:mi><mml:mo>=</mml:mo><mml:mn mathvariant="normal">0</mml:mn><mml:mo>,</mml:mo></mml:mrow></mml:mtd></mml:mtr><mml:mtr><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mi>U</mml:mi><mml:mo>→</mml:mo><mml:mn mathvariant="normal">0</mml:mn><mml:mspace width="1em" linebreak="nobreak"/></mml:mrow></mml:mtd><mml:mtd><mml:mrow><mml:mstyle class="stylechange" displaystyle="true"/><mml:mtext>at infinity</mml:mtext><mml:mo>.</mml:mo></mml:mrow></mml:mtd></mml:mtr></mml:mtable></mml:math></disp-formula></p>
      <p id="d1e4996">Under the uniqueness theorem, we can remove the ground surface if we put the postulated image charges of <inline-formula><mml:math id="M305" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:msub><mml:mi>Q</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M306" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> to the corresponding
mirror points. Then for an arbitrary point <inline-formula><mml:math id="M307" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula> near the boundary, the vertical electric field is equal to the following expression according to Coulomb's law (Griffiths, 1999):
          <disp-formula id="App1.Ch1.S1.Ex3"><mml:math id="M308" display="block"><mml:mrow><mml:msub><mml:mi>E</mml:mi><mml:mo>⊥</mml:mo></mml:msub><mml:mo>=</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mn mathvariant="normal">1</mml:mn><mml:mrow><mml:mn mathvariant="normal">4</mml:mn><mml:mi mathvariant="italic">π</mml:mi><mml:msub><mml:mi mathvariant="italic">ε</mml:mi><mml:mn mathvariant="normal">0</mml:mn></mml:msub></mml:mrow></mml:mfrac></mml:mstyle><mml:mfenced open="[" close="]"><mml:mrow><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:msub><mml:mi>Q</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub><mml:msub><mml:mi>h</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow><mml:mrow><mml:msup><mml:mfenced open="(" close=")"><mml:mrow><mml:msubsup><mml:mi>d</mml:mi><mml:mn mathvariant="normal">1</mml:mn><mml:mn mathvariant="normal">2</mml:mn></mml:msubsup><mml:mo>+</mml:mo><mml:msubsup><mml:mi>h</mml:mi><mml:mn mathvariant="normal">1</mml:mn><mml:mn mathvariant="normal">2</mml:mn></mml:msubsup></mml:mrow></mml:mfenced><mml:mrow><mml:mn mathvariant="normal">3</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:mfrac></mml:mstyle><mml:mo>-</mml:mo><mml:mstyle displaystyle="true"><mml:mfrac style="display"><mml:mrow><mml:mn mathvariant="normal">2</mml:mn><mml:msub><mml:mi>Q</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:msub><mml:mi>h</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow><mml:mrow><mml:msup><mml:mfenced close=")" open="("><mml:mrow><mml:msubsup><mml:mi>d</mml:mi><mml:mn mathvariant="normal">2</mml:mn><mml:mn mathvariant="normal">2</mml:mn></mml:msubsup><mml:mo>+</mml:mo><mml:msubsup><mml:mi>h</mml:mi><mml:mn mathvariant="normal">2</mml:mn><mml:mn mathvariant="normal">2</mml:mn></mml:msubsup></mml:mrow></mml:mfenced><mml:mrow><mml:mn mathvariant="normal">3</mml:mn><mml:mo>/</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:mfrac></mml:mstyle></mml:mrow></mml:mfenced><mml:mo>.</mml:mo></mml:mrow></mml:math></disp-formula></p>
      <p id="d1e5146">In the simplest case, when <inline-formula><mml:math id="M309" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is equal to <inline-formula><mml:math id="M310" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math id="M311" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub><mml:mo>=</mml:mo><mml:msub><mml:mi>d</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mo>=</mml:mo><mml:mi>d</mml:mi></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math id="M312" display="inline"><mml:mrow><mml:msub><mml:mi>E</mml:mi><mml:mo>⊥</mml:mo></mml:msub></mml:mrow></mml:math></inline-formula> varies with the distance <inline-formula><mml:math id="M313" display="inline"><mml:mi>d</mml:mi></mml:math></inline-formula>. If <inline-formula><mml:math id="M314" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is larger than <inline-formula><mml:math id="M315" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>
(<inline-formula><mml:math id="M316" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M317" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> <inline-formula><mml:math id="M318" display="inline"><mml:mrow><mml:msub><mml:mi>Q</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M319" display="inline"><mml:mo>&gt;</mml:mo></mml:math></inline-formula> 0) and the negative charge <inline-formula><mml:math id="M320" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:msub><mml:mi>Q</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is closer to the observing point <inline-formula><mml:math id="M321" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula> (<inline-formula><mml:math id="M322" display="inline"><mml:mrow><mml:msub><mml:mi>d</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msub><mml:mo>&lt;</mml:mo><mml:msub><mml:mi>d</mml:mi><mml:mn mathvariant="normal">1</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>), <inline-formula><mml:math id="M323" display="inline"><mml:mrow><mml:msub><mml:mi>E</mml:mi><mml:mo>⊥</mml:mo></mml:msub></mml:mrow></mml:math></inline-formula> would acquire
negative values (e.g., with the upward direction). A brief simulation result is shown by Fig. A1d, exhibiting persistent
negative values for <inline-formula><mml:math id="M324" display="inline"><mml:mrow><mml:msub><mml:mi>E</mml:mi><mml:mo>⊥</mml:mo></mml:msub></mml:mrow></mml:math></inline-formula>.</p>

      <?xmltex \floatpos{h!}?><fig id="App1.Ch1.S1.F7"><?xmltex \currentcnt{A1}?><?xmltex \def\figurename{Figure}?><label>Figure A1</label><caption><p id="d1e5334">The diagram illustrates the global electric circuit. <bold>(a)</bold> The atmospheric electric field under fair weather with a downward field returning from the ionosphere. <bold>(b)</bold> The dynamo area, with thunderstorms generating an upward electric field towards the ionosphere. The electric field intensity <inline-formula><mml:math id="M325" display="inline"><mml:mrow><mml:msub><mml:mi>E</mml:mi><mml:mo>⊥</mml:mo></mml:msub></mml:mrow></mml:math></inline-formula> could be deduced through the electric imaging method. <bold>(c)</bold> The deduced vertical electric field intensity at any point <inline-formula><mml:math id="M326" display="inline"><mml:mi>P</mml:mi></mml:math></inline-formula> within the thundercloud. <bold>(d)</bold> The calculated <inline-formula><mml:math id="M327" display="inline"><mml:mrow><mml:msub><mml:mi>E</mml:mi><mml:mo>⊥</mml:mo></mml:msub></mml:mrow></mml:math></inline-formula> based on the electric imaging method.</p></caption>
        <?xmltex \hack{\hsize\textwidth}?>
        <?xmltex \igopts{width=369.885827pt}?><graphic xlink:href="https://acp.copernicus.org/articles/21/11927/2021/acp-21-11927-2021-f07.png"/>

      </fig>

<?xmltex \hack{\clearpage}?>
</app>
  </app-group><notes notes-type="dataavailability"><title>Data availability</title>

      <p id="d1e5393">The data sets of the ionosonde and the fluxgate magnetometer are publicly available from the Chinese Meridian Project database at <uri>http://data.meridianproject.ac.cn/</uri> (Chinese Meridian Project, 2021). Observation data of the atmospheric electric field mill at Wuhan Geomagnetic Station is from the National Space Science Data Center, <ext-link xlink:href="https://doi.org/10.12176/01.05.065" ext-link-type="DOI">10.12176/01.05.065</ext-link> (Wuhan Geomagnetic Station, 2010). The sodium density data of the <inline-formula><mml:math id="M328" display="inline"><mml:mrow><mml:mi>T</mml:mi><mml:mo>/</mml:mo><mml:mi>W</mml:mi></mml:mrow></mml:math></inline-formula> lidar over Hefei is available from the National Space Science Data Center (<ext-link xlink:href="https://doi.org/10.12176/01.05.026" ext-link-type="DOI">10.12176/01.05.026</ext-link>; University of Science and Technology of China, 2011). The lightning location and power data can be downloaded from the World Wide Lightning Location Network (<uri>http://wwlln.net/</uri>, WWLLN, 2021).</p>
  </notes><notes notes-type="authorcontribution"><title>Author contributions</title>

      <p id="d1e5423">SQ conceived this study and wrote this paper. She also prepared Figs. 2–5 in the main text and Fig. A1 in the Appendix. NW performed data analysis. WS was in charge of the organization and polishing the English of the whole paper. GL added some materials about thunderstorms and lightning strokes. MJ prepared Fig. 1 and gave some useful comments on the content. XW wrote the response to reviewers and calculated the model simulation results. XX wrote the response to reviewers and added some materials in the discussion. TL helped with the response to reviewers. XD conceived this study and provided data from the Chinese Meridian Project.</p>
  </notes><notes notes-type="competinginterests"><title>Competing interests</title>

      <p id="d1e5429">The authors declare that they have no conflict of interest.</p>
  </notes><notes notes-type="disclaimer"><title>Disclaimer</title>

      <p id="d1e5435">Publisher's note: Copernicus Publications remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.</p>
  </notes><ack><title>Acknowledgements</title><p id="d1e5441">This work is supported by the National Natural Science Foundation of China (nos. 41974178 and 41831071), the CNSA pre-research Project on Civil Aerospace Technologies (no. D020105), and the National Key R&amp;D Program of China (no. 2017YFC0602202). We acknowledge the constructive reviews by both referees. Thanks to Wuhu Feng from the University of Leeds, Jianfei Wu from the University of Science &amp; Technology of China, and Jing Jiao from National Space Science Center for their help on the model simulation. We thank Han Jin and Jin Wang for calibration of the ionograms. The first author would like to thank Hao Chen and Yandong Liu for their help on debugging programs.</p></ack><notes notes-type="financialsupport"><title>Financial support</title>

      <p id="d1e5446">This research has been supported by the National Natural Science Foundation of China (grant nos. 41974178 and 41831071), the CNSA pre-research Project on Civil Aerospace Technologies (no. D020105), and the National Key R&amp;D Program of China (grant no. 2017YFC0602202).</p>
  </notes><notes notes-type="reviewstatement"><title>Review statement</title>

      <p id="d1e5452">This paper was edited by Gabriele Stiller and reviewed by two anonymous referees.</p>
  </notes><ref-list>
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<abstract-html><p>In this research, we reveal the inter-connection between lightning strokes, reversal of the electric field, ionospheric disturbances, and a sodium
layer (Na<sub>S</sub>), based on the joint observations by a temperature/wind (<i>T</i>∕<i>W</i>, where the slash means <q>and</q>) lidar, an ionosonde, an atmospheric electric mill, a fluxgate
magnetometer, and the World Wide Lightning Location Network (WWLLN). Our results suggest that lightning strokes could trigger or amplify the
formation of an Na<sub>S</sub> layer in a descending sporadic E layer (E<sub>S</sub>), through a mechanism that involves the overturning of the electric
field. A conjunction between the lower and upper atmospheres could be established as follows by these inter-connected phenomena, and the key processes could be suggested to be: lightning strokes&thinsp; → &thinsp;overturning of the electric field&thinsp; → &thinsp;E<sub>S</sub> generating Na<sub>S</sub>.</p></abstract-html>
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