Severe Californian wildfires in November 2018 observed from space: the carbon monoxide perspective

Due to proceeding climate change, some regions such as California face rising weather extremes with dry periods becoming warmer and drier, entailing the risk that wildfires and associated air pollution episodes will continue to increase. November 2018 turned into one of the most severe wildfire episodes on record in California, with two particularly destructive wildfires spreading concurrently through the north and the south of the state. Both fires ignited at the wildland–urban interface, causing many civilian fatalities and forcing the total evacuation of several cities and communities. Here we demonstrate that the inherent carbon monoxide (CO) emissions of the wildfires and subsequent transport can be observed from space by analysing radiance measurements of the TROPOspheric Monitoring Instrument (TROPOMI) onboard the Sentinel-5 Precursor satellite in the shortwave infrared spectral range. From the determined CO distribution we assess the corresponding air quality burden in major Californian cities caused by the fires and discuss the associated uncertainties. As a result of the prevailing wind conditions, the largest CO load during the first days of the fires is found in Sacramento and San Francisco, with city area averages reaching boundary layer concentration anomalies of about 2.5 mgCOm−3. Even the most polluted city scenes likely comply with the national ambient air quality standards (10 mgCOm−3 with 8 h averaging time). This finding based on dense daily recurrent satellite monitoring is consistent with isolated ground-based air quality measurements.

Abstract. Due to proceeding climate change, some regions such as California face rising weather extremes with dry periods becoming warmer and drier, entailing the risk that wildfires and associated air pollution episodes will continue to increase. November 2018 turned into one of the most severe wildfire episodes on record in California, with two particularly destructive wildfires spreading concurrently through the north and the south of the state. Both fires ignited at the wildland-urban interface, causing many civilian fatalities and forcing the total evacuation of several cities and communities.
Here we demonstrate that the inherent carbon monoxide (CO) emissions of the wildfires and subsequent transport can be observed from space by analysing radiance measurements of the TROPOspheric Monitoring Instrument (TROPOMI) onboard the Sentinel-5 Precursor satellite in the shortwave infrared spectral range. From the determined CO distribution we assess the corresponding air quality burden in major Californian cities caused by the fires and discuss the associated uncertainties. As a result of the prevailing wind conditions, the largest CO load during the first days of the fires is found in Sacramento and San Francisco, with city area averages reaching boundary layer concentration anomalies of about 2.5 mg CO m −3 . Even the most polluted city scenes likely comply with the national ambient air quality standards (10 mg CO m −3 with 8 h averaging time). This finding based on dense daily recurrent satellite monitoring is consistent with isolated ground-based air quality measurements.

Introduction
As a consequence of climate change, precipitation and temperature extremes in California during the cool season (October-May) are occurring more frequently with dry periods becoming warmer and drier (Swain et al., 2016), which is associated with an increased fire risk. The increasing number of people living in the wildland-urban interface paired with proceeding climate change, entailing longer-lasting and more intense fire seasons, affect the outlook for the future (Radeloff et al., 2018).
The wildfire season of 2018 was the most destructive on record with respect to burned land area, destroyed buildings, and fatalities (California Department of Forestry and Fire Protection, 2019). After a series of extensive fires in July-August including the Mendocino Complex, the largest wildfire in California since the beginning of recording, another round of large wildfires erupted in November, most prominently the Camp Fire and the Woolsey Fire. The Camp Fire started in the morning of 8 November in Butte County in the north of the state and grew rapidly. It became California's most destructive and deadliest wildfire since records began. The Woolsey Fire ignited on the same day as the Camp Fire in the early afternoon near the boundary between Los Angeles and Ventura counties and burnt all the way to Malibu. Both fires forced the total evacuation of several cities and communities.
Smoke from the fires also reached the major cities of the state, prompting health warnings and the advice to remain indoors or wear face masks in certain areas (Sacramento Metropolitan Air Quality Management District, 2018;Bay Area Air Quality Management District, 2018). The air quality was affected by particulate matter and carbon monoxide (CO), which results from the incomplete combustion of Published by Copernicus Publications on behalf of the European Geosciences Union.

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O. Schneising et al.: Californian wildfires in November 2018: the CO perspective biomass during wildfires (Yurganov et al., 2005). CO is a colourless, odourless, and tasteless gas that is toxic in large concentrations because it combines with hemoglobin to form carboxyhemoglobin, which can no longer effectively transport oxygen. As a consequence, it has the ability to cause severe health problems (Omaye, 2002). CO also plays an important role in tropospheric chemistry, being the leading sink of the hydroxyl radical (OH) and acting as a precursor to tropospheric ozone (The Royal Society, 2008).
The Environmental Protection Agency (EPA) is required to set National Ambient Air Quality Standards (NAAQS) for six pollutants considered harmful to public health and the environment, including carbon monoxide, by the Clean Air Act. The CO standards are fixed at 9 ppm (corresponding to 10 mg m −3 for normal temperature and pressure) with an 8 h averaging time and 35 ppm (40 mg m −3 ) with a 1 h averaging time, neither to be exceeded more than once per year (U.S. Environmental Protection Agency, 2011).
Several spaceborne instruments have been measuring CO on a global scale including the Atmospheric Infrared Sounder (AIRS) (McMillan et al., 2005), the Tropospheric Emission Spectrometer (TES) (Luo et al., 2015), and the Infrared Atmospheric Sounding Interferometer (IASI) , which observe emissions in the thermal infrared (TIR) and are mainly sensitive to mid-to upper-tropospheric abundances. The sensitivity of TIR satellite sounders to nearsurface CO concentrations varies with the thermal contrast conditions (Deeter et al., 2007;Bauduin et al., 2017). The Measurement of Pollution in the Troposphere (MOPITT) instrument  combines observations of spectral features in the TIR and in the shortwave infrared (SWIR) to increase surface-level sensitivity in some scenes (Worden et al., 2010). Nearly equal sensitivity to all altitude levels including the boundary layer can be achieved from radiance measurements of reflected solar radiation in the SWIR part of the spectrum. This was first demonstrated by CO retrievals from the SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY (SCIAMACHY) instrument (Burrows et al., 1995;Bovensmann et al., 1999) onboard ENVISAT (Buchwitz et al., 2004;de Laat et al., 2010) in the 2.3 µm spectral range.

Data and methods
In this study, we derive and analyse atmospheric carbon monoxide from the radiance measurements of the TRO-POspheric Monitoring Instrument (TROPOMI) onboard the Sentinel-5 Precursor (Sentinel-5P) satellite (Veefkind et al., 2012) using the latest version of the Weighting Function Modified DOAS (WFM-DOAS) algorithm (Buchwitz et al., 2006;Schneising et al., 2011) optimised to retrieve vertical columns of carbon monoxide and methane simultaneously (TROPOMI/WFMD v1.2) .
Sentinel-5P was launched in October 2017 into a sunsynchronous orbit with an Equator crossing time of 13:30. TROPOMI is a spaceborne nadir-viewing imaging spectrometer measuring solar radiation reflected by the Earth in a push-broom configuration. It has a swath width of 2600 km on the Earth's surface and covers wavelength bands between the ultraviolet (UV) and the shortwave infrared (SWIR), combining a high spatial resolution with daily global coverage. The horizontal resolution of the TROPOMI nadir measurements, which depends on the orbital position and spectral interval, is typically 7 × 7 km 2 for the SWIR bands used in this study. Due to its wide swath in conjunction with high spatial and temporal resolution, the observations of TROPOMI yield CO amounts and distributions with an unprecedented level of detail on a global scale (Borsdorff et al., 2018a).
As a result of the observation of reflected solar radiation in the SWIR part of the solar spectrum, TROPOMI yields atmospheric carbon monoxide measurements with high sensitivity to all altitude levels including the planetary boundary layer and is thus well-suited to study emissions from fires. In order to convert the retrieved columns into mole fractions, they are divided by the corresponding dry air columns obtained from the European Centre for Medium-Range Weather Forecasts (ECMWF) analysis. Thereby, the ECMWF dry columns are corrected for the actual surface elevation of the individual TROPOMI measurements as determined from the Global Multi-resolution Terrain Elevation Data 2010 (GMTED2010; United States Geological Survey, 2018), inheriting the high spatial resolution of the satellite data. The resulting column-averaged dry air mole fractions are denoted by XCO.
The retrieval error sources can be grouped into systematic and random error components. Systematic errors typically occur when the analysed scenes are not well-characterised by the forward model, particularly in the presence of strong scatterers under challenging conditions concerning measurement geometry and albedo. The random component is dominated by detector noise and pseudo-noise determined by specific atmospheric parameters or instrumental features. Based on a validation with ground-based Fourier transform spectrometer (FTS) measurements of the Total Carbon Column Observing Network (TCCON) (Wunch et al., 2011), the TROPOMI/WFMD XCO data set is characterised by a ran-O. Schneising et al.: Californian wildfires in November 2018: the CO perspective 3319 dom error (precision) of 5.1 ppb and a systematic error (relative accuracy) of 1.9 ppb after quality filtering .
Among others, the standard quality filter typically removes cloudy scenes and was chosen to be rather strict to meet the demanding requirements for the precision and accuracy of simultaneously retrieved XCH 4 globally. For example, qualityfiltered ocean retrievals are mainly limited to sun glint or glitter scenes as a consequence of the otherwise weak signal above water surfaces. However, a local comparison with the cloud product from the Visible Infrared Imaging Radiometer Suite (VIIRS) instrument (Hutchison and Cracknell, 2005) onboard the joint NASA-NOAA Suomi National Polar-orbiting Partnership (Suomi-NPP) satellite for days before fire ignition has indicated that the filter can be somewhat relaxed for the present study to maximise the number of utilisable scenes. The implemented alternative quality screening algorithm is based on simultaneously measured methane and filters scenes in which the retrieved XCH 4 is more than 3 times the random error ≈ 50 ppb smaller than an assumed reference (averaged cloud-free abundances of 5-7 November). The threshold was chosen to distinguish systematic from random deviations. Over weakly reflecting ocean or inland water scenes the filter is augmented by additionally flagging scenes with large estimated CO fit error (> 10 %). The rationale behind the use of simultaneously measured XCH 4 as a quality criterion is the following. To begin with, XCH 4 is far less variable than XCO in the presence of wildfires. Furthermore, both gases typically exhibit similar error characteristics regarding the sign and percentage magnitude of systematic errors . Hence, potential issues of the XCO data, for example due to reduced nearsurface sensitivity in the presence of clouds or smoke, are clearly detected in the corresponding XCH 4 data and filtered out.
To get a visual impression of the smoke distribution originating from the fires, so-called true colour images (red: band I1, green: band M4, blue: band M3) from the VIIRS instrument are used, which show land surface, oceanic, and atmospheric features like the human eye would see them (Hillger et al., 2014). The TROPOMI CO retrievals are also compared to the analysis of the ECMWF Integrated Forecasting System (IFS) provided by the Copernicus Atmosphere Monitoring Service (CAMS) (Inness et al., 2015), which assimilates MOPITT and IASI CO observations and biomass burning emissions from the CAMS Global Fire Assimilation System (GFAS) (Kaiser et al., 2012).
To assess the CO burden in major Californian cities we compute the average total column enhancement E CO (within a 20 km radius around midtown, in units of mass per area) for the first days of the fire relative to 7 November, which is considered background. It is assumed that the additional CO from the fires is located in the well-mixed boundary layer, while the remaining upper part of the contaminated profile closely resembles the background profile, allowing us to dis-entangle the near-surface abundances from the total column measurements. To this end, the total column enhancement is divided by the boundary layer height h bl obtained from the hourly ECMWF ERA5 reanalysis product (Hersbach et al., 2018) to get the boundary layer concentration anomaly ρ bl due to the fires (in units of mass per volume): where v CO is the enhancement (in units of molecules per area) relative to the prefire background. The molar mass of carbon monoxide M CO = 28 g mol −1 and the Avogadro constant N A = 6.022 × 10 23 molec mol −1 are used to convert molecules per area to mass per area; A CO = 0.95±0.05 is the dimensionless near-surface CO averaging kernel characterising the boundary layer sensitivity of the retrieval determined for appropriate conditions (solar zenith angle ∈ [50 • , 60 • ], albedo ∈ [0.1, 0.2]). The boundary layer height determines the available volume for pollution dispersion and is thus a critical parameter for air quality assessment. The ERA5 boundary layer height is defined as the lowest height at which the bulk Richardson number, which interrelates stability with vertical wind shear, reaches the critical value of 0.25 (ECMWF, 2018). The corresponding uncertainty estimates are based on a 10-member 4D-Var ensemble. Furthermore, an additional uncertainty associated with the estimation method of the boundary layer height is introduced, which is derived from a comparison of ERA5 boundary layer heights to lidar measurements (Wang et al., 2019). The areal variation of this anomaly is determined from the standard deviations of the CO columns measuring the inhomogeneity of the boundary layer concentrations within the respective city area.
The error analysis includes uncertainties arising from boundary layer height, the vertical distribution of emissions near the source, and smoke aerosol. Thereby, gridded Integrated Monitoring and Modelling System for Wildland Fires (IS4FIRES) injection heights (Sofiev et al., 2012) (corresponding to the top of the plume) as obtained from the CAMS GFAS and CAMS CO vertical profiles are used to estimate how much of the pyrogenic CO may leave the boundary layer.
3 Results and discussion 3.1 Quality filtered XCO and comparison to CAMS As a result of the Camp and Woolsey fires ignited on 8 November, associated smoke overcast large parts of the state for nearly 2 weeks. This can clearly be seen on the VIIRS true colour images in Fig. 1 for the first days of the fires. Sentinel-5 Precursor and Suomi-NPP fly in loose formation, with Sentinel-5P trailing behind by 3.5 min, ensuring that both satellites observe (almost) the same scene. Thus, the corresponding images can be compared directly. The performance of the quality filter based on simultaneously measured methane is demonstrated in Fig. 2 for an example day before the start of the analysed fires. In line with the error analysis based on synthetic data presented in Schneising et al. (2019), there is typically a considerable underestimation of XCH 4 in the presence of clouds due to shielding of the underlying partial columns. After application of the alternative quality filter, there are no obvious issues with the XCO data. The relaxed quality screening algorithm provides similar results as the standard filter concerning the overall agreement rate with the VIIRS cloud product but actually yields more scenes passing the filter (about 20 % for the analysed example day). Figure 3 shows the daily XCH 4 distribution over California, which is used for quality screening. For each day, XCH 4 resembles the prefire background abundances shown in Fig. 2a with the exception of considerable underestimations here and there mainly due to reduced near-surface sensitivity in the presence of clouds or smoke near the origin of the fires. However, at a sufficient distance from the seat of the fire the XCH 4 abundances are not affected and a quantitative analysis is still possible, even in cases in which efficient scattering in the visible spectral range is indicated by extensive plumes in the VIIRS images. The explanation for this is the particle size distribution of the wildfire smoke. While clouds typically consist of water droplets with an effective radius of the order of 10 µm, smoke is dominated by considerably smaller particles. The mass distribution of smoke plumes shows a prominent peak at about 0.3 µm (Stith et al., 1981) but is nevertheless dominated by a small number of supermicron-sized particles, including some very large particles (Radke et al., 1990). As a consequence of the different size distributions, clouds have a typical Ångström exponent α = 0 and thus no wavelength dependence of the aerosol optical depth, while biomass burning aerosols have a distinct wavelength dependence with typical α ranging between 1 and 2 depending on the fire (Eck et al., 2009). The submicron particles reduce visibility and lead to extended smoke plumes over large distances in the VIIRS true colour reflectances shown in Fig. 1. However, the 2.3 µm spectral range, in which the satellite measurements are taken, is subject to little scattering at these small particles. The satellite retrievals close to the source of the fire are rather affected by the large supermicron-sized particles, which have a short atmospheric lifetime, tend to fall out rapidly (World Health Organization, 2006), and thus become more and more negligible when departing from the seat of the fire. Thus, a reliable XCO retrieval is possible in smoke plumes in the far field of the fire origin for scenes passing the quality filter. Corresponding simulations with a realistic aerosol optical depth and Ångström exponent are included in the error analysis in the next subsection to quantify the impact of scattering at smoke aerosols. Figure 4 shows the XCO distribution over California, which matches the smoke emission and transport patterns detected by VIIRS unambiguously. This substantiates the fact that the observed CO enhancements are actually originating from the wildfires. It can be seen that the abundances over the major cities we want to analyse are typically not filtered out and are thus suitable for a quantitative analysis. However, the quantitative interpretation of scenes right above or too close to the origin of the fire is limited by reduced vertical retrieval sensitivity near the surface, and they are consequently filtered out.
For comparison, Fig. 5 shows the CAMS near-real-time CO analysis on a 0.1 • × 0.1 • grid for the same days shown in the previous figures and the closest available time to the TROPOMI overpass at 13:30 local time. As CAMS is available in time steps of 6 h, the analysis corresponding to 16:00 local time is used for the comparison. Although CO emissions from the fires are obviously included in the CAMS data, the transport patterns seem to be somewhat dif-ferent. While the patterns are broadly consistent for 9 and 10 November, the modelled wind fields close to the fires seem to deviate on 8 and 11 November, which results in a longer continuance of the plume over land, while the VI-IRS images and the TROPOMI data suggest a faster transport westwards to the sea. This can also be seen in Fig. 6, showing departures of the CAMS analysis from the TROPOMI XCO after averaging the satellite data on the CAMS resolution. Apart from the partially different transport patterns, the intensity distribution close to the fire sources is also different, with CAMS abundances being considerably higher for the most part and deviations reaching several hundred parts per billion (ppb). This may be due to overestimated wildfire fluxes, underestimated initial horizontal transport in the vicinity of the fire sources, or a combination of both.

Boundary layer concentration anomalies and associated uncertainties
To assess the CO burden in Californian cities, the boundary layer CO concentration anomaly is computed according to Eq.
(1). The diurnal variation of the ECMWF ERA5 boundary layer heights and their inherent uncertainties are illustrated in Fig. 7. There is a strong diurnal cycle, with low val- Figure 3. Retrieved methane column-averaged mole fractions from TROPOMI for the same days as in Fig. 1. XCH 4 is used to filter out scenes with significant underestimation (dotted scenes), mainly due to reduced near-surface sensitivity in the presence of clouds or smoke due to shielding of the subjacent partial columns. The Central Valley exhibits combined anthropogenic methane emissions from oil fields and agriculture .
ues at night and maximal values around local noon close to the time of the TROPOMI overpass at 13:30. The boundary layer concentration uncertainty arising from boundary layer height σ (h bl ) is determined from the maximal ERA5 ensemble uncertainty between 13:00 and 14:00 local time and the variation within this hour in each case. Typical values of σ (h bl ) range between 10 % and 25 %. The ERA5 boundary layer height around the satellite overpass time is about 300 m smaller than the boundary layer height derived from aerosol and turbulence detection lidar measurements by different retrieval methods (Wang et al., 2019). This uncertainty associated with the estimation method is additionally taken into account in the error budget by an extra term σ m (h bl ) quantifying the percentage impact on the smaller end of ρ bl . The potentially largest source of uncertainty in the calculation of the boundary layer CO burden is plume dynamics and the question of whether all CO remains in the boundary layer or if a certain proportion reaches the free tropo-sphere. The vertical distribution of emissions near the source is driven by the fire radiative power and the local ambient atmospheric conditions such as stability and humidity. Three types of wildfire plumes are distinguished by the amount of condensed water vapour during plume formation (Fromm et al., 2010): (1) dry smoke plumes, which contain water vapour and usually stay within the boundary layer, (2) pyrocumulus containing water droplets either staying in the boundary layer or reaching the free troposphere depending on atmospheric conditions, and extreme (3) pyrocumulonimbus scenarios containing ice particles and potentially reaching the stratosphere. Typically, most of the biomass burning emissions stay within the mixing layer, and cases with pyroconvection or direct injection to the free troposphere or even higher are rare (Labonne et al., 2007;Mazzoni et al., 2007;Tosca et al., 2011).
As can be seen in Fig. 7, the IS4FIRES injection heights corresponding to the top of the plume are equal to or smaller . Retrieved carbon monoxide column-averaged mole fractions from TROPOMI for the same days as in Fig. 1. Dotted scenes are excluded by the quality filter based on simultaneously retrieved XCH 4 . Also shown is the mean wind in the boundary layer obtained from ECMWF data. than the respective maximum boundary layer height at the location of the fires (all the more when considering the additional uncertainty associated with the estimation method of the boundary layer height, which is not shown in the figure), with the exception of the first day of the Camp Fire. This sole discrepancy may be linked to overestimated fire radiative power for the Camp Fire on the day of ignition, which is also suggested by the comparison of the CAMS XCO analysis to the TROPOMI retrievals, showing considerably higher abundances for CAMS in the vicinity of the fire source. In summary, the IS4FIRES injection height analysis indicates that most of the CO load stays within the boundary layer. Furthermore, the entire state of California was at least abnormally dry within the analysed time period, with a moderate drought at the Camp Fire origin and a severe drought at the seat of the Woolsey Fire according to the United States Drought Monitor (https://droughtmonitor.unl.edu/, last access: 20 January 2020). These are favourable conditions for dry smoke plumes being trapped in the boundary layer, also rendering later deep moist convection with transport to the free troposphere during the first days of the fire at another location unlikely. Finally, there is also no indication for pyrocumulus or pyrocumulonimbus in the VIIRS true colour images as there is no obvious cloud formation over the fires (see Fig. 1).
Nevertheless, partial venting to the free troposphere cannot be entirely excluded and we therefore introduce an uncertainty σ (h inj ) arising from unknown plume dynamics, which is only applied to the smaller end of the boundary layer concentration anomaly because lost CO of this type can only lead to an overestimation of the near-surface concentrations. σ (h inj ) for the analysed cities is estimated by the CO mass fraction f a above the upper bound of the ERA5 boundary layer height uncertainty range as determined from the CAMS model CO vertical profiles (see Fig. 8). As there is no indication that the CO fraction in the free troposphere grows significantly during the analysed period over the cities considered, mean CAMS profiles for days with substantial CO enhancement are examined. The CAMS CO profile analysis further reinforces the assumption that most of the emitted CO stays within the boundary layer even 4 d after ignition and at a greater distance from the fire sources. f a is below 10 % with the exception of San Diego. Thus, the uncertainty σ (h inj ) is set to 30 % for San Diego and 10 % for the other cities.
Another potential error source associated with fires is smoke aerosol. Scenes with reduced near-surface sensitivity due to clouds and smoke with large particles near the seat of the fires are automatically filtered out using simultaneously measured methane. Figure 3 also demonstrates that methane is not considerably increased compared to the prefire background abundances (Fig. 2a) and that the XCO enhancement patterns are not resembled in XCH 4 . Thus, it can be excluded that the detected XCO enhancement is only an artefact as a result of light path lengthening because of aerosol scattering at the particulate matter of the smoke because such systematic errors would affect both retrieved gases similarly.
To assess the potential impact of smoke aerosol quantitatively, simulated measurements are used. This means that sun-normalised radiances for an assumed smoke scenario are calculated with the radiative transfer model, which are subsequently used as measurement input in the retrieval. The errors are then defined as the deviation of the retrieved columns for the smoke scenario from the corresponding columns for the background scenario also used to calculate the forward model lookup table. To model wildfire conditions at a sufficient distance from the seat of the fire with low visibility but decreasing scattering issues at larger wavelengths (consistent with Figs. 1 and 3) we use the extreme in BL aerosol scenario originally introduced in Schneising et al. (2008), containing urban aerosol with a significant soot fraction (Shettle and Fenn, 1979), combined with an extreme CO profile with a 10-fold enhancement in the boundary layer compared to the standard profile. The aerosol scenario used (aerosol optical depth τ 550 nm ≈ 3 and Ångström exponent α ≈ 1) is considered a realistic worst-case scenario for the analysed fires because it is at the upper end of optical depths and at the lower end of Ångström exponents for typical fire aerosols (Eck et al., 2009). Furthermore, the corresponding aerosol profile is consistent with the previous results for the vertical distribution of the emitted species during the first 4 d of the fires. Thus, the Camp Fire and the Woolsey Fire very likely exhibit less scattering in the 2.3 µm spectral range than our model scenario assumes, at least during the period analysed. The corresponding results are summarised in Fig. 9. Typical systematic CO errors for Californian cities on the analysed days range between about −3 % and 2 % for the assumed aerosol type and CO profile. Therefore, the uncertainty due to smoke aerosol σ (a smo ) is set to 5 %, adding an extra amount due to the uncertainty of the actual aerosol type.
The total uncertainty of the boundary layer concentration anomaly σ ( ρ bl ) is determined by Averaged boundary layer concentration anomalies of CO (relative to 7 November) in major Californian cities during the first days of the Camp and Woolsey fires are presented in Fig. 10 together with the total uncertainty of Eq.
(2) and an estimate of the areal variation measuring the inhomogeneity of the CO concentrations within the city area. The largest values are found for Sacramento and San Francisco on 9 and 10 November due to the prevailing wind conditions, with boundary layer concentration anomalies of about 2.5 mg CO m −3 , which is well below the national CO air quality standard of 10 mg m −3 even after adding a typical background concentration of about 0.5-1.0 mg CO m −3 . The cities in the southern part of the state are less affected owing to more favourable weather conditions. Although the Sacramento and San Francisco city averages are compliant with air quality standards, the large associated areal variations indicate an uneven CO distribution within both towns, in particular for Sacramento. This interpretation is supported by the CO distribution depicted in Fig. 4, showing that the plume's edge of the Camp Fire is located near Sacramento, leading to a larger burden in the northwest compared to the rest of the city.
The largest burden with respect to CO within all city radii is actually found on 10 November about 10 km to the east of Sacramento International Airport, where one finds a considerable column enhancement of 3.14 g m −2 . Given the ECMWF ERA5 boundary layer height of 580 m, this corresponds to a boundary layer concentration anomaly of 5.42 mg CO m −3 [3.41-6.00; 1σ ]. The largest enhancement on 9 November is also located in the vicinity of Sacra- Figure 7. Diurnal variations of the boundary layer heights obtained from the ECMWF ERA5 reanalysis for major Californian cities (solid) and fires (dotted). The uncertainty estimates are based on a 10-member 4D-Var ensemble; the additional uncertainty associated with the estimation method of the boundary layer height is not shown here. Also shown are mean IS4FIRES smoke injection heights and their variation for both analysed fires as horizontal bars and hatched areas. The grey-shaded area illustrates the TROPOMI overpass time. On 8 November the injection height of the Woolsey Fire is zero because it started later in the day. mento Airport (about 10 km to the southwest) and amounts to 3.13 g m −2 , with a boundary layer height of 592 m leading to a boundary layer concentration anomaly of 5.28 mg CO m −3 [3. 32-5.93; 1σ ]. Thus, the national ambient air quality standard of 10 mg CO m −3 was likely not exceeded even for the most polluted city scenes and after adding a typical background of about 0.5-1.0 mg CO m −3 .
To further assess the described area with significantly increased boundary layer concentrations, we revisit the discussed contaminated scene near Sacramento Interna- Figure 9. Panel (a) shows the aerosol extinction profiles used in the analysis of smoke aerosol errors. Also given are the corresponding aerosol optical depths at 550 nm. The other panels show the systematic errors of CO and CH 4 as a function of solar zenith angle and albedo when using the extreme instead of the background aerosol scenario. The green boxes highlight the typical conditions for the Californian cities on the analysed days using percentiles corresponding to 1σ (68 % of data) and 2σ (95 % of data). The green circle is the pair of median albedo and median solar zenith angle. tional Airport on 10 November and analyse associated results from CAMS and ground-based air quality monitoring data provided by the California Air Resources Board. For the grid box comprising the mentioned satellite scene, CAMS predicts a considerably larger column enhancement of 5.93 g m −2 , corresponding to a boundary layer concentration anomaly of 10.23 mg CO m −3 [6.51-11.04; 1σ ] using the ERA5 boundary layer height and the associated uncertainties. Although this is almost twice as high as the satellitederived concentration anomaly and potentially exceeds the national ambient air quality standards, the error bars of the CAMS and satellite-derived concentration anomalies almost overlap due to the relatively large uncertainties arising from boundary layer height estimation and unknown plume dynamics.
Ground-based measurements are available from the Air Quality and Meteorological Information System (AQMIS) network (California Air Resources Board, 2018), providing daily maximum and daily average values. There are three CO measurement sites in Sacramento County. For the site at Bercut Drive in Sacramento the data set is incomplete during the first days of the fire and therefore excluded from the comparison. The second site at Blackfoot Way in North Highlands is located farther north and closer to the analysed contaminated satellite scene. The maximum value during the first 4 d of the fire is stated to be 4.1 ppm (4.8 mg CO m −3 ) on 10 November. Relative to the maximum value of 7 November this corresponds to a concentration anomaly of 3.60 mg CO m −3 . The third site is at Del Paso Manor in Sacramento with a maximum value of 3.8 ppm (4.4 mg CO m −3 ) on 10 November corresponding to a concentration anomaly of 3.00 mg CO m −3 . When using the daily averages instead of the maximum values, the concentration anomalies amount to 1.93 mg CO m −3 for both sites. Figure 11 shows the boundary layer concentration anomalies in Sacramento and its surrounding districts, allowing for an overview of the situation by highlighting the locations of the different measurements. As can be seen, the AQMIS sites are located east of the satellite scene with the maximal city area CO value, where concentrations are beginning to decline steeply. The corresponding satellite averages at both analysed AQMIS sites are broadly consistent with the groundbased measurements, taking into account the potential variability within a satellite scene indicated by the scene-to-scene gradient of the satellite data and the fact that the sites are located at the edge of satellite scenes. While the ground-based anomaly based on the maximum values in North Highlands matches well with the value of the associated satellite scene, the ground-based anomaly based on the daily averages rather resembles the values of adjacent satellite scenes to the east or to the south. At Del Paso Manor the opposite is true: the ground-based anomaly based on the daily averages fits the surrounding satellite scene well, while the anomaly based on the maximum values rather matches the adjacent satellite scene to the north.

Conclusions
We have performed an analysis of atmospheric carbon monoxide (CO) concentration changes introduced by emissions of fires using measurements in the shortwave infrared spectral range of TROPOMI onboard the Sentinel-5 Precursor satellite. The local CO emissions of Californian wildfires and subsequent transport can be clearly observed from space. Due to its unique features, CO retrievals from TROPOMI have the potential to trigger model improvement and a better quantification of fire emissions through the assimilation of satellite-derived XCO in integrated systems such as CAMS.
Furthermore, new fields of application are enabled, in particular the detection of emission hot spots or air quality monitoring tasks, because large sources are readily detected in a single overpass. The evaluation of TROPOMI's capabilities for dense air quality monitoring has shown that the quantitative assessment of the CO burden in major Californian cities is possible on a daily recurrent basis using the example of the first days of the Camp Fire and Woolsey Fire in November 2018.
However, the accurate determination of boundary layer concentrations depends on reliable external mixing layer height information. In the case of fires, the feasibility is also subject to specific favourable circumstances affecting the vertical distribution of emissions. The local ambient atmospheric conditions such as stability and humidity have to ensure that most of the fire emissions stay within the boundary layer and that pyro-convection or direct injection to the free troposphere is unlikely. As a consequence, unknown plume dynamics generally remain the largest source of uncertainty in the calculation of the boundary layer CO burden caused by wildfires. The case study presented here benefits from the fact that most of the emitted CO remains in the boundary layer during the analysed period, which considerably reduces the associated uncertainties.
The quantitative analysis has shown that even intense wildfire events are not necessarily associated with the exceedance of national ambient air quality standards in the far field of the fires because all major city scenes for the analysed days comply with the regulatory limits. This finding is also confirmed by isolated ground-based air quality measurements near the most polluted city scenes.
Increasing unusual weather conditions with dryness of vegetation on the rise may lead to longer-lasting and more intense fire seasons in the future. Therefore, it is getting more and more important to monitor and forecast the air quality decline associated with wildfires in a changing climate to evaluate whether the compliance with regulatory limits will last or not. This can be achieved by an integrated monitoring system combining modelling with complementary information from accurate ground-based measurements and observations from various satellites.
Author contributions. OS designed and operated the TROPOMI/WFMD satellite retrievals, performed the data analysis, interpreted the results, and wrote the paper. MB, MR, HB, and JPB provided significant conceptual input to the design of the TROPOMI/WFMD satellite retrievals, the interpretation, and the improvement of the paper. All authors discussed the results and commented on the paper.
Competing interests. The authors declare that they have no conflict of interest.
Special issue statement. This article is part of the special issue "TROPOMI on Sentinel-5 Precursor: first year in operation (AMT/ACP inter-journal SI)". It is not associated with a conference.
Acknowledgements. This publication contains modified Copernicus Sentinel data and modified Copernicus Climate Change Service Information (2018). Sentinel-5 Precursor is an ESA mission implemented on behalf of the European Commission. The TROPOMI payload is a joint development by the ESA and the Netherlands Space Office (NSO). The Sentinel-5 Precursor ground-segment development has been funded by the ESA and with national contributions from the Netherlands, Germany, and Belgium. The research leading to the presented results has in part been funded by the ESA projects GHG-CCI, GHG-CCI+, and S5L2PP, the Federal Ministry of Education and Research project AIRSPACE, and by the State and the University of Bremen.
We acknowledge the use of VIIRS imagery from the NASA Worldview application (https://worldview.earthdata.nasa.gov/, last access: 20 January 2020) operated by the NASA/Goddard Space Flight Center Earth Science Data and Information System (ESDIS) project as well as the use of data from the California Department of Forestry and Fire Protection and the U.S. Environmental Protection Agency. We also thank the European Centre for Medium-Range Weather Forecasts (ECMWF) for providing the meteorological analysis, the ERA5 reanalysis, the Copernicus Atmosphere Monitoring Service (CAMS) carbon monoxide analysis, and the Global Fire Assimilation System (GFAS) data. Neither the European Commission nor the ECMWF is responsible for any use that may be made of the Copernicus information or data it contains. Ground-based CO data were obtained using the Air Quality Data (PST) Query Tool (https://www.arb.ca.gov/aqmis2/aqmis2.php, last access: 20 January 2020) of the Air Quality and Meteorological Information System (AQMIS).
Financial support. The article processing charges for this openaccess publication were covered by the University of Bremen.
Review statement. This paper was edited by Thomas Röckmann and reviewed by two anonymous referees.