Evaluated kinetic and photochemical data for atmospheric chemistry: Volume VII – Criegee intermediates

This article, the seventh in the series, presents kinetic and photochemical data sheets evaluated by the IUPAC Task Group on Atmospheric Chemical Kinetic Data Evaluation. It covers an extension of the gas-phase and photochemical reactions related to Criegee intermediates previously published in Atmospheric Chemistry and Physics (ACP) in 2006 and implemented on the IUPAC website up to 2020. The article consists of an introduction, description of laboratory measurements, a discussion of rate coefficients for reactions of O3 with alkenes producing Criegee intermediates, rate coefficients of unimolecular and bimolecular reactions and photochemical data for reactions of Criegee intermediates, and an overview of the atmospheric chemistry of Criegee intermediates. Summary tables of the recommended kinetic and mechanistic parameters for the evaluated reactions are provided. Data sheets summarizing information upon which the recommendations are based are given in two files, provided as a Supplement to this article.


Introduction
Laboratory kinetic and mechanistic studies of the reactions of alkenes with ozone (O 3 ) have established that "Criegee intermediates" (CIs) produced from these reactions are potentially important oxidants in atmospheric chemistry (e.g. Calvert et al., 2000;Johnson and Marston, 2008;Taatjes et al., 2014). This followed the suggestion by Penkett (1971, 1972) that the rapid oxidation of SO 2 in the presence of reacting mixtures of O 3 and alkenes in air was caused by production of a reactive intermediate, namely the peroxidic zwitterion, R 1 R 2 C=O + −O − , proposed by Rudolf Criegee, based on studies of the liquid-phase ozonolysis of alkenes (e.g. Criegee et al., 1954).
This has led to extensive study of the mechanisms of O 3 + alkene reactions, and of the chemistry of the CIs formed. It is well established that the reaction proceeds by initial cyclo-addition of O 3 across the C=C double bond in an alkene to form an energy-rich primary ozonide (POZ), which rapidly decomposes to form either of two sets of CI and carbonyl compound, as shown in Fig. 1. The reac-tion is exothermic, leading to an excess of energy (200-250 kJ mol −1 ) distributed between these reaction products. Some of this excess energy is deposited as internal energy in the nascent CIs, which can promote unimolecular decomposition or which can be lost by collisional energy transfer to other gas molecules, leading to formation of stabilized Criegee intermediates (sCIs), which can themselves react with other atmospheric trace species. The impact of the ozonolysis reaction on atmospheric oxidation chemistry is therefore influenced by the relative importance of prompt CI decomposition vs. formation of sCI. The recognition of the important distinction between the chemically activated CI, formed promptly in excited state, and the thermally equilibrated sCI has led to extensive experimental efforts to determine the yield of sCI (Y ) formed from the ozonolysis of a variety of alkenes, as discussed further in Sect. 3. It is also well established that the decomposition of both CI and sCI leads to the formation of hydroxyl (HO) radicals and other radical products. Due to its important role in initiating the oxidation of organics (including alkenes), the formation of HO radicals has received particular attention, and this is discussed further in Sect. 4.
The mechanism in Fig. 1 shows that the CIs (and sCIs) formed from the ozonolysis of a simple alkene can each be formed as either of two stereo-isomers, with different orientations of the outer O atom relative to the substituent groups. This potentially has an important impact on the chemical pathways available, and their relative rates. The stereo-isomers have generally been distinguished using the terms synand anti-, to specify the orientation of the outer O atom relative to a particular substituent; although the use of the IUPAC Zand Enomenclature is becoming increasingly adopted (e.g. . As shown in Fig. 1, the ozonolysis of a simple alkene containing four different substituents therefore produces four distinct CIs, with this number being systematically reduced in symmetrical alkenes (because the products of the two POZ fragmentation pathways are the same) or in alkenes possessing two identical substituents on the same carbon atom (because the stereoisomerism in the CI is removed). However, the number of different CI isomers can also be increased if the alkene contains alkenyl substituents, as is the case for the CIs formed from the ozonolysis of dienes such as the C 4 species derived from isoprene because of additional stereo-isomerism in the substituent group(s).
Based on current understanding of the mechanism of alkene ozonolysis (as illustrated in Fig. 1), the steady-state concentration of a given stabilized Criegee intermediate, [sCI i ], maintained by a balance between production and loss, is described by Eq. (1): [SO 2 ] + k 5i [NO 2 ] + · · · + · · ·) , (1) Figure 1. Mechanism of the reaction of ozone with alkenes, showing formation of Criegee intermediates (CIs). The general types of reaction available for stabilized Criegee intermediates (sCIs) are also illustrated for one example. The substituents R 1 to R 4 can be either H atoms or organic groups, although the illustrated sCI/CI vinyl hydroperoxide route is unavailable if R 2 = H. Note that in the case of endocyclic C=C bonds in cycloalkenes, the initially formed carbonyl and CI moieties are substituents of the same organic product. where k 1j is the rate coefficient for the reaction of O 3 with alkene j and Y ij is the yield of sCI i from that reaction. The numerator of Eq. (1) therefore quantifies the source term for formation of sCI i from all relevant alkenes, and the denominator quantifies the sum of the rates of the unimolecular and individual bimolecular loss processes for sCI i , with the example contributors to the summation being based on the processes shown in Fig. 1. This illustrates that knowledge of the yields, rate coefficients and products for the component reactions is important for quantitative description of the chemical pathways controlling the atmospheric chemistry and impact of the given sCI i . It also shows the importance of establishing how these parameters vary from one sCI to another, e.g. the structural dependence of the rate coefficients for their unimolecular and bimolecular reactions.
Although rate constants have been determined accurately for a large number of O 3 + alkene reactions, using both direct and relative rate techniques, all kinetic data reported for sCI reactions prior to 2012 were based on indirect relative rate techniques. Many of these data were previously evaluated by the IUPAC Task Group on Atmospheric Chemical Kinetic Data Evaluation (Atkinson et al., 2006). Since 2012, many new rate coefficients for sCI reactions have been reported in direct kinetic studies, providing a wealth of data for the elementary reaction kinetics and spectroscopy of sCI reactions. The current evaluation therefore addresses these reactions, substantially extending the scope of our former evaluation published in ACP in 2006. This includes a major extension of the scope of the evaluation to include rate coefficients of elementary reactions of selected sCIs, which have provided a better understanding of the atmospheric impact of sCI chemistry.
In this review we summarize the results of this evaluation activity, presenting in turn the recommended kinetic data for the key reactions in the above mechanism, using data for those species which are representative of the chemistry of the terrestrial atmosphere. The rate coefficients for O 3 + alkene initiation reactions are presented and discussed in Sect. 2, with reference to a series of detailed data sheets which are provided in Supplement A. Information on the sCI and HO radical yields from the ozone + alkene reactions is presented in Sects. 3 and 4, with additional discussion once again provided in the corresponding data sheets in Supplement A. The data sheets therefore each include summary information on the kinetics studies of the given reaction and provide an overview of mechanistic information and product yields where available.
The spectroscopy and kinetics recommendations for the sCI reactions are presented and discussed in Sects. 5 and 6. These include data for bimolecular and unimolecular reactions of selected sCIs of particular atmospheric relevance for which direct kinetic data have been reported, namely CH 2 OO, Zand E-CH 3 CHOO, (CH 3 ) 2 COO and E-(CH=CH 2 )(CH 3 )COO, and we also provide some discussion of the complete set of C 4 intermediates formed from isoprene (see Fig. 2 for sCI structures). These are predicted to be among the most important sCIs in tropospheric chemistry , and can also act as a systematic set of template species for representing the fates of some larger and more complex sCIs. Detailed data sheets for the sCI reactions are provided in Supplement B, providing supporting summary information and discussion. Finally, the recommended kinetics parameters are used to evaluate the relative importance of the different fates of the sCIs under representative atmospheric conditions in Sect. 7, and an overview of Figure 2. Structures of the stabilized Criegee intermediates considered in the present evaluation, and the nomenclature assigned. In the cases of the di-substituted (isoprene-derived) C 4 intermediates, the Z and E notations specify the orientation of the first named substituent (which has the higher Cahn-Ingold-Prelog priority) relative to the CI moiety. The displayed rotamers of the C 4 intermediates are calculated to be in near equilibrium under atmospheric conditions  and are assumed to act as a single species in each case. the impact of Criegee intermediates in atmospheric oxidation chemistry is given in Sect. 8.

Rate coefficients of O 3 + alkene reactions
The present evaluation considers the reactions of O 3 with 31 alkenes, including small (C 1 to C 4 ) alkenes, isoprene, monoterpenes and sesquiterpenes. This represents a substantial increase on those considered in our previous evaluation (Atkinson et al., 2006), which were limited to ethene, propene, isoprene and α-pinene. The reactions are listed in Table 1, along with the associated recommended rate coefficients. A detailed data sheet for each reaction is also provided in Supplement A. As discussed in detail previously (e.g. Calvert et al., 2000Calvert et al., , 2015, the data indicate that the rate coefficients are highly sensitive to alkene structure, and depend on the degree of alkyl substitution of the unsaturated bond(s), on steric effects and on ring-strain effects in cyclic compounds. The lower tropospheric lifetimes of the alkenes, with respect to reaction with 20 ppb O 3 , therefore cover several orders of magnitude, ranging from as short as 2-3 min for reactive species such as α-terpinene, β-caryophyllene and α-humulene, to about 7 weeks or longer for camphene and longifolene. For the simple alkenes, the lifetimes range from about 30 min for the fully substituted 2,3-dimethylbut-2-ene to about 2 weeks for ethene. With the exception of the least reactive compounds, removal by ozonolysis is expected to make a contribution for all the evaluated alkenes under lower tropospheric conditions and is generally the domi-nant fate for those with rate coefficients in excess of about 10 −15 cm 3 molec. −1 s −1 .

sCI yields from O + alkene reactions
As described in Sect. 1 and Fig. 1, the chemically activated CIs formed from the O 3 + alkene reactions may either decompose promptly or lose energy by collisions with other molecules to form stabilized Criegee intermediates (sCIs). The sCIs have the potential to undergo reactions with other atmospheric trace gases, leading to their oxidation and formation of characteristic products. Thus, it is important to quantify the yield (Y ) of each sCI from each relevant precursor alkene if the impact of alkene ozonolysis and Criegee chemistry on oxidation processes is to be correctly represented in atmospheric mechanisms, or to allow the local steady-state concentration of the sCIs to be estimated by Eq. (1).
There have been extensive experimental efforts to determine Y for a variety of O 3 + alkene systems. The yields have generally been expressed as a fraction of the molar amount of O 3 reacted, and have been determined by reaction of the sCIs formed with an appropriate added scavenger reagent (e.g. SO 2 , H 2 O, HCHO, HCOOH, CF 3 C(O)CF 3 ). The yield is determined either from quantitative analysis of a characteristic product of the sCI + scavenger reaction, or through measurement of the loss of the scavenger. The reported values of Y are therefore indirect measurements that have generally quantified the total yield of sCIs formed in a given alkene + O 3 system, with little or no information on the contributions of the component sCI species for asymmetric alkenes being reported. Table 2 gives a summary of the recommended values of Y for the evaluated O 3 + alkene reactions at 298 K and 1 bar, with additional details provided in the corresponding reaction data sheets in Supplement A. Values for selected other alkenes (trans-dec-5-ene, transtetradec-7-ene and cyclohexene) are also given to help illustrate structural variations in Y , as discussed further below.
As indicated in Sect. 1, the stabilization of the promptly formed chemically activated CIs requires loss of internal energy through collisional energy transfer to other gas molecules. As a result, studies of a number of O 3 + alkene systems have shown that Y depends on pressure (e.g. Hatekayama et al., 1986;Drodz and Donahue, 2011;Donahue, 2016, 2018;Campos-Pineda and Zhang, 2017) but with significant residual values at zero pressure. This indicates that a limiting yield of sCIs (i.e. with internal energy below the threshold required for decomposition or isomerization) is typically formed directly from decomposition of the primary ozonide, POZ (although this is not illustrated in Fig. 1 for simplicity), with additional sCI formation resulting from collisional stabilization of the chemically activated CIs.
The value of Y is also expected to vary systematically with alkene structure, and the reported data display some logical structural trends that are consistent with theoretical treatments. These can be rationalized in terms of the nascent internal energy in the Criegee intermediate and how this is influenced by partitioning of the excess energy into either translational modes (i.e. recoil), internal energy of the carbonyl co-product, or into non-reactive vibrational or rotational modes within the Criegee intermediate (e.g. Choung et al., 2004;. The value of Y is therefore expected to increase with alkene size along a homologous series, as has been confirmed for a set of transsymmetric alkenes between C 4 and C 14 by Hakala and Donahue (2018). As a result, the values at 298 K and 1 bar for large acyclic alkenes (e.g. Y = 1.0 for trans-dec-5-ene and trans-tetradec-7-ene) tend to be larger than those for the smaller acyclic alkenes, as listed in Table 2. Similarly, those for large cycloalkenes with endocylic double bonds (e.g. Y > 0.6 for the C 15 β-caryophyllene) tend to be larger than those for smaller species such as the C 10 α-pinene (Y = 0.18) and the C 6 cyclohexene (Y < 0.05). It is also clear that the values for cycloalkenes with endocylic double bonds are systematically lower than those for similarly sized acyclic alkenes (or cycloalkenes with exocylic double bonds). This can be rationalized in terms of the excess energy being confined within a single product possessing both Criegee and carbonyl functionalities for the cycloalkenes with endocylic double bonds; whereas it can be dissipated into translational modes, and the internal energy of the carbonyl co-product, for acyclic alkenes (and for cycloalkenes with exocylic double bonds).
It is also recognized that the indirect yield measurements are often subject to significant uncertainties and variability between different measurement methods (e.g. see Hakala and Donahue, 2016), such that systematic trends can be masked. Another important consideration is that exceptionally rapid unimolecular decomposition and isomerization reactions are predicted to be available for some sCIs, e.g. some of the C 4 species formed from O 3 + isoprene , as is discussed further in Sects. 4 and 7. In these cases it is possible that the bimolecular reactions with scavengers are unable to compete with the fast unimolecular processes, and consequently the reported yields for sCI formation may be underestimated.

HO radical yields from O 3 + alkene reactions
It has been established for several decades that the reactions of O 3 with alkenes lead to the formation of HO radicals (e.g. Finlayson et al., 1972;Donahue et al., 1998), and considerable attention has been given to quantifying HO radical yields for many O 3 + alkene systems. In most of the reported studies, the yields have been determined indirectly by reaction of the HO formed with an appropriate added scavenger reagent (e.g. cyclohexane, 1,3,5-trimethylbenzene, butan-2-ol). The yield is then determined either from quantitative analysis of the yield of a characteristic product of the HO + scavenger reaction or through measurement of the loss of the scavenger. However, direct detection methods (particularly laser-induced fluorescence) have also been used to quantify HO yields in a number of studies (e.g. Donahue et al., 1998;Siese et al., 2001;Kroll et al., 2001a, b;Malkin et al., 2010;Alam et al., 2013), providing unequivocal identification of HO as a product of O 3 + alkene reactions, and a means of confirming the validity and interpretation of the indirect methods (e.g. Malkin et al., 2010). Table 3 gives a summary of the recommended HO radical yields for the evaluated O 3 + alkene reactions at 298 K and 1 bar, with additional details provided in the corresponding reaction data sheets in Supplement A. The formation of HO radicals can result from both prompt unimolecular decomposition of chemically activated CIs and decomposition of thermally equilibrated sCIs over longer timescales (e.g. as demonstrated in the time-resolved pressure dependence measurements of Kroll et al., 2001c). The most important mechanism forming HO is generally accepted to proceed by a 1,4 H shift isomerization to an excited vinyl hydroperoxide intermediate, which decomposes to form HO and a vinoxy or β-oxo alkyl radical; and this cis-but-2-ene 0.38 ± 0.10 (e) Ox_VOC18 trans-but-2-ene 0.43 ± 0.10 (f) Ox_VOC15 2-methylpropene 0.21 ± 0.05 (g) Ox_VOC41 2,3-dimethylbut-2-ene 0.38 ± 0.10 (h) Ox_VOC7 isoprene 0.65 ± 0.10 (i)
Another key route involves initial rearrangement (1,3 ringclosure) to form a dioxirane intermediate (see Fig. 1). This provides an alternative unimolecular decomposition pathway for CH 2 OO and Emono-substituted Criegee intermediates (e.g. E-CH 3 CHOO) and is also calculated to be competitive for some Zmono-substituted Criegee intermediates possessing oxygenated substituents . In the former case, it is likely to be significant only for the chemically activated CI, [CH 2 OO] * , because unimolecular loss of the thermally equilibrated sCI, CH 2 OO, is observed and calculated to be slow (see Sect. 7). The dioxirane intermediate isomerizes to form "hot" formic acid, [HC(O)OH] * , which can fragment via a number of pathways: Reaction (R7a) can therefore account for the small HO yield (0.17) resulting from the O 3 + ethene reaction (Table 3), and the set of product channels can also rationalize the observed formation of HO 2 (from the reactions of O 2 with H and HCO), CO and CO 2 (see data sheet OX_VOC5 in Supplement A). In the cases of Emono-substituted Criegee intermediates (e.g. E-CH 3 CHOO), isomerization via a dioxirane intermediate is again expected to be significant for chemically activated CIs and is also calculated to occur for thermally equilibrated sCIs (e.g. . For sCIs, however, it is in competition with some particularly rapid bimolecular reactions under atmospheric conditions (see Sects. 7 and 8) and may therefore be of limited importance. In the case of the chemically activated [E-CH 3 CHOO] * , the dioxirane intermediate isomerizes to form "hot" acetic acid, [CH 3 C(O)OH] * , and the following path-ways can rationalize the observed formation of HO 2 , CO 2 , CH 2 =CO (ketene), CH 4 and CH 3 OH from the reactions of O 3 with propene and cisand trans-but-2-ene (see data sheets OX_VOC6 , OX_VOC17 and OX_VOC18 in Supplement Sect. A1). [ In principle, formation of HO (and CH 3 CO, or CH 3 and CO) may also occur by a route analogous to Reaction (R7a). The possible contribution of the corresponding channel more generally for Emono-substituted CIs is poorly characterized, although it is generally accepted to be only a minor source of HO compared with the 1,4 H shift isomerization route for the Zconformers. The dioxirane route has also been reported to lead to the formation of stabilized acid, ester or lactone products, particularly in larger O 3 + alkene systems (e.g. Hakola et al., 1994;Griesbaum et al., 1998;Winterhalter et al., 2009;Nguyen et al., 2009a, b). A number of other unimolecular reactions are available for Criegee intermediates possessing larger organic substituents, particularly those that are unsaturated (e.g. see . For example, very rapid 1,5 ring-closure reactions are expected to dominate for Z-α,βunsaturated sCIs, such as Z-(CH=CH 2 )(CH 3 )COO and Z-(C(CH 3 )=CH 2 )CHOO formed from O 3 + isoprene, e.g. for Z-(CH=CH 2 )(CH 3 )COO.
In the cases of carbonyl-substituted sCIs, such as those formed from cycloalkenes with endocyclic double bonds, the potential for (bicyclic) ring-closure to form intramolecular secondary ozonides is well established.
These reactions have been characterized in a number of theoretical studies (e.g. Chuong et al., 2004;Nguyen et al., 2009b;Mackenzie-Rae et al., 2016;Long et al., 2019), with experimental evidence for their formation also reported (e.g. Winterhalter et al., 2009;Beck et al., 2011). In practice, however, these reactions are only observed (and calculated) to be significant for larger systems (e.g. sesquiterpene ozonolysis), where the Criegee intermediates are formed significantly stabilized, and the ring closure reaction does not result in prohibitive ring strain. Where these criteria are met, they are predicted to be rapid reactions that can compete with, or dominate over, other decomposition routes, and this is one factor contributing to the low HO yields reported for some sesquiterpenes (e.g. βcaryophyllene and α-humulene).

Structure and spectroscopy of Criegee intermediates
Assessment of the photolysis rates and product channels for sCIs requires quantitative data for the absorption cross sections and quantum yields for individual sCI species at atmospheric, actinic wavelengths, mainly in the UV and visible. The development of methods for creating specific sCIs in defined concentrations has allowed experimental investigation of their spectroscopy and structure; see the review by Osborn and Taatjes (2015), for example. Moreover, advances in theoretical methods have also provided insight into the spectra and structure of sCIs, and quantum calculations have given further details of reaction mechanisms and product channels of sCI photolysis (e.g. Samanta et al., 2014).
The spectroscopic studies of sCIs have led to the recognition that they have a single ground electronic state, whose dominant configuration is that of a zwitterion, and this is reflected in the large dipole moment of these species (Chhantyal-Pun et al., 2017a). The observed spectra of the C 1 -C 3 sCIs exhibit strong and broad absorptions centred in the near UV, with maximum cross sections of the order of 10 −17 cm 2 molec. −1 . These features, and their detailed rovibrational structures, are consistent with B(1A ) ← X(1A ) transitions, i.e. intense π * ← π transitions analogous to the familiar UV spectrum of O 3 in the Hartley-Huggins bands. Photodissociation of CH 2 OO from this excitation is reported to proceed with a quantum yield of unity (e.g. Ting et al., 2014), producing HCHO and either O( 3 P) or O( 1 D). Production of O( 1 D) has been reported to be dominant (e.g. Li et al., 2015) and exclusive in the long wavelength tail (λ ≥ 364 nm; Vansco et al., 2017).

Conformers
As described in Sect. 1 and Fig. 1, Criegee intermediates with dissimilar substituents can exist as two possible conformers, denoted Eand Z-, which differ in the orientation of the outer O atom relative to the substituent groups. The simplest examples are Eand Z-CH 3 CHOO (acetaldehyde oxide, see Fig. 2), for which conformer dependence has been demonstrated experimentally and theoretically in its spectra and its reaction rates and pathways. Calculations place Z-CH 3 CHOO about 15 kJ mol −1 lower in energy than E-CH 3 CHOO (Kuwata et al., 2010), reflecting the zwitterionic character of the Criegee intermediate structure. Calculated energies of the Eand Zconformers of CH 3 CHOO are consistent with the spectral shift of λ max (Z-) < λ max (E-) shown in Fig. 3. This has enabled conformer-specific reactions to be investigated, using direct observation of the kinetics and products of the two conformers. The barrier to interconversion is substantial (∼ 160 kJ mol −1 ), and consequently E-  Criegee et al. (1954).

UV spectra of stabilized Criegee intermediates
In experimental studies of UV-visible spectra, the series of C 1 -C 3 sCIs have mainly been formed by photolysis of the corresponding di-iodoalkane (via C-I bond fission), followed by the reaction of the iodoalkyl radical with O 2 , e.g. in the case of CH 2 OO (e.g. Beames et al., 2012;Sheps, 2013).
The formation of CH 2 I (and subsequently CH 2 OO) from the photolysis of CH 2 IBr (via C-Br bond fission) has also recently been reported (Peltola et al., 2020), suggesting that bromo-iodoalkanes may also be used more widely as sCI precursors. Absolute cross sections at specific wavelengths have been derived by monitoring the laser UV-induced depletion of the sCIs, monitored, for example, by mass spectrometry or by time resolved UV-absorption spectroscopy. The experimental data reveal some discrepancies regarding the shapes, structure, and intensities of the B( 1 A ) ← X( 1 A ) spectra determined using transient absorption spectroscopy, compared with laser-induced depletion techniques, determined under molecular beam conditions. This discrepancy has been attributed to the much lower temperatures reached in the molecular beams, compared to measurements at ambient temperature, but lack of detailed data on the temperature dependence of the cross sections over the required range precludes firm conclusions from being drawn. The evaluation of the spectral data and detailed discussion of the reported studies are given for the C 1 -C 3 sCIs in the data sheets in Supplement Sect. B5. The recommendations for the maximum absorption cross sections are given in Table 4, and the spec-tra are presented in Fig. 3. Using these data, representative lower tropospheric photolysis removal rates in the range 0.4-1.4 s −1 can be calculated for a solar zenith angle of 30 • at the surface, based on the actinic flux estimates of Madronich, presented by Finlayson-Pitts and Pitts (2000). This indicates that loss by photolysis is likely only a minor or negligible loss process for sCIs in the lower atmosphere, compared with their collective removal by the thermal reactions discussed in the following section. Novel methods for the production of the C 4 isoprenederived sCIs have also been reported (Barber et al., 2018;Vansco et al., 2019), with Zand E-(CH=CH 2 )(CH 3 )COO formed from the photolysis of 1,3-di-iodobut-2-ene and Zand E-(C(CH 3 )=CH 2 )CHOO formed from the photolysis of 1,3-di-iodo-2-methylprop-1-ene, both in the presence of O 2 . This has allowed characterization of the UV-visible spectra of the unsaturated C 4 sCIs (Vansco et al., , 2019, which are reported to be broader and shifted to longer wavelengths compared with those of the simple C 1 -C 3 sCIs as a result of the conjugation of the vinyl and carbonyl oxide groups (see the detailed discussion in the data sheets in Supplement Sect. B5).
6 Rate coefficients for thermal reactions of sCIs 6.1 Measurements of absolute rate coefficients for reactions of sCIs In recent years, numerous direct studies of the elementary reaction kinetics of sCIs have been reported. This has been made possible by two developments. First, the discovery of a novel fast photochemical source of sCIs, from the reactions of iodo-alkyl radicals with O 2 , has allowed generation of specific sCIs, following the photolysis of the corresponding di-iodoalkane (and recently, bromo-iodoalkene), as shown above in Sect. 5 for the example of CH 2 OO (Reactions R11 and R12). Second, direct time-resolved detection and measurements of sCI concentrations have been achieved using spectroscopic methods involving both tunable vacuum UV multiplexed photoionization mass spectrometry (MPIMS) and UV or IR absorption. The first breakthrough in these developments for direct studies of sCI kinetics came from the work of Taatjes and coworkers, who used MPIMS to monitor the time-resolved decay of CH 2 OO in the presence of bimolecular reaction partners such as SO 2 , NO and NO 2 . Subsequently it was shown that this technique for detection and production could be equally well applied to kinetics studies of the larger Criegee intermediates (e.g. Taatjes et al., 2013;Chhantyal-Pun et al., 2017b), so that structural effects on the basic oxidation rates and mechanisms could be explored directly.
The tunable light sources needed for MPIMS are not readily available for conventional laboratory rate constant measurements. The characterization of the strong absorption spectrum of CH 2 OO in the mid UV (Sheps, 2013) offered a second, more flexible and sensitive (but less specific) detection method for following sCI kinetics, which has the advantage of the ability to monitor sCI kinetics at up to 1 bar pressure, appropriate for lower atmospheric conditions. The UV absorption method is also applicable to the larger Criegee intermediates, produced from the same source chemistry (e.g. Sheps et al., 2014;Huang et al., 2015), and can provide kinetic-spectroscopic distinction of the Zand Econformers, where applicable.
The lower atmosphere contains many alkenes from both natural and anthropogenic sources, which react with O 3 to form Criegee intermediates with a wide variety of structures. Earlier work on ozone-alkene reactions gave little clue on the structural dependence of sCI reactivity with trace gases such as SO 2 , H 2 O, NO 2 and organics, or of their unimolecular decomposition rates. Direct kinetic studies have provided new information on the reaction rate constants and mechanisms of C 1 -C 3 sCIs formed from ozonolysis of simple alkenes. As indicated in Sect. 5.2, methods for the production and spectroscopic characterization of more complex isoprene-derived species are emerging (e.g. Barber et al., 2018;Vansco et al., 2018Vansco et al., , 2019, and these have provided the basis for their direct kinetics study (Caravan et al., 2020). However, direct experimental determinations of rate coefficients have not yet been reported for larger complex species (> C 4 ) derived, for example, from monoterpenes and sesquiterpenes.

Evaluation of rate coefficients for bimolecular reactions
As noted in Sect. 1, most of the information on the kinetics of sCI reactions up to 2006 was based on data obtained using indirect relative rate techniques. These were evaluated by the IUPAC Task Group on Atmospheric Chemical Kinetic Data Evaluation and published in ACP in 2006 (Atkinson et al., 2006). Since 2012, the direct kinetics studies described above have provided a wealth of new data on the elementary reaction kinetics and spectroscopy of sCIs. This has stimulated further competitive rate studies using static and slow-flow experiments in chambers to generate sCIs from O 3 + alkene reactions under atmospheric pressure and temperature conditions. In this evaluation, recommended rate coefficients are generally based on the results of direct kinetic studies of the sCIs, derived from di-iodoalkane precursors as described above (Sects. 5.2 and 6.1). However, the results of relative rate studies are also used to assess information on the kinetics and to check for consistency of the kinetic data for C 1 -C 3 sCIs, when they are produced by alkene ozonolysis. Table 5 provides a summary of the preferred values of bimolecular reaction rate coefficients, with additional details given in the corresponding reaction data sheets in Supplement B. As indicated in Sect. 1, the evaluation focuses on classes of reaction that are of particular significance in Table 4. Summary of the recommended spectral data for C 1 -C 3 sCIs.
Reaction ID a Reaction σ max σ max λ max λ range φ b cm 2 molec. −1 cm 2 molec. OH for the set of sCIs, with some additional reactions also considered for CH 2 OO. It is noted that data have been reported for some other classes of reaction (e.g. with alkenes and alcohols) that are uncompetitive under tropospheric conditions and some relative rate data are also available for large sCIs not considered here, e.g. as summarized in the compilation reported by Khan et al. (2018).
With the exception of the reactions of E-(CH=CH 2 )(CH 3 )COO with SO 2 and HC(O)OH (Caravan et al., 2020), there are currently no direct kinetics determinations for reactions of the C 4 sCIs derived from isoprene. In these cases, the recommendations are either inferred from those for the simpler C 2 and C 3 species and E-(CH=CH 2 )(CH 3 )COO or adopted from reported theoretical studies Chhantyal-Pun et al., 2017a). The performance of the ensemble of bimolecular reactions with SO 2 , H 2 O and (H 2 O) 2 (and unimolecular decomposition reactions) has been checked for consistency, using the results of published chamber and slow-flow experiments Newland et al., 2015b;Nguyen et al., 2016), as described in detail in data sheet CGI_21 (Supplement B). The results provide some confidence in these recommendations for use in practical applications, although the data also support some tolerance in the parameter values applied. Measurements of speciated sCI yields, and further direct kinetics studies of the rate coefficients and product channels for the reactions of the C 4 sCI isomers are therefore required to allow these recommendations to be confirmed or refined. Table 6 shows a summary of preferred values of unimolecular decomposition rate coefficients, k d , given in the corresponding data sheets in Supplement B. The evaluations are based on both consideration of direct time-resolved measurements, and those reported in relative rate experiments, where k d is determined relative to the loss rate of sCI via a well-defined competing bimolecular reaction. In the former case, k d is determined from observation of the decay kinetics of the Criegee intermediates themselves (or of a marker species) in the absence of a second reagent or by extrapolation of the observed first-order removal rate vs. reagent concentration plots to zero. Although unimolecular decomposition can make a major (or even the dominant) contribution to such limiting first-order removal rates, other processes also need to be taken into account (e.g. wall loss, reaction with impurity gases or diffusive loss from the monitoring probe area), as is usually discussed in the individual studies. In some cases, therefore, direct kinetics studies can only provide upper limit estimates of unimolecular decomposition rates for sCIs, particularly when the decomposition rate is slow. Relative rate determinations can also be influenced by background loss processes for the sCI (e.g. reaction with impurity gases or products), and reported rate coefficient ratios need to be placed on an absolute basis using the rate coefficient for the competing, reference bimolecular reaction, which itself has an associated uncertainty. In the present evaluations, the reference (bimolecular) rate coefficients are all based on the preferred values given in Table 5. As indicated above in Sect. 6.2, the recommendations for the unimolecular decomposition of C 4 sCIs derived from isoprene ozonolysis are adopted from the theoretical study of . These recommendations have been assessed, along with the recommended bimolecular rate coefficients for reactions with SO 2 , H 2 O and (H 2 O) 2 , using the results of published chamber and slow-flow experiments Newland et al., 2015b;Nguyen et al., 2016), as described in detail in data sheet CGI_21 (Supplement B).

Overall reactivity conclusions -comparison of experiment and theory
In addition to the progressive increase in the availability of experimental data, there have been substantial advances in the theoretical treatment of structure and reaction kinetics of sCIs in the gas phase (e.g. Olzmann et al., 1997;Zhang et al., 2002;Anglada et al., 2002Anglada et al., , 2011Ryzhkov and Ariya, 2004; 7.3 ×10 −10 ± 0.3 4.9 ×10 −18 T 2 exp(1620/T ) 240-340 ± 500 + CF 3 C(O)OH + 6.3 ×10 −10 * Rate coefficients for SO 2 reactions with Z-(CH=CH 2 )(CH 3 )COO, Z-(C(CH 3 )=CH 2 )CHOO and E-(C(CH 3 )=CH 2 )CHOO are inferred from those for E-(CH=CH 2 )(CH 3 )COO, Z-CH 3 CHOO and E-CH 3 CHOO, respectively. Temperature-dependent rate coefficients for H 2 O and (H 2 O) 2 reactions are adopted from the theoretical/ SAR methods reported by , as presented in Supplement Tables 35 and 40 of that paper. Individual parameters are not currently assigned uncertainties, but performance of ensemble of reactions (also including sCI decomposition reactions) was tested against reported O 3 + isoprene product observations (see data sheet CGI_21, Supplement B). Table 6. Summary of recommended rate coefficients for gas-phase unimolecular reactions of sCIs.  Table 31 of that paper (note that the exponent of the pre-exponential factor changed from 9 to 8 in the case of Z-(CH=CH 2 )(CH 3 )COO, for consistency with 298 K rate coefficient reported by . Individual parameters are not currently assigned uncertainties, but performance of the ensemble of reactions (also including sCI reactions with SO 2 , H 2 O and (H 2 O) 2 ) was tested against reported O 3 + isoprene product observations (see data sheet CGI_21, Supplement B). Kuwata et al., 2010;Vereecken et al., 2012Liu et al., 2014;Anglada and Solé, 2016;Long et al., 2016;Vereecken and Nguyen, 2017;Chhantyal-Pun et al., 2017a;Stephenson and Lester, 2020). Theoretical studies provided particular guidance prior to the advances in sCI production and detection methods for direct kinetics measurements, as described above. However, the body of experimental information now available for a series of sCIs allows the results of theoretical studies to be validated and for the methods to be refined, optimized and extended. This has included a comparison of experimental and theoretical unimolecular decay rates of a number of infra-red activated sCIs for a range of excitation energies (e.g. Fang et al., 2016Fang et al., , 2017Barber et al., 2018).

Reaction Reaction
In this section, the recommended rate coefficients for unimolecular decomposition and bimolecular reactions of the C 1 -C 3 sCIs with H 2 O and (H 2 O) 2 at 298 K and atmospheric pressure are compared with those derived from theoretical calculations (see Table 7). With the exception of the uni-   . d Based on the value at 1 bar reported by Long et al. (2016). e Value inferred from that for E-(CH=CH 2 )(CH 3 )COO. f IUPAC k value is adopted from , and each given entry is therefore identical to the SAR value shown. g Values for Z-and E-(C(CH 3 )=CH 2 )CHOO inferred from those for Z-and E-CH 3 CHOO, respectively. molecular decomposition of CH 2 OO, the calculated values are based on the high-pressure limiting values reported in the comprehensive study of , which presented theory-based structure-activity relationships (SARs) for 98 atmospherically relevant classes of sCI. Those for unimolecular decomposition reactions were derived from consideration of 14 reaction types (e.g. including the 1,4 H shift isomerization, 1,3 ring-closure and 1,5 ring-closure reactions discussed and illustrated in Sect. 4) for a benchmark series of sCIs containing key substituents, comprising a set of about 170 calculated rate coefficients. Those for the bimolecular reactions with H 2 O and (H 2 O) 2 were based on fitting theoryderived reactivity trends to a set of literature data, which included rate coefficients available at the time for the same set of C 1 -C 3 sCIs considered in the present evaluation. As a result, the absolute scaling of the theory-based SAR values cannot be considered to be entirely independent of our experimentally based evaluations for the H 2 O and (H 2 O) 2 reactions, although comparison of the (considerable) reactivity variation across the series of sCIs is valid.
The comparisons shown in Table 7 demonstrate that the theory-based SAR rate coefficients reported by  show a good level of consistency with our recommended rate coefficients for the reactions of the C 1 -C 3 sCIs. Both sets of parameters display a similar structural dependence across the series of sCIs. The rate coefficients for the bimolecular reactions with H 2 O and (H 2 O) 2 agree to within about a factor of about four (which is well within the combined uncertainties), where direct comparison is possible (i.e. for CH 2 OO and E-CH 3 CHOO), and where only an upper limit recommendation is possible in the present work (i.e. for Z-CH 3 CHOO and (CH 3 ) 2 COO), the SAR rate coefficient is fully compatible with that recommendation. This indicates a consistent structure-reactivity variation across the series, with systematically higher reactivities for the reactions of CH 2 OO and E-CH 3 CHOO with both H 2 O and (H 2 O) 2 .
The unimolecular decomposition parameters recommended in the present study for Eand Z-CH 3 CHOO and (CH 3 ) 2 COO are in very good agreement with the theory-based SAR values; being consistent with dominant 1,3 ring-closure to form a dioxirane intermediate for E-CH 3 CHOO, and dominant 1,4 H shift isomerization to form vinyl hydroperoxide intermediates for Z-CH 3 CHOO and (CH 3 ) 2 COO. In the case of CH 2 OO, the upper limit rate coefficient at 298 K and atmospheric pressure recommended in the present work is consistent with the value calculated by Long et al. (2016), which is about a factor of four lower than the calculated high-pressure limiting value (see data sheet CGI_12). Both the recommended and calculated values are sufficiently slow for unimolecular decomposition to be uncompetitive under tropospheric conditions. Also shown in Table 7 are representative lower tropospheric first-order loss rates (k I ) (at 298 K and atmospheric pressure) calculated for the same series of reactions using both sets of rate parameters; and for the bimolecu-lar reactions with SO 2 , based on the rate coefficients recommended here. The representative rates for the bimolecular reactions assume a mid-range relative humidity of 40 % (corresponding to [H 2 O] ≈ 3 ×10 17 molec. cm −3 and [(H 2 O) 2 ] ≈ 2 ×10 14 molec. cm −3 ), and an SO 2 concentration of 2.5 ×10 10 molec. cm −3 (about 1 ppbv), broadly typical of urban background air. Although these concentrations are only representative, the associated values of k I nevertheless give a clear indication that unimolecular decomposition is the dominant loss route for Z-CH 3 CHOO and (CH 3 ) 2 COO, consistent with a widespread role for 1,4 H shift isomerization for Zmonoalkyl-substituted and dialkyl-substituted sCIs possessing a β-hydrogen atom. In contrast, bimolecular reactions with H 2 O and/or (H 2 O) 2 are the dominant loss routes for CH 2 OO and E-CH 3 CHOO, and likely most other Emonoalkyl-substituted sCIs. The values of k I also give an indication that loss due to reaction with SO 2 generally only makes a minor contribution to sCI removal, away from the immediate vicinity of SO 2 sources, such that their ambient concentration is mainly controlled by either decomposition or reaction with H 2 O and/or (H 2 O) 2 .
The match between the experimentally based recommendations presented here and those derived from the theory-based SARs for this set of sCIs, gives some confidence that the SAR rate coefficients of  provide a very reasonable basis for representing the structural dependence of the kinetic parameters for unimolecular decomposition and bimolecular reactions with H 2 O and (H 2 O) 2 . In view of this, our corresponding recommendations for the more complex C 4 isoprenederived species (E-and Z-(CH=CH 2 )(CH 3 )COO and Eand Z-(C(CH 3 )=CH 2 )CHOO) are currently adopted from , as evaluated and discussed in detail in data sheet CGI_21 (Supplement B). The 298 K rate coefficients and representative first-order loss rates (k I ) are also shown for these C 4 sCIs in Table 7. The values of k I clearly demonstrate that bimolecular reactions cannot compete with the very rapid unimolecular decomposition of Z-(CH=CH 2 )(CH 3 )COO and Z-(C(CH 3 )=CH 2 )CHOO (via 1,5 ring-closure) under atmospheric conditions (and indeed most reported experimental conditions) and that decomposition of Z-(CH=CH 2 )(CH 3 )COO (via 1,4 H shift isomerization) is also likely to be its major loss route, by virtue of its slow bimolecular reactions with H 2 O and (H 2 O) 2 . In the case of E-(C(CH 3 )=CH 2 )CHOO, however, loss via unimolecular decomposition and bimolecular reactions with H 2 O and (H 2 O) 2 are predicted to occur at comparable rates, and experimental confirmation of the rate coefficients would be of particular value for this species.

Impact of Criegee intermediates in atmospheric oxidation chemistry
The kinetics and mechanistic information for sCI reactions recommended in the present evaluation provides the basis for representing the associated impact of alkene ozonolysis in atmospheric chemical mechanisms. The significance of sCIs as atmospheric oxidants can be discussed in terms of Eq.
(1), which defines the local balance between production and loss of sCIs, and hence their steady-state concentrations.
As described in more detail in Supplement C, the parameters recommended in this evaluation (supplemented by data from other sources) have been used to calculate surface production rates, loss rates and steady-state concentrations of a series of sCIs for average ambient conditions representative of rural background, suburban background and urban kerbside (urban traffic) locations in the south-eastern UK in both winter and summer. The calculations make use of measured or inferred concentrations of a series of C 1 -C 6 alkenes, isoprene, α-pinene, limonene, O 3 , NO 2 , SO 2 and HC(O)OH, in conjunction with H 2 O and (H 2 O) 2 concentrations based on modelled temperature and relative humidity data typical of the region. In this section, the key results are summarized and placed in context by comparison with reported results calculated for other locations, and in global modelling studies. Although the calculations presented here aim to take account of the most important production and loss routes, the estimates are inevitably subject to potential omissions and uncertainties in the sources and sinks of the sCIs (as discussed further in Sect. C4), in addition to uncertainties associated with the kinetic parameters and sCI yields, as discussed in earlier sections and in the data sheets in Supplements A and B.

sCI production rates
The formation of a series of 28 C 1 -C 10 sCIs from the speciation of 19 precursor alkenes was represented in the present calculations (see Supplement C for full details). The core set of C 1 -C 4 sCIs specifically considered in the present evaluation collectively makes an important contribution to the total production rate at each of the three locations; the respective winter and summer contributions lying in the ranges 88 %-91 % and 45 %-86 % (see Table 8). The speciation of this core set of sCIs is also presented in Fig. 4 for the example of the rural background location (Chilbolton Observatory). The formation of Eand Z-CH 3 CHOO is most significant because they are formed from propene and all the alk-2-enes in the applied speciation. They are also favoured because reaction with O 3 is a major (and sometimes the dominant) removal route for alk-2-enes (and other internal alkenes) because of their particularly rapid reactions with O 3 (see Table 1). CH 2 OO also makes a notable contribution to the totals because it is formed from all the alk-1-enes and isoprene. The higher alkyl-substituted sCIs make systematically lower for the core set of C 1 -C 4 sCIs for representative rural background conditions in the south-eastern UK. Note that the information is presented on log scales, with cut-offs of 10 molec. cm −3 s −1 and 1 molec. cm −3 , respectively. The total sCI production rates and concentrations are given in Table 8. Results for an extended series of 28 sCIs, and for suburban and urban traffic conditions, are presented in Supplement C.
contributions, primarily because their precursor alkenes have systematically lower abundances (see Table 8). As also shown in Table 8, sCIs formed from biogenic hydrocarbons logically make an increased and important collective contribution under the summer conditions. This is particularly the case at the suburban background location (London Eltham), which has a mixture of trees and other vegetation in close proximity to the measurement site. The monoterpene-derived (α-pinene and limonene) sCIs are calculated to be particularly significant because ozonolysis generally makes a major contribution to the removal of endocyclic alkenes, by virtue of their particularly rapid reactions with O 3 (see Table 1). In contrast, the reaction of O 3 with isoprene is comparatively slow, its dominant removal reaction being with HO radicals. Therefore, the production rates of the isoprene-derived sCIs are approaching an order of magnitude lower than those of the monoterpene-derived sCIs under the conditions represented here. However, isoprene-derived sCIs have been shown to make more important contributions globally, particularly in specific regions such as the Ama-  Fig. 2, for which evaluated rate parameters have been presented in Sect. 6. e Comprises E-and Z-C 2 H 5 CHOO, E-and Z-n-C 3 H 7 CHOO, E-and Z-i-C 3 H 7 CHOO, E-and Z-n-C 4 H 9 CHOO, E-and Z-(C 2 H 5 )(CH 3 )COO, and E-and Z-(CH=CH 2 )CHOO formed from the C 4 -C 6 alkenes considered (see Supplement C). f Comprises eight pinonaldehyde oxide and limononaldehyde oxide isomers formed from the monoterpenes α-pinene and limonene (see Supplement C). g Specifies the contribution to the total SO 2 or HC(O)OH oxidation rate due to reaction with sCIs.
zonian rainforest (e.g. Khan et al., 2018), as a result of the dominant contribution of isoprene to global biogenic VOC emissions.

sCI loss rates
Based on the information presented and discussed in Sects. 6 and 7, sCI removal by unimolecular decomposition and bimolecular reactions with H 2 O, (H 2 O) 2 , NO 2 , SO 2 and HC(O)OH was taken into account. Table 8 and Fig. 5 present information on the speciated and total first-order loss rates of the sCIs, and the contributions made by the series of removal reactions considered. Consistent with the analysis presented in Sect. 7, the results confirm that the major loss routes for most of the sCIs are either thermal decomposition or reaction with (H 2 O) 2 , supplemented by reaction with H 2 O. As a result, these reaction classes dominate total sCI removal under all conditions, with reaction with (H 2 O) 2 and H 2 O being slightly more important in the winter, and thermal decomposition being slightly more important in the summer, based on the average of the three sites. As also indicated in Sect. 7, thermal decomposition tends to dominate the removal of Zmono-substituted and di-substituted sCIs, with reaction with (H 2 O) 2 and H 2 O dominating the removal of CH 2 OO and Emono-substituted sCIs. Figure 5. Contributions of the unimolecular and bimolecular removal routes for the core set of C 1 -C 4 sCIs under winter conditions (a) and summer conditions (b) for representative rural background conditions in the south-eastern UK. The data label shows the total removal rate (in s −1 ) for the given sCI. Results for an extended series of sCIs, and for suburban and urban traffic conditions, are presented in Supplement C.
The total first-order loss rates for the individual sCIs lie in an approximate range of 20 to 20 000 s −1 for the full series of considered conditions (see Supplement C). Those toward the low end of the range generally correspond to sCIs for which the dominant removal route is 1,4 H atom migration, occurring at only a modest rate (e.g. in the cases of Z-CH 3 CHOO and E-(CH=CH 2 )(CH 3 )COO), particularly under winter conditions, and for which the reactions with (H 2 O) 2 and H 2 O are very slow. Those at the high end of the range generally correspond to Emonosubstituted sCIs (e.g. E-CH 3 CHOO) for which the dominant removal reactions with (H 2 O) 2 and H 2 O are very fast. The associated loss rates for selected sCIs in the former category are sufficiently slow for removal by reaction with HC(O)OH and SO 2 (and to a lesser extent, reaction with NO 2 ) to make a notable contribution (e.g. E-(CH=CH 2 )(CH 3 )COO in Fig. 5). In collective terms, however, these classes of reaction each make only a small (< 4 %) contribution to total sCI removal under the series of conditions considered here, as shown in Table 8.

Steady-state concentrations and speciation
The total first-order sCI loss rates indicated above correspond to individual sCI lifetimes lying in the range 50 µs to 50 ms, confirming that calculation of their concentrations using the steady-state approximation, described by Eq. (1), is valid. The resultant calculated steady-state concentrations of the core set of C 1 -C 4 sCIs for the rural background conditions are shown in Fig. 4, with the total sCI concentrations for the three scenarios given in Table 8. The totals calculated for the rural background conditions (386 and 375 molec. cm −3 for winter and summer, respectively) are broadly consistent with the low annual average values simulated for the UK in the global modelling calculations of , and the concentrations calculated for the series of locations and conditions (up to about 1100 molec. cm −3 ) are comparable with those reported by Khan et al. (2018), based on similar UK calculations to those reported here.
The distributions of sCIs are generally dominated by a limited number of individual species and show similarities to those reported elsewhere for locations with significant anthropogenic VOC emissions (e.g. . Z-CH 3 CHOO is the most abundant sCI for all the considered scenarios, accounting for 75 %-79 % of the totals for winter conditions, and 25 %-77 % of the totals for summer conditions. This results from the combination of its high production rate (see Fig. 4) and its relatively slow removal rate (see Fig. 5), as discussed above. Its lowest contribution occurs for summer conditions at the suburban location, when the sCIs derived from α-pinene and limonene (and to a lesser extent, isoprene) are collectively dominant (67 %), as discussed in more detail in Supplement C. Given the relatively low biogenic hydrocarbon emission rates in the UK, this result for a suburban location in London gives a strong indication that biogenic hydrocarbon-derived sCIs will dominate the global concentrations, as clearly demonstrated in the modelling studies presented by  and Khan et al. (2018). Those studies reported important and widespread global contributions from sCIs derived from both isoprene and monoterpenes, although they report substantially different sCI concentrations. In the work of , the rapid unimolecular decomposition rates calculated for many of the of sCIs (as also adopted in the present work) strongly suppress the simulated concentrations compared with those reported by Khan et al. (2018). The resultant annual average sCI concentration at the surface maximizes at 7 ×10 3 molec. cm −3 over the Amazon basin but is generally less than 2 ×10 3 molec. cm −3 over most of the globe . This further emphasizes the need for direct kinetics studies of a structurally diverse series of isoprene and terpene-derived sCIs to help validate and refine the rate coefficients calculated in theoretical studies.

Oxidation of SO 2 and organic acids
The speciated sCI distributions have also been used to calculate the associated SO 2 oxidation rates. As shown in Table 8, the total oxidation rates are calculated to be between 0.006 % h −1 and 0.028 % h −1 . They broadly follow the simulated trend in total sCI concentrations but also reflect that the rate coefficient values for individual species span almost an order of magnitude. These oxidation rates can be compared with a reference SO 2 oxidation rate of about 0.3 % h −1 for reaction with HO radicals at a concentration of 10 6 molec. cm −3 . This comparison is therefore consistent with the < 10 % annual average contribution to gas-phase SO 2 oxidation for the UK, reported in the global modelling calculations of  and Khan et al. (2018). The more widespread potential role of biogenic hydrocarbon derived sCIs in global SO 2 oxidation has also been considered in those modelling studies. Although the results possess some similarities, in terms of the relative regional variation, their role is much more limited in the  calculations because of the high calculated decomposition rates applied to many of the sCIs and the resultant suppression of sCI concentrations commented on above. Nevertheless, annual average contributions of up to about 70 % were still simulated for the terrestrial equatorial belt.
The largest bimolecular rate coefficients for sCI reactions that have been measured experimentally are those for reactions with organic acids such as HC(O)OH, CH 3 C(O)OH and CF 3 C(O)OH (see Table 5). HC(O)OH and CH 3 C(O)OH are present in the troposphere in significant concentrations (e.g. Andreae et al., 1988;Millet et al., 2015;Bannan et al., 2017) due in part to their formation in the photochemical oxidation or ozonolysis of many VOCs, from both anthropogenic and natural sources. As discussed above and shown more widely in the calculations of , the reactions with organic acids can make small but significant contributions to sCI removal in some regions. The total sCI concentrations calculated here suggest associated oxidation rates of (0.04-0.11) % h −1 for HC(O)OH and similar rates for CH 3 C(O)OH. This can be compared with reference oxidation rates of about 0.16 % h −1 and 0.25 % h −1 for the reaction of HC(O)OH and CH 3 C(O)OH with HO radicals at a concentration of 10 6 molec. cm −3 . This indicates that reaction with sCIs makes an important contribution to the oxidation of these acids under the conditions considered here, with oxidation rates comparable to those via HO reaction calculated for equatorial regions in the global modelling study of . It is noted that the reactions of larger sCIs and organic acids (e.g. derived from the ozonolysis of monoterpenes and sesquiterpenes) potentially form highly oxidized, low-volatility products (hydroperoxyl-esters), which may play a role in secondary organic aerosol (SOA) formation (e.g. Tobias and Ziemann, 2001;Chhantyal-Pun et al., 2018). Table 5, the reactions of sCIs with CF 3 C(O)OH are particularly rapid. The total sCI concentrations calculated here suggest an associated oxidation rate of (0.1-0.3) % h −1 for CF 3 C(O)OH, compared with 0.25 % h −1 for its reaction with HO radicals at a concentration of 10 6 molec. cm −3 . This demonstrates the potential importance of sCIs as gas-phase oxidants for CF 3 C(O)OH (and other perfluoro-carboxylic acids, C n F 2n+1 C(O)OH) over land masses. However, it is noted that the reaction of the resultant hydroperoxyl-fluoroester products with HO radicals probably reforms the perfluoro-carboxylic acids on a timescale of 1-2 d (Taatjes et al., 2019).

As shown in
Current understanding of the atmospheric chemistry of sCIs therefore supports the original hypothesis of Penkett (1971, 1972) regarding their potential importance as atmospheric oxidants, identified from chamber measurements of SO 2 oxidation associated with alkene ozonolysis, and the observed effect of relative humidity on the oxidation rates. Considerable progress has since been made in the understanding of the kinetics and mechanisms of alkene ozonolysis, resulting from both experimental and theoretical studies, with particular advances since the pioneering work of Taatjes and co-workers less than a decade ago (e.g. Welz et al., 2012;Taatjes et al., 2013) in the detection of sCIs and direct measurements of the kinetics of their reactions. However, significant uncertainties remain in some aspects of mechanistic understanding, including measurements of the yields of sCIs and their speciation in asymmetric alkene systems. The current evaluation has focused primarily on those sCIs for which direct kinetics measurements are available (i.e. CH 2 OO, E-CH 3 CHOO, Z-CH 3 CHOO and (CH 3 ) 2 COO), with some consideration also given to the C 4 intermediates formed from isoprene. Whilst these represent an important subset of atmospheric sCIs, it is recognized that an enormous variety of sCIs are generated, with particularly important global contributions from those generated from the ozonolysis of monoterpenes and sesquiterpenes. The concurrent progress in the theoretical treatment of the structure and reaction kinetics of sCIs in the gas phase has allowed the development of theory-based structure-activity relationships (SARs) , which provide a basis for representing the reactions of structurally complex sCIs in atmospheric mechanisms. As a result, there is a need for direct kinetics studies of a structurally diverse series of isoprene and terpene-derived sCIs to help validate and refine the rate coefficients calculated in theoretical studies. In addition, the continued development of sensitive detection methods for sCIs (e.g. Berndt et al., 2017) that may eventually allow sCI concentrations to be measured in the field would be valuable for evaluation and testing of the representation of sCI sources and sinks in atmospheric models. Data availability. All relevant data and supporting information have been provided in the Supplement. The detailed reaction data sheets are also available at the IUPAC Task Group on Atmospheric Chemical Kinetic Data Evaluation website: http://iupac.pole-ether. fr/ (IUPAC, 2020).
Author contributions. All authors defined the scope of the work. RAC, MEJ and TJW developed and drafted the data sheets and manuscript. All authors reviewed, refined, and revised the data sheets, and all sections of the manuscript and Supplement.