ACPAtmospheric Chemistry and PhysicsACPAtmos. Chem. Phys.1680-7324Copernicus PublicationsGöttingen, Germany10.5194/acp-18-9411-2018Impact of long-range transport over the Atlantic Ocean on Saharan dust
optical and microphysical properties based on AERONET dataImpact of long-range transport over the Atlantic OceanVelasco-MerinoCristianMateosDavidhttps://orcid.org/0000-0001-5540-4721ToledanoCarlostoledano@goa.uva.eshttps://orcid.org/0000-0002-6890-6648ProsperoJoseph M.MolinieJackhttps://orcid.org/0000-0002-2813-7186Euphrasie-ClotildeLovelyhttps://orcid.org/0000-0002-6860-8886GonzálezRamirohttps://orcid.org/0000-0003-0017-5591CachorroVictoria E.CalleAbelde FrutosAngel M.Grupo de Óptica Atmosférica, Dpto. de Física Teórica
Atómica y Óptica, Universidad de Valladolid, Valladolid, SpainCooperative Institute for Marine and Atmospheric Studies, Rosenstiel
School of Marine and Atmospheric Science, University of Miami, Miami,
Florida, USALaboratory of Geosciences and Energy, Université des Antilles,
Pointe-à-Pitre,
Guadeloupe, FranceCarlos Toledano (toledano@goa.uva.es)5July201818139411942423November201720December201724May201810June2018This work is licensed under the Creative Commons Attribution 4.0 International License. To view a copy of this licence, visit https://creativecommons.org/licenses/by/4.0/This article is available from https://acp.copernicus.org/articles/18/9411/2018/acp-18-9411-2018.htmlThe full text article is available as a PDF file from https://acp.copernicus.org/articles/18/9411/2018/acp-18-9411-2018.pdf
Arid regions are a major source of mineral dust aerosol.
Transport from these sources can have a great impact on aerosol climatology
in distant regions. In order to assess the impact of dust on climate we must
understand how dust properties change after long distance transport from
sources. This study addresses the changes in columnar aerosol properties when
mineral dust outbreaks from western Africa arrive over the eastern Caribbean
after transport across the Atlantic Ocean, a transit of 5–7 days. We use
data from the NASA Aerosol Robotic Network (AERONET) located at five
Caribbean and two western Africa sites to characterize changes in columnar
aerosol properties: aerosol optical depth (AOD), size distribution, single
scattering albedo, and refractive indexes. We first characterized the local
aerosol climatology at each site and then using air mass back trajectories we
identified those days when trajectories over Caribbean sites back-tracked to
western Africa. Over the period 1996–2014 we identify 3174 days, an average of
167 days per year, when the air mass over the Caribbean sites could be linked
to at least one of the two western Africa sites. For 1162 of these days, AOD
data are available for the Caribbean sites as well as for the corresponding
western Africa sites about 5–7 days earlier, when the air mass passed over
these sites. We identified dust outbreaks as those air masses yielding
AOD ≥ 0.2 and an Ångström exponent below 0.6. On this basis of
the total 1162 days, 484 meet the criteria for mineral dust outbreaks. We
observe that the AOD at 440 nm decreases by about 0.16 or 30 % during
transport. The volume particle size distribution shows a similar decrease in
the volume concentration, mainly in the coarse mode. The single scattering
albedo, refractive indexes, and asymmetry factor remain unchanged. The
difference in the effective radius over western Africa sites with respect to
Caribbean sites ranges between 0 and -0.3 µm. Finally we conclude
that in about half of the cases only non-spherical dust particles are present
in the atmosphere over the western Africa and Caribbean sites, while in the other
cases dust particles were mixed with other types of aerosol particles.
Introduction
Mineral dust is one of the most abundant aerosol types in the global
atmosphere and as such it could play an important role in climate. Mineral
dust absorbs and scatters terrestrial and solar radiation and thus affects
the Earth's radiation budget (Choobari et al., 2014). Dust is also involved
in cloud microphysical processes which in turn affect radiation properties
and the hydrological cycle (Karydis et al., 2017; DeMott et al., 2010). Dust
also serves as a major source of nutrients for ocean and terrestrial
ecosystems and in this way dust deposition can impact the carbon cycle
(Jickells et al., 2005). All these processes could have a significant impact
on climate. Given the importance of dust there is a need to understand the
factors affecting African dust source activity, the properties of the
dust so produced, and how those properties change during transport. Africa is
the world's largest dust source, estimated to produce over half the global
total (Huneeus et al., 2011). Much African dust is transported to the west
and significant quantities reach South America (Prospero et al., 2014; Yu et
al., 2014, 2015), the Caribbean Sea (Prospero and Lamb, 2003), and southern
United States (Bozlaker et al., 2013).
Studies of the dust transport from Africa to the Americas have been carried
out using meteorological information linked to in situ and satellite aerosol
data (e.g., Jickells et al., 2005; Rodríguez et al., 2015; García
et al., 2017). Recently developed techniques such as MACC (Monitoring
Atmospheric Composition and Climate; Chouza et al., 2016) or MOCAGE
(Modélisation de la Chimie Atmosphérique Grande Echelle; Martet et
al., 2009) models have been also used to monitor dust plumes.
AERONET sites in the Caribbean area (a) and
western Africa region (b). For acronyms see Table 1.
Long-term (e.g., Prospero and Lamb, 2003; Prospero and Mayol-Bracero, 2013)
and short-term (e.g., Reid et al., 2003; Colarco et al., 2003; Kaufman et
al., 2005; Valle-Díaz et al., 2016) studies show a seasonal dependence
in the intensity of dust transport to the Caribbean with the greatest
transport in boreal summer. In the SALTRACE program (Weinzierl et al., 2017)
an aircraft was used to carry out atmospheric column closure experiments
performed in June and July 2013 at western Africa and Caribbean sites. A unique
Lagrangian in situ study was carried out in SALTRACE wherein a dusty air mass
was sampled aboard an aircraft over the islands of Cabo Verde and again 5
days later over Barbados, a distance of more than 4000 km. They measured a
distinct change in particle size during transit across the Atlantic and noted
that the removal rate of large super-micron particles was slower than
expected based on simple sedimentation calculations (Weinzierl et al., 2017).
Similar results had been obtained on comparisons between surface based
measurements at sites in the Canary Islands and Puerto Rico (Maring et al.,
2003).
Geographical coordinates, considered time period, and total number of
level 2.0 AOD daily data from the different AERONET sites used for the global
African and Caribbean databases. To highlight the number of available
inversion products, the number of daily data of volume particle size
distribution (VPSD) is presented.
AreaSiteCoordinatesTime periodNumber of AOD/(∘ N, ∘ E, m a.s.l.)VPSD daily dataAFCapo_Verde (CV)(16.71, -22.93, 60)1993–20144635/1910Dakar (DK)(14.38, -16.95, 0)1996–20143593/2466CARBarbados (BA)(13.15, -59.62, 114)1996–2000938/50Barbados_SALTRACE (BA)(13.15, -59.62, 114)2013–2014181/7Ragged_Point (RG)(13.15, -59.42, 40)2007–20141768/415Guadeloup (GU)(16.22, -61.53, 39)1997–20141949/441La_Parguera (LP)(17.97, -67.03, 12)2000–20143303/1467Cape_San_Juan (SJ)(18.38, -65.62, 15)2004–20141901/401
Our study is inspired by that experiment, although our approach is to use
columnar aerosol data collected from CIMEL sun photometers of the AERosol
RObotic NETwork (AERONET) in two areas, western Africa and on islands in the
eastern Caribbean. The temporal coverage of the AERONET data is large in both regions, 19 years from 1996 to 2014. Therefore, the aim of this work is to
investigate the changes in dust optical and microphysical properties due to
the long-range transport, by comparing AERONET observations in western Africa
and the Caribbean sites using a climatological approach.
In Sect. 2 we present an overview of the database and methodology used to
match daily averaged AERONET data at both sides of the Atlantic Ocean using
air mass backwards trajectories. Section 3 describes, separately, the
long-term aerosol climatology observed at the western Africa and the Caribbean
sites and the correlation between aerosol optical depth (AOD) and dust concentration observed at the
Caribbean sites. Section 4 presents the monthly variability of size-related
aerosol parameters. Section 5 presents the seasonality of African–Caribbean
Sea air mass connections, as well as the change in aerosol optical depth,
size distribution, and single scattering albedo, among others after the
long-range transport. Finally the conclusions are presented in Sect. 6.
Database and methodologyAERONET measurements and sites
The main database for this study includes the daily mean values of columnar
aerosol data measured by CIMEL CE-318 Sun photometer in the AERONET framework
(Holben et al., 1998). The direct sun algorithm provides a database that
contains instantaneous values (every 15 min) of spectral AOD at
7 wavelengths in the range 340–1020 nm (in some cases also 1640 nm
depending on the instrument model) and the associated Ångström
exponent (AE) based on the wavelengths 440 and 870 nm. We only use AOD and
AE quality-assured cloud-screened level 2.0 data (version 2) which ensures
the reliability of the measurements (see
http://aeronet.gsfc.nasa.gov/new_web/PDF/AERONETcriteria_final1.pdf;
last access: 18 June 2018). In this work we
use only the 440 nm measurements. Figure 1 and Table 1 present the five
AERONET sites in the Caribbean (CAR) area and the two sites in the western Africa (AF) region chosen in this study.
In addition the CIMEL instrument takes hourly measurements of sky radiances in
almucantar geometry at certain wavelengths in the range 440–1020 nm (in
some cases also 1640 nm; number of wavelengths depends on the instrument
model). The sky radiances, together with the AOD, are used to derive optical
and microphysical properties of the aerosol using inversion procedures
(Dubovik et al., 2006). The inversion-derived parameters used in this study
are volume particle size distribution (dV(r)/dln(r); VPSD) and the volume concentration for the fine, coarse, and total size
distribution (VCF, VCC, VCT,
respectively), sphericity fraction (SF), total effective radius
(ERT), real part of the refractive index (REFR), imaginary part
of the refractive index (REFI), single scattering albedo (SSA), and asymmetry
parameter (g).
The Level 2 inversion requirement rejects AOD values less than 0.4 which
dramatically reduces the amount of data. In order to increase the number of
measurements in the data set we used level 1.5 inversion products but we
applied an extra level of quality control to ensure the reliability of the
inversion data:
VPSD and ERT: same as AERONET level 2.0 criteria (solar
zenith angle > 50∘, number of symmetrical angles, and sky
error between 5 and 8 % depending on AOD; see above), but without
threshold with respect to AOD.
SSA, g, REFR, REFI, and SF: same as AERONET level 2.0 criteria but with AOD ≥ 0.20 (see Dubovik et al., 2006; Mallet et al., 2013; Mateos et al.,
2014) instead of > 0.4.
The use of level 1.5 filtered data with an extra quality control has been
previously used by other authors (e.g., Burgos et al., 2016) with minor loss
of accuracy (Mateos et al., 2014). All the available inversion products are
daily averaged in this study. With the threshold of AOD ≥ 0.2, estimated
uncertainty for dust retrievals of the single scattering albedo is 0.03, REFR
is 0.04, REFI is 50 %, and the VPSD is 35 % (see Dubovik et al.,
2000). The climatology of key aerosol properties measured at western Africa and
Caribbean sites is addressed in Sect. 3. All daily available records (see
Table 1) at the two western Africa and five Caribbean sites are averaged in the
1996–2014 period, resulting in two databases with 5656 and 5099 days of data,
respectively.
Linkage between Caribbean and western Africa by air mass
back trajectories
All the air mass links between western Africa and Caribbean sites are
examined. This task requires separate analysis for each Caribbean site.
For example, the methodology used in this study for Barbados is the
following:
Step 1: We calculated three-dimensional 10-day back trajectories with
1 h time resolution using the Hybrid Single Particle Lagrangian Integrated
Trajectory (HYSPLIT) model version 4.0 (Stein et al., 2015). The geographical
coordinates used as the start point for Barbados are presented in Table 1. As
mineral dust can be transported at altitude levels higher than the boundary
layer, most notably in the Saharan Air Layer (SAL; Carlson and Prospero, 1972; Yu
et al., 2014; Groß et al., 2016), back trajectories were calculated at
750, 2500 and 4500 m (a.g.l.). The core of the SAL is typically at around
2500 m. For the trajectory vertical motion, we used the model vertical
velocity. The meteorological database used as input for HYSPLIT is the global
NCAR/NCEP Reanalysis (Kalnay et al., 1996). The evaluation is
performed for each day in the period 1996–2014 at 16:00 UTC (around local
noon).
Step 2: If any of these trajectories for Barbados (at one, two or
three heights) passes through a 3∘× 3∘ box centered
on the western Africa sites, we consider that a link has been established
between the two sites. The transit time is typically about 5–7 days. In some
cases an air mass back trajectory may link both the Capo_Verde and Dakar
boxes. In such cases the mean of the aerosol observations is used.
Step 3: Once the dates in which the air mass is measured in Barbados
and in Capo_Verde or Dakar (or both) sites are established, the associated
AERONET aerosol data are identified. In the case of Barbados site, the
corresponding daily means of all AERONET products are used. However, the western Africa site analysis requires a special procedure. The visual inspection of
many of the cases shows that the aerosol records for the specific date
obtained in the trajectory analysis often fell on a day without data (e.g.,
due to cloudy or rainy conditions) or did not capture the central days of the
dust event. To resolve this problem, we introduced a ±1-day adjustment to
the back-trajectory-estimated date at Capo_Verde and Dakar. This is in line
with previous studies which state that desert dust episodes in western Africa
sites usually last for several days (e.g., Knippertz and Stuut, 2014). The
aerosol values for each western Africa site are therefore averaged over the
3 days (the estimated date and ±1 day). For the Barbados–African
cases with air masses overflowing both Capo_Verde and Dakar sites, the
corresponding average of aerosol data is used.
These three steps described above are applied to all Caribbean sites as shown
in Table 1. This methodology yields five databases (one per site) in which
each Caribbean site is linked with data for western Africa sites. For each day
between 1996 and 2014 we determine which Caribbean sites present an air mass
link with western Africa sites. If more than one western Africa site yields a link for
a specific Caribbean event, we use the mean properties as discussed above.
We identify a desert dust event on the basis of the following criteria:
AOD ≥ 0.2 and AE ≤ 0.6 (e.g., Dubovik et al., 2002; Guirado et
al., 2014). In the evaluated global Caribbean–African linked database, the
Caribbean and African data are analyzed separately. Hence, there are two
different inventories that contain all days meeting the criteria for mineral
dust events over the Caribbean and western Africa sites. In the global database
there are, therefore, three different cases which are extensively analyzed in
Sect. 5:
DAF+DCAR: desert dust conditions occur in both
Caribbean and western Africa sites;
DAF+ NoDCAR: dust conditions in western Africa sites but no-dust
condition at the Caribbean sites;
NoD: no-dust conditions or dust conditions at the Caribbean sites with unproven origin.
We found a total of 3174 days with connections between western Africa and
Caribbean sites. Only 1162 out of 3174 days yielded AERONET data (level 2.0)
for AOD and AE. Of these 1162 acceptable days, 484 meet the criteria for
mineral dust outbreaks (AOD ≥ 0.2 and AE ≤ 0.6,
“DAF+DCAR” case). However for the analysis of
microphysical and radiative properties, the number of matching inversion data
is much smaller (just 71 cases) because of the more stringent requirements.
The frequent cloudiness at the Caribbean sites is the main difficulty in the
inversion of sky radiances (see Table 1).
Monthly average of AOD and AE from 1996 to 2014 in the
western Africa area. The number of daily means used in the multi-annual averages is
5656.
Seasonal variability of aerosol load at the western Africa and Caribbean
sites
In this section the analysis of the monthly seasonal cycle of the main
aerosol properties at the Caribbean and western Africa sites is presented
separately since there is no requirement that trajectories connect the
sites. This section summarizes overall multi-year statistics (from 1996 to
2014) of AOD, AE, and VPSD quantities.
Figures 2 and 3 present the multiannual AOD and AE monthly averages of
19 years in western Africa and Caribbean regions, respectively. There is a
significant difference between the “cold” (October–April) and “warm”
(May–September) seasons in both areas.
Monthly average of AOD and AE in the Caribbean area from 1996 to
2014 and surface dust concentrations in Barbados in the period 1996–2011.
The number of daily means used in the multi-annual averages is 5099 for
AODCAR and AECAR and 5167 for surface dust
concentration in Barbados.
Scatter plot of (a) monthly and (b) interannual
monthly means of surface dust concentration and AOD in the Caribbean Basin in
the period 1996–2011. Solid line indicates the linear fit between both
quantities and R indicates the correlation coefficient.
Monthly averages of the volume particle size distribution
(dV(r)/dln(r)) from 1996–2014 in western Africa
(a) and Caribbean (b) areas.
In the winter season there is a weak variation of AOD and AE at the western Africa sites (see Fig. 2) with values around 0.3 and 0.3–0.5, respectively.
In contrast in the summer season there is an increase of AOD together with a
decrease of AE until June when the maximum of AOD (0.6) coincides with a
minimum of AE (0.16). The AOD peak was also observed by, e.g., Tegen et
al. (2013). After June there is a progressive decrease of AOD values and
increase in AE until once again reaching winter levels. Overall, the large
AOD and low AE values suggest dominant effect of coarse particles in dust
episodes. The ranges of AOD between 0.3 and 0.6 and AE below 0.5 were also
obtained by previous studies in western Africa sites (e.g., Dubovik et al.,
2002; Horowitz et al., 2017). Haywood et al. (2008), Derimian et al. (2008),
and Leon et al. (2009) reported that M'Bour site (western Senegal, 70 km away
from Dakar) is strongly influenced by desert dust throughout the year.
The effects of biomass burning are seen in November and December when AE
reaches its maximum of about 0.5; this is the time of year when biomass
burning is at a maximum in the Sahel.
The annual cycle of AOD at the Caribbean sites (see Fig. 3) shows a bell
shape with the maximum in June (AOD = 0.3) and the minimum values in
December–January. In contrast, the AE displays a larger variability along the
year: an increase from January to April when AE = 0.7 (the annual
maximum), followed by a steady sharp decline until the absolute minimum in
June–July with AE = 0.26. Levels remain constant around 0.55 from
September to December. These features in the AOD and AE seasonality can be
understood as the fingerprint of the occurrence of mineral dust transport
from Africa. The AE variability evidenced by the standard deviations is
largely driven by the changes in aerosol mixture that occur in this area
(e.g., Reid et al., 2003). Clean maritime conditions, associated with
background values, have low AOD and low AE (Smirnov et al., 2000), but they
can be modified by mineral dust outbreaks from African deserts and biomass
burning episodes. In particular, the large change in AE in the cold
season is largely due to the advection of pollutant aerosols from higher
latitudes (e.g, Savoie et al., 2002; Zamora et al. 2013).
Previous work (e.g., Smirnov et al., 2000) has shown that high concentrations
of dust at the surface are correlated with high column optical depths
measured by a collocated AERONET instrument. Yu et al. (2014) has shown that
CALIPSO (Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations)
dust concentrations over Barbados track the surface-based measurements of
dust. In Fig. 3 we show the relationship between the long-term measurements
of dust concentrations at the surface with the columnar aerosol load
manifested in AOD. We use the surface dust concentration measured at the Ragged
Point site, Barbados (e.g., Prospero and Lamb, 2003; Prospero and Mayol,
2013) between 1996 and 2011. Daily surface dust concentrations are obtained
with high-volume filter samplers using measured aluminum concentrations and
assuming an Al content of 8 % in soil dust (e.g., Prospero, 1999) or from
the weights of filter samples ashed at 500 ∘C after extracting
soluble components with water (Prospero, 1999; Prospero et al., 2014; Savoie
et al., 2002).
Surface dust concentration seasonal cycle (Fig. 3) presents a significant
increase between low values during October–April season up to larger
concentrations in May–September season. Overall, the shapes of the annual
cycles of AOD and surface dust concentration at Barbados are similar and the
same seasonal pattern in both variables is observed.
Monthly mean AOD is highly correlated with surface dust concentrations as
shown in Fig. 4 which is based on 3700 pairs of daily data, a total of
192 monthly mean values, and 12 interannual monthly mean values, the latter
calculated as the average of the available daily data from the same month
over a multi-annual period. The seasonal distribution of the surface–columnar
values seems to follow a linear increasing pattern from winter (bluish
colors) to summer (reddish colors). The slope of the fit between dust
concentration and AOD is about 115 µg m-3 per unit of AOD for
the two cases analyzed here: using 192 monthly means (Fig. 4a) and
12 interannual monthly means (Fig. 4b). The Barbados dust concentration vs.
AOD shows very good correlation when the same months are averaged along the
years. However, the monthly agreement between these two variables displays a
certain degree of dispersion with a moderate correlation coefficient. The
positive intercepts on AOD in the fits are most likely attributable to the
effects of sea salt aerosol on AOD.
Monthly variability of size-related aerosol parameters
Figure 5 displays the average monthly cycle of the volume particle size
distribution (VPSD) for the western Africa and Caribbean sites, respectively.
These figures are based on 3346 and 2165 daily mean values of the AERONET
inversion products selected as described above.
The coarse-mode predominance can be observed throughout the year in both
areas. The seasonal cycle of VPSD in western Africa sites (Fig. 5a) shows a
clear change of coarse-mode concentration throughout the year, although the
coarse-mode effective radius does not change, with peak concentration
of about 2 µm. The coarse-mode concentration ranges
between maximum values in June with
0.32 µm3µm-2 and minima in November–December
with 0.05 µm3µm-2. In terms of volume
concentration the fine mode plays an almost negligible role throughout the
year for the DAF+DCAR cases. This seasonal
pattern was already reported by previous studies at the western Africa sites
(e.g., Dubovik et al., 2002; Eck et al., 2010; Guirado et al., 2014). These
studies showed the domination of large particles (i.e., radius greater than
0.6 µm) with VPSD peaks in the coarse mode at 2 µm, which
are independent of the aerosol load.
Seasonal cycle of number of African–Caribbean Sea air mass
connections. The number of air mass links is 169 per year, with a total of 3174 links in the 19-year period analyzed.
AE–AOD scatter plot for all data days in (a) western Africa and
(b) Caribbean Sea. Red circles are dust days in both Africa
(DAF) and Caribbean (DCAR) databases, green
squares are dust days in western Africa that are not dusty in Caribbean area
(NoDCAR), and grey triangles are non-dusty days (“NoD”).
Dashed lines indicate the criteria for identifying mineral dust (AOD ≥ 0.2 and AE ≤ 0.6). See text in Sect. 2.2.
The conditions observed at the Caribbean sites (Fig. 5b) show a change in the
mean size of the aerosol particles during the course of the year. In the
warm season (May–September) the maximum concentration peaks of about
2 µm radius identical to the coarse-mode size distribution found at
the western Africa sites (Fig. 5a), although the concentration values are lower
(as is AOD). In the cold season (October–April), however, the coarse-mode maximum concentration is shifted to larger radii
(> 3 µm) highlighting the predominance of large sea
salt particles. This difference in the coarse-mode radii between marine
aerosol and dust has been observed in other coastal locations affected by
dust outbreaks (e.g., Prats et al., 2011). In addition, the maximum volume
concentration of the coarse-mode exhibits maximum values in June with
0.12 µm3µm-2 and minimum ones in
November–December with 0.02 µm3µm-2. In terms
of volume concentration the fine mode plays a minor role throughout the year
at the Caribbean sites. The entire size range of VPSD in the cold season
is in line with previous studies carried out in oceanic environments (e.g.,
Dubovik et al., 2002) with low particle volume concentrations peaking at very
large radius (> 3 µm).
Air mass connections between western Africa and Caribbean areas
In this section, we select only those days when the back trajectories link
western Africa sites with Caribbean sites as explained in Sec. 2.2. In this way, the
aerosol properties observed at the Caribbean sites can be compared those
observed 5–7 days earlier over the western Africa sites.
Overview over air mass connections
Following the methodology described in steps 1 and 2 of Sect. 2.2, we
obtained a list of days when Caribbean air masses could be linked to western
Africa. Figure 6 shows the seasonal cycle of the total number of days with
this connection in the period 1996–2014. Overall, almost half of the days
each year (∼ 167 days per year) display a Caribbean–African linkage
with a total of 3174 cases in 19 years.
The total number of air mass connections between both areas exhibits small
values from January through April with an absolute minimum in April of only
2 days per month. This minimum at the Caribbean sites coincides with the
minimum in aerosol load observed in the seasonal cycle at the western Africa
sites (see Fig. 2).
With the beginning of the warm season (May–September) the number of
connections shows a notable increase achieving its maximum in July with
almost all the days at the Caribbean sites being connected with those in western
Africa. From October to December there is a progressive decline in links
from 20 to 10 days per month.
Unfortunately, columnar aerosol data are not available for all of the 3174
connection days. A total of 1162 out of 3174 days (36 % of the total) are
present in AERONET AOD and AE data of level 2.0 (see Sect. 2.1). Furthermore,
only 484 cases (15 % of the total) meet the dusty criteria in both areas
(DAF+DCAR case described in Sect. 2.2). This is
due to the limitation in the data coverage and to the strict criteria used to
unambiguously identify desert dust events. It should be noted that this
procedure underestimates the actual number of desert dust events observed by
ground-based measurements. For instance, during June–July–August at the
Caribbean sites there is essentially continuous dust (e.g., Prospero et al.,
2014), which is corroborated in this study with an average of
23–28 connection days in these months.
Scatter plot of AE–AOD in the western Africa and Caribbean areas
The next step focuses on the comparison of the aerosol properties observed at
the Caribbean sites and the values of the same properties which were observed
5–7 days earlier over the western Africa sites. In this way, the impact of the
long-range transport can be quantified. Figure 7 presents the scatter plot
of AE–AOD for those days with aerosol data and air mass links between the two
areas. When the criteria for identifying mineral dust (AOD ≥ 0.2 and
AE ≤ 0.6) are applied to the global Caribbean–African connected
database, three different cases are identified (see Sect. 2.2).
At the western Africa sites (Fig. 7a), as expected because of the proximity to
the Saharan Desert, the influence of the mineral dust aerosol properties is
predominant: 86 % of the available data have AOD ≥ 0.2 and
AE ≤ 0.6, (1000 out of 1162 days). We identified the occurrence of 498
dusty days at the Caribbean sites, about 42 % of the entire global
Caribbean–African connected database, but just 484 days (in the period
1996–2014) are shown to be dusty days at the Caribbean sites with aerosol
origin in the Saharan desert (indicated as a DAF+DCAR case in Fig. 7). Intense dusty days (AOD larger than
0.5) occur in western Africa and Caribbean sites in 430 and 67 cases,
respectively. This difference is attributable to a decrease in aerosol load
during transport between the two regions. Out of the total of 1162 cases 516
meet the dusty criteria only in the African database (DAF+ NoDCAR case in Fig. 7). This decrease in dust loads is also
observed in the change of the AE and AOD using ground-based and satellite
measurements (see, e.g., Yu et al., 2014). For instance, there are 102 cases
in the Caribbean database where AE > 0.6, whereas the same air
mass yielded AE < 0.6 at the western Africa sites days before.
Probably there are days with presence of dust with AOD and AE values close to
the required thresholds (156 and 59 days in the interval of
0.15 < AOD < 0.20 at the Caribbean and western Africa
sites, respectively). We considered lowering the AOD threshold so as to
include more cases but this would reduce confidence about the actual presence
of dust.
Scatter plot of AOD in the Caribbean
(AODCAR) versus AOD in the western Africa region
(AODAF) when dust is observed in both areas
(DAF+DCAR case; see
Sect. 2.2). The color scale indicates the AE in the Caribbean area
(AECAR). Dashed line indicates no change in AOD
between both areas, and R indicates the correlation coefficient.
Volume particle size distribution,
dV(r)/dln(r),
in the western Africa (AF) and the Caribbean (CAR) areas under desert dust
conditions (DAF+DCAR case; see
Sect. 2.2).
Scatter plot of connected AOD data
Once the connections have been detected, changes in AOD due to the long-range
transport over the Atlantic Ocean are studied depending on the AE values. The
results are shown in Fig. 8. The AODCAR has been plotted as a
function of AOD at the western Africa sites (AODAF).
The scatter plot in Fig. 8 shows that there is, as expected, a decrease in
AOD in air masses transiting the Atlantic. The mean decrease of AOD between
western Africa and Caribbean sites is 0.16, a decrease of about 30 % with
respect to the values at Dakar and Cabo Verde. They are greatest for cases
where AOD values are large (AOD > 0.8) at the western Africa
sites, with decreases up to 70 %. In the interval
0.5 < AOD < 0.8 the decreases are in the range of about
28–45 %, while those in the interval 0.2 < AOD < 0.5
are in the range 11–27 %. These percentages based on long-term and
ground-based data are a first approach to assess the estimations done by
studies dealing with satellite data. For instance, Yu et al. (2015) have
reported, in a latitudinal belt of 10∘ S–30∘ N, a loss of
70 % (±45–70 %) of the dust amount (in Tg yr-1) between
western Africa (at 15∘ W) and the end of the Caribbean sites (at
75∘ W). Hence, our estimations are in line with these findings
considering that the measured variable and studied area are not identical.
The cases with low AE values are those cases with a wider variability in AOD
difference. In addition, there are some cases in which AOD is larger at the
Caribbean sites. There could be different reasons which explain this effect:
inhomogeneity of the dust layer, addition of other aerosol particles at the
Caribbean sites, temporal gaps in the instantaneous measurements that cause
non-representative daily averages, and cloud contamination not detected by
the cloud-screening algorithm, for example.
Aerosol microphysical properties for African–Caribbean Sea
connections
In this section we focus on the key aerosol microphysical properties for
those cases where we found a link between the western Africa and Caribbean
sites. Figure 9 shows the average VPSD for the case analyzed before: dust
conditions in both areas (DAF+DCAR). The main
characteristics of the VPSD curve for this collection of data in the western Africa
sites are the same as described in detail in Sect. 4. The fine-mode volume
fraction (obtained as the ratio VCF/ VCT) is on
average 0.077.
Histogram of the differences between the total effective
radii in the western Africa region and in the Caribbean area for those cases with
connected desert dust conditions in both areas (DAF+DCAR case).
The VPSD at the Caribbean sites for the DAF+DCAR case is similar to that at the western Africa sites:
average coarse-mode volume concentration of
0.22 µm3µm-2, maximum peak of about
2 µm radius, and very low fine-mode concentration (average of
0.02 µm3µm-2 peaking at 0.086 µm,
fine-mode volume fraction of 0.09). The coarse-mode volume concentration
decreases from 0.34 µm3µm-2 in western Africa to
0.22 µm3µm-2 at the Caribbean sites. Hence,
there is a loss of about 35 % in the coarse-mode concentration between
both areas caused by the long-range transport over the Atlantic Ocean.
Sphericity fraction values in the western Africa region and in
the Caribbean area for those cases with desert dust in both areas
(DAF+DCAR case; see
Sect. 2.2).
Average values of (a) single scattering albedo (SSA) and
asymmetry parameter (g), (b) imaginary part of the refractive
index (REFI), and (c) real part of the refractive index (REFR) for those
cases with desert dust in both the western Africa region (black lines) and Caribbean
area (red lines; DAF+DCAR case; see
Sect. 2.2).
To quantify the change in the mean aerosol size caused by the long-range
transport, Fig. 10 shows the histogram of the differences between the
effective radius of the total size distribution (ERT) in the two
areas. On average, ERT shows values of 0.88 and 0.76 µm
in western Africa and Caribbean sites, respectively. Most of the differences in
the ERT values are negative, thus indicating the size
distribution in western Africa generally having larger particles than at the
Caribbean sites. The differences in the effective radii are mostly confined
(about 70 % of the cases) between no change and a decrease in the
effective radius of about 0.3 µm between both areas. The maximum of
occurrence is found for a decrease of about 0.2 µm. Positive
differences (15 % of the cases), meaning larger particle size at the
Caribbean sites, could be attributed to the presence of other aerosol layers
(e.g., sea salt) in the atmospheric column. Uncertainties of the inversion
could also explain the positive differences.
The third microphysical property studied here is the fraction of
spherical particles found in the inversion process. In the retrieval,
particles are modeled both as spheres and spheroids, and the inversion finds
which fraction of spherical and non-spherical particles better fits the
observations (for details, see Dubovik at al., 2006). The results are
presented in Fig. 11. This figure shows that at the western Africa sites there
is a large predominance of non-spherical particles, that is,
SF < 0.05. Respectively, about 80 and 53 % of the values at the
western Africa and Caribbean sites were completely non-spherical. Overall, in
32 out of 71 cases (45 %) there is no change between both areas and the
shape of the particles is predominantly non-spherical. Cases with sphericity
fraction below 0.05 in western Africa sites display a wide variability in the
observed fraction at the Caribbean sites, even achieving values of 0.7. This
increase could be explained by the mixture of mineral dust with other
(spherical) aerosol particles, such as maritime aerosols. Note that we use
column observations; therefore the mixture in this case does not mean that
dust and other aerosol particles are necessarily in the same layer; they can
be separated in different atmospheric layers. For instance, during the
SALTRACE experiment the main four dust events recorded presented a vertical
structure with up to three layers: the boundary layer, the entrainment or
mixing layer, and the pure Saharan dust layer (Groß et al., 2015).
Uncertainties of the inversion method can also be a reason for the high
fraction of spherical particles. The in situ measurements at Barbados
collect dust in the boundary layer (Prospero, 1999; Smirnov et al., 2000; Yu
et al., 2014), so that dust is collected simultaneously with sea salt and
other aerosol types (e.g., Ansmann et al., 2009; Toledano et al., 2011;
Groß et al., 2011). There is a correlation between high in situ dust mass
concentrations, high total aerosol optical depth, and low Ångström
exponent (Groß et al., 2016). However the highest concentrations of dust
are found in the elevated Saharan Air Layer (Yu et al., 2014), where there are
no significant concentrations of sea salt aerosol (Savoie et al., 2002).
Aerosol radiative properties for African–Caribbean Sea
connections
Figure 12 compares the main radiative properties (SSA, g, REFR, and REFI)
at the Caribbean and western Africa sites to assess changes in optical properties
that occur after long-range transport. SSA in Fig. 12a and REFI in Fig. 12c
are the same in both areas within the limits of uncertainty. The SSA at Dakar
and Cabo Verde increases with wavelength: from 0.94 at 440 nm up to 0.98 at
670, 870, and 1020 nm. These figures are in line with previous studies in
this area (Dubovik et al., 2002; Eck et al., 2010; Kim et al., 2011; Toledano
et al., 2011; Giles et al., 2012, among others) and also with measurements at
various Spanish and Mediterranean sites during desert dust outbreaks (e.g.,
Meloni et al., 2006; Cachorro et al., 2010; Valenzuela et al., 2012; Burgos
et al., 2016). The SSA in dust events at the Caribbean sites is essentially
identical to that at the western Africa sites. The same is true for REFI:
0.0025 at 440 nm and 0.001–0.0015 in the interval 670–1020 nm. The values
in the visible and near infrared ranges are slightly larger than those
reported by Dubovik et al. (2002) which were about 0.0007; their value at
440 nm is very similar to the value we present here. There is no significant
change in the REFR either, as it is the mean real part of the refractive index
in the African and Caribbean database, at about 1.45 ± 0.01. This value is
slightly lower than that reported by Dubovik et al. (2002) which was about
1.48. Finally, the asymmetry factor g at 440 nm decreases slightly from 0.77
in western Africa sites to 0.755 at the Caribbean sites. The g values reported
in this study are slightly larger than those reported by previous studies for
desert dust in Africa (e.g., Dubovik et al., 2002). Overall, the intensive
optical properties (both absorption and scattering quantities) do not change
significantly in spite of the long-range transport.
Conclusions
The objective of this study was to characterize changes in aerosol
physical–radiative properties that occur in dust-laden air masses that
transit the Atlantic from Africa to the eastern Caribbean. To this end we
compared AERONET sun photometer measurements and inversion products made over
the period 1996–2014 at five island sites in the eastern Caribbean with
those made at two sites in western Africa. Focusing first on the
results observed from the two western Africa sites, we find that the dust properties
are quite similar to those previously reported for Saharan dust in field
experiments and previous studies using AERONET data.
We focused efforts on paired measurements made on the same dust outbreaks in
a procedure that identified trajectories from the Caribbean island sites that
back-tracked to one or both of the western Africa sites. We find that there is no
substantial change in the intensive radiative properties in western Africa air
masses after a journey of 5–7 days over a distance of 4000 km. There is a
decrease of about 30 % in the coarse-mode concentration of the size
distributions but the coarse-mode effective radius does not change.
Non-spherical particles characteristic of dust are the predominant shape in
both areas. In general there were no substantial changes in the spectral
dependence of the absorbing and scattering properties of dust during transit.
Our findings that suggest uniformity in properties are similar to those
reached in Bozlaker et al. (2017), who measured the concentrations and
isotopic composition of a broad suite of elements in Barbados dust samples
collected in 2013 and 2016. Although dust concentrations were highly
variable, the elemental and isotopic abundances fell within a relatively narrow
range compared to wide-ranging compositions reported for hypothesized dust
sources in North Africa. In contrast the Barbados composition was very
similar to that reported in the literature for samples collected at sites on
the coast of western Africa on islands or ships close to the coast. These
results suggest that during large dust events, the dust from different
sources which may have different signatures becomes homogenized during
transport from the interior of North Africa to the coast and that there is
relatively little change in dust properties during transit of the Atlantic.
The results of our study and that of Bozlaker et al. (2017) suggest that the
modeling of the radiative effects of dust over the Atlantic can be
simplified in that it can be assumed that the radiative properties of dust
are relatively uniform and unchanging during transport within the context of
the range of properties discussed here.
Backward trajectories analysis has been supported by air
mass transport computation with the NOAA (National Oceanic and Atmospheric
Administration) HYSPLIT (HYbrid Single-Particle Lagrangian Integrated
Trajectory) model using GDAS meteorological data (Stein et al., 2015).
AERONET sun photometer data are downloaded from the AERONET web page (Holben
et al., 1998).
The authors declare that they have no conflict of
interest.
This article is part of the special issue “The Saharan Aerosol
Long-range Transport and Aerosol-Cloud-interaction Experiment (SALTRACE; ACP/AMT inter-journal SI)”. It
is not associated with a conference.
Acknowledgements
The authors gratefully acknowledge the NASA AERONET program for the very
valuable data used in this study. We thank Brent Holben (Barbados,
La_Parguera), Didier Tanre (Capo_Verde, Dakar), and Olga Mayol-Bracero
(Cape San Juan) for their effort in establishing and maintaining their sites.
This work has received funding from the European Union's Horizon 2020
research and innovation programme under grant agreement no. 54109 (ACTRIS-2).
The authors are grateful to Spanish MINECO for the financial support of the
IJCI-2014-19477 grant, PTA2014-09522-I grant, and POLARMOON project
(ref. CTM2015-66742-R). We also thank “Consejería de Educación” of
“Junta de Castilla y León” for supporting the GOA-AIRE project (ref.
VA100P17). Prospero received support from NSF AGS-0962256 and NASA
NNX12AP45G. Edited by: Bernadett
Weinzierl Reviewed by: three anonymous referees
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