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<article xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:oasis="http://docs.oasis-open.org/ns/oasis-exchange/table" dtd-version="3.0"><?xmltex \hack{\sloppy}?>
  <front>
    <journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">Atmos. Chem. Phys.</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>

    <article-meta>
      <article-id pub-id-type="doi">10.5194/acp-17-12051-2017</article-id><title-group><article-title>Technical note: The US Dobson station network data record prior to 2015, re-evaluation of NDACC and WOUDC archived records with WinDobson processing software</article-title>
      </title-group><?xmltex \runningtitle{The US Dobson station network data record prior to 2015}?><?xmltex \runningauthor{R.~D.~Evans et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff2">
          <name><surname>Evans</surname><given-names>Robert D.</given-names></name>
          <email>robert.d.evans@noaa.gov</email>
        <ext-link>https://orcid.org/0000-0002-8693-9769</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Petropavlovskikh</surname><given-names>Irina</given-names></name>
          
        <ext-link>https://orcid.org/0000-0001-5352-1369</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>McClure-Begley</surname><given-names>Audra</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>McConville</surname><given-names>Glen</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Quincy</surname><given-names>Dorothy</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3">
          <name><surname>Miyagawa</surname><given-names>Koji</given-names></name>
          
        </contrib>
        <aff id="aff1"><label>1</label><institution>Cooperative Institute for Research in Environmental Sciences, University of Colorado, Boulder, CO 80309, USA</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Retired from NOAA/ESRL, Global Monitoring Division, Boulder, CO 80305, USA</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>Visitor with NOAA/ESRL, Global Monitoring Division, Boulder, CO 80305, USA</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Robert D. Evans (robert.d.evans@noaa.gov)</corresp></author-notes><pub-date><day>11</day><month>October</month><year>2017</year></pub-date>
      
      <volume>17</volume>
      <issue>19</issue>
      <fpage>12051</fpage><lpage>12070</lpage>
      <history>
        <date date-type="received"><day>26</day><month>April</month><year>2017</year></date>
           <date date-type="accepted"><day>28</day><month>August</month><year>2017</year></date>
           <date date-type="rev-recd"><day>8</day><month>August</month><year>2017</year></date>
           <date date-type="rev-request"><day>8</day><month>May</month><year>2017</year></date>
      </history>
      <permissions>
<license license-type="open-access">
<license-p>This work is licensed under the Creative Commons Attribution 3.0 Unported License. To view a copy of this licence, visit <ext-link ext-link-type="uri" xlink:href="https://creativecommons.org/licenses/by/3.0/">https://creativecommons.org/licenses/by/3.0/</ext-link></license-p>
</license>
</permissions><self-uri xlink:href="https://acp.copernicus.org/articles/17/12051/2017/acp-17-12051-2017.html">This article is available from https://acp.copernicus.org/articles/17/12051/2017/acp-17-12051-2017.html</self-uri>
<self-uri xlink:href="https://acp.copernicus.org/articles/17/12051/2017/acp-17-12051-2017.pdf">The full text article is available as a PDF file from https://acp.copernicus.org/articles/17/12051/2017/acp-17-12051-2017.pdf</self-uri>


      <abstract>
    <p>The United States government has operated Dobson ozone spectrophotometers at
various sites, starting during the International Geophysical Year
(1 July 1957 to 31 December 1958). A network of stations for long-term
monitoring of the total column content (thickness of the ozone layer) of the
atmosphere was established in the early 1960s and eventually grew to 16
stations, 14 of which are still operational and submit data to the United
States of America's National Oceanic and Atmospheric Administration (NOAA).
Seven of these sites are also part of the Network for the Detection of
Atmospheric Composition Change (NDACC), an organization that maintains its
own data archive. Due to recent changes in data processing software the
entire dataset was re-evaluated for possible changes. To evaluate and
minimize potential changes caused by the new processing software, the
reprocessed data record was compared to the original data record archived in
the World Ozone and UV Data Center (WOUDC) in Toronto, Canada. The history of
the observations at the individual stations, the instruments used for the
NOAA network monitoring at the station, the method for reducing zenith-sky
observations to total ozone, and calibration procedures were re-evaluated
using data quality control tools built into the new software. At the
completion of the evaluation, the new datasets are to be published as an
update to the WOUDC and NDACC archives, and the entire dataset is to be made
available to the scientific community. The procedure for reprocessing Dobson
data and the results of the reanalysis on the archived record are presented
in this paper. A summary of historical changes to 14 station records is also
provided.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

      <?xmltex \floatpos{t}?><fig id="Ch1.F1" specific-use="star"><caption><p>Diagram of the Dobson instrument, with cover omitted from view (some
components shown are actually mounted in the cover).</p></caption>
      <?xmltex \igopts{width=500.768504pt}?><graphic xlink:href="https://acp.copernicus.org/articles/17/12051/2017/acp-17-12051-2017-f01.png"/>

    </fig>

<sec id="Ch1.S1" sec-type="intro">
  <title>Background</title>
      <p>The Dobson ozone spectrophotometer was designed in the 1920s and is still in
use today. The instrument is fully described elsewhere (Dobson, 1931, 1968)
but, briefly, it measures the relative intensity of solar radiation between
selected wavelength pairs in the range of 300–350 nm. These pairs are named
A (305.5 and 325.4 nm), C (311.5 and 334.4 <inline-formula><mml:math id="M1" display="inline"><mml:mi mathvariant="normal">nm</mml:mi></mml:math></inline-formula>), C<inline-formula><mml:math id="M2" display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> (334.4
and 453.6 <inline-formula><mml:math id="M3" display="inline"><mml:mi mathvariant="normal">nm</mml:mi></mml:math></inline-formula>) and D (317.5 and 339.8 <inline-formula><mml:math id="M4" display="inline"><mml:mi mathvariant="normal">nm</mml:mi></mml:math></inline-formula>) and are combined in
the measurement process as either A and D (AD), C and C<inline-formula><mml:math id="M5" display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula>
(CC<inline-formula><mml:math id="M6" display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula>) or C and D (CD). Observations on the direct solar beam have DS (direct sun) attached to the wavelength identifier
(for example, ADDS is an observation using the A and D pairs, on the direct solar beam).
Observations on the zenith sky have ZB for zenith clear, ZC for zenith cloudy, and ZS for general zenith-sky observations.
The optical arrangement of the instrument is
presented in Fig. 1. Measurements on either direct solar light or light
scattered from the zenith can be used to calculate the amount of ozone
between the instrument and the top of the atmosphere (total ozone column or
TOC). Approximately 90 % of this TOC resides in the region between 15 and
30 <inline-formula><mml:math id="M7" display="inline"><mml:mi mathvariant="normal">km</mml:mi></mml:math></inline-formula> above the Earth's surface, which is defined as the ozone layer.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2" specific-use="star"><caption><p>Distribution of cumulative differences between results from direct
sun (ADDS) compared to zenith measurements on the same day. The frequency of
compared zenith and ADDS total ozone (<inline-formula><mml:math id="M8" display="inline"><mml:mi>y</mml:mi></mml:math></inline-formula> axis) is accumulated between 0 and
6 % (<inline-formula><mml:math id="M9" display="inline"><mml:mi>x</mml:mi></mml:math></inline-formula> axis). Results are shown for other types of zenith-sky
measurements denoted by colors in the legend. Results are the average of 12
stations in the US network except for the CC<inline-formula><mml:math id="M10" display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> results, which are
based on the SPO data record.</p></caption>
        <?xmltex \igopts{width=312.980315pt}?><graphic xlink:href="https://acp.copernicus.org/articles/17/12051/2017/acp-17-12051-2017-f02.png"/>

      </fig>

      <p>The relative intensity of wavelength pairs measured if instrument was operated outside the Earth's atmosphere is referred to as the
extraterrestrial constant (ETC). The instrument's ETC is determined either through a Langley plot method (Langley, 1884) or by direct
comparison with a standard Dobson instrument (Komhyr and Evans, 2008). The concept of measurement of the Dobson spectrophotometer
exploits the change in the ratio of solar light intensities measured at the respective wavelength pairs as caused by the passage of UV
light through the ozone layer. The light enters the instrument (Fig. 1), and the right side of the optics produces a spectrum projected
on a slit arrangement containing slits S<inline-formula><mml:math id="M11" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>, S<inline-formula><mml:math id="M12" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula> and S<inline-formula><mml:math id="M13" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">4</mml:mn></mml:msub></mml:math></inline-formula> (only used for C<inline-formula><mml:math id="M14" display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> measurements). The left side of the optics
combines the images of the slits into the photomultiplier tube. The measurement of the relative intensities is performed by moving
a neutral density filter (the optical “wedge”) across the light path of the wavelength less absorbed by ozone, specifically the light
passing through slit S<inline-formula><mml:math id="M15" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula>. The wedge is moved to reduce the light intensity of S<inline-formula><mml:math id="M16" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">3</mml:mn></mml:msub></mml:math></inline-formula> to equal the intensity of S<inline-formula><mml:math id="M17" display="inline"><mml:msub><mml:mi/><mml:mn mathvariant="normal">2</mml:mn></mml:msub></mml:math></inline-formula>, the
wavelength more absorbed by ozone, as seen by the photomultiplier tube. The instrument's output, <inline-formula><mml:math id="M18" display="inline"><mml:mi>R</mml:mi></mml:math></inline-formula> value, indicates the position of
the neutral density filter as indicated on an engraved plate, which is the primary measurement and is specific to the Dobson instrument
optical properties.</p>
      <p>The <inline-formula><mml:math id="M19" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> value represents the attenuation by ozone and by other scattering and absorption during the UV light's passage through the
atmosphere between the sun and the instrument. The relationship between <inline-formula><mml:math id="M20" display="inline"><mml:mi>R</mml:mi></mml:math></inline-formula> values and <inline-formula><mml:math id="M21" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> values is both wavelength and instrument
specific. <inline-formula><mml:math id="M22" display="inline"><mml:mi>R</mml:mi></mml:math></inline-formula> values are converted to <inline-formula><mml:math id="M23" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> values using tables called <inline-formula><mml:math id="M24" display="inline"><mml:mi>R</mml:mi></mml:math></inline-formula> to <inline-formula><mml:math id="M25" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> tables (<inline-formula><mml:math id="M26" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> tables). These tables change during the
instruments' lifespans due to repairs, updates and aging; thus each set has a limited period of application. The applicability of the
<inline-formula><mml:math id="M27" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> table is monitored by means of intercomparisons with standard Dobson instruments and with the use of instrument-specific reference
lamps. The calculation of ozone from observations made on the DS light (or reflected light from the moon) is with
a defined algorithm based on Beer's law. The resolution of the measurement is 1 <inline-formula><mml:math id="M28" display="inline"><mml:mi mathvariant="normal">DU</mml:mi></mml:math></inline-formula>, and the precision (uncertainty) is
considered to be <inline-formula><mml:math id="M29" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula> % (Grant, 1989). Accuracy is another issue. The accuracy is dependent on knowledge of the ozone and
temperature profile at the time of the measurement to correctly calculate the ozone absorption cross section. As this information is
not available for individual observations, some assumptions must be made. A standard algorithm for the reduction of
DS
observations (Komhyr et al., 1993) is used by all organizations reporting daily values to the WOUDC or NDACC archives. The accuracy
is also dependent on the knowledge of the ozone cross-section datasets used to determine the absorption coefficients in the reduction
algorithm (Redondas et al., 2014). The reduction of measurements on the ZS is more complicated, as it is based on
statistical analysis of DS and ZS observations close in time. The precision (uncertainty) of the ZS empirical model is found to be
2–5 % in this work and is dependent on the wavelength pairs used and the sky conditions. An accepted method of statistical
analysis is not defined in the standard operating procedures; different organizations using the instrument employ different methods to
build the empirical relation between direct-sun and zenith-sky measurements (Josefsson and Löfvenius, 2008).</p>
      <p>The Dobson instrument has limitations in the accuracy of measurements at certain observing conditions (Basher, 1982). Internal stray
light is one such limitation. Moreover, each Dobson instrument has unique optical components that result in an instrument-specific
level of the stray light. The quality and aging stability of the individual wedge construction has improved over time, especially for
instruments within the NOAA network, which had optical components replaced with those of a more robust design during instrument
rebuilding in the 1980s.</p>
      <p>Data reduction algorithms are fully discussed in  Sect. 7 of the Operations Handbook (Komhyr and Evans, 2008;
<uri>http://www.wmo.int/pages/prog/arep/gaw/documents/GAW183-Dobson-WEB.pdf</uri>).</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1" specific-use="star"><caption><p>Current stations in the NOAA network using Dobson ozone spectrophotometers.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="5">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:colspec colnum="3" colname="col3" align="left"/>
     <oasis:colspec colnum="4" colname="col4" align="justify" colwidth="128.037402pt"/>
     <oasis:colspec colnum="5" colname="col5" align="justify" colwidth="71.13189pt"/>
     <oasis:thead>
       <oasis:row>  
         <oasis:entry colname="col1">Station Name</oasis:entry>  
         <oasis:entry colname="col2">NOAA station</oasis:entry>  
         <oasis:entry colname="col3">Station</oasis:entry>  
         <oasis:entry colname="col4">Responsible</oasis:entry>  
         <oasis:entry colname="col5">Current</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2">code and WMO</oasis:entry>  
         <oasis:entry colname="col3">Dobson</oasis:entry>  
         <oasis:entry colname="col4">organizations</oasis:entry>  
         <oasis:entry colname="col5">automation</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2">station number</oasis:entry>  
         <oasis:entry colname="col3">record</oasis:entry>  
         <oasis:entry colname="col4">(archives)</oasis:entry>  
         <oasis:entry colname="col5">status</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3">started</oasis:entry>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>  
         <oasis:entry colname="col1">Mauna Loa GMD Observatory</oasis:entry>  
         <oasis:entry colname="col2">MLO  31</oasis:entry>  
         <oasis:entry colname="col3">1963</oasis:entry>  
         <oasis:entry colname="col4">NOAA  (NDACC and WOUDC)</oasis:entry>  
         <oasis:entry colname="col5">WinDobson full</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">South Pole</oasis:entry>  
         <oasis:entry colname="col2">SPO  111</oasis:entry>  
         <oasis:entry colname="col3">1963</oasis:entry>  
         <oasis:entry colname="col4">NOAA   (NDACC and WOUDC)</oasis:entry>  
         <oasis:entry colname="col5">NOAA semi-auto</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Bismarck, North Dakota</oasis:entry>  
         <oasis:entry colname="col2">BIS  19</oasis:entry>  
         <oasis:entry colname="col3">1962</oasis:entry>  
         <oasis:entry colname="col4">NOAA</oasis:entry>  
         <oasis:entry colname="col5">NOAA semi-auto</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Caribou, Maine</oasis:entry>  
         <oasis:entry colname="col2">CAR   20</oasis:entry>  
         <oasis:entry colname="col3">1962</oasis:entry>  
         <oasis:entry colname="col4">NOAA</oasis:entry>  
         <oasis:entry colname="col5">NOAA semi-auto</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Nashville, Tennessee</oasis:entry>  
         <oasis:entry colname="col2">BNA   106</oasis:entry>  
         <oasis:entry colname="col3">1962</oasis:entry>  
         <oasis:entry colname="col4">NOAA</oasis:entry>  
         <oasis:entry colname="col5">NOAA semi-auto</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Fairbanks, Alaska</oasis:entry>  
         <oasis:entry colname="col2">FBK;  POK   105;  217</oasis:entry>  
         <oasis:entry colname="col3">1965</oasis:entry>  
         <oasis:entry colname="col4">NOAA;  University of Alaska</oasis:entry>  
         <oasis:entry colname="col5">WinDobson full</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Boulder, Colorado</oasis:entry>  
         <oasis:entry colname="col2">BDR  67</oasis:entry>  
         <oasis:entry colname="col3">1966</oasis:entry>  
         <oasis:entry colname="col4">NOAA   (NDACC and WOUDC)</oasis:entry>  
         <oasis:entry colname="col5">WinDobson full</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Wallops Is., Virginia</oasis:entry>  
         <oasis:entry colname="col2">WAI  107</oasis:entry>  
         <oasis:entry colname="col3">1967</oasis:entry>  
         <oasis:entry colname="col4">NOAA;  NASA   (NDACC and WOUDC)</oasis:entry>  
         <oasis:entry colname="col5">NOAA semi-auto</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Barrow GMD Observatory</oasis:entry>  
         <oasis:entry colname="col2">BRW  199</oasis:entry>  
         <oasis:entry colname="col3">1973</oasis:entry>  
         <oasis:entry colname="col4">NOAA</oasis:entry>  
         <oasis:entry colname="col5">NOAA semi-auto</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">American Samoa, GMD Observatory</oasis:entry>  
         <oasis:entry colname="col2">SMO 191</oasis:entry>  
         <oasis:entry colname="col3">1976</oasis:entry>  
         <oasis:entry colname="col4">NOAA   (NDACC and WOUDC)</oasis:entry>  
         <oasis:entry colname="col5">NOAA semi-auto</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Haute Provence, France</oasis:entry>  
         <oasis:entry colname="col2">OHP 40</oasis:entry>  
         <oasis:entry colname="col3">1983</oasis:entry>  
         <oasis:entry colname="col4">NOAA;  Centre National de la Recherche Scientifique (NDACC and WOUDC)</oasis:entry>  
         <oasis:entry colname="col5">WinDobson full</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Fresno and Hanford, California</oasis:entry>  
         <oasis:entry colname="col2">FAT;  HNX   244;  341</oasis:entry>  
         <oasis:entry colname="col3">1983</oasis:entry>  
         <oasis:entry colname="col4">NOAA</oasis:entry>  
         <oasis:entry colname="col5">NOAA semi-auto</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Perth, Australia</oasis:entry>  
         <oasis:entry colname="col2">PTH   159</oasis:entry>  
         <oasis:entry colname="col3">1984</oasis:entry>  
         <oasis:entry colname="col4">NOAA;  Australian Bureau Meteorology</oasis:entry>  
         <oasis:entry colname="col5">NOAA full</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Lauder, New Zealand</oasis:entry>  
         <oasis:entry colname="col2">LDR 256</oasis:entry>  
         <oasis:entry colname="col3">1987</oasis:entry>  
         <oasis:entry colname="col4">NOAA;  National Institute for Water and Atmosphere   (NDACC and WOUDC)</oasis:entry>  
         <oasis:entry colname="col5">WinDobson full</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

</sec>
<sec id="Ch1.S2">
  <title>Station history</title>
      <p>There are measurements of TOC in the USA prior to 1960 made by university and federal organizations (Brönnimann, 2003), but the
development of a coherent network of observing sites within the US Weather Service  started in the 1960s under the guidance of
Walter Komhyr. The network was transferred to NOAA's Global Monitoring for Climate Change (GMCC) in the early 1970s and is currently
operated by NOAA's Earth System Research Laboratory's Global Monitoring Division (ESRL/GMD). As many as 16 stations comprised the
network since its establishment. One station was closed; another was transferred to another parent authority. Table 1 displays the
stations reporting at end of 2015. Originally, observations using the Dobson instruments were recorded with pen or pencil on forms
designed to assist manual calculations (<uri>https://youtu.be/w1rV_96UChk</uri>). As computer power increased, the data were transcribed to
punched cards for processing and then to direct entry by keyboard. By the mid-1990s, the NOAA instruments were equipped with computers and
encoders, and the data were recorded in a “dayfile” at the time of the measurement. Six stations were equipped with fully automated
instruments in the 1980s.</p>
<sec id="Ch1.S2.SS1">
  <title>Data processing</title>
      <p>TOC is normally archived as a single representative value of TOC selected for
each day. This not an average value, but the result of the “best”
observation during the day. As the exact instrumentation and observational
scheduling vary from station to station, the number of observations made
daily also vary. The full record of
observations is available per request from NOAA Dobson network personnel
listed at <uri>https://www.esrl.noaa.gov/gmd/ozwv/dobson/contact.html</uri>. In
this publication, the term “select value” means the daily value produced in
the NOAA processing stream. An earlier reprocessing of the stations' data was
done in the 1990s (Komhyr et al., 1995); the report also details much of the
early history of measurements in the US system of stations.</p>
      <p>To convert measurements to TOC values, calibration <inline-formula><mml:math id="M30" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> tables and information
(reference lamp adjustment) from monthly instrument tests using reference
lamps are required. The <inline-formula><mml:math id="M31" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> tables are defined by comparison of the station
instrument to a reference standard. These referencings are normally done on
a 4- to 6-year schedule. The calibration of the wedge is normally measured at
the same time. The reference lamp tests are an indication of the instrument's
aging but are only a single point test in the instrument measurement range.
The comparison process measures instrument performance over a typical
mu range of 1.15 to 3.85 but this is
often adjusted with consideration to circumstances such as an instrument's
location. Mu is the normalized optical path length through the ozone layer and is calculated from the solar zenith angle (SZA). The calibration <inline-formula><mml:math id="M32" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> tables
are changed when the difference between the station and reference instrument
is greater than the equivalent of 1 % in TOC. When the calibration
<inline-formula><mml:math id="M33" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> tables are changed due to a drift (determined from an inspection of the
past calibrations, instrument operational history and, if possible,
comparison with other instrumental records), the existing dataset from the
last calibration change to the new calibration was reprocessed and
republished in the archives.</p>
      <p>The set of computer programs used for the NOAA processing were written in the FORTRAN language and, by the 2010s, were difficult to use
and maintain due to changes in computer hardware and personnel. The decision was made to convert the NOAA processing to processing
using the WinDobson software package, as the fully automated instruments were updated to a modern system based on this
software. Developed by personnel of the Japan Meteorological Agency (Miyagawa, 1996), WinDobson is a software package for operations,
data analysis and quality assurance of Dobson spectrophotometer observations. The algorithm for the reduction of ozone from DS
observations with the Dobson is the standard method used by the NOAA software, but the ZS observations are reduced with a method
described later in this paper.  For the NOAA application, new components were developed. These new components are available from
NOAA to other users of WinDobson. It is applicable for both TOC and Umkehr (ozone vertical profile) measurements. As this software has
a different statistical method for the reduction of the zenith measurements, and set of rules (see Sect. 2.4) for determining the
representative value of total ozone for each day with observations, the entire data record of each operational station was reprocessed
in the WinDobson system to minimize the effect of the change when future data are placed in the archive. In the development of the data
files and calibration information for WinDobson processing, the entire record of observations, repair and calibration checks of each
station was investigated and re-evaluated. This investigation allows for correction of past errors.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T2" specific-use="star"><caption><p>Statistics of the overall differences between WOUDC and NDACC records and WinDobson record (WinDobson–WOUDC, NDACC).</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="5">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:colspec colnum="3" colname="col3" align="left"/>
     <oasis:colspec colnum="4" colname="col4" align="left"/>
     <oasis:colspec colnum="5" colname="col5" align="left"/>
     <oasis:thead>
       <oasis:row>  
         <oasis:entry colname="col1">Station</oasis:entry>  
         <oasis:entry colname="col2">Offset WinDobson–</oasis:entry>  
         <oasis:entry colname="col3">Linear trend</oasis:entry>  
         <oasis:entry colname="col4">Offset WinDobson–</oasis:entry>  
         <oasis:entry colname="col5">Linear trend</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">code</oasis:entry>  
         <oasis:entry colname="col2">WOUDC</oasis:entry>  
         <oasis:entry colname="col3">WinDobson–WOUDC</oasis:entry>  
         <oasis:entry colname="col4">NDACC</oasis:entry>  
         <oasis:entry colname="col5">WinDobson–NDACC</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3">per year</oasis:entry>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5">per year</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>  
         <oasis:entry colname="col1">MLO</oasis:entry>  
         <oasis:entry colname="col2"><inline-formula><mml:math id="M34" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.1</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1.6</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math id="M35" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.014</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.001</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col4"><inline-formula><mml:math id="M36" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.1</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1.8</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col5"><inline-formula><mml:math id="M37" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.015</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.001</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">SPO</oasis:entry>  
         <oasis:entry colname="col2"><inline-formula><mml:math id="M38" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.0</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">4.0</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math id="M39" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.016</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.003</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col4"><inline-formula><mml:math id="M40" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.5</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">6.9</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col5"><inline-formula><mml:math id="M41" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.026</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.006</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">BIS</oasis:entry>  
         <oasis:entry colname="col2"><inline-formula><mml:math id="M42" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.1</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">2.2</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math id="M43" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.004</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.001</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col4">N<inline-formula><mml:math id="M44" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula>A</oasis:entry>  
         <oasis:entry colname="col5">N<inline-formula><mml:math id="M45" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula>A</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">CAR</oasis:entry>  
         <oasis:entry colname="col2"><inline-formula><mml:math id="M46" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.2</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">3.2</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math id="M47" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.022</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.002</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col4">N<inline-formula><mml:math id="M48" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula>A</oasis:entry>  
         <oasis:entry colname="col5">N<inline-formula><mml:math id="M49" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula>A</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">BNA</oasis:entry>  
         <oasis:entry colname="col2"><inline-formula><mml:math id="M50" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.6</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">2.7</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math id="M51" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.002</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.001</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col4">N<inline-formula><mml:math id="M52" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula>A</oasis:entry>  
         <oasis:entry colname="col5">N<inline-formula><mml:math id="M53" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula>A</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">FBK</oasis:entry>  
         <oasis:entry colname="col2"><inline-formula><mml:math id="M54" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.4</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">2.8</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math id="M55" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.033</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.003</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col4">N<inline-formula><mml:math id="M56" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula>A</oasis:entry>  
         <oasis:entry colname="col5">N<inline-formula><mml:math id="M57" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula>A</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">BDR</oasis:entry>  
         <oasis:entry colname="col2"><inline-formula><mml:math id="M58" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.3</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1.7</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math id="M59" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.007</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.001</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col4"><inline-formula><mml:math id="M60" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.3</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1.5</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col5"><inline-formula><mml:math id="M61" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.001</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.001</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">WAI</oasis:entry>  
         <oasis:entry colname="col2"><inline-formula><mml:math id="M62" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.1</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">3.3</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math id="M63" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.024</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.003</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col4"><inline-formula><mml:math id="M64" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.0</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1.6</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col5"><inline-formula><mml:math id="M65" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.032</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.006</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">BRW</oasis:entry>  
         <oasis:entry colname="col2"><inline-formula><mml:math id="M66" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.7</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">2.8</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math id="M67" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.011</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.004</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col4">N<inline-formula><mml:math id="M68" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula>A</oasis:entry>  
         <oasis:entry colname="col5">N<inline-formula><mml:math id="M69" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula>A</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">SMO</oasis:entry>  
         <oasis:entry colname="col2"><inline-formula><mml:math id="M70" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.1</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1.7</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math id="M71" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.042</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.002</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col4"><inline-formula><mml:math id="M72" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.1</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">2.3</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col5"><inline-formula><mml:math id="M73" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.042</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.002</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">OHP</oasis:entry>  
         <oasis:entry colname="col2"><inline-formula><mml:math id="M74" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.1</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1.8</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math id="M75" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.002</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.003</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col4"><inline-formula><mml:math id="M76" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.1</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1.7</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col5"><inline-formula><mml:math id="M77" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.004</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.003</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">FAT/HNX</oasis:entry>  
         <oasis:entry colname="col2"><inline-formula><mml:math id="M78" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.0</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1.5</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math id="M79" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.003</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.002</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col4">N<inline-formula><mml:math id="M80" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula>A</oasis:entry>  
         <oasis:entry colname="col5">N<inline-formula><mml:math id="M81" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula>A</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">PTH</oasis:entry>  
         <oasis:entry colname="col2"><inline-formula><mml:math id="M82" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.3</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1.6</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math id="M83" display="inline"><mml:mrow><mml:mo>+</mml:mo><mml:mn mathvariant="normal">0.022</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.002</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col4">N<inline-formula><mml:math id="M84" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula>A</oasis:entry>  
         <oasis:entry colname="col5">N<inline-formula><mml:math id="M85" display="inline"><mml:mo>/</mml:mo></mml:math></inline-formula>A</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">LDR</oasis:entry>  
         <oasis:entry colname="col2"><inline-formula><mml:math id="M86" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.1</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1.8</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math id="M87" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.022</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.003</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col4"><inline-formula><mml:math id="M88" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.3</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1.3</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col5"><inline-formula><mml:math id="M89" display="inline"><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">0.066</mml:mn><mml:mo>±</mml:mo><mml:mn mathvariant="normal">0.002</mml:mn><mml:mspace width="0.125em" linebreak="nobreak"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

</sec>
<sec id="Ch1.S2.SS2">
  <title>Data format conversion and initial comparison of datasets</title>
      <p>The NOAA processed data were converted to “long line format” (LLF) files.  These files are actually the image of the information sent
to printers in the 1990s version of the data stream. The select values for the WOUDC and NDACC archives were originally produced from
these files, using a process of both machine and inspection by personnel. Programs were developed to convert the LLF and dayfiles into
formats compatible with the WinDobson data stream.  Files with instrument, station and calibration information (parafiles) were also
developed to complete the structure of the WinDobson system.  Connections to other sources of TOC information (satellite data records,
for example) were developed so that comparisons with these values could be performed using tools internal to WinDobson. Reference lamp
values were extracted from the LLF records for time periods prior to 1995 and from the dayfiles afterwards. By the end of 2015, all
operational stations' data were being processed in WinDobson.</p>
      <p>Initially, the datasets of only ADDS
(fundamental wavelength pairs) observations from the two processing streams
were compared with the expectation that the results should agree within
<inline-formula><mml:math id="M90" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="normal">DU</mml:mi></mml:mrow></mml:math></inline-formula>. The ADDS observations are considered the most reliable
(fundamental), as the equation derived for conversion to ozone minimizes the
Rayleigh scattering term, and the aerosol term can be considered to be zero.
Time periods with differences greater than this <inline-formula><mml:math id="M91" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula> <inline-formula><mml:math id="M92" display="inline"><mml:mi mathvariant="normal">DU</mml:mi></mml:math></inline-formula> were
investigated to determine the source of the problem, and correct any
differences. When the ADDS differences were reconciled, the ZS observations
were compared to the DS observations to define a polynomial method within the
WinDobson system for converting the ZS observations to TOC. Separate
polynomials were defined for various time periods related to instrument
repairs and calibration changes. The change in the methods of reduction of ZS
measurements often produced large changes in reported TOC values. The
improvement in the ZS results with respect to the ADDS results is displayed
in Fig. 2 and in Table 3. The new method has resulted in <inline-formula><mml:math id="M93" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">91</mml:mn></mml:mrow></mml:math></inline-formula> % of
ZS-derived total ozone (ADZB) within 2 % of the coincident DS ozone
column (ADDS). This is an improvement over the 78 % value reported in the
Operations Handbook (Komhyr and Evans, 2008). Results of observations made on
the direct sun using the CD wavelength pairs differ from those made on AD
pairs. The differences come primarily from imperfect knowledge of the ozone
cross sections used to determine the absorption coefficients used in the
algorithm and of the optical characteristics of the instrument (Redondas
et al., 2014). The differences in observational results within a specific SZA
range were analyzed, and a multiplying factor was established to bring the
average of the CD results to that of the AD results with in the WinDobson
system.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T3" specific-use="star"><caption><p>Displayed is the cumulative agreement in percent for specific ZS and
CDDS results compared to ADDS results on the same day. For example, an
agreement of 2 % occurs in 91 % of the cases for ADZB observations.
Displayed are the average of 12 stations in the NOAA network (Barrow,
Fairbanks, Caribou, Bismarck, Haute Provence, Boulder, Wallops Island, Mauna
Loa, Tutuila, Perth, Lauder and South Pole). Definitions of all abbreviations are in Sect. 1.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="8">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:colspec colnum="8" colname="col8" align="right"/>
     <oasis:thead>
       <oasis:row>  
         <oasis:entry colname="col1">%</oasis:entry>  
         <oasis:entry colname="col2">ADZB</oasis:entry>  
         <oasis:entry colname="col3">ADZC</oasis:entry>  
         <oasis:entry colname="col4">CDZB</oasis:entry>  
         <oasis:entry colname="col5">CDZC</oasis:entry>  
         <oasis:entry colname="col6">CDDS</oasis:entry>  
         <oasis:entry colname="col7">CC<inline-formula><mml:math id="M94" display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula>ZB</oasis:entry>  
         <oasis:entry colname="col8">CC<inline-formula><mml:math id="M95" display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula>ZC</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">difference</oasis:entry>  
         <oasis:entry colname="col2">(%)</oasis:entry>  
         <oasis:entry colname="col3">(%)</oasis:entry>  
         <oasis:entry colname="col4">(%)</oasis:entry>  
         <oasis:entry colname="col5">(%)</oasis:entry>  
         <oasis:entry colname="col6">(%)</oasis:entry>  
         <oasis:entry colname="col7">(%)</oasis:entry>  
         <oasis:entry colname="col8">(%)</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1">from ADDS</oasis:entry>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>  
         <oasis:entry colname="col6"/>  
         <oasis:entry colname="col7"/>  
         <oasis:entry colname="col8"/>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>  
         <oasis:entry colname="col1">0</oasis:entry>  
         <oasis:entry colname="col2">33</oasis:entry>  
         <oasis:entry colname="col3">25</oasis:entry>  
         <oasis:entry colname="col4">22</oasis:entry>  
         <oasis:entry colname="col5">20</oasis:entry>  
         <oasis:entry colname="col6">22</oasis:entry>  
         <oasis:entry colname="col7">20</oasis:entry>  
         <oasis:entry colname="col8">14</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">1</oasis:entry>  
         <oasis:entry colname="col2">74</oasis:entry>  
         <oasis:entry colname="col3">61</oasis:entry>  
         <oasis:entry colname="col4">54</oasis:entry>  
         <oasis:entry colname="col5">47</oasis:entry>  
         <oasis:entry colname="col6">56</oasis:entry>  
         <oasis:entry colname="col7">55</oasis:entry>  
         <oasis:entry colname="col8">41</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">2</oasis:entry>  
         <oasis:entry colname="col2">91</oasis:entry>  
         <oasis:entry colname="col3">81</oasis:entry>  
         <oasis:entry colname="col4">78</oasis:entry>  
         <oasis:entry colname="col5">72</oasis:entry>  
         <oasis:entry colname="col6">79</oasis:entry>  
         <oasis:entry colname="col7">74</oasis:entry>  
         <oasis:entry colname="col8">68</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">3</oasis:entry>  
         <oasis:entry colname="col2">96</oasis:entry>  
         <oasis:entry colname="col3">90</oasis:entry>  
         <oasis:entry colname="col4">90</oasis:entry>  
         <oasis:entry colname="col5">86</oasis:entry>  
         <oasis:entry colname="col6">90</oasis:entry>  
         <oasis:entry colname="col7">84</oasis:entry>  
         <oasis:entry colname="col8">82</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">4</oasis:entry>  
         <oasis:entry colname="col2">98</oasis:entry>  
         <oasis:entry colname="col3">94</oasis:entry>  
         <oasis:entry colname="col4">95</oasis:entry>  
         <oasis:entry colname="col5">92</oasis:entry>  
         <oasis:entry colname="col6">95</oasis:entry>  
         <oasis:entry colname="col7">90</oasis:entry>  
         <oasis:entry colname="col8">91</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">5</oasis:entry>  
         <oasis:entry colname="col2">99</oasis:entry>  
         <oasis:entry colname="col3">96</oasis:entry>  
         <oasis:entry colname="col4">97</oasis:entry>  
         <oasis:entry colname="col5">96</oasis:entry>  
         <oasis:entry colname="col6">97</oasis:entry>  
         <oasis:entry colname="col7">94</oasis:entry>  
         <oasis:entry colname="col8">96</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">6</oasis:entry>  
         <oasis:entry colname="col2">99</oasis:entry>  
         <oasis:entry colname="col3">97</oasis:entry>  
         <oasis:entry colname="col4">98</oasis:entry>  
         <oasis:entry colname="col5">97</oasis:entry>  
         <oasis:entry colname="col6">98</oasis:entry>  
         <oasis:entry colname="col7">95</oasis:entry>  
         <oasis:entry colname="col8">98</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">7</oasis:entry>  
         <oasis:entry colname="col2">99</oasis:entry>  
         <oasis:entry colname="col3">98</oasis:entry>  
         <oasis:entry colname="col4">99</oasis:entry>  
         <oasis:entry colname="col5">98</oasis:entry>  
         <oasis:entry colname="col6">98</oasis:entry>  
         <oasis:entry colname="col7">96</oasis:entry>  
         <oasis:entry colname="col8">98</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1">8</oasis:entry>  
         <oasis:entry colname="col2">100</oasis:entry>  
         <oasis:entry colname="col3">99</oasis:entry>  
         <oasis:entry colname="col4">100</oasis:entry>  
         <oasis:entry colname="col5">98</oasis:entry>  
         <oasis:entry colname="col6">99</oasis:entry>  
         <oasis:entry colname="col7">96</oasis:entry>  
         <oasis:entry colname="col8">98</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Frequency</oasis:entry>  
         <oasis:entry colname="col2">ADZB</oasis:entry>  
         <oasis:entry colname="col3">ADZC</oasis:entry>  
         <oasis:entry colname="col4">CDZB</oasis:entry>  
         <oasis:entry colname="col5">CDZC</oasis:entry>  
         <oasis:entry colname="col6">CDDS</oasis:entry>  
         <oasis:entry colname="col7">CC<inline-formula><mml:math id="M96" display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula>ZB</oasis:entry>  
         <oasis:entry colname="col8">CC<inline-formula><mml:math id="M97" display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula>ZC</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">85</oasis:entry>  
         <oasis:entry colname="col2">1.5</oasis:entry>  
         <oasis:entry colname="col3">2.3</oasis:entry>  
         <oasis:entry colname="col4">2.5</oasis:entry>  
         <oasis:entry colname="col5">3.0</oasis:entry>  
         <oasis:entry colname="col6">2.5</oasis:entry>  
         <oasis:entry colname="col7">3.3</oasis:entry>  
         <oasis:entry colname="col8">3.3</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">90</oasis:entry>  
         <oasis:entry colname="col2">1.9</oasis:entry>  
         <oasis:entry colname="col3">3.0</oasis:entry>  
         <oasis:entry colname="col4">3.0</oasis:entry>  
         <oasis:entry colname="col5">3.6</oasis:entry>  
         <oasis:entry colname="col6">3.0</oasis:entry>  
         <oasis:entry colname="col7">4.0</oasis:entry>  
         <oasis:entry colname="col8">3.8</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <?xmltex \floatpos{t}?><fig id="Ch1.F3" specific-use="star"><caption><p>The probability of a daily value changing by a particular percentage
for each station. The red line is for ADDS-type observations; the blue for
all other types; the horizontal line is the percent of ADDS in the range <inline-formula><mml:math id="M98" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1</mml:mn><mml:mspace linebreak="nobreak" width="0.125em"/><mml:mi mathvariant="italic">%</mml:mi></mml:mrow></mml:math></inline-formula> differences.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://acp.copernicus.org/articles/17/12051/2017/acp-17-12051-2017-f03.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4" specific-use="star"><caption><p>Graphic representation of the changes in the Mauna Loa Observatory, Hawai'i, USA (19<inline-formula><mml:math id="M99" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 156<inline-formula><mml:math id="M100" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W; NDACC
station), record after the conversion into WinDobson processing. <bold>(a)</bold> The time record of total ozone measured at the station
from the start of observations through  2015 (or until the station was converted to WinDobson processing. <bold>(b)</bold> Percent
difference between daily WinDobson total ozone records compared to the WOUDC record (WinDobson–WOUDC). The red line is a linear
fit. <bold>(c)</bold> The same as <bold>(b)</bold> but for monthly and yearly averages (based on all the values in the month in each dataset).
The small white circles are averages made from DS observations only; the red symbols represent averages using all Dobson total
ozone records; the large black open circles are yearly averages of all observations, based on monthly averages. Large triangle
symbols indicate major calibration or instrument changes that lead to creating the new <inline-formula><mml:math id="M101" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> tables; however, not all calibration
checks of the station record are shown. For NDACC stations only: panel <bold>(d)</bold> is the same as <bold>(b)</bold> but for comparisons
with the data archived at NDACC center (WinDobson–NDACC). The black line is a linear fit. Panel <bold>(e)</bold> is the same as <bold>(c)</bold>
for comparisons with the NDACC archived monthly and yearly averages. NDACC values are not recorded as observation type.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://acp.copernicus.org/articles/17/12051/2017/acp-17-12051-2017-f04.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5" specific-use="star"><caption><p>Graphic representation of the changes in the South Pole, Antarctica (90<inline-formula><mml:math id="M102" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S, 59<inline-formula><mml:math id="M103" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E; NDACC station), record with the conversion into WinDobson processing.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://acp.copernicus.org/articles/17/12051/2017/acp-17-12051-2017-f05.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F6" specific-use="star"><caption><p>Graphic representation of the changes in the Bismarck, North Dakota, USA (47<inline-formula><mml:math id="M104" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 101<inline-formula><mml:math id="M105" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W), record with the conversion into WinDobson processing.</p></caption>
          <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://acp.copernicus.org/articles/17/12051/2017/acp-17-12051-2017-f06.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F7" specific-use="star"><caption><p>Graphic representation of the changes in the Caribou, Maine, USA (47<inline-formula><mml:math id="M106" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 68<inline-formula><mml:math id="M107" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W), record with the conversion into WinDobson processing.</p></caption>
          <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://acp.copernicus.org/articles/17/12051/2017/acp-17-12051-2017-f07.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F8" specific-use="star"><caption><p>Graphic representation of the changes in the Nashville, Tennessee, USA (36<inline-formula><mml:math id="M108" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 87<inline-formula><mml:math id="M109" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W), record with the conversion into WinDobson processing.</p></caption>
          <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://acp.copernicus.org/articles/17/12051/2017/acp-17-12051-2017-f08.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F9" specific-use="star"><caption><p>Graphic representation of the changes in the Fairbanks, Alaska, USA (65<inline-formula><mml:math id="M110" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 148<inline-formula><mml:math id="M111" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W), record with the conversion into WinDobson processing.</p></caption>
          <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://acp.copernicus.org/articles/17/12051/2017/acp-17-12051-2017-f09.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F10" specific-use="star"><caption><p>Graphic representation of the changes in the Boulder, Colorado, USA (40<inline-formula><mml:math id="M112" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 105<inline-formula><mml:math id="M113" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W, NDACC station), record with the conversion into WinDobson processing.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://acp.copernicus.org/articles/17/12051/2017/acp-17-12051-2017-f10.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F11" specific-use="star"><caption><p>Graphic representation of the changes in the Wallops Island Flight Center, Virginia, USA (38<inline-formula><mml:math id="M114" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 76<inline-formula><mml:math id="M115" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W; NDACC station), record with the conversion into WinDobson processing.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://acp.copernicus.org/articles/17/12051/2017/acp-17-12051-2017-f11.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F12" specific-use="star"><caption><p>Graphic representation of the changes in the NOAA/ESRL/GMD Observatory, Barrow, Alaska, USA (71<inline-formula><mml:math id="M116" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 157<inline-formula><mml:math id="M117" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W), record with the conversion into WinDobson processing.</p></caption>
          <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://acp.copernicus.org/articles/17/12051/2017/acp-17-12051-2017-f12.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F13" specific-use="star"><caption><p>Graphic representation of the changes in the NOAA/ESRL/GMD Observatory, American Samoa (14<inline-formula><mml:math id="M118" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S, 171<inline-formula><mml:math id="M119" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W; NDACC station), record with the conversion into WinDobson processing.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://acp.copernicus.org/articles/17/12051/2017/acp-17-12051-2017-f13.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F14" specific-use="star"><caption><p>Graphic representation of the changes in the Fresno and Hanford, California, USA (36<inline-formula><mml:math id="M120" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 120<inline-formula><mml:math id="M121" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W), record with the conversion into WinDobson processing.</p></caption>
          <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://acp.copernicus.org/articles/17/12051/2017/acp-17-12051-2017-f14.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F15" specific-use="star"><caption><p>Graphic representation of the changes in the Observatoire de Haute-Provence, France (44<inline-formula><mml:math id="M122" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 6<inline-formula><mml:math id="M123" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E; NDACC
station), record with the conversion into WinDobson processing.</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://acp.copernicus.org/articles/17/12051/2017/acp-17-12051-2017-f15.png"/>

        </fig>

      <?xmltex \floatpos{t}?><fig id="Ch1.F16" specific-use="star"><caption><p>Graphic representation of the changes in the Perth Airport, Western Australia, Australia (32<inline-formula><mml:math id="M124" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S, 116<inline-formula><mml:math id="M125" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E), record with the conversion into WinDobson processing.</p></caption>
          <?xmltex \igopts{width=398.338583pt}?><graphic xlink:href="https://acp.copernicus.org/articles/17/12051/2017/acp-17-12051-2017-f16.png"/>

        </fig>

</sec>
<sec id="Ch1.S2.SS3">
  <title>Comparison of WinDobson representative values with archived daily values</title>
      <p>The individual station records are archived as daily values in the World Ozone and Ultraviolet Radiation Data Centre (WOUDC) in Canada
(<uri>http://woudc.org/home.php</uri>). The format of reporting is a single value for the local day, but in UTC (universal time coordinated)
time with a resolution of an hour. The NDACC (<uri>http://www.ndsc.ncep.noaa.gov/data/</uri>) archive has the same TOC values for a subset
of the WOUDC stations but in a different format, with date and time in UTC. The reprocessed datasets will be archived in WOUDC and
NDACC. For each station, tools in WinDobson were used to make a dataset of daily representative TOC values. These datasets were
compared to the datasets of select values downloaded from the WOUDC and NDACC, and the differences were investigated. The history of
the instrument calibrations was again reviewed, and changes in the <inline-formula><mml:math id="M126" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> tables and the periods of the use of <inline-formula><mml:math id="M127" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> tables within the
WinDobson system were made as needed. The differences stem from a number of reasons.
<list list-type="bullet"><list-item>
      <p>There are data in the WOUDC dataset for some stations that were reported by earlier organizations. The processing and selection
rules for these data are unknown.</p></list-item><list-item>
      <p>The older (1995) processing included time periods of special processing to attempt to account for specific problems in the older
optics of specific instruments. This was accomplished by a modification to the reference lamp correction used in the data
processing. The lamp corrections for the pre-1995 processing were extracted from the LLF format and applied to the WinDobson data
process to introduce the correction applied in the earlier processing. In some cases, the full correction was not possible to
reproduce, so special <inline-formula><mml:math id="M128" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> tables were reconstructed from the information in the LLF format and applied on an annual basis. These
periods are displayed graphically and discussed in the individual station reports. The problems that the special processing were
attempting to correct were as follows:
<list list-type="bullet"><list-item>
      <p>The so-called mu dependency (Komhyr et al., 1995), where DS results are lower at low sun angles. As this effect is dependent on the
intensity of the input solar beam, and thus on the TOC, no attempt was made to account for this effect in WinDobson processing. This
problem is related to the internal scattered light in the instrument, which is difficult to evaluate.</p></list-item><list-item>
      <p>Drifts in the shape of “wedge” calibration. It is unclear how the drift correction was actually performed in earlier
processing; no attempt was made to account for this effect in WinDobson processing. Newer construction of the optical wedges used in
the instrument have proved to have a much more stable calibration.</p></list-item><list-item>
      <p>Drifts in the “extraterrestrial constant” as part of the calibration.  This was done in the WinDobson processing of later
data, but with a different scheme – multiple <inline-formula><mml:math id="M129" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> tables with shorter time periods of applicability.</p></list-item><list-item>
      <p>There was a weakness in the NOAA processing in choosing a select value for each day. During the original review of observations,
certain observations were rejected for selection; this rejection was not recorded in the LLF files, and thus rejected observations
appeared in the WinDobson dataset. We scrutinized the record for these discrepancies and amended the results.</p></list-item></list></p></list-item><list-item>
      <p>The results of the zenith measurements changed due to updates to the reduction method, and these types of changes affect all
stations – some of the changes are large and are discussed in the individual station reports.</p></list-item><list-item>
      <p>For some stations, it is common for observations to be made throughout the local day but with later observations being on the
next consecutive UTC day.  This occurs at Lauder (LDR), Samoa (SMO) and the South Pole (SPO), where UTC dates change during normal
observing period. For SPO, observations on a local day can differ by 22 h; thus the choice of the selected/representative ozone in the
change from NOAA to WinDobson processing and selection may differ by 22 h. At certain times of the year, the TOC can change
appreciatively during this time period at SPO.</p></list-item><list-item>
      <p>Data archives sometimes failed to be updated after a calibration drift was detected during an intercomparison with
a standard. This is not necessarily a failure of the internal WOUDC archiving process. NDACC appears to capture these periods more
correctly.</p></list-item><list-item>
      <p>The rules for choosing the NOAA selected value for the day were similar to that of WinDobson but were not consistent throughout
the record or across stations, and the documentation of these rules is incomplete. For the WinDobson processing, the same rules are
applied throughout the record and stations and are described in Sect. 2.4.</p></list-item><list-item>
      <p>Our investigations of the station and instrument operation history revealed several periods for which different <inline-formula><mml:math id="M130" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> tables were
used in the archived records as compared to the historical record of NOAA <inline-formula><mml:math id="M131" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> tables. Also, when a station instrument is compared to
a standard instrument, and the results are within the uncertainty of the measurements (<inline-formula><mml:math id="M132" display="inline"><mml:mrow><mml:mo>±</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:math></inline-formula> %), the station instrument's
calibration is considered to be stable and thus is not changed.  Otherwise, the instrument's calibration is changed and the existing
data record starting from the time of the last comparison against a standard is reprocessed with the assumption that instrument's
calibration has changed in a linear manner. Using the tools in WinDobson, our studies of the stations' records allowed comparisons
with long-term records indicating TOC. These comparisons showed that at certain stations, the calibration change was not
linear. Further investigation of stations' history revealed damage to the instrument at that point (for example, rain entering the
instrument shelter). These investigations also identified instances where the comparison against the Dobson standard was not
performed correctly, and therefore the calibration should not have been changed.</p></list-item></list></p>
</sec>
<sec id="Ch1.S2.SS4">
  <title>WinDobson selection rules</title>
      <p>Often there are multiple observations on an individual day. The observations are given an internal numeric code in WinDobson, based on
the observation type and operator input about the observation. The representative value is chosen by the software with the priority
groups given below, highest to lowest.  These groups are based on Table 2 in the Operations Handbook (Komhyr and Evans, 2008). If there
are multiple observations of the highest priority on that day, the observation closest in time to local noon is chosen. After the
automatic selection, the daily representative values are reviewed by human inspection with possible intervention to select a different
value. The WinDobson software also has quality control routines that rates individual observations as good, questionable (flagged
yellow) and likely bad (flagged red), based on internal consistencies of the measurements. If an observation is rejected by the human
inspector, the observation is not removed from the data record but flagged as “not included”.</p>
      <p>Priority groups are listed here; operator inputs as to sky quality are included in determining priority:
<list list-type="order"><list-item>
      <p>Direct-sun observations using the AD pair combination with or without ground
quartz plate (diffuser) in the instrument's inlet window. Observations with
diffuser have higher priority.</p></list-item><list-item>
      <p>Zenith-sky observations using the AD pair combination. Observations on the
clear zenith have higher priority over those on cloudy conditions.</p></list-item><list-item>
      <p>Direct-sun observations using the CD pair combination with ground
quartz plate (diffuser) in the instrument's inlet window. Observations without
diffuser have lower priority.</p></list-item><list-item>
      <p>Zenith-sky observations using the CD pair combination. Observations on the
clear zenith have higher priority over those on cloudy conditions.</p></list-item><list-item>
      <p>Zenith-sky observations using the CC<inline-formula><mml:math id="M133" display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> pair combination. Observations on the
clear zenith have higher priority over those on cloudy conditions.</p></list-item><list-item>
      <p>Observations on light reflected from the moon. Observations using AD pair
combination have higher priority. Note these observations are rarely made
other than at the South Pole station during the austral winter.</p></list-item></list>
A discussion of the individual station records and the changes is presented
in the following section.</p>
      <p>The station discussions are accompanied by a referenced graphic of the
time-dependent differences, consisting of either three panels (all stations)
or five panels (NDACC stations). Panel A is the time record of total ozone
measured at the station from the start of observations through 2014 (or until
station was converted to WinDobson processing). Panel B is the percent
difference between daily WinDobson total ozone records compared to the WOUDC
record (WinDobson–WOUDC). The red line is a linear fit. Panel C is the same
as the second but for monthly and yearly averages (based on all the values in
the month in each dataset). The small white circles are averages made from DS
observations only, the red symbols represent averages using all Dobson total
ozone records and the large black open circles are yearly averages of all
observations, based on monthly averages. Large triangle symbols indicate
major calibration or instrument changes that lead to creating the new
<inline-formula><mml:math id="M134" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> tables; however, not all calibration checks of the station record are
shown as not all calibration checks revealed problems. For NDACC stations
only, panel D is the same as panel B but for comparisons with the
data archived at NDACC center (WinDobson–NDACC). The black line is a linear
fit. Panel E is the same as panel C for comparisons with the NDACC
archived monthly and yearly averages. NDACC values are not recorded as
observation type. Table 2 displays standard statistics of the differences
between WinDobson and WOUDC and between WinDobson and NDACC records.</p>
      <p>Assessment of changes in the WinDobson representative dataset relative to
WOUDC record is analyzed in the form of probability distributions, where
percent differences in TOC are plotted (Fig. 3) as a function of likely change
when the archive is updated. The datasets analyses are separated into ADDS
and other type of measurements. The ADDS curves are symmetric and
indicate that the vast majority of ADDS values will be unchanged. The
“other” curves are less symmetric and are driven by the updated ZS
reduction polynomials. As the overall record average offsets are small
(<inline-formula><mml:math id="M135" display="inline"><mml:mrow><mml:mo>&lt;</mml:mo><mml:mn mathvariant="normal">1.0</mml:mn></mml:mrow></mml:math></inline-formula> %), this is an indication of the number of ADDS
observations vs. other observation types.</p>
<sec id="Ch1.S2.SS4.SSS1">
  <?xmltex \opttitle{Mauna Loa Observatory, Hawai'i, USA (19{${}^{{\circ}}$}\,N, 156{${}^{{\circ}}$}\,W; NDACC station)}?><title>Mauna Loa Observatory, Hawai'i, USA (19<inline-formula><mml:math id="M136" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 156<inline-formula><mml:math id="M137" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W; NDACC station)</title>
      <p>Observations at MLO were started in December 1957. The instrument was
damaged in 1961, and thus the calibration is unknown prior to 1963. Before
1984, the primary instrument was D063, with short periods with other
instruments. The data in the archive prior to 1984 were not processed in the
standard method in an attempt to account for instrument calibration drifts
and other instrument problems, which causes larger variation in the
comparison of original to the WinDobson record prior to 1984. The automated
instrument D076 was installed at the station in 1984 after rebuilding in
Boulder. A mirror deteriorated, so the calibration in the period 1990–1995
(indicated by the yearly <inline-formula><mml:math id="M138" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> table triangles) is based on comparisons with
World Standard Dobson D083 while it was on station for Langley plot
campaigns. (The Langley plot method is used to establish an
extraterrestrial constant for an instrument; Langley, 1884.) This new
calibration is not reflected in the WOUDC or NDACC archives. The instrument
was rebuilt and the WinDobson automation installed in June 2010. Data from
2010 to 2014 were processed in the NOAA system after converting
WinDobson data files to a format compatible with the NOAA system. The
NDACC archive appears to have updates not reflected in the WOUDC Archive,
but there are periods with data missing from the NDACC archive (July–December 2012). The difference between the WOUDC and NDACC archive records
processed in the NOAA system and WinDobson system is presented graphically
in Fig. 4.</p>
</sec>
<sec id="Ch1.S2.SS4.SSS2">
  <?xmltex \opttitle{South Pole, Antarctica (90{${}^{{\circ}}$}\,S, 59{${}^{{\circ}}$}\,E; NDACC station)}?><title>South Pole, Antarctica (90<inline-formula><mml:math id="M139" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S, 59<inline-formula><mml:math id="M140" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E; NDACC station)</title>
      <p>The South Pole station was established in 1957. The first Dobson instrument
failed due to the extreme cold. Observations started again in 1961 and
these results are in the NOAA archive, but the calibration record dates from
1963. The normal routine established in 1985 was to change the instrument
every 4 years for calibration checks, but this was not always achieved. This station has the possibility of large changes in reported daily values
in the WinDobson, primarily due to the extended daily observation period,
and high variation in total ozone during certain periods of the year. The
station local day is the same as that of Christchurch, New Zealand, for ease
of logistics, but the Dobson observations are reported in the WOUDC in UTC
date and hour. The date and time combination often is misleading (for
example, in the WOUDC archive, 14 November 1994 has a time of 28 h UTC,
which matches the WinDobson and NDACC 15 November 1994 values). The
calculation of the astronomical parameters used in the algorithm for
reducing reflected moon observations was incorrect in the NOAA program
throughout the period of record. Changes in the method of deriving total
ozone from ZS observations improved the average with respect to DS averages
but creates differences between the old and new archives. There are
several periods missing from the WOUDC and NDACC archives (for example, July
through December 2002). The difference between the WOUDC and NDACC
archive records processed in the NOAA system and WinDobson system is
presented graphically in Fig. 5. The exclusion of low TOC values in early
October in the archived data (small white circles are outside of the plot
range) in some years also produces large percentage differences in the
averages (see large deviations in open circles seen in some years in the
panels c and e). An example is October 1994, where there are 25 reported
days in the WinDobson record but only 18 reported in the WOUDC and only 10
in the NDACC archive. These inconsistencies can produce large percentage
differences, especially during low ozone conditions.</p>
      <p>The rules for selection and inclusion of days in the archives appear have
been inconsistent in earlier (NOAA) processing and archiving. The NDACC
archive prior to 1999 has TOC expressed as vertical column density
(<inline-formula><mml:math id="M141" display="inline"><mml:mrow><mml:mi mathvariant="normal">molecules</mml:mi><mml:mspace linebreak="nobreak" width="0.125em"/><mml:msup><mml:mi mathvariant="normal">cm</mml:mi><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup></mml:mrow></mml:math></inline-formula>). These numbers appear to have been calculated from DU, as
this archive is derived from the WOUDC archive. There are periods where
this calculation was done incorrectly (for example, October 1998, where the
NDACC values differ by more than 100 <inline-formula><mml:math id="M142" display="inline"><mml:mi mathvariant="normal">DU</mml:mi></mml:math></inline-formula> when converted back to DU). While
the NDACC archive is supposed to be derived from the same internal NOAA
archive as WOUDC, there are random differences (for example, February 1981
is missing from the NDACC archive). The change in the yearly cycle of TOC
(panel A) is evident in the austral spring due the depletion related to
chlorofluorocarbon release (Farman etal, 1985). Station and observing
schedules were changed to accommodate research needs after  1985.</p>
</sec>
<sec id="Ch1.S2.SS4.SSS3">
  <?xmltex \opttitle{Bismarck, North Dakota, USA (47{${}^{{\circ}}$}\,N, 101{${}^{{\circ}}$}\,W)}?><title>Bismarck, North Dakota, USA (47<inline-formula><mml:math id="M143" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 101<inline-formula><mml:math id="M144" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W)</title>
      <p>The instrument is operated by the US National Weather Service office at
Bismarck Airport. There are observations in the archive from the late
1950s, but the documented record starts in December 1962. The difference
between the WOUDC and NDACC archive records processed in the NOAA system
and WinDobson system is presented graphically in Fig. 6. The periods where
the <inline-formula><mml:math id="M145" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> tables were reconstructed from the results of the special processing
in 1995 are indicated by the yearly <inline-formula><mml:math id="M146" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> table triangles. The instrument's
calibration has been quite stable since 1995.</p>
</sec>
<sec id="Ch1.S2.SS4.SSS4">
  <?xmltex \opttitle{Caribou, Maine, USA (47{${}^{{\circ}}$}\,N, 68{${}^{{\circ}}$}\,W)}?><title>Caribou, Maine, USA (47<inline-formula><mml:math id="M147" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 68<inline-formula><mml:math id="M148" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W)</title>
      <p>The instrument is operated at the National Weather Service office at the
Caribou Airport. There are observations in the archive from the late 1950s,
but the documented record starts in August 1962. The Weather Service office
was rebuilt in the early 2000s, with data gaps during that period of the
record. The difference between the WOUDC and NDACC archive records
processed in the NOAA system and WinDobson system is presented graphically
in Fig. 7. The periods where the <inline-formula><mml:math id="M149" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> tables were reconstructed from the
results of the special processing in 1995 are indicated by the yearly
<inline-formula><mml:math id="M150" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> table triangles. The instrument's calibration has been quite stable since
1995.</p>
</sec>
<sec id="Ch1.S2.SS4.SSS5">
  <?xmltex \opttitle{Nashville, Tennessee, USA (36{${}^{{\circ}}$}\,N, 87{${}^{{\circ}}$}\,W)}?><title>Nashville, Tennessee, USA (36<inline-formula><mml:math id="M151" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 87<inline-formula><mml:math id="M152" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W)</title>
      <p>The instrument is operated at the National Weather Service office near Old
Hickory, Tennessee. There are observations in the archive from the late
1950s, but the documented record starts in July 1962. This station record
shows a larger offset (<inline-formula><mml:math id="M153" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula>0.6 %) between the WOUDC and WinDobson datasets due to the change to the zenith observations results. The difference
between the WOUDC and NDACC archive records processed in the NOAA system
and WinDobson system is presented graphically in Fig. 8. The periods where
the <inline-formula><mml:math id="M154" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> tables were reconstructed from the results of the special processing
in 1995 are indicated by the yearly <inline-formula><mml:math id="M155" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> table triangles.</p>
</sec>
<sec id="Ch1.S2.SS4.SSS6">
  <?xmltex \opttitle{Fairbanks, Alaska, USA (65{${}^{{\circ}}$}\,N, 148{${}^{{\circ}}$}\,W)}?><title>Fairbanks, Alaska, USA (65<inline-formula><mml:math id="M156" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 148<inline-formula><mml:math id="M157" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W)</title>
      <p>Observations were started at the Fairbanks airport in 1964 using instrument D076 but ceased in 1972. The values in the WOUDC archive
in the 1964–1972 period do not correspond to the values in the older NOAA internal archive for reasons not determined. Observations
were restarted at the Poker Flat Research Range (65<inline-formula><mml:math id="M158" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 147<inline-formula><mml:math id="M159" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W) in 1985. The mission of the range changed in 1993 and
the Dobson shelter was moved to the roof of the Geophysical Institute at the University of Fairbanks. Operations restarted in
April 1994. This station is at 65<inline-formula><mml:math id="M160" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, with observations on low sun with high ozone amounts common, especially in March and
April. Researchers are advised that this instrument shows patterns in the comparison with other instrumentation that imply an under
estimation of ozone on the ADDS wavelength under conditions of low sun and high ozone. The older NOAA processing and selection of
observations was different from other stations, as CD pair combinations were often selected over AD pair combinations, while WinDobson
uses the same rules for all stations. This change in selection is reflected in the variability in the comparison with WOUDC
archive. The difference between the WOUDC archive records processed in the NOAA system and WinDobson system is presented graphically
in Fig. 9.</p>
</sec>
<sec id="Ch1.S2.SS4.SSS7">
  <?xmltex \opttitle{Boulder, Colorado, USA (40{${}^{{\circ}}$}\,N, 105{${}^{{\circ}}$}\,W, NDACC station)}?><title>Boulder, Colorado, USA (40<inline-formula><mml:math id="M161" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 105<inline-formula><mml:math id="M162" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W, NDACC station)</title>
      <p>Dobson observations were started at the University of Colorado east campus in
1966. Earlier observations were made either at the National Center for
Atmospheric Research or at the Table Mountain facility north of Boulder. The
station was moved to the David Skaggs Research Center in 1999. Multiple
instruments have been used here in the record, especially prior to the
automation of Dobson instrument D061 in 1980. The observations made after
1980 automation do not include CC<inline-formula><mml:math id="M163" display="inline"><mml:msup><mml:mi/><mml:mo>′</mml:mo></mml:msup></mml:math></inline-formula> zenith observations. The
instrument was rebuilt with the WinDobson automation, but the data were
processed in the NOAA system until the beginning of 2015. There is data in
the WOUDC archive prior to 1966 but not connected to a calibration. The data
for July 2013 to July 2014 are missing from the WOUDC and NDACC archives. The
periods 1992–1996 and 1998–2005 were not processed or archived using the
correct calibration information. The difference between the WOUDC and NDACC
archive records processed in the NOAA system and WinDobson system is
presented graphically in Fig. 10. The instrument's calibration is tracked
more closely than at other stations, as the World Standard Dobson D083 is
kept in Boulder.</p>
</sec>
<sec id="Ch1.S2.SS4.SSS8">
  <?xmltex \opttitle{Wallops Island Flight Center, Virginia, USA (38{${}^{{\circ}}$}\,N, 76{${}^{{\circ}}$}\,W; NDACC station)}?><title>Wallops Island Flight Center, Virginia, USA (38<inline-formula><mml:math id="M164" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 76<inline-formula><mml:math id="M165" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W; NDACC station)</title>
      <p>Dobson observations were started at WIFC in 1967 as support for balloon- and rocket-borne experiments. The station has moved several
times to different sites within the facility. Since 1995 only ADDS observations are made to support ozonesonde flights. There are
periods in the WOUDC and NDACC archives with either missing data or archived with incorrect calibration. The
difference between the WOUDC and NDACC archive records processed in the NOAA system and WinDobson system is presented graphically in
Fig. 11.</p>
</sec>
<sec id="Ch1.S2.SS4.SSS9">
  <?xmltex \opttitle{NOAA/ESRL/GMD Observatory, Barrow, Alaska, USA (71{${}^{{\circ}}$}\,N, 157{${}^{{\circ}}$}\,W)}?><title>NOAA/ESRL/GMD Observatory, Barrow, Alaska, USA (71<inline-formula><mml:math id="M166" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 157<inline-formula><mml:math id="M167" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W)</title>
      <p>Dobson observations at the NOAA observatory began in 1973. The instrument was out of operation between 1983 and 1986 due to lack of
funding. The difference between the WOUDC archive processed in the NOAA system and WinDobson system is presented graphically in
Fig. 12. The station's weather is far cloudier than at other stations, with the station reporting 58 % ZS observations. The change
in the method for retrieving TOC from these observations is evident in the variability in the differences between the archives.</p>
</sec>
<sec id="Ch1.S2.SS4.SSS10">
  <?xmltex \opttitle{NOAA/ESRL/GMD Observatory, American Samoa (14{${}^{{\circ}}$}\,S, 171{${}^{{\circ}}$}\,W; NDACC station)}?><title>NOAA/ESRL/GMD Observatory, American Samoa (14<inline-formula><mml:math id="M168" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S, 171<inline-formula><mml:math id="M169" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W; NDACC station)</title>
      <p>Dobson observations were started at the NOAA observatory in 1976. The station is in a warm, humid marine environment, which caused
instrument degradation in the early part of the record. The original processing pre-1995 was not standard and not repeatable. The
periods where the <inline-formula><mml:math id="M170" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> tables were reconstructed from the results of the special processing in 1995 are indicated by the yearly <inline-formula><mml:math id="M171" display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula> table
triangles. An earthquake and tsunami on  29 September 2009 damaged the station and instrument and observations were interrupted for
several years. The difference between the WOUDC and NDACC archive records processed in the NOAA system and WinDobson
system is
presented graphically in Fig. 13. The period 1999–2001 was not processed or archived using the correct calibration information. The
WOUDC and NDACC were not completely updated after observations were restarted due to perceived instrument problems which since have
been resolved.</p>
</sec>
<sec id="Ch1.S2.SS4.SSS11">
  <?xmltex \opttitle{Fresno and Hanford, California, USA (36{${}^{{\circ}}$}\,N, 120{${}^{{\circ}}$}\,W)}?><title>Fresno and Hanford, California, USA (36<inline-formula><mml:math id="M172" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 120<inline-formula><mml:math id="M173" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W)</title>
      <p>Dobson observations were started at the Fresno Weather Service Office, California (37<inline-formula><mml:math id="M174" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 120<inline-formula><mml:math id="M175" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W), in 1982, with
observations starting the next year. The Weather Service Office was moved to Hanford in March  1995. The difference between the WOUDC
and NDACC archive records processed in the NOAA system and WinDobson system is presented graphically in Fig. 14. There are very few
issues with the Fresno and Hanford records.</p>
</sec>
<sec id="Ch1.S2.SS4.SSS12">
  <?xmltex \opttitle{Observatoire de Haute-Provence, France (44{${}^{{\circ}}$}\,N, 6{${}^{{\circ}}$}\,E; NDACC station)}?><title>Observatoire de Haute-Provence, France (44<inline-formula><mml:math id="M176" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 6<inline-formula><mml:math id="M177" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E; NDACC station)</title>
      <p>Dobson observations were started at the Observatoire de Haute-Provence (Station Géophysique Gérard Mégie) in 1983 with an
automated instrument. This instrument was updated to the WinDobson automation and data processing in 2014. The station and instrument
are operated by the Centre National de la Recherché Scientifique (CNRS). The period of 1990 to 1999 was reprocessed to account for
calibration drift but has not yet been updated in WOUDC and NDACC. The difference between the WOUDC and NDACC archive records
processed in the NOAA system and WinDobson system is presented graphically in Fig. 15. The instrument was damaged several time in its
history; inspection within WinDobson resulted in the removal of days from inclusion in the record. This produced several months of
higher differences (February 2013, for example).</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F17" specific-use="star"><caption><p>Graphic representation of the changes in the Lauder, Central Otago, New Zealand (45<inline-formula><mml:math id="M178" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S, 170<inline-formula><mml:math id="M179" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E; NDACC station), record with the conversion into WinDobson processing.</p></caption>
            <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://acp.copernicus.org/articles/17/12051/2017/acp-17-12051-2017-f17.png"/>

          </fig>

</sec>
<sec id="Ch1.S2.SS4.SSS13">
  <?xmltex \opttitle{Perth Airport, Western Australia, Australia (32{${}^{{\circ}}$}\,S, 116{${}^{{\circ}}$}\,E)}?><title>Perth Airport, Western Australia, Australia (32<inline-formula><mml:math id="M180" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S, 116<inline-formula><mml:math id="M181" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E)</title>
      <p>Dobson observations were started originally in 1969 at Perth Airport weather radar,  Western Australia, then the NOAA automated
instrument D081 was installed in 1984. The instrument is operated by the Australian Bureau of Meteorology (BoM). In the late 1990s, the
station was moved to the newly constructed weather station. There are periods of missing data in the WOUDC archive. The period after
2012 in the WOUDC archive does not have correct calibration information, as the BoM recalibrated the instrument, and this information
was not included in NOAA's database of calibrations. The difference between the WOUDC and NDACC archive records processed in the NOAA
system and WinDobson system is presented graphically in Fig. 16.</p>
</sec>
<sec id="Ch1.S2.SS4.SSS14">
  <?xmltex \opttitle{Lauder, Central Otago, New Zealand (45{${}^{{\circ}}$}\,S, 170{${}^{{\circ}}$}\,E; NDACC station)}?><title>Lauder, Central Otago, New Zealand (45<inline-formula><mml:math id="M182" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> S, 170<inline-formula><mml:math id="M183" display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> E; NDACC station)</title>
      <p>Dobson observations began in early 1987 at the research station in Central Otago, South Island, New Zealand. The instrument is operated
by New Zealand's National Institute of Water and Atmospheric Research (NIWA). The station's time zone is UTC <inline-formula><mml:math id="M184" display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> 12, which means the
UTC day changes at noon local standard time. The calculation of the local day and UTC day for reporting the selected value was
incorrect prior to 1992, indicated by the higher scatter in the comparison of the old and new archives in that time period. Also,
a selected value could be from the afternoon of one local day and the representative value from the morning of the following local day
while still being in the same UTC day. When inspected during the WinDobson processing, the instrument record between 2006 and 2011
revealed rain damage following reinstallation shortly after the 2006 intercomparison in Melbourne. The 2012 calibration information
determined before the rebuilding of the instrument was used to process the data in WinDobson during 2006 through 2012. The inspection
also determined that the calibration was stable from 1992 to 2006, while the instrument calibration was checked in 1997 and 2001. The
WOUDC and NDACC records are not yet updated. The instrument was rebuilt at the beginning of 2012 and has been operated with the data
reduction in WinDobson since that time. The difference between the WOUDC and NDACC archive records processed in the NOAA system and
WinDobson system is presented graphically in Fig. 17.</p>
</sec>
</sec>
</sec>
<sec id="Ch1.S3" sec-type="conclusions">
  <title>Conclusions</title>
      <p>NOAA has submitted nearly a half-century's data into the WOUDC and NDACC
archives. Personnel and data processing protocols changed many times
throughout that period, and knowledge of early techniques was slowly lost.
Furthermore NOAA personnel tended to use a larger and more comprehensive
database when performing research, so the accuracy of data within the WOUDC
and NDACC archives was seldom questioned. Our experiences in the
investigation of the long-term archived NOAA Dobson data records should alert
other Dobson data producers of the importance of regular review and
intercomparisons of the archived station's records residing at multiple
archives. The Dobson station data processing procedures and software tend to
change over time after the new knowledge or technology becomes available.
Although the reprocessing of historical datasets is extremely difficult due
to lost documentation or even raw data, the benefit of the investigation is
record's homogenization and adjustment to conform to the WMO/GAW operating
procedure guidance (Komhyr and Evans, 2008). With the advent of WinDobson
software and its newer technique for calculating TOC from zenith observations
and selecting representative observations, we felt it was prudent to
reprocess all previous measurements for the sake of homogeneity. It also
seemed logical to compare and replace data within the WOUDC and NDACC
archives with the newly reprocessed data. The overall changes are small
(<inline-formula><mml:math id="M185" display="inline"><mml:mrow><mml:mo>∼</mml:mo><mml:mn mathvariant="normal">0.1</mml:mn></mml:mrow></mml:math></inline-formula> % offset), but several individual stations have a larger
offset (maximum 0.7 %) driven by the changes in the
ZC reduction polynomials. During comparisons between WinDobson dataset and the
existing NDACC and WOUDC archives, we were able identify periods with either
missing data or incorrectly processed data. The differences between the
historical and the new version of Dobson data have overall small offsets and
trends (Table 2), but within the long-term record there are periods with
greater differences of which researchers should be aware (see Figs. 4–16 and
description of the individual station histories). The paper includes
a section that describes individual station histories, which provides
information on specific-to-station updates and their effects on the total
ozone record. The offsets and trends for differences between the old and the
new version of the data are not the same for WOUDC and NDACC archives, as the
NDACC set of data is not a perfect match to the one available from the WOUDC
archive. For example, the Wallops Island NDACC record is 1995–2014, while
the WOUDC record is 1967–2014. When the NDACC and WOUDC archives are
updated, these archived datasets will be complete and homogenized. Moreover,
after all calibrations and the applicable periods were reviewed, the history
method of applying calibrations to all of the instruments in the networks has
been standardized. The new, complete (all observations) WinDobson operational
database, available to researchers on request, will allow investigators to
improve the accuracy and consistency of the Dobson retrieval algorithms and
stations records. The expectation is that in the future the WOUDC and NDACC
archives will consist of all observation results.</p>
</sec>

      
      </body>
    <back><notes notes-type="dataavailability">

      <p>The new WinDobson data are now available from
<uri>ftp://aftp.cmdl.noaa.gov/data/ozwv/Dobson/WinDobson/</uri>. The WOUDC archive
is available from <uri>http://woudc.org/</uri>, and the NDACC archive is available
from <uri>ftp://ftp.cpc.ncep.noaa.gov/ndacc/</uri>. The WinDobson software as
extended by NOAA, Level 0 Dobson data, and calibration records are available
on request to NOAA Dobson network personnel.</p>
  </notes><notes notes-type="competinginterests">

      <p>The authors declare that they have no conflict of
interest.</p>
  </notes><notes notes-type="sistatement">

      <p>This article is part of the special issue “Twenty-five years of
operations of the Network for the Detection of Atmospheric Composition Change
(NDACC) (AMT/ACP/ESSD inter-journal SI)”. It is not associated with a
conference.</p>
  </notes><ack><title>Acknowledgements</title><p>The authors would like to acknowledge the work done in the past by such people as Walter Komhyr, Robert Grass and Kent Leonard  in establishing the US Dobson ozone network.</p><p>The Dobson observations at Lauder are supported through NIWA's core research funded by the NZ Ministry of Business, Innovation and
Employment; at Perth by the Bureau of Meteorology, an executive agency of the Australian government; and at l'Observatoire du Haute-Provence
by the National Center for Scientific Research (CNRS), under the responsibility of the French Ministry of Education and
Research. Support for  updating of the automation at several NDACC sites was provided by the NOAA Joint Polar Satellite System
(JPSS) Calibration/Validation program.<?xmltex \hack{\newline}?><?xmltex \hack{\newline}?>
Edited by: Hal Maring<?xmltex \hack{\newline}?>
Reviewed by: three anonymous referees</p></ack><ref-list>
    <title>References</title>

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  </ref-list><app-group content-type="float"><app><title/>

    </app></app-group></back>
    <!--<article-title-html>Technical note: The US Dobson station network data record prior to 2015, re-evaluation of NDACC and WOUDC archived records with WinDobson processing software</article-title-html>
<abstract-html><p class="p">The United States government has operated Dobson ozone spectrophotometers at
various sites, starting during the International Geophysical Year
(1 July 1957 to 31 December 1958). A network of stations for long-term
monitoring of the total column content (thickness of the ozone layer) of the
atmosphere was established in the early 1960s and eventually grew to 16
stations, 14 of which are still operational and submit data to the United
States of America's National Oceanic and Atmospheric Administration (NOAA).
Seven of these sites are also part of the Network for the Detection of
Atmospheric Composition Change (NDACC), an organization that maintains its
own data archive. Due to recent changes in data processing software the
entire dataset was re-evaluated for possible changes. To evaluate and
minimize potential changes caused by the new processing software, the
reprocessed data record was compared to the original data record archived in
the World Ozone and UV Data Center (WOUDC) in Toronto, Canada. The history of
the observations at the individual stations, the instruments used for the
NOAA network monitoring at the station, the method for reducing zenith-sky
observations to total ozone, and calibration procedures were re-evaluated
using data quality control tools built into the new software. At the
completion of the evaluation, the new datasets are to be published as an
update to the WOUDC and NDACC archives, and the entire dataset is to be made
available to the scientific community. The procedure for reprocessing Dobson
data and the results of the reanalysis on the archived record are presented
in this paper. A summary of historical changes to 14 station records is also
provided.</p></abstract-html>
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