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  <front>
    <journal-meta>
<journal-id journal-id-type="publisher">ACP</journal-id>
<journal-title-group>
<journal-title>Atmospheric Chemistry and Physics</journal-title>
<abbrev-journal-title abbrev-type="publisher">ACP</abbrev-journal-title>
<abbrev-journal-title abbrev-type="nlm-ta">Atmos. Chem. Phys.</abbrev-journal-title>
</journal-title-group>
<issn pub-type="epub">1680-7324</issn>
<publisher><publisher-name>Copernicus Publications</publisher-name>
<publisher-loc>Göttingen, Germany</publisher-loc>
</publisher>
</journal-meta>

    <article-meta>
      <article-id pub-id-type="doi">10.5194/acp-16-6475-2016</article-id><title-group><article-title>An evaluation of the impact of aerosol particles on weather forecasts
from a biomass burning aerosol event over the Midwestern United States:
observational-based analysis of surface temperature</article-title>
      </title-group><?xmltex \runningtitle{An evaluation of the impact of aerosol particles on weather forecasts}?><?xmltex \runningauthor{J.~Zhang et al.}?>
      <contrib-group>
        <contrib contrib-type="author" corresp="yes" rid="aff1">
          <name><surname>Zhang</surname><given-names>Jianglong</given-names></name>
          <email>jzhang@atmos.und.edu</email>
        <ext-link>https://orcid.org/0000-0001-8647-3519</ext-link></contrib>
        <contrib contrib-type="author" corresp="no" rid="aff2">
          <name><surname>Reid</surname><given-names>Jeffrey S.</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff1">
          <name><surname>Christensen</surname><given-names>Matthew</given-names></name>
          
        </contrib>
        <contrib contrib-type="author" corresp="no" rid="aff3">
          <name><surname>Benedetti</surname><given-names>Angela</given-names></name>
          
        <ext-link>https://orcid.org/0000-0002-9971-9976</ext-link></contrib>
        <aff id="aff1"><label>1</label><institution>Department of Atmospheric Sciences, University of North Dakota, Grand Forks, ND, USA</institution>
        </aff>
        <aff id="aff2"><label>2</label><institution>Marine Meteorology Division, Naval Research Laboratory, Monterey, CA, USA</institution>
        </aff>
        <aff id="aff3"><label>3</label><institution>European Centre for Medium-Range Weather Forecasts, Reading, UK</institution>
        </aff>
      </contrib-group>
      <author-notes><corresp id="corr1">Jianglong Zhang (jzhang@atmos.und.edu)</corresp></author-notes><pub-date><day>27</day><month>May</month><year>2016</year></pub-date>
      
      <volume>16</volume>
      <issue>10</issue>
      <fpage>6475</fpage><lpage>6494</lpage>
      <history>
        <date date-type="received"><day>10</day><month>December</month><year>2015</year></date>
           <date date-type="rev-request"><day>18</day><month>January</month><year>2016</year></date>
           <date date-type="rev-recd"><day>16</day><month>April</month><year>2016</year></date>
           <date date-type="accepted"><day>23</day><month>April</month><year>2016</year></date>
      </history>
      <permissions>
<license license-type="open-access">
<license-p>This work is licensed under a Creative Commons Attribution 3.0 Unported License. To view a copy of this license, visit <ext-link ext-link-type="uri" xlink:href="http://creativecommons.org/licenses/by/3.0/">http://creativecommons.org/licenses/by/3.0/</ext-link></license-p>
</license>
</permissions><self-uri xlink:href="https://acp.copernicus.org/articles/.html">This article is available from https://acp.copernicus.org/articles/.html</self-uri>
<self-uri xlink:href="https://acp.copernicus.org/articles/.pdf">The full text article is available as a PDF file from https://acp.copernicus.org/articles/.pdf</self-uri>


      <abstract>
    <p>A major continental-scale biomass burning smoke event from 28–30 June 2015,
spanning central Canada through the eastern seaboard of the United States,
resulted in unforecasted drops in daytime high surface temperatures on the
order of 2–5  <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C in the upper Midwest. This event, with strong smoke
gradients and largely cloud-free conditions, provides a natural laboratory
to study how aerosol radiative effects may influence numerical weather
prediction (NWP) forecast outcomes. Here, we describe the nature of this
smoke event and evaluate the differences in observed near-surface air
temperatures between Bismarck (clear) and Grand Forks (overcast smoke), to
evaluate to what degree solar radiation forcing from a smoke plume
introduces daytime surface cooling, and how this affects model bias in
forecasts and analyses. For this event, mid-visible (550 nm) smoke aerosol
optical thickness (AOT, <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">τ</mml:mi></mml:math></inline-formula>) reached values above 5. A direct surface
cooling efficiency of <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C per unit AOT (at 550 nm, <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>) was found. A further analysis of European Centre for Medium-Range
Weather Forecasts (ECMWF), National Centers for Environmental Prediction
(NCEP), United Kingdom Meteorological Office (UKMO) near-surface air
temperature forecasts for up to 54 h as a function of Moderate
Resolution Imaging Spectroradiometer (MODIS) Dark Target AOT data across
more than 400 surface stations, also indicated the presence of the daytime
aerosol direct cooling effect, but suggested a smaller aerosol direct
surface cooling efficiency with magnitude on the order of <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.25
to <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.0 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C per unit <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>. In addition, using
observations from the surface stations, uncertainties in near-surface air
temperatures from ECMWF, NCEP, and UKMO model runs are estimated. This study
further suggests that significant daily changes in <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> above 1,
at which the smoke-aerosol-induced direct surface cooling effect could be
comparable in magnitude with model uncertainties, are rare events on a
global scale. Thus, incorporating a more realistic smoke aerosol field into
numerical models is currently less likely to significantly improve the
accuracy of near-surface air temperature forecasts. However, regions such as
eastern China, eastern Russia, India, and portions of the Saharan and Taklamakan
deserts, where significant daily changes in AOTs are more frequent, are
likely to benefit from including an accurate aerosol analysis into numerical
weather forecasts.</p>
  </abstract>
    </article-meta>
  </front>
<body>
      

<sec id="Ch1.S1" sec-type="intro">
  <title>Introduction</title>
      <p>The impacts of aerosol particles on long-term climate variations have been
extensively studied from the standpoint of both their direct and indirect
effects (e.g., IPCC, 2013). It is frequently hypothesized that aerosol
particles impart a radiative perturbation that ultimately can alter overall
atmospheric temperature, and consequently boundary layer and flow patterns
(e.g., Cook and Highwood, 2004; Jacobson and Kaufman, 2006; Lau and Kim,
2006; Jacobson, 2014; Tesfaye et al., 2015, to name a few). However, the
climate impact of aerosol particles is derived from a mosaic of individual
aerosol events. Upscaling aerosol effects from individual weather phenomenon
to climate requires a thorough understanding of the nature of individual
aerosol events, how aerosol events relate to other meteorological forcing
terms, and the data and model tools used to diagnose outcomes. As one would
expect, focus in the community has been towards the direct radiative effects
of either climatologically mean aerosol characteristics within climate
models, or, on the other extreme, large aerosol outbreaks where the aerosol
signal is hopefully clearer and more tractable. But even for severe events,
diagnosing the extent of aerosol radiative effects on “real meteorology” is
a challenge. Due to model inadequacies, free-running models diverge from the
true atmospheric state. Numerical weather prediction (NWP) simulations, on
the other hand, in part compensate for aerosol radiative effects through the
assimilation of copious amounts of observations. Thus, one method for
assessing aerosol impacts on weather is to utilize coupled models or NWP
forecasts themselves, searching for indicators of aerosol impacts in short-
to medium-range forecasts with well-characterized initial conditions (e.g.,
Pérez et al., 2006; Chapman et al., 2009; Grell et al., 2011; Ge et al.,
2014; Mulcahy et al., 2014; Kolusu et al., 2015; Rémy et al., 2015).</p>
      <p>Biomass burning plumes and airborne dust are attractive classes of
phenomenon that lend themselves to studies of how aerosol particle radiative
effects can perturb the atmosphere. Indeed, smoke and dust plumes can cover
intercontinental scales with very high aerosol optical thickness (AOT, <inline-formula><mml:math display="inline"><mml:mi mathvariant="italic">τ</mml:mi></mml:math></inline-formula>).
Smoke is particularly amenable to natural laboratory studies as biomass
burning smoke, unlike dust, is largely a shortwave forcing agent, and thus
compensating long-wave effects are minimized. The plume nature of smoke also
allows a certain degree of control for underlying meteorology, and smoke
production is not directly coupled to the meteorology. Finally, smoke can
display a range of absorption and thus can vary between being a net warmer
and net cooler of the local environment, yet maintain net cooling at the
surface. Indeed, effects of significant biomass burning events on local
temperatures have long been noted. Through analysis of several significant
biomass burning events, Robock (1991) showed a 1–7 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C decrease in
near-surface air temperature with a possible maximum decrease of
20 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, due to smoke plumes. Using a numerical model, Westphal and
Toon (1991) simulated the effects of a massive 1982 fire, deriving surface
cooling of 8–10 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. Other studies have also suggested
incorporating aerosol events in numerical weather models for more accurate
weather forecasts over aerosol-contaminated regions (e.g., Robock, 1991;
Mulcahy et al., 2014).</p>
      <p>Integrating aerosol events into weather prediction models has not been an
easy task in the past as aerosol particles have high variability in both
spatial and temporal domains. Thus far there has been little justification
for the computational expense to include aerosol particle radiative effects
in operational simulations relative to other areas, such as cloud
representation. However, in recent years, breakthrough advancements have been
made in both satellite aerosol data and aerosol data assimilation, resulting
in the development of both off- and in-line aerosol models at NWP centers
(e.g., Tanaka and Chiba, 2005; Zhang et al., 2008; Benedetti et al., 2009;
Colarco et al., 2010; Pérez et al., 2011; Kukkonen et al., 2012; Sessions
et al., 2015).</p>
      <p>From the point of view of satellite aerosol retrievals, regional and global
aerosol events have been routinely monitored with the use of both active- and
passive-based space borne sensors including Moderate Resolution Imaging
Spectroradiometer (MODIS), Multi-angle Imaging SpectroRadiometer (MISR), and
Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) on a daily basis
(e.g., Levy et al., 2013; Kahn et al., 2010; Hsu et al., 2013). From the
point of view of modeling, advanced data assimilation schemes, including
2D/3D/4D-Var and ensemble Kalman filter methods, have been applied to
assimilate satellite and ground-based observations (e.g., Zhang et al., 2008,
2011, 2014; Benedetti et al., 2009; Schutgens et al., 2010; Collins et al.,
2001; Yu et al., 2003; Generoso et al., 2007; Adhikary et al., 2008; Tombette
et al., 2008; Niu et al., 2008; Lin et al., 2008; Kahnert, 2008; Pagowski and
Grell, 2012; Rubin et al., 2016). The cumulative research progress in both
observational- and modeling-based aerosol studies has pushed the research
front to the edge of fully incorporating prognostic aerosol fields into
weather forecasting models.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F1" specific-use="star"><caption><p>Overview of the study region based on the RGB Aqua MODIS overpass of
29 June 2015 with marking of study domains (yellow boxes) and states referred
to in the text. Terra and Aqua fire hotspot detections for that day are also marked in red.</p></caption>
        <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://acp.copernicus.org/articles/16/6475/2016/acp-16-6475-2016-f01.pdf"/>

      </fig>

      <p>In realizing this potential, a few studies have attempted to incorporate
advanced aerosol schemes into numerical models for weather forecasting. For
example, some earlier studies have used the Weather Research and Forecasting (WRF)-Chem model for aerosol-related weather
research and forecasting (e.g., Chapman et al., 2009; Grell et al., 2011).
Kolusu et al. (2015) studied the impact of biomass burning events on weather
forecasts with the use of the UK Met Office Unified Model. However, no
significant improvements were reported in weather forecasts after the
inclusion of more complicated aerosol representations (e.g., Mulcahy et al.,
2014; Kolusu et al., 2015). Most recently, Rémy et al. (2015) studied the
radiative feedbacks of dust on boundary layer meteorology and found slight
improvements to surface temperature forecasts. The inability to significantly
improve weather forecasts via the incorporation of more realistic aerosol
data in the forecasting processes from these initial attempts could be from
multiple causes. It is possible that improvements in both quality and
quantity of aerosol observations are needed. It is also possible that
uncertainties from other sources in traditional weather forecasts exceed the
benefit of incorporating accurate aerosol features in weather forecasting
models. In addition, for regions with persistent aerosol contamination, the effect
of aerosol particles on weather forecasts may already, in part, be accounted
for through assimilation of temperature data that are already affected by the
direct cooling effect of aerosol plumes.</p>
      <p>In late June 2015, a rapidly evolving smoke aerosol event in the free
troposphere, originating from Canadian boreal fires, provided a near step
function in fine-mode AErosol RObotic NETwork (AERONET) 500 nm AOT (<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>) from 0.1 to over 4 in the upper Midwestern United States (Fig. 1 for a Aqua MODIS RGB regional overview for the peak of the event, Fig. 2
for a MODIS 4 day time series, and Fig. 2e for AERONET observations).
This event, when coupled with operational NWP models, provides a natural
laboratory for the evaluation of the direct effect of aerosol particles on
weather forecasts. The abrupt increase in daily mean aerosol loading was not
expected by either weather forecasters or modelers, leading to a noticeable
difference between forecasted and observed near-surface air temperatures for
29 and 30 June 2015 as the largely cloud-free smoke plume propagated from
Canada through the upper Midwest through the Ohio River Valley (Sect. 3
for details). This event then provided pairs of sites experiencing low
vs. high AOT environments. For example, while significant aerosol loading
is reported from the Grand Forks AERONET station (<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> &gt; 3), Bismarck, only 300 km to the west, experienced low
to mild aerosol loading with <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> of <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.1–0.4 as
reported from the Collection 6 Terra MODIS Dark Target AOT data. The sharp
spatial gradient in aerosol loading makes this case an opportunity for
further understanding the effects of smoke aerosol particles on forecasts of
surface temperature, and perhaps on any downstream dependencies such as
boundary layer height.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F2"><caption><p>Overview of the 29 June burning event. <bold>(a–d)</bold> MODIS Terra
RGB with daily combined MODIS active fire hotspot detections for
27–30 June. <bold>(e)</bold> Time series of AERONET fine-mode <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>500</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>,
sites marked 1–4 indicated on panels <bold>(a–d)</bold>.</p></caption>
        <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://acp.copernicus.org/articles/16/6475/2016/acp-16-6475-2016-f02.pdf"/>

      </fig>

      <p>This paper is the first of two that explore the NWP implications of the
29–30 June 2015 biomass burning event. Here, we describe the nature of the
event and demonstrate the daytime direct cooling effect of smoke aerosol
particles on the near-surface air temperature forecasts. This investigation
then constrains a follow-up study using the ECMWF forecast model through
(a) quantification of the daytime direct aerosol effects as a function of
altitude and aerosol loading; (b) establishment of the baseline uncertainties
in the modeled near-surface (1.5 to 2 m) air temperatures over the study
domain; and (c) investigation of the conditions under which aerosol-induced
cooling effects can be strong enough to significantly alter upper air
temperature and downstream dynamical forecasts.</p>
      <p><?xmltex \hack{\newpage}?>To meet these objectives, the impact of smoke aerosol particles on the
European Centre for Medium-Range Weather Forecasts (ECMWF) 2 m air
temperature forecasts and analyses are studied and regions that could
experience noticeable impacts of aerosols on weather forecasts are explored.
In addition, statistics are also generated for the National Centers for
Environmental Prediction (NCEP) and the United Kingdom Meteorological Office
(UKMO) ensemble data sets. This study is predominantly observational-based
and describes the overall nature of the event and the observed biases in NWP
forecasts. In a companion paper, a sensitivity study using in-line
simulations of the ECMWF forecast model is developed to further explore the
impacts of smoke aerosols on weather forecasts not only on surface
temperatures, but also on any other potential dynamical parameters such as
predicted boundary layer height, and geopotential heights and their
gradient.</p>
</sec>
<sec id="Ch1.S2">
  <title>Data sets</title>
      <p>This study focuses on the impact of the 29–30 June smoke event
on near-surface air temperature forecasts from three numerical weather
prediction models, ECMWF, NOAA NCEP Global Ensemble Forecast System (GEFS),
and UKMO Unified Model (UM). It includes their comparison to Automated
Surface Observing System (ASOS) surface data and National Weather Service
(NWS) forecasted temperature, controlled by AOT as derived from AERONET and
MODIS. The data are described below.</p>
<sec id="Ch1.S2.SS1">
  <title>Aerosol data</title>
      <p>Aerosol optical thickness (AOT) data over the study period are estimated from
both regional AERONET station data and Collection 6 (C6) Terra MODIS Dark
Target (DT) aerosol products (Levy et al., 2013). AERONET AOTs are derived
from the measured solar energy at seven wavelengths including 340, 380, 440,
500, 675, 870, and 1020 nm (Holben et al., 1998).
For the study period, quality-assured Level 2.0 AERONET data are not
available, and thus the cloud-screened Level 1.5 AERONET data are used in
this study. To derive fine-mode AOT associated with smoke and to help remove
any thin cirrus contamination that may be a residual in the level 1.5 data,
the Spectral Deconvolution Algorithm as described by O'Neill et al. (2003)
and verified by Chew et al. (2011) and Kaku et al. (2014), is utilized.
Retrievals of several aerosol-related parameters, including effective radius,
spectral single scattering albedo and upwelling and downwelling aerosol
forcing efficiencies are also obtained from the AERONET inversion products
(Dubovik and King, 2000).</p>
      <p>No AERONET data are available at the 550 nm spectral channel. To be
consistent with the MODIS AOT data, AERONET <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> values are derived
by interpolating AERONET AOTs reported at the 500 and 675 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m
channels using a method described in Shi et al. (2011). While there are a
number of AERONET sites installed in mid-to eastern United States, four
observed the nature of the plume particularly well: Grand Forks, North
Dakota, (47.91<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 97.33<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W); Sioux Fall, South Dakota
(43.74<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 96.63<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W); Ames, Iowa (42.02<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N,
93.77<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W), and Bondville, Illinois (40.05<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N,
88.37<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W). These are labeled in Figs. 1 and 3a, c and e, with
500 nm fine-mode AOTs listed in Fig. 2e.</p>
      <p>Over land, MODIS DT aerosol data are available over dark surfaces such as
non-desert regions (Levy et al., 2013), and in this study, the Terra MODIS
nadir 10 km resolution <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> retrievals are used, which best
correspond to the midday 12:00 LST/18:00 Z forecast period evaluated. The
accuracy of C6 MODIS AOT is reported to be on the order of
0.05 <inline-formula><mml:math display="inline"><mml:mo>+</mml:mo></mml:math></inline-formula> 15 % <inline-formula><mml:math display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> AOT (Levy et al., 2013), although individual
retrieval uncertainties may be higher (e.g., Shi et al., 2011). As
verification, Terra MODIS retrievals were compared to AERONET sites listed
above for the period of 29 June through 4 July 2015, with
five data points available at Grand Forks having <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> spanning
from 0.88 to 3.7, three at Sioux Falls spanning 0.12 to 3.98, and one at
Ames with a <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> of 0.58. Regression showed MODIS having a slight
10–20 % high bias, and outstanding regression coefficients
(<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi>r</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup><mml:mo>=</mml:mo><mml:mn>0.98</mml:mn></mml:mrow></mml:math></inline-formula>). However, AOT retrievals failed for <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> above
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 4 due to saturation of the aerosol signal.</p>

      <?xmltex \floatpos{p}?><fig id="Ch1.F3" specific-use="star"><caption><p><bold>(a, c, e)</bold> True color images of a smoke event over the
Midwestern United States (28, 29, 30 June 2015, respectively), constructed
using the Level 1b Terra MODIS data. The ASOS 18:00 Z temperatures are overlaid. Core evaluation
sites are labeled; <bold>(b, d, f)</bold> corresponding 550 nm aerosol optical thickness from the
Collection 6 Terra MODIS aerosol products; <bold>(g, h)</bold> mean 18:00 Z
station temperature <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>15 days of the event (15 June–14 July 2015. 29 June
data are excluded for constructing Fig. 3g, and 30 June data are excluded for
constructing Fig. 3h).</p></caption>
          <?xmltex \igopts{width=341.433071pt}?><graphic xlink:href="https://acp.copernicus.org/articles/16/6475/2016/acp-16-6475-2016-f03.pdf"/>

        </fig>

</sec>
<sec id="Ch1.S2.SS2">
  <title>Official forecast comparison</title>
      <p>The hypotheses developed for this effort originated from observations of
significant temperature forecast errors in the Dakotas in association with
the central Canadian smoke plume. Thus a key comparison for forecasted and
observed daily maximum temperatures is performed between Grand Forks
(47.95<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 97.18<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W), in the center of the plume, and
Bismarck (46.77<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 100.75<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W), 300 km to the west and
outside of the plume. These sites are marked in Fig. 3a, c. Official forecast
data were obtained from the National Weather Service-issued text weather
reports (Point Forecast Matrices and Climate Reports) from the Grand Forks
and Bismarck, ND, stations respectively. The NWS Point Forecast Matrices
include forecasted daily maximum near-surface air temperatures and other
weather conditions. The observed daily maximum surface temperatures are
obtained from the NWS Climate Reports which, per the ASOS Users' Guide
(<uri>http://www.nws.noaa.gov/asos/aum-toc.pdf</uri>, accessed on 29 October 2015)
have accuracy at the half degree Celsius level. The archived NWS weather
reports from 15 June–14 July 2015 are obtained from the Iowa Environmental
Mesonet (IEM) site (<uri>https://mesonet.agron.iastate.edu/</uri>; Todey et al.,
2002), which also hosts the NWS-issued Morning Temperature and Precipitation
Summary, from which the observed daily maximum surface temperatures for
Roseau (48.86<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 95.70<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W) and Baudette
(48.73<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N, 94.61<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W), MN, were retrieved, as these were not
available from the NWS Climate Reports.</p>
</sec>
<sec id="Ch1.S2.SS3">
  <title>Surface station data</title>
      <p>To supply surface observations for comparisons to forecast models over the
greater upper Midwest and Upper Mississippi and Ohio River Valley study area,
Automated Surface Observing System (ASOS) surface data are obtained from the
Iowa Environmental Mesonet (IEM) site
(<uri>https://mesonet.agron.iastate.edu/</uri>) for North Dakota, South Dakota,
Nebraska, Minnesota, Iowa, Alabama, Arkansas, Illinois, Indiana, Kansas,
Kentucky, Missouri, Mississippi, Oklahoma, and Tennessee (Fig. 3a and e). The ASOS data include surface temperature
(2 m standard), dew point (2 m standard), wind speed (10 m standard), and direction (10 m standard) as well as visibility conditions. The surface
temperature data used in study have the accuracy on the order of
0.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C for the normal temperature range of <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>50 to 50 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C
(ASOS user's guide, <uri>http://www.nws.noaa.gov/asos/aum-toc.pdf</uri>, accessed
on 29 October 2015).</p>
</sec>
<sec id="Ch1.S2.SS4">
  <title>Forecast model data</title>
      <p>The next step in this analysis was to compare model midday
(12:00–13:00 LST, 18:00 Z) surface temperature forecasts with ASOS
observations, and relate differences to the location of the smoke plume.
18:00 UTC was selected because it is near local noon and is only 15 min off
the Terra satellite overpass time (17:45 UTC) for North Dakota on 29 June
2015. The primary model set used for comparison is the deterministic
forecasts from ECMWF. Two-meter surface temperate forecasts for the 18:00 Z
valid times (30 and 54 h forecasts) are examined. The 29 and 30 June 2015
18:00 Z forecasts and ASOS observations are examined in detail. The forecast
error statistics are also examined for these ASOS sites from 15 June through
14 July.</p>
      <p>Model data from the operational version of the European Centre for Medium-Range Weather Forecasts Integrated Forecast System (ECMWF IFS) were used.
Forecast data are available 3-hourly from the 00:00 and 12:00 UTC analysis.
Analyses are also available at 06:00 and 18:00 UTC from the four-dimensional
variational (4D-Var) system with ensemble-generated flow-dependent
background error statistics. The current resolution of the ECMWF IFS is
approximately 16 km (T1279 spectral) with 137 vertical levels. More
information is available here: <uri>https://software.ecmwf.int/wiki/display/IFS/CY41R1+Official+IFS+Documentation</uri>.</p>
      <p>In addition to ECMWF, two other model data sets were also examined. Forecast
surface temperatures at 24 and 48 h forecast intervals from the Global
Ensemble forecast System (GEFS) UKMO UM ensemble, at 18:00 UTC, were
obtained from the THORPEX Interactive Grand Global Ensemble (TIGGE) data
archive (Bougeault et al., 2010). The NCEP GEFS data are available on a
global scale, with a regridded 0.5 <inline-formula><mml:math display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 0.5<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>
(latitude/longitude) spatial resolution at 00:00, 06:00, 12:00, and 18:00 UTC. Gridded statistical interpolation is included
as the data assimilation method for the control analysis
(<uri>http://tigge.ecmwf.int/models.html</uri>). The 2 m air temperatures from
the NCEP model runs are used. Note that the NCEP data record is not complete
for the selected study period, and missing data are listed in Table 1.</p>
      <p>The UKMO data are available at a regridded spatial resolution of
0.5 <inline-formula><mml:math display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 0.5<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> (latitude/longitude) on a global scale. The
4D-Var assimilation scheme is included for the control analysis
(<uri>http://tigge.ecmwf.int/models.html</uri>). The reported 1.5 m air
temperature from the UKMO model runs are used in this study. Other details of
the UKMO and NCEP models can be found from Bougeault et al. (2010) and the
TIGGE website (<uri>http://tigge.ecmwf.int/models.html</uri>).</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T1"><caption><p>Missing data for the NCEP model runs. (Data are not available from
the TIGGE site.)</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="2">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:thead>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1">NCEP</oasis:entry>  
         <oasis:entry colname="col2">Missing data</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>  
         <oasis:entry colname="col1">0 h forecast</oasis:entry>  
         <oasis:entry colname="col2">20, 22, 25 June, 5, 14 July</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">24 h forecast</oasis:entry>  
         <oasis:entry colname="col2">21, 23, 26 June, 6 July</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">48 h forecast</oasis:entry>  
         <oasis:entry colname="col2">22, 24, 27 June, 7 July</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

</sec>
<sec id="Ch1.S2.SS5">
  <title>Other data and metadata used in this analysis</title>
      <p>To assist the analysis, data from a number of sources are utilized.
Descriptions of fire activity were obtained from the Canadian Interagency
Forest Fire Center (CIFFC) situation reports (<uri>http://www.ciffc.ca/</uri>,
last accessed 1 December 2015). MODIS fire hotspot data were also used
(MOD14/MYD14, Justice et al., 2002). Soundings with temperatures, dew points,
and mixing ratios from radiosonde data at Aberdeen, SD, are used
(45.45<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> N; 98.4<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> W). To diagnose lower middle troposphere
flow patterns, ECMWF reanalysis was utilized (Dee et al., 2011). Finally to
assess the transport trajectory of individual smoke parcels, the Hybrid
Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) model (Draxler and
Hess, 1997) is also used. The HYSPLIT model computes trajectories of air
parcels, both in forward and backward modes, given the geolocation and
altitude of an air parcel, as well as model initiation and spinning times.</p>
</sec>
</sec>
<sec id="Ch1.S3">
  <title>Results</title>
<sec id="Ch1.S3.SS1">
  <title>General description of the June event</title>
      <p>The smoke event described here originated in a set of fires in the Northwest
Territories and northern Alberta and Saskatchewan that were initiated
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 23 June 2015, as discussed by CIFFC and observed in MODIS
fire hotspot anomalies. These fires were likely the result of lighting in
association with widespread thunderstorm activity in central Canada lasting
several days. By 27 June 2015 (Fig. 2a), over 60 individual
fires or complexes were visible in the MODIS fire product, with over 30 fires reported greater than 1000 Ha by the CIFFC. 28 June 2015 MODIS
imagery (Fig. 2b) showed significantly enhanced fire activity, with
thick palls of smoke being visible over central Canada. Comparison of MODIS
fire to the CIFFC suggests that a number of major fire complexes were missed
in the satellite product, with significant burning being missed in central
Saskatchewan and Manitoba. Nevertheless the dense smoke was present. By 29 and 30 June, smoke was clearly being transported across the
Midwest, through the Upper Mississippi and Ohio River Valley, and into the
Carolinas.</p>
      <p>The rapid transport of this smoke event was related to a persistent long-wave
high over the western United States, and corresponding trough over the
eastern seaboard. The resulting lower free tropospheric winds were
west–northwesterly (e.g., see 700 hPa height and wind analysis from the ECMWF
reanalysis in Fig. 4). These winds veered to north–northwest at 500 hPa.</p>
      <p>Thus, smoke was channeled into the upper Midwest from central Canada. Smoke
transport was further enhanced by a fast-moving shortwave and cold front,
with 700 hPa winds at <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 25 m s<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> (evident from the upper Great
Lakes through Iowa and Nebraska in Fig. 4a). This shortwave resulted in the
first tongue of smoke entering the United States through central North and
South Dakota on 28 June (Fig. 2b). The most dramatic day, 29 June 2015, saw
the rapid transport of the major smoke pall from northern Canada into the
central Midwest behind the aforementioned shortwave with mid-visible AOTs in
the upper Midwest above 4 (Fig. 2c and e). Embedded in this smoke event were
a set of smaller disturbances and associated wind enhancements across south
central Canada and the upper Midwest (Fig. 4b). At the core 18:00 Z analysis
time for this study, peak winds associated with the shortwave ranged from
west–northwesterly 10 m s<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> at 950 hPa, veering to northwesterly to
25 m s<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula> at 500 hPa.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F4"><caption><p>ECMWF Reanalysis of 700 hPa geopotential heights overlayed on winds
for <bold>(a)</bold> 28, <bold>(b)</bold> 29, and <bold>(c)</bold> 30 June 2015 at
18:00 Z.</p></caption>
          <?xmltex \igopts{width=170.716535pt}?><graphic xlink:href="https://acp.copernicus.org/articles/16/6475/2016/acp-16-6475-2016-f04.pdf"/>

        </fig>

      <p>A major shift in the pattern occurred on 30 June. Smoke from the
previous day had now advected into the Upper Mississippi and Ohio River
Valley. Indeed, HYSPLIT trajectories suggest smoke over Grand Forks should
have advected to South Central Illinois within 24 h. At the same time, a
low and occluded front moved into the Dakotas, bringing heavy cloud cover,
some rain, and more zonal winds (Figs. 2d, 4c). At the same
time, observed fire activity diminished. Over the first week of July, while
smoke was still clearly present at moderately high levels in the upper
Midwest (Fig. 2e), the plume structure was not as nearly dramatic. Smoke
was also frequently embedded in cloud layers. By 6 July, a
significant cold front moved through the area, largely putting the smoke
event to an end (e.g., Fig. 2e). From 23 June–9 July, CIFFC reported
that <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2 000 000 Ha were burned.</p>
      <p><?xmltex \hack{\newpage}?>Operational radiosonde releases within the 29–30 June main smoke event are
rare due to the unfortunate trajectory of the main plume, perfectly
between the Bismarck and International Falls stations in the north and
the Omaha/Topeka/Springfield corridor and Chahassen/Davenport/Lincoln
corridor in the south. Further, the 00:00 Z and 12:00 Z releases are
nominally in the plume region in the morning and evening. However, there were two radiosondes
related to the event, collected under cloud-free sky conditions, the 29 June
12:00 Z and 30 June 00:00 Z release at Aberdeen (Fig. 5). Even though the
site is on the edge of the main plume, the MODIS-inferred <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> was still high <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2. Clearly, the soundings are dry, with
temperature and dew point profiles indicative of relative humidity on the
order of 40–50 %. Water vapor mixing ratios dropped to below 2 g kg<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>, by 600 hPa, or 4 km.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T2" specific-use="star"><caption><p>Averaged aerosol-related properties, including effective radius
(<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>r</mml:mi><mml:mi mathvariant="normal">eff</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>), upwelling and downwelling aerosol forcing efficiencies
(at 500 nm), and single scattering albedo (SSA), corresponding to Dubovik
retrievals from measurements from four selected AERONET stations for
29 June–3 July 2015.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="5">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:thead>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2">Grand Forks</oasis:entry>  
         <oasis:entry colname="col3">Sioux Falls</oasis:entry>  
         <oasis:entry colname="col4">Ames</oasis:entry>  
         <oasis:entry colname="col5">Bondville</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>  
         <oasis:entry colname="col1"><inline-formula><mml:math display="inline"><mml:mi>N</mml:mi></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col2">7</oasis:entry>  
         <oasis:entry colname="col3">7</oasis:entry>  
         <oasis:entry colname="col4">11</oasis:entry>  
         <oasis:entry colname="col5">5</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">AOT (500 nm)</oasis:entry>  
         <oasis:entry colname="col2">1.4 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.6</oasis:entry>  
         <oasis:entry colname="col3">1.3 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.16</oasis:entry>  
         <oasis:entry colname="col4">0.5 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.12</oasis:entry>  
         <oasis:entry colname="col5">0.8 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.4</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1"><inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>r</mml:mi><mml:mi mathvariant="normal">eff</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m)</oasis:entry>  
         <oasis:entry colname="col2">0.162 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.017</oasis:entry>  
         <oasis:entry colname="col3">0.164 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.017</oasis:entry>  
         <oasis:entry colname="col4">0.160 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.012</oasis:entry>  
         <oasis:entry colname="col5">0.170 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.013</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Up. Forcing Eff.</oasis:entry>  
         <oasis:entry colname="col2"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>50 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 5</oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>48 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 12</oasis:entry>  
         <oasis:entry colname="col4"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>55 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 10</oasis:entry>  
         <oasis:entry colname="col5"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>58 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 9</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">(W m<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup><mml:msubsup><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>500</mml:mn><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula>)</oasis:entry>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Down Forcing Eff.</oasis:entry>  
         <oasis:entry colname="col2"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>118 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 16</oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>122 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 15</oasis:entry>  
         <oasis:entry colname="col4"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>165 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 27</oasis:entry>  
         <oasis:entry colname="col5"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>124 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 10</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">(W m<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup><mml:msubsup><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>500</mml:mn><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula>)</oasis:entry>  
         <oasis:entry colname="col2"/>  
         <oasis:entry colname="col3"/>  
         <oasis:entry colname="col4"/>  
         <oasis:entry colname="col5"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">SSA(440 nm)</oasis:entry>  
         <oasis:entry colname="col2">0.94 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.01</oasis:entry>  
         <oasis:entry colname="col3">0.94 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.01</oasis:entry>  
         <oasis:entry colname="col4">0.93 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.01</oasis:entry>  
         <oasis:entry colname="col5">0.95 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.01</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">SSA(670 nm)</oasis:entry>  
         <oasis:entry colname="col2">0.94 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.02</oasis:entry>  
         <oasis:entry colname="col3">0.93 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.02</oasis:entry>  
         <oasis:entry colname="col4">0.91 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.02</oasis:entry>  
         <oasis:entry colname="col5">0.95 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.02</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">SSA(870 nm)</oasis:entry>  
         <oasis:entry colname="col2">0.93 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.03</oasis:entry>  
         <oasis:entry colname="col3">0.92 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.03</oasis:entry>  
         <oasis:entry colname="col4">0.88 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.02</oasis:entry>  
         <oasis:entry colname="col5">0.94 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.01</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">SSA(1020 nm)</oasis:entry>  
         <oasis:entry colname="col2">0.92 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.03</oasis:entry>  
         <oasis:entry colname="col3">0.92 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.03</oasis:entry>  
         <oasis:entry colname="col4">0.86 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.03</oasis:entry>  
         <oasis:entry colname="col5">0.93 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 0.01</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <?xmltex \floatpos{t}?><fig id="Ch1.F5"><caption><p>Radiosonde release for Aberdeen, South Dakota, for 29 June 12:00 Z
(solid) and 30 June 00:00 Z (dashed).</p></caption>
          <?xmltex \igopts{width=236.157874pt}?><graphic xlink:href="https://acp.copernicus.org/articles/16/6475/2016/acp-16-6475-2016-f05.pdf"/>

        </fig>

      <p>Unfortunately for ascertaining plume altitudes for this event, no
Cloud-Aerosol Lidar with Orthogonal Polarization (CALIOP) lidar data are
available until 30 June due to solar flare activity. Over the
remaining days, orbit and clouds prevented clear operations across the axis
of the plume. However, we can infer from the early morning and afternoon
1 July overpasses over the east coast that this plume was largely
below 5 km in altitude. This is corroborated by the Aberdeen sounding, which
showed very low water vapor mixing ratios above 4 km in altitude. In regard
to smoke base, despite the very high AOTs, surface PM<inline-formula><mml:math display="inline"><mml:msub><mml:mi/><mml:mn>10</mml:mn></mml:msub></mml:math></inline-formula> measurements
hardly registered the plume passage. Based on all of the above information,
we are confident that the plume was confined to the lower to middle free
troposphere.</p>
      <p>Estimates of particle size and optical properties of the smoke plume were
retrieved from the four core AERONET sites used in this analysis (Table 2).
These retrievals were collected from 29 June–3 July over the study area.
Particle sizes were fairly stable over the United States, with an effective
radius of <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.165 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m, or a volume median diameter of
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.38 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m. This value is large in comparison to more typical
boreal fires (e.g., Reid et al., 2005), but well within values found for mega
events from Canada (e.g., 2002 Quebec fire with <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> &gt; 5; Colarco et al., 2004; O'Neill et al., 2005).
Retrieved single scattering albedo was also consistent and within expected
values, <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.94 in the mid-visible. In regard to this analysis of
surface temperature, what we are most interested in is forcing efficiencies,
which ranged from <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>48 to <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>58 W m<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup><mml:msubsup><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula> for the top of
the atmosphere. For retrieved surface forcing efficiencies, values varied
more between sites. Grand Forks, Sioux City, and Bondville all agreed well,
ranging from <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>118 to <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>124 W m<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup><mml:msubsup><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula>. Note that top-of-atmosphere
(TOA) (surface) aerosol forcing efficiency is defined as the amount of change in upward (downward) shortwave
radiation at TOA (surface) for a unit change in AOT. Negative surface aerosol
forcing efficiencies indicate a reduction in shortwave radiation reaching the
surface and mostly likely linkage to a decrease in surface temperature.
However the Ames site had several outlier retrievals, leading to a higher
magnitude downward forcing efficiency of <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>165 W m<inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">2</mml:mn></mml:mrow></mml:msup><mml:msubsup><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msubsup></mml:mrow></mml:math></inline-formula>,
due to noticeably lower near-infrared single scattering albedos and slightly
smaller size. This departure was consistent through the event. One
explanation of this difference between Ames and other sites is that the
averaged AOT (0.5 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m) is around 0.5 for the Ames site, whereas the
averaged AOT (0.5 <inline-formula><mml:math display="inline"><mml:mi mathvariant="normal">µ</mml:mi></mml:math></inline-formula>m) for the other sites ranges from 0.8 to 1.4
(Table 2) . Thus, sampling bias is likely a factor.</p>
</sec>
<sec id="Ch1.S3.SS2">
  <title>Observed temperature patterns in association with the 29–30 June
event</title>
      <p>Figure 3a, c, and e show the RGB true color images of the smoke event over
the upper Midwestern United States on 28 June (17:00 and 17:05 UTC) and
29 June (17:45 UTC), and over the Upper Mississippi and Ohio River Valley on
30 June (16:50 and 16:55 UTC), constructed using the Collection 6, Level 1b
Terra MODIS data. Figure 3b, d, and f show the corresponding Terra
MODIS C6 DT <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> for the same study periods as Fig. 3a, c, and e. The
observed surface temperatures reported from ASOS stations are overplotted on
Fig. 3a, c, and e from North Dakota, South Dakota, Nebraska, Minnesota, and
Iowa on 28 and 29 June, and from Alabama, Arkansas, Iowa, Illinois, Indiana,
Kansas, Kentucky, Missouri, Mississippi, Nebraska, Oklahoma and Tennessee on
30 June. Each data point in Fig. 3a, c, and e represent the averaged
observations within <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>10 min from 18:00 UTC of each given day for a
given station. The observations from 18:00 UTC are selected as both model
analyses and forecasts are available at this time, enabling us to further
explore differences between modeled and observed surface temperatures with
respect to smoke aerosol properties.</p>
      <p>Shown in Fig. 3a, on 28 June, is a stripe of smoke aerosol plume which
starts to appear over the upper Midwest region. The overall aerosol loadings
are still relatively low (<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> &lt; 0.8 for the stripe of
plume and less than 0.2 for most other regions) across the domain. A mild
temperature difference on the order of 1–2 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C is observed between
eastern and western North Dakota. In comparison, on 29 June, a thick
smoke plume is observed over the eastern Dakotas and western Minnesota with
significant MODIS DT <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> values of 2–5. While warmer surface
temperatures of 27–32 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C are observed over the Western Dakotas
where lighter aerosol loadings (less than 0.6) are found, surface
temperatures of 22–24.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C are found over the eastern Dakotas and
western Minnesota. The sharp spatial gradient in surface temperature on the
order of 5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C between eastern and western North Dakota on 29 June 2015, matching the smoke plume pattern, shows the potential influence of
the smoke aerosol particles on the observed surface temperatures.</p>
      <p>On 30 June, the smoke plume migrates to the Upper Mississippi and
Ohio River Valley, as shown in Fig. 3e and f. Note that surface
observations are obtained around 18:00 UTC, and the Terra MODIS overpasses
are 16:50–16:55 UTC. Thus, there is <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1 h difference between surface- and satellite-based observations. Still, as shown in Fig. 3e, especially over Missouri (Center of Fig. 3e), lower surface
temperatures are visible over regions with heavy aerosol loadings, which
again, reinforces the finding from the 29 June case.</p>
</sec>
<sec id="Ch1.S3.SS3">
  <title>Impacts of the smoke plume on an operational weather forecast</title>
      <p>To assess the degree to which the smoke event impacted forecast temperatures,
we first performed a hand analysis of the difference in forecast and observed
surface temperatures between Grand Forks and Bismarck as reported from the
National Weather Service for 29 June. These two sites correspond to the
middle and just outside of the main plume. Figure 6 shows the forecast
maximum surface air temperatures up to 96 h for Grand Forks and Bismarck for
29 June 2015. Filled diamonds represent forecast update time. The final daily
maximum temperatures, nominally 25.6 and 33.3 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C for Grand Forks and
Bismarck respectively, are also shown. For 29 June, an <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 8 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C
difference is seen between sites in and out of the plume even though,
typically, the high temperatures between Grand Forks and Bismarck are highly
correlated. For the month surrounding the event (15 June–14 July, excluding
29 June), Bismarck was historically warmer than Grand Forks by
1.0 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 2.0 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, with a correlation of 0.90. Forecasters are well
aware of this natural difference and hence account for it in their forecasts.
It is also noteworthy that while the daily maximum near-surface air
temperature forecasts for 29 June remain unchanged since 27 June for
Bismarck, the Grand Forks NWS made a <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>2.8 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>F)
adjustment for their daily maximum near-surface air temperature forecast at
around 10:00 local time on 29 June 2015, possibly to compensate for the
initial unexpected surface cooling due to the thick smoke aerosol plume.
Despite the higher winds in the lower to middle free troposphere, 29 June was
a relatively calm day with moderate winds at the surface,
(<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3–5 m s<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mrow><mml:mo>-</mml:mo><mml:mn mathvariant="normal">1</mml:mn></mml:mrow></mml:msup></mml:math></inline-formula>). Taking all of the above factors into
consideration, it is hypothesized that the smoke plume with an
AERONET-reported daily mean <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> of <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 3.4 introduced a surface
temperature cooling for Grand Forks of <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. This is
equivalent to a daytime aerosol cooling efficiency of
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C/<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, given that the daily averaged <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is 3.4 as reported from Grand Forks AERONET station. Meanwhile, the
reported MODIS <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> value over Bismarck was <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 0.35.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F6"><caption><p>The forecasted daily maximum temperatures from Grand Forks and
Bismarck National Weather Service offices as a function of forecasting hours.
Short lines on the top and bottom of the right-hand side of the figure
represent observed daily maximum temperatures for the two stations on 29 June
2015.</p></caption>
          <?xmltex \igopts{width=170.716535pt}?><graphic xlink:href="https://acp.copernicus.org/articles/16/6475/2016/acp-16-6475-2016-f06.pdf"/>

        </fig>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T3" specific-use="star"><caption><p>The monthly mean differences (<inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula>) as well as correlations in
the observed daily maximum temperatures between Grand Forks, ND (GFK) and
three ASOS site: Bismarck, ND (west of GFK), Roseau and Baudette, MN (east of
GFK) for 15 June–14 July 2015, excluding 29 June 2015. The daily maximum
temperature differences (<inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula>) between GFK and other three ASOS
sites on 29 June 2015 are also reported. Also included are the latitude,
longitude of the three ASOS sites and estimated <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> values from
MODIS (17:47 UTC, 550 nm).</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="8">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="left"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="right"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:colspec colnum="8" colname="col8" align="right"/>
     <oasis:thead>
       <oasis:row>  
         <oasis:entry colname="col1">Location</oasis:entry>  
         <oasis:entry colname="col2">Relative to the</oasis:entry>  
         <oasis:entry colname="col3">Lat.</oasis:entry>  
         <oasis:entry colname="col4">Long.</oasis:entry>  
         <oasis:entry colname="col5"><inline-formula><mml:math display="inline"><mml:mrow><mml:msup><mml:mi>R</mml:mi><mml:mn mathvariant="normal">2</mml:mn></mml:msup></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col6">MODIS <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col7">Mean <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col8"><inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula> (<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C)</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2">GFK site</oasis:entry>  
         <oasis:entry colname="col3">(<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>)</oasis:entry>  
         <oasis:entry colname="col4">(<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>)</oasis:entry>  
         <oasis:entry colname="col5"/>  
         <oasis:entry colname="col6">17:47 Z</oasis:entry>  
         <oasis:entry colname="col7">(<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C)</oasis:entry>  
         <oasis:entry colname="col8">(29 June)</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>  
         <oasis:entry colname="col1">Bismarck, ND</oasis:entry>  
         <oasis:entry colname="col2">West</oasis:entry>  
         <oasis:entry colname="col3">46.8</oasis:entry>  
         <oasis:entry colname="col4"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>100.7</oasis:entry>  
         <oasis:entry colname="col5">0.81</oasis:entry>  
         <oasis:entry colname="col6">0.35</oasis:entry>  
         <oasis:entry colname="col7"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.0 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 2.0</oasis:entry>  
         <oasis:entry colname="col8"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>7.8</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Roseau, MN</oasis:entry>  
         <oasis:entry colname="col2">East</oasis:entry>  
         <oasis:entry colname="col3">48.9</oasis:entry>  
         <oasis:entry colname="col4"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>95.7</oasis:entry>  
         <oasis:entry colname="col5">0.72</oasis:entry>  
         <oasis:entry colname="col6">0.84</oasis:entry>  
         <oasis:entry colname="col7">1.9 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 2.1</oasis:entry>  
         <oasis:entry colname="col8"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.6</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">Baudette, MN</oasis:entry>  
         <oasis:entry colname="col2">East</oasis:entry>  
         <oasis:entry colname="col3">48.7</oasis:entry>  
         <oasis:entry colname="col4"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>94.6</oasis:entry>  
         <oasis:entry colname="col5">0.73</oasis:entry>  
         <oasis:entry colname="col6">1.06</oasis:entry>  
         <oasis:entry colname="col7">1.8 <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula> 2.1</oasis:entry>  
         <oasis:entry colname="col8">1.1</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p>While observations from Bismarck and Grand Forks represent measurements at
the diffuse western edge and the central smoke plume, Roseau and Baudette,
MN, which are close to Grand Forks, are selected to represent the eastern
diffuse edge of the smoke plume. As listed in Table 3, <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> values
are 0.84 and 1.06 for Roseau and Baudette respectively at 17:45 UTC, 29 June
2015, as approximated from MODIS DT retrievals. Note that using the observed
surface temperature differences between Grand Forks and the two selected
cities in MN for evaluating aerosol direct cooling effect is not ideal, as
surface temperatures from Roseau and Baudette may also be modulated by nearby
lakes. Further, lower correlations in daily maximum temperatures, around
0.85, are found between Grand Forks and the other two locations in MN. Still,
Grand Forks is around 2 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C warmer than Roseau and Baudette on a
monthly average (Table 3). However, on 29 June 2015, a much smaller
temperature difference of 1.1 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C is found between Grand Forks and
Baudette, and Roseau is actually 0.6 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C warmer than Grand Forks.
Both cases may indicate the potential smoke cooling effect. It is noteworthy
that the NWS made a <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.7 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>3<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>F) adjustment for the
forecasted daily maximum temperatures on 29 June 2015 for both Roseau and
Baudette, MN, possibly to compensate for the unexpected smoke-aerosol-induced
surface cooling. Lastly, besides the aerosol direct surface cooling effects,
surface temperatures could also be impacted by differences in dynamical
environments, which adds uncertainties to the study.</p>
</sec>
<sec id="Ch1.S3.SS4">
  <title>Impacts of the smoke plume on numerical model predictions</title>
      <p>The above hand analysis provides a benchmark estimate of the cooling
efficiency of the Canadian smoke plume. To test this value through an
objective analysis, we compared this finding to surface forecast errors
focusing on the ECMWF models, starting with the 29 June case. After
this analysis, we extended the study to the NCEP and UKMO models and for the
30 June case as well. A synopsis of findings is provided in Fig. 7,
where we show (a) the relationship between recorded 18:00 Z temperature to
MODIS <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>; (b) the difference of ASOS observation to ECMWF 30 h forecast against <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>; and (c) and (d), the corresponding
overlay of observation minus ECMWF 30 h forecast mapped over the 29 and 30 June investigation domains. The plots are generated using
measurements from ground stations as shown in Fig. 3c and e. In addition,
over the center of the smoke-aerosol-polluted regions, the smoke plume is so
optically thick that the MODIS aerosol retrieval scheme failed to report
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> values. Thus, the closest MODIS <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> value
within 1<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> latitude/longitude of a given ground station is used to
represent the <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> value of that station where there is no MODIS
aerosol retrieval available. Note that this assumption may introduce a bias
in the estimated MODIS AOTs.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F7"><caption><p><bold>(a)</bold> The observed near-surface air temperature and
<bold>(b)</bold> the differences in observed and ECMWF 30 h forecasted near-surface air temperature (<inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>T</mml:mi><mml:mrow><mml:mn>30</mml:mn><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>) as a function of MODIS DT
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> for both the 29 June and the 30 June case. <bold>(c)</bold> RGB
image over the upper Midwest on 29 June 2015, constructed using Terra MODIS
level 1B data. <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>T</mml:mi><mml:mrow><mml:mn>30</mml:mn><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> values from each ASOS station are overplotted on Fig. 7c. <bold>(d)</bold> Similar to panel <bold>(c)</bold> but over
the Ohio River Valley on 30 June 2015.</p></caption>
          <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://acp.copernicus.org/articles/16/6475/2016/acp-16-6475-2016-f07.pdf"/>

        </fig>

<?xmltex \hack{\newpage}?>
<sec id="Ch1.S3.SS4.SSS1">
  <title>The 29 June case</title>
      <p>The 29 June 2015 case is an ideal case for studying the impact of
the smoke plume on numerical-model-forecasted near-surface air temperatures
for a few reasons. Firstly, both surface and satellite observations are in
close proximity in time (15 min) to the 18:00 UTC model forecasts and
analysis. Secondly, the thick smoke plume is not expected by the model and
has not been accounted for in numerical model simulations.</p>
      <p>Certainly over the region, there is a clear relationship between 18:00 Z
measured temperature (<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">obs</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) and MODIS <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> (Fig. 7a). In
general, temperature is reduced by 1 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C per unit <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>.
However, there are exceptions, notably a drop in temperature for a cluster
of data points of at <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> of <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1. This group of
data points belongs to sites on the eastern side of the 29 June upper
Midwest domain, associated with the great lakes and lake country of
Wisconsin (as is also evident in Fig. 3). Thus, we must be careful to
acknowledge that there is a natural overall east to west positive
temperature gradient on this day. Indeed, for the <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>15 day period
surrounding but excluding the event (Fig. 3g), Wisconsin is generally 1–4<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> cooler. Excluding these cooler data points, the overall tendency is
1–2 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C per unit <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>. We consider this 1–2 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C per unit
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> set of values to be the range of observational
sensitivity.</p>
      <p>As the next step, we attempt to control for the gradient in temperature
using the forecast model itself. Fig. 7b presents the ASOS 18:00 Z
observation minus the ECMWF 30 h forecast against MODIS <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>.
The values of this difference are also spatially mapped in Fig. 7c.
Here, in corroboration with the pure observations from Fig. 7a, there is
a trend for forecast temperature overestimation with <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, on the
order of <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1 to 2 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. Use of the ECMWF forecast error in
the analysis clearly mitigates a significant amount of the non-plume-related
temperature gradient across the domain. Temperatures in the heavy smoke
plume region tended to be over forecasted by 1 to 6 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. Conversely, on
either side of the smoke plume, the 30 h forecast tends to underestimate
temperature by <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1 to 2 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, leading to an overall
temperature difference of <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>2 to <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>8 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, only slightly lower than the
findings of a similar study by Westphal and Toon (1991). As an example,
Grand Forks had a 18:00 Z maximum temperature of 23.9 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C with a
MODIS <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> of 4.4, in comparison to the ECMWF forecast of
26.8 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C.</p>
      <p>We can expand this analysis further, to examine the skill of ECMWF 18:00 Z
analyses and 54 h forecasts relative to the 30 h forecast discussed above.
Figure 8a–c show the 0 h analysis, and 30 and 54 h forecasts of the 2 m
air temperatures from ECMWF. Again, over the Grand Forks region at
18:00 UTC, the actual surface temperature is around 23.9 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. In
comparison, the analysis, 30 h forecast, and 54 h forecasts were 25.2, 26.8,
and 28.2 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C respectively (or <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1.3, 2.9, and 4.3 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C
difference). This is not surprising, as (shown later in Table 6) a much
smaller forecasting error is expected for the 0 h forecast. Expanding for all
data in the domain, Fig. 8d–f show the differences between observed and
modeled 2 m air temperatures (<inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>T</mml:mi><mml:mrow><mml:mn mathvariant="normal">0</mml:mn><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>T</mml:mi><mml:mrow><mml:mn>30</mml:mn><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>
and <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>T</mml:mi><mml:mrow><mml:mn>54</mml:mn><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>) as a function of MODIS <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>. In all
cases clear relationships are found. Ultimately, smoke-induced cooling for
the 54 h and 30 h forecasts and the analysis are
<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.9 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C/<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.0 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C/<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, and
<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.6 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C/<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, respectively. The slope and offset values
are also shown in Table 4.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F8"><caption><p><bold>(a–c)</bold> 0, 30, and 54 h forecasts of 2 m air temperatures
for the study region as shown in Fig. 3a at 18:00 UTC, 29 June 2015 from
ECMWF model runs. <bold>(d–f)</bold>. The differences between surface observations (using
ground stations as shown in Fig. 3c) and ECMWF-modeled 2 m temperatures (at 18:00 UTC, 29 June 2015) as a function of Collection 6 Terra MODIS DT <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>. Data pairs are
colored based on the observed monthly mean surface temperatures at 18:00 UTC
as shown in Fig. 3g. Data pairs for regions with monthly mean temperatures of
&lt; 22 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, between 22 and 24.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C and
&gt; 24.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C are colored in blue, green, and red
respectively. Red dashed lines are the linear fit lines to the data pairs
with red colors, and green dashed lines are the linear fit lines for data
pairs with green colors.</p></caption>
            <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://acp.copernicus.org/articles/16/6475/2016/acp-16-6475-2016-f08.pdf"/>

          </fig>

      <p>The same analysis is also conducted for the analysis and 24 and 48 h forecasts
of 1.5 m air temperatures from the UKMO model, and the 0, 24, and 48 h
forecasts of 2 m air temperatures from the NCEP model. Similar results, as
shown in Fig. 8a–f for ECMWF, are found and are summarized in Table 4.
Similar plots as Fig. 8 are provided in Appendix Figs. A1 and A2 for UKMO and
NCEP respectively. For these other models, smoke-induced cooling values range
from <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.3 to <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.8 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C/<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> for the analysis and 24 and
48 h forecasts from UKMO and NCEP models. Figure 8 and Table 4 suggest that a
clear relationship exists between the differences in observed and modeled
near-surface air temperature (<inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula>) and <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, for the 0,
24(30), and 48(54) h forecasts, regardless of the model evaluated. All
nine cases suggest a daytime smoke aerosol direct surface cooling efficiency
(<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="italic">τ</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) on the order of <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.4 to <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.8 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C /<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>
(550 nm) for 18:00 Z analyses, and <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.3 to <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.0 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C /
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> for 24 to 54 h forecasts, although the slopes could be biased
by uncertainties in the numerical simulations.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T4" specific-use="star"><caption><p>Offsets (<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C) and slopes (<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C/<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>) of MODIS
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> vs. the differences between observed (using ground stations as
shown in Fig. 7c) and modeled near-surface air temperatures (at 18:00 UTC,
29 June 2015) from ECMWF, UKMO, and NCEP model runs. Similar results using
only stations with monthly mean temperatures (<inline-formula><mml:math display="inline"><mml:mover accent="true"><mml:mi>T</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula>) within the
range of 22 to 24.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, as well as for stations with
<inline-formula><mml:math display="inline"><mml:mover accent="true"><mml:mi>T</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula> &gt; 24.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C are also shown.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="4">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:thead>
       <oasis:row>  
         <oasis:entry colname="col1">Offset/slope</oasis:entry>  
         <oasis:entry colname="col2">ECMWF</oasis:entry>  
         <oasis:entry colname="col3">UKMO</oasis:entry>  
         <oasis:entry colname="col4">NCEP</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2">(<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C)/(<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C/<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>)</oasis:entry>  
         <oasis:entry colname="col3">(<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C)/(<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C/<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>)</oasis:entry>  
         <oasis:entry colname="col4">(<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C)/(<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C/<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>)</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>  
         <oasis:entry colname="col1">0 h forecast</oasis:entry>  
         <oasis:entry colname="col2">0.70/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.56</oasis:entry>  
         <oasis:entry colname="col3">0.15/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.38</oasis:entry>  
         <oasis:entry colname="col4"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.39/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.81</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">(22 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C &lt; <inline-formula><mml:math display="inline"><mml:mover accent="true"><mml:mi>T</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula> &lt; 24.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C)</oasis:entry>  
         <oasis:entry colname="col2">(1.03/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.72)</oasis:entry>  
         <oasis:entry colname="col3">(0.22/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.46)</oasis:entry>  
         <oasis:entry colname="col4">(<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.47/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.86)</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1">(<inline-formula><mml:math display="inline"><mml:mover accent="true"><mml:mi>T</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula> &gt; 24.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C)</oasis:entry>  
         <oasis:entry colname="col2">(0.17/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.27)</oasis:entry>  
         <oasis:entry colname="col3">(0.06/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.14)</oasis:entry>  
         <oasis:entry colname="col4">(<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.31/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.45)</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">24 (30) h forecast</oasis:entry>  
         <oasis:entry colname="col2">1.08/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.02</oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.40/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.71</oasis:entry>  
         <oasis:entry colname="col4">0.62/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.55</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">(22 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C &lt; <inline-formula><mml:math display="inline"><mml:mover accent="true"><mml:mi>T</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula> &lt; 24.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C)</oasis:entry>  
         <oasis:entry colname="col2">(1.49/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.18)</oasis:entry>  
         <oasis:entry colname="col3">(0.51/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.01)</oasis:entry>  
         <oasis:entry colname="col4">(<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.83/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.68)</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1">(<inline-formula><mml:math display="inline"><mml:mover accent="true"><mml:mi>T</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula> &gt; 24.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C)</oasis:entry>  
         <oasis:entry colname="col2">(0.77/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.71)</oasis:entry>  
         <oasis:entry colname="col3">(<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.92/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.36)</oasis:entry>  
         <oasis:entry colname="col4">(0.93/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.16)</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">48 (54) h forecast</oasis:entry>  
         <oasis:entry colname="col2">0.96/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.93</oasis:entry>  
         <oasis:entry colname="col3">0.03/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.67</oasis:entry>  
         <oasis:entry colname="col4">0.18/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.31</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">(22 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C &lt; <inline-formula><mml:math display="inline"><mml:mover accent="true"><mml:mi>T</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula> &lt; 24.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C)</oasis:entry>  
         <oasis:entry colname="col2">(1.44/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.13)</oasis:entry>  
         <oasis:entry colname="col3">(0.75/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.88)</oasis:entry>  
         <oasis:entry colname="col4">(0.72/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.52)</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">(<inline-formula><mml:math display="inline"><mml:mover accent="true"><mml:mi>T</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula> &gt; 24.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C)</oasis:entry>  
         <oasis:entry colname="col2">(0.48/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.50)</oasis:entry>  
         <oasis:entry colname="col3">(<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.37/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.54)</oasis:entry>  
         <oasis:entry colname="col4">(0.31/0.04)</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p>In addition to statistical noise, variability in the daytime smoke <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="italic">τ</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>
could be a function of aerosol properties (e.g., absorption), surface
characteristics, and the mixed layer (e.g., stability and advection). From
the AERONET data in the region (Table 2), optical properties appear to be
consistent over the region. Thus surface or regional attributes are likely a
larger source of variability here. We hypothesized that such variability may
covary with mean regional surface temperature. In Fig. 8, the scatter plots
of <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula> vs. <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> are also plotted as a function of monthly mean
temperature at 18:00 UTC. To construct the monthly mean temperatures at
18:00 UTC for each ASOS site, daily observations within <inline-formula><mml:math display="inline"><mml:mo>±</mml:mo></mml:math></inline-formula>10 min of
18:00 UTC are averaged to represent the daily surface temperature at
18:00 UTC. Then, those daily 18:00 UTC values are averaged over the study
period of 15 June–14 July 2015, excluding observations from 29 June 2015
(Fig. 3g). Only ASOS sites having more than 20 daily averages are used. Data
pairs with monthly mean temperatures lower than 22 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, between
22 and 24.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, and greater than 24.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C (arbitrarily selected
numbers) are colored in blue, green, and red, respectively. Data points are
largely scattered for the cooler temperatures, representing the far eastern
region of the domain. However, steeper slopes are found for middle
temperature sites in comparison to those with warmer temperatures. Similar
behaviors are also found for all UKMO and NCEP model forecasts and analyses
(Table 4). This suggests that a higher absolute daytime smoke <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="italic">τ</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is
expected for areas with monthly mean temperatures of 22–24.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C in
comparison with regions that are typically warmer. On the other hand, a higher absolute
daytime smoke <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="italic">τ</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is expected for a colder region or a colder season.
This topic will be further explored in a companion paper.</p>
</sec>
<sec id="Ch1.S3.SS4.SSS2">
  <title>The 30 June case</title>
      <p>The second day of the event, 30 June, is less ideal in comparison with the
29 June case, as the smoke plume is less dense, clouds form within the
region, and the <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> field has a smaller spatial gradient. Additionally, the
Terra MODIS satellite overpasses are approximate 1 h ahead of the model
data at 18:00 UTC, and one should expect that both aerosol and temperature
fields may change within 1 h. However, as an occluded front was moving
into the Dakotas, the entire smoke air mass transited fairly uniformly into
the Upper Mississippi River Valley. Thus it is an interesting analysis to
make.</p>
      <p>Aerosol-induced surface cooling, while noisier, is nevertheless observable as
shown in Fig. 7. Figure 7d shows a Terra MODIS RGB image of the 30 June case
over the Upper Mississippi and Ohio Valley region. Similar to 29 June,
Fig. 7a and b include the scatter plots of regional
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mi mathvariant="normal">obs</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> and <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>T</mml:mi><mml:mrow><mml:mn>30</mml:mn><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> vs. Terra MODIS DT <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>. On average, there is a 2 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C
decrease in <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>T</mml:mi><mml:mrow><mml:mn>30</mml:mn><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> for an increase
in MODIS <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> to 4, roughly half the 29 June sensitivity. Examining
the ECMWF 30 h forecast, the model has low biases in the great lakes region,
which in part leads to this suppressed value.</p>
      <p>As shown in Sect. 3.4.1, similar analyses are conducted for the ECMWF-, UKMO-,
and NCEP-modeled near-surface air temperatures for the Mississippi and Ohio
Valley region, as shown in Table 5. Again, smoke-aerosol-induced surface
cooling is found for all nine scenarios (0, 24, and 48 h forecasts for UKMO
and NCEP, 0, 30, and 54 h forecasts for ECMWF). However, smaller daytime
smoke <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="italic">τ</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> values on the order of <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.25 to
<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C/<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> are found for the 30 June case in comparison
with the 29 June case. The smaller daytime smoke <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="italic">τ</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> values may be
partially due to a larger temporal difference between the model and satellite
data for the 30 June case; but again, this may also be a result of a
difference in the atmosphere, and atmospheric simulation in the Great Lakes
region.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T5" specific-use="star"><caption><p>Offsets (<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C) and slopes (<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C/<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>) of MODIS
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> vs. the differences between observed (using ground stations as
shown in Fig. 7d) and modeled near-surface air temperatures (at 18:00 UTC,
30 June 2015) from ECMWF, UKMO, and NCEP model runs. Similar results for
stations with monthly mean temperatures (<inline-formula><mml:math display="inline"><mml:mover accent="true"><mml:mi>T</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula>) less than
28 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C are also shown.</p></caption><oasis:table frame="topbot"><oasis:tgroup cols="4">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:thead>
       <oasis:row>  
         <oasis:entry colname="col1">Offset/slope</oasis:entry>  
         <oasis:entry colname="col2">ECMWF</oasis:entry>  
         <oasis:entry colname="col3">UKMO</oasis:entry>  
         <oasis:entry colname="col4">NCEP</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2">(<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C)/(<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C/<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>)</oasis:entry>  
         <oasis:entry colname="col3">(<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C)/(<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C/<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>)</oasis:entry>  
         <oasis:entry colname="col4">(<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C)/(<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C/<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>)</oasis:entry>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>  
         <oasis:entry colname="col1">0 h forecast</oasis:entry>  
         <oasis:entry colname="col2"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.01/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.29</oasis:entry>  
         <oasis:entry colname="col3">0.08/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.25</oasis:entry>  
         <oasis:entry colname="col4"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.60/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.17</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1">(<inline-formula><mml:math display="inline"><mml:mover accent="true"><mml:mi>T</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula> &lt; 28 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C)</oasis:entry>  
         <oasis:entry colname="col2">(0.24/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.41)</oasis:entry>  
         <oasis:entry colname="col3">(0.27/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.43)</oasis:entry>  
         <oasis:entry colname="col4">(<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.14/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.33)</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">24(30) h forecast</oasis:entry>  
         <oasis:entry colname="col2">0.18/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.52</oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.27/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.30</oasis:entry>  
         <oasis:entry colname="col4">0.78/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.42</oasis:entry>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1">(<inline-formula><mml:math display="inline"><mml:mover accent="true"><mml:mi>T</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula> &lt; 28 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C)</oasis:entry>  
         <oasis:entry colname="col2">(1.76/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.05)</oasis:entry>  
         <oasis:entry colname="col3">(<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.57/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.57)</oasis:entry>  
         <oasis:entry colname="col4">(1.61/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.62)</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">48(54) h forecast</oasis:entry>  
         <oasis:entry colname="col2">0.17/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.20</oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.46/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.29</oasis:entry>  
         <oasis:entry colname="col4">1.20/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.44</oasis:entry>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">(<inline-formula><mml:math display="inline"><mml:mover accent="true"><mml:mi>T</mml:mi><mml:mo mathvariant="normal">‾</mml:mo></mml:mover></mml:math></inline-formula> &lt; 28 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C)</oasis:entry>  
         <oasis:entry colname="col2">(1.70/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.63)</oasis:entry>  
         <oasis:entry colname="col3">(<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.94/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.59)</oasis:entry>  
         <oasis:entry colname="col4">(1.67/<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.50)</oasis:entry>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup></oasis:table></table-wrap>

      <p>In addition, as suggested from Sect. 3.4.1, it is possible that daytime smoke
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="italic">τ</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> could be a function of surface temperature in itself. Compared
to the upper Midwest region, the Mississippi and Ohio River Valley are at
lower latitudes with warmer surface temperatures on average, and thus may
experience a smaller <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="italic">τ</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>. To test this hypothesis, monthly mean
surface air temperatures at 18:00 UTC are computed from ASOS data, following
similar steps mentioned in Sect. 3.4.1, but with 30 June 2015
instead of 29 June 2015 excluded from the monthly averages (Fig. 3h). With the constructed monthly mean temperatures for available ASOS
stations, the smoke aerosol <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="italic">τ</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> values are recomputed for all
nine scenarios (Table 5), but with the use of only ASOS stations that have
monthly mean temperatures lower than 28 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C. Lower daytime smoke
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="italic">τ</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> values on the order of <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.5 to <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.0 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C/<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> are found by restricting the study region to colder areas.
Still, these are only potential possibilities for the differences between
the 29 and 30 June cases.</p>
</sec>
</sec>
<sec id="Ch1.S3.SS5">
  <title>Cooling efficiencies as related to baseline uncertainties for the
modeled near-surface air temperature</title>
      <p>The question of how important the smoke cooling efficiency is to numerical
weather prediction is fundamentally related to the overall skill of the
natural model. Models with large root-mean-square errors (RMSEs) will mask
the aerosol signal; such models have more important sources of error. Models
with high skill, on the other hand, naturally are sensitive to higher order
terms. In this section, we examine this phenomenon and by evaluating
near-surface air temperature forecasts from ECMWF, UKMO, and NCEP in the
upper Midwest region with respect to smoke <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> for the 29 June case.
As the first step, baseline uncertainties in near-surface air temperatures
from NCEP, UKMO, and ECMWF model runs are evaluated (Table 6) using surface
observations from ground stations, as shown in Fig. 3g. To construct Table 6,
0-, 24(30), and 48(54) h model forecasts at 18:00 UTC from 15 June to
14 July are collocated with ground-based ASOS data (the numbers included in
parentheses are for ECMWF). The means of the differences between observed and forecasted
temperatures are computed for the 0, 24(30), and 48(54) h model forecasts and are represented by <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>T</mml:mi><mml:mrow><mml:mn mathvariant="normal">0</mml:mn><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>T</mml:mi><mml:mrow><mml:mn>24</mml:mn><mml:mo>/</mml:mo><mml:mn>30</mml:mn><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>, and <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>T</mml:mi><mml:mrow><mml:mn>48</mml:mn><mml:mo>/</mml:mo><mml:mn>54</mml:mn><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>,
respectively, in this study. Indicated in Table 6, similar <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>T</mml:mi><mml:mrow><mml:mn>48</mml:mn><mml:mo>/</mml:mo><mml:mn>54</mml:mn><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> values of around <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C with similar 1 standard
deviation of <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 2.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C are found for the 48 h forecasted
near-surface air temperatures from UKMO and NCEP. A smaller <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>T</mml:mi><mml:mrow><mml:mn>48</mml:mn><mml:mo>/</mml:mo><mml:mn>54</mml:mn><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> of <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.4 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, with a
smaller 1 standard deviation of 2.0 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, is found for the 54 h
forecasted 2 m air temperatures from ECMWF. <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>T</mml:mi><mml:mrow><mml:mn>24</mml:mn><mml:mo>/</mml:mo><mml:mn>30</mml:mn><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> and 1
standard derivation of <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>T</mml:mi><mml:mrow><mml:mn>24</mml:mn><mml:mo>/</mml:mo><mml:mn>30</mml:mn><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> of around <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.8 and
2.3 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C are found for the 24 h forecasted 2 m air temperatures for
NCEP, and the values are <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.6 and 2.1 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C for the 24 h forecasted
1.5 m air temperatures for UKMO. Again, smaller values of <inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:msub><mml:mi>T</mml:mi><mml:mrow><mml:mn>24</mml:mn><mml:mo>/</mml:mo><mml:mn>30</mml:mn><mml:mi mathvariant="normal">h</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula> and 1 standard derivation of <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.2 and 1.9 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C
are found for the 30 h forecasted 2 m air temperatures for ECMWF. In
comparison, the 0 h forecasts of near-surface air temperatures exhibit much
smaller standard derivations of the differences to the observed surface
temperatures; around 1.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C from all three models.</p>
      <p>The root-mean-square error (RMSE) values for the 0, 24(30), and 48(54) h
model-forecasted near-surface air temperatures are 2.3, 2.5, and
2.7 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C for NCEP data, 1.3, 2.2, and 2.7 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C for UKMO, and
1.6, 1.9, and 2.0 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C for ECMWF model runs, respectively. The same
analysis has also been conducted for the 30 June 2015 case. Not
surprisingly, the reported RMSE values are consistent for both the upper
Midwest and the Ohio River Valley regions. For example, the computed RMSE
values for the 30 June case are 1.5, 2.0, and 2.2 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C for
the 0, 30, and 54 h ECMWF forecasts. The RMSE values for the 0, 24, and
48 h NCEP and UKMO model forecasted near-surface air temperatures are 1.9,
2.2, 2.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, and 1.3, 2.1, 2.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, respectively.</p>

<?xmltex \floatpos{t}?><table-wrap id="Ch1.T6" specific-use="star"><caption><p>The means and 1 standard deviations (1 SD) of the differences in
observed and modeled near-surface air temperatures
(<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mrow><mml:mi mathvariant="normal">ground</mml:mi><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">FC</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula>) for 0-, 24-, and 48 h (0, 30, and 54 h for
ECMWF) forecasts for NCEP, UKMO, and ECMWF model runs over the upper Midwest
region. The modeled data are compared with surface temperature measurements
from ground stations as shown in Fig. 3g for the
period of 15 June–14 July 2015 (excluding 29 June 2015 data).</p></caption><oasis:table frame="topbot"><?xmltex \begin{scaleboxenv}{.97}[.97]?><oasis:tgroup cols="13">
     <oasis:colspec colnum="1" colname="col1" align="left"/>
     <oasis:colspec colnum="2" colname="col2" align="right"/>
     <oasis:colspec colnum="3" colname="col3" align="right"/>
     <oasis:colspec colnum="4" colname="col4" align="right"/>
     <oasis:colspec colnum="5" colname="col5" align="left"/>
     <oasis:colspec colnum="6" colname="col6" align="right"/>
     <oasis:colspec colnum="7" colname="col7" align="right"/>
     <oasis:colspec colnum="8" colname="col8" align="right"/>
     <oasis:colspec colnum="9" colname="col9" align="left"/>
     <oasis:colspec colnum="10" colname="col10" align="right"/>
     <oasis:colspec colnum="11" colname="col11" align="right"/>
     <oasis:colspec colnum="12" colname="col12" align="right"/>
     <oasis:colspec colnum="13" colname="col13" align="left"/>
     <oasis:thead>
       <oasis:row>  
         <oasis:entry colname="col1"/>  
         <oasis:entry namest="col2" nameend="col4" align="center">ECMWF </oasis:entry>  
         <oasis:entry colname="col5"/>  
         <oasis:entry namest="col6" nameend="col8" align="center">UKMO </oasis:entry>  
         <oasis:entry colname="col9"/>  
         <oasis:entry namest="col10" nameend="col12" align="center">NCEP </oasis:entry>  
         <oasis:entry colname="col13"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1"/>  
         <oasis:entry rowsep="1" namest="col2" nameend="col4" align="center">(<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C) </oasis:entry>  
         <oasis:entry colname="col5"/>  
         <oasis:entry rowsep="1" namest="col6" nameend="col8" align="center">(<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C) </oasis:entry>  
         <oasis:entry colname="col9"/>  
         <oasis:entry rowsep="1" namest="col10" nameend="col12" align="center">(<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C) </oasis:entry>  
         <oasis:entry colname="col13"/>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1"/>  
         <oasis:entry colname="col2">Analysis</oasis:entry>  
         <oasis:entry colname="col3">30 h</oasis:entry>  
         <oasis:entry colname="col4">54 h</oasis:entry>  
         <oasis:entry colname="col5"/>  
         <oasis:entry colname="col6">Analysis</oasis:entry>  
         <oasis:entry colname="col7">24 h</oasis:entry>  
         <oasis:entry colname="col8">48 h</oasis:entry>  
         <oasis:entry colname="col9"/>  
         <oasis:entry colname="col10">Analysis</oasis:entry>  
         <oasis:entry colname="col11">24 h</oasis:entry>  
         <oasis:entry colname="col12">48 h</oasis:entry>  
         <oasis:entry colname="col13"/>
       </oasis:row>
     </oasis:thead>
     <oasis:tbody>
       <oasis:row>  
         <oasis:entry colname="col1"><inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>T</mml:mi><mml:mrow><mml:mi mathvariant="normal">ground</mml:mi><mml:mtext>-</mml:mtext><mml:mi mathvariant="normal">FC</mml:mi></mml:mrow></mml:msub></mml:mrow></mml:math></inline-formula></oasis:entry>  
         <oasis:entry colname="col2"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.2</oasis:entry>  
         <oasis:entry colname="col3"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.2</oasis:entry>  
         <oasis:entry colname="col4"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.4</oasis:entry>  
         <oasis:entry colname="col5"/>  
         <oasis:entry colname="col6">0.0</oasis:entry>  
         <oasis:entry colname="col7"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.6</oasis:entry>  
         <oasis:entry colname="col8"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.8</oasis:entry>  
         <oasis:entry colname="col9"/>  
         <oasis:entry colname="col10"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.5</oasis:entry>  
         <oasis:entry colname="col11"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.8</oasis:entry>  
         <oasis:entry colname="col12"><inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.0</oasis:entry>  
         <oasis:entry colname="col13"/>
       </oasis:row>
       <oasis:row rowsep="1">  
         <oasis:entry colname="col1">1-SD</oasis:entry>  
         <oasis:entry colname="col2">1.5</oasis:entry>  
         <oasis:entry colname="col3">1.9</oasis:entry>  
         <oasis:entry colname="col4">2.0</oasis:entry>  
         <oasis:entry colname="col5"/>  
         <oasis:entry colname="col6">1.3</oasis:entry>  
         <oasis:entry colname="col7">2.1</oasis:entry>  
         <oasis:entry colname="col8">2.5</oasis:entry>  
         <oasis:entry colname="col9"/>  
         <oasis:entry colname="col10">1.8</oasis:entry>  
         <oasis:entry colname="col11">2.3</oasis:entry>  
         <oasis:entry colname="col12">2.5</oasis:entry>  
         <oasis:entry colname="col13"/>
       </oasis:row>
       <oasis:row>  
         <oasis:entry colname="col1">RMSE</oasis:entry>  
         <oasis:entry colname="col2">1.6</oasis:entry>  
         <oasis:entry colname="col3">1.9</oasis:entry>  
         <oasis:entry colname="col4">2.0</oasis:entry>  
         <oasis:entry colname="col5"/>  
         <oasis:entry colname="col6">1.3</oasis:entry>  
         <oasis:entry colname="col7">2.2</oasis:entry>  
         <oasis:entry colname="col8">2.7</oasis:entry>  
         <oasis:entry colname="col9"/>  
         <oasis:entry colname="col10">2.3</oasis:entry>  
         <oasis:entry colname="col11">2.5</oasis:entry>  
         <oasis:entry colname="col12">2.7</oasis:entry>  
         <oasis:entry colname="col13"/>
       </oasis:row>
     </oasis:tbody>
   </oasis:tgroup><?xmltex \end{scaleboxenv}?></oasis:table></table-wrap>

      <p>The RMSE values represent the baseline cases for the modeled uncertainty in
near-surface air temperatures. Theoretically, the effect of aerosols on
weather forecasts can likely be detected if the aerosol-induced surface
cooling is larger than the baseline uncertainties in the modeled near-surface
air temperatures. Given a rough estimation of
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C/<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> for the daytime smoke <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="italic">τ</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>,
the changes in <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> need to be above <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1.5–2 for the aerosol-induced cooling effect to be observable from the 48(54) h model forecasts.
Similarly, <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> values of <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1–1.5 and <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1.5 are required
for the aerosol-induced cooling effect to be detectable from the 0 and
24(30) h model forecasts.</p>
</sec>
</sec>
<sec id="Ch1.S4">
  <title>Application: straw assessment on a global scale</title>
      <p>It is suggested from Sect. 3 that smoke aerosol plumes have a daytime
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="italic">τ</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> on the order of <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.25 to <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C/<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>; yet RMSE values estimated over the study region for the
modeled near-surface air temperatures from NCEP, UKMO, and ECMWF are on the
order of 1.3–2.3 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C for 0 h forecasts and are much larger for a
longer period of forecasts. Clearly, even with the inclusion of perfect
aerosol fields in numerical models, the impact of aerosol particles on near-surface temperature forecasts are unlikely to be observable due to the
inherent uncertainties in numerical model simulations. An exception to this
is a region experiencing very high AOTs, in particular a sharp change in
aerosol loading of a significant amount (e.g., daily <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> change
&gt; 1 for aerosol effects to be observable from 0 h, near-surface
air temperature forecasts).</p>
      <p>Next, we assume the <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C/<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>
daytime <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="italic">τ</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> is applicable to all aerosol types and the estimated
RMSE values from over the study region are applicable on a global scale.
Regions whose near-surface air temperature forecasts could potentially be
affected by aerosol plumes with a detectable signal are studied. Note that
only sharp daily changes in AOT can introduce detectable signals in weather
forecasts: for a region with persistent high aerosol loading, the aerosol
cooling effects are likely to be accounted for through assimilating
meteorological-based observations that are impacted by aerosol particles. As
mentioned above, for the aerosol direct cooling effect to be detectable on
0 h near-surface air temperature forecasts, a minimum sharp daily <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> change of approximately 1 is required. Therefore, using 1 year
of Collection 6 MODIS Dark Target (DT) and Deep Blue (DB) aerosol products
from both Aqua and Terra, we have studied regions that have sharp daily AOT
changes above 1.</p>
      <p>For illustration purposes, Fig. 9a and b show the spatial distribution of
yearly mean MODIS AOT and the number of days with MODIS <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> larger
than 1, respectively, at a spatial resolution of 0.5<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>
(latitude/longitude), constructed using C6 Aqua and Terra aerosol products
for 2014. The combined DT and DB data, which are included in C6 MODIS aerosol
products, are used. Additionally, “bad” retrievals, as indicated by the quality assurance flag included in the products, are discarded.</p>

      <?xmltex \floatpos{t}?><fig id="Ch1.F9"><caption><p><bold>(a)</bold> Yearly averaged, 0.5 <inline-formula><mml:math display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 0.5<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>
(latitude/longitude) binned <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> from the Collection 6 Aqua and Terra
MODIS combined DT and DB aerosol products for 2014; <bold>(b)</bold> the number
of days with daily mean MODIS <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> larger than 1 for a given
0.5 <inline-formula><mml:math display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 0.5<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> (latitude/longitude) bin; <bold>(c)</bold> the number
of cases when an absolute change in daily MODIS <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> of above 1 is
detected from two contiguous days for a given 0.5 <inline-formula><mml:math display="inline"><mml:mo>×</mml:mo></mml:math></inline-formula> 0.5<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>
(latitude/longitude) bin.</p></caption>
        <?xmltex \igopts{width=199.169291pt}?><graphic xlink:href="https://acp.copernicus.org/articles/16/6475/2016/acp-16-6475-2016-f09.pdf"/>

      </fig>

      <p>The global yearly average <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>, as shown in Fig. 9a, is
consistent with the spatial <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> distributions as reported from
previous studies (e.g., Levy et al., 2013; Zhang and Reid, 2010). In addition, not
surprisingly, regions with MODIS <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> larger than 1 (Fig. 9b),
which include central and northern Africa, the Middle East, India, eastern Asia,
southeastern Asia, and upper North America. In particular, over India and
eastern China, the number of <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>-larger-than-1 days exceeds 2 months,
indicating potential severe aerosol pollution issues for the two regions.</p>
      <p>Using the MODIS aerosol products as shown in Fig. 9a and b, the
0.5<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> (latitude/longitude) gridded daily AOT data from a given day
are compared with the gridded daily AOT data from the next day. If a change
in <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> of larger than 1.0 is found for a 0.5<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> (latitude/longitude) grid box, the event is recorded. Figure 9(c) shows the
global distribution of the number of cases when sharp changes of <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> of &gt; 1 are detected for a 0.5<inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula> (latitude/longitude) grid box. A total of 1 year (2014) of Terra and Aqua
combined DT and DB <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> data are used. However, the average
number of cases with sharp <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> changes are rather low in
general, indicating that even by incorporating an accurate aerosol field in
a numerical model, the aerosol-induced surface cooling effect would remain
mostly undetected for the 0 h forecast due to relatively larger
uncertainties in modeled near-surface air temperatures. Still, Fig. 9c
suggests that for regions such as eastern China, eastern Russia, India, and
portions of the Saharan and Taklamakan deserts, sharp changes in <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> of above 1 happen more than 10 times a year. These are the regions
where incorporating aerosol models is likely to have the most impact on
weather forecasts of near-surface air temperatures.</p>
      <p>Lastly, readers should be aware that aerosol plumes with extreme high aerosol
loadings could be misidentified as clouds; thus these aerosol plumes could be
excluded from the MODIS DT/DB retrievals (e.g., Alfaro-Contreras et al.,
2016). Therefore, the frequency distribution of the sharp aerosol loading
changes, as shown in Fig. 9c, is likely underestimated. Still, this is the
first attempt at such efforts, and is worth reporting.</p>
</sec>
<sec id="Ch1.S5" sec-type="conclusions">
  <title>Conclusions and implications</title>
      <p>In this study, the effect of smoke aerosol plumes on 2 m (1.5 m for the UKMO
model) air temperature forecasts from European Centre for Medium-Range
Weather Forecasts (ECMWF), National Centers for Environmental Prediction
(NCEP), and United Kingdom Meteorological Office (UKMO) models are investigated
over a significant smoke aerosol event that happened on 28–30 June 2015 over the Midwestern United States. The smoke-aerosol-induced
daytime direct surface cooling effect is studied and the baseline
uncertainties in the modeled near-surface air temperatures are evaluated
over the study domain. This study suggests the following.
<list list-type="order"><list-item><p>Consistent with several previous studies, the 29 June 2015 smoke
event introduced a noticeable surface cooling of <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C over Grand Forks, ND. The smoke-aerosol-induced daytime
direct surface cooling efficiency (<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="italic">τ</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula>) is estimated to be
<inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C per 1.0 AOT (550 nm, <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>).</p></list-item><list-item><p>The differences in observed near-surface air
temperatures and modeled 2 m/1.5 m air temperatures from NCEP, UKMO, and
ECMWF models (<inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula>) are studied as a function of MODIS <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> for
0, 24, and 48 h forecasts (0, 30, and 54 h forecasts for the ECMWF model)
for the 29 June 2015 smoke event. All nine cases show a clear decrease in
<inline-formula><mml:math display="inline"><mml:mrow><mml:mi mathvariant="normal">Δ</mml:mi><mml:mi>T</mml:mi></mml:mrow></mml:math></inline-formula> as <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> increases to 4, indicating that the smoke event
does have an observable cooling effect on the near-surface air temperature
forecasts, with an estimated daytime <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="italic">τ</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> on the order of <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.5 to
<inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C per unit <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>. Those <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="italic">τ</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> values are still
likely to be affected by uncertainties in modeled temperatures.</p></list-item><list-item><p>Similar analysis was also conducted on 30 June 2015 over the Ohio
River Valley. Again, the smoke-aerosol-plume-induced surface cooling is
found from all nine scenarios, however with a smaller (in magnitude) daytime
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="italic">τ</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> on the order of <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.25 to <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>0.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C per
unit <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>. Further analysis seems to indicate that <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="italic">τ</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> may also be a function of surface temperature, and a smaller (in
magnitude) daytime <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="italic">τ</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> may be expected over a warmer region. This
hypothesis will be further examined in a modeling-based paper.</p></list-item><list-item><p>Using 1 month of observed surface temperatures from the study region,
baseline uncertainties for near-surface air temperatures from the 0, 24(30),
and 48(54) h forecasts are estimated to be 1.3–2.3,
1.9–2.5, and 2.0–2.7 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, respectively.
Thus, for the aerosol-induced direct cooling effect to be observable from the
0 h model forecasted near-surface air temperature fields, a daily change in
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> of <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1.0–1.5 (550 nm) is needed. Similar requirements in
<inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> of <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1.5 and <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> 1.5–2.0 are needed for the aerosol
direct cooling effect to be detected from 24(30) and 48(54) h forecasted
near-surface air temperature fields respectively, assuming the estimated
daytime <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi>C</mml:mi><mml:mi mathvariant="italic">τ</mml:mi></mml:msub></mml:mrow></mml:math></inline-formula> of <inline-formula><mml:math display="inline"><mml:mo>∼</mml:mo></mml:math></inline-formula> <inline-formula><mml:math display="inline"><mml:mo>-</mml:mo></mml:math></inline-formula>1.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C per unit <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> is
applicable to all cases.</p></list-item><list-item><p>Using 1 year of Terra and Aqua Collection 6 MODIS combined Dark Target and
Deep Blue aerosol products, the number of days with significant changes in
daily <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> of &gt; 1 are estimated. Globally, events with
a daily <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> change of &gt; 1 are rare, indicating that
at the current stage, incorporating aerosol models in-line with a weather
forecasting model is unlikely to introduce a noticeable improvement in the
forecasted near-surface air temperatures. Still, for regions such as eastern
China, eastern Russia, India, and portions of Saharan and Taklamakan deserts,
the number of days with sharp <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula> changes is above 10 for the
year 2014, showing that accurate aerosol analysis may be needed for weather
forecasts for these regions.</p></list-item><list-item><p>Note that this study is focused on cloud-free conditions and only the direct
smoke aerosol surface cooling effect is studied. Still, aerosol particles may
indirectly affect weather by altering cloud microphysics in both stratiform
and convective clouds (e.g., Tao et al., 2012). Such effects warrant further
discussions and evaluations.</p></list-item></list></p>
      <p>Through an observational-based analysis, this study suggests that aerosol
particles do have an observable cooling effect on near-surface air
temperatures. In a companion paper, the aerosol-induced direct cooling effect
will be further explored from a modeling perspective with the use of a
numerical model in-line with an aerosol transport
model.<?xmltex \hack{\vadjust{\newpage}}?> Lastly, we expect, with the improvement in
accuracy of numerical forecasting models in the future, that the inclusion of
accurate aerosol estimates will be unavoidable for the further improvement of
numerical weather forecasts.</p>
<sec id="Ch1.S5.SSx1" specific-use="unnumbered">
  <title>Data availability</title>
      <p>The deterministic forecasts from ECMWF were obtained from Angela Benedetti.
All other data sources were obtained online with data links mentioned in the
data set section (accessed on or before 1 December 2015).</p><?xmltex \hack{\clearpage}?>
</sec>
</sec>

      
      </body>
    <back><app-group>

<app id="App1.Ch1.S1">
  <title/>

      <?xmltex \floatpos{h!}?><fig id="App1.Ch1.F1"><caption><p><bold>(a–c)</bold> 0, 24, and 48 h forecasts of 1.5 m air
temperatures for the study region as shown in Fig. 3a at 18:00 UTC, 29 June
2015, from UKMO model runs. <bold>(d–f)</bold> The differences between surface
observations (using ground stations as shown in
Fig. 3c) and UKMO-modeled 1.5 m temperatures (at 18:00 UTC, 29 June 2015) as a function of
Collection 6 Terra MODIS DT <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>. Data pairs are colored based on the
observed monthly mean surface temperatures at 18:00 UTC as shown in Fig. 3g.
Data pairs for regions with monthly mean temperatures of
&lt; 22 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C, between 22 and 24.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C and
&gt; 24.5 <inline-formula><mml:math display="inline"><mml:msup><mml:mi/><mml:mo>∘</mml:mo></mml:msup></mml:math></inline-formula>C are colored in blue, green, and red
respectively. Red dashed lines are the linear fit lines to the data pairs
with red colors, and green dashed lines are the linear fit lines for data
pairs with green colors.</p></caption>
        <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://acp.copernicus.org/articles/16/6475/2016/acp-16-6475-2016-f10.pdf"/>

      </fig>

<?xmltex \hack{\newpage}?><?xmltex \floatpos{h!}?><fig id="App1.Ch1.F2"><caption><p><bold>(a–c)</bold> 0, 24, and 48 h forecasts of 2 m air temperatures
for the study region as shown in Fig. 3a at 18:00 UTC, 29 June 2015, from
NCEP model runs. <bold>(d–f)</bold> The differences between surface observations (using
ground stations as shown in Fig. 3c) and NCEP-modeled 2 m
temperatures (at 18:00 UTC, 29 June 2015) as a function of Collection 6 Terra MODIS DT <inline-formula><mml:math display="inline"><mml:mrow><mml:msub><mml:mi mathvariant="italic">τ</mml:mi><mml:mn>550</mml:mn></mml:msub></mml:mrow></mml:math></inline-formula>. Others are similar
to Fig. A1.</p></caption>
        <?xmltex \igopts{width=241.848425pt}?><graphic xlink:href="https://acp.copernicus.org/articles/16/6475/2016/acp-16-6475-2016-f11.pdf"/>

      </fig>

<?xmltex \hack{\clearpage}?>
</app>
  </app-group><ack><title>Acknowledgements</title><p>Authors Jianglong Zhang and Matthew Christensen acknowledge the support of
the NASA project NNX14AJ13G and the NSF project IIA-1355466. Author
Jeffrey S. Reid was supported by ONR Code 322 (N0001415WX00854). We thank the
THORPEX Interactive Grand Global Ensemble (TIGGE) group for the NCEP and UK
Met Office model data. We thank the Iowa Environmental Mesonet (IEM) for
surface-based meteorological observations. We also thank the AERONET program
and their affiliated members for the surface-based aerosol optical property
measurements. We further thank Morgan M. Simms for obtaining NWS related
weather data. Editorial support from E. A. Reid is gratefully
acknowledged.<?xmltex \hack{\newline}?><?xmltex \hack{\newline}?> Edited by: H. Wang</p></ack><ref-list>
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    <!--<article-title-html>An evaluation of the impact of aerosol particles on weather forecasts
from a biomass burning aerosol event over the Midwestern United States:
observational-based analysis of surface temperature</article-title-html>
<abstract-html><p class="p">A major continental-scale biomass burning smoke event from 28–30 June 2015,
spanning central Canada through the eastern seaboard of the United States,
resulted in unforecasted drops in daytime high surface temperatures on the
order of 2–5  °C in the upper Midwest. This event, with strong smoke
gradients and largely cloud-free conditions, provides a natural laboratory
to study how aerosol radiative effects may influence numerical weather
prediction (NWP) forecast outcomes. Here, we describe the nature of this
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forecasts and analyses. For this event, mid-visible (550 nm) smoke aerosol
optical thickness (AOT, <i>τ</i>) reached values above 5. A direct surface
cooling efficiency of −1.5 °C per unit AOT (at 550 nm, <i>τ</i><sub>550</sub>) was found. A further analysis of European Centre for Medium-Range
Weather Forecasts (ECMWF), National Centers for Environmental Prediction
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temperature forecasts for up to 54 h as a function of Moderate
Resolution Imaging Spectroradiometer (MODIS) Dark Target AOT data across
more than 400 surface stations, also indicated the presence of the daytime
aerosol direct cooling effect, but suggested a smaller aerosol direct
surface cooling efficiency with magnitude on the order of −0.25
to −1.0 °C per unit <i>τ</i><sub>550</sub>. In addition, using
observations from the surface stations, uncertainties in near-surface air
temperatures from ECMWF, NCEP, and UKMO model runs are estimated. This study
further suggests that significant daily changes in <i>τ</i><sub>550</sub> above 1,
at which the smoke-aerosol-induced direct surface cooling effect could be
comparable in magnitude with model uncertainties, are rare events on a
global scale. Thus, incorporating a more realistic smoke aerosol field into
numerical models is currently less likely to significantly improve the
accuracy of near-surface air temperature forecasts. However, regions such as
eastern China, eastern Russia, India, and portions of the Saharan and Taklamakan
deserts, where significant daily changes in AOTs are more frequent, are
likely to benefit from including an accurate aerosol analysis into numerical
weather forecasts.</p></abstract-html>
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